Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
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materials Article Repair of a Cracked Historic Maryan Bell by Gas Welding Dariusz Bartocha and Czesław Baron * Department of Foundry, Silesian University of Technology, 7 Towarowa St., 44-100 Gliwice, Poland; dariusz.bartocha@polsl.pl * Correspondence: czeslaw.baron@polsl.pl Abstract: In this article, the range of works connected with the repair of a historical Maryan bell from 1639 are presented. The first attempts to repair damaged bells occurred in the 1930s in Poland. How- ever, this process was stopped because of extensive technological difficulties. Welding and soldering- welding were the basic methods. There is one difference between these two methods—connecting surfaces are melted during the welding process but only heated until the melting temperature of the material added to the connection (that is the solder) during the soldering-welding process. It was important to heat the bell to the proper temperature during welding. Uneven heating causes the enlargement of existing cracks or the appearance of new ones, or even the complete destruction of the bell. Nowadays, a method of even heating using a special heating mat has been devised. Thanks to this method it is possible to control the heating and cooling process. The most important task during the whole operation of bell welding was obtaining the original sound. During this research, the chemical composition was examined to prepare a welding rod with a suitable chemical composition. After the repair process, an analysis of the sound of the bell was conducted. It was shown that the repair of bells is possible when correct thermal parameters are used. The most highly recommended technique for repairing bells is gas welding. Keywords: high-tin bronzes; microstructure; welding of bell; bell’s sound Citation: Bartocha, D.; Baron, C. Repair of a Cracked Historic Maryan Bell by Gas Welding. Materials 2021, 14, 2504. https://doi.org/10.3390/ 1. Introduction ma14102504 There are a lot of churches with very old, historical bells in Poland, as it has historically been a Catholic country. Unfortunately, their strength is decreasing and cracks and scratches Academic Editor: Sergei Yu Tarasov are have appeared. These defects make them useless, because not only does the sound become worse, but reacting to the damage too late can cause the complete destruction of Received: 2 April 2021 the bell as well. Accepted: 9 May 2021 Published: 12 May 2021 The lifetime of the bell was determined to be 200–300 years [1] on the basis of data in the literature. After that time the probability of the bell cracking is increased. Of course, Publisher’s Note: MDPI stays neutral it depends on many factors, such as the frequency of bell work and the bell’s rotation on with regard to jurisdictional claims in its suspension. Unless the bell is rotated, the clapper hits the same place and it may cause published maps and institutional affil- cracks. It is important to control the thickness of that place. If the thickness falls more than iations. 10%, it is necessary to rotate the bell to allow it to hit another place. Constant hits on the same place also causes changes to the inner structure of the material. It becomes harder and loses strength properties. Concurrently, inner stresses increase. When stresses exceed the material strength limit, the bell will be damaged, and cracks and scratches will appear. It is hard to notice such a crack on a bell placed high in a tower, but it is possible to hear Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland. the change in the sound, which is usually much worse than the original sound. This article is an open access article The repair of the bell is possible up to its complete destruction. Repairing the bell is distributed under the terms and an expensive and time-consuming process. However, attempts to repair these bells are not conditions of the Creative Commons rare, because the bell is a precious item not only thanks to its material value but also its Attribution (CC BY) license (https:// historical and artistic value as well. Despite the avoidance of the repair of cracked bells in creativecommons.org/licenses/by/ Poland for a long time, this problem has been considered in many other countries [2,3]. 4.0/). Materials 2021, 14, 2504. https://doi.org/10.3390/ma14102504 https://www.mdpi.com/journal/materials
Materials 2021, 14, x FOR PEER REVIEW 2 of 10 Materials 2021, 14, 2504 2 of 10 It is necessary to examine the chemical composition of the alloy used to produce the It is bell to necessary repair the crack. to examine thebells The oldest chemical are madecomposition of gunmetal,of the alloy while theused to produce younger are made the bell to repair of bronze. the crack. Copper at a The oldest bellsofare concentration made about 80%of and gunmetal, tin with while the younger between a concentration are made of bronze. Copper at a concentration of about 80% and 19% and 21% are the main components in both alloys. Gunmetal also contains zinc,tin with a concentration between lead, 19% and 21% are the main components in both alloys. Gunmetal carbon, and iron. Trace amounts of silver and gold are also possible to observe in both also contains zinc, lead, carbon, and iron. Trace amounts of silver