Reliable Solutions from Dow for Automotive Appearance - Consumer Solutions Formulation Guide
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Household Care Consumer Solutions Reliable Solutions from Dow for Automotive Appearance Formulation Guide
Contents Formulating Tips and Resources Glass Cleaner uto Care Formulation Information: General Auto Polish A Glass Care – Screenwash and Formulation Tips Glass Care – Cleaner Automotive Appearance Chemicals Application Selector Glass Cleaner with Ammonia and Citric Glass Cleaner and Product Comparison Guide Anti-Fog Glass Cleaner Dow C.A.R.B.-Compliant Solutions for Automotive Surfaces Tip Sheet for California Regulations for Auto Appearance Products Interior Protection Auto Care Raw Material Explanations Cockpit Enhancers – Aerosol Product Cockpit Enhancers – Liquid Product Formulations Cockpit Enhancers – Sheen Finish Automotive Wax Leather Conditioner Lotion Emulsion Hard Wax Vinyl Protectant Hard Wax Creamy Vinyl Surface Protectant Wax Conditioner Fabric Water Repellent Low-VOC Polish Multi-Surface Medium Shine Dressing Car Polish Premium Protectant Lotion (Low Odor) Paintable Polish Leather Conditioner Lotion Spray-and-Wipe Polish Cockpit Enhancer – Sheen Finish Instant Car Polish Polymer Sealant Low-Solvent Liquid Polish Polymer Sealant Liquid Polish Pre-Softened Polymer Sealant Paste – Formulation I Car Wash Pre-Softened Polymer Sealant Paste – Formulation II Standard Shampoo Scratch Concealer Protective Shampoo – Formulation I Scratch Concealer Protective Shampoo – Formulation II Solvent-free Polish Dry Washer Solvent-Free Polish Shampoo for Use in Professional Detailing Tire Care Drying Agent Multi-Surface Medium Shine Dressing Final Rinse Formula for Automatic Car Wash (Concentrate) Tire Enhancer Foam Spray Durable Polish Solvent-based Liquid Tire Surface Protectant Automotive Cream Wax – Durable Polish Tire Dressing with XIAMETER™ MEM-1171 Emulsion Automotive Cream Wax Cream Tire Dressing with XIAMETER™ MEM-1171 Emulsion High-Gloss Automotive Cream Wax for Professional Detailing Fast Dry Premium Shine Tire Dressing Automotive Cream Wax for Professional Detailing Spray & Walk Away Tire Dressing Durable, High-Gloss Paste Polish Spray & Wipe Low-Cost Tire Dressing Detergent-Resistant Cleaner Paste Polish Water-based Tire Shine Exterior Trim Protection Exterior Plastic/Rubber Enhancers – Liquid Exterior Plastic/Rubber Enhancers – Sheen Finish Exterior Plastic/Rubber Enhancers – Aerosol Product Exterior Plastic/Rubber Enhancers – Gel Premium Protectant Lotion (Low Odor) pg 2
Auto Care Formulation Information General Auto Polish and Formulation Tips above. This is because a polish is essentially 3.1 Silicones a compromise of all the properties. A variety of silicones, including polydimethylsiloxanes, aminofunctional 2. Polish Types silicones and silicone resins, are used as Polishes can be described in terms of active ingredients in polish formulations. their physical form, carrier system, ability Silicone emulsifiers, waxes and volatile to clean and durability. Physical forms of silicones are also used in polish polishes include pastes, pre-softened pastes formulations and will be addressed in (non-flowing emulsions), liquids and gels. other sections. There are three types of carrier system: Polydimethylsiloxane is a nonreactive 2.1. Water-free Polishes linear silicone fluid, which is supplied in a number of viscosities. In the auto Where the active ingredients are polish industry the convention is to dissolved in a compatible carrier such as classify polydimethylsiloxane as either a hydrocarbon solvent. “intermediate” (350-1000 mm2/s) or “high” 2.2. Emulsion Polishes (above 1000 mm2/s) viscosity. Combining two incompatible phases Intermediate-viscosity (hydrocarbon solvent + water) by polydimethylsiloxanes are lower in incorporating a surfactant to form a molecular weight. They provide bridge between the two phases. excellent application ease and rubout, 1. Introduction as well as streak resistance. Due to their The word “polish” is a non-specific name 2.3. Solvent-free Polishes low surface tension, they can improve but may be defined as any product that Using pre-emulsified materials with the polish cleaning abilities by increasing enhances and protects the painted surface carrier being water. the surface wettability. This enables of an automobile by depositing a thin a more direct contact between the The ability of a polish to clean depends powder and the painted surface. They layer or film of material. More specifically, on the presence of powders and solvents. are very good at spreading and thus the name polish is assigned to a product Powders clean physically by removing the provide excellent film continuity. The with particular properties, as listed below. oxidation layer and smoothing the surface. film provided by intermediate-viscosity Polishes may contain many different Solvents clean chemically by dissolving polydimethylsiloxanes, especially at (1000 ingredients and come in various forms the films and dirt present on the surface. mm2/s, provides high shine. that contribute to a range of final product Powder-free polishes, typically referred to properties. It is essential to choose the High-viscosity polydimethylsiloxanes are as paint conditioners and glazes, are used correct ingredients and form to satisfy much higher in molecular weight. They strictly to provide gloss and protection. customers’ needs for specific applications. provide improvements in durability and They should be applied only to non- The following information should assist provide excellent shine characteristics. oxidized painted surfaces. in making those choices. However, they are more likely to A polish may also be described by its cause streaking. In general, solvent- Silicones are used to improve a number of level of durability. Durability ranges in-water polishes use 50-1000 mm2/s auto polish properties, including: from temporary (a few weeks) to durable polydimethylsiloxane, while water-in- • Ease of application films that remain after numerous solvent polishes enable higher-viscosity • Polish cleaning ability detergent washes or months (formerly polydimethylsiloxanes to be used. In called “polymer sealants”). To the user, polish formulations it is advantageous • Ease of buffing durability is typically judged by a polish’s to use a combination of high-and • Gloss ability to sustain water beading. intermediate-viscosity fluids favoring • Color intensity the following broad spectrum: 3. Active Ingredients • Durability and detergent resistance 3 : 1 : 1 The term “active ingredient,” as used • Water repellency here, is defined as that part of the polish 350 1000 12,500 left behind in the form of a film on the This helps to optimize shine and The best choice of silicone will depend on polished surface after application. durability in comparison to ease of use the relative importance of the properties and film continuity. pg 3
