FINAL 29th International Conference on Organometallic Chemistry - Prague Congress Centre
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29th International Conference on Organometallic Chemistry Prague Congress Centre July 17–22, 2022 FINAL PROGRAMME
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 CONTENTS WELCOME MESSAGE Welcome Message 1 The 29th International Conference on Organometallic Chemistry (ICOMC 2022) in Prague follows the many previous successful meetings after years of silence International Advisory Board 2 enforced by covid-19 pandemic. In keeping with the tradition, it is focused on all aspects of organometallic chemistry, mainly on the synthesis and further studies on main group organoelement compounds, organometallic compounds of transition National Advisory Board 3 metals, lanthanides and actinides, and also on all fields, where these compounds find use (e.g., catalysis, bioorganometallic chemistry, material science and many other). Programme Overview 4 The conference will be held from July 17 to July 22, 2022 in the premises of the Prague Detailed Scientific Programme 8 Conference Centre. Poster Session 32 The organizing committee has assembled renowned speakers and offered wide opportunities for participation of young researchers and students. Hence, we believe that all participants will be provided with a unique opportunity to present their Instructions for Speakers (Authors) 53 interesting scientific results and to listen to the most recent news in the field of modern organometallic chemistry. Useful Information 55 Because Prague is not only a good place to discuss research but also a renowned place Floorplan and Exhibition 57 where history and art meet in a unique way, we hope that you also find time to enjoy the beautiful art, nature and the specific atmosphere of our historical capital and other Social Programme 58 places in the Czech Republic. We wish you a pleasant stay in Prague, many stimulating discussions Partners 59 and new partnerships! Petr Štěpnička Aleš Růžička Conference Co-Chairmen Conference Co-Chairmen 1
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 INTERNATIONAL ADVISORY BOARD NATIONAL ADVISORY BOARD Munetaka Akita (Tokyo Institute of Technology, Japan) Aleš Růžička (University of Pardubice) Jitendra K. Bera (Indian Institute of Technology, India) Petr Štěpnička (Charles University, Prague) Pierre Braunstein (University of Strasbourg, France) Yun Chi (City University of Hong Kong, China) Radek Cibulka (Institute of Chemical Technology, Prague) Deryn E. Fogg (University of Ottawa, Canada) Jan Čermák (J. E. Purkyně University, Ústí nad Labem) John A. Gladysz (Texas A&M University, USA) Libor Dostál (University of Pardubice) Anthony F. Hill (Australian National University) Bohumír Grüner (Institute of Inorganic Chemistry, AS CR, Řež) William D. Jones (University of Rochester, USA) Petr Hermann (Charles University, Prague) A. Hugo Klahn (Pontificia Universidad Católica de Valparaíso, Chile) Michal Horáček (J. Heyrovský Institute of Physical Chemistry, AS CR, Prague) Sensuke Ogoshi (Osaka University, Japan) Petr Klán (Masaryk University, Brno) Maurizio Peruzzini (Institute of Chemistry of the Organometallic Compounds, Italy) Martin Kotora (Charles University, Prague) Tamotsu Takahashi (Hokkaido University, Japan) Jiří Pinkas (Masaryk University, Brno) Yong Tang (Shanghai Institute of Organic Chemistry, China) Milan Pour (Charles University, Hradec Králové) Zhenfeng Xi (Peking University, China) Martin Putala (Comenius University, Bratislava, Slovakia) Philip Andrews (Monash Universit, Australia) Jiří Schulz (Charles University, Prague) Heinz Berke (University of Zürich, Switzerlan) Ivo Starý (Institute of Organic Chemistry and Biochemistry, AS CR, Prague) Christian Bruneau (University of Rennes, France) Jan Sýkora (Institute of Chemical Processes Fundamentals, AS CR, Prague) Pierre H. Dixneuf (University of Rennes, France) Petr Švec (University of Pardubice) Michael D. Fryzuk (University of British Columbia, Canada) Zdeněk Trávníček (Palacký University, Olomouc) F. Ekkehardt Hahn (University of Münster, Germany; chairman) Jan Veselý (Charles University, Prague) Guoxin Jin (Fudan University, China) Peter Junk (James Cook University, Australia) Alessandro Mordini (University of Firenze, Italy) Luis A. Oro (University of Zaragoza, Spain) Armando J. L. Pombeiro (University of Lisbon, Portugal) Matthias Tamm (Technical University Braunschweig, Germany) Alexander Trifonov (Russian Academy of Sciences, Russian Federation) Zuowei Xie (Chinese University of Hong Kong, China) 2 3
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 PROGRAMME OVERVIEW Sunday Monday Tuesday Wednesday Thursday Friday July 17, 2022 July 18, 2022 July 19, 2022 July 20, 2022 July 21, 2022 July 22, 2022 OC43C OC43A OC43B Jedreze- 08:30 KL4A KL4B KL4C Hejda Boronski Opening jewska PL2 Hevia Spokoyny Harder PL4 Arnold Nozaki IL7A IL7B IL7C Pietschnig Bera Fleischer 09:00 IL3A IL3B IL3C Tamm Alcarazo Dielmann PL1 Stephan KL2A KL2B KL2C KL5A KL5B KL5C KL6A KL6B KL6C 09:30 Driess Hey-Hawkins Xie OC27A OC27B OC27C Salmain Bourissou Mulvey Scheer Hong Ito Müller T. Dietz Brodie 10:00 Coffee break Coffee break Coffee break Coffee break Coffee break IL4A OC44A OC44B OC44C IL4B IL4C Hadlington Bím Terlecki 10:30 Gandel- KL1A KL1B KL1C Hahn Royo PL3 man PL5 Bertrand Nolan Gessner Xi Braunschweig OC45A OC45B OC45C OC28A OC28B OC28C Takahashi Simonneau Volk Lamprecht Webster Hochloch 11:00 OC1A OC1B OC1C OC46A OC46B OC46C Schwamm Poyatos Kobayashi OC29A OC29B OC29C Färber Stevens Das IL2A IL2B IL2C Jayaraman Townrow Gyton IL5A IL5B IL5C OC2A OC2B OC2C Müller Šebesta Campos Izod Strassner Yamashita OC47A OC47C Rice Lefévre Takebayashi Ballmann Rios 11:30 OC30B OC30C OC30A Tambo- Saßmann- OC15A Urwin OC3A OC3B OC3C OC15B OC15C rnino shausen OC33A OC33B OC33C OC48A OC48B OC48C Scheschke- Williamson Burt van Beek Winter Schaub Pearce Broere Neale Acuňa Horáček Gauld witz OC31A OC31B 12:00 OC4A OC4B OC4C OC16A OC16B OC16C Hinz Colebatch OC34B OC34C OC49A OC49B OC49C Morisako Tubaro Domestici Kirk Reiß Groysman Hill Cirera Bowles Rýček Mirica OC32A OC32B OC32C OC5A OC5B OC5C OC17A OC17B OC17C Vrána Lainer Abbenseth OC35A OC35B OC50A OC50B OC50C 12:30 Warring Malischewski Denker Young Smith Collins Buchner Chadwick Bakas Price Walensky IAB Meeting Awards & Closing 13:00 Lunch Lunch Lunch Lunch 13:30 14:00 4 5
