EURO 7 IMPACT ASSESSMENT: THE OUTLOOK FOR AIR QUALITY COMPLIANCE IN THE EU AND THE ROLE OF THE ROAD TRANSPORT SECTOR OZONE SUPPLEMENT - An ...
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EURO 7 IMPACT ASSESSMENT: THE OUTLOOK FOR AIR QUALITY COMPLIANCE IN THE EU AND THE ROLE OF THE ROAD TRANSPORT SECTOR OZONE SUPPLEMENT An independent study undertaken on behalf of ACEA
Executive Summary This report is part of a Euro 7 Impact Assessmenta intended to quantify the impact on measured air quality in urban environments throughout the EU 1 between 2020 and 2035 following the implementation of currently mandated emission reduction measures 2 in all contributing sectors, including road transport. The main study explored NO2, PM2.5, PM10 and Ozone; the aim of this study is to focus on the effect of these measures on ozone, including the impact on compliance with EU legislated targets and WHO guideline values. The emissions Base Case adopted for this study is consistent with the Thematic Strategy on Air Pollution Report #16 Current Legislation Baseline Scenario data from the GAINS3 model for all sectors except road transport. Road transport emissions are derived from the SIBYL 4 baseline fleet and COPERT5 emission tool. Specific elements of the Baseline fleet have been modified to more accurately reflect the anticipated real-world fleet composition predicted by ACEA.6 To determine the impact of emission changes, the concentrations at urban monitoring stations across the EU have been modelled using the AQUIReS+ model, developed by Aeris Europe and used in previously published works on urban air quality.b, c Regarding the impact on urban ozone, the results of this study indicate that widespread non- compliance with the targets in the current Ambient Air Quality Directive (AAQD) d will continue throughout the study period. The study also shows that the magnitude and extent of this non- compliance increases significantly if the lower threshold in the current World Health Organisation (WHO) guidelinese is applied. However, the effect of reducing road transport emissions beyond that achieved in the Base Case does not improve the ozone compliance situation in urban areas. NOX and NMVOC emissions are both important contributors to the photochemical production of tropospheric (low-level) ozone on a regional scale. Therefore generally, the reduction of both these pre-cursor emissions contributes to the reduction of tropospheric ozone. However, over cities, ozone levels (produced through photochemical processes on the regional scale) are reduced due to the titrating effect of NO (the most significant component of overall NOX emissions) to produce molecular oxygen and NO2. This is most marked in densely trafficked city centres where the reductions in ozone levels can be very significant, with reductions ranging from 10-20µg/m3. Therefore, when this titrating effect is removed from the city, ozone levels/ozone non-compliance in the city increases. This is despite any contribution that the NOX reductions in the city have on reducing photochemical production of ozone at a regional scale. This effect is most marked in cities where the regional, photochemical production of ozone is relatively low e.g., Northern European countries bordering seas. This is clearly seen in the cities of Brussels, London, and Paris but is also seen in the city of Madrid. The significance of this titration effect is clearly demonstrated by the so-called ‘source receptor’ (SRs) relationships for ozone derived from the EMEP model which are incorporated into IIASA’s Integrated Assessment Model, GAINS. Both models are 1 For the purposes of this study, the ‘EU’ includes the EU 27 nations and the United Kingdom. 2 Where it has not been possible to quantify the impact of a measure, for example the Medium Combustion Plant Directive, emissions have not been reduced. 3 The Greenhouse gas - Air pollution Interactions and Synergies (GAINS) model, developed at the International Institute for Applied Systems Analysis (IIASA). 4 SIBYL baseline: vehicle fleet and activity data projections for the member states of the of the EU. 5 COPERT is the EU standard vehicle emissions calculator, developed and maintained by EMISIA SA for the EEA. 6 The European Automobile Manufacturers' Association (ACEA) represents the 15 major Europe-based car, van, truck, and bus makers. 3
used to support air quality policy development in the EU and have been used to support the UN-ECE Convention on Long Range Transport of Air Pollution (CLRTAP) for more than two decades. The responses to NOX and NMVOC emission changes as seen through the lens of these SRs are discussed in the body of this report and show that reductions in national NOX emissions in the countries where these cities are located, result in increased ozone concentrations. When it comes to NO2 compliance, the ozone response to NOX emission reductions creates an ‘environmental tension’ since reductions in NOX designed to reduce NO2 health impacts results in increased ozone health impacts in such cities. This suggests targeted, city specific measures, rather than the introduction of tougher EU-wide NOX emission limits is the wiser route to address the diminishingly small residual ‘islands of NO2 non-compliance’. The study also shows that a more effective strategy to reduce ozone, especially in urban areas, is to target NMVOC emissions from the ‘solvent and product use’ sector. This sector is the largest contributor to anthropogenic NMVOC emissions in the Base Case. The study also shows that further NMVOC emissions reductions in other sectors has only a small effect on ozone levels/ozone compliance. a (Aeris Europe, 2021) Euro 7 Impact Assessment: The Outlook for Air Quality Compliance in the EU and the Role of the Road Transport Sector b (Aeris Europe, 2016) Urban Air Quality Study, #11/16 c (Concawe, 2018) A comparison of real driving emissions from Euro 6 diesel passenger cars with zero emission vehicles and their impact on urban air quality compliance d (Directive (EU) 2008/50/EC, 2008) Directive 2008/50/EC Of The European Parliament And Of The Council on ambient air quality and cleaner air for Europe e (WHO, 2005) WHO Air quality guidelines for particulate matter, ozone, nitrogen dioxide and sulfur dioxide 4