and gold are also possible alloys because of the tradition to add these elements into the liquid metal to ennoble the to observe in both alloys material because [4–6]. of the tradition to add these elements into the liquid metal to ennoble the material [4–6]. The melting temperature of bronze is about 850–950 °C. The alloys with high tin con- ◦ C. The alloys with high tin tent The melting temperature are characterized by great of bronzebut strength, is about 850–950low concurrently toughness—they are very content are characterized brittle (Figure 1). This, in by great strength, combination withbuthigh concurrently low toughness—they thermal expansion and high diversityare very of brittle (Figure 1). This, in combination with high thermal expansion the microstructure component properties, has a negative influence on weldability. It is and high diversity of the microstructure proper to heat the whole component bell at theproperties, adequatehas a negative speed influence until it reaches theontemperature weldability.ofIt is350–450 proper°C, to heat before welding. This allows differences in temperature between the weldedof the whole bell at the adequate speed until it reaches the temperature 350–450 ◦ C, before welding. This allows differences in temperature between the welded place and the rest of the bell which are too large to be avoided. What’s more, it is also place and the important restitofslowly to cool the bell andwhich evenly are toospeed (the largeoftothe becooling avoided. What’s process more, should beitslower is also important to cool it slowly and evenly (the speed of the cooling process than heating). This is connected with the risk of inducing residual heat as a result of dif- should be slower than heating). ferences This is rates in the cooling connected with parts of different the risk of structure of the inducing(Figure residual heat 2a,b as adifferent shows result of differences phases accordingin the cooling rates ofcooling to different different partsIfofthe rates). the bell structure (Figure had not been2a,b showsonly heated, different the phases welded part would have shrunk and new cracks would have appeared. On thewelded according to different cooling rates). If the bell had not been heated, only the other part hand,would have process a cooling shrunk and new which iscracks too fast would have appeared. may cause new stresses,On the withother newhand, cracksa cooling as the process result. which is too fast may cause new stresses, with new cracks as the result. Figure Figure 1. Theinfluence 1. The influenceofoftin tinonon chosen chosen mechanical mechanical properties, properties, the the tin bronze tin bronze hardness hardness change change dependent on tin dependent tin concentration. concentration.(E—elongation, UTS—ultimate (E—elongation, UTS—ultimate tensile strength, tensile BHN—Brinell strength, BHN—Brinell hardness number, hardness number,KV—impact KV—impact strength, strength, YS—yield YS—yield strength) [7].
Materials 2021, 14, Materials 2021, 14, 2504 x FOR PEER REVIEW 33 of of 10 10 2. (a) Phase Figure 2. Phase diagram diagram Cu-Sn, Cu-Sn, (b) (b) Metastable Metastable phases phases Cu-Sn; Cu-Sn; dashed dashed line—casting line—casting solidified in sandy mold, dotted line—casting solidified solidified in in aa metal metal mold mold [8,9]. [8,9]. 2. Historical Historical Background In Poland, In Poland,the the first first attempts attempts to repair to repair damaged damaged bells bells were were observed observed in the 1930s.in the 1930s. Welding Welding and soldering-welding were the base methods. There and soldering-welding were the base methods. There is one difference between these two is one difference between these two methods: methods: connecting connecting surfaces aresurfaces melted areduring melted welding during welding processprocess and only andheated only heated until untilmelting the the melting temperature temperature of the of the material material added added to to the the connection(that connection (thatisissolder) solder) during the soldering-welding process. Additionally, a welding rod with a chemical composition similar to similar to indigenous indigenous metal metal was was used used during during welding welding process, process, whilst whilst sticks sticks made made of of brass brass alloy (known as bronzite) were used for soldering-welding. alloy (known as bronzite) were used for soldering-welding. First, it First, it was wasdesirable desirabletotoestimate estimate thethesize of the size crack. of the A simple crack. A simplepenetration penetrationstudy was study conducted with the use of chalk and kerosene. Chalk was rubbed was conducted with the use of chalk and kerosene. Chalk was rubbed into the inner side into the inner side of the bellthe of and theand bell external side was the external lubricated side with kerosene. was lubricated The greasy with kerosene. Thespot greasywasspotusedwas to show used the range of the crack. After estimating the size of the damage, the to show the range of the crack. After estimating the size of the damage, the place of repairplace of repair should be properly should prepared. be properly In bothIn prepared. cases, boththe method cases, of action the method of was actionsimilar. A groove was similar. with a A groove v–shape was cut along the crack and metal was poured