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 Sunday Monday Tuesday Wednesday Thursday Friday July 17, 2022 July 18, 2022 July 19, 2022 July 20, 2022 July 21, 2022 July 22, 2022 14:00 KL3A KL3B KL3C IL1A IL1B IL1C Gilliard Nishibayashi You IL6A IL6B IL6C 14:30 Saito Ogasawara Milani Inoue Sarkar Erb OC6A OC6B OC6C OC18A OC18B OC18C OC36A OC36B OC36C 15:00 F. Garcia Scattolin Hapke Lim Roesky Bara-Estaun Liu Suhr Sorbelli OC37A OC7A OC7B OC7C OC19A OC19B OC19C OC37B OC37C A. F. B. Krempner Munz Hoshimoto Schäfer Donnelly Albéniz Löwe Marchetti Garcia 15:30 OC38C OC8A OC8B OC8C OC20A OC20B OC20C OC38A OC38B Kaluarach- Ellwanger Emslie Stroek Albers Enders Liptrot Lu Martín chige Don 16:00 Coffee break Coffee break Coffee break OC9C OC9A OC9B OC21B OC21C OC39A OC39B OC39C Lin- 16:30 Hicks Tzouras Jagirdar Radius Hreczycho Agrawal Borys ford-Wood OC10A OC10B OC10C OC22A OC22B OC22C OC40A OC40B OC40C Sindlinger Kathuria de Ruiter Jenek Gonell Dixneuf Kalra Termühlen Mita 17:00 OC11A OC41C OC11B OC11C OC23A OC23B OC23C OC41A OC41B Registration Schwedt- Emer- Weber Joshi McManus Magnoux Kim Howley Böhme mann son-King OC12A OC12B OC12C OC24A OC24B OC24C OC42A OC42B OC42C 17:30 Leon-Baeza Bevilacqua Jones W. D. Haas Camp Trzeciak Dostál Schulz Murugavel OC13A OC13B OC13C OC25A OC25B OC25C Groll Nishihara Giri Czernetzki Lapointe Bulko 18:00 OC14A OC14B OC14C OC26A OC26B OC26C Chlupatý Grüner Baszczyňski Sen Hrdina Procházková 18:30 Welcome party Posters A Posters B Speakers’ dinner Conference dinner 6 7
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 DETAILED SCIENTIFIC PROGRAMME 11:30–11:50 OC2B Hall B TAMING REDOX NON-INNOCENCE OF WEAK-FIELD IRON COMPLEXES : AN OPPORTUNITY IN CATALYSIS Monday Monday MONDAY, JULY 18, 2022 Guillaume Lefevre 08:30–09:00 Opening 11:30–11:50 OC2C Hall C IRON-CATALYSED RING OPENING METATHESIS Chairperson: PL1 09:00–09:50 – Petr Štěpnička, Aleš Růžička POLYMERIZATION OF OLEFINS AND MECHANISTIC 09:00–09:50 PL1 Hall A INVESTIGATIONS FRUSTRATED LEWIS PAIRS IN THE REDUCTION OF CO2 AND CO Satoshi Takebayashi Doug Stephan 11:50–12:10 OC3A Hall A 10:00–10:30 Coffee break A RARE REGIOSELECTIVITY: C6 MAGNESIATION OF BULKY Chairperson: KL1A & OC1A- OC5A (10:30–12:40, Panorama Hall A) – INDOLES Tuesday Tuesday Libor Dostál Darcy Williamson KL1B & OC1B- OC5B (10:30–12:40, South Hall 1 – Hall B) – 11:50–12:10 OC3B Hall B Barbara Milani BIMETALLIC HALOCARBYNES, PHOSPHONIOCARBYNES KL1C & OC1C- OC5C (10:30–12:40, South Hall 1 – Hall C) – AND CARBIDOS OF LATE TRANSITION METALS Masamichi Ogasawara Liam K. Burt 10:30–11:10 KL1A Hall A 11:50–12:10 OC3C Hall C CARBENES AS POWERFUL TRANSITION-METAL SURROGATES E-SELECTIVE SEMI-HYDROGENATION OF ALKYNES UNDER Guy Bertrand MILD CONDITIONS BY A DIRUTHENIUM HYDRIDE COMPLEX Wednesday Wednesday 10:30–11:10 KL1B Hall B Cody van Beek SUSTAINABILITY IN GOLD CATALYSIS 12:10–12:30 OC4A Hall A Steven Nolan GENERATION OF A BIPHENYLENE-SUBSTITUTED GERMYLENE 10:30–11:10 KL1C Hall C Shogo Morisako YLIDE-FUNCTIONALIZATION: A POWERFUL TOOL FOR STABILIZING 12:10–12:30 OC4B Hall B REACTIVE MAIN GROUP SPECIES AND CATALYST DESIGN GOLD COMPLEXES WITH PHOSPHONIUM-FUNCTIONALIZED Viktoria Gessner N-HETEROCYCLIC CARBENE LIGANDS 11:10–11:30 OC1A Hall A Cristina Tubaro REVERSIBLE DISSOCIATION OF A DIGALLENE 12:10–12:30 OC4C Hall C Ryan Schwamm Cp*Ir-BASED CATALYSTS FOR THE REDUCTION OF NICOTINAMIDE Thursday Thursday 11:10–11:30 OC1B Hall B AND FLAVIN COFACTORS: APPLICATION TO PROMOTE REDOX-SWITCHABLE CATALYSIS WITH CHEMOENZYMATIC SELECTIVE TRANSFORMATION NAPTHANELENEDIIMIDE DERIVED NHC COMPLEXES Chiara Domestici Macarena Poyatos 12:30–12:50 OC5A Hall A 11:10–11:30 OC1C Hall C SYNTHESIS, STRUCTURE, AND LEWIS ACIDITY DEVELOPMENT OF IRON CATALYST SYSTEMS FOR EFFICIENT OF CARBODICARBENE-STABILIZED STIBENIUM H-E (E = H, Si, Ge, Sn) BOND ACTIVATION AND BISMUTHENIUM IONS Yoshinao Kobayashi Levi Warring 11:30–11:50 OC2A Hall A 12:30–12:50 OC5B Hall B GROUP 13 METATHESIS: A ROUTE TO GROUP 13-ELEMENT Friday Friday THE TENFOLD MERCURATION, BROMINATION AND SILYLATION MULTIPLE BONDS OF FERROCENE Ella Rice Moritz Malischewski 8 9
