Corporate Presentation - September 2022 - Mining Data Online

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Corporate Presentation - September 2022 - Mining Data Online
Corporate Presentation
        September 2022
Corporate Presentation - September 2022 - Mining Data Online
Disclaimer
No Offer or Solicitation Regarding Securities

This presentation has been prepared by Sigma Lithium Corporation (“Sigma”) for general information purposes only and does not constitute an offer to sell or a solicitation of an offer to buy any securities of Sigma or its affiliates in any jurisdiction, including but not limited to Canada and the United
States. The contents of this presentation should not be interpreted as financial, investment, tax, legal, or accounting advice. Readers should consult their own advisors.

The contents of this presentation have not been approved or disapproved by any securities commission or regulatory authority in United States or Canada or any other jurisdiction, and Sigma expressly disclaims any responsibility to make disclosures or any filings with any securities commission or
regulatory authority, beyond that imposed by applicable laws.

Cautionary Note Regarding Forward-Looking Statements

This presentation contains “forward-looking information” within the meaning of applicable Canadian securities legislation and “forward-looking statements” within the meaning of applicable United States securities laws (collectively referred to herein as “Forward Looking Information”). All such Forward
Looking Information is made under the provisions of the U.S. Private Securities Litigation Reform Act of 1995, Section 27A of the U.S. Securities Act of 1933, as amended and Section 21E of the U.S. Securities Exchange Act of 1934, as amended. All statements, other than statements of historical fact,
may be Forward Looking Information, including, but not limited to, mineral resource or mineral reserve estimates (which reflect a prediction of mineralization that would be realized by development). When used in this presentation, such statements generally use words such as “may”, “would”, “could”,
“will”, “intend”, “expect”, “believe”, “plan”, “anticipate”, “estimate” and other similar terminology. These statements reflect management’s current expectations regarding future events and operating performance and speak only as of the date such statements were made. Forward Looking Information
involves significant risks and uncertainties, should not be read as guarantees of future performance or results, and does not necessarily provide accurate indications of whether or not such results will be achieved. A number of factors could cause actual results to differ materially from the results
discussed in the Forward-Looking Information, which is based upon what management believes are reasonable assumptions, and there can be no assurance that actual results will be consistent with the Forward-Looking Information.

In particular (but without limitation), this presentation contains Forward Looking Information with respect to the following matters: the lithium sector and long-term outlook thereof; the growth of European electric vehicle (“EV”) demand; anticipated trends relating to lithium structural supply tightness;
development, construction and large scale production at Sigma’s Grota do Cirilo Lithium Project (the “Project”) and the phases and timing thereof; sustainability and environmental initiatives and the continued success thereof; processing production costs and other cost estimates; the quality and
grades of lithium concentrates; publishing of additional pre-feasibility and feasibility studies; expansion of mineral resources and mineral reserves at the Project; intentions to fund construction using debt from commercial and development banks; anticipated start-up costs at the Project; relationships
with engineering and construction companies; anticipated risk mitigation and execution plans; the adherence by Sigma to global environmental guidance; and economic performance, financial projections and requirements, and other expectations of Sigma. In addition, documents referred to in this
presentation and filed publicly by Sigma may contain further Forward-Looking Information with respect to the following matters: anticipated decision making with respect to the Project; capital expenditure programs; estimates of mineral resources and mineral reserves; development of mineral
resources and mineral reserves; government regulation of mining operations and treatment under governmental and taxation regimes; the future price of commodities, including lithium; the realization of mineral resource and mineral reserve estimates, including whether mineral resources will ever be
developed into mineral reserves; the timing and amount of future production; entering into binding offtake arrangements; currency exchange and interest rates; expected outcome and timing of environmental surveys and permit applications and other environmental matters; Sigma’s ability to raise
capital and obtain project financing; expected expenditures to be made by Sigma on its properties; successful operations and the timing, cost, quantity, capacity and quality of production; capital costs, operating costs and sustaining capital requirements, including the cost of construction of the
processing plant for the Project; competitive conditions and anticipated trends post-COVID-19 pandemic and the ongoing uncertainties and effects in respect of the COVID-19 pandemic.

Forward Looking Information does not take into account the effect of transactions or other items announced or occurring after the statements are made. Forward Looking Information is based upon a number of expectations and assumptions and is subject to a number of risks and uncertainties, many
of which are beyond Sigma’s control, that could cause actual results to differ materially from those disclosed in or implied by such Forward Looking Information. With respect to the Forward Looking Information, Sigma has made assumptions regarding, among other things: General economic and
political conditions; Stable and supportive legislative, regulatory and community environment in the jurisdictions where Sigma operates; Stability and inflation of the Brazilian Real, including any foreign exchange or capital controls which may be enacted in respect thereof, and the effect of current or
any additional regulations on Sigma’s operations; Anticipated trends and effects in respect of the COVID-19 pandemic and post-pandemic; Demand for lithium, including that such demand is supported by growth in the EV market; Estimates of, and changes to, the market prices for lithium; The impact
of increasing competition in the lithium business and Sigma’s competitive position in the industry; Sigma’s market position and future financial and operating performance; Sigma’s estimates of mineral resources and mineral reserves, including whether mineral resources will ever be developed into
mineral reserves; Anticipated timing and results of exploration, development and construction activities; Reliability of technical data; Sigma’s ability to develop and achieve production at the Project; Sigma’s ability to obtain financing on satisfactory terms to develop the Project; Sigma’s ability to obtain
and maintain mining, exploration, environmental and other permits, authorizations and approvals for the Project; The timing and possible outcome of regulatory and permitting matters for the Project; The exploration, development, construction and operational costs for the Project; The accuracy of
budget, construction and operations estimates for the Project; Successful negotiation of definitive commercial agreements, including off-take agreements for the Project; Sigma’s ability to operate in a safe and effective manner.

Although management believes that the assumptions and expectations reflected in such Forward-Looking Information are reasonable, there can be no assurance that these assumptions and expectations will prove to be correct. Since Forward Looking Information inherently involves risks and
uncertainties, undue reliance should not be placed on such information. Sigma’s actual results could differ materially from those anticipated in any Forward-Looking Information as a result of various known and unknown risk factors, including (but not limited to) the risk factors referred to under the
heading “Risk Factors” in the most recent amended and restated annual information form of Sigma. Such risks relate to, but are not limited to, the following: Sigma may not develop the Project into a commercial mining operation; There can be no assurance that market prices for lithium will remain at
current levels or that such prices will improve; The market for EVs and other large format batteries currently has limited market share and no assurances can be given for the rate at which this market will develop, if at all, which could affect the success of Sigma and its ability to develop lithium
operations; Changes in technology or other developments could result in preferences for substitute products; New production of lithium hydroxide or lithium carbonate from current or new competitors in the lithium markets could adversely affect prices; The Project is at development stage and
Sigma’s ability to succeed in progressing through development to commercial operations will depend on a number of factors, some of which may be outside its control; Sigma’s financial condition, operations and results of any future operations are subject to political, economic, social, regulatory and
geographic risks of doing business in Brazil; Violations of anti-corruption, anti-bribery, anti-money laundering and economic sanctions laws and regulations could materially adversely affect Sigma’s business, reputation, results of any future operations and financial condition; Sigma is subject to
regulatory frameworks applicable to the Brazilian mining industry which could be subject to further change, as well as government approval and permitting requirements, which may result in limitations on Sigma’s business and activities; Sigma’s operations are subject to numerous environmental laws
and regulations and expose Sigma to environmental compliance risks, which may result in significant costs and have the potential to reduce the profitability of operations; Physical climate change events and the trend toward more stringent regulations aimed at reducing the effects of climate change
could have an adverse effect on Sigma’s business and future operations; As Sigma does not have any experience in the construction and operation of a mine, processing plants and related infrastructure, it is more difficult to evaluate Sigma’s prospects, and Sigma’s future success is more uncertain
than if it had a more proven history of developing a mine; Sigma’s future production estimates are based on existing mine plans and other assumptions which change from time to time. No assurance can be given that such estimates will be achieved; Sigma may experience unexpected costs and cost
overruns, problems and delays during construction, development, mine start-up and operations for reasons outside of Sigma’s control, which have the potential to materially affect its ability to fully fund required expenditures and/or production or, alternatively, may require Sigma to consider less
attractive financing solutions; Sigma’s capital and operating cost estimates may vary from actual costs and revenues for reasons outside of Sigma’s control; Sigma’s operations are subject to the high degree of risk normally incidental to the exploration for, and the development and operation of,
mineral properties; Insurance may not be available to insure against all such risks, or the costs of such insurance may be uneconomic. Losses from uninsured and underinsured losses have the potential to materially affect Sigma’s financial position and prospects; Sigma is subject to risks associated
with securing title and property interests; Sigma is subject to strong competition in Brazil and in the global mining industry; Sigma may become subject to government orders, investigations, inquiries or other proceedings (including civil claims) relating to health and safety matters, which could result in
consequences material to its business and operations; Sigma’s mineral resource and mineral reserve estimates are estimates only and no assurance can be given that any particular level of recovery of minerals will in fact be realized or that identified mineral resources or mineral reserves will ever
qualify as a commercially mineable (or viable) deposit; Sigma’s operations and the development of its projects may be adversely affected if it is unable to maintain positive community relations; Sigma is exposed to risks associated with doing business with counterparties, which may impact Sigma’s
operations and financial condition; Any limitation on the transfer of cash or other assets between Sigma and Sigma’s subsidiaries, or among such entities, could restrict Sigma’s ability to fund its operations efficiently; Sigma is subject to risks associated with its reliance on consultants and others for
mineral exploration and exploitation expertise; The current COVID-19 pandemic could have a material adverse effect on Sigma’s business, operations, financial condition and stock price; If Sigma is unable to ultimately generate sufficient revenues to become profitable and have positive cash flows, it
could have a material adverse effect on its prospects, business, financial condition, results of operations or overall viability as an operating business (…)