Contents Executive Summary................................................................................................................................. 3 Introduction ............................................................................................................................................ 7 Methodology......................................................................................................................................... 11 Overview of Base Case Emissions by Sector - NOX and VOCs ........................................................... 11 Scenarios ........................................................................................................................................... 13 Passenger Car and Light Duty Vehicle Scenarios .......................................................................... 13 HDV and Bus Scenarios ................................................................................................................. 13 Other Scenarios:............................................................................................................................ 13 Ozone Targets ................................................................................................................................... 14 Air Quality Model - AQUIReS+ .......................................................................................................... 14 Modelling Results.................................................................................................................................. 15 An Insight Through the EMEP Source-Receptor Relationships ......................................................... 15 Base Case Modelling Results............................................................................................................. 18 Air Quality Response to Key Ozone Scenarios .................................................................................. 19 City Focus .......................................................................................................................................... 20 Conclusions ........................................................................................................................................... 25 Appendices............................................................................................................................................ 26 National Emissions ............................................................................................................................ 27 NOX Base Case Emissions (kt/a) .................................................................................................... 27 NMVOC Base Case Emissions (kt/a) .............................................................................................. 28 SOMO35 and Daily Exceedances* at Stations in the Nine Cities (Base Case) .................................. 29 Berlin ............................................................................................................................................. 29 Brussels ......................................................................................................................................... 29 London .......................................................................................................................................... 30 Madrid........................................................................................................................................... 31 Milan ............................................................................................................................................. 32 Paris............................................................................................................................................... 32 Rome ............................................................................................................................................. 33 Stuttgart ........................................................................................................................................ 33 Warsaw ......................................................................................................................................... 33 References ............................................................................................................................................ 34 5
© 2021 Aeris Europe Ltd. Report prepared by: Les White, Adam Miles, Chris Boocock, John-George Cooper, Stephen Mills. Revision: 1.0 Background maps used in this report are © OpenStreetMap contributors. The full terms of this license are available at https://www.openstreetmap.org/copyright Extracts from ‘Ozone Trends in the United Kingdom over the Last 30 Years’ Florencia M. R. Diaz, M. Anwar H. Khan, Beth M. A. Shallcross, Esther D. G. Shallcross, Ulrich Vogt, and Dudley E. Shallcross © 2020 by the authors. Licensee MDPI, Basel, Switzerland. Used under the terms of the CC BY License. 6
Introduction Air Quality in European Cities continues to be an issue of policy and public concern at European, national and city level. While the last few years has seen attention focussed almost exclusively on non- compliance with the current AQLV for ambient nitrogen dioxide (NO2), over much of the EU compliance with ozone target values remains an issue. Importantly, efforts to reduce NOX emissions from road transport generally cause little to no reduction on ozone concentrations, and in many cities increases ozone concentration. The forthcoming revision of the AAQD is likely to reduce the permitted concentrations of specific pollutants, this is likely to further intensify current concerns over air quality and increase the focus on those emission sources that are believed to be major contributors to non-compliance. In response to this, the European Commission have started to prepare draft regulatory proposals for the next iteration of vehicle emission standards. To assist in the formulation of these Euro 7/VII proposals, the Commission have contracted members of CLOVE (Consortium for Ultra Low Vehicle Emissions) to conduct a series of studies. The aim of this independent study is to put the contribution of road transport emissions into a Europe- wide context by examining the impact on urban air quality that currently mandated emission reduction measures from all contributing sectors will achieve. This is followed by an assessment of what a further tightening of Euro standards, including a hypothetical ‘Euro 7/VII’ can offer to the improvement of air quality compared to other available actions. The AQUIReS+ model has been used to forecast the effect of emissions changes on atmospheric concentrations at urban monitoring stations across the EU from 2020 to 2035. This ensures the modelling is directly related to the individual measuring stations used to monitor compliance with the legislated limit values. In this regard, it is worth noting that these limit values, as set forth in the Ambient Air Quality Directive, are the result of a lengthy legislative process beginning with the ‘Risk Assessment’ step undertaken