in. In with a v–shape was cut along the crack and metal was poured in. In this procedure this procedure the hole at the the end of the crack must be remembered. Its task was to limit the increase hole at the end of the crack must be remembered. Its task was to limit the increase of the of the crack during bell heating. crack duringAn bellacetylene heating. torch was usedtorch An acetylene as the welding was used as tooltheinwelding both methods. tool in Uniformity both meth- of the weld obtained was the main difference between welding ods. Uniformity of the weld obtained was the main difference between welding and the and the soldering-welding process. The weld had nearly the same chemical composition as welded material during soldering-welding process. The weld had nearly the same chemical composition as the welding process. The weld had different chemical composition to the repaired bell welded material during the welding process. The weld had different chemical composi- during the soldering-welding process, which caused worse sound. tion to the repaired bell during the soldering-welding process, which caused worse sound. The position heated by charcoal (in the past it was often used as a fuel) was used The position heated by charcoal (in the past it was often used as a fuel) was used to to heat the bell before repair. This solution was connected with uneven bell heating and heat the bell before repair. This solution was connected with uneven bell heating and cool- cooling. It may have caused new cracks or increased the old ones as a result. ing. It may have caused new cracks or increased the old ones as a result.
Materials 2021, 14, 2504 4 of 10 3. Maryan Bell Crack Repairing The company Rduch Bells & Clocks and Foundry Department collectively made a decision to repair a cracked Maryan bell from the 17th century at the request of urban restorer in Krosno–Marta Rymar. The bell hangs in a church tower. It is the smallest bell of three cast in 1639, weighing 580 kg. It is characterized by producing a “G#” sound. The bell was cast by two bell founders, Szepan Meutel and Jerzy Olivier, for a special order from the great philanthropist Robert Wojciech Portius. The Maryan bell is one of three treated bells. On the tower there are also the Urban bell and the Jan bell. The bells are tuned to a major scale. This means that they sound happy, merry, and concurrently noble. The lack of one bell or unclear sound will cause the whole set to lose its musical value. This is why it was so important not only to repair the crack but to do it in such a way as to avoid changes to the sound. The most important task during welding process was to obtain the original sound. Fortunately, in 2013, during the change of the clapper, acoustic measurements were con- ducted. Thanks to this it was possible to obtain the sound before and after the damage to the bell (the damage occurred in 2017—exact date is unknown). This was the base for further activities. The work was divided into a few steps: 1. The first step was to take a material sample to determine the averaged chemical composition of the alloy, which was analyzed with a glow–discharge spectrometer LECO GDS500A (LECO Corporation, St. Joseph, MI, USA, 2011) (Table 1); 2. In the next step a series of welding rods with the same chemical composition were prepared on the basis of these results, which were used during bell welding process; 3. The next step was to determine the size and range of the crack, and penetration research was conducted; 4. The next step was preparing the bell for the welding process by properly bevelling the sides of the bell; 5. The next step was heating and keeping the bell at the proper temperature; 6. The next step was obtaining the required temperature to conduct welding process; 7. After welding slow cooling was conducted to avoid stresses; 8. The last step was analysis of the sound of the repaired bell. Table 1. Chemical composition of the Maryan bell (wt. %). Sn Pb Sb Zn Fe Ni Ag Cu 15.2 2.84 2.69 0.35 0.03 0.41 0.15 bal. Accuracy in all of these activities allowed us to obtain the ideal sound from the repaired bell. The samples of material obtained were examined with the use of a spectrometer to determine averaged chemical composition (presented in Table 1). The analysis of structure was also conducted with the use of a scanning microscope to determine the distribution and size of solid and gaseous inclusions. (Figure 3a,b). The chemical composition in particular places (with visible solid and gaseous inclusions) was presented in Table 2. Metallographic microsections showed the original structure of the bell. Unfortunately, many gaseous (Figure 3a, 6) and non–metallic inclusions were observed. A large amount of carbon (Figure 3b, 1) can indicate residue of charcoal, which was used as fuel during the melting process. Zinc inclusions were also observed (Figure 3a, 5).This negatively influenced the welding process. A series of welding rods were made after chemical composition determination and consultations with the company conducting the welding process. Their composition was selected to be as compatible as possible with the examined material of the bell. A set of molds was worked out and prepared in the Foundry Department, and thanks to them welding rods of different lengths and diameters were produced (Figure 4).
