IMPROVING BATTERIES THROUGH SELF-HEALING SILICON ANODES
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Mandala 2:00 Team 13 Disclaimer: This paper partially fulfills a writing requirement for first-year (freshmen) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student paper, not a professional paper. This paper is not intended for publication or public circulation. This paper is based on publicly available information, and while this paper might contain the names of actual companies, products, and people, it cannot and does not contain all relevant information/data or analyses related to companies, products, and people named. All conclusions drawn by the authors are the opinions of the authors, first- year (freshmen) students completing this paper to fulfill a university writing requirement. If this paper or the information therein is used for any purpose other than the authors' partial fulfillment of a writing requirement for first-year (freshmen) engineering students at the University of Pittsburgh Swanson School of Engineering, the users are doing so at their own--not at the students', at the Swanson School's, or at the University of Pittsburgh's--risk. IMPROVING BATTERIES THROUGH SELF-HEALING SILICON ANODES Raul Casas RAC198, Andrew Buonanno APB57, Josh Briggs JMB431 Abstract—Constructing more efficient batteries has emerged CURRENT LITHIUM-ION BATTERY as a crucial prerequisite in the process of making new TECHNOLOGY technologies viable, such as electric cars. When considering how to improve upon current batteries, factors like energy- density, cost, and safety are key. This means manufacturers Lithium-ion batteries are the current standard for battery can increase energy output from each battery, resulting in technology. Lithium is lightweight and has massive increased driving range and fewer batteries necessary. For electrochemical potential, which leads to higher possible consumers, this means a more viable alternative to gas or voltages than previous batteries using nickel [1]. There are hybrid vehicles. other options for batteries, but they are outdated or flawed. Replacing the widely-used carbon graphite anode with a The closest competitor for lithium-ion batteries is the silicon based self-healing anode is a possible solution. This Nickel Metal-Hydride (NiMH) battery, but in application the paper will discuss how this switch could improve energy- lithium-ion battery is by far the most effective option in density by a factor of ten; however, during the charging and electric vehicles, a growing market. The future of the electric discharging cycle, silicon expands over four times its initial vehicles market is heavily reliant on improving batteries to size, which leads to detachment from surrounding electrical yield better driving range and reduce cost. When compared to connections and pulverization of the silicon anode. Over time, NiMH batteries, there are several key advantages of lithium- this decreases efficiency, lifespan, and charge capacity. ion batteries. Although they have similar energy storage, Currently, silicon is used in small amounts with the carbon NiMH batteries are much heavier and have shorter lifespans, graphite anode to improve energy-density, but it is difficult to usually caused by the memory effect, which limits the add more silicon without managing the anode’s expansion. battery’s future charge capacity when recharged before the This paper will evaluate possible methods to incorporate existing charge is completely used [2]. The memory effect has more silicon into battery anodes. The primary focus will be consequences, especially in electric vehicles. If the battery is on the use of various self-healing polymers to create a binder not drained of all charge before recharging repeatedly, or casing that restricts the silicon’s expansion. During crystals begin to form and reduce the NiMH battery’s charge experimental trials, batteries using self-healing binders have capacity [3]. When an electric vehicle is charged after each shown the potential to endure many charge and discharge use without a periodic complete discharge, the crystallization cycles, while taking advantage of silicon’s charge capacity occurs. This effect also occurs if the battery is overcharged. advantage over graphite. Other methods to make silicon This phenomenon is known as the memory effect because it anodes a possibility will also be considered. This paper will is the result of the battery remembering previous energy focus on comparing methods of integrating more silicon into output and not delivering more than that on subsequent uses. anodes with the results compared to carbon graphite anodes NiMH batteries have a specific energy of 50-64 Wh/Kg, and will evaluate the impact of silicon anodes with a focus on but lithium-ion batteries have a specific energy of around 90 the application for electric vehicles. Wh/Kg. Lithium-ion batteries have a specific power twice that of the NiMH battery. Predictions by Aditya Prabhakar, a Key words- carbon graphite anode, electric cars, lithium-ion graduate student at Missouri University of Science and battery, silicon anode, self-healing polymer Technology, and Mehdi