ADD - Additives Product Guide - An IGM Group Company - ADD Additives BV
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An IGM Group Company Product Range Introduction ADD-1000 range ADD Additives BV started in 2010 and is rapidly expanding Binders for Pigment throughout Europe. ADD Additives manufactures and supplies an Concentrates Page 4 extensive range of high quality additives for industrial coatings, decorative paints, printing inks, adhesives, sealants, plastics and ADD-2000 range building materials. Foam Control Additives Page 6 All ingredients used for the production for ADD-Additives products are ADD-3000 range European sourced. The additives are Slip & Levelling manufactured at our state of the art Additives Page 10 production facility in The Netherlands. ADD-4000 range To complement the already existing additives range, ADD-Ad- High Molecular Weight ditives is investing resources into new developments. The new Dispersants Page 13 developments and the technical service inquiries are carried out by our highly skilled staff. ADD Additives creates and nourishes ADD-5000 range solid and long term successful relationships with their partners Low Molecular Weight by providing excellent customer service, customer support and Dispersants Page 16 supplying high quality materials. Our extensive portfolio has allowed us to be a partner of choice for ADD-6000 range both multinational companies and small independent companies. Modern Low Molecular We deliver what we say and actively engage in finding the optimal Dispersants Page 19 solution for your business, creating top-notch customer satisfaction and profitability. ADD-7000 range Miscellaneous Page 21 2
An IGM Group Company Binders for Pigment Concentrates Binders for Resin Minimal Pigment Concentrates The RMPC concept improves the manufacture of pigmented coatings or paints through the use of a highly pigmented, low resin content pigment concentrates. The concentrates can be formulated to be compatible with the majority of resins used to manufacture industrial coatings, while meeting the specific requirements of paint end-users. Resin Minimal Pigment Concentrates (RMPC) based on ADD binders and high molecular weight dispersants off er the following advantages over conventional pigment concentrates: 1. Consistent colour development / no flocculation 2. Considerably lower resin content 3. Significantly lower viscosity This leads to the following benefits: ► No flooding or floating ► Minimal effect on the quality of the finished product ► Application in a very wide range of different systems and solvents due to excellent compatibility of the pigment concentrates ADD-1000 range 3
An IGM Group Company ADD-1000 range Binders for Pigment Concentrates Binders Active Product Incorpo- Solvent Water- Description / Application Content UV name ration borne borne in % Fatty acid modified polymer, ADD-1501 crosslinkable with amino or polyiso- Before 100 • • cyanate resins Fatty acid modified polymer, VOC ADD-1502 Before 95 • free 4
An IGM Group Company Foam Control Additives Foam During the production and application of paint systems, foam is an undesired side-effect of mixing. It is usually slowing production and making it difficult to fill vessels with the correct amount of paint. In addition it can cause surface defects such as craters and weak points in the dried film. Stable dispersion of gas bubbles in a liquid medium The most general definition of foam is a substance that is formed by trapping many gas bubbles in a liquid or solid. A foam is normally an extremely complex system consisting of poly disperse gas bubbles separated by draining films. In other words foam can be described as a stable dispersion of gas bubbles in a liquid medium. In pure liquids, foam is not stable. Foam is only stable in systems containing surfactants. 5