Aminofunctional silicone fluids are also However, they are often more difficult silicones provide some unique used extensively in polishes in both to apply and buff out. application properties such as better curable (crosslinking) and noncurable spreading and lubrication properties Softer waxes, such as paraffin forms. They provide properties similar due to their lower surface tension, and and beeswax, tend to be better at to the polydimethylsiloxanes, but with improved compatibility with silicones. lubricating, providing better application enhanced durability and detergent Different evaporation rates can be in terms of rubout ease and improved resistance, particularly with the achieved by blending. This allows even spreading. However, soft waxes provide curable forms. deposition of other ingredients, while less shine to the system. In most their cleaning ability for various deposits One advantage of aminofunctional formulations, it is best to blend a hard is comparable to traditional solvents. It silicones is that they contain a polar wax with a soft wax to optimize their has been shown that volatile silicones amine group that provides excellent benefits in the formulation. do not contribute to tropospheric ozone deposition or surface affinity. This A recent innovation has been the formation. Therefore, volatile silicones effectively anchors the product to the introduction of silicone waxes into are not classified as VOCs in the USA. substrate. In the case of the curable auto polishes. These provide a different amine silicones, a reactive alkoxy group 3.4 Powders combination of properties to that of the undergoes a condensation reaction traditional waxes. While having a low Powders or polishing agents provide that provides a crosslinked film on the melting point, they can provide a film physical surface preparation and substrate. Aminofunctional silicones with increased detergent resistance and cleaning, and aid leveling of the are available with different viscosities, weathering abilities, especially when deposited film. The ability of a powder which allow optimization of properties combined with functionalized silicones. to clean and smooth out surface for a particular application. They are They provide a dry film that improves imperfections depends on the particle compatible with other silicone fluids the resistance to dirt pickup, while size, its shape and hardness. The larger and resins and therefore may be retaining the application ease, spreading and less uniform the powder particle the blended to create the desired polish characteristics and shine associated with greater the cleaning ability to remove performance. Fatty acids may be combined softer waxes. the oxidized paint layer. Milder powders with aminofunctional silicones to improve the corrosion resistance of a polish film. Stearic or are composed of more uniform, smaller 3.3 Solvents lauric acid is often used for this purpose. particles, which polish more and clean Solvents are another component of most less, giving greater gloss. These are These can also crosslink with acid waxes polish systems and can have an impact better suited to surfaces with little or through the amino group. on the overall formulation performance. no oxidation. For cars less than one Silicone resins may also be used in polish The purpose of the solvent in a polish year old, it may not be necessary to formulations. These networked silicones is to carry the active ingredients; to include powders in the formulation. are available either bodied or linear and “wet” the surface so a uniform film Most powders contain kaolin clays, provide intermediate durability to the is produced; and to clean the surface. diatomaceous earths and hydrated polish film. When used in conjunction In choosing a solvent, drying rates, aluminas such as Sillitin, Kaopolite, with polydimethylsiloxanes, they provide combustibility, compatibility with the Diafil and Alcan grades. improved durability with excellent leveling surface and compatibility with the while maintaining similar ease-of-use, packaging must be considered. 3.5 Emulsifiers shine and water-repellent characteristics. It is important to optimize the solvent A polish emulsion may be described 3.2 Waxes choice to provide appropriate drying time by either its emulsion system or its for the specific application and actives in ionic character. Waxes are commonly found in polish the formulation. Too little or too much An oil-in-water (o/w) emulsion is a system formulations. A wide variety of different drying time for a specific formulation in which the water is the external waxes are available, including naturally may lead to poor performance by or continuous phase and the oil is in occurring (carnauba), synthetic (silicone leaving streaks or a discontinuous film the form of suspended droplets. These wax, polyethylene) and refined (paraffin) finish. Aliphatic hydrocarbons with can give a better shine than the other waxes. If properly selected, a wax may Kauri-Butanol values of less than 32 are emulsion type, are less flammable and reduce smear, improve film continuity recommended for polishes. Examples may be considered safer for skin contact. (or uniformity), provide durability of these include de-aromatized and and promote stability by acting as Water-in-oil (w/o) polishes are popular Isopar rafinic solvents. Solvents that a thickener. due to easier processing in some cases contain aromatic substances are not Most waxes may be described as either recommended for use in these products and better cleaning properties. Here soft or hard wax. Hard waxes, such as because they may damage the surface the oil is the continuous phase, with carnauba and polypropylene, tend to and may raise flammability, health and the water suspended as droplets. have higher melting points. They provide environmental issues. Emulsifiers for this type of system a harder film finish and promote good have a hydrophilic/hydrophobic balance Volatile silicones are an alternative to favoring the oil phase, e.g., silicone gloss, color intensity and durability. these traditional solvents. Volatile emulsifiers. For best results, the water pg 4