by the WHO and concluding with the ‘Risk Management’ step of the finalisation process of the Directive. As such, these limits represent the legislator’s view of the appropriate level of managing the risk associated with human exposure to each pollutant in the context of a multi-risk world. Therefore, from an air quality perspective, compliance with limit values must be the priority for the protection of human health. The main study explored NO2, PM2.5, PM10 and ozone (O3); the aim of this companion report is to focus solely on ozone. In so doing, it draws on the detailed results and findings of the main study but also provides additional ozone specific considerations, including a brief overview of the processes involved in the formation of this secondary pollutant. It also seeks to compare the main findings with other published studies. Tropospheric ozone,1 commonly known as low-level ozone, is a recognised transboundary pollutant and is photochemically formed in the boundary layer2 by the reaction of primary pollutants (e.g., NOX and VOCs) in the presence of sunlight. Ozone production (and therefore concentrations) downwind of cities and in rural and suburban areas, is typically higher than in cities due to the reaction between local emissions of natural and/or anthropogenic NMVOCs and NOX exported from the cities. Within 1 The authors gratefully acknowledge the following source of information in the drafting of this introductory section: Tropospheric ozone: background information (https://www.eea.europa.eu/publications/TOP08-98/page004.html) 2 The lowest part of the troposphere that is directly influenced by the presence of the earth's surface. 7
cities and more densely populated areas, where NOX emissions are typically higher, ozone concentrations tend to be lower due to the titrating effect of NO. The chemical formation of ozone The photochemical chain reaction which produces ozone is initiated and maintained by reactive radicals. VOCs act as ‘fuel’ in the formation process (from both biogenic and anthropogenic sources), whereas NO essentially functions as a catalyst since it is regenerated in the formation process. NO also plays a key role in the regeneration of the reactive radicals and the further progress of the reactions. High concentrations of freshly emitted NO scavenge ozone from the local atmosphere, a process leading to the formation of NO2. Close to the emission sources, this titration process is effectively an ozone sink. Because of these reactions a decrease in NOX can lead to an increase in ozone, as is the case in cities. This is known as a ‘VOC-limited regime’ and as such, emission control of VOCs is a more efficient strategy to reduce peak values of ozone. As an air mass moves away from an urban centre its VOC:NOX ratio changes due to further photochemical reactions, meteorological processes, and the occurrence of fresh emissions. The concentration of NOX decreases faster than that of VOC and consequently the VOC:NOX ratio is amplified. At high VOC:NOX ratios, like those often found in background situations, the chemistry tends towards the NOX limited case and NOX reductions are considered more effective to reduce ozone in these situations. The role of methane (CH4) in ozone formation Methane is recognised as an important contributor to background ozone levels at a hemispherical scale3 over long timescales. The background level in Europe and the USA is currently between 10 and 30ppb and is increasing by some 1ppb each decade. a,b However, over shorter timescales (days or weeks), methane, due to its very low chemical reactivity, does not significantly contribute to tropospheric ozone levels on top of this background level. Figure 1 shows the long term (over three decades) trend in ozone concentrations and NOX concentrations averaged over thirteen rural and six urban air quality monitoring stations in the UK. The trend in average ozone concentration from the rural sites (showing an increase of some 1.3ppb/decade) is consistent with the general increase in background ozone in the northern hemisphere as noted above. At the urban stations, this growth is more significant (some 2ppb/decade) due to the additional contribution from increased urban ozone due to the loss in titration arising from the significant decrease in NOX over the same period. In contrast to the increase in annual mean ozone levels at the rural stations, the maximum ozone (averaged over the thirteen stations) shows a strong downward trend, consistent with the significant reductions in both NOX and VOC emissions through the wide range of legislative initiatives in Europe over the same period. 3Given the effects of meteorology and global emissions on ozone production, background ozone levels (and production processes) are typically divided into northern and southern hemispheres. 8
Figure 1 - Long term trends in average and maximum O3 and average NOX levels from 13 rural and 6 urban air quality monitoring stations in the UK 4 4Extracted from ‘Ozone Trends in the United Kingdom over the Last 30 Years’ Florencia M. R. Diaz, M. Anwar H. Khan, Beth M. A. Shallcross, Esther D. G. Shallcross, Ulrich Vogt, and Dudley E. Shallcross © 2020 by the authors. Licensee MDPI, Basel, Switzerland and used under the terms of the CC BY License. 9
Table 1, derived from the same study, shows the number of 8-hour rolling average exceedances above a 50ppb threshold in a year (average over the number of Rural and over the number of Urban stations). The number of exceedances for the urban sites is clearly much lower than that for the rural sites due to the titrating effect of NO over the urban areas. The increase in average exceedances between the 1990s and the 2000s is indicative of the significant reduction in road transport NOX emissions from the progressive introduction of Euro standards into the pre-Euro standard vehicle parc in this period. The authors of the source paper indicate that the subsequent reduction in exceedance in the next decade was likely due to the reduction in anthropogenic NMVOCs from meeting the obligations of the 1999 Gothenburg protocol, which reduced NMVOC emissions in the UK by some 40% from the 2000s to the 2010s. Although the UK is used as an example, this is typical of EU member states. Table 1 - Average ozone exceedances over the last three decades Site Type 1990s 2000s 2010s Overall Rural 1941 2141 1412 5494 Urban 532 647 376 1554 Figure 2, also taken from the same study, shows the total number of exceedances for each day of the week in both rural and urban sites averaged for the same three decades. Total exceedance is calculated as the total number of hours over an ozone concentration of 50 ppb. Again, these data show the much lower number of exceedances at urban sites, typically less than 20% of the average of rural sites during a weekday. The increase in urban exceedances during the lower traffic activity occurring at weekends is also very evident, again illustrating the effect of reduced ozone titration. Figure 2 - Daily total ozone exceedances in (a) rural and (b) urban sites averaged for the decades of the 1990s, 2000s and 2010s. a (Golomb & Fay, 1989) The Role of Methane in Tropospheric Chemistry (MIT-EL-89-001) b (Diaz, et al., 2020) Ozone Trends in the United Kingdom over the Last 30 Years 10