An IGM Group Company ADD-200 Range Foam Control Additives Silicone-free foam control additives Product Incorpora- Dosage Solvent Water- Description / Application UV name tion in % borne borne Acid-cure and NC-curtain coating Before or after ADD-2020 systems, unsaturated polyester 0.1-0.7 • • processing and gelcoats Polyurethane, acid-cure and End of process- ADD-2021 0.5-2.0 • • stoving enamels ing Mineral oil-based high perfor- Before and/or ADD-2504 mance defoamer for aqueous 0.1-0.5 • after processing formulations Vegetable oil-based high perfor- Before and/or ADD-2508 mance defoamer for aqueous 0.1-1.0 • after processing formulations High performance liquid defoamer Before and/or ADD-2523 0.1-0.5 • for aqueous formulations after processing Defoamer for various water-based Before and/or ADD-2526 coating and water based ink 0.1-1.0 • after processing systems Very effective silicone free, high performance defoamer for water- Before and/or ADD-2540 0.5-1.0 • based ink & coatings, partly based after processing on vegetable oils Very effective silicone free high Before and/or ADD-2548 performance defoamer for water- 0.5-1.0 • after processing based ink & coatings Unsaturated polyester, epoxy and Before or after ADD-2720 0.1-1.0 • • polyurethane systems processing Unsaturated polyester, epoxy and Before or after ADD-2724 0.1-1.5 • polyurethane systems processing * Dosages: % on total formulation 6
An IGM Group Company Silicone-containing foam control additives Product Incorpora- Dosage Solvent Water- Description / Application UV name tion in % borne borne Polyurethane curtain coatings and Before or after ADD-2022 0.1-1.0 • stoving enamels processing Physically drying systems and air Before or after ADD-2025 0.1-1.0 • drying alkyds processing Physically drying systems and air Before or after ADD-2026 0.1-1.0 • drying alkyds and especially for ink processing Air-drying systems based on acrylic, vinyl or chlorinated polymers; and Final produc- ADD-2035 fast-drying industrial, decorative and 0.5-1.0 • tion decorative finishes based on medium- to long-oil alkyd resins Solvent borne industrial and decorative Final produc- ADD-2041 finishes, including roller, brush and 0.1-0.7 • tion airless spray applications For solvent borne and radiation curing Before pro- ADD-2286 coatings, inks and varnishes. Ideal for 0.05-0.6 • • cessing high speed rotation screen printing inks Waterborne coatings and pigment Before or after ADD-2524 0.1-1.0 • concentrates processing Highly compatible silicone based high Before pro- ADD-2525 performance defoamer for water-based 0.1-1.0 • cessing pigment concentrates. VOC-free clear silicone-based defoamer which is particularly designed Before or after ADD-2560 0.1-0.5 • for water- and glycol-based pigment processing concentrates and universal colorants VOC-free silicone-based defoamer for water-based coatings, printing inks, Before or after ADD-2561 overprint varnishes and emulsion 0.05-0.8 • processing adhesives. Suitable for pigment con- centrates VOC-free all-purpose defoamer that is easy to incorporate in all kinds of Before or after ADD-2563 water-based coatings, printing inks, 0.2-1.0 • processing overprint varnishes and emulsion adhesives VOC-free clear defoamer that is easy to incorporate in all kinds of water- Before or after ADD-2564 based coatings, printing inks, overprint 0.1-1.0 • processing varnishes and emulsion adhesives. Suitable for pigment concentrates VOC-free clear defoamer that is easy to incorporate in all kinds of water- Before or after ADD-2568 0.1-1.0 • based coatings, printing inks, overprint processing varnishes and emulsion adhesives 7
An IGM Group Company Product Incorpora- Dosage Solvent Water- Description / Application UV name tion in % borne borne Defoaming substances in acrylate ADD-2721 Any stage 0.5-1.0 • monomers for radiation curing systems Before addi- Solvent-free epoxy and polyurethane ADD-2722 tion of pig- 0.5-1.5 • systems ments/fillers Solvent-free epoxy and polyurethane Prior to pro- ADD-2723 0.5-1.5 • systems, low odour cessing 2 Component polyurethane and epoxy Prior to pro- ADD-2730 0.5-1.5 • systems cessing * Dosages: % on total formulation 8