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 12:30–12:50 OC5C Hall C 15:20–15:40 OC7C Hall C COBALT CATALYZED HYDROSILYLATION OF OLEFINES AMINO MAIN-GROUP CATALYSIS FOR H2 PURIFICATION BASED IMIDAZOLINE-2-IMINES AS LIGANDS IN CATALYSIS ON LIQUID ORGANIC HYDROGEN CARRIERS Monday Monday Lars Denker Yoichi Hoshimoto 12:50–14:30 Lunch break 15:40–16:00 OC8A Hall A Chairperson: IL1A & OC6A–OC8A (14:30–16:00, Panorama Hall A) – JOURNEY TOWARDS A TERMINAL CALCIUM-MONOFLUORIDE Petr Švec COMPLEX AND ITS REACTIVITY IL1B & OC6B–OC8B (14:30–16:00, South Hall 1 – Hall B) – Mathias Ellwanger Jiří Schulz 15:40–16:00 OC8B Hall B IL1C & OC6C–OC8C (14:30–16:00, South Hall 1 – Hall C) – GROUP 3 ALKYL MONOCATIONS AND DICATIONS SUPPORTED Jan Veselý BY RIGID PINCER LIGANDS 14:30–15:00 IL1A Hall A David Emslie Tuesday Tuesday A CHALLENGE TO EXPAND AROMATICITY FROM PI-AROMATICITY 15:40–16:00 OC8C Hall C TO (SIGMA+PI)-DOUBLE AROMATICITY MECHANISTIC INVESTIGATIONS OF THE IRON–CATALYZED Masaichi Saito SYNTHESIS OF PYRROLIDINES BY INTRAMOLECULAR C–H 14:30–15:00 IL1B Hall B AMINATION DIASTEREO- AND ENANTIOSELECTIVE METATHESIS Wowa Stroek DIMERIZATION/KINETIC RESOLUTION OF RACEMIC 16:00–16:30 Coffee break PLANAR-CHIRAL VINYLFERROCENES Chairperson: OC9A–OC14A (16:30–18:30, Panorama Hall A) – Masamichi Ogasawara Thomas Müller Wednesday Wednesday 14:30–15:00 IL1C Hall C OC9B–OC14B (16:30–18:30, South Hall 1 – Hall B) – PALLADIUM CATALYSTS FOR FUNCTIONALIZED POLYOLEFIN Radovan Šebesta SYNTHESIS: TUNABLE INCORPORATION OF POLAR OC9C–OC14C (16:30–18:30, South Hall 1 – Hall C) – MONOMERS THROUGH SECONDARY INTERACTIONS Viktoria Gessner Barbara Milani 16:30–16:50 OC9A Hall A 15:00–15:20 OC6A Hall A NON: AN EXCEPTIONAL LIGAND FOR THE STABILISATION MAIN GROUP MECHANOCHEMISTRY: NEW OPPORTUNITIES OF REACTIVE MAIN GROUP COMPLEXES IN SYNTHETIC CHEMISTRY Jamie Hicks Felipe Garcia 16:30–16:50 OC9B Hall B 15:00–15:20 OC6B Hall B “GOLDEN” SYNTHONS, PRE-CATALYSTS AND MECHANISTIC Thursday Thursday ALLYL AND INDENYL PALLADATES: FROM BONDING PROBES TO ANTICANCER PROPERTIES Nikolaos Tzouras Thomas Scattolin 16:30–16:50 OC9C Hall C 15:00–15:20 OC6C Hall C IRON(II)-(μ-H)2-9-BORABICYCLO[3.3.1]NONANE COMPLEXES: CYCLIZATIONS WITH PNICTOGENS: COBALT-CATALYZED ELUCIDATING INTERMEDIATES IN THE CATALYTIC SYNTHESIS OF PYRIDINES AND PHOSPHININES DEUTERATION OF BORANES AND SILANES Marko Hapke Thomas G. Linford-Wood 15:20–15:40 OC7A Hall A 16:50–17:10 OC10A Hall A SMALL MOLECULE ACTIVATION WITH INTRAMOLECULAR ON THE CHEMISTRY OF 2,5-DISILYLBOROLES Friday Friday FRUSTRATED LEWIS PAIRS Christian Sindlinger Clemens Krempner 15:20–15:40 OC7B Hall B PALLADIUM NITRENES Dominik Munz 10 11
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 16:50–17:10 OC10B Hall B 17:50–18:10 OC13B Hall B SYNTHESIS AND MECHANISTIC STUDY OF N-HETEROCYCLIC NICKEL OR PALLADIUM-CATALYZED DECARBONYLATIVE CARBENE DECORATED RU NANOCATALYSTS FOR TRANSFER TRANSFORMATIONS OF ACYL FLUORIDES Monday Monday HYDROGENTION Yasushi Nishihara Lakshay Kathuria 17:50–18:10 OC13C Hall C 16:50–17:10 OC10C Hall C ALKENE DICARBOFUNCTIONALIZATION: BOND FORMATION BREAKING THROUGH BARRIERS IN CATALYSIS VIA BESPOKE AT CLASSICAL AND NONCLASSICAL SITES LIGAND DESIGN: ONCE CARBON ATOMS MAKES ALL Ramesh Giri THE DIFFERENCE 18:10–18:30 OC14A Hall A Graham de Ruiter FROM GUANIDINATES TO BIGUANIDES – MAIN GROUP METAL 17:10–17:30 OC11A Hall A COMPLEXES CHELATED BY GUANIDINATO VS. BIGUANIDO UNIT FUNCTIONALIZATION OF WHITE PHOSPHORUS Tomáš Chlupatý Tuesday Tuesday TO P4-BUTTERFLY (LC)2P42+ AND REACTIONS 18:10–18:30 OC14B Hall B WITH TRANSITION METALS (LC = NHC) NEW SUBSTITUTIONS ON COBALT BIS(DICARBOLLIDE) ION Kai Schwedtmann WITH POTENTIAL UTILITY AS CHIRAL PLATFOM PLATFORMS 17:10–17:30 OC11B Hall B AND BUILDING BLOCKS MANGANESE(I) COMPLEXES AS EFFICIENT CATALYSTS Bohumír Grüner FOR (HYDRO)BORATION OF ALKENES, ALKYNES AND BEYOND 18:10–18:30 OC14C Hall C Stefan Weber PHOSPHORUS-BASED SELF-IMMOLATIVE LINKERS 17:10–17:30 OC11C Hall C Ondrej Baszczynski Wednesday Wednesday PICOLYL FUNCTIONALIZED-NHC HALF-SANDWICH COMPLEX 18:30 Poster session A OF Ru(II): EFFICIENT CATALYST FOR CHALCOGEN DIRECTED C- H ACTIVATION OF ARENE Raj Kumar Joshi 17:30–17:50 OC12A Hall A REDUCTIVE ELIMINATION AT Pb (II) CENTER OF AN (AMINO) PLUMBYLENE-SUBSTITUTED PHOSPHAKETENE: NEW PATHWAY FOR PHOSPHINIDENE SYNTHESIS José León Baeza 17:30–17:50 OC12B Hall B Thursday Thursday RATIONAL SYNTHETIC APPROACHES TOWARDS NHC STABILIZED MOLECULAR GOLD NANOCLUSTERS Matteo Bevilacqua 17:30–17:50 OC12C Hall C DEVELOPMENT OF NEW FIRST-ROW METAL FOX COMPLEXES FOR ALCOHOL DEHYDRATION William Jones 17:50–18:10 OC13A Hall A CO2 ACTIVATION AND CATALYTIC REDUCTION Friday Friday BY NHI-STABILIZED STANNYLENES – LIGAND INFLUENCES Lisa Groll 12 13
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 11:20–11:50 IL2C Hall C TUESDAY, JULY 19, 2022 FRUSTATED LEWIS PAIRS BASED ON TRANSITION METALS Chairperson: PL2 08:30–09:20 – Michal Horáček Jesus Campos Monday Monday 08:30–09:20 PL2 Hall A 11:50–12:10 OC15A Hall A F-BLOCK DINITROGEN CHEMISTRY; FROM RARITY GRAFTING AND INCORPORATION OF TRANSITION METALS TO CATALYSIS IN THREE LIGAND MODIFICATIONS TO UNSATURATED SILICON CLUSTERS (SILICONOIDS) Polly Arnold David Scheschkewitz Chairperson: KL2A (09:20–10:00, Panorama Hall A) – Michal Horáček 11:50–12:10 OC15B Hall B KL2B (09:20–10:00, South Hall 1 – Hall B) – Heinz Berke VALENCE ISOMERISM IN FERROCENYL-TRITYLIIUM DYADS KL2C (09:20–10:00, South Hall 1 – Hall C) – Martin Kotora Rainer Winter 09:20–10:00 KL2A Hall A 11:50–12:10 OC15C Hall C BIS(SILYLENE) PINCERS TO STABILIZE MONOATOMIC WHAT IS DOING THE CATALYSIS? ON SPECIES FORMED WHEN Tuesday Tuesday ZERO-VALENT HEAVY GROUP 14 METALS (‘TETRYLONES’) USING THE HIGHLY ACTIVE RU-MACHO CATALYST IN ESTER Matthias Driess HYDROGENATIONS AND THE MOVE TO MANGANESE 09:20–10:00 KL2B Hall B Thomas Schaub PHOSPHORUS-FUNCTIONALISED FERROCENE DERIVATIVES 12:10–12:30 OC16A Hall A FOR REDOX-SWITCHABLE CATALYSIS THE ORGANOMETALLIC POTENTIAL OF ARSOLES Evamarie Hey-Hawkins Ryan Kirk 9:20–10:00 KL2C Hall C 12:10–12:30 OC16B Hall B CONTROLLED FUNCTIONALIZATION OF CARBORANES VIA GROUP 4 ALL-C-DEPROTIO-1-METALLACYCLOBUTA-2,3-DIENES; Wednesday Wednesday TRANSITION METAL-CATALYZED B-H ACTIVATION SYNTHESIS, CHARACTERISATION AND