       High Purity Lithium, Responsibly Sourced                                                                                                                                                                                                                                                               page 2
Corporate Presentation - September 2022 - Mining Data Online
Disclaimer
(…) Sigma is subject to liquidity risk and therefore may have to include a “going concern” note in its financial statements; Sigma may not be able to obtain sufficient financing in the future on acceptable terms, which could have a material adverse effect on Sigma’s business, results of operations and
financial condition. In order to obtain additional financing, Sigma may conduct additional (and possibly dilutive) equity offerings or debt issuances in the future; Sigma may be unable to achieve cash flow from operating activities sufficient to permit it to pay the principal, premium, if any, and interest on
Sigma’s indebtedness, or maintain its debt covenants; Sigma has not declared or paid dividends in the past and may not declare or pay dividends in the future; Sigma will incur increased costs as a result of being a public company both in Canada listed on the TSXV and in the United States listed on
Nasdaq, and its management will be required to devote further substantial time to United States public company compliance efforts; If Sigma does not maintain adequate and appropriate internal controls over financial reporting as outlined in accordance with National Instrument 52-109 – Certification
of Disclosure in Issuers’ Annual and Interim Filings or the rules and regulations of the U.S. Securities and Exchange Commission (the “SEC”), Sigma will have to report a material weakness and disclose that Sigma has not maintained appropriate internal controls over financial reporting; As a foreign
private issuer, Sigma is subject to different U.S. securities laws and rules than a domestic U.S. issuer, which may limit the information publicly available to its shareholders; Failure to retain key officers, consultants and employees or to attract and, if attracted, retain additional key individuals with
necessary skills could have a materially adverse impact upon Sigma’s success; Sigma is subject to currency fluctuation risks; From time to time, Sigma may become involved in litigation, which may have a material adverse effect on its business financial condition and prospects; Certain directors and
officers of Sigma are, or may become, associated with other natural resource companies which may give rise to conflicts of interest; The market price for Sigma’s shares may be volatile and subject to wide fluctuations in response to numerous factors beyond its control, and Sigma may be subject to
securities litigation as a result; If securities or industry analysts do not publish research or reports about Sigma’s business, or if they downgrade the common shares of Sigma (the “Common Shares”), the price of the Common Shares could decline; Sigma will have broad discretion over the use of the
net proceeds from offerings of its securities; There is no guarantee that the Common Shares will earn any positive return in the short term or long term; Sigma has a major shareholder which owns 47.7% of the outstanding Common Shares and, as such, for as long as such shareholder directly or
indirectly maintains a significant interest in Sigma, it may be in a position to affect Sigma’s governance, operations and the market price of the Common Shares; As Sigma is a Canadian corporation but most of its directors and officers are not citizens or residents of Canada or the U.S., it may be
difficult or impossible for an investor to enforce judgements against Sigma and its directors and officers outside of Canada and the U.S. which may have been obtained in Canadian or U.S. courts or initiate court action outside Canada or the U.S. against Sigma and its directors and officers in respect of
an alleged breach of securities laws or otherwise. Similarly, it may be difficult for U.S. shareholders to effect service on Sigma to realize on judgments obtained in the United States; Sigma is governed by the corporate and securities laws of the Province of Ontario and of Canada, which in some cases
have a different effect on shareholders than U.S. corporate laws and U.S. securities laws; Sigma is subject to risks associated with its information technology systems and cyber-security; Sigma may be a Passive Foreign Investment Company, which may result in adverse U.S. federal income tax
consequences for U.S. holders of Common Shares.

Readers are cautioned that the foregoing lists of assumptions and risks is not exhaustive. The Forward-Looking Information contained in this presentation is expressly qualified by these cautionary statements. All Forward Looking Information in this presentation speaks as of the date of such
statements were made, as applicable. Sigma does not undertake any obligation to update or revise any Forward-Looking Information, whether as a result of new information, future events or otherwise, except as required by applicable securities law. Additional information about these assumptions,
risks and uncertainties is contained in Sigma’s filings with securities regulators, including Sigma’s then-current annual information form, which are available on SEDAR at www.sedar.com. and on EDGAR at www.sec.gov.

Cautionary Note Regarding Mineral Resource and Mineral Reserve Estimates

Technical disclosure regarding Sigma’s properties included in this presentation has not been prepared in accordance with the requirements of U.S. securities laws. Without limiting the foregoing, such technical disclosure uses terms that comply with reporting standards in Canada and estimates are
made in accordance with National Instrument 43-101 – Standards of Disclosure for Mineral Projects (“NI 43-101”). Unless otherwise indicated, all mineral reserve and mineral resource estimates contained in the technical disclosure have been prepared in accordance with NI 43-101 and the Canadian
Institute of Mining, Metallurgy and Petroleum Definition Standards on Mineral Resources and Reserves (the “CIM Definition Standards”).

Under the SEC rules regarding disclosure of technical information, the definitions of “proven mineral reserves” and “probable mineral reserves” are substantially similar to the corresponding CIM Definition Standards, and the SEC recognizes “measured mineral resources”, “indicated mineral resources”
and “inferred mineral resources” which are also substantially similar to the corresponding CIM Definition Standards. However, there are still differences in the definitions and standards under the SEC rules and the CIM Definition Standards. Therefore, Sigma’s mineral resources and reserves as
determined in accordance with NI 43-101 may be significantly different than if they had been determined in accordance with the SEC rules.

Third Party Information

This presentation includes market, industry, economic data and projections which was obtained from various publicly available sources and other sources believed by Sigma to be true. Although Sigma believes it to be reliable, it has not independently verified any of the data from third party sources
referred to in this presentation or analyzed or verified the underlying reports relied upon or referred to by such sources, or ascertained the underlying economic and other assumptions relied upon by such sources. Sigma believes that the market, industry and economic data is accurate and that the
estimates and assumptions are reasonable, but there can be no assurance as to the accuracy or completeness thereof. The accuracy and completeness of the market, industry and economic data in this presentation are not guaranteed, and Sigma does not make any representation as to the
accuracy or completeness of such information.

Technical Information

Wes Roberts, P.Eng., a member of the technical committee of Sigma, is the “qualified person” under NI 43-101 who reviewed and approved the technical information disclosed in this presentation.