Ferdowsi, a professor researching plug-in hybrid electric vehicles at Missouri University of Science and Technology, state that the switch from NiMH to lithium-ion batteries provides a 40-50% weight reduction, a University of Pittsburgh, Swanson School of Engineering 1 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 20-30% battery volume reduction, and an increase to graphite’s charge capacity of 372 mAh g-1. The result is a efficiency [4]. battery that can store much more charge. Additionally, lithium-ion batteries may eventually be the cheaper option over time. In 2007, the NiMH battery was LIMITATIONS OF SILICON ANODES cheaper, but the price of nickel has been rising since 1958. Rising nickel price combined with an increasingly efficient The problem with using a pure silicon anode is that mass production of lithium-ion batteries in gigafactories during the charging and discharging cycle, the anode expands could result in a turning point in pricing [5]. Cost is a massive over four times its initial size. This is due to an improved consideration for electric vehicles. It is estimated that the lithiation ability over graphite. For every one silicon atom, 4.4 battery cost for Tesla Model 3 is around 37% of the vehicle lithium atoms can be bound to form Li22Si5 [9]. For every one cost. Taking advantage of economies of scale for production carbon atom, .17 lithium atoms can be bound to form LiC 6. while nickel prices continue to rise is important. Lithium-ion The difference in ratios is the main cause of silicon’s immense batteries also have a longer lifespan with a typical life of 500- expansion compared to carbon. This expansion can cause 1,000 cycles, rather than 300-500 cycles for NiMH batteries reduced contact with the electrode and other connectors, [2]. In this case, the lifespan is defined as the number of which reduces efficiency, and damages the silicon in the charging cycles before dropping below 80% of the initial anode, which shortens the lifespan and reduces charge capacity. NiMH batteries also experience up to 30% self- capacity. This also causes an unstable solid electrode interface discharge per month, while lithium-ion batteries experience (SEI) layer to form on the anode [10]. This occurs primarily 10% self-discharge per month. Since electric vehicles may sit during the first charging cycle but continues to affect the between charges, this is an important metric. battery through subsequent cycles. The formation of an SEI In application, such as electric vehicles, these effects are greatly reduces the charge capacity. This creates internal amplified due to the scale of the batteries required for electric resistance. Reducing the SEI formations is an important cars. Because of this, lithium is essential in current batteries. consideration for developing a silicon anode. This is a Attempts at improving batteries further would require total manageable problem, though. Fluoroethylene carbonate is a changes in either composition, such as solid state batteries, or common additive to the electrolyte of a battery. Its presence utilizing different chemistries. These ideas are far from being creates a thinner SEI formation on the anode with a lesser cost-effective and require more research. Thus, when impact on the battery’s efficiency. Thus, being able to control improving batteries, the next logical step is to look at the the silicon’s expansion or minimize the effects becomes the anode. focus for further analysis. Graphite anodes are currently the most popular choice for the lithium-ion anode. These anodes are low-cost, long- SELF-HEALING POLYMERS lasting, and utilize a relatively high reversible capacity of 372 mAh g-1 [6]. So, further improving the graphite anode could One method of restricting silicon’s expansion during the be crucial for technological advancements. charging and discharging cycle is by using self-healing polymers as a binder to limit the expansion [8]. Self-healing NEW ANODE TECHNOLOGY materials are defined as having the ability to heal damages automatically and autonomously, or without human One current procedure for improving batteries is adding intervention [11]. Further, there are intrinsic self-healing small amounts of silicon to improve performance. George polymers that require a stimulus to be activated [12]. Their Crabtree, director of the Joint Center for Energy Storage counterpart, extrinsic self-healing polymers, utilize a healing Research, estimates that upwards of 10% of current lithium- agent that is encapsulated and embedded into the polymer ion anodes are silicon [7]. In 2015, Elon Musk stated that the during the manufacturing stage. Intrinsic and extrinsic Tesla Model S would use silicon in batteries to improve the systems are both currently in use as self-healing polymers for driving range by six percent. Small improvements to current anodes. technology by using silicon have already shown immense The process of self-healing, regardless of the type, potential impact when applied to electric vehicles. occurs in three stages [13]. First, a triggering must occur that Based on current lithium-ion batteries, developing begins the process. This stage is a direct effect of the