Materials 2021, 14, x FOR PEER REVIEW 5 of 10 Materials 2021, 14, 2504 5 of 10 (a) 100 μm (b) 20 μm Figure Figure 3. Location 3. Location of the of the measurement measurement points points for for scanning scanning microscope microscope examination examination withwith visible visible impurities impurities andand inclusions. inclusions. (a) 1–6 (a) 1–6 measurement measurement points points for magnification for magnification 530× 530×, , (b) (b) 1–31–3 measurement measurement points points for for magnification magnification 800×. 800× . Table Table 2. Chemical 2. Chemical composition composition in particular in particular examined examined places places presented presented in Figure in Figure 3. 3. Figure Figure 3a 3a Figure Figure 3b 3b Element Element Atomic Atomic Element Element Atomic Atomic Number Number Number Symbol Concentration Number Symbol Concentration Symbol Concentration Symbol Concentration Cu 21.43 C 75.57 Cu 21.43 C 75.57 C C 70.37 70.37 Zn Zn 12.53 12.53 1 1 SnSn 1.77 1.77 1 1 CuCu 3.56 3.56 OO 6.446.44 S S 5.12 5.12 OO 3.22 3.22 CuCu 28.54 28.54 CuCu 17.76 17.76 SnSn 6.34 6.34 C C 75.99 75.99 2 2 2 2 C 57.87 S 3.79 C 57.87 S 3.79 O 7.25 O 2.47 O 7.25 O 2.47 Cu 24.57 Pb 9.95 C Cu 24.57 64.84 C Pb 9.95 64.53 3 S C 64.84 6.57 3 Cu C 64.53 7.85 3 O S 3.846.57 3 O Cu 177.85 Sb 0.19 Sn 0.68 O 3.84 O 17 Cu 25.7 Sb 0.19 Sn 0.68 4 C 63.68 S Cu 25.7 7.44 4 Zn C 63.68 24.46 C S 7.44 57.29 5 S Zn 13.12 24.46 Cu 2.88 C 57.29 O 2.25 5 S 13.12 Cu 2.88 O 2.25
during the melting process. Zinc inclusions were also observed (Figure 3a, 5).This nega- during the melting process. Zinc inclusions were also observed (Figure 3a, 5).This nega- tively influenced the welding process. tively influenced the welding process. A series of welding rods were made after chemical composition determination and A series of welding rods were made after chemical composition determination and consultations with the company conducting the welding process. Their composition was consultations with the company conducting the welding process. Their composition was Materials 2021, 14, 2504 selected to be as compatible as possible with the examined material of the bell. A6set of of 10 selected to be as compatible as possible with the examined material of the bell. A set of molds was worked out and prepared in the Foundry Department, and thanks to them molds was worked out and prepared in the Foundry Department, and thanks to them welding rods of different lengths and diameters were produced (Figure 4). welding rods of different lengths and diameters were produced (Figure 4). Figure4.4.Welding Welding rodsofof different lengths and diameters (the length of rods was 40 the cm;diameters the diam- Figure Figure 4. Welding rods rods ofdifferent differentlengths lengthsand anddiameters diameters(the length (the of of length rods was rods 40 cm; was 40 cm; the diam- eters were 8 mm and 6 mm). were were eters 8 mm8and mm6and mm).6 mm). Thesize The sizeand andrange rangeofofthe thecrack crackwere were examinedwith with theuse use ofpenetration penetration testing The size and range of the crack were examined examined with the the use of of penetration testing testing (Figure 5). (Figure 5). Penetrator 5). Penetrator was Penetrator was used was used for used for this for this examination this examination by examination by covering by covering the covering the crack the crack andfilm, crack and and film,which which (Figure film, which helped helped toto determine to determine determine thethe range the range of range of the of the crack. the crack. crack. helped Figure 5. Penetration testing. Figure 5. Penetration Figure 5. Penetration testing. testing. After crack range determination, mechanical treatment of the damaged place was conducted to remove the external oxidized surface (Figure 5). This phase was performed in such way to obtain the best access to whole crack by the welder during the welding process (Figure 6). It was found during mechanical treatment that the bell’s structure is very porous, especially the external surface. This worsened the welding process. The welding process was conducted with the use of an oxyacetylene torch. During this process the bell edges were melted with the welding rods made earlier. Welding was conducted with the use of the “up method”. Better efficiency of welding and very good penetration of the whole thickness of the connected parts were obtained thanks to this method. It was possible to perform the weld with a single torch cut due to this method.