Certain technical information in this presentation was derived from the technical report dated August 4, 2022, with an effective date of May 30, 2022, titled “Grota do Cirilo Lithium Project, Araçuaí and Itinga Regions, Minas Gerais, Brazil, Phase 3 Mineral Resource Estimate” and prepared by Homero
Delboni Jr, B.E., M.Eng.Sc., Ph.D., Marc-Antoine Laporte, P. Geo, Jarrett Quinn, P.Eng., Porifrio Cabaleiro Rodriguez, MEng., and Brian Talbot, FAusIMM, Rtek Pty Ltd. (the “Updated Technical Report”). The Updated Technical Report is available on the SEDAR profile of Sigma at www.sedar.com. Mineral
resources in the Updated Technical Report are reported inclusive of mineral reserves. Readers are advised that mineral resources that are not mineral reserves do not have demonstrated economic viability. Some figures herein have been rounded for presentation purposes. It is noted that Sigma has
not yet made a production decision in respect of the Barreiro deposit. Sigma expects that it will assess the results of a definitive feasibility study before making a production decision in respect of the Barreiro deposit. All statements regarding mine development or production in respect of the Barreiro
deposit in this presentation are expressly qualified by this statement.

Non-GAAP Measures

This presentation and the Updated Feasibility Study Report contain certain non-GAAP measures. The non-GAAP measures do not have any standardized meaning within IFRS and therefore may not be comparable to similar measures presented by other companies. These measures provide
information that is customary in the mining industry and that is useful in evaluating the Project. This data should not be considered as a substitute for measures of performance prepared in accordance with IFRS.

       High Purity Lithium, Responsibly Sourced                                                                                                                                                                                                                                                               page 3
Corporate Presentation - September 2022 - Mining Data Online
Sigma Lithium: Near Term Production
Building the world’s next tier-1 lithium operation, sustainably

1        Large-Scale Production of Battery Grade Lithium Concentrate:
         • Run-rate production of 531,000 tpa (72,200 t LCE)

2        Ongoing Construction is Fully Funded:
         • Greentech plant commissioning initiation planned for 2022

3        Projected to Supply a Tight Market in Deficit:
         • Lithium price inelasticity from 2022 to at least 2025

4        “Value-Added” High Quality Lithium:
         •      Unique direct offtake with LG – global battery producer

5        Global Leader in ESG:
         • Recognized at COP 25 & 26 and United Nations
    High Purity Lithium, Responsibly Sourced                              page 4
Corporate Presentation - September 2022 - Mining Data Online
Sigma Lithium: Greentech Business
Pioneered environmentally friendly high purity lithium production

  Green Mining:                              Greentech                        Batteries &    Aligned
  Dry Stacking                               Transformation                   Cathodes      End-Users

                                                Battery Grade Lithium
                                             Concentrate Spot: US$6,750 (1)

                                             Sigma Lithium EBITDA Margin @
 (1) Fastmarkets as of September 15, 2022.          US$2,247/t: 82%

  High Purity Lithium, Responsibly Sourced                                                              page 5
Corporate Presentation - September 2022 - Mining Data Online
Sigma Lithium: By the Numbers
The largest lithium project in the Americas

      PHASE 1 & 2 ONLY HIGHLIGHTS (BASED ON 2P RESERVES)                                           RESOURCE INVENTORY

 $5.1 B                                      589%              13 years          $455/t          33.6 Mt            73.6 Mt
        P 1 & 2 After-                        P 1 & 2 After-    P1&2              P 1 & 2 AISC     2P Reserves       M&I Resources
        Tax NPV8%                             Tax IRR           Operating Life    (CIF China)      (P 1 & 2 Only)    (Includes P3)

                                                                                                 12.1 Mt
                                             $111 M            270 kt/y          $455 M            Inferred Resources
    Phase 1                                                                                        (Includes P3)
                                              Remaining P1      8 years           P 1 Avg.
    (2023)                                    Pre-Production                      Annual FCF       UPCOMING CATALYSTS
                                              Capex

                                                                                                 ✓ Phase 1 Commissioning by
                                                                                                   YE-2022
     Phase                                   $76 M             531 kt/y          $595 M          ✓ Phase 2 Production
      1&2                                     Incremental       13 years          P 1 & 2 Avg.     Potentially in 2024
    (∼2024)                                   P2 Pre-Prod.                        Annual FCF     ✓ Phase 3 PEA H2-2022
                                              Capex
                                                                                                 ✓ Phase 4 Resource Update
 Source: the Updated Technical Report.                                                             H2-2022
  High Purity Lithium, Responsibly Sourced                                                                                       page 6
Corporate Presentation - September 2022 - Mining Data Online
Corporate Structure: Concentrated Institutional Ownership
Fully-financed for Phase 1 construction with no current debt following >US$100 million equity financing
completed in December 2021
Capitalization Summary (1,2)                                                                                     USD Share Price (NASDAQ:SGML)
Shares Outstanding                             (MM)                      100.7                                                                SGML Traded Value (Nasdaq & TSXV)                    SGML Share Price (Nasdaq)
                                                                                                                                              NASDAQ (Indexed to SGML)
52-Week Range (3)                              (US$)               $7.35-$29.50
                                                                                                                                     $30.00                                                                                     $60.0
Share Price                                    (US$)                    $24.70

Average 30-D Traded Value (4)                 (US$ MM)                   $20.1                                                       $25.00                                                                                     $50.0

                                                                                                                                                                                                                                        Traded Value (US$ M)
                                                                                                                 Share Price (US$)
Market Capitalization                         (US$ MM)                  $2,488
                                                                                                                                     $20.00                                                                                     $40.0

Cash & Cash Equivalents                       (US$ MM)                    $96
                                                                                                                                     $15.00                                                                                     $30.0
Total Debt                                    (US$ MM)                    $0.2

Enterprise Value                              (US$ MM)                  $2,392                                                       $10.00                                                                                     $20.0

Research Coverage                                                                                                                     $5.00                                                                                     $10.0
Broker                                                                   Analyst
                                                                                                                                          -                                                                                      -
Bank of America                                                    Matthew DeYoe                                                         Sep-2021               Dec-2021              Mar-2022                 Jun-2022    Sep-2022

Canaccord Genuity                                                  Katie Lachapelle                              Largest Shareholders

Cormark Securities                                               MacMurray Whale

National Bank                                                         Lola Aganga
                                                                                                                                      Family
                                                                                                                                      Offices
Red Cloud                                                             David Talbot
                                                                                                                                        (1)   F
                                                                                                                                        (2)   Share price and trading data as of September 23, 2022.F
   High Purity Lithium, Responsibly Sourced       Source: Capital IQ, company materials.                                                (3)   Based on intraday trading prices.                                                  page 7
                                                  (1) Balance sheet items and share count as of June 30, 2022.                          (4)   Based on trading on the Nasdaq and TSXV over the last 30 days.
Corporate Presentation - September 2022 - Mining Data Online
Canadian Company With Operations in Brazil: Strategically Located for
the EV Supply Chain
Operation Located in one of the world’s largest mining provinces with existing infrastructure, including roads,
water, clean power and port access
               Favourable Atlantic Port Location                                     Nearby Infrastructure
                                                                    Shipping: Ilhéus Port        Water License for River at Property

                                       Intercontinental Seaport
                                             (~500 km NE)
                                                                      Power:                Transmission          Road: Existing
                                                                  Hydroelectricity             Lines             Highway to Port
                           Sigma Lithium Operations

  High Purity Lithium, Responsibly Sourced                                                                                     page 8
Corporate Presentation - September 2022 - Mining Data Online
Near-Term Production with Significant Organic Growth Profile
                      Significant growth profile with 72.2 kt LCE in annual production in the near term and further growth potential
                      via Phase 3 (growth to leverage Phase 1 infrastructure)

                                                                                                                    Phase 3: PEA to be Completed in the H2-2022

                                                                                                                             Potential to  production from Phase 3
                                                                                                                             (M&I resource of 23.3 Mt @ 1.49% Li2O)
Production Forecast

                                                                                                                          Phase 2: PFS Completed Q2-2022
                           +261 kt

                                                                                                                         Additional 261,100 tpa (35,500 t LCE)
                                                                                                                              Phase 1 + 2 = 72,200 t LCE

                                                                   Phase 1: In Construction (1)
                           270 kt

                                                               270,000 tpa (36,700 t LCE)
                                                                      (Based on Updated FS)
                                          4Q22 (1)

                                                             2H23

                                                                                                                                                                                    2036
                                                                                                                                 2030

                                                                                                                                                                      2034
                                                                                                                                                           2033
                                                                           2024