Methodology Overview of Base Case Emissions by Sector - NOX and VOCs One of the aims of this study was to put the emissions from each primary source sector into context. This is important for two reasons: It provides a historical perspective, and it facilitates appropriate prioritising of any new emission reductions. Figure 3 shows the total Base Case emissions of NOX in the EU and Figure 4 the total Base Case emissions of VOC used in this study. Each source sector is shown separately so that the contribution of each to overall emissions can be clearly seen. The detailed build-up of the emissions from Road Transport (based on the Sibyl Baseline developed by Emisia) is given in the main report.1 The remaining sectoral contributions are consistent with the TSAP16 Base Case Scenario developed by IIASA and associated with the revision of the EU’s Thematic Strategy on Air Pollution. 2 Agri cul ture Wa s te Ma na gement Non Roa d Mobi l e Ma chi nery Road Trans port kt/a Sol vent roduct Us e Fuel Extra c on Indus tri a l roces s es Indus trial ombus on 2 Domes c ommerci a l ombus on Energy roduc on 2 2 2 2 2 2 2 2 ear Figure 3 - EU - NOX emissions Base Case. Source: GAINS IIASA 1(Aeris Europe, 2021) Euro 7 Impact Assessment: The Outlook for Air Quality Compliance in the EU and the Role of the Road Transport Sector 11
7 Agri cul ture Wa s te Ma na gement Non Roa d Mobi l e Ma chi nery Road Trans port kt/a Sol vent roduct Us e Fuel Extra c on Indus tri a l roces s es 2 Indus trial ombus on Domes c ommerci a l ombus on Energy roduc on 2 2 2 2 2 2 2 2 ear Figure 4 - EU - NMVOC emissions Base Case. Source: GAINS IIASA 12
Scenarios All the scenario explored in the overall study are described in the main report,2 therefore only those scenarios relevant to the ozone focus of this complementary report are described below. Passenger Car and Light Duty Vehicle Scenarios Scenario 7 - Diesel PC and LCV: NOX 0 For diesel PC and LCV N1-I both NOX and PM2.5 exhaust emissions were set to zero. Scenario 8 - Diesel LCV N1-II and LCV N1-III: NOX 0 For diesel LCV N1-II and LCV N1-III both NOX and PM2.5 exhaust emissions were set to zero. HDV and Bus Scenarios Scenario 12 - Ultra-Low NOX scenario (Diesel HCV) NOX limit of 30 mg/kWh An ultra-low NOX scenario modelling a reduction in NOX limit to 30mg/kWh by applying a coefficient of 0.075 to diesel LCV N2 and HDV Base Case emissions. Other Scenarios: Scenario 9 - Zero Emissions from Domestic & Commercial Combustion A hypothetical scenario to test the impact on air quality if residential and commercial emissions of NOX were reduced to zero from 2025. Scenario 15 - VOC Emissions from Road Transport: Zero A hypothetical scenario to explore the impact on air quality of eliminating all VOC emissions from the road transport sector from 2025, evaporative and exhaust. Scenario 16 - VOC Emissions from Solvent and Product Use sector: 50% A hypothetical scenario to explore the impact on air quality by reducing VOC emissions from the ‘solvent and product use’ sector by 50% from 2025. 2(Aeris Europe, 2021) Euro 7 Impact Assessment: The Outlook for Air Quality Compliance in the EU and the Role of the Road Transport Sector 13
Ozone Targets The AAQD does not specify a binding limit value for ozone, instead there are target values for the protection of human health and protection of vegetation. The WHO have also published a guideline value for the protection of human health. These values are summarised in Table 2. Table 2 - AAQD and WHO ozone target values for the protection of human health Source Frequency Value (µg/m3) Allowed Exceedances Maximum 25 days AAQD – Protection of human health 120 daily (averaged over 3 years) eight-hour WHO – Protection of human health 100 0 mean Air Quality Model - AQUIReS+ AQUIReS+ is Aeris Europe’s air quality forecasting model. Designed to predict the concentration of the main pollutants covered by the AAQD, and compliance with air quality limit values at individual monitoring stations in the European Air Quality monitoring station network. The detail of the modelling system, including its sister tool ‘AQUIReS’, is covered in detail in the main report.3 For ozone, the AQUIReS+ model was used to generate a series of predictions for the ozone metrics of ‘SOMO35’4 and the ‘Maximum daily 8 hour mean’ (rolling average). The primary metric in the source- receptor relationships (derived from EMEP modelling runs) to relate emission changes of NOX and NMVOC to changes in ozone is SOMO35. Within the AQUIRES+ modelling framework, the SOMO35 metric, derived from hourly historical measuring station data, is statistically correlated to the ‘Maximum daily 8 hour mean’ (rolling average), again based on hourly measuring station data. These relationships are generated for each individual measuring station. Station selection criteria and the uncertainty aspects of the modelling are discussed in detail in the main report. 3 (Aeris Europe, 2021) Euro 7 Impact Assessment: The Outlook for Air Quality Compliance in the EU and the Role of the Road Transport Sector 4 SOMO35 - defined as the sum of means over 35 ppb from a daily maximum 8-hour rolling average 14