and oil phases are blended separately, well as reduce the phase separation. The or other ingredients is too great as this and then the water phase is slowly presence of aminofunctional silicones tends to favor water-in-oil emulsions and added to the oil phase using a mixer provides a richer, thicker end product can actually prevent oil-in-water polishes that provides high shear. With some with this emulsion type. from forming properly. formulations it is possible to blend the With oil-in-water formulations, the If the emulsion forms, but is prone to phases in a certain order in one vessel. aqueous phase may be thickened with settling or breaking, thickening the Silicone emulsifiers represent a natural gums, cellulose gums or acrylic emulsion will often enhance the stability. unique material for use in water-in-oil acid polymers. Magnesium aluminium This may be accomplished by thickening polish formulations. These lipophilic silicates provide minimum thickening, the external phase with gums or acrylic materials produce very stable, shear- but tend to reduce powder settlement. acid polymers. thickened emulsions. In addition, they This is of particular benefit in spray- are thixotropic, providing excellent and-wipe formulations where lower 4.1.2 Water-in-oil Polishes application ease. The inherent lubricating viscosity is desired. Probably the most common type of nature of the silicone improves rubout. instability in water-in-oil polishes is As emulsifiers they can provide better 3.7 Biocides “oiling out” of the phases. This condition shine than their organic counterparts Microbes can spoil polishes, causing occurs because of the natural tendency due to compatibility with active residual breakdown of the product as indicated by of the less dense solvents to collect at the material in the polish film. a color change or offensive odor. Microbes top of the polish, but can normally be Emulsions defined by their ionic can also affect the packaging of the polish redispersed by agitation such as shaking. character are either anionic, nonionic by distorting the container. Microbial To eliminate this tendency, the emulsion or cationic. An anionic emulsion particle testing must be undertaken to verify can be made extra thick to reduce the shows a net negative charge typical of the whether the product needs protecting. mobility of the phases. Alternatively, formulations, based on the saponification steps can be taken to make the phases 3.8 Miscellaneous more compatible, for example by adding of a fatty acid such as oleic acid and an alkali. Nonionic emulsions show no net Other additives may be added to the a hydrophilic co-surfactant. charge and are typical of the emulsions, polish as desired. For example, coloring Also, applying more shear will reduce based on alcohol ethoxylates. Cationic agents can be added to shade the polish, the particle size of the emulsion and emulsion particles have a net positive while fragrances give an attractive smell. thicken the polish. It is possible however charge similar to the alkyl quaternary Both are typically incorporated at 0.1-0.2% to overshear the polish and make the compounds, giving good wetting and by weight (higher levels of fragrance can particles too small, consuming the substantivity properties as well as affect stability). In other situations the surfactant and contributing to instability. synergy with silicones. coloring agent (pigment or dye) is added When using silicone emulsifiers, adding in larger amounts to create “colored 0.5-1.0 of a water-soluble electrolyte, such The key to making stable polishes is polishes.” Other resins, such as acrylic and as sodium citrate, in the water phase can using the right level of emulsifier, correct polyurethane, can be incorporated at low substantially enhance stability. HLB value and chemical type for the levels to increase the immediate water system – with the ingredients added resistance (not repellency). However, 4.2 Performance Issues in the proper order. Oleic acid and a compatibility needs to be determined. 4.2.1 Streaking Problems volatile amine can be used together because this combination leaves no Streaking is generally defined as marks or 4. Formulation Tips residual surfactant on the surface and imperfections in the polish film that are therefore avoids re-emulsification. 4.1 Stability Problems immovable, or hard to move, with simple Substituting a higher-molecular-weight 4.1.1 Oil-in-water polishes rubbing. In extreme cases streaking fatty acid, such as stearic, for the oleic Many different stability problems occur appears as harder swirl marks where the can increase the emulsion viscosity and in oil-in-water polishes, but the most polish was originally applied. Generally improve stability. common ones can be remedied fairly there are two main causes for streaking: easily. One such problem occurs when • The film-forming ingredients 3.6 Thickeners the emulsifying system is the reaction cannot level and spread well. A variety of thickeners are commonly product of a reactive amine source with • The film-forming ingredients used in polish formulations to a fatty acid. If there is interference with interfere with each other. provide better stability and improved this reaction, there will be insufficient consistency. For maximum efficiency, the surfactant to emulsify the internal The first cause is usually manifested external phase should be thickened with phase. It is advisable to combine the by insufficient drying time, improper no more thickener used than necessary. reactants in the same phase (usually solvent choice or improper application the oil phase) and allow them to pre- conditions. Allowing too little or too In a water-in-oil system, a solvent-based react before adding reactive ingredients much drying time can have negative thickener such as bentonite clay can such as aminofunctional silicones or effects on the polish film. It is important be used. This will increase the viscosity neutralizing agents. Problems also occur to choose appropriate solvents as well and improve the product consistency as when the amine content of silicones as the proper phase ratios (water phase pg 5