                                                                                              2026

                                                                                                                2028

                                                                                                                                                                             2035
                                                                                                                                                 2032
                                                                      Source: the Updated Technical Report.                             2031                                               page 9
                        High Purity Lithium, Responsibly Sourced      (1) Commissioning forecasted to begin at the end of 2022
Corporate Presentation - September 2022 - Mining Data Online
Large Scale Operation
Sigma will be one of the largest and highest-grade lithium producers globally
                                                                                                                                          Commissioning                                                                                                                     Market
                                                             Producers (kt LCE)                                                              Start                             Near-Term Producers (kt LCE)                                                               Capitalization

                               Total Deb t

                                                              101                                                                   202     Q4-2022                                           $0. 5

                                                                                                                                                                                                                 37                   72            Disconnect              US$2.5 B

                 Total Cas h & Equivalents

                                                             92                                                      166                    Q4-2022                                           $2. 4

                                                                                                                                                                                                                      25                                                    US$1.6 B

                                                                                                     Phase 1= 2023                          H2-2022                                               -

                                                                                                                                                                                                            18         27                                                   US$3.5 B
                                                        37                  72
                                                                                                     Phase 2=2024
                                                                                                     Phase 3= TBD
                                                                                                                                                                               Next Cycle Producers (kt LCE)
                                                                                                                                                                                              $2. 8

                                                    32                 56

                                                                                                                                               2024                                           $0. 2

                                                                                                                                                                                                                                      76                                    US$2.3 B
                                                    30                       80
                                                                                                                                            Litigation                               Volume (TSXV)

                                                                                                                                                                                                                             41                                              Halted
                                                    30           46
                                                                                                                                               TBD                                   52-We ek Low

                                                                                                                                                                                                                            36                                              US$0.7 B
                                                    29         44
                                                                                                                                               TBD                                   52-We ek H igh

                                                                                                                                                                                                                       30                                                   US$1.0 B

                                                   25                            83
                                                                                                                                               TBD                                                                    26                                                    US$0.9 B

                                                   22                                          108
                                                                                                                                               TBD                                                                18                                                        US$1.3 B

                                                                                                                  2021 Production
                                                   19         40                                                                               2024                                                              10                                                         US$0.9 B
                                                                                                                  2024E Production
                                             0.0               50. 0                  100 .0             150 .0            200 .0

                                                                                                                                                                                                      0.0                     50. 0        100 .0                150 .0            200 .0

                                                                            Source: Capital IQ as of September 23, 2022. Peers based on Benchmark Intelligence and company materials; Sigma Lithium based on the Updated Technical Report.
  High Purity Lithium, Responsibly Sourced                                  Note: based on attributable production (e.g. Lithium Americas on a 100% basis is 60 kt LCE).                                                                                                        page 10
Production Re-Rate Potential
         Sigma is one of the few near-term producers of scale
       Market Capitalization vs. Production Scale

                                          Producers                                          Near-Term Producers                                                       Next Cycle Producers

                                                                                                                                                                                    Basic Market Capitalization (US$ Bn)
        $35.0

                  202                                                                                                                                                                                                                           200.0

        $30.0
                                                                                                                                                                                    Attributable 2021 Production (kt LCE)
                                   166
                                                                                                                                                                                                                                              (1)
                                                                                                                                                                                    Attributable 2024E / Expanded Production (kt LCE)
                                                                                                                                                                                                                                                150.0

        $25.0

                                                                                                                                                                                                                              (1)
                                                                                                                                                                                    Attributable 2023 Production (kt LCE)
                   101                                                                                                                                                                                                                          100.0

                                    92
                                                    80                                                                                        76
        $20.0

                                                                                                              72
                                                               56                                                                                                                                                                               50.0

                                                                               40              27             37                                                                                                     36              41
                                                    30         32                                                                                                      30
        $1 5.0

                  $31.6
                                  $26.8                                                                                       25                                                                      26
                                                                               19              18                                                            18
                                                                                                                                                                                       10
                                                    $9.5
                                                                                                                                                                                                                                                0.0

        $1 0.0

                                                                                                         Disconnect
                                                               $6.2
                                                                               $5.5
                                                                                                                                                                                                                                                -50.0

                                                                                              $3.5
         $5.0

                                                                                                              $2.5                           $2.3
                                                                                                                              $1.6                           $1.3      $1.0           $0.9           $0.9            $0.7
                                                                                                                                                                                                                                    Halted
         $0.0                                                                                                                                                                                                                                   -100.0

                     1               2                3          4              5               6               7              8               9                 10     11             12             13              14              15

  ADTV
(US$ M) (2)
                  $383             $246             $112       $54            $144             $92            $20             $27             $20            $32       $32             $4             $25             $5              n/a

                                                            Source: Capital IQ as of September 23, 2022. Company materials and Benchmark Intelligence; peers          (1) Developers based on LOM averages disclosed in technical
                 High Purity Lithium, Responsibly Sourced   based on Benchmark Intelligence and company materials; Sigma Lithium the Updated Technical Report.            reports or estimates from Benchmark Intelligence.                 page 11
                                                                                                                                                                      (2) Based on the last 30-days.
Phase 1 ONLY Technical Report Economic Highlights
 Phase 1 Economics Overview
 5.5% Li2O Battery-Grade Lithium Concentrate

                                                                                                     Annual Average Economics
 Estimated Revenue, Operating
                                                                                    (8 Year Operating Life @ 270,000 tpa of Lithium Concentrate)
 Costs and After-Tax Earnings
                                                                                            (US$ M)                (US$/t Lithium Concentrate Sold)
 Gross Revenue                                                                               $675                               $2,499
 Net Revenues                                                                                $656                               $2,429
    Less: Site Operating Costs                                                               $105                                $387
    (-) Mining                                                                                $53                                $195

    (-) Processing                                                                            $15                                $56

    (-) Transport                                                                             $32                                $119

    (-) SG&A                                                                                  $5                                  $18
 EBITDA                                                                                      $551                               $2,041
    % EBITDA Margin                                                                           84%                                84%
 After-Tax Earnings                                                                          $455                               $1,686
    % After-Tax Earnings Margin                                                               69%                                69%

 High Purity Lithium, Responsibly Sourced   Source: the Updated Technical Report.                                                                     page 12
Phase 1 & 2 ONLY Technical Report Economic Highlights
 Phase 1 & 2 Economics Overview
 5.5% Li2O Battery-Grade Lithium Concentrate

                                                                                                    Annual Average Economics
 Estimated Revenue, Operating
                                                                                   (13 Year Operating Life @ 531,000 tpa Lithium Concentrate) (1)
 Costs and After-Tax Earnings
                                                                                                     (US$ M)                    (US$/t Lithium Concentrate Sold)
 Gross Revenue                                                                                          $915                                $2,247
 Net Revenues                                                                                          $889                                 $2,184
    Less: Site Operating Costs                                                                          $159                                 $390
    (-) Mining                                                                                           $79                                 $194

    (-) Processing                                                                                       $23                                  $57

    (-) Transport                                                                                        $46                                  $114

    (-) SG&A                                                                                             $10                                  $25
 EBITDA                                                                                                 $730                                $1,794
    % EBITDA Margin                                                                                     82%                                  82%
 After-Tax Earnings                                                                                    $596                                 $1,463
    % After-Tax Earnings Margin                                                                          67%                                 67%

                                            Source: the Updated Technical Report.
 High Purity Lithium, Responsibly Sourced   (1) Run-Rate production of 531,000 tpa vs. LOM average production of 407,000 tpa.                                      page 13
High Quality and Low Cost Battery Grade Lithium Concentrate
     Unique high grade, high purity and coarse-grained concentrate enables low cost lithium chemical production
     and cost savings
              Illustrative CIF Cash-Cost (1)                                                      Low Impurities                                                                        Coarse Spodumene

    Hard-Rock Producers                                                       Iron Oxide Content (%)                                                     Sigma’s Dry Coarse                       Australian Wet Fines
                                                                                   2.0%

                                        $373
(Greenbushes)

                                                                                           1.2%
                                                                                                  1.0%
                                                                                                         0.9% 0.9%
                                            $454                                                                       0.8% 0.8%
 Phase 1 & 2                                                                                                                        0.5% 0.5%
                                                                                                                                             0.4%