REACTIVITY Zuowei Xie Fabian Reiß 10:00–10:30 Coffee break 12:10–12:30 OC16C Hall C Chairperson: PL3 10:30–11:20 – Martin Kotora CATALYTIC SYNTHESIS OF AZOARENE VIA IRON-ALKOXIDE 10:30–11:20 PL3 Hall A MEDIATED NITRENE COUPLING DINICKELAFERROCENE: FERROCENE ANALOGUE WITH TWO Stanislav Groysman AROMATIC NICKELOLES 12:30–12:50 OC17A Hall A Zhenfeng Xi A FRUSTRATED LEWIS PAIR SOLUTION TO A FRUSTRATING Chairperson: IL2A & OC15A- OC17A (11:20-12:50, Panorama Hall A) – PROBLEM: MONO-SELECTIVE FUNCTIONALIZATION OF C–F BONDS IN DI- AND TRIFLUOROMETHYL GROUPS Thursday Thursday Martin Kotora IL2B & OC15B- OC17B (11:20-12:50, South Hall 1 – Hall B) – Rowan D. Young Jitendra Bera 12:30–12:50 OC17B Hall B IL2C & OC15C- O17C (11:20-12:50, South Hall 1 – Hall C) – REVERSIBLE P-P BOND CLEAVAGE OF DIPHOSPHANES Pierre H. DIxneuf Martin Smith 11:20–11:50 IL2A Hall A 12:30–12:50 OC17C Hall C PHOTOCHEMICAL C-C BOND ACTIVATION IN PHOSPHAALKYNES: NEW WEAKLY COORDINATING CHIRAL ANIONS AND THEIR A NEW ROUTE TO TERMINAL CYAPHIDO COMPLEXES LM−CP APPLICATION IN ENANTIOSELECTIVE CATALYSIS Christian Müller Richard Collins 11:20–11:50 IL2B Hall B 12:50–14:20 Lunch break Friday Friday DIASTEREOSELECTIVE PALLADIUM-CATALYZED C-H BOND ACTIVATIONS OF CHIRAL FERROCENE DERIVATIVES Radovan Šebesta 14 15
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 Chairperson: KL3A & OC18A–OC20A (14:20–16:00, Panorama Hall A) – 15:40–16:00 OC20A Hall A Shigeyoshi Inoue UNEXPECTED SILOLE AND GERMOLE COMPLEXES KL3B & OC18B–OC20B (14:20–16:00, South Hall 1 – Hall B) – OF ALUMINIUM Monday Monday Biprajit Sarkar Lena Albers KL3C & OC18C–OC20C (14:20–16:00, South Hall 1 – Hall C) – 15:40–16:00 OC20B Hall B Beatriz Royo SYNTHESIS OF BENT ANSA-DI(BORATABENZENE) METAL 14:20–15:00 KL3A Hall A COMPLEXES BORON-DOPED POLYCYCLIC AROMATICS: FROM REDOX Peter Endres CHEMISTRY TO STIMULI-RESPONSIVE MATERIALS 15:40–16:00 OC20C Hall C Robert Gilliard NHC-SUPPORTED COPPER(I) MAIN GROUP COMPLEXES 14:20–15:00 KL3B Hall B FOR SYNTHESIS AND CATALYSIS MOLYBDENUM-CATALYZED REDUCTION OF MOLECULAR David Liptrot Tuesday Tuesday DINITROGEN INTO AMMONIA UNDER AMBIENT CONDITIONS 16:00–16:30 Coffee break Yoshiaki Nishibayashi Chairperson: OC21A–OC26A (16:30–18:30, Panorama Hall A) – 14:20–15:00 KL3C Hall C Christian Müller RECENT PROGRESS ON CATALYTIC ASYMMETRIC OC21B–OC26B (16:30–18:30, South Hall 1 – Hall B) – DEAROMATIZATION REACTIONS Makoto Yamashita Shu-Li You OC21C–OC26C (16:30–18:30, South Hall 1 – Hall C) – 15:00–15:20 OC18A Hall A Evamaria Hey-Hawkins SYNTHESIS AND CHARACTERISATION OF LOW OXIDATION 16:30–16:50 OC21B Hall B Wednesday Wednesday STATE GROUP 14 RADICALS DIHYDROGEN VERSUS DIHYDRIDE EQUILIBRIUM Li Feng Lim IN AN IRIDIUM PINCER COMPLEX 15:00–15:20 OC18B Hall B Balaji Rao Jagirdar SELECTIVE FORMATION OF COINAGE METAL STRING 16:30–16:50 OC21C Hall B COMPLEXES USING ORTHOGONAL LIGAND SCAFFOLDS PREPARING (MULTI)FLUOROARENES AS BUILDING BLOCKS Peter Roesky FOR SYNTHESIS: NICKEL-CATALYZED BORYLATION 15:00–15:20 OC18C Hall C OF POLYFLUOROARENES VIA C-F BOND CLEAVAGE MAPPING CATALYST ACTIVATION, TURNOVER SPECIATION Udo Radius AND DEACTIVATION IN Rh/PPh3-CATALYSED OLEFIN 16:50–17:10 OC22A Hall A HYDROFORMYLATION VARIABLE AND EFFICIENT SYNTHESIS OF NEW Thursday Thursday Alejandro Bara Estaun TETRA-SUBSTITUTED PENTALENIDE LIGANDS 15:20–15:40 OC19A Hall A Niko Jenek PROPERTIES AND COORDINATION CHEMISTRY 16:50–17:10 OC22B Hall B OF TETRELOCENES AND RELATED HALF-SANDWICH TETRYLENES STRUCTURE-FUCTION STUDIES ON RU AND FE André Schäfer CARBENE-SUPPORTED COMPLEXES FOR CO2 15:20–15:40 OC19B Hall B ELECTROREDUCTION INVESTIGATING FORMIC ACID DECOMPOSITION PATHWAYS Sergio Gonell WITH RUTHENIUM PCCARBENEP HYDRIDES 16:50–17:10 OC22C Hall C Laurie Donnelly CATALYTIC C-H BOND FUNCTIONALIZATIONS OF PHOSPHINES Friday Friday 15:20–15:40 OC19C Hall C TO IMPROVE CATALYSTS FACILE C-C CLEAVAGE IN A NI-NORBORNYL INTERMEDIATE: Pierre H. Dixneuf A NEW POLYNORBORNENE BY COMBINATION OF VINYLIC ADDITION AND RING OPENING ENABLED BY A Ni CATALYST Ana Albéniz 16 17
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 17:10–17:30 OC23A Hall A 18:10–18:30 OC26B Hall B INSERTION OF INTERNAL ALKYNES INTO AN ALUMINIUM – BIFUNCTIONAL DIRHODIUM(II,II) PADDLEWHEEL COMPLEXES COPPER BOND FOR SELECTIVE AMINATION REACTIONS Monday Monday Caitilín McManus Radim Hrdina 17:10–17:30 OC23B Hall B 18:10–18:30 OC26C Hall C SYNTHESIS OF 3D TRANSITION METAL(II) BIS-PHOSPHOLYL STEREOCHEMICAL ANALYSIS OF PHOSPHORUS-CONTAINING COMPLEXES AND REDUCTION TO PHOSPHAMETALLOCENE COMPOUNDS ANIONS Eliška Procházková Corentin Magnoux 18:30 Poster session B 17:10–17:30 OC23C Hall C COBATLT-CATALYZED C–H ALKENYLATION AND ALLYLATION WITH CYCLOPROPENES VIA SEQUENTIAL C–H/C–C BOND Tuesday Tuesday ACTIVATION Yelim Kim 17:30–17:50 OC24A Hall A RECENT ADVANCES IN THE CHEMISTRY OF ACYLGERMANES Michael Haas 17:30–17:50 OC24B Hall B COOPERATIVE REACTIVITY AT POLARIZED HETEROBIMETALLIC PAIRS Wednesday Wednesday Clément Camp 17:30–17:50 OC24C Hall C PALLADIUM-CATALYZED HYDROGENATION OF CHLORONITROBENZENES TO CYCLOHEXANONE IN WATER Anna Trzeciak 17:50–18:10 OC25A Hall A SYNTHESIS AND REACTIVITY OF A NEUTRAL BERYLLIUM(I) RADICAL Corinna Czernetzki 17:50–18:10 OC25B Hall B Thursday Thursday EXPLORING THE CHEMISTRY OF NOVEL PHOSPHOROUS YLIDE AND THEIR RHODIUM COMPLEXES Sébastien Lapointe 17:50–18:10 OC25C Hall C STERIC AND ELECTRONIC EFFECT OF SUBSTITUTED PHENYLBORONIC ACIDS ON DERACEMIZATIVE ARYLATION OF BINAPHTHYL MOIETY BY SUZUKI CROSS-COUPLING. Filip Bulko 18:10–18:30 OC26A Hall A Friday Friday DICOORDINATE STIBENIUM CATION AS EFFICIENT CYANOSILYLATION CATALYST Nilanjana Sen 18 19