An IGM Group Company Slip & Levelling Additives The surface of coating Although the coating might be for different purposes; protective, decorative or both, it is the eye-catcher for its users and consumers. It is exposed to “the world” and has not only to withstand some severe circumstances like weathering, but is responsible for the appearance of the coating, colour, brightness, gloss and the “touch”. It all starts at the surface. In most cases, superior surface properties cannot be achieved without the addition of slip & levelling additives which alter the surface properties of the coating. Polysiloxanes have a very high surface activity and therefore are often used as surface control additives. Silicone-based surface control additives are modified by polyethers, polyesters or alkyl side groups to improve recoatability and inter-coat adhesion. Modification parameters are silicone content, molecular weight, and modification degree. Polyacrylates, homo- and copolymers based on (meth)acrylic monomers are well known surface control additives. In addition to their positive impact on flow and levelling, acrylic homo- and co-pol- ymers are effective as air-release agents. Since they are not reducing the surface tension of the coating to the extent of silicone-based products, the wetting of substrate surfaces is improved (substrate wetting). 9
An IGM Group Company ADD-3000 range Slip & Levelling Additives Silicone-free slip & levelling additives Active Product Description / Incorpo- Dosage Solvent Water- content UV name Application ration in % * borne borne % Wetting, levelling and flow End of ADD-3260 control agent with excellent 0.05-1.0 100 • • process anti-cratering properties Paraffin wax emulsion for anti-blocking, scratch and End of ADD-3506 0.05-1.0 40 • burnish resistance for inks and process coatings Anionic substrate wetting End of ADD-3572 0.1-0.5 70 • agent process After or Excellent substrate wetting, prior to ADD-3575 0.5-1.5 55 • levelling and anti-cratering process- ing Solvent borne or solvent free End of ADD-3772 systems, coil coatings, OEM 0.5-2.0 60 • • process and industrial coatings End of ADD-3777 Strong anti-cratering 0.5-1.0 70 • process Polyethylene wax for Depend- ADD-3906 anti-blocking and scratch ing on 0.5-2.0 100 • • resistance system * Dosages: % on total formulation 10
An IGM Group Company Silicone-containing slip & levelling additives Active Product Description / Incorpora- Dosage Solvent Water- Content UV name Application tion in % * borne borne in % Improve slip and mar ADD-3030 Any stage 0.1-1.0 52 • • resistance, very compatible Solvent borne metal, wood ADD-3031 and paper coatings, includ- Any stage 0.1-1.0 52 • ing UV cured Improve surface flow, ADD-3033 excellent compatibility in Any stage 0.1-1.0 15 • clear coat Strong substrate wetting End of ADD-3034 0.05-0.5 52 • • and cratering process Solvent- and water borne stoving enamels, unsatu- End of ADD-3035 0.5-1.0 52 • • rated PE including UV process cured ADD-3230 100% version of ADD-3030 Any stage 0.05-0.5 100 • • • End of ADD-3235 100% version of ADD-3035 0.25-0.5 100 • • • process Solvent borne wood fin- ADD-3236 ishes, industrial coatings After thinning 0.02-0.3 100 • • and solvents-free coatings Similar to ADD-3236, but ADD-3239 stronger defoaming prop- After thinning 0.05-0.3 100 • • erties Premium additive that increases slip, surface ADD-3290 Any stage 0.05-0.5 100 • • • smoothness and “soft- touch” effect Anti-cratering and leve- After or prior ADD-3580 ling agent for waterborne 0.1-1.0 100 • to processing coatings Leveling agent for water- ADD-3581 borne coatings with Any stage 0.2-1.0 100 • impregnating properties After or prior ADD-3585 Solution of ADD-3580 0.2-2.0 52 • to processing * Dosages: % on total formulation 11