versus oil phase) to provide a drying time is usually caused by overdeposition of film and left on the surface. This reduces that allows the polish active ingredients higher-viscosity active ingredients. One the wet look. to wet out to a thin, uniform film. solution is to reduce the level of high- viscosity ingredients such as silicones 4.2.4 Durability versus Ease of Use Polishes that dry too quickly tend to leave and other materials, or change the Waxes were the first reasonably a film that varies in thickness over the ratio of low and high-viscosity actives. durable polish components and were surface. This creates a film with poor The choice and level of powders can applied from solvent over the surface, gloss properties because the actives do play a significant part in the amount then buffed to a smooth appearance. not have time to wet out prior to solvent of material left behind on the surface. The harder the wax the better the evaporation. This is especially the case for This can be optimized by trying to durability but the harder it was to buff. higher-viscosity and reactive silicones. incrementally increase or decrease Polydimethylsiloxanes were introduced Polishes that are left to dry for too long powder and active levels, but this too to help lubricate waxes and allowed may also yield a non-uniform film with is a bit of a balancing act and requires easier buffing, but these compromised poor gloss and color enhancement. perseverance. Every ingredient added durability. The solution was curable This is because after the solvent has or subtracted in a formulation can affect silicones, which allow easy application, evaporated, the remaining actives the final properties and physical form of spreading and buffing. They then cure in cannot be buffed to a smooth finish – a polish. place and become more durable. especially if the materials have begun to crosslink and anchor to the surface. 4.2.3 Gloss and Color The curable silicones used in automotive Environmental conditions (primarily polishes are normally aminofunctional These properties are a function of ones. The requirement is to apply as temperature and humidity) affect the several factors of a formulation as well required drying times; on warm surfaces much as needed for good durability as the conditions and surface where it while retaining good gloss and ease the solvent evaporates too quickly is applied. Gloss can be measured by for reactive polymers to wet out. It is of use. Low-viscosity aminofunctional reflectance properties and clarity of silicones are more reactive and more important to consider these factors when image, while color is assessed from such choosing the solvent or solvent blend durable, but do not provide significant factors as hue, lightness and saturation. levels of gloss or lubricity. By blending for your formulation. In most cases a polydimethylsiloxane will be more “Clarity of image” is how well the finish with higher-viscosity aminofunctional flexible than a reactive polymer, and can shows details of the reflected image. A silicones or polydimethylsiloxanes, the accommodate a variety of drying times. common way to assess clarity is to hold best balance of durability and ease of use If these measures do not eliminate the a ruler or printed page perpendicular to can be achieved. problem, then a wetting agent should the surface of the paint and observe the The typical ratio of reactive amino-silicones be tried at low dosage levels, typically reflected markings and letters on the used in traditional polishes is 4 to 6 parts 0.1-0.3%. Silicone polyethers are effective paint. This is usually affected by how high viscosity to 1 part lower viscosity. wetting agents used in small quantities; smooth the surface is. A film-former This balance can be adjusted to affect they reduce the tendency to re-emulsify, that is smeary can cause unevenness in ease of application, buffing, gloss and and avoid incompatibility problems. the image and can distort the image. durability. Small, incremental changes are However, a film-former that is too rigid, best, because altering one property can The second cause of streaking (i.e., the or one that dried too quickly, can cause film-forming ingredients interfering with affect another. a spotty or mottled deposition, also each other) can be more difficult to resolve. An approach would be to eliminate each resulting in distortion. Clarity can be 5. Notes on Formulations Shown improved by blending different film- ingredient in turn to determine the source 5.1. U nless stated, all quantities are in formers; by choosing slower- or faster- of the interference. Sometimes the final percentage parts by weight. drying solvents; or by using a very fine film may be compatible, but in getting grade of powder to polish the surface to 5.2. A ll formulations are for illustrative to that film, there may be stages where a smooth finish. purposes only and have been ingredients interfere with each other and subjected to limited stability tests. cause streaking. In this case, choosing Color intensity is often referred to as You should perform your own coalescing solvents that help solubilize “jetting” or “wet look” and is influenced stability and performance tests. all of the active ingredients can help. by the type of film-former used. Thicker films (e.g., higher-viscosity silicones) will 5.3. W hile Dow endeavors to provide Finally, it must be said that streaking is usually help the jetting but this can be up-to-date information on all the not an easy problem to solve, so plenty carried too far and result in smearing. toxicological aspects of its products, of persistence is required. Hard waxes have the same benefits and it cannot provide such information problems as high-viscosity silicones but on other ingredients mentioned in 4.2.2 Smearing have the disadvantage of being difficult the formulations. As the formulations Smearing is the tendency of a polish film to buff. In some instances, where a high themselves have not been subjected to be too mobile. This can contribute level of reactive silicones or hard waxes to safety tests, formulators must to a more hazy appearance, and show is used, it is possible for some of the satisfy themselves that their final fingerprints or an oily look. Smearing powder residues to be trapped in the products are safe and compliant with current legislation. pg 6