Modelling Results The current AAQD specifies a non-binding target value for the protection of human health from exposure to ozone. This is based on limiting the number of exceedance days in one year to 25 days of the rolling eight-hour average concentration above an ozone concentration threshold of 120µg/m 3, averaged over three-years. The WHO 2005 Guidelines reduces the daily threshold from 120µg/m3 (in their previous published guidelines) to 100µg/m3. This study therefore also examines the implications of this lower threshold, should it be adopted in a future revision of the AAQD. An Insight Through the EMEP Source-Receptor Relationships As discussed in the introduction, the formation of ozone in the atmosphere is a complex photochemical process involving reactive hydrocarbons (NMVOC1) and oxides of nitrogen. Complex chemical models have been developed to represent these reactions, including the EMEP model developed and maintained by the Norwegian Meteorological Institute.2 Data from the EME model is used to generate European ‘source-receptor’ (SR) functions which relate emissions (e.g., NMVOC and NOX) from each country and sea area to their contribution to pollutant concentrations in each ‘receptor grid’ of the model domain. These SRs are derived from the results of a large number of EMEP model simulations undertaken by the Norwegian Meteorological Institute. For the whole European region (comprising more than forty countries and five sea areas) this involves some 1200 individual simulations. In each run, the emissions of a single pollutant, from a single country or sea area, are reduced from an emissions ‘Base ase’ by %. This same run is repeated for five separate meteorological years to enable the inter-annual meteorological variability to be built into a set of ‘five meteorological year averaged’ SRs. Aeris gratefully acknowledges the co-operative relationship with NMI in their provision of these detailed simulations results which enabled generation of detailed SR functions for the whole of Europe and their incorporation into AQUIReS+. It is worth noting, that these SRs are consistent with those incorporated into the IIASA GAINS model used to support the European ommission’s Clean Air for Europe Programme (CAPE). In themselves, these SRs at the individual EMEP grid level provide a helpful insight into the ozone response to reductions of both NOX and NMVOC emissions, especially at the urban level, which is the focus of this study. Figure 5 shows maps of four of the nine selected cities.3 In each case, the maps are overlaid with the boundaries of the EMEP grids that correspond to the city domain. In addition, the locations of the ozone monitoring stations are also shown. For each EMEP grid, the SR relationship for SOMO35 consists of a NOX and NMVOC emission term from each contributing country (including the country in which the city is located). 1 NMVOC - Non-Methane Volatile Organic Compounds 2 The co-operative programme for monitoring and evaluation of the long-range transmission of air pollutants in Europe: 'European Monitoring and Evaluation Programme' (EMEP). A scientifically based and policy driven programme under the Convention on Long-range Transboundary Air Pollution (CLRTAP) for international co-operation to solve transboundary air pollution problems. The EMEP model has been used to support European Air Quality Policy for more than three decades. 3 Berlin, Brussels, London, Madrid, Milan, Paris, Rome, Stuttgart, and Warsaw 15
Brussels In Figure 6, the SOMO35 response to a 1kt change in emissions from both NOX and NMVOC is shown for all nine selected cities including Brussels, Paris, Madrid and Rome.4 The SOMO35 responses to a change of 1kt of emissions in the country in which the city is located, and the equivalent change of 1kt (shared proportionally) from all the other contributing countries are shown separately. Although ozone is a transboundary air pollutant, Madrid Figure 6 shows that the most significant influence per unit change in emissions is from the country in which the city is located. This is particularly evident in the case of Brussels, London, Madrid, and Paris. Furthermore, the significant increase in SOMO35 in these cities when NOX emissions are reduced in the country where these cities are located, is also evident. This is consistent with Paris the long-term measurement data from UK monitoring stations discussed in the introduction of this report. It is also evident from the monitoring station data in the city of Madrid, as discussed below. In contrast, the response to reductions in NMVOCs across all cities is to reduce SOMO35, affirming that targeting these emissions, rather than NOX, at least in the short/medium term, is Rome the appropriate urban ozone mitigation strategy. Figure 5 - Maps of four of the nine selected cities, overlaid with EMEP model grids and indicating the location of ozone monitoring stations 4 For simplicity, if a city covers multiple grids, only one grid is represented in Figure 6. 16
Berlin Brussels London Madrid Milan Paris Rome Stuttgart Warsaw SOMO35 per kt change in emissions 5 4 3 2 1 0 -1 -2 -3 NMVOC from the city's parent country NMVOC from all other countries NOₓ from the city's parent country NOₓ from all other countries Figure 6 - The SOMO35 response to a 1kt emission reduction in the nine selected cities based on the SRs derived from EMEP simulations Figure 7 shows the levels of SOMO35 in Madrid based on measurement station data from the city and its surrounding area. Here the SOMO35 for ozone has been calculated at each ozone measuring station for 2005, 2010 and 2015. In 2005 (with road transport made up of a mix of Pre-Euro, Euro I, Euro II, and a few Euro III vehicles) the NO component of NOX emissions from road transport activity in the city centre substantially reduces ozone levels compared to the suburban and rural areas around the city centre. In terms of SOMO35, the health impact metric, the reduction is five-fold. Over the next ten years NOX vehicle emission limits were progressively reduced, and NOX/NO emissions fell. By 2010 the effect of the reduced NO emissions is already visible with the SOMO35 level in the city centre doubling from the 2005 level, and by 2015 increasing to three to four times the 2005 level. Of course, these reductions in NOX have made an important contribution to the reduction of NO2 in the city of Madrid and to compliance with the NO2 limit value. However, ozone also has important health impacts and this ‘environmental tension’ between reducing NO2 concentrations and increasing ozone concentrations is an important consideration in the development of any further action to address NOX emissions. 2005 2010 2015 Figure 7 - SOMO35 based on monitoring data in Madrid: 2005 - 2010 - 2015 17
Base Case Modelling Results By 2025, ozone concentrations in the Base Case are predicted to meet the EU target of 25 exceedance days at all but 12% of the 1166 monitoring stations currently located in urban and suburban areas of the EU that have recorded exceedances in the last five years. This increases to 74% of stations if the limit is reduced to 100µg/m3. A summary of Base Case compliance is shown in Table 3. Table 3 – Number of ozone monitoring stations exceeding the EU target value of allowable exceedances of 25 days above a 120 µg/m3 threshold and WHO guide value threshold of 100 µg/m3 5 2020 2025 2030 2035 EU AAQD: 120µg/m3 (> 25 days) 204 (17%) 145 (12%) 116 (10%) 110 (9%) WHO: 100µg/m3 (> 25 days) 921 (77%) 884 (74%) 851 (71%) 841 (70%) Between 2020 and 2030 the number of urban and suburban stations that are non-compliant with the EU target value reduces by over 43% as a result of currently mandated emission reduction measures. However, this reduction is not seen in the case of the WHO threshold value of 100µg/m3. Against the WHO value, the reduction is only 8%, with over 70% of stations remaining non-compliant and only marginal further improvement by 2035. Compliance with the WHO guide value would therefore be a significant challenge in the EU. This difference in the compliance picture is clearly shown in Figure 8. Figure 8 - Ozone exceedance days in 2030 against the AAQD 120µg/m 3 target and WHO 100µg/m3 guideline 5AQUIReS+ requires a monitoring station to have recorded exceedances in the past five years to be able to predict exceedances. Therefore, stations which have never recorded an exceedance are excluded from these totals. This also means that there are slightly different numbers of stations for the two concentrations: • 120µg/m3 - 1166 stations • 100µg/m3 - 1198 stations 18