An IGM Group Company Dispersing Additives Pigment stabilization by steric hindrance When dispersing pigments, in particular organic pigments, one often encounters problems such as flocculation, insufficient colour or transparency, poor rheological behaviour or bad stability. These issues arise along every step of the coatings life cycle from production and storage through to the end-use performance of the film. The dispersing of solid pigments or fillers into the liquid phase of binder solutions is an important step in paint and coatings production influencing optical properties like gloss and colour strength. Dispersion control additives are used to improve and accelerate the dispersion process and to stabilize the dispersion during storage. High molecular weight wetting and dispersing agents Are built of linear or branched polyacrylate or polyurethane structures with a molecular weight between 5,000 g/mol - 30,000 g/mol and have special groups which have high affinity towards specific sites on the pigment surface. These are called anchoring groups, and are built in at strategic points on the polymer backbone. Mode of action Anchoring groups enable strong interaction between the dispersion control additive and the pigment surface. This interaction is much stronger compared to the anchoring mechanism of the conventional low molecular weight types. Because these dispersion control additives have multiple adsorptions points, they are therefore connected to numerous sites on the surface of the pigment particles. The remaining parts of the dispersion control additive act as a steric barrier to the surroundings by stretching into the liquid phase and assuring an effective steric hindrance preventing flocculation. 12
An IGM Group Company ADD-4000 range High Molecular Weight Dispersants High molecular weight dispersants based on Block co-polymer Waterbone inorganics % of DBP Organics Product % of OA Content Solvent Description / Application Blacks Active name borne % of in % BET UV Particularly recommended for carbon black pigments. Ideal for ADD-4276* pigment concentrates for polyols -- -- -- 100 • and PVC plastisols and color mas- terbatches for thermoplastics Aqueous coating systems, printing ADD-4519 inks and adhesives. Ideal for res- 8-12 30-50 50-60 40 • in-free pigment concentrates * Recommended addition levels (based upon pigment weight): 15-50% for carbon blacks, 10-25% for organic pigments and 5-10% for inorganic pigments High Molecular weight dispersants based on Polyurethane Chemistry Content in % Organics % Waterbone inorganics % of DBP Product % of OA Description / Application Solvent name Blacks Active borne BET UV of General-use industrial coatings ADD-4009 where cost effective performance 10 30-50 15-25 60 • is vital General-use industrial coatings ADD-4010 including coil coatings and decora- 5-10 20-40 25-30 50 • tive finishes ADD-4046 General-use industrial coatings 10 30-50 15-25 40 • High quality industrial finishes ADD-4047 including automotive OEM and 10 30-50 15-25 35 • • refinish Solvent-based coatings, including automotive topcoats and high-qual- ADD-4063 ity industrial coatings. Ideal for 10 25-50 20-30 45 • pigment concentrates for high-end applications requiring durability High quality industrial finishes including automotive OEM, refinish, ADD-4100 10 30-50 15-25 50 • as well as universal solvent-based colorants 13
An IGM Group Company Content in % Organics % Waterbone inorganics % of DBP Product % of OA Description / Application Solvent name Blacks Active borne BET UV of Particularly suitable for the man- ufacture of APE-free and sol- ADD-4685 vent-free universal colorants used 10 30-50 25-30 52 • • in aqueous, solvent-based and solvent-free coatings * Recommended addition levels (based upon pigment weight): 15-50% for carbon blacks, 10-25% for organic pigments and 5-10% for inorganic pigments High molecular weight dispersants based on polyacrylates Solvent borne Content in % Organics % Waterbone inorganics Product % of DBP Description / Application % of OA name Blacks Active BET UV of High quality industrial coatings ADD-4401 10 30-50 15-25 50 • • including transportation coatings High quality industrial coatings, ADD-4430 especially RMPC’s including NC 10 30-50 20-30 50 • lacquers High molecular weight dispersants based on polyacrylates OA: Oil absortion value BET: Surface area value DBP: Dibutyl Phtalate absorption value 14