5.4. Note that these are representative The developed polishes presented by emulsions can be incorporated to impart formulations only and are Dow have been formulated to satisfy one durability to these products. Notice not commercialized products. of the requirements in the table below: that some aminofunctional silicone Information and data contained emulsions have cationic surfactants. in the formulations are based on Condition of Painted Surface Choose nonionic or cationic emulsions information Dow believes to be Slightly when combining with these emulsions. New Good reliable, but Dow does not warrant Weathered The recommended silicone actives merchantability, fitness for use, Abrasive 0-5% 5-12% 10-15% content for tire dressings and protectants performance or efficacy. It is the formulations is 15-25%. Poly Poly formulator’s obligation to test Durable Wax Sealant Sealant Conditioner Silicone polyethers such as XIAMETER™ any application and to conclude Liquid Paste satisfactory performance and safety OFX-5211 Fluid can be utilized to enhance Semi- Hard Wax “Polish” - wetting properties for these products. tests before commercialization. Durable Suggestions of uses should not be The recommendation is to use 0.1-0.3% Temporary Instant - - taken as inducements to infringe depending on how difficult to wet the any particular patent. surface is. 6. Tire Care and Protectants Elastomer emulsions and dispersions, 5.5. Please note that certain aminofunctional siloxanes can Tire dressings, also known as tire silicone polyethers and silicone waxes display acute toxicity via aerosol renovators, and protectants, also known can help to create innovative look and inhalational exposure. Safety data as vinyl dressings, have the purpose of feel finishes such as soft or dry feel. sheets should be referred to before enhancing the appearance of rubber and These types of silicones can help to handling and formulating with plastic surfaces. These products can be formulate non-oily-feel products. these products. water- or solvent-based. Protectants are Solvent-based tire dressings can be typically water-based products. Silicone formulated following the recommended 5.6. Soft water should be used for all emulsions made of polydimethylsiloxane ratios found in section 3.1 (Silicones). The formulations. fluids can be combined to achieve desired same principles found in polishes on 5.7. Biocides have not been shown but gloss levels. It is recommended to start how to achieve different levels of gloss all formulations should be subjected with emulsions made of intermediate- apply to tire dressings. to microbial testing. Coloring agents viscosity fluids and use emulsions made and fragrances may also be included of high-viscosity fluids to improve depth at low addition levels. of gloss. Aminofunctional silicone pg 7
Table I: Application Selector Guide Target Application → Exterior Wax, Conditioner Benefit ↓ Wash and Rinse Aid and Sealant Exterior Trim Protectant Upholstery Care Gloss DOWSIL™ FZ-4658 XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0062 Emulsion XIAMETER™ MEM-0062 Emulsion XIAMETER™ MEM-0346 XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-1015 Emulsion XIAMETER™ MEM-1015 Emulsion Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-0039 Emulsion Durability XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-8035 Emulsion DOWSIL™ FZ-4658 DOWSIL™ BY 22-749 SR Emulsion DOWSIL™ HV 495 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-1101 Emulsion Ease of Use XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion Water Beading DOWSIL™ FZ-4658 DOWSIL™ BY 22-749 SR Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0062 Emulsion Water-based Leveling XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-0039 Emulsion XIAMETER™ MEM-0039 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-1473 Emulsion Paintability XIAMETER™ MEM-5009 Emulsion XIAMETER™ MEM-5009 Emulsion DOWSIL™ 2418 Release Emulsion DOWSIL™ 2418 Release Emulsion Wetting XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0062 Emulsion PS Slip XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-0346 Emulsion Color Enhancement DOWSIL™ HV 495 Emulsion DOWSIL™ HV 495 Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-1101 Emulsion pg 8
Interior Trim Renovator Leather Conditioner Glass Care Vinyl Protectant Tire Care XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ OFX-0193 Fluid XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-1015 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0039 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-0062 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-0039 Emulsion XIAMETER™ MEM-1015 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0039 Emulsion XIAMETER™ MEM-1015 Emulsion XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-8035 Emulsion DOWSIL™ HV 495 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-8035 Emulsion DOWSIL™ HV 495 Emulsion DOWSIL™ BY 22-729 EX Emulsion XIAMETER™ MEM-0062 Emulsion PS DOWSIL™ HV 495 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-0062 Emulsion XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ OFX-0193 Fluid XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0062 Emulsion XIAMETER™ MEM-0039 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-8035 Emulsion DOWSIL™ 2418 Release Emulsion XIAMETER™ MEM-5009 Emulsion DOWSIL™ 2418 Release Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ OFX-5211 Fluid XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ OFX-0193 Fluid XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-1716 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-1171 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion DOWSIL™ HV 495 Emulsion DOWSIL™ HV 495 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-1865 Emulsion XIAMETER™ MEM-1865 Emulsion DOWSIL™ HV 495 Emulsion XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-1101 Emulsion pg 9