Air Quality Response to Key Ozone Scenarios As discussed earlier in the report, reducing NOX emissions can increase ozone concentrations, particularly in cities and city centres, whereas reducing NMVOC emissions reduces ozone concentrations both in and outside the city. Therefore, to ascertain the scale of possible reductions in ozone concentration the scenario that has the greatest impact on NMVOC emissions (Scenario 16), and the elimination of all (exhaust and evaporative) NMVOC emissions from road transport are briefly looked at here. Table 4 shows that eliminating VOC emissions from road transport has a marginal impact on compliance across the EU. This is the case for both the EU AAQD target value and the WHO guideline value. This limited impact is consistent with the small contribution that modern gasoline and diesel vehicles make to total VOC emissions. This indicates that any further tightening of VOC emission limits for road transport (exhaust or evaporative) would have a minimal impact on ozone compliance. Conversely, further reducing emissions from the ‘solvent and product use’ sector is foreseen to have a more significant impact on ozone compliance in the EU. This reflects the much higher contribution from this sector to VOC emissions in the Base Case. Table 4 – Number of non-compliant ozone measuring stations (urban and suburban) with ozone exceedances for key scenarios at 120µg/m3 and 100µg/m3 2020 2025 2030 2035 120µg/m3 (> 25 days) Base Case 204 (17%) 145 (12%) 116 (10%) 110 (9%) VOC Emissions from Road Transport: Zero 204 (17%) 138 (12%) 109 (9%) 108 (9%) Scenario 15 VOC Emissions from Product Use sector: 50% 204 (17%) 107 (9%) 88 (8%) 83 (7%) Scenario 16 100µg/m3 (> 25 days) Base Case 921 (77%) 884 (74%) 851 (71%) 841 (70%) VOC Emissions from Road Transport: Zero 921 (77%) 870 (73%) 839 (70%) 824 (69%) Scenario 15 VOC Emissions from Product Use sector: 50% 921 (77%) 839 (70%) 800 (67%) 770 (64%) Scenario 16 19
City Focus For each of the nine selected cities, Table 5 through Table 13 provide the results of the modelled compliance with the current EU AAQD exceedance target.6 The results are given for the Base Case and the key scenarios impacting ozone: • Scenario 7: Zero NOx from Diesel Passenger Cars and Vans • Scenario 15: Zero VOC emissions from all road transport • Scenario 16: A 50% reduction in the Base Case VOC emissions from the Solvent and Product Use sector from 2025. The tables provide the modelled number of exceedance days at each ozone measuring station in each of the cities. The colours indicate the ‘compliance uncertainty bands' based on the RMS deviation between measured exceedance days and modelled exceedance days. The ‘green’ designation indicates compliance, the ‘yellow’ uncertain compliance/non-compliance and the ‘red’, non- compliance. By 2025, only three of the selected cities, Madrid, Milan and Paris are predicted to remain non- compliant in the Base Case (i.e., with at least one station remaining non-compliant). The suburban stations in these cites generally have higher levels of exceedance than urban stations while urban traffic stations having the lowest levels of exceedance. This is particularly visible in the case of Madrid, where exceedance levels at the urban traffic stations are some 7 days/year compared to the exceedances at the three suburban stations ranging between 33 and 39 days per year. This is entirely consistent with the significant titration of ozone by the NO component of NOX emissions particularly in city centres as discussed in the introduction. Although compliant, this pattern of higher exceedance days in suburban stations is evident in each of the studied cities. The impact of the key emission reduction scenarios affecting ozone compliance are also given in these tables. The road transport NOX reduction scenario (Scenario 7: Zero NOx diesel passenger cars and vans from 2025) has negligible impact beyond the baseline in all nine cities. As discussed in the main report, the additional emission reduction beyond that achieved by the Base Case is very limited, however, even this small further reduction in NOX increases the non-compliance at one station in the cities of Madrid and Paris. Again, this is consistent with the expectation from the EMEP source receptor relationship for these two cities as discussed in the introduction (Figure 6). The zero NMVOC emissions from road transport (Scenario 15) also has little impact on compliance given the small contribution of road transport to overall NMVOC levels, shown in Figure 4. However, as expected, this reduces exceedances by one day in a limited number of stations. Of all the scenarios considered in this study, the most significant improvement in ozone compliance come from the 50% reduction in NMVOC emissions from the ‘solvent and product use’ sector (Scenario 16). This is particularly evident in the cities of Madrid, Milan, and Paris. 6No more than 25 exceedance days per year of the highest 8-hour rolling average ozone concentration in a 24-hour period above the threshold of 120µg/m3 20
Table 5 - City of Berlin: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Area 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND SUBURBAN 15 13 13 15 13 13 14 13 13 13 11 11 BACKGROUND URBAN 14 12 12 14 12 11 13 12 11 11 10 9 BACKGROUND URBAN 12 11 10 12 10 10 12 10 10 10 9 8 Table 6 - City of Brussels: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Location 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND SUBURBAN 13 13 13 13 13 13 13 13 13 12 12 12 BACKGROUND SUBURBAN 14 13 13 14 13 13 12 12 12 8 8 7 BACKGROUND URBAN 10 9 9 10 9 9 9 9 9 8 8 8 BACKGROUND URBAN 7 7 7 7 7 7 6 6 6 6 6 6 BACKGROUND URBAN 6 6 6 6 6 6 6 6 6 5 5 5 TRAFFIC SUBURBAN 0 0 0 0 0 0 0 0 0 0 0 0 Table 7 - City of London: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Area 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND URBAN 9 9 9 9 9 9 9 9 9 9 9 9 BACKGROUND URBAN 4 5 5 4 5 5 4 5 5 4 4 4 BACKGROUND URBAN 3 4 4 3 4 4 3 4 4 3 3 3 BACKGROUND URBAN 0 1 1 0 1 1 0 1 1 0 0 0 BACKGROUND URBAN 0 0 0 0 0 0 0 0 0 0 0 0 BACKGROUND SUBURBAN 0 0 0 0 0 0 0 0 0 0 0 0 TRAFFIC URBAN 0 0 0 0 0 0 0 0 0 0 0 0 21