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 Chairperson: IL4A & OC28A–OC32A (10:30–12:40, Panorama Hall A) – WEDNESDAY, JULY 20, 2022 Robert Mulvey Chariperson: KL4A, IL3A & OC27A (08:30–10:00, Panorama Hall A) – IL4B & OC28B–OC32B (10:30–12:40, South Hall 1 – Hall B) – Monday Monday Ekkehardt Hahn Matthias Driess KL4B, IL3B & OC27B (08:30–10:00, South Hall 1 – Hall B) – IL4C & OC28C–O32C (10:30–12:40, South Hall 1 – Hall C) – Rudolf Pietschnig Thomas Strassner KL4C, IL3C & OC27C (08:30–10:00, South Hall 1 – Hall C) – 10:30–11:00 IL4A Hall A Sjoerd Harder CHEMISTRY OF NITRENIUM IONS 08:30–09:10 KL4A Hall A Mark Gandelman BESPOKE BIMETALLICS FOR CHEMICAL COOPERATIVITY 10:30–11:00 IL4B Hall B Eva Hevia METALLOSUPRAMOLECULAR ASSEMBLIES FROM POLY-NHC 08:30–09:10 KL4B Hall B LIGANDS Tuesday Tuesday ORGANOMETALLIC STRATEGIES FOR BIOCONJUGATION Ekkehardt Hahn Alexander Spokoyny 10:30–11:00 IL4C Hall C 08:30–09:10 KL4C Hall C THE IMPACT OF MESOIONIC AND N-HETEROCYCLIC CARBENE NEW HORIZONS IN LOW-VALENT ALKALINE-EARTH METAL LIGANDS IN MANGANESE CATALYSIS CHEMISTRY Beatriz Royo Sjoerd Harder 11:00–11:20 OC28A Hall A 09:10–09:40 IL3A Hall A SYNTHESIS AND REACTIVITY OF NOVEL FUNCTIONALIZED TETRAAMINOCYCLOPENTADIENONE IRON COMPLEXES 1,2-AZABORININES Wednesday Wednesday AS HYDROGENATION CATALYSTS Anna Lamprecht Matthias Tamm 11:00–11:20 OC28B Hall B 09:10–09:40 IL3B Hall B SYNTHESIS AND REACTIVITY OF TITANIUM PINCER SYNTHETIC APPLICATIONS OF CATIONIC PHOSPHINES COMPLEXES Manuel Alcarazo Leah Webster 09:10–09:40 IL3C Hall C 11:00–11:20 OC28C Hall C ABOUT SUPERBASIC PHOSPHINES AND HOW THEY CAN BE DEOXYGENATION CATALYSIS USING HIGH-VALENT USED TO GENERATE NEW CARBENES MOLYBDENUM NHC AND MIC COMPLEXES Fabian Dielmann Stephan Hohloch 09:40–10:00 OC27A Hall A 11:20–11:40 OC29A Hall A Thursday Thursday SILOLES AND GERMOLE DIANIONS AS PRECURSORS BASE-STABILIZED DIBORENES: SYNTHESIS AND REACTIVITY FOR UNUSUAL MAIN GROUP COMPOUNDS WITH SMALL MOLECULES Thomas Müller Arumugam Jayaraman 09:40–10:00 OC27B Hall B 11:20–11:40 OC29B Hall B NEUTRAL DIBORAACENES: HARNESSING THE POWER ZINTL CLUSTERS, MULTIFUNCTIONAL LIGANDS OF COOPERATING, SPATIALLY-SEPARATED SUBVALENT FOR HOMOGENEOUS CATALYSTS BORON ATOMS Oliver Townrow Maximilian Dietz 11:20–11:40 OC29C Hall C 09:40–10:00 OC27C Hall C HYPERPOLARISATION OF LIGHT HYDROCARBON SUBSTRATES Friday Friday AN AIR-STABLE, EASY TO ASSEMBLE, CATALYST FOR SELECTIVE THROUGH SOLID-STATE MOLECULAR ORGANOMETALLIC AMINE-BORANE DEHYDROPOLYMERISATION: MECHANISM, (SMOM) CATALYSIS CHAIN CONTROL AND ON-SCALE POLYMER PRODUCTION Matthew Gyton Claire Brodie 10:00–10:30 Coffee break 20 21
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 11:40–12:00 OC30A Hall A ON CYAPHIDE AND ISOCYAPHIDE THURSDAY, JULY 21, 2022 Stephanie Urwin Chairperson: PL4 08:30–09:20 – Jan Čermák Monday Monday 11:40–12:00 OC30B Hall B 08:30–09:20 PL4 Hall A CONSTITUTIONAL AND CONFORMATIONAL ISOMERISM LATE TRANSITIONMETAL CATALYSTS FOR POLYMER SYNTHESIS IN CARBONYL PSEUDOHALIDES AND DEGRADATION Frank Tambornino Kyoko Nozaki 11:40–12:00 OC30C Hall C Chairperson: KL5A (09:20–10:00, Panorama Hall A) – Viktoria Gessner Ru-H BOND ACTIVATION BY MEANS OF X-RAY RADIATION KL5B (09:20–10:00, South Hall 1 – Hall B) – Matthias Tamm Jörg Saßmannshausen KL5C (09:20–10:00, South Hall 1 – Hall C) – William Jones 12:00–12:20 OC31A Hall A 09:20–10:00 KL5A Hall A A MONODENTATE CARBAZOLE AS LIGAND SCAFFOLD HALF-SANDWICH IRIDIUM(III) COMPLEXES WITH CYTOTOXIC Tuesday Tuesday FOR ALKALINE EARTH METAL COMPLEXES PROPERTIES: SYNTHESIS, BIOLOGICAL STUDIES AND CELL Alexander Hinz IMAGING 12:00–12:20 OC31B Hall B Michele Salmain DESIGNING FOR COOPERATIVITY: BIMETALLIC COMPLEXES 09:20–10:00 KL5B Hall B OF 1,8-NAPHTHYRIDINE LIGANDS GOLD CHEMISTRY UNDER LIGAND CONTROL Annie Colebatch Didier Bourissou 12:20–12:40 OC32A Hall A 09:20–10:00 KL5C Hall C SYNTHESIS OF CATIONIC HETEROBORANES PUTTING ON WEIGHT: HEAVY ALKALI METAL MEDIATION Wednesday Wednesday Jan Vrána IN SYNTHESIS AND CATALYSIS 12:20–12:40 OC32B Hall B Robert Mulvey NEW SINGLE-SOURCE PRECURSORS FOR THIN-FILM 10:00–10:30 Coffee break DEPOSITION Chairperson: PL5 10:30–11:20 – Robert Gilliard Thomas Lainer 10:30–11:20 PL5 Hall A 12:20–12:40 OC32C Hall C ACTIVATION OF SMALL MOLECULES: CAN BORON ACT SMALL MOLECULE ACTIVATION AND PROTON COUPLED AS A TRANSITION METAL? ELECTRON TRANSFER WITH A Ta(V) COMPLEX LIGATED Holger Braunschweig BY A REDOX ACTIVE NNN PINCER LIGAND Chairperson: IL5A & OC33A–OC35A (11:20–12:50, Panorama Hall A) – Josh Abbenseth Thursday Thursday Robert Gilliard 12:40–14:20 Lunch break IL5B & OC33B–OC35B (10:30–12:50, South Hall 1 – Hall B) – 13:00–15:00 IAB Meeting Bohumír Grüner 18:30 Speakers’ dinner IL5C & OC33C–O35C (10:30–12:50, South Hall 1 – Hall C) – Milan Pour 11:20–11:50 IL5A Hall A HEAVIER MAIN GROUP CARBENE AND ALKENE ANALOGUES SUPPORTED BY PHOSPHANYL LIGANDS – UNEXPECTED TWISTS AND TURNS Keith Izod Friday Friday 11:20–11:50 IL5B Hall B PHOSPHORESCENT PLATINUM(II) AND IRIDIUM C^C* COMPLEXES – TUNING THE EXCITED STATE Thomas Strassner 22 23