in such way to obtain the best conducted access to to remove whole the crack external by the surface oxidized welder (Figure during 5). theThis welding phase was performed process (Figure 6). It was found during mechanical treatment that the bell’s structure in such way to obtain the best access to whole crack by the welder during is the welding very porous, especially the external surface. This worsened the welding process. The process (Figure 6). It was found during mechanical treatment that the bell’s structure is welding process was veryconducted with the use porous, especially theofexternal an oxyacetylene surface. torch. During thisthe This worsened process welding process. The the bell edges were melted with the welding rods made earlier. Welding was conducted welding process was conducted with the use of an oxyacetylene torch. During this process Materials 2021, 14, 2504 with the use of the “up 7 of 10 the bellmethod”. Better edges were efficiency melted of welding with the weldingandrodsvery madegood penetration earlier. Welding was conducted of the whole thickness of the with the useconnected of the “upparts were obtained method”. thanks to Better efficiency ofthis method. welding andItvery was good penetration possible to perform the weld with a single torch cut due to this method. of the whole thickness of the connected parts were obtained thanks to this method. It was possible to perform the weld with a single torch cut due to this method. Figure 6. Mechanical treatment of the damaged place. Figure 6. Mechanical treatment of the damaged place. Figure 6. Mechanical treatment of the damaged place. It It was important was to heat important toand heatkeep andthekeep bell atthe the bell properat temperature the proper during the weld- temperature during the ing process. This temperature It was was obtained important to heat by using and keep heating mats and aluminosilicate welding process. This temperature was obtained bythe bell at using the proper heating matstemperature during the weld- and aluminosilicate fiber isolation. The whole process oftemperature heating waswas under the control of and recorded byand a aluminosilicate fiber isolation.ing Theprocess. wholeThis process of heating obtained was under bytheusing heating control of mats and recorded by computer program (Figure fiber 7);theThe isolation. heating wholerate was ~10 process of °C/h. heatingThe wastime of cooling under the after per- control of a computer forming program the weld was longer(Figure than 7);the heating the(Figure heating time,rate and was ◦ ~10 C/h. the rate cooling The~7time cooling after by a ofThus and recorded computer program 7);the heating wasrate~10was °C/h. °C/h. The time of cooling after per- performing slow theconducted cooling was weld was longer than the which heating time, and the cooling bellrate was ~7 ◦ C/h. forming theto avoid weld wasstresses, longer than thecould have heating caused time, the cooling and the to crack rate was ~7 °C/h. Thus Thus slow cooling was conducted to avoid stresses, which could have caused the bell to again. slow cooling was conducted to avoid stresses, which could have caused the bell to crack crack again. again. A A B B (a) (b) (a)fibro isolation; red circle–the place of welding (b) (b) Figure 7. Welding process (a) the bell protected by close–up of the place of welding. A—acetylene torch, B—bronze rod. Figure 7. Welding Figure 7.process (a) the Welding bell protected process by fibro (a) the bell isolation; protected byred circle–the fibro placered isolation; of welding (b) close–up circle–the place of of the place welding of welding. A—acetylene torch, B—bronze rod. (b) close–up After the of the place cooling of welding. process, A—acetylene the place torch, of welding was B—bronze ground rod.8) and the sound (Figure of bell was examined. After the cooling process, the place of welding was ground (Figure 8) and the sound Materials 2021, 14, x FOR PEER REVIEW After the cooling process, the place of welding was ground (Figure 8) and 8 of the 10 sound of bell was examined. of bell was examined. Figure 8. Figure 8. Welded Weldedbell bellattached attachedto to thethe tower. tower. 4. Sound Analysis of the Bell In 2013, before the crack, the bell’s sound was analyzed. After welding and the ther- mal stabilization process, this analysis was repeated. The sound of the bell, a G#4 note, did not worsen or even improve as a result of the negligible reduction of the main aliquots