Table 8 - City of Madrid: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Location 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND SUBURBAN 33 33 34 33 33 34 31 32 33 28 29 30 BACKGROUND SUBURBAN 34 33 32 34 33 32 33 32 32 31 29 29 BACKGROUND SUBURBAN 39 40 41 39 40 41 38 39 39 34 35 35 BACKGROUND URBAN 33 32 31 33 32 31 32 31 31 30 29 28 BACKGROUND URBAN 26 27 27 26 27 28 25 26 27 23 23 24 BACKGROUND URBAN 31 32 32 31 32 32 30 31 31 27 28 28 BACKGROUND URBAN 25 26 26 25 26 26 25 25 26 24 24 24 BACKGROUND URBAN 27 28 28 27 28 28 26 27 27 23 24 24 BACKGROUND URBAN 13 14 14 13 14 14 12 13 13 10 11 11 TRAFFIC URBAN 20 20 20 20 20 20 19 20 20 18 18 18 BACKGROUND URBAN 5 6 6 5 6 6 5 5 5 3 3 4 BACKGROUND URBAN 20 21 21 20 21 21 19 20 20 17 17 18 TRAFFIC URBAN 7 7 7 7 7 7 7 7 7 6 6 6 TRAFFIC URBAN 7 7 7 7 7 7 6 6 7 5 5 6 Table 9 - City of Milan: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Area 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND URBAN 65 60 59 65 60 58 61 57 56 50 45 44 BACKGROUND URBAN 29 25 24 29 25 23 26 23 22 18 15 13 BACKGROUND URBAN 28 24 23 28 24 23 25 22 21 18 14 13 22
Table 10 - City of Paris: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Location 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND URBAN 10 9 8 10 9 8 10 9 8 8 7 7 BACKGROUND SUBURBAN 6 5 5 6 5 5 6 5 5 5 4 3 BACKGROUND URBAN 13 13 13 13 13 13 12 13 13 12 12 12 BACKGROUND URBAN 5 4 4 5 4 4 5 4 3 4 3 2 BACKGROUND URBAN 12 12 13 12 12 13 12 12 12 11 11 11 BACKGROUND URBAN 13 14 14 13 14 15 13 13 14 11 12 12 BACKGROUND URBAN 3 4 4 3 4 4 3 3 4 1 2 2 BACKGROUND URBAN 3 4 4 3 4 4 2 3 4 1 2 2 BACKGROUND URBAN 2 2 3 2 2 3 1 2 2 0 0 1 Table 11 - City of Rome: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Location 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND URBAN 22 18 16 22 17 15 21 16 15 16 11 10 BACKGROUND URBAN 12 8 6 12 8 6 11 7 5 6 2 1 BACKGROUND SUBURBAN 11 7 6 11 7 5 10 6 5 5 2 0 BACKGROUND URBAN 7 4 2 7 3 2 6 2 1 2 0 0 BACKGROUND SUBURBAN 0 0 0 0 0 0 0 0 0 0 0 0 BACKGROUND URBAN 0 0 0 0 0 0 0 0 0 0 0 0 BACKGROUND URBAN 6 5 5 6 5 5 5 5 5 4 4 3 BACKGROUND URBAN 1 1 1 1 1 1 1 1 1 1 1 1 23
Table 12 - City of Stuttgart: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Area 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND URBAN 23 23 23 23 23 23 23 23 22 23 22 22 Table 13 - City of Warsaw: Ozone Exceedance Days > 25 Days (120µg/m3 threshold) Base Case and Selected Scenarios Base Case Scenario 7 Scenario 15 Scenario 16 Type Area 2025 2030 2035 2025 2030 2035 2025 2030 2035 2025 2030 2035 BACKGROUND URBAN 5 4 4 5 4 4 5 4 4 4 3 3 BACKGROUND URBAN 8 8 8 8 8 8 8 8 8 8 8 8 BACKGROUND URBAN 2 1 0 2 0 0 1 0 0 1 0 0 24
Conclusions The current AAQD requirements are based on an ozone threshold of 120µg/m3 and a maximum annual number of 25 days in exceedance of this value. By 2025, with Base Case emissions, about 87% of the urban/suburban monitoring stations in the EU achieve the non-binding limit on exceedance days. All the ‘beyond the baseline road transport scenarios’ explored in the study have very limited further impact on the Base Case situation. This is especially so for further NOX emission reductions due to the loss of the titrating effect of NO, and its involvement in reducing ozone over urban areas. In contrast to this, further action to reduce VO emissions from the ‘solvent and product use’ sector was found to have a more significant impact on compliance. This is in-line with the findings by others as discussed in the introduction of this report. At the more stringent ozone threshold in the WHO Guidelines, ozone compliance in 2025 falls to just 2 % of the urban/suburban monitoring stations in the EU. Despite this high level of ‘non-compliance’, all the ‘beyond the baseline road transport scenarios’ explored at this stage have very limited further impact on the Base Case situation. Again, in contrast to this, further action to reduce VOC emissions from the ‘solvent and product use’ sector has a more significant impact on ozone compliance. The focus on the nine selected cities clearly shows significant reductions in ozone levels in cities and especially city centres arising from the titration of ozone by the NO component of NOX emissions. This is visible from the much lower exceedance days in urban traffic stations. This is consistent with the findings in other studies and with the insights provided through source-receptor relationships derived from the EMEP model. Although ozone was modelled in the COVID scenarios considered in this study, given the strong interannual/monthly variations in concentrations it was difficult to discern the ‘ OVID’ signal from the Base Case. However, other studies have shown that during lockdown periods ozone levels have increased, particularly in city centres, due to the loss of the titrating effect of NO emissions.a The consistent finding of this study, that reducing NOX emissions increases ozone levels and ozone non-compliance in urban environments, highlights the ‘environmental tension’ between reducing NO2 levels in urban environments and the consequential increase (and potentially significant increases) in ozone related impacts. As the main study shows, NO2 non-compliance is currently confined to very limited islands of non-compliance in the EU. Given the demonstrated efficacy of the continuing impact of Euro 6/VI in further reducing these small islands of non-compliance, the study findings indicate a better strategy would be to use local measures to address these rather than further EU-wide measures. Conversely, non-compliance with EU and WHO ozone targets would suggest that reducing NMVOC emissions from the Solvents and Product Use Sector should be a high priority. However, given the nature and sources of these emissions it is likely that legislation at an EU level would be necessary to effectively target this sector and reduce concentrations of ozone. a (Lee, et al., 2020) UK surface NO2 levels dropped by 42% during the COVID-19 lockdown: impact on surface O3 25
Appendices 26