                                              $494
 (Pilgangoora)

                                               $529
 (Mt. Marion)

                                                                              Mica Content (%)
                                               $530
  (Ngungaju)                                                                     10.0%

                                                   $588
    (Finiss                                                                                7.2%
                                                                                                      6.5%

                                                     $628                                                       4.5%
                                                                                                                          4.0%
  (Mt. Catlin)                                                                                                                     3.1%
                                                                                                                                              2.7%

                                                         $681
   (Bald Hill)

                                                                                 Frontier Rock tech   Livent   Piedmont   Livent   Sigma      Critical
                                                                                 Lithium   Lithium              Lithium            Lithium   Elements
                                                                Source: Company materials.
              High Purity Lithium, Responsibly Sourced          (1) Benchmark Mineral Intelligence C3 Cash Cost Curve for peers. Sigma Lithium based on the Updated Technical Report.                                    page 14
Commercial Offtakes
Partnerships established with global leader in advanced battery
manufacturing
                                             ✓ Take-or-pay contracts with prices
                                               linked to the lithium hydroxide price (1)

 Typical Producers Long Route
    to Batteries (end users)                                    Direct with Battery Producer

           Lithium Concentrate                                          Lithium Concentrate

                   Chemical                                                    Chemical
                    Tollers                                                     Tollers

            Precursor Cathode
                Producer

                     Battery                                                 Battery &
                     Makers                                                Cathode Maker

  High Purity Lithium, Responsibly Sourced       (1) Company announcement as of October 5, 2021.   page  1515
                                                                                                      page
Phase 1 Construction
~47% Project Progress Complete
 Targeting initiation of commissioning in December 2022

Detailed Engineering Progress (%)
                    Procurement                                     100%
                             Safety                                 100%
   90%
  Overall               Concentre                                   100%
Completion             Mechanical                                   100%
                        Platework                                   99%
                           Process                                  99%
                              Piping                                99%
                         Structural                            92%
     Electrical & Instruments                                  90%
          General Engineering                                 86%
               Control Systems                          68%
                                 Civil                  67%
                            Planing               50%

H2-2022 Workstreams
 •     Pre-stripping to prepare for mining

 •     Civil and electromechanical construction

 •     Erection of plant equipment

     High Purity Lithium, Responsibly Sourced                              page 17
Detailed Engineering Completed
Phase 1 Feasibility Study completed to FEL3 level to minimize execution risk

                                Junior                                                                           Detailed
                              Mining Cos                                    Pre- Feasibility     Feasibility
                                                                                                                Engineering

                                    ✓        ✓
    Definitive                                   IPA Front End
 Feasibility Study                                                               FEL1              FEL2           FEL3
                                                 Loading

                                                                                                               Initial Capex
                                                 Status                            Study or Feasibility
                                                                                                               Authorization

                                    ✓        ✓
       Basic
    Engineering
                                                 Estimating
                                                                              Factored          Calculated       Detailed
                                                 Methodology

                                             ✓
     Detailed
    Engineering                                  Contingency                15% to 20%          10% to 15%      5% to 10%

     Project
  Execution Plan
                                             ✓          Extensive
                                                    experience building
                                                                          Best-in-Class Engineering Partners
                                                     processing plants
  FEL3 Accuracy
    of Capex                                 ✓
  High Purity Lithium, Responsibly Sourced                                                                                     page 18
Timeline to Phase 1 Plant Commissioning
   Proceeding on schedule and on budget

                         Q4-20                    Q1-21         Q2-21         Q3-21            Q4-21             Q1-22        Q2-22           Q3-22            Q4-22        Q1-23

    Pre-
                      Geotech              Foundation        Structural
Construction
                      Drilling              Modeling        Calculations
   Plant
                                                                               Final
                                                Trade-Off      Design        Designs
                                                 Studies    Confirmations   Trade-Off
                                                                             Studies
                                                                             Process
                                                                              Layout
                                                                             Design
 Detailed
                                                                             Criteria
Engineering
                                                                            Equipment
                                                                            Data Sheet
                                                                                  3D Model
                                                                            Implementation Capex
                                                                                  (FEL3)
                                                                                      PEP
                                                                                                                                                 WE
Procurement                                                                                                              Long Lead Items
                                                                                                                                                 are
                                                                                                                                                 here
                                                                                         Earthworks / Drainage
Construction                                                                                                                          Civil Construction

                                                                                                                                           Electromechanical

 Production                                                                                                                                                            Commissioning

     High Purity Lithium, Responsibly Sourced                                                                                                                                 page 19
Timeline to Phase 1 Mining
   Proceeding on schedule and on budget

                         Q4-20                  Q1-21       Q2-21         Q3-21             Q4-21     Q1-22        Q2-22   Q3-22          Q4-22        Q1-23

                           Geotech                           Mine
                                                   Model
                           Drilling                        Schedule
    Pre-
Construction
  Mining
                                                                       Ongoing
                                Hydrogeological            Piezo-       Hydro-
                                    Drilling               meters     geological
                                                                      Monitoring

                                                                                                                             WE
                                                                                                                             are
                                                                                                                             here

                                                                                                                              Pre-
Construction                                                                       Biding           Mobilization
                                                                                                                              Stripping

                                                                                                                                             Mining   Ongoing
   Mining
                                                                                                                                             (ROM)     Mining

     High Purity Lithium, Responsibly Sourced                                                                                                           page 20
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 21
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 22
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 23
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 24
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 25
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 26
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 27
Phase 1 Plant Construction

 High Purity Lithium, Responsibly Sourced   page 28
Phase 1 Pre-Stripping

 High Purity Lithium, Responsibly Sourced   page 29
Phase 1 Pre-Stripping

 High Purity Lithium, Responsibly Sourced   page 30
Phase 1 Pre-Stripping

 High Purity Lithium, Responsibly Sourced   page 31
Phase 1 Pre-Stripping

 High Purity Lithium, Responsibly Sourced   page 32
Phase 1 & 2 Operations
Fully Funded Phase 1 Capex
Phase 1 will produce 270,000 tpa with US$111 M in remaining initial capex, making it one of the lowest capital
intensity lithium projects globally

                    Sources (US$ millions) (1)                                                             Remaining Phase 1 Initial Capex (US$ millions) (2)

                                                                                                                                Mine                                                 $8.5

                                Current                                                                                         Plant                                               $105.6
                                                                       $95.7
                              Cash Position
                                                                                                                          Substation                                                 $7.4

                                                                                                                  Opex & ESG During
                                                                                                                                                                                     $9.8
                                                                                                                    Construction

                                                                                                                   Working Capital &
                                                                                                                                                                                     $6.1
                                                                                                                       Spares
                            Project Finance
                                                                       $60.0                                      Estimated VAT Tax
                             (Term Sheet)                                                                                                                                           ($5.9)
                                                                                                                       Incentive

                                                                                                                    Capex Disbursed                                                 ($20.7)

                                   Sources                            $155.7                                  Remaining Initial Capex                                               $110.9

                                              (1) Company Q2-2022 financial statements.
  High Purity Lithium, Responsibly Sourced    (2) The Updated Technical Report (remaining initial capex as of Phase 1 Feasibility Study Technical Report filing on May 25, 2022).             page 34
Phase 1 & 2 Economics
Updated Technical Report presents robust economics for the combined operation

Economic Highlights @ 5.5% SC                                                                                         After-Tax NPV8% Sensitivity to Lithium Prices (US$ B)

Economic Analysis                                                                                                                    $8.0

 After-Tax Net Present Value (@ 8% Discount Rate)                   US$5.1 billion
                                                                                                                                     $7.0
 After-Tax Internal Rate of Return                                  589%
                                                                                                                                                                                                            $6.4
 Payback Period                                                     3 months
                                                                                                                                     $6.0                                                 $5.7
Revenues, Cash Flow and Capex

                                                                                                       After-Tax NPV (US$ billion)
                                                                                                                                                                            $5.1
 Operating Life                                                     13 years                                                         $5.0
                                                                                                                                                           $4.4
 Phase 1 Remaining Initial Capex                                    US$111 million
                                                                                                                                     $4.0    $3.8
 Phase 2 Growth Capex                                               US$76 million