An IGM Group Company Dispersing Additives Pigment stabilization by controlled flocculation The dispersing of solid pigments or fillers into the liquid phase of binder solutions is an important step in paint and coatings production influencing optical properties like gloss and colour strength. Dispersion control additives are used to improve and accelerate the dispersion process and to stabilize the dispersion during storage. Low molecular weight wetting and dispersing agents are categorized according to their chemical structure and the nature of their hydrophilic groups (amphoteric, cationic, … etc). The molecular weight is between 800 and approximately 2000 g/ mol which is too low to give enough steric hindrance for stabilization of organic and carbon black pigments The interaction of their polar groups with the pigment surface and the behaviour of the non-polar chains in the medium determine their effectiveness. Mode of action The polar heads will form hydrogen bonding interactions between different pigment units resulting in a network that enhances the separation of the particles (controlled floccu- lation). Inorganic pigments are usually metal oxides which contain positive metal ions and negative oxide ions. These ions are good anchoring points on which the anchoring groups of the dispersion control additive can attach to (polar interactions). 15
An IGM Group Company ADD-5000 range Low Molecular Weight Dispersants Low Molecular Weight Dispersants Solvent borne Inorganics Organics Bentonite Content in % Waterbone Product Description / name Application % Dosage based on Active Pigment/Bentonite UV Cost effective dispersant ADD-5001 based on fatty acids for 0.5-2.0 30-50 30 • • primers and under-coats Solvent borne architectural ADD-5002 4.0-7.0 3.0-7.0 70 • and decorative paints Solvent borne industrial ADD-5005 0.2-2.0 2.0-5.0 52 • and marine coatings All types of industrial coat- ADD-5010 ings, especially for inor- 1.0-10.0 - - 50 • ganic pigments Solvent borne or sol- ADD-5044 vent-free coating systems. 0.2-2.0 2.0-5.0 30-50 52 • Also for bentonite gels Non-polar to medium-polar ADD-5054 coating systems. Also for 0.2-2.0 2.0-5.0 30-50 52 • bentonite gels Polyurethane systems and stoving enamels. Also for ADD-5065 0.5-2.5 - - 52 • orientation of aluminium pigments Polyurethane systems and ADD-5066 stoving enamels. Strong 0.5-2.5 - - 52 • anti-settling effect Water and solvent borne ADD-5071 systems. Strong anti-set- 0.5-2.0 2.5-5.0 - 52 • • tling effects Similar to ADD-5065, but ADD-5165 with different solvents com- 0.5-2.5 - - 52 • bination Similar to ADD-5066, but ADD-5166 with different solvents com- 0.5-2.5 - - 52 • bination 16
An IGM Group Company Solvent borne Inorganics Organics Bentonite Content in % Waterbone Product Description / name Application % Dosage based on Active Pigment/Bentonite UV Solvent borne architectural ADD-5207 0.5-5.0 2.0-5.0 - 100 • • and decorative paints Solvent borne, solventless coatings and printing inks. ADD-5217 0.5-5.0 - - 100 • • Excellent for Titanium Dioxide and extenders Solvent-free version of ADD-5244 0.1-1.0 1.0-2.5 15-25 100 • • ADD-5044 Solvent borne or sol- vent-free coating systems. ADD-5844 0.1-1.5 1.0-3.0 20-30 80 • Ideal for dispersing extend- ers in thermosetting resins 17
An IGM Group Company Dispersing Additives Pigment stabilization by hybrid dispersants Hybrid dispersant are modern low molecular weight dispersants. They contain anchoring mecha- nisms similar as in high molecular weight dispersants but have significant lower molecular weights varying between 1000 – 5000 g/mol. Due to the anchoring groups, multi adsorption is possible and therefore anchoring on organic- & carbon black pigments can be achieved. Compared to conven- tional low molecular weight dispersants the molecular weight of these hybrid dispersants are usually much higher which ensures more improved steric hindrance. The active substance of hybrid dispersant is typically 100%. Because high molecular weight disper- sants are usually having 30 – 60% activity, hybrid dispersants are very cost effective to use. Unlike conventional low molecular weight dispersants, hybrid dispersants can be used for inorganic-, organic- and carbon black pigments. Example of a hybrid dispersant polymer with ‘triple tail’ technology. 18