National Emissions NOX Base Case Emissions (kt/a) 2005 2010 2015 2020 2025 2030 2035 AT 213 166 139 101 75 63 59 BE 305 241 213 173 141 124 119 BG 145 118 83 79 66 55 51 HR 76 67 62 57 48 43 40 CY 21 17 13 9 7 6 5 CZ 287 219 180 146 119 101 94 DK 177 134 113 89 71 61 59 EE 35 30 30 27 23 19 19 FI 181 171 147 126 109 96 91 FR 1395 1112 937 753 578 461 409 DE 1428 1266 1064 846 681 558 536 GR 373 279 223 191 152 126 121 HU 146 121 106 82 67 56 51 IE 133 84 79 69 54 44 39 IT 1207 905 779 645 501 422 387 LV 44 39 32 30 26 23 22 LT 46 40 41 33 23 20 19 LU 30 22 16 11 7 5 5 MT 9 8 7 4 3 2 2 NL 362 291 240 193 162 142 135 PL 790 823 635 532 426 358 341 PT 247 183 153 135 112 97 90 RO 277 220 196 177 155 137 129 SK 99 79 69 61 55 50 47 SI 51 44 37 26 19 15 13 ES 1385 877 734 624 518 449 415 SE 184 147 125 101 80 68 65 GB 1537 1074 956 727 561 437 409 EU 11183 8778 7406 6047 4838 4041 3770 27
NMVOC Base Case Emissions (kt/a) 2005 2010 2015 2020 2025 2030 2035 AT 170 138 129 116 111 105 105 BE 151 128 122 119 118 114 114 BG 128 108 79 67 60 53 53 HR 101 78 71 64 59 56 56 CY 11 9 7 7 6 6 6 CZ 196 167 155 136 127 112 112 DK 112 91 78 66 62 58 58 EE 37 34 33 32 31 28 28 FI 118 100 86 74 67 63 63 FR 1217 849 731 659 617 593 593 DE 1185 1024 944 900 877 818 818 GR 263 199 168 142 135 117 117 HU 130 110 97 85 78 73 73 IE 59 47 46 45 44 41 41 IT 1165 890 811 755 700 670 670 LV 56 47 44 39 36 34 34 LT 80 66 64 60 53 47 47 LU 14 9 8 8 7 7 7 MT 4 3 3 3 3 3 3 NL 172 150 148 143 141 139 139 PL 605 549 502 457 429 403 403 PT 224 171 154 146 143 134 134 RO 394 337 268 231 208 179 179 SK 71 72 64 61 59 56 56 SI 45 40 37 35 34 31 31 ES 871 728 666 637 625 615 615 SE 206 177 160 137 131 125 125 GB 1063 785 711 681 677 673 673 EU 8846 7105 6386 5901 5637 5350 5350 28
SOMO35 and Daily Exceedances* at Stations in the Nine Cities (Base Case) * Exceedances are daily exceedances of the 120µg/m3 daily maximum of the 8-hour rolling mean as defined in the AAQD. Berlin Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND SUBURBAN 20 16 17 15 13 13 BACKGROUND URBAN 14 19 16 14 12 12 BACKGROUND URBAN 12 14 14 12 11 10 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND SUBURBAN 2205 2475 1884 1759 1668 1641 BACKGROUND URBAN 2022 1952 1708 1586 1497 1471 BACKGROUND URBAN 1879 2132 1606 1499 1422 1399 Brussels Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND SUBURBAN 16 11 13 13 13 13 BACKGROUND SUBURBAN 18 11 13 14 13 13 BACKGROUND URBAN 12 9 9 10 9 9 BACKGROUND URBAN 13 6 7 7 7 7 BACKGROUND URBAN 5 6 6 6 6 6 TRAFFIC SUBURBAN 0 0 0 0 0 0 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND SUBURBAN 1497 1510 1504 1523 1512 1505 BACKGROUND SUBURBAN 1417 1519 1425 1443 1432 1425 BACKGROUND URBAN 1063 1330 1069 1082 1074 1069 BACKGROUND URBAN 844 886 848 859 852 848 BACKGROUND URBAN 780 646 784 794 788 784 TRAFFIC SUBURBAN 532 589 535 542 538 535 29
London Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 8 9 9 9 9 9 BACKGROUND URBAN 3 4 4 4 5 5 BACKGROUND URBAN 2 2 3 3 4 4 BACKGROUND URBAN 2 0 0 0 1 1 BACKGROUND URBAN 0 0 0 0 0 0 BACKGROUND SUBURBAN 0 0 0 0 0 0 TRAFFIC URBAN 0 0 0 0 0 0 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 857 1003 1091 1225 1327 1344 BACKGROUND URBAN 783 703 915 997 1060 1069 BACKGROUND URBAN 678 556 792 863 917 925 BACKGROUND URBAN 296 311 377 423 459 464 BACKGROUND URBAN 201 154 235 256 272 274 BACKGROUND SUBURBAN 653 607 663 678 689 689 TRAFFIC URBAN 15 15 17 19 20 20 30
Madrid Daily Exceedances Type Location 2010 2015 2020 2025 2030 2035 BACKGROUND SUBURBAN 53 29 31 33 33 34 BACKGROUND SUBURBAN 46 55 36 34 33 32 BACKGROUND SUBURBAN 46 53 37 39 40 41 BACKGROUND URBAN 39 43 35 33 32 31 BACKGROUND URBAN 26 33 25 26 27 27 BACKGROUND URBAN 24 49 30 31 32 32 BACKGROUND URBAN 21 25 25 25 26 26 BACKGROUND URBAN 19 40 26 27 28 28 BACKGROUND URBAN 11 15 12 13 14 14 TRAFFIC URBAN 10 24 19 20 20 20 BACKGROUND URBAN 9 4 5 5 6 6 BACKGROUND URBAN 6 28 19 20 21 21 TRAFFIC URBAN 6 11 7 7 7 7 TRAFFIC URBAN 5 6 6 7 7 7 SOMO35 Type Location 2010 2015 2020 2025 2030 2035 BACKGROUND SUBURBAN 3049 3562 3146 3211 3247 3270 BACKGROUND SUBURBAN 3835 4606 3581 3489 3424 3396 BACKGROUND SUBURBAN 3517 3801 3628 3704 3745 3772 BACKGROUND URBAN 3598 3426 3359 3273 3211 3186 BACKGROUND URBAN 2783 2915 2871 2931 2963 2985 BACKGROUND URBAN 3016 3224 3111 3176 3211 3234 BACKGROUND URBAN 2022 2613 2086 2130 2153 2169 BACKGROUND URBAN 2809 3883 2898 2958 2991 3013 BACKGROUND URBAN 2130 2831 2198 2244 2268 2285 TRAFFIC URBAN 2401 3100 2477 2529 2556 2575 BACKGROUND URBAN 1739 2674 1794 1831 1852 1865 BACKGROUND URBAN 2478 2882 2557 2610 2639 2658 TRAFFIC URBAN 1637 2181 1689 1724 1743 1756 TRAFFIC URBAN 1447 1640 1493 1524 1541 1552 31
Milan Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 79 64 72 65 60 59 BACKGROUND URBAN 72 35 35 29 25 24 BACKGROUND URBAN 47 41 34 28 24 23 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 4658 5007 4124 3896 3748 3703 BACKGROUND URBAN 3370 2968 2938 2748 2625 2586 BACKGROUND URBAN 3344 3146 2915 2727 2605 2566 Paris Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 12 13 12 10 9 8 BACKGROUND SUBURBAN 10 16 8 6 5 5 BACKGROUND URBAN 11 12 12 13 13 13 BACKGROUND URBAN 13 8 7 5 4 4 BACKGROUND URBAN 9 14 11 12 12 13 BACKGROUND URBAN 10 8 12 13 14 14 BACKGROUND URBAN 5 5 2 3 4 4 BACKGROUND URBAN 0 5 2 3 4 4 BACKGROUND URBAN 8 0 1 2 2 3 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 1687 1709 1449 1354 1288 1264 BACKGROUND SUBURBAN 1831 1773 1573 1469 1397 1372 BACKGROUND URBAN 1391 1578 1507 1601 1660 1696 BACKGROUND URBAN 1700 1680 1461 1365 1298 1274 BACKGROUND URBAN 1289 1848 1396 1483 1538 1571 BACKGROUND URBAN 1220 1185 1322 1404 1456 1488 BACKGROUND URBAN 1076 1041 1166 1239 1284 1312 BACKGROUND URBAN 1065 1081 1153 1225 1270 1298 BACKGROUND URBAN 992 845 1075 1142 1184 1209 32
Rome Daily Exceedances Type Location 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 45 37 30 22 18 16 BACKGROUND URBAN 32 25 18 12 8 6 BACKGROUND SUBURBAN 31 24 18 11 7 6 BACKGROUND URBAN 26 23 13 7 4 2 BACKGROUND SUBURBAN 20 10 1 0 0 0 BACKGROUND URBAN 17 14 5 0 0 0 BACKGROUND URBAN 9 8 7 6 5 5 BACKGROUND URBAN 6 2 2 1 1 1 SOMO35 Type Location 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 3276 3242 2782 2543 2395 2338 BACKGROUND URBAN 2849 2609 2419 2211 2083 2033 BACKGROUND SUBURBAN 2872 3346 2438 2229 2100 2050 BACKGROUND URBAN 2660 3430 2259 2065 1945 1899 BACKGROUND SUBURBAN 3003 3535 2607 2425 2307 2264 BACKGROUND URBAN 2359 1900 2003 1831 1725 1684 BACKGROUND URBAN 1597 2258 1386 1290 1227 1204 BACKGROUND URBAN 1299 1439 1128 1049 998 979 Stuttgart Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 20 23 24 23 23 23 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 2516 2394 2052 1866 1727 1684 Warsaw Daily Exceedances Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 16 13 7 5 4 4 BACKGROUND URBAN 6 11 9 8 8 8 BACKGROUND URBAN 2 6 4 2 1 0 SOMO35 Type Area 2010 2015 2020 2025 2030 2035 BACKGROUND URBAN 1939 2007 1636 1519 1444 1422 BACKGROUND URBAN 1551 1721 1277 1170 1102 1082 BACKGROUND URBAN 1484 1347 1233 1137 1075 1057 33
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