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 11:20–11:50 IL5C Hall C 14:30–15:00 IL6B Hall B CHARACTERISTIC REACTIVITY OF GROUP 13 ELEMENT A TALE OF TWO DEPROTONATION REACTIONS: UNUSUAL COMPOUNDS: DIBORANE(4) AND Al-ANION REACTIVITY IN MESOIONIC CARBENE BASED METAL Monday Monday Makoto Yamashita COMPLEXES 11:50–12:10 OC33A Hall A Biprajit Sarkar UNCATALYSED PREPARATION OF BIARYLS VIA MOLECULAR 14:30–15:00 IL6C Hall C CALCIUM PHENYLS ORIGINAL POLYSUBSTITUTED FERROCENE DERIVATIVES Kyle Pearce BASED ON THE USE OF SULFUR-BASED DIRECTING GROUPS 11:50–12:10 OC33B Hall B William Erb COMBINING METAL-METAL AND METAL-LIGAND 15:00–15:20 OC36A Hall A COOPERATIVITY USING ‘EXPANDED PINCER’ LIGANDS COOPERATIVE REACTIVITIES OF {Mg2Na2} UNIT ON A FLEXIBLE Daniël L J Broere DIAMIDO-BACKBONE Tuesday Tuesday 11:50–12:10 OC33C Hall C Han-Ying Liu THE ELECTRONIC STRUCTURE AND REDUCTIVE REACTIVITY 15:00–15:20 OC36B Hall B OF A Mg(I)2Na(I)2 HETEROBIMETALLIC COMPLEX DIAMIDOBENZENE COMPLEXES OF [CP*RH(III)] OFFER Samuel Neale ACCESS TO NOVEL SPECIES IN ORGANOMETALLIC RHODIUM 12:10–12:30 OC34B Hall B CHEMISTRY ISOLATION AND REACTIVITY OF BENT CARBIDO COMPLEXES Simon Suhr Anthony Hill 15:00–15:20 OC36C Hall C 12:10–12:30 OC34C Hall C SO SIMILAR YET SO DIFFERENT: INSIGHTS ON THE ELECTRONIC Wednesday Wednesday TUNING THE SPIN-CROSSOVER PROPERTIES IN METALLOCENE PROPERTIES AND REACTIVITY OF ALUMINYLS AND CARBENES COMPLEXES: A COMPUTATIONAL STUDY AS LIGANDS TO GOLD Jordi Cirera Diego Sorbelli 12:30–12:50 OC35A Hall A 15:20–15:40 OC37A Hall A DIPHENYLBERYLLIUM: STRUCTURE, PROPERTIES SYNERGYSTIC MAIN GROUP CATALYSIS; COOPERATIVE AND REACTIVITY ALUMINIUM/BORON CATALYSIS FOR ALKENE Magnus Buchner HYDROBORATION 12:30–12:50 OC35B Hall B Alexander F. Beaton Garcia EARLY TRANSITION METAL PINCER COMPLEXES 15:20–15:40 OC37B Hall B WITH PHOSPHORUS CONTAINING LIGANDS CRYSTALLINE PHOSPHINO(SILYL)CARBENES AS LIGANDS Thursday Thursday F. Mark Chadwick FOR TRANSITION METAL COMPLEXES 12:50–14:30 Lunch break Pawel Löwe Chairperson: IL6A & OC36A–OC38A (14:30–16:00, Panorama Hall A) – 15:20–15:40 OC37C Hall C Didier Bourissou FUNCTIONALIZED HYDROCARBYL LIGANDS FROM IL6B & OC36B–OC38B (14:30–16:00, South Hall 1 – Hall B) – THE ASSEMBLY OF MOLECULAR UNITS IN DIIRON COMPLEXES Alexander Hinz Fabio Marchetti IL6C & OC36C–O38C (14:30–16:00, South Hall 1 – Hall C) – 15:40–16:00 OC38A Hall A Clemens Krempner UNRAVELLING GROUP-1 METAL COMPLEX AGGREGATES 14:30–15:00 IL6A Hall A USING NEUTRAL MULTIDENTATE LIGANDS Friday Friday CARBON MONOXIDE ACTIVATION BY SILYLENES Erli Lu AND DISILENES Shigeyoshi Inoue 24 25
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 15:40–16:00 OC38B Hall B 17:10–17:30 OC41A Hall A FIRST EXAMPLE OF CATALYTIC RHODIUM TO GOLD(III) AIR- AND MOISTURE-STABLE PHOSPHORUS PRECURSORS TRANSMETALATION: A DE NOVO ENTRY TO CYCLOMETALATED TO INDIUM PHOSPHIDE QUANTUM DOTS Monday Monday GOLD(III) COMPLEXES Jack Howley Jaime Martín 17:10–17:30 OC41B Hall B 15:40–16:00 OC38C Hall C REGIOSELECTIVE METALATION OF BIS-NHC PRECURSORS DEVELOPMENT OF COOPERATIVE HETEROBIMETALLIC Matthias Böhme SYSTEMS FOR CO OXIDATION 17:10–17:30 OC41C Hall C Umesh Kaluarachchige Don MAGNETIC PROPERTIES AND UNUSUAL REACTIVITY 16:00–16:30 Coffee break OF LANTHANIDE(III) SILYLAMIDE COMPLEXES APPROACHING Chairperson: OC39A–OC42A (16:30–17:50, Panorama Hall A) – A LINEAR COORDINATION ENVIRONMENT Manfred Scheer Jack Emerson-King Tuesday Tuesday OC39B–OC42B (16:30–17:50, South Hall 1 – Hall B) – 17:30–17:50 OC42A Hall A Keith Izod BEYOND THE HETERO-DIELS-ALDER REACTION. NEW OC39C–OC42C (16:30–17:50, South Hall 1 – Hall C) – HORIZONTS IN REACTIVITY OF HEAVIER PNICTINIDENES Ivana Fleischer WITH UNSATURATED MOLECULES 16:30–16:50 OC39A Hall A Libor Dostál NEW EFFECTIVE AND SUSTAINABLE METHODOLOGIES 17:30–17:50 OC42B Hall B FOR THE SYNTHESIS OF ORGANOMETALLOIDAL COMPOUNDS SYNTHESIS OF DEFINED MULTIMETALLIC ARRAYS Grzegorz Hreczycho BY METALLATION OF A GOLD(I) METALLOLIGAND Wednesday Wednesday 16:30–16:50 OC39B Hall B WITH P,C-BRIDGING PHOSPHINOFERROCENYL GROUPS DUAL ROUTES TOWARDS OBSERVATION OF TRANS-H2/ Jiří Schulz HYDRIDE COMPLEX IN AN IRIDIUM PINCER SYSTEM AND ITS 17:30–17:50 OC42C Hall C HYDROGENATION CATALYTIC ACTIVITY CONTROLLING DIMENSIONALITY OF METAL PHOSPHATE Nisha Kumari Agrawal FRAMEWORKS: A CHEMICAL SYNTHESIS APPROACH TO NEW 16:30–16:50 OC39C Hall C MATERIALS ALKALI-METAL NICKELATES: SYNTHESIS, STRUCTURE Ramaswamy Murugavel AND CATALYTIC APPLICATIONS 19:00 Conference Dinner Andryj Borys 16:50–17:10 OC40A Hall A Thursday Thursday A PINCER-TYPE BIS(SILYLENE) MANGANESE COMPLEX WITH REMARKABLE REACTIVITY MIMICKING THE [Mn(CO)5] RADICAL Shweta Kalra 16:50–17:10 OC40B Hall B COMPLEXES BEARING N-ALKYLATED, ANIONIC OR PROTIC CAACS THROUGH OXIDATIVE ADDITION Sebastian Termühlen 16:50–17:10 OC40C Hall C Friday Friday SYNTHESIS OF UNSYMMETRIC DPPE DERIVATIVES FROM ETHYLENE: PHYSICAL PROPERTIES AND CATALYTIC ACTIVITIES OF THEIR METAL COMPLEXES Tsuyoshi Mita 26 27
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 09:20–10:00 KL6C Hall C FRIDAY, JULY 22, 2022 MECHANOCHEMICAL SYNTHESIS OF ORGANOMETALLIC Chairperson: KL6A, IL7A & OC43A (08:30–10:00, Panorama Hall A) – COMPOUNDS AND CROSS-COUPLING REACTIONS Monday Monday Michele Salmain Hajime Ito KL6B, IL7B & OC43B (08:30–10:00, South Hall 1 – Hall B) – 10:00–10:30 Coffee break Mark Gandelman Chairperson: OC44A–OC50A (10:30–12:50, Panorama Hall A) – KL6C, IL7C & OC43C (08:30–10:00, South Hall 1 – Hall C) – Jiří Pinkas Fabian Dielmann OC44B–OC50B (10:30–12:50, South Hall 1 – Hall B) – 08:30–08:50 OC43A Hall A Thomas Schaub A NOVEL E-H BOND ACTIVATION, E-RADICAL TRANSFER OC44C–OC50C (10:30–12:50, South Hall 1 – Hall C) – AND E-E COUPLING REACTION USING TELLURIUM-NITROGEN Manfred Scheer BOND-CONTAINING LEWIS SUPERACID 10:30–10:50 OC44A Hall A Tuesday Tuesday Martin Hejda FRONTIERS IN MODERN BERYLLIUM CHEMISTRY: 08:30–08:50 OC43B Hall B HYDROBERYLLATION AND TRANSIENT LOW-VALENT SPECIES CYCLOBUTADIENYL REAGENTS IN ORGANOACTINIDE Terrance Hadlington CHEMISTRY 10:30–10:50 OC44B Hall B Josef Boronski DISENTANGLING EXCITED STATES OF REACTIVE 08:30–08:50 OC43C Hall C