Materials 2021, 14, 2504 8 of 10 4. Sound Analysis of the Bell In 2013, before the crack, the bell’s sound was analyzed. After welding and the thermal stabilization process, this analysis was repeated. The sound of the bell, a G#4 note, did not worsen or even improve as a result of the negligible reduction of the main aliquots frequency. The target frequencies for the first partials are in the ratios 0.5:1.0:1.2:1.5:2.0 and these needed to be quite closely matched. The first aliquot, called the hum, is not prominent, and the perceived pitch is usually that of the second aliquot, called the prime, perhaps because it is reinforced by the harmonically-related aliquots with relative frequencies 2, 3, and 4. The tone of the bell is complex, however, particularly because of the presence of the minor-third (From Old French tierce, from Latin tertia) interval of 1.2 [10]. The lower (tone lower than the prime about the octave) and upper (tone higher than the prime about the octave) octaves with prime, tierce and quint were found to be beautifully harmonious after the repair. There was no distortionary vibration and the bell sustained its note for a long time. The frequency spectrums of the Maryan bell before and after the crack are presented in Figure 9. The units of the amplitude in the figure are arbitrary; they are measured as voltages from a microphone, i.e., sound pressure levels on a linear scale. The amplitude of the spectrum is described in decibel scale. The program Wavanal [11] was used to analyze the sound of bell examined to determine the spectrum of emitted sound waves. This program was developed by W. A. Hibbert [12] for the sound analysis of bells to determine the influence of side tones on the height of the perceived strike tone (pitch tone). The possibility of fast and precise determination of their frequency was crucial, and the Wavanal program enabled it. This program allows a Fourier transform of sound waves directly recorded by a microphone joined to a computer or saved in a sound file recorded with other devices to be performed (Figure 10a,b). This program has received recognition among many bell makers as a great device for the evaluation of a bell’s sound and the process of tuning it up. Materials 2021, 14, x FOR PEER REVIEW Determined by the Wavanal program, values of frequency of basic side tones (aliquots): 9 the lower octave (hum), prime (fundamental), minor tierce, quint, and upper octave (nominal) of the bells examined are presented in Table 3 and as a diagram in Figure 11. Figure 9. The spectrum of the St. Maryan bell’s sound, before (BW) and after (AW) welding. Figure 9. The spectrum of the St. Maryan bell’s sound, before (BW) and after (AW) welding.
Materials 2021, 14, 2504 9 of 10 Figure 9. The spectrum of the St. Maryan bell’s sound, before (BW) and after (AW) welding. (a) (b) 10. The Figure 10. Theanalysis analysisofof sound sound wave wave emitted emitted by C3 by bell bellinC3 in program program Wavanal; Wavanal; (a) theofshape (a) the shape of recorded recorded wave, (b) wave, (b) its its spectrum. spectrum. Table 3. Main partials of the St. Maryan bell’s sound frequencies before and after welding in Determined comparison by the to harmonic Wavanal tones program, for the musical notevalues G#4. of frequency of basic side tones (ali- quots): the lower octave (hum), prime (fundamental), minor tierce, quint, and upper oc- Partials Tone tave (nominal) BW (Hz) of the bells examined AW (Hz) are presented in Table G#4 (Hz) 3 and as a diagram (ET) 11. in Figure Hum 212.5 208.5 207.6 Table 3. Main Primepartials of the St. Maryan 422 bell’s sound frequencies 413 before and after welding 415.3 in com- parison to harmonic tones for the musical note G#4. Tierce 512 502.5 493.8 Partials QuintTone BW635 (Hz) AW619 (Hz) G#4 622.3 (Hz) (ET) Materials 2021, 14, x FOR PEER REVIEW Hum 212.5 208.5 207.6 10 of 10 Nominal 853.5 836 830.6 Prime 422 413 415.3 Tierce 512 502.5 493.8 Quint 635 619 622.3 Nominal 853.5 836 830.6 Figure11. Figure Themain 11.The main partials partials of of thethe St.St. Maryan Maryan bell’s bell’s sound sound frequencies, frequencies, before before (BW),(BW), afterafter (AW) (AW) welding and for musical note G#4 according to the equal temperament scale welding and for musical note G#4 according to the equal temperament scale (ET). (ET). 