An IGM Group Company ADD-6000 range Modern Low Molecular Weight Dispersants Inorganics Organics Bentonite Solvent borne Content in % Waterbone Product Description / name Application % Dosage based Active on Pigment/Bentonite UV Acidic polyether, disper- sant for solvent-based and ADD-6211 solvent-free coatings and 0.5-2.0 - - 100 • composite, is particularly suitable for car putties Acidic polyether, disper- sant for solvent-based and ADD-6212 5-10 - - 100 • • solvent-free coatings and composite Fatty acid dispersant for PVC plastisol’s, solvent ADD-6213 5-10 10-30 15-25 100 • based and solvent free coatings Anionic wetting agent to improve compatibility and color acceptance of all ADD-6215 3-10 10-20 15-25 100 • • kinds of tinting pastes in both solvent and water- based systems, VOC-Free Hybrid dispersant to improve compatibility and ADD-6220 5-10 10-20 15-25 100 • • color acceptance of univer- sal colorants in base paints Hybrid dispersant for uni- ADD-6225 versal colorants for tinting 5-10 10-20 15-25 100 • • systems Hybrid dispersant for oil and solvent- based ADD-6228 systems and colorants. 5-10 10-20 100 • Also for heatset and offset inks Aliphatic polyether with ADD-6230 1-3 - - 100 • • • acidic groups Aliphatic polyether with ADD-6231 acidic groups especially for 1-3 - - 100 • • • PVC plastisol purposes 19
An IGM Group Company Inorganics Organics Bentonite Solvent borne Content in % Waterbone Product Description / name Application % Dosage based Active on Pigment/Bentonite UV Hybrid dispersant for uni- versal colorants for tinting ADD-6245 systems, VOC- free and 5-10 10-20 15-25 100 • • • low viscosity pumpable dispersant Hybrid dispersant stabiliz- ing all kind of pigment and ADD-6525 extenders in waterborne 10-20 20-40 - 50 • coatings, especially in dec- orative coatings Triple tail technology dis- persant to improve stability of tinting pastes as well ADD-6540 0.5-2.0 2.5-5.0 - 62 • as dispersant for organic, inorganic and pearlescent pigments Fatty acid modified polyes- ADD-6622 7-14 14-28 - 70 • • ter in di-basic ester Incorporation: In the mill base before adding the pigments 20
An IGM Group Company ADD-7000 range Miscellaneous Active Product Dosage Solvent Water- Description / Application Content UV name % borne bone in % Anti-setting rheology control additive for ADD-7101 0.5-5.0 50 • solvent based systems Alkali- swellable acrylic thickener for Newto- ADD-7112 0.3-1.5 40 • nian rheological behaviour ADD-7200 Solvent and halogen free conductivity agent 0.2-2.0 100 • • Reactive UV Absorber for air drying coat- ADD-7725 0.5-3.0 100 • ings Combination of a reactive UV Absorber with ADD-7730 0.5-3.0 100 • HALS for air drying coatings Solution of an ammonium salt of an acrylic ADD-A40* 0.5-2.0 45 • polymer in water Solution of a sodium salt of an acrylic ADD-N40* 0.5-2.0 45 • polymer in water * Recommended addition levels are based upon pigment weight 21
ADD-Additives global brochure V1.2 - 01/2021 DISCLAIMER The information and recommendations provided Contact information in this product catalogue are presented in good faith and believed to be correct. ADD-Additives makes no representations or warranties as to To find your distributor, please contact: the completeness or accuracy of the information provided. The information is provided on the condition ADD Additives BV that the persons receiving it will make their own Daltonstraat 42 assessment as to its suitability for their own 3846 BX Harderwijk purpose and use. The Netherlands No representations or warranties, either express Tel. +31 (0)88 070 17 00 or implied, of fitness for purpose or of any other nature are made herein with respect to information or product to which the information info@add-additives.com refers. www.add-additives.com An IGM Group Company
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