damage methods to increase the amount of silicon in the anode is a incurred. The second stage is the transport of materials to the clear pathway toward an improved battery capable of damaged site. The final stage is the resulting chemical sustaining technological growth. Compared to the current reaction that heals the damage. This final stage is where the graphite carbon anodes, pure silicon anodes could various types of self-healing polymers vary. The process of theoretically increase charge capacity by a factor of ten [8]. capsule-based self-healing is extrinsic and limited to one use Silicon has a charge capacity of 4,200 mAh g-1, compared to in theory. Capsules are embedded in the material, so a damage to the material ruptures the local capsules and releases a University of Pittsburgh, Swanson School of Engineering 2 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 healing agent. Additionally, vascular self-healing materials rely on a network of capillaries that allow the healing agent to flow throughout the material in an extrinsic system. This concept can have multiple uses, and it also has the benefit of being able to inject more healing agent to the system. Last, an intrinsic system may use intermolecular forces, such as hydrogen bonding in organic compounds. Because many of these intrinsic systems use reversible reactions, the self- healing capabilities are not limited to one use. Intrinsic systems are the most popular option for creating a binder that serves to contain the expansion of the silicon anode because cracking occurs everywhere on the binder. Figure 1 [14] HOW SELF-HEALING POLYMERS WORK Benefit of a self-healing binder surrounding a WITH SILICON ANODES silicon anode Figure 1 shows the benefit of the self-healing polymer Since there are clear, quantitative benefits to using a used in the study compared to traditional polymer binders, silicon anode, the next step is to evaluate various methods to such as polyvindylidene fluoride (PVDF), sodium make the silicon anode viable, and to balance the benefits of carboxymethyl cellulose (CMC), and alginate binders, each improved charge capacity with charge retention. For intrinsic common in graphite anodes. These do not need to expand as systems, the self-healing polymers each rely on different much due to graphite not experiencing expansion to the same intermolecular forces and dynamic bonding between silicon extent as silicon. They can only be stretched to 10%, 4%, and nanoparticles and the organic binder. They all have similar 2%, respectively. This means that none of them are a healing capabilities, so comparisons based mainly on reasonable option for use with silicon anodes. Wang’s quantitative data are fair. composite polymer can be subjected to 100% stretching. The anode used in trials has a charge capacity of 2,617 mAh g-1. Analysis of Hydrogen Bonding This is six times larger than the theoretical capacity of graphite. After 20, 50, and 90 cycles, the anode coated in Wang et al. describes a silicon microparticle (SiMP) Wang’s composite experienced 100%, 95%, and 80% anode with self-healing properties that is readily available, capacity retention, respectively. PVDF, CMC, and alginate- low-cost, has a life cycle ten times longer than state-of-art coated anodes had 14%, 27%, and 47% capacity retention, anodes made from SiMPs, and retain a capacity upwards of respectively, after just 20 cycles. This research lays the 3,000 mAh g-1 [14]. The self-healing binder relies on groundwork for self-healing polymers providing significant hydrogen bonding in this case. The anode in this experiment improvements in lifespans for batteries. Based on the is 50% silicon by weight, which is an immense improvement improved life cycle of this composite over binders used with over the projected 10% silicon by weight currently in lithium- graphite anodes, it will now become the benchmark for future ion batteries. The self-healing coating uses a stretchable layer comparison. of self-healing polymer with dynamic bonding and conductive carbon black nanoparticles. This creates a Analysis of Ionic Bonding repeatable and autonomous healing process with conductive properties. The researchers use a synthesized, randomly- Kang et al. takes a different approach to the development branched hydrogen-bonding polymer. The hydrogen bonds of the self-healing binder [8]. Kang references various studies are dynamic in this case. Figure 1 depicts the intrinsic self- where dynamic ionic bonding has shown usefulness in self- healing system compared to traditional binders used with healing materials. Kang and his team developed a polymer graphite anodes. The self-healing binder keeps the silicon made with amine functionalized silicon (Si-NH2), carbon interlocked to preserve lithiation ability and conductivity. black as a conductive filler particle, and poly(acrylic acid) Through this process, the anode is healed and maintains its (PAA). These are mixed with water and stirred. Once the charge capacity over longer durations. mixture is dried, the electrode is formed. Kang proves the ionic bonding of ammonium carboxylate salt at the boundary between silicon nanoparticles and PAA. The created