Target Application → Exterior Wax, Conditioner Benefit ↓ Wash and Rinse Aid and Sealant Exterior Trim Protectant Upholstery Care Gloss XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid (350-1,000 cSt) (350-1,000 cSt) XIAMETER™ OFX-0531 Fluid XIAMETER™ OFX-0531 Fluid DOWSIL™ 3527 Release Agent DOWSIL™ 3527 Release Agent DOWSIL™ 2-1912 Fluid DOWSIL™ 2-1912 Fluid DOWSIL™ 2-5088 Wax Durability XIAMETER™ OFX-8630 Fluid XIAMETER™ OFX-0536 Fluid DOWSIL™ 3527 Release Agent XIAMETER™ OFX-0531 Fluid DOWSIL™ 593 Fluid DOWSIL™ 3527 Release Agent DOWSIL™ 2-1912 Fluid DOWSIL™ 2-1912 Fluid DOWSIL™ 593 Fluid DOWSIL™ 2-5088 Wax XIAMETER™ OFX-8630 Fluid Ease of Use XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid (50-1,000 cSt) (50-1,000 cSt) XIAMETER™ OFX-0531 Fluid XIAMETER™ OFX-0531 Fluid Water Beading XIAMETER™ PMX-0245 DOWSIL™ 3527 Release Agent DOWSIL™ 593 Fluid DOWSIL™ FBL-0563 Cyclopentasiloxane DOWSIL™ 2-1912 Fluid XIAMETER™ OFX-0531 Fluid Formulated Blend XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-0531 Silicone Fluid XIAMETER™ OFX-0536 Fluid XIAMETER™ OFX-8630 Silicone Fluid DOWSIL™ 2-5088 Wax DOWSIL™ 2-5088 Wax XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid Leveling XIAMETER™ PMX-0245 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid Solvent-based Cyclopentasiloxane DOWSIL™ 593 Fluid Paintability DOWSIL™ 2-5088 Wax XIAMETER™ OFX-0203 Fluid XIAMETER™ OFX-0203 Fluid XIAMETER™ OFX-0230 Fluid XIAMETER™ OFX-0230 Fluid Dry Finish DOWSIL™ 2-5088 Wax Wetting XIAMETER™ PMX-0245 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Cyclopentasiloxane Silicone Fluid Slip XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid Color Enhancement XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid (10,000-60,000 cSt) (10,000-60,000 cSt) pg 10
Interior Trim Renovator Leather Conditioner Glass Care Vinyl Protectant Tire Care XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid (350-1,000 cSt) (350-1,000 cSt) (350-1,000 cSt) (350-1,000 cSt) DOWSIL™ 2-5088 Wax DOWSIL™ 2-5088 Wax XIAMETER™ PMX-200 Silicone Fluid (12,500-60,000 cSt) XIAMETER™ OFX-8630 Fluid DOWSIL™ 3527 Release Agent DOWSIL™ 593 Fluid DOWSIL™ 2-1912 Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid (50-1,000 cSt) (50-1,000 cSt) (50-1,000 cSt) (50-1,000 cSt) DOWSIL™ 593 Fluid DOWSIL™ 2-5088 Wax DOWSIL™ 3527 Release Agent XIAMETER™ PMX-200 Silicone Fluid DOWSIL™ 2-1912 Fluid DOWSIL™ 2-1912 Fluid DOWSIL™ 593 Fluid DOWSIL™ 3527 Release Agent DOWSIL™ 3527 Release Agent XIAMETER™ PMX-200 XIAMETER™ PMX-200 Silicone Fluid Silicone Fluid XIAMETER™ PMX-200 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-0244 Cyclotetrasiloxane Silicone Fluid XIAMETER™ PMX-0245 Cyclopentasiloxane DOWSIL™ OS-2 Silicone Cleaner and Solvent XIAMETER™ OFX-0203 Fluid DOWSIL™ 2-5088 Wax XIAMETER™ OFX-0203 Fluid XIAMETER™ OFX-0230 Fluid XIAMETER™ OFX-0230 Fluid XIAMETER™ OFX-0230 Fluid XIAMETER™ OFX-0203 Fluid DOWSIL™ 2-5088 Wax DOWSIL™ 2-5088 Wax XIAMETER™ PMX-200 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-0244 Cyclotetrasiloxane Silicone Fluid XIAMETER™ PMX-0245 Cyclopentasiloxane XIAMETER™ PMX-0345 Siloxane Blend DOWSIL™ OS-2 Silicone Cleaner and Solvent XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid Silicone Fluid XIAMETER™ PMX-200 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid Silicone Fluid (10,000-60,000 cSt) (10,000-60,000 cSt) (10,000-60,000 cSt) pg 11
Table II: Water-based Product Comparison Comparison Ratings1 Currently Available in These Functions, Benefits and Description Geographic Areas Product Recommendations Shine Durability Silicone Fluid Americas, Asia XIAMETER™ MEM-0349 Emulsion Preferred for water-based formulations, •••• ••• Emulsion these emulsions and microemulsions Americas, Asia XIAMETER™ MEM-0039 Emulsion •• •• offer significant advantages when Americas XIAMETER™ MEM-1171 Emulsion formulating flexibility is desirable; •••• •• good compatibility; good surface Americas abrasion characteristics; good gloss, •• ••• minimum smear; for use in automotive polishes and rubber/vinyl protectant formulations, cleaning properties; Americas XIAMETER™ MEM-1101 Emulsion provide proven performance, reliable ••• •• quality and speed to market; the small Europe XIAMETER™ MEM-0346 Emulsion particle size of the microemulsion •••• ••• products offers better penetration, Europe XIAMETER™ MEM-1473 Emulsion •••• ••• improved wetting out, more consistent Global XIAMETER™ MEM-0347G Emulsion coatings. ••• •• Europe XIAMETER™ MEM-1015 Emulsion •••• ••• Global DOWSIL™ HV 495 Emulsion •••• •••• Silicone Fluid Global XIAMETER™ MEM-1716 Emulsion ••• •• Microemulsion Global XIAMETER™ MEM-1865 Emulsion •• ••• Amino Functional Global XIAMETER™ MEM-8035 Emulsion Provide outstanding bonding and ••• •••• Silicone adhesion properties to automotive Emulsion finishes, allowing repeated washings and adverse weather conditions. Alkylaryl Global XIAMETER™ MEM-5009 Emulsion Have properties similar to •• •• Functional intermediate-viscosity fluids, but with Silicone alkyl functionality; serve as actives Emulsion for leather conditioners; provide Europe DOWSIL™ 2418 Release Emulsion preferred technologies to formulate ••• ••• products for body shop use. Amino Emulsion Japan DOWSIL™ BY 22-729 Provides durability to tire treatment •• •••• Silicone EX Emulsion products. Emulsion Resin Emulsion Japan DOWSIL™ BY 22-729 Provides durable water repellency ••• •••• to liquid car polish products, tire treatment products. Amino Japan DOWSIL™ FZ-4658 Provides durable water repellency to ••• •••• Microemulsion shampoo for automated car washes; the small particle size prevents blockage in the pipes of the washing mechanism. 1. omparison Ratings (••••• = Best, • = Moderate). Note: Ratings are a preliminary guideline only. See product data sheets for detailed information. C All tested products have been tested at 5% actives on automotive panels using a suitable solvent. pg 12
Comparison Ratings1 Compliant Viscosity, cSt2 with European (‡polymer viscosity Detergent Ease of for the emulsion Emulsifier Free of APEO Regulations EC Use Wetting Slip products) % Actives Type Surfactants 648/2004 Notes •••• ••• •• 350 ‡ 60 Nonionic Yes Yes ••• •• • 350‡ 35 Nonionic Yes Yes •••• ••• ••• approximately 550‡ 50 Nonionic Low-odor ••• ••• •• 1,000‡ 60 Slightly Yes Emulsifiers catwwionic are readily biodegradable ••• ••• ••• 125,000‡ 60 Anionic Yes •••• ••• •• 350 ‡ 60 Nonionic Yes Yes ••• ••• • 400 50 Nonionic Yes Yes •••• ••• • OH Functional 60 Nonionic Yes Yes •••• ••• ••• 1,000‡ 60 Slightly Yes Yes anionic • ••• •• 100,000‡ 35 Anionic Yes Yes •• •• •••• 10,000 ‡ 30 Cationic Yes Yes Clear translucent •• •• •••• 12,500‡ 25 Anionic / Yes Yes Translucent nonionic •• • •••• - 35 Cationic Yes Yes ••• ••• •• - 50 Nonionic Yes Emulsifiers are readily biodegradable ••• ••• • - 50 Nonionic Yes No • • •• 20 Nonionic Yes •••• ••• •• 70 Nonionic Yes •••• ••• ••• 15 Nonionic Yes Yes Translucent gray pg 13