5.5.Conclusions Conclusions Basedon Based onthe the experience experience gained gained during during the the workwork and and research research carried carried out onout theon the Mar- Maryan bell, the following conclusions can be yan bell, the following conclusions can be drawn:drawn: 1. If the welding process is carried out with the correct parameters, especially with 1. If the welding process is carried out with the correct parameters, especially with ther- thermal ones, and with monitoring and control of the heating and cooling rates, the mal ones, and with monitoring and control of the heating and cooling rates, the repair repair even of contaminated high tin bronze bells is possible; even of contaminated high tin bronze bells is possible; 2. After repair by welding, the bell has a “better” sound, and this is probably due to 2. After repair by welding, the bell has a “better” sound, and this is probably due to a a kind of heat treatment performed, including a cycle of slow heating and cooling kind of heat treatment performed, including a cycle of slow heating and cooling which improves the properties of the material; and which improves the properties of the material; and 3. The most highly recommended technique for repairing bells is gas welding, due to 3. The most highly recommended technique for repairing bells is gas welding, due to the relatively low temperature in the bonding area and the efficiency of the process. the relatively low temperature in the bonding area and the efficiency of the process. Author Contributions: Conceptualization, methodology, software, formal analysis, writing—re- view and editing, D.B.; conceptualization, methodology, investigation, writing—original draft prep- aration, C.B. Both authors have read and agreed to the published version of the manuscript. Funding: This research received no external funding
Materials 2021, 14, 2504 10 of 10 Author Contributions: Conceptualization, methodology, software, formal analysis, writing—review and editing, D.B.; conceptualization, methodology, investigation, writing—original draft preparation, C.B. Both authors have read and agreed to the published version of the manuscript. Funding: This research received no external funding. Institutional Review Board Statement: Not applicable. Informed Consent Statement: Not applicable. Data Availability Statement: The data presented in this study are available in article. Acknowledgments: The authors would like to acknowledge to Rduch Bells and Clocks and Jan Felczynski’s Bell Foundry for materials and technical support. Conflicts of Interest: The authors declare no conflict of interest. References 1. Szupp, B. Repair of church bells by welding. Weld. Cut. Metals 1936, 12, 198–205. 2. Ernesto Ponce, L. Restoration of ancient bronze bells. Part II: Welding. Ingeniare Rev. Chil. Ing. 2015, 23, 30–37. [CrossRef] 3. Raimbault, L. Process for Welding Bells. Patent No FR2703615A1, 14 October 1994. France. 4. Strafford, K.N.; Newell, R.; Audy, K.; Audy, J. Analysis of Bell Material from the Middle Ages to the Recent Time. Endeavour 1996, 20, 22–27. [CrossRef] 5. Audy, J.; Audy, K. Analysis of bell materials: Tin bronzes. China Foundry 2008, 5, 199–204. 6. Bartocha, D.; Baron, C. The “Secret” of Traditional Technology of Casting Bells. Arch. Foundry Eng. 2015, 15, 5–10. 7. Kurski, K. Cooper and Its Technical Alloys; Wydawnictwo Ślask: ˛ Katowice, Poland, 1967. 8. Górny, Z.; Sobczak, J.J. Modern Casting Materials Based on Non-Ferrous Metals; ZA-PIS: Kraków, Poland, 2005. 9. Górny, Z. Foundry Non-Ferrous Metal Alloys; WNT: Warszawa, Poland, 1992. 10. Fletcher, N.H. The nonlinear physics of musical instruments. Rep. Prog. Phys. 1999, 62, 723–764. [CrossRef] 11. Available online: http://www.hibberts.co.uk (accessed on 5 October 2020). 12. Hibbert, W.A. The Quantification of Strike Pitch and Pitch Shifts in Church Bells. Ph.D Thesis, The Open University Milton Keynes, Milton Keynes, UK, 2008, in press.
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