NICKEL-BIPYRIDINE PHOTOREDOX CATALYSTS FROM NOVEL HETEROMETALLIC PRECURSORS TO LITHIUM Daniel Bím DOPED ZINC OXIDE NANOCRYSTALS 10:30–10:50 OC44C Hall C Wednesday Wednesday Maria Jędrzejewska MANAGING THE MOLECULAR AND SUPRAMOLECULAR 08:50–09:20 IL7A Hall A STRUCTURE OF ORGANOALUMINUM CARBOXYLATES BOND ACTIVATION IN STEREOCHEMICALLY DEFINED BY TUNING THE SECONDARY COORDINATION SPHERE PHOSPHA-FERROCENOPHANES AND RELATED FERROCENE Michał Terlecki COMPOUNDS 10:50–11:10 OC45A Hall A Rudolf Pietschnig Si(II) SPECIES STABILIZED BY s-DONATING Ni(0) FRAGMENT 08:50–09:20 IL7B Hall B Shintaro Takahashi DESIGNER LIGAND SCAFFOLDS FOR METAL-LIGAND 10:50–11:10 OC45B Hall B COOPERATIVE CATALYSIS REVISITING N2 FUNCTIONALIZATION WITH NUCLEOPHILES Jitendra Bera Antoine Simonneau Thursday Thursday 08:50–09:20 IL7C Hall C 10:50–11:10 OC45C Hall C CATALYTIC MAKING AND BRAKING OF C-S BONDS A CRYSTALLINE CYCLIC ALKYL(AMINO)CARBENE Ivana Fleischer WITH A 1,1’-FERROCENYLENE BACKBONE 09:20–10:00 KL6A Hall A Julia Volk PENTAPHOSPHAFERROCENE – A VERSATILE BUILDING BLOCK 11:10–11:30 OC46A Hall A Manfred Scheer BARE BARIUM CATALYSIS: FROM OLD IDEAS TO NEW 09:20–10:00 KL6B Hall B HYDROGENATION CONCEPTS HIGHLY ACTIVE RUTHENIUM OLEFIN METATHESIS CATALYSTS Christian Färber ENABLING RING-OPENING METATHESIS POLYMERIZATION 11:10–11:30 OC46B Hall B Friday Friday OF LOW-STRAINED CYCLIC OLEFINS TOWARDS CATALYSIS WITH BIMETALLIC TRANSITION METAL Soon Hyeok Hong ‘EXPANDED PINCER’ COMPLEXES Michael Stevens 28 29
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 11:10–11:30 OC46C Hall C 12:30–12:50 OC50A Hall A REVERSIBLE MULTI-ELECTRON RELEASE FROM REDOX-ACTIVE TMEDA-IRON ADDUCT REACTION MANIFOLD TWO- TO THREE-DIMENSIONAL MOLECULAR ASSEMBLIES IN IRON-CATALYZED C(SP2)-C(SP3) CROSS-COUPLING Monday Monday WITH RUTHENIUM-ALKENYL MOIETIES REACTIONS Rajorshi Das Nikki Bakas 11:30–11:50 OC47A Hall A 12:30–12:50 OC50B Hall B SYNTHESIS, STRUCTURE AND REACTIVITY OF RUBIDIUM MANGANESE GERMYLENE COMPLEXES: SYNTHESIS AND CAESIUM ALUMINIUM HYDRIDES MADE FROM THEIR AND REACTIVITY PARENT ALUMINYLS Jeffrey Price Gerd Ballmann 12:30–12:50 OC50C Hall C 11:30–11:50 OC47C Hall C SMALL MOLECULE ACTIVATION WITH URANIUM(III) SYNTHESIS OF ROBUST DICOPPER(I) μ-BORYL COMPLEXES: COMPLEXES Tuesday Tuesday STRUCTURAL AND REACTIVITY STUDIES Justin Walensky Pablo Rios 11:50–12:10 OC48A Hall A TIN, GERMANIUM AND ALUMINUM COMPOUNDS STABILIZED BY BIS-AMIDINATE LIGANDS WITH A RIGID NAPHTHALENE BACKBONE Alejandra Acuña 11:50–12:10 OC48B Hall B Wednesday Wednesday CATALYTIC UTILIZATION OF A SYSTEM COMPRISING HYDROSILANE, B(C6F5)3, AND TRANSITION METAL COMPLEX Michal Horáček 11:50–12:10 OC48C Hall C UNDER PRESSURE: AN EXPLORATION OF THE EFFECTS OF HIGH PRESSURE ON ORGANOMETALLIC AGGRGATION IN SOLUTION Richard Gauld 12:10–12:30 OC49A Hall A A BLUEPRINT FOR THE SYNTHESIS OF LOW-VALENT ALKALINE Thursday Thursday EARTH METAL COMPLEXES Alex Bowles 12:10–12:30 OC49B Hall B SYNTHESIS AND APPLICATION OF NEW COMPLEXES OF SILVER WITH N-HETEROCYCLIC CARBENE LIGANDS Lukáš Rýček 12:10–12:30 OC49C Hall C A RADICAL APPROACH: PARAMAGNETIC Ni AND Pd COMPLEXES IN ORGANOMETALLIC CATALYSIS Friday Friday Liviu Mirica 30 31
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 LIST OF POSTERS P015A GRAFTING OF A SILICONOID TO A SILSESQUIOXANE AS A POTENTIAL MODEL SYSTEM FOR SILICON MONOXIDE Marc Hunsicker P001A SMALL STRAINED SILYL PHOSPHONIUM IONS Alexander Falk P016A INVESTIGATIONS INTO A FLEXIBLE N-O-N CHELATING LIGAND IN THE STABILISATION OF LOW-OXIDATION STATE GROUP 13 P002A SYNTHESIS OF GENUINE GERMENYL LITHIUMS AND THE FIRST COMPOUNDS PERSISTENT GERMENYL RADICALS Emily Nahon Yuri Glagovsky P017A DERIVATIVES OF 2,5-SILYL SUBSTITUTED BOROLES P003A SYNTHESIS OF N-HETEROCYCLIC CARBENE STABILISED GROUP 13 Tobias Heitkemper HALIDES AND HYDRIDES Fáinché Murphy P018A SYNTHESIS AND REACTIVITY OF A HOMOLEPTIC MAGNESIUM BIS ALUMINYL COMPOUND P004A PREPARATION AND CHARACTERIZATION OD TIN(II) AND Liam Griffin GERMANIUM(II) AMIDES BEARING BULKY BIS(AMIDO)SILYL LIGAND Petr Leinweber P019A METATHESIS POLYMERISATION OF DIGERMENES Anna-Lena Thömmes P005A ABOUT THE SYNTHESIS OF PLANAR-CHIRAL 1,1‘-DIAMINOFERROCENES AND THE REACTIVITY OF CORRESPONDING P020A BEYOND BCF: EXPLORING REACTIVITY BY TUNING ACIDITY TETRYLENES IN XANTHENE BASED FRUSTRATED LEWIS PAIRS Robin Guthardt Aisling Roper P006A MOLECULAR HETEROCYCLIC SILICOMETALLOPHOSPHATE MODELS P021A A REVIVAL MECHANISM OF FRUSTRATED LEWIS PAIR FROM CARBENE– Robin Rothfelder BORANE COMPLEX VIA PHOSPHINE OXIDE–BORANE COMPLEX Mahiro Sakuraba P007A TUNING INCLUSION CRYSTAL SELF-ASSEMBLY BY METAL SWITCHING IN CINCHONINE ALKALOID ORGANOMETALLICS P022A TARGETING AN ACYCLIC ALUMINYL ANION Maximilian Rajski Aidan Matthews P008A SUPERCHARGED CARBON AS SUPERELECTROPHILE P023A PHOSPHANYL-SUBSTITUTED CYCLOPENTADIENYL COMPOUNDS Florian Mulks OF MAIN GROUP ELEMENTS Carsten Müller P009A STRUCTURAL OVERVIEW OF MONODEPROTONATED GUANIDINE COORDINATION VERSATILITY TO MAIN GROUP ELEMENTS P024A FACILE SYNTHESIS OF A GERMACUBANE WITH TWO Ge(0) ATOMS Natália Gira AND ITS RADICAL ANION Roman Bashkurov P010A BENZENE COUPLING AND SOLVENT-FREE BIRCH-TYPE REDUCTION DRIVEN BY A MECHANOCHEMICAL SYNTHESISED ELECTRIDE P025A A PHOSPHABORENE TRANSFER REAGENT Nathan Davison Abhishek Koner P011A ANSA-HALF-SANDWICH COMPLEXES OF GROUP 14 ELEMENTS P026A SILA- AND GERMACYCLOPENTADIENEDIIDES AND THEIR REACTION Inga Bischoff WITH GROUP 13 HALIDES Lukas Bührmann P012A AIR AND MOISTURE TOLERANT HYDROAMINATION REACTIONS USING ALKALI-METAL AMIDES AS CATALYSTS P027A DEVELOPMENT OF REDOX-ACTIVE DIBORON CONTAINING Sophia Belrhomari N-HETEROCYCLIC LIGANDS FOR TRANSITION METAL COMPLEXES Hiroto Hayashi P013A SYNTHESIS AND REACTIVITY OF HEAVIER ALUMINIUM CHALCOGENIDES Huihui Xu P028A RPOSS CAGES AND AZIDO-FUNCTIONALIZED AROMATIC PHOSPHONATE ESTERS IN LANTHANIDE ION COORDINATION P014A 18F-LABELLING OF DIFLUORO- AND TRIFLUOROMETHYL GROUPS Ingo Köhne VIA SELECTIVE C-F ACTIVATION; TOWARDS THE SYNTHESIS OF NEW RADIOTRACERS FROM OFF-THE-SHELF DRUGS P029A SYNTHESIS AND REACTIVITY OF BIS(SIGMA)BORATE AND BRIDGING Kenneth Lye BORYL COMPLEXES OF RUTHENIUM: HYDROBORATION OF ALKYNES Urminder Kaur 32 33
