RPM and TSF New processes to manufacture thermoset composite parts - In cooperation with
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Partner LZS and NEM • Polish Start-Up of the Uni Stettin • German development supplier for • Innovative thermoset systems light weight technology • Inventors of new thermoset resin • International costumer network system A.S.SET • Process-know-how Work share Development/Sale Development of A.S.SET-process innovative thermoset technologies (RPM, TSF) systems (A.S.SET) In cooperation with 2
A.S.SET Technology Adjustable Simple Thermoset • Epoxy Resins with thermoplastic processing properties • Multiple melting/softening, fast curing • Storage at room temperature First Presentation • Producible with various Epoxy Resins Hanover trade fair • Modifiable (e.g. fire prevention, temperature resistance) 2014 In cooperation with 3
Characteristics A.S.SET Material Temperature Temperature 120°C 120°C 60°C 60°C 60°C 60°C RT Viskosity Viskosity (Powder) solid solid liquid liquid Curing Curing Time Time In cooperation with 4
Resin Powder Moulding ‐ RPM Powder application • Spray gun / Sieve / conveyor belt • No mixing of Resin • No cooling chain Pressing • Classic press/ membrane • Short cycle times • Low process pressures Comparable to preform‐ and binder process! In cooperation with 5
Process impressions ‐ RPM Video RPM (http://www.youtube.com/watch?v=YxUeRvvmN1g) In cooperation with 6
Fixation of A.S.SET Powder Fabric on a heating plate Applying A.S.SET Powder Fixating the Powder (30 sec at 70°C) CFRP-ply with fixated A.S.SET-Powder In cooperation with 8
Thermoset Sheet Forming ‐ TSF Pre-heating • To handle like thermoplastic organic sheets • Heating field or oven Pressing • Classic press/ membrane-press • Pressing without vacuum • Short cycle times • No variothermal process • Low process pressures Processing analogue to thermoplastic organic sheets! In cooperation with 9
Process impressions ‐ TSF Video TSF http://www.youtube.com/watch?v=MLXWBX4E_DA In cooperation with 10
Advantages of RPM and TSF • Simple process technology • Short cycle times + • Multiple forming possible + RPM (before final curing) TSF • Large Resin variety • Excellent surface finish • Very good fire prevention • Simple Handling • Demoulding out of the hot mould In cooperation with 11
Material Properties Decomposition Resin Curing cycle Tg max. temperature 5 min at 140°C A.S.SET 125°C 350°C + 15 min at 140°C RTM6 2 h 180°C 196°C 290°C 4 h at 80°C LY 556 155°C 310°C + 8 h at 160°C L‐Harz 15 h at 100°C 90°C 320°C Glass Thermal transition degradation In cooperation with 12
Example Panel Material A.S.SET-Powder / CF fabric Process RPM Parameters 130° (constant), no vacuum, 1.8 bar pressure Cycle time 8 minutes pressing time, 10 minutes tempering In cooperation with 13
Mechanical Analysis a) b) c) a) Ultra sonic scan, b) Microscopy, c) Computer tomography Static tensile test CF-A.S.SET-Fabric • Small pore content, even without Vf ~ 60% vacuum Load direction 0° Stress [Mpa] • Fibre volume content at approx. 60 vol.% • Strength in and perpendicular to fibre direction comparable to common CF- ER-laminates Strain [%] In cooperation with 14
Example Panels [Wood-CF]S [Decor layer-Wood-GF]S [Wood-GF]S [Wood-BF]S [GF-Balsa-CF]S [Hemp-Balsa-CF]S In cooperation with 15
Example CFRP‐Frame Material A.S.SET-Powder / Aviation Fabric resp. Non-crimp Fabric Process RPM with autoclave or vacuum bag without autoclave Parameters 60°C pre-heating, 120°C autoclave, 3 bar for 15 min Tempering 20 min at 140°C outside the mould Properties Probably passes Airbus fire prevention standard In cooperation with 16
Frame‐Manufacturing impressions No Bridging No resin rich areas! In Kooperation mit 17
Process comparison – Example Frame Process times Cutting Laminating Bagging Curing Tempering Conventional Frame manufacturing with Prepreg Frame manufacturing with A.S.SET-Powder Additional advantages Challenges • Cost‐effective Preform • Automated Powder application • No cooling chain • Slipping of Layers • Better fire prevention • No pores • No resin richness In cooperation with 18
Example Sandwich‐Seat Material A.S.SET-Sheets / GF-Fabric Process TSF with membrane press Parameters 120° (constant), no vacuum Cycle time 8 minutes pressing time, 15 minutes tempering Properties Passes fire prevention standards of railway industries In Kooperation mit 19
Example Repairing NASA Damaged Part A.S.SET-Sheet-Patch Repairing Repaired Part Material A.S.SET-Sheets Process „Ironing Process“ Parameters 140°C (constant), no vacuum Cycle time 10 Minuten „ironing“, optimization possible In cooperation with 20
Chance: Repairing wind turbines Boats and cars wind-energie.de boot-service.at Today: Repairing trough wet laminating Future: Repairing with A.S.SET Sheets? • Dirty work, at max. 80 days a year possible • Clean • Long curing times • Repaired structure loadable after few • Low fibre volume content minutes • High quality of the patches In cooperation with 21
Prospect • Further development of RPM and TSF • Data sheets available for selected reinforcement materials • Starting Series production of A.S.SET • Starting Series production of the railway-seat • Developing A.S.SET-Parts together with industrial partners In cooperation with 22
Thank you for your attention! In cooperation with 23
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