Si- NH2/PAA anode relies heavily on this ionic bonding, which can be increased by a heavier coating of amine groups. University of Pittsburgh, Swanson School of Engineering 3 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 The initial Coulombic efficiency of the Si-NH2/PAA that is injected into the silicon anode [15]. This is an extrinsic anode is 75%. For CMC and PAA binders without the amine system with vascular characteristics. Although more functional group, the initial Coulombic efficiencies are 70% restrictive on charge capacity than the binders, the proposed and 76%, respectively. Last, the researchers used a control of anodes are still an improvement over graphite anodes. The silicon nanoparticles functionalized with surface methyl claimed benefits are increased life span due to the alloy groups and a PAA binder. The addition of methyl groups possessing self-healing properties, reduced stress on the limits the intermolecular forces to being weak van der Waal anode due to the injection being liquid, and improved interactions. For the control, the initial Coulombic efficiency conductivity compared to the self-healing polymer binders. is only 58%. The theory is that nanostructures have inactive elements that Next, the researchers cycled the different batteries at a contribute extra weight, extra volume, and unnecessary current density of 2.1 A g-1. The Si-NH2/PAA results show a reactions with the electrolyte. To support the claim of a longer capacity retention of 80% at 400 cycles. The discharge life span, Wu states that there is no obvious decay over 1,000 capacity was 1,177 mAh g-1 at the end of 400 cycles. For the cycles. Although this anode is only 33% silicon by weight, it CMC and PAA binders, where only hydrogen bonding is is impressive to control the expansion to achieve such a possible with the silicon, the capacity retention is only 35% reduction in capacity fade over many more cycles than studied after 400 cycles. Last, the control group shows capacity with Kang’s anode. The liquid metal, a silicon-gallium alloy, retention of 5% after 400 cycles. The resulting conclusion is is more conductive than carbon materials or organic that stronger intermolecular forces between the silicon polymers. Adding silicon to a more conductive liquid metal nanoparticles and the binder yield improved capacity material than graphite yields better charge capacity and adds retention due to the ability of the binder to interact when the healing effects. To compare to Kang’s study, however, when silicon fractures. Thus, ionic bonding yields the best healing used at 2 A g-1, the battery has a charge capacity of only 670 effects on the anode. mAh g-1. Being greater than the theoretical capacity for pure In addition, the Si-NH2/PAA contained 10% graphite anodes, this is an option to consider due to its fluoroethylene carbonate by weight to control the SEI longevity; however, from a charge capacity perspective, the formation. This reacts with the amine functional groups in the anode in Si-NH2/PAA anode is a much better option. Over Si-NH2/PAA binder. The SEI is stable, and the resistance due 1,000 cycles, the Coulombic efficiency is 99.3%. The to the SEI is consistently around 40 ohms. Without the amine minimal capacity fade over a long period of use is vital to functional group and the resulting ionic bonding, the being useful in application. resistance peaks at roughly 180 ohms. Since much of the Wu ran another trial with 66% silicon by weight. This capacity fade from SEI occurs in the first cycle, the Si- resulted in an initial capacity of roughly 2,000 mAh g-1, but NH2/PAA binder has minimal initial fade compared to its after just 300 cycles, the charge capacity dropped to 584 mAh counterparts without the amine functional group. This is g-1. Since Wu’s 66% silicon by weight is similar to Kang’s important for longevity and consistency in the battery. 60% silicon by weight anode, a direct comparison is fair. The Comparing this to Wang’s the aforementioned study liquid metal has significant capacity fade. After 400 cycles, shows the importance of the Si-NH2/PAA binder. First, Kang’s battery had over twice the charge capacity as Wu’s Wang’s composite was studied with a .4 A g-1 current density battery did after 100 fewer cycles. [14]. This is much lower than the current density used by In this sense, Kang’s Si-NH2/PAA anode is the better Kang (2.1 A g-1). The lower current density reduces the option for electric vehicle application in terms of driving silicon’s expansion and the deleterious effects resulting from range, but Wu’s battery with 33% silicon by weight may be prolonged use. Therefore, maintaining 80% capacity retention overall better in application for electric vehicles due to the with the Si-NH2/PAA binder after 400 cycles at the higher minimal capacity fade after 1,000 cycles. Increased longevity current density is much more impressive than 80% after 90 means less maintenance is necessary regarding the vehicle’s cycles for the first composite at the lower current density. batteries, but driving range is sacrificed. Furthermore, the anode in Wang’s study was 50% silicon by weight; the anode in Kang’s study was 60% by