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 P030A INVESTIGATION OF BERYLLIUM-CARBON BONDING P065A DINUCLEAR COMPLEXES OF THE HIEBER ANION VIA BRIDGED WITH A SCORPIONATE SYSTEM N-HETEROCYCLIC PHOSPHOLENIUMIONS Chantsalmaa Berthold Carlo Sibold P031A SIMPLE MULTIGRAM SYNTHESIS OF SECONDARY PHOSPHINES P066A NON-PALINDROMIC RHODIUM PCCARBENEP PINCER COMPLEXES FOR USE IN NOVEL TRIPODAL LIGANDS Clarence Tan Amanda Fogh P067A ASYMMETRICALLY SUBSTITUTED PHOSPHOLES AS LIGANDS P032A EXPLOITING THE BRØNSTED BASICITY OF BERYLLIUM-CARBON BONDS FOR COINAGE METAL COMPLEXES Lewis Thomas-Hargreaves Fabian Roesler P033A SYNTHESIS AND REACTIVITY OF PHOSPHA-STANNENES AND GERMENES P068A ION PAIRING IN GOLD(I)/W(IV) HETEROBIMETALLIC DIHYDRIDES Matthew Reveley Martina Landrini P034A BEYOND THE SQUARATE DIANION: HIGHLY REDUCED LINEAR P069A N-HETEROCYCLIC PHOSPENIUM IONS: A NOBLE ADDENDUM CC CHAINS, [C4O4]N- (N = 4, 6) AND [C6O6]4-, FROM THE TO A BASE METAL ALUMINYLMEDIATED HOMOLOGATION OF CO Nicholas Birchall Andreas Heilmann P070A GROUP 6 CARBONYL COMPLEXES WITH A PYRIDYL-MESOIONIC P035A COMPLEXES AND REACTIONS OF FERROCENE DISTIBINE LIGAND CARBENE LIGAND: STRUCTURAL, (SPECTRO)ELECTROCHEMICAL, Jakub Antala PHOTOCHEMICAL AND THEORETICAL INVESTIGATIONS P036A SYNTHESIS AND CHARACTERIZATION OF NOVEL BISACYLDISILANES Tobias Bens AND -DIGERMANES – EVALUATION OF THEIR PHOTOCHEMISTRY P071A REACTIVITY STUDIES OF [RuH(CO)PNiPrPPh]BAr4F COMPLEX Tanja Wiesner (BAr4F = B[3,5-(CF3)2C6H3]4) WITH SMALL MOLECULES P037A REACTIVITY OF N-COORDINATED ORGANOGERMANIUM HYDRIDE Kamla Devi Netam Dominik Vítek P072A HYDRAZINOFERROCENE: A SIMPLE MOLECULE WITH STRONG P038A FUNCTIONALIZATION OF SILICONOIDS SYNTHETIC POTENTIAL Luisa Giarrana Milan Erben P039A C,N-CHELATED ORGANOTIN(IV) SPECIES AS TRIFLUOROMETHYLATION P073A CLIPPANE: A MECHANICALLY INTERLOCKED MOLECULE (MIM) BASED AGENTS ON MOLECULAR TWEEZERS Petr Švec Susana Ibáñez Maella P040A GALLANDIYL SUBSTITUTED TETRYLENES AND THEIR REACTIVITY P074A ROOM-TEMPERATURE REVERSIBLE CHEMISORPTION OF CARBON TOWARD SMALL MOLECULES MONOXIDE ON NICKEL(0) COMPLEXES Anna Bücker Yasuhiro Yamauchi P041A EXTENDING THE SINGLE-CENTRE AMBIPHILE CONCEPT TO GROUP 13 P075A METHANDIIDE-BASED CARBENE COMPLEXES IN (DE)HYDROGENATION Till Kalkuhl REACTIONS: EXPERIMENTAL AND COMPUTATIONAL STUDIES P042A SYNTHESIS AND REACTIVITY OF AN ANIONIC CALCIUM HYDRIDE Michelle Schmidt COMPLEX P076A LUMINESCENT CATIONIC GROUP 4 METALLOCENE COMPLEXES Ryan Huo WITH N,O-CHELATING LIGANDS P043A DEVELOPMENT OF EXTREMELY STERICALLY DEMANDING Martin Lamač DIHYDROACRIDINE BASED LIGANDS AND COMPLEXATION TO MAIN P077A WEAK-BASE MIXED-METAL DEPROTONATION AND DERIVATIZATION GROUP METALS OF COBALTOCENIUM Gareth Nelmes Daniel Menia P044A IN SITU GRIGNARD METALATION METHOD – ONE STEP SYNTHESIS P078A CLATHROCHELATE COMPLEXES CONTAINING AXIAL CYMANTRENE TO CALCIUM AND MAGNESIUM AMIDES AND TROMANCENIUM SUBSTITUENTS Philipp Schüler Reinhard Thaler 34 35
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 P079A REDOX-ACTIVE ALL CARBON-LIGATED IRIDIUM METALLACYCLES Tereza Dušková FROM BIS(DIPYRIDO-ANNULATED N-HETEROCYCLIC CARBENE) P116A SYNTHESIS OF NOVEL PLANAR CHIRAL MONOPHOSPHINE LIGANDS Nakanishi Kazuki BEARING FERROCENYL-TRIAZOLE BACKBONES AND THEIR USE P080A ADVANCED CROSS–COUPLING REACTIONS FOR THE PREPARATION IN ASYMMETRIC CROSS-COUPLING REACTION OF FUNCTIONALIZED SULFONIC ACIDS Suguru Sakai Jakub Koudelka P117A TRIARYL BORANES FOR CATALYTIC HYDROGENATION P081A LOW-COORDINATE 3D TRANSITION METAL COMPLEXES WITH A BULKY OF N-HETEROAROMATICS WITH H2/CO/CO2 MIXED GAS CARBAZOLYL LIGAND Taiki Hashimoto Michelle Kaiser P118A SYNTHESIS OF HELICAL QUINILIZINIUM SALTS VIA CATALYTIC P082A ELECTRON-RICH 2,2’-BIPYRIDINE AND PHENANTHROLINE LIGANDS CYCLOTRIMERIZATION REACTIONS INVOLVING ALKYNES WITH COOPERATIVE BINDING SITES – COORDINATION CHEMISTRY Lucia Feriancová AND H2 ACTIVATION P119A TRIAZOLIUM SALTS AS LEWIS ACID CATALYSTS Jonas H. Franzen Deepak Ranolia P083A ISOCYANOFERROCENE AND ITS CARBENES’ GOLD(I) COMPLEXES P120A α-DIIMINE COBALT CATALYSED TRANSFER HYDROGENATION Petr Vosáhlo OF OLEFINS USING NH3BH3 P084A FERROCENE AMIDO- AND AMINO-BIS(PHOSPHINE) LIGANDS Felix Seeberger AND THEIR κ2, κ3 AND κ4 COORDINATION ON PALLADIUM(II) COMPLEXES P121A NEW APPROACHES FOR SYNTHESIS OF AZAHELICENES Michal Navrátil Marina Degač P086A (MULTI)STIMULI-RESPONSIVE PHOSPHAFERROCENOPHANES P122A STEREOSELECTIVE CYCPLOPROPANATION OF BORON DIPYRROMETHENE AND THEIR METAL COMPLEXES APPLIED IN CATALYSIS DERIVATIVES BY AN ORGANOCASCADE REACTION Bernhard Birenheide Vojtěch Dočekal P087A EXPLORING THE SCOPE OF ANILIDOPHOSPHINE BASED LIGANDS P123A THE MECHANISM OF MONONUCLEAR „GOLD ONLY“ PHOTOCATALYSIS IN RARE EARTH METAL CHEMISTRY Rebeka Eshagh Saatlo Benjamin Wittwer P124A ENANTIOSELECTIVE SYNTHESIS OF SPIRO IMIDAZOLONES BY P088A N-HETEROCYCLIC AND MESOIONIC CARBENES IN EARLY TRANSITION COMBINATION OF ORGANOCATALYSIS AND METAL CATALYSIS METAL CHEMISTRY Michael Franc Florian Neururer P125A CATALYTIC REDUCTION OF KETONES IN