Table III: Solvent-based Product Comparison Currently Available in These Description Geographic Areas Product Functions, Benefits and Recommendations Volatile Global XIAMETER™ PMX-200 Volatile, low-viscosity fluids designed for use as carriers, high-performance Silicone Silicone Fluid, 0.65 cSt non-VOC3 solvents and cleaning aids in a wide range of automotive polish Global DOWSIL™ OS-2 Silicone formulations; effective wetting properties deliver actives to the automotive Cleaner and Solvent surface; slip, water repellency and gloss characteristics are present for a limited time; replace mineral seal oil in rinse aids; effective microemulsions Global XIAMETER™ PMX-1184 can be achieved when combined with silicone surfactants. Silicone Fluid Global XIAMETER™ PMX-0244 Cyclotetrasiloxane Global XIAMETER™ PMX-0245 Cyclopentasiloxane Global XIAMETER™ PMX-0345 Cyclosiloxane Blend Silicone Fluid Global XIAMETER™ PMX-200 High-viscosity fluids provide excellent depth of gloss and improvements Silicone Fluid in durability and water resistance; useful in solvent-based formulations; blend of intermediate- and high-viscosity fluids recommended to achieve a good balance in gloss, application ease and rub-out; a 3:1:1 ratio of 350, 1,000 and 12,500 cSt products optimizes shine and durability; products are available in emulsion form. Amino Global XIAMETER™ OFX-0531 Fluid Offering enhanced durability, detergent resistance and corrosion resistance; Functional offered in crosslinkable (curable) and non-crosslinkable versions; curable Global XIAMETER™ OFX-0536 Fluid Silicone products produce a continuous film; non-crosslinkable products offer Global XIAMETER™ OFX-8630 Fluid excellent stability and shelf life; deposit and adhere strongly to automobile finishes, chrome and aluminum surfaces. Alkylaryl Global XIAMETER™ OFX-0203 Fluid Have properties similar to intermediate-viscosity fluids, but with alkyl Functional functionality; serve as actives for leather conditioners; provide preferred Global XIAMETER™ OFX-0230 Fluid Fluid technologies to formulate products for body shop use. Silicone Global DOWSIL™ 2-5088 Wax Serves as active for leather conditioners; provides preferred technologies to Wax formulate products for body shop use; serves as an ingredient for hard waxes, paintable polishes, wax conditioners, polishes and polymer sealants. Emulsifier Global XIAMETER™ OFX-0190 Fluid Cleaning and wetting properties; lubricity in glass cleaners; ability to Wetting be used in water-in-oil and water-in-silicone emulsions makes them Global XIAMETER™ OFX-0193 Fluid Agent unique to formulate non-VOC products; XIAMETER™ OFX-0190 Fluid, Global DOWSIL™ 3225 C XIAMETER™ OFX-0193 Fluid and XIAMETER™ OFX-3667 Fluid are suited Formulation Aid for cosurfactants; XIAMETER™ OFX-0193 Fluid for anti-fog applications; DOWSIL™ 3225C Formulation Aid for water-in-silicone emulsions; Global XIAMETER™ OFX-3667 Fluid DOWSIL™ 5200 Formulation Aid for water-in-oil emulsions. Global DOWSIL™ 5200 Formulation Aid Silicone Resin Global DOWSIL™ 593 Fluid Long-lasting water durability and repellency that protects automotive surfaces; preferred when enhanced water beading is desired; some can Global DOWSIL™ FBL-0563 Formulated Blend be reacted with catalyst agents to formulate fabric water repellents. Global DOWSIL™ 2-1912 Fluid Global DOWSIL™ 3527 Release Agent 1. omparison Ratings (••••• = Best; • = Moderate). Note: Ratings are a preliminary guideline only. See product data sheets for C detailed information. All tested products have been tested at 5% actives on automotive panels using a suitable solvent. 2. The above information is not intended for use in preparing product specifications. Contact Dow before writing specifications. 3. VOC = Volatile Organic Compounds, according to the U.S. Clean Air Act. Contact Dow for product compliance in your area. 4. California Air Resources Board. pg 14
Comparison Ratings1 Viscosity, Shine Durability Ease of Use Wetting Slip cSt2 % Actives Notes ••••• ••••• 0.65 100 Volatile carrier; CARB4 compliant •••• 0.78 100 1.6 100 Not tested for comparison ratings 2.5 100 Volatile carrier; CARB4 compliant; not tested for comparison ratings ••••• ••••• 4.0 100 Volatile carrier; CARB4 compliant ••••• ••••• 5.0 100 Volatile carrier; CARB4 compliant •••• •• •••• •••• ••••• 50 - 1,000 100 •••• •••• •• • •••• 10,000 - 100 60,000 ••••• ••• ••• •• • 160 50 •• ••••• ••• • •• 40 100 • •••• ••• •• •• 500 100 ••• ••• ••• ••• • 1,200 100 Not tested for comparison ratings 1,125 - 100 1,645 •••• •••• •• • - 100 Melt at 70°C prior to use 2,000 100 Not tested for comparison ratings • ••••• ••••• • 400 100 • • ••• ••• • 700 100 200 - 500 100 Not tested for comparison ratings •••• • •• •• • 2,500 100 •• •• •••• •••• ••• 700 100 7 42 Air-drying, air-curing; imparts a high degree of water repellency on natural and synthetic fabrics; not tested for comparison ratings •••• •• •••• •••• ••• 700 100 ••• ••• ••• ••• •• 2,000 100 pg 15
Reformulate Your Tire and Vinyl Dressings with Products from Dow and Avoid Costly Fines Dow C.A.R.B. – Compliant Solutions for Automotive Surfaces Failure to comply with the California Air vehicles and making them look like decision to switch from your current Resources Board’s (C.A.R.B.’s) volatile organic new. And they rely on your vinyl and solvent to slow-drying Isopar affin compound (VOC) limits could cost you up to tire dressings to help them do just that. solvents, for example, could short-change $50,000 per day in fines. We understand how difficult it can be to your product (and your customers) in reformulate solvent-based dressings that critical performance benefits. The good news is that Dow can help you comply with environmental regulations Dow offers solutions that can help you easily reformulate your products to meet without sacrificing the performance your customers have come to expect. • Control your wetting properties C.A.R.B. requirements. and drying time A Challenging Task Reliable Solutions • Enhance color for that new-car Effective January 1, 2003, non-aerosol Dow can offer you reliable solutions showroom look automotive rubber and vinyl protectants that deliver both high performance and • Modify shine and durability sold in the state of California required C.A.R.B. compliance. • Make your product easier to apply a maximum VOC limit of 3 percent. There are many ways to reformulate, (To learn more about how C.A.R.B. including cost-inviting water-based We have prepared sample formulations regulations impact your business, read formulas and VOC-exempt solvent to show you how easy it is to formulate a our Tip Sheet on California regulations alternatives. However, many of these VOC-exempt Fast Dry tire dressing using for auto appearance products.) Today’s solutions come with trade-offs. The XIAMETER™ PMX-1077 Fluid. Compare consumers enjoy beautifying their the outstanding results Dow delivers pg 16