weight. With CONSIDERING SILICON ANODES more silicon in the anode, resulting in more fracturing, but overall improved longevity, Kang’s Si-NH2/PAA binder is a WITHOUT A POLYMER BINDER clear improvement on composites utilizing hydrogen bonding. Because silicon anodes pulverize or show signs of damage after the first cycle, finding data to compare for a Liquid Metal: An Alternative to Polymers benchmark is difficult. However, Dose et al. discusses this in “Capacity Fade in High Energy Silicon-Graphite Electrodes Wu et al. describes another type of self-healing silicon for Lithium-Ion Batteries.” They use approximations to anode that uses liquid metal, an alloy of gallium and silicon, isolate the silicon’s decay. In a 15% silicon by weight graphite University of Pittsburgh, Swanson School of Engineering 4 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 anode with an initial charge capacity of roughly 860 mAh g - charge densities, and typically require little to no 1 , the capacity retention after 100 cycles is around 75% [16]. maintenance. Over a test of 1,000 cycles, the capacity retention is down to However, as previously examined, most current lithium- around 41%. From the battery used in the study, Dose ion batteries use graphite anodes. These batteries need to be assumes that the graphite components had “little fade,” so the improved in order to be more efficient and cost-effective for silicon components are assumed to account for the decline the mass market. In reference to an article by the Royal from 61% capacity retention after 400 cycles to 46% capacity Society of Chemistry titled “Lithium-ion Batteries: A Look retention after 1,000 cycles. into the Future,” to ensure a driving range of 150 km with a Isolating the data from 400 cycles and comparing to the single charge for a common sub-compact passenger car, the battery with a polymer binder yields interesting results. The battery would have to weigh over 160 kg based on the current unrestricted silicon’s 61% capacity retention, observed by average lithium-ion energy density [19]. This is impractical Dose, compared to 80% capacity retention, observed by when options exist to make the batteries more efficient. A Kang, if a self-healing binder is used appears to be an battery with a much higher energy density would be the ideal insignificant change. It is important to note, though, that as solution. Researchers have found that replacing the graphite the silicon becomes less efficient in the anode at lithiation, anode with a silicon anode can increase the battery’s capacity there is reduced volume expansion, which leads to less by more than ten-fold and, thus, greatly increase the energy cracking and a steadier charge capacity over time [8]. Even density, which allows for weight reduction of the battery more impressive, the anode used in Kang’s study was 60% pack. However, a silicon anode on its own is not the perfect silicon by weight, rather than 15%. The battery used in Dose’s solution. Testing has found that during the lithiation study is similar, albeit slightly improved in terms of silicon electrochemical process, the anode expands and contracts percentage by weight, to current lithium-ion batteries. which causes cracks, pulverization, and eventually the battery Maintaining a higher charge capacity, despite increasing the is no longer reliable to function. silicon composition in the anode, shows a massive In an interview with Elon Musk, the founder of Tesla, improvement resulting from the binder. When compared to he proposed that by the year 2035, electric vehicles will the liquid metal alternative, the results are also similar. The dominate our roads [20]. Society will likely see these changes liquid metal battery has a charge capacity to Dose’s battery come to fruition, but researchers must first improve on and much less capacity fade. Compared to traditional graphite making electric cars more practical and affordable to anodes with trace amounts of silicon possible, these methods consumers. At the moment, affordable, yet advanced, electric of incorporating silicon into anodes are successful. They have cars, such as the Chevy Bolt, take several hours to reach full improved charge capacity and have proven to be long-lasting charge. The Chevy Bolt still takes around ten hours for it to in tests. The silicon anode is viable when coupled with the reach full charge [21]. For many people, this is impractical benefits derived from methods to control and contain its compared to the ease of filling up a gasoline car in just a few expansion. Although these methods are in the study phase and minutes, especially for long trips. The Bolt’s power comes likely far from being cost effective, batteries can be improved. from a nickel-rich lithium-ion battery, which weighs around Therefore, lithium-ion battery-dependent technology, such as 435 kg and boasts a range of 238 miles from a single charge. electric vehicles, is indirectly improved. As long as the development of silicon-anode lithium-ion batteries continues, we could soon see more striking APPLICATION TO ELECTRIC VEHICLES performance from electric cars at more affordable prices. These improvements could open up a wider variety of electric cars. Budget cars with similar driving range to today’s electric Currently, around 95% of vehicles rely on the burning vehicles would appear on the market. This would be of fossil fuels, and transportation is one of the largest sources accomplished by using the improved silicon anode batteries of CO2 emissions [17]. In fact, 14% of greenhouse gas to increase efficiency and range, reduce weight of the vehicle, emissions come directly from transportation. As a result, car and reduce the input costs of production. These savings are manufacturers and scientists have been developing more compounded by the fact that driving with gas is more sustainable, energy-efficient, and environmentally-friendly expensive than electricity. One study at the University of vehicles. The most advanced electric vehicles today, such as Michigan by Michael Sivak and Brandon Schoettle analyzes Tesla’s Model S, rely on lithium-ion batteries, which appear the average annual cost difference for each state [22]. The to be the best option moving forward [18]. However, current study considers gas prices on December 23, 2017. Given these batteries have limitations for this application. As formerly prices for each state, they used average data. They assume that discussed, lithium-ion batteries are more efficient than other gas vehicles get an average of 25 miles per gallon, electric types of batteries used in electric cars, such as NiMH vehicles consume 33 kWh per 100 miles, and the average batteries. Lithium-ion batteries charge faster, have higher annual driving distance is 11,443 miles. For simplicity, this paper will analyze averages of data across the entire United University of Pittsburgh, Swanson School of Engineering 5 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 States, rather than individual state considerations. The there is a demonstrated potential to improve the driving range average annual cost of gas consumption is $1,117, while the in smaller vehicles. average annual cost of electricity consumption is $485. This yields an annual savings of $632. Therefore, an improvement POSSIBLE ECONOMIC AND LOGISTICAL on batteries will not only make purchasing electric vehicles cheaper, it will have annual savings. This decrease in price IMPACT OF IMPROVED LITHIUM-ION will make electric vehicles much more viable. As the price of BATTERY IN ELECTRIC VEHICLES vehicles decreases due batteries improved with silicon anodes, the savings from using electricity instead of gasoline Improved lithium-ion batteries are predicted to be higher will help to entice consumers to switch to electric vehicles. in demand in the near future with their use becoming more From a perspective with driving range being the most common in electric vehicles, as well as consumer electronics. important benefit, electric vehicles using all of their potential According to the Market Research Engine, the global lithium- space could lead to massive improvements of driving range. ion battery market is expected to exceed more than $92 billion Given that many vehicles have limited space available for at a compound annual growth rate of 16.5% [25]. This shows batteries, the most efficient way to improve driving range is that the market for better batteries, produced cost-effectively, improving the batteries. This does not require more space has the potential for profit and is bound to open up thousands dedicated to batteries. As this becomes a reality, public of job opportunities in the future. The goal for producing cost- transport and long-range semi-trucks may make a drastic effective batteries is reaching economies of scale. Tesla has switch to electric power. Currently, there are around 1,600 demonstrated some interest in developing the Gigafactory to electric buses in the United States [23]. However, the L.A. make every step of the process efficient [18]. Tesla’s target is Metro, for example, stated that the buses were not reliable past to account for around 60% of the world’s production of 100 miles of driving, and some buses even needed charging lithium-ion batteries. Some of the major forces propelling this after just 78 miles. Making electric buses more viable is market forward are increasing demand for improved batteries important because electric buses are estimated to save coming from automobile manufacturers, rapidly-spreading $130,000 over the bus’s lifetime, along with drastically concerns for the environment, which relates to people looking reducing emissions. Figure 2 illustrates the potential impact into electric cars instead of standard gasoline cars, and that results even in a switch from hybrid buses to electric applications of lithium-ion batteries in other consumer buses. This switch from diesel-hybrid buses to battery electric electronics. With all of this in mind, it appears that the market busses, as seen on the graph, halves the resulting emissions. production of lithium-ion batteries could grow to a massive extent in the coming years. One of the main forces holding back the market for lithium-ion batteries is the high cost of production. Electric cars are currently more expensive than gasoline models due to the high cost of