 Run-Rate Lithium Concentrate Production                            531,000 tpa
                                                                                                                                     $3.0
 Average LOM Lithium Concentrate Price (2)                          US$2,247/t

 Average Annual Revenue                                             US$915 million                                                   $2.0

 Average Annual After-Tax Free Cash Flow                            US$595 million
                                                                                                                                     $1.0
Costs per Tonne of Lithium Concentrate                                                                                                         (20%)          (10%)           Base            10%           20%
                                                                                                                                            (US$1,798/t)   (US$2,023/t)    (US$2,247/t)   (US$2,472/t)   (US$2,697/t)
 Cash Cost at Production (FOB)                                      US$340/t
                                                                                                                                                                  Lithium Concentrate Price Change (%)
 AISC (CIF China)                                                   US$455/t

                                             (1) The Updated Technical Report.
 High Purity Lithium, Responsibly Sourced    (2) Based on Benchmark Mineral Intelligence’s Q1-2022 lithium hydroxide price forecast.                                                                                    page 35
Phase 2 to be Fully Integrated with the Phase 1 Operations
Streamlined construction of Phase 2 production line expected with certain infrastructure being built as part of
the Phase 1 initial capex (Phase 3 could be added as a third parallel line)

  High Purity Lithium, Responsibly Sourced                                                                        page 36
Phase 2 Update
Phase 2 could be added as early as 2024 and would increase total capacity to 531,000 tpa of 5.5% lithium
concentrate (72,200 tpa LCE)

              Phase 2 PEA
               Filed July 2021
                                             ✓      Maiden Reserve and
                                                     Resource Update
                                                                            ✓         Phase 2 PFS
                                                                                      Filed May 2022
                                                                                                        ✓           Phase 2 DFS /
                                                                                                                    Construction
                                                     Announced April 2022

✓• Increased  production
   capacity from         ✓ 2P Reserves of 21.8Mt
                           @ 1.37% Li O (732Kt
                                                 ✓ DMS testwork
                                                   completed     2
                                                                                                            ✓• DMS Metallurgy
        34,000t LCE to                               LCE)
                                                                                                            ✓• Plant Design
        67,000t LCE
                                                 ✓ M&I Resources of
                                                                                ✓ Geotechnical
                                                                                  drilling field work         • Geotechnical drilling
✓   • 13-year mine life                            25.1Mt @ 1.38% Li O      2                                   field work

✓• Positive economics
                                                     (857Kt LCE)
                                                                                ✓ Hydrogeology
                                                                                  work
                                                                                               field
                                                                                                              • Hydrogeology field work
   to be updated in
                                                 ✓ Inferred Resource of
        upcoming PFS                               3.8Mt @ 1.39% Li O
                                                     (131Kt LCE)
                                                                            2
                                                                                ✓ Groundwater
                                                                                  measurements
                                                                                              level           • DFS to be published in
                                                                                                                H2-2022

                                                                                ✓ Mining Plan                 • Construction earthworks
                                                                                                                could commence as
                                                                                ✓ Published PFS                 early as 2022

  High Purity Lithium, Responsibly Sourced                                                                                              page 37
Additional Growth Potential
(Including Phase 3)
Phase 3 Deposit Located Nearby Phase 2
Phase 3 M&I mineral resource of 23.3 Mt @ 1.49% Li2O and Inferred mineral resource of 3.5 Mt @ 1.48% Li2O
located nearby the Phase 2 pit and suggests further high-grade prospectivity in the region (e.g. Phase 4)

                                                                             Phase 3 Overview

                                                            Phase 2
                                                             (Barreiro)

                                                                             800m
                    5km

                                                                     Phase 3
                                                                          (NDC)

 High Purity Lithium, Responsibly Sourced                                                                   page 39
Phase 3 Update
Phase 3 could be added as early as 2025 (if not earlier) as a third parallel line in the production plant and could
increase total capacity to firmly place Sigma Lithium as one of the world largest producers of lithium

  Maiden Mineral Resource
         Announced June 2022
                                             ✓           Phase 3 PEA
                                                                                Phase 3 PFS & Maiden
                                                                                  Mineral Reserve
                                                                                                             Phase 3 DFS /
                                                                                                             Construction

✓• M&I Resources of
   23.3 Mt @ 1.49%
                                                 ✓
                                                 • HLS testwork
                                                   completed
                                                                             • DMS testwork
                                                                               completed
                                                                                                       • DMS Metallurgy

        Li2O                                                                                           • Plant Design
                                                 ✓
                                                 • Preliminary mining plan   • Geotechnical drilling

✓• Inferred Resources
   of 3.5 Mt @ 1.48%
                                                   completed                   field work
                                                                                                       • Geotechnical drilling field
                                                                                                         work
        Li2O                                     • Optimized mining plan     • Hydrogeology field
                                                   to be evaluated             work
                                                                                                       • Hydrogeology field work
                                                 • Publish PEA and           • Groundwater level
                                                   optimize acceleration       measurements            • DFS to be published in
                                                   study                                                 2023
                                                                             • Mining Plan
                                                                                                       • Construction could
                                                                             • Published PFS
                                                                                                         commence in 2023 or
                                                                                                         2024 (depending on
                                                                                                         permitting)
  High Purity Lithium, Responsibly Sourced                                                                                       page 40
Licensing Update
Phase 1 fully licensed for construction, including the approval of simultaneous mining of the North and South
Pits; Phase 2 licensing process on track, enabling the Project's rapid expansion to match robust lithium demand
Phase 1 Licensing North Pit

                          EIA / RIMA
                                                  ✓                             LP / LI
                                                                                                     ✓                               LO
                           Completed                                          Completed                                 (administrative inspection when
                        Filed June 2019                                   Received June 2019                              construction is completed)

Phase 1 Licensing South Pit

                          EIA / RIMA
                                                  ✓                             LP / LI
                                                                                                     ✓                               LO
                           Completed                                          Completed                                 (administrative inspection when
                        Filed June 2022                                   Received June 2022                              construction is completed)

Phase 2 Licensing

                          EIA / RIMA
                           Completed
                                                  ✓                             LP / LI                                              LO
                                                                              In Progress                               (administrative inspection when
                      Filed August 2022                                          Filed                                    construction is completed)

                                             EIA / RIMA = Environmental Impact Studies / Environmental & Social Impact Assessment Report
                                             LP / LI = Preliminary and Installation Licenses
  High Purity Lithium, Responsibly Sourced   LO = Operating Licenses                                                                                      page 41
Significant Potential for Growth as EV Demand Accelerates
Current focus is on just one part of the broader land package and only 4 of the 9 former operating lithium
mines have NI 43-101 mineral resource estimates to date

                                                                 Phase 1

                                                                     Phase 2           Phase 4

                                                                 Phase 3

  High Purity Lithium, Responsibly Sourced                                                                   page 42
Significant Potential for Growth as EV Demand Accelerates (continued)
Additional exploration potential beneath the Piaui “seasonal stream” and with all deposits open
Phase 1 UG potential                                 Phase 1 remains open at depth     Phase 2 remains open at
                                                     and to the west / east            depth and to the northeast

                                                     Phase 3 remains open at depth     Phase 4 remains open at
                                                     and to the north / south          depth and to the north / south

  High Purity Lithium, Responsibly Sourced                                                                     page 43
Sigma 3.0: the Next Level of Social
& Environmental Sustainability

  ANA CABRAL-GARDNER
  Co-Chairperson & Co-CEO
Delivered Significant Environmental & Social Impact Programs
UN SDGs drive all business decisions, lead by the ESG Committee
Corporate Mission Guidance (UN SGDs)                                UN Case Study on “Green Mining”
                                                                                 Scope 1 Impact              Scope 2 Impact

                                                                    ✓ Minimal water impact              ✓ 100% green hydro
                                                                                                          power used
                                                                    ✓ No hazardous chemicals

Global Thought Leader on Sustainability                             ✓ Tailings are 100% dry stacked

                                                                    ✓ Potential to upcycle tailings

                                                                    ✓ Seasonal “stream” preserved for
                                                                      local communities

                                                                    Focused on the Sustainable Development Where We Operate

ESG Committee Members
              ANA CABRAL-                    MARIA JOSE   MARCELO
              GARDNER                        SALUM        PAIVA
              Chairperson