(Figure 1) to the results obtained using an content. There is a fee for these services, Isopar affin-based formula (Figure 2). but they can save you money, time, and Keep your business trouble by helping you avoid violations Or, if a water-based formula is an and costly fines. moving forward. option for you, try the XIAMETER™ MEM-0349 Emulsion multi-surface Copies of our California regulations Tip Save money, time, and dressing formulation with vertical Sheet and C.A.R.B.-compliant prototype trouble with Dow clinging properties (Figure 3). formulations are available from your Service Solutions. Dow representative. Compare the Alternatives Figure 4: Drying-Time Chart – VOC-exempt solvents are shown in purple The drying-time chart (Figure 4) lets you compare the performance of Dow’s Comparison of Volatile Siloxanes and Common Solvents Thin-Film Drying Time on Metal Surface volatile siloxanes vs. common organic- based solvents. As you can see, an organic- based VOC-exempt solvent may not meet 100 DOWSIL™ OS-2 Silicone your formulation requirements. Dow’s Cleaner & Solvent VOC-exempt fluids, on the other hand, 80 IPA Isopar H can give you the flexibility you need to % Weight Remaining O.M. SPIRITS formulate compliant products that live XIAMETERTM PMX-0245 up to your customers’ expectations. 60 Cyclopentasiloxane XIAMETER™ PMX-0345 Need to know if your product or Cyclosiloxane Blend proposed formulation will stand up to a 40 XIAMETER™ PMX-200 C.A.R.B. inspection? Silicone Fluid, 2 cSt Isopar M Dow Analytical Services has the 20 XIAMETER™ PMX-200 Silicone Fluid, 5 cSt capability to analyze for water content, ammonium content, prohibited 0 compounds, ketones, and alcohols to 0 20 40 60 80 100 120 140 help you determine if you are meeting Time (minutes) the C.A.R.B. guidelines for volatile See product datasheet for more information. Figure 1: Tire treated with Tire Dressing Formula TP-750 Figure 2: Tire treated with Tire Dressing Formula TP-770 Figure 3: Tire treated with Water-Based Tire Dressing Formula (XIAMETER™ PMX-1077 Fluid), Form No. 26-1613 (Isopar affin), Form No. 26-1615 IP-580 (XIAMETER™ MEM-0349 Emulsion), Form No. 26-1616 pg 17
Tip Sheet for California Regulations for Auto Appearance Products The California Air Resources Board (C.A.R.B.) has a Consumer New York: Products Compliance Program that implements regulations and • www.dec.ny.gov/regs/2492.html ensures compliance for the amount of volatile organic compounds (VOCs) in consumer products. • www.dec.ny.gov/regs/4201.html WHO is impacted by these regulations? New Jersey: Companies that manufacture, distribute and/or sell consumer Subchapter 24: Prevention of Air Pollution from Consumer products for both retail sales and institutional sales in the state Products and Subchapter 16: Control and Prohibition of Air of California. Pollution by Volatile Organic Compounds Because both retail sales and institutional use are included • www.state.nj.us/dep/aqm/rules.html#27 in these regulations, it is important to know the difference Pennsylvania: between these categories. • www.dep.state.pa.us/dep/deputate/airwaste/aq/regs/regs.htm In retail sale the end formula is purchased for personal use by a consumer at a retail store, such as a gas station, retail chain • www.pacode.com/secure/data/00.25/chapter130/s130.211.html or auto specialty store. Whereas with institutional use the end Virginia formula is purchased by a company such as a car dealership, body shop, rental car agency or car wash and the user is an 9VAC5-40-7270. Standard for volatile organic compounds employee of that company. • http://leg1.state.va.us/cgi-bin/legp504. exe?000+reg+9VAC5-40-7270 WHAT auto products are affected and WHEN do the regulations become effective? Delaware The table on page 19 is a partial list from the Consumer Regulation No. 1141: Limiting Emissions of Volatile Organic Products Program. Compounds from Consumer and Commercial Products WHERE can I find more information about these • http://regulations.delaware.gov/AdminCode/ regulations? title7/1000/1100/1141.shtml Visit www.arb.ca.gov for more information on the Consumer District of Columbia Products Program of the California Air Resources Board (C.A.R.B.). Chapter 7 – Volatile Organic Compounds WHY are some solvents classified as “VOC-exempt”? • http://ddoe.dc.gov/ddoe/frames.asp?doc=/ddoe/lib/ddoe/ There are two ways a solvent can be classified as “VOC-exempt” information2/air.reg.leg/chapter7revised.pdf for the California Consumer Products Program. First, if a solvent is a low vapor pressure or high boiling point compound, Maine it is considered exempt. These solvents are called “LVP-VOC” Bureau of Air Quality compounds and are dramatically slower to dry than traditional Chapter 152: Control of Emissions of Volatile Organic solvents used in auto appearance products (such as odorless Compounds from Consumer Products mineral spirits). Second, there is a small family of fast-drying • www.maine.gov/dep/air/regulations/docs/CHAP152%20 solvents that have been exempted by the California Consumer Consumer%20Products%202007.pdf Products Program. Dow volatile methyl siloxanes are recognized as being non-ozone-depleting; they are exempt from U.S. Chapter 159: Control of Volatile Organic Compounds from EPA VOC regulations and are also exempt by the California Adhesives and Sealants Consumer Products Program. • www.maine.gov/dep/air/regulations/recentlyadopted.htm ARE OTHER STATES adopting these or similar standards? Maryland YES, various states in the country are or have already adopted Code of Maryland Regulations 26.11.32 Control of Emissions of these standards. Consult the specific state regulations on air Volatile Organic Compounds from Consumer Products quality or air resources of your concern. Below, we offer links to • www.mde.state.md.us/ResearchCenter/laws_regs/ assist you. procreg_26_11_32_033007.asp • www.mde.state.md.us/ResearchCenter/laws_regs/index.asp pg 18
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