producing batteries. Given the high cost and the fact that there are only four fully electric vehicles that can currently surpass ranges of 200 miles from a single charge, the average consumer is not inclined to purchase an electric vehicle [5]. The switch to electric vehicles indirectly affects the market for oil, leading to more economic changes. The possibility of increased dependence on electric vehicles, especially in the United States, could lead to decreased dependence on foreign oil. Just considering electric buses in China, there was a reduction of 233,000 barrels of oil [23]. Figure 2 [23] Forecasts for the world by Eco Watch show that this reduction Emissions from buses over their lifetime could increase in magnitude to 7.3 million barrels of oil per day. Although this is just below 10% of the daily market for There are already plans for improving the viability of oil, a change of this magnitude would have immense effects electric vehicles beyond consumer cars. Tesla plans to release on worldwide economic relations. For the United States semi-trucks with 300 and 500-mile driving ranges [24]. specifically, a continuing dependence on foreign oil increases Accomplishing this, in turn, shows viability for buses and the deficit. Instead of borrowing to reinvest, around 27% of other heavy-weight vehicles. By showing the potential for foreign oil is being used for passenger vehicles as of 2017 improved driving range in larger, heavy-weight vehicles, [26]. This is not economically viable because running a deficit in a country’s current account, used to quantify imports and University of Pittsburgh, Swanson School of Engineering 6 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 exports account, to only increase a temporary standard of SOURCES living is not logical [27]. A deficit should be used in expansionary practices but not for unsustainable practices. [1] U. Koehler. “High Performance Nickel-Metal Hydride Using investment to fund current consumption is adding an and Lithium-Ion Batteries.” Journal of Power Sources. ever-growing burden on future generations in the form of 03.20.2002. Accessed 02.19.2019. debt. From a strictly economic point-of-view, the dependence https://www.sciencedirect.com/science/article/pii/S0378775 of the United States on foreign oil is not a long-term strategy 301009326. for trade. [2] “What’s the Best Battery?” Battery University. 03.21.2017. Accessed 03.04.2019. CONCLUSION https://batteryuniversity.com/learn/archive/whats_the_best_b attery. In the future, science, technology, and society in general [3] “Memory: Myth or Fact?” Battery University. will require an extremely efficient battery to support existing 03.10.2011. Accessed 03.04.2019. technologies, as well as future development. The https://batteryuniversity.com/learn/archive/memory_myth_o improvements in battery anodes will result in improvement to r_fact. a wide range of technology, from electric vehicles to more [4] A. Prabhakar. “Comparison of NiMH and Li-ion Batteries general technology. These will be heavily dependent on in Automotive Applications.” Missouri University of Science increased efficiency, decreased weight, and decreased cost of and Technology Scholars’ Mine. 09.01.2008. Accessed production of batteries. Although other battery technologies 03.04.2019. are being researched, the most potential for long-lasting https://scholarsmine.mst.edu/cgi/viewcontent.cgi?article=16 impact appears to be updating the current lithium-ion battery 67&context=ele_comeng_facwork. technology. Switching from a graphite anode to a silicon [5] A. Ulvestad. “A Brief Review of Current Lithium Ion anode yields much better charge capacity, but silicon’s Battery Technology and Potential Solid State Battery expansion needs self-healing binders or materials to contain Technologies” Arxiv. 12.03.2018. Accessed 07.02.2019. its expansion. https://arxiv.org/ftp/arxiv/papers/1803/1803.04317.pdf. Research yields multiple solutions ranging from a Si- [6] M. Yoshio. “Improvement of Natural Graphite as a NH2/PAA binder that uses dynamic ionic bonding to heal the Lithium-ion Battery Anode Material, from Raw Flake to silicon anode to liquid metal solutions with self-healing Carbon-Coated Sphere.” Journal of Materials Chemistry. properties. There are various options to consider for making 2004. Accessed 03.04.2019. silicon anodes viable, and they have different benefits. The https://pubs.rsc.org/en/content/articlelanding/2004/jm/b3167 self-healing binder is able to incorporate more silicon into the 02j#!divAbstract. anode, which improves the battery’s charge capacity [8]. The [7] C. Mims. “The Battery Boost We’ve Been Waiting for Is liquid metal solution, on the other hand, is able to last much Only a Few Years Out.” The Wall Street Journal. 03.18.2018. longer, with some tests proving minimal fade over 1,000 Accessed 02.18.2019. https://www.wsj.com/articles/the- cycles [14]. Because both have potential for different battery-boost-weve-been-waiting-for-is-only-a-few-years- applications, it is important to continue research on this out-1521374401. subject. [8] S. Kang. “Silicon Composite Electrodes with Dynamic This switch could help electric cars overcome their main Ionic Bonding.” Advanced Energy Materials. 