  High Purity Lithium, Responsibly Sourced                                                                                    page 45
UN SDGs Guiding Sigma Lithium’s Corporate Mission
“UN Energy Compact” member with 100% of business decisions made with sustainable development in mind
Lithium is desperately needed for EV Transition   Jequitinhonha Valley to become part of global supply chain

Promoting sustainable economic development &
employment opportunities in the Jequitinhonha
Valley region where we operate

  High Purity Lithium, Responsibly Sourced                                                                     page 46
Global Thought Leader Driving Change
Speaking at the UN COP-25 and COP-26, participating at the UN High Level Energy Dialogue with Vale and
participating in Tailings Working Group of Swedish Pension Board / Church of England Pension Board

 High Purity Lithium, Responsibly Sourced                                                                page 47
Recognized Nationally in Brazil for ESG Leadership
Awarded for making an ESG difference in the mining, metallurgy and steel category

  High Purity Lithium, Responsibly Sourced                                          page 48
“Green Mining” Case Study: Water & Chemicals
Committed to operating in an environmentally-friendly way (scope 1)
Water sourced is non-drinkable and needs to be                                                            Piaui “seasonal stream” preserved for local communities
treated for industrial use                                                                                (Phase 1 mined as two pits instead of one)

Zero hazardous chemicals used in the
production process (1)

  High Purity Lithium, Responsibly Sourced   (1) 3D rendering of the Phase 1 Production Plant (which will leverage DMS technology).                                 page 49
“Green Mining” Case Study: Tailings
Committed to operating in an environmentally-friendly way (scope 1)
Tailings to be dry stacked (no tailings dams), enabling the potential to upcycle tailings

  High Purity Lithium, Responsibly Sourced                                                  page 50
“Green Mining” Case Study: Power
Committed to operating in an environmentally-friendly way (scope 2)
100% of power needs to be sourced from clean and cheap hydroelectricity from the 360 MW Irape Hydroelectric
Power Plant (transmission lines run directly to site) and net zero carbon emissions targeted for 2024 (1)

                                             (1) Net zero to be achieved by replacing 50% of the diesel used in Sigma’s mining fleet with biodiesel and pursuing carbon- in-setting strategies.
  High Purity Lithium, Responsibly Sourced   (2) Compensation of the Co-CEOs and Co-Chairpersons is partially tied to achieving this goal.                                                        page 51
Microcredit Program for Female Entrepreneurs
Fostering sustainable development of the Jequitinhonha Valley region, where we operate

500
    female entrepreneurs
    empowered

R$2,000
    lent to each female
    entrepreneur

10,000
    female entrepreneurs to be
    empowered (ultimate goal)

 High Purity Lithium, Responsibly Sourced                                                page 52
Zero Hunger Action
Fighting hunger and poverty in the Jequitinhonha Valley region, where we operate

           2021 Program: Completed

7,000                                 >3,000
     food baskets                            people in
     delivered                               need fed

                  1.2 million
                         meals provided

        2022 Program: In Progress (1)

14,000                                >3,000
     food baskets                            people in
     delivered                               need fed

                  2.4 million
                         meals provided

  High Purity Lithium, Responsibly Sourced     (1) Cummulative numbers (including 2021 program).   page 53
COVID-19 Prevention & Relief
Fighting to keep people safe in the Jequitinhonha Valley region, where we operate

12,000 liters
     of disinfectant delivered to 16
     local hospitals

840 kg
     of alcohol gel hand sanitizer
     delivered to 16 local hospitals

20,000
     medical appointments enabled
     per month

  High Purity Lithium, Responsibly Sourced                                          page 54
Disaster Relief During Unprecedented Flooding
Supporting families in the Jequitinhonha Valley region during the Holiday Season

11,000 liters
     of potable water distributed

400
     families supported that lost
     their homes during the Holiday
     Season of 2021

  High Purity Lithium, Responsibly Sourced                                         page 55
Homecoming Employment Program
Fostering sustainable development of the Jequitinhonha Valley region, where we operate

>440
     workers on site for
     construction

~60%
     of workforce local to the
     Jequitinhonha Valley region

              ANA CABRAL-GARDNER
              Co-Chairperson & Co-CEO

“Reconstitution of the social fabric of
the region by reuniting families, bringing
back home to the municipalities in which
we operate, the qualified workforce that
previously migrated out of the region
due to lack of employment opportunities”

  High Purity Lithium, Responsibly Sourced                                               page 56
Education Program for Mining Technicians Established
Fostering sustainable development of the Jequitinhonha Valley region, where we operate

Partnership with

     creating first program to
     prepare mining technicians in
     the region

              ANA CABRAL-GARDNER
              Co-Chairperson & Co-CEO

“Sigma Lithium                   is contributing to
transform the                 Jequitinhonha Valley
region into a                 knowledge hub for
innovation and                training of qualified
professionals in              lithium materials and
mining”

  High Purity Lithium, Responsibly Sourced                                               page 57
Childcare Center Sponsorship
Enabling the mothers of the Jequitinhonha Valley region resume gainful employment

two
     local childcare centers
     sponsored (one in each of the
     municipalities where we operate)

560
     children in need supported

              ANA CABRAL-GARDNER
              Co-Chairperson & Co-CEO

“The childcare centers serve children
under the age of three years old and are
integral to enabling their mothers rejoin
the workforce during the economic
reopening following the Omicron Covid-
19 wave”

  High Purity Lithium, Responsibly Sourced                                          page 58
Appendix
Engaged, Diverse and Accountable Board of Directors
Seasoned Board of Directors combining technical, operations and capital markets expertise

                                                                       ANA CABRAL-GARDNER                                              CALVYN GARDNER
    Chairperson Gender                                                 Co-Chairperson & Co-CEO                                         Co-Chairperson & Co-CEO
         Diversity                                                     • Co-Founder and Managing Partner at A10                        • Former CEO of Trans Hex Diamonds and General
                                                                         Investimentos                                                   Manager of Operations of Anglo American’s Highveld
                                                                       • Former Head of Latin America Capital Markets at                 Steel & Vanadium group
                                                                         Goldman Sachs in New York
        Male                 Female
        50%                   50%

 Board of Directors Gender                                             GARY LITWACK                                                    DANA PERLMAN
         Diversity                                                     Independent Director & Chairperson of the Audit                 Independent Director
                                                                       Committee                                                       • Director of O’Reilly Automotive Inc.
                             Female                                    • Canadian lawyer and Counsel at McCarthy Tétrault              • Former Chief Strategy Officer and Treasure, EVP of
                              33%                                         LLP in Toronto                                                  PVH Corp. and Investment Banking Director of
       Male                                                            • Adjunct Professor of Advanced Securities Law at                  Barclays
       50%                                                                Osgoode Hall Law School
                            LGBTQ
                             17%

       Committee Chair                                                 FREDERICO MARQUES                                               MARCELO PAIVA
                                                                       Independent Director & Chairperson of the                       Director
        Independence                                                   Compensation Committee                                          • Co-Founder and Managing Partner at A10
                                                                       • Director of 4B Mining Corp. and Head of the Canadian             Investimentos
                           Independant                                    operations of the Brazilian law firm Cescon, Barrieu,        • Former Portfolio Manager at the Mittal Family Office in
                               60%                                        Flesch & Barreto Advogados in Toronto                           São Paulo and Vice President at Millennium Global in
                                                                       • Former Partner and Foreign Consultant at McCarthy                London
      Non-
                                                                          Tétrault LLP and Chairman of the Brazil-Canada
  Independant
                                                                          Chamber of Commerce
      40%

      Board of Directors                                               WES ROBERTS                                                     VICENTE LOBO
      Average Tenure (1)                                               Co-Chair Technical Committee                                    Co-Chair Technical Committee
                                                                       • Professional mining engineer                                  • Professional mining engineer
                                                                         with >35 years of experience                                    with >30 years of experience
 ~4 years (2018 IPO)

 High Purity Lithium, Responsibly Sourced   (1) Excludes Dana Perlman who was appointed to the Board of Directors in September 2022.                                                       page 60
Diverse Leadership Team Focused on Delivering Stakeholder Value
Experienced senior leadership team focused on creating stakeholder value, in a sustainable way
   Chief Executive Officer
      Gender Diversity                                ANA CABRAL-GARDNER             CALVYN GARDNER                BRIAN TALBOT
                                                      Co-Chairperson & Co-CEO        Co-Chairperson & Co-CEO       Chief Operating Officer
                                                      • >25 years of experience      • >20 years of experience     • >25 years of experience

         Male                 Female
         50%                   50%

          Head Office
        Gender Diversity                              MARIA JOSE SALUM               FELIPE PERES                  REINALDO GOMES
                                                      Chief Sustainability Officer   Chief Financial Officer       Head of Mining Operations
                              Female                  • ~40 years of experience      • >20 years of experience     • >20 years of experience
                               41%
         Male
         59%

         Geology Team
        Gender Diversity                              JAMIE FLEGG                    RODRIGO ROSO                  MARINA BERNARDINI
                                                      Chief Development Officer      Chief Legal Officer           Chief Commercial Officer
                                                      • >10 years of experience      • ~15 years of experience     • >10 years of experience
         Male
         42%
                              Female
                               58%

     Construction Team                        Construction
     Regional Breakdown                      Workforce at Site                       JAMES NEAL-ELLIS              KESSIANE LIMA SILVA
                                                                                     VP, Corporate Development &   Senior Geology Coordinator
  Non-Local                                                                          Investor Relations            • ~15 years of experience
                                                                                     • ~7 years of experience
    43%
                             Local           >440 workers
                             57%

  High Purity Lithium, Responsibly Sourced    Recent Additions                                                                         page 61
Inflation Reduction Act of 2022
The United States towards a net zero pathway
                                             IRA Summary                                                                              Electric Vehicles and EV Infrastructure

On August 16th, the IRA was signed, allocating ~$369 B in federal
    funding over the next decade to combat climate change                                                         ~$23 B                   allocated to EVs and EV infrastructure

     ✓ Mobilize investments, production and infrastructure                                                                ✓ Tax credit for new EVs placed in service before 2033

     ✓ Support jobs and communities in net zero transition                                                                ✓ Credit reduced by 50% if the battery is not primarily sourced
                                                                                                                            from North America

                                  Two Key Components                                                                              ✓ Benefits OEMs building plants in North America, such
                                                                                                                                    as our partner
      1) Climate Provision                            2) Energy Security Provision
                                                                                                                          ✓ Tax credit also applicable for used EVs

Focused on funding and                                                                                                                                     Funding Allocation
                                                       Focused on securing
providing incentives tied
                                                     domestic energy supplies
  to de-carbonization                                                                                                                                          ~$234bn Funding Selected Energy
                                                                                                            400

                                                                                                                             78
                                                                                                            350

                                                                                                            300

                                                                                                                                        37                                        Technologies
                                                                                                                                                    34
                                                                                                            250

                                                                                                            200

                                                                                                                  369                                        30           23
                             Main Industries Incentivized                                                   150

                                                                                                            100
                                                                                                                                                                                             9             8          8          3
                                                                                                             50                                                                                                                              135
                                                     Industrial &
                                                                                                              0

Transportation                 Real Estate                                        Energy

                                                                                                                                                                                                           Hydrogen
                                                                                                                                       Efficiency

                                                                                                                                                                        Infrastructure

                                                                                                                                                                                         Grid Resilience

                                                                                                                                                                                                                                CCUS & DAC
                                                                                                                                                    Wind

                                                                                                                                                                                                                      Storage
                                                                                                                              Solar
                                                                                                                  Total

                                                                                                                                                              Nuclear

                                                                                                                                                                                                                                             Non-Technology
                                                    Manufacturing

                                                                                                                                        Energy

                                                                                                                                                                                          Energy Tx &
                                                                                                                                                                           EV & EV

                                                                                                                                                                                                                                                Specific
  High Purity Lithium, Responsibly Sourced           Source: Inflation Reduction Act of 2022 and BCG Discussion Deck: US Climate Policy.                                                                                                                      page 62
EV Battery Demand Disrupted Lithium Market Entirely

Electric Car Sales (Million of EVs)
                                                                                                                          51.0
   China
                                                                                                                                  Decarbonization Trends Underpinning the
   Europe                                                                                                        44.7      6.6
                                                                                                                                  Future of Mobility

   United States                                                                                                   5.1
                                                                                                   38.0                    9.1
   Others
                                                                                                     3.8           8.2            Market Share of EV Increased Exponentially
                                                                                     31.8                                         Post Pandemic
                                                                                      2.8            7.2
                                                                      25.8                                                 14.3
                                                                                      6.0
                                                                        2.1                                       13.0
                                                         20.8                                                                     Electrification was Chosen by Governments as
                                                                        4.6                         11.8
                                                          1.5                                                                     The Quick Path to Decarbonization to Solve
                                                  16.3    3.3                        10.3                                         Climate Change
                                                  1.1
                               12.9               2.2                   8.5
                10.5             0.7
                                 1.5
                                                          7.1
                 0.5                              5.7                                                                      21.1
                 0.9                                                                                              18.3
 6.5                             4.6                                                                15.3
 0.4
 0.6
                 3.5
                                                                                      12.7                                        Governments Accelerated Targets as Part of
                                                                       10.6
 2.3
                                 6.1              7.4     8.8                                                                     Green Recovery Economic Plans Post-
                 5.6
 3.3                                                                                                                              Pandemic
2021          2022E           2023E          2024E       2025E       2026E         2027E          2028E         2029E     2030E

       High Purity Lithium, Responsibly Sourced            Source: Benchmark Mineral Intelligence and UBS Evidence Labs                                                page 63
Agnostic to Battery Technology
Sigma Lithium will deliver material before chemical conversion, enabling technological flexibility

Lithium Weightage in Different Li-ion Batteries Chemistry Type
                                                   Lithium          Manganese    Phosphate       Cobalt   Nickel         Iron

    11%                       6%             8%              11%                11%                11%             11%          11%               11%          11%
    LCO                       LMO            LFP             NCM                NCM                NCM             NCM          NCM               NCA          NCA+
                                                              111               442                532             622           811

Not All Lithium Are the Same

 Brine                                                                                  Li Carbonate                                   Nickel & Cobalt Free
                                                                                                                                            Batteries

 Spodumene                                                                              Li Hydroxide                                   Nickel Rich Batteries

  High Purity Lithium, Responsibly Sourced                                                                                                                            page 64
Agnostic to Battery Technology
Sigma Lithium will deliver material before chemical conversion, enabling technological flexibility
✓ Sigma Lithium is not constructing a hydroxide conversion plant

     •     Reduced capex and operational complexity

✓ Strategy provides technological flexibility

     •     Material can be delivered to hydroxide or carbonate-based cathodes

                                             Source: Benchmark Mineral Intelligence.
  High Purity Lithium, Responsibly Sourced   Note: LCO = Lithium Cobalt Oxide; NCA = Lithium Nickel Cobalt Aluminum Oxide; NCM = Lithium Nickel Manganese Cobalt Oxide; LMO = Lithium Manganese Oxide;   page 65
                                             LMNO = Lithium Manganese Nickel Oxide; LFP = Lithium Iron Phosphate.
Lithium Carbonate (2011-Today)
   Asian Metals as of September 09, 2022
(USD/t)

                                2011             2012       2013         2014             2015               2016          2017         2018        2019      2020      2021      2022
           Maximum             $6,045            $7,036     $7,177       $6,945          $19,626            $25,944       $27,283      $26,441    $26,441    $8,160    $43,544   $78,402
            Median             $5,989            $6,899     $7,036       $6,607          $7,837             $21,975       $21,927      $17,190     $17,192   $6,358    $13,890   $70,893
           Minimum             $5,841            $5,978     $6,403       $6,274          $6,939             $17,861       $18,251      $11,356     $11,356    $5,781   $8,208    $43,649
             Mean              $5,987            $6,670     $6,903       $6,558          $8,933             $21,759       $22,492      $17,435    $17,458    $6,432    $18,957   $69,656

  $90,000

  $80,000

  $70,000

  $60,000

  $50,000

  $40,000

  $30,000

  $20,000

  $10,000

          $-
           Jun-11               Jun-12             Jun-13       Jun-14          Jun-15             Jun-16             Jun-17        Jun-18       Jun-19      Jun-20     Jun-21     Jun-22

      High Purity Lithium, Responsibly Sourced                                                                                                                                              page 66
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