05.12.2017. bottleneck from a consumer’s point-of-view, being too Accessed 02.18.2019. expensive, and from a manufacturer’s point-of-view, having https://onlinelibrary.wiley.com/doi/full/10.1002/aenm.20170 limited driving range, especially on heavy-weight vehicles. 0045. This could result in electric public transportation or trucking [9] J. Tarascon. “Issues and Challenges Facing Rechargeable in addition to an immense change of preferences towards Lithium Batteries.” Nature International Journal of Science. electric vehicles. In turn, this reduces the output of emissions 11.15.2001. Accessed 03.04.19. pollution. Therefore, the impact of an improved battery is not https://www.nature.com/articles/35104644. limited to economic improvement. The significance of [10] M. Nie. “Silicon Solid Electrolyte Interphase (SEI) of potential improvements shows that self-healing polymers and Lithium Ion Battery Characterized by Microscopy and other self-healing materials for batteries deserve attention and Spectroscopy.” Journal of Physical Chemistry. 06.07.2013. further research. Accessed 03.04.2019. https://pubs.acs.org/doi/10.1021/jp404155y. [11] S. Ghosh. Self-Healing Materials: Fundamentals, Design, Strategies, and Applications. Weinheim, Germany: 2009. pp. 1-2, 145 University of Pittsburgh, Swanson School of Engineering 7 First-Year Conference Paper 04.06.2019
Mandala 2:00 Team 13 [12] Y. C. Yuan. “Self Healing in Polymers and Polymer [23] A. Schmitt. “Why are We Still Waiting for Electric Composites. Concepts, Realization and Outlook: A Review.” Buses?” Streetsblog USA. 12.07.2019. Accessed 03.04.2019. eXPRESS Polymer Letters. 2008. Accessed 02.18.2019. https://usa.streetsblog.org/2018/12/07/why-are-we-still- www.expresspolymlett.com/letolt.php?file=EPL- waiting-for-electric-buses/. 0000602&mi=c. [24] F. Lambert. “Tesla Semi Met and then Crushed Almost [13] B. J. Blaiszik. “Self-Healing Polymers and Composites.” All of Our Expectations.” Electrek. 11.17.2017. Accessed Annual Review of Materials Research. 08.04.2010. Accessed 03.04.2019. https://electrek.co/2017/11/17/tesla-semi- 02.18.2019. electric-truck-specs-cost/. https://www.annualreviews.org/doi/10.1146/annurev-matsci- [25] “Lithium-Ion Battery Market”. Market Research Engine. 070909-104532. 11.2019. Accessed 02.19.2019. [14] C. Wang. “Self-Healing Chemistry Enables the Stable https://www.marketresearchengine.com/lithium-ion-battery- Operation of Silicon Microparticle Anodes for High-Energy market1. Lithium-ion Batteries.” Nature Chemistry.” 11.17.2013. [27] J. Hamilton. “The Economic Benefits of Reducing Oil Accessed 02.20.2019. Imports.” OilPrice. 10.22.2012. Accessed 03.08.2019. https://web.stanford.edu/group/cui_group/papers/selfhealing. https://oilprice.com/Energy/Crude-Oil/The-Economic- pdf. Benefits-of-Reducing-Oil-Imports.html. [15] Y. Wu. “Self-Healing Liquid Metal and Si Composite as [28] M. Kah. “Electric Vehicles and Their Impact on Oil a High-Performance Anode for Lithium-Ion Batteries.” Demand: Why Forecasts Differ.” Columbia University American Chemical Society. 2018. Accessed 01.28.2019. Center on Global Energy Policy. 17.24.2018. Accessed https://pubs.acs.org/doi/pdfplus/10.1021/acsaem.8b00022. 03.08.2019. [16] W. M. Dose. “Capacity Fade in High Energy Silicon- https://energypolicy.columbia.edu/research/commentary/elec Graphite Electrodes for Lithium-Ion Batteries.” Chemical tric-vehicles-and-their-impact-oil-demand-why-forecasts- Communications. 2018. Accessed 02.18.2019. differ. https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc00 456k#!divAbstract. ACKNOWLEDGEMENTS [17] “Global Greenhouse Gas Emissions Data.” EPA. 04.13.2017. Accessed 03.08.2019. We would like to acknowledge our writing instructor, Rachel https://www.epa.gov/ghgemissions/global-greenhouse-gas- McTernan, for working closely with us throughout the emissions-data. research and writing process. We would also like to thank our [18] S. O’Kane. “Tesla Will Live and Die by the Gigafactor.” co-chair, Sabrina Nguyen, for providing advice on the The Verge. 11.30.2018. Accessed 03.08.2019. technical side of our research. https://www.theverge.com/transportation/2019/11/30/18118 451/tesla-gigafactory-nevada-video-elon-musk-jobs-model- 3. [19] B. Socratsi. “Lithium-Ion Batteries: A Look Into the Future”. Royal Society of Chemistry. 07.27.2011. Accessed 02.19.2019. https://pubs.rsc.org/en/content/articlehtml/2011/ee/c1ee0138 8b. [20] “The Future We’re Building- and Boring.” Ted. 04.2017. Accessed 02.19.2019. https://www.ted.com/talks/elon_musk_the_future_we_re_bu ilding_and_boring?language=en. [21] “BU-1003: Electric Vehicle (EV).” Battery University. 01.28.2019. Accessed 03.08.2019. https://batteryuniversity.com/learn/article/electric_vehicle_e v. [22] M. Sivak. “Relative Costs of Driving Electric and Gasoline Vehicles in the Individual U.S. States.” University of Michigan Sustainable Worldwide Transportation. 01.2018. Accessed 03.04.2019. http://umich.edu/~umtriswt/PDF/SWT-2018-1.pdf. University of Pittsburgh, Swanson School of Engineering 8 First-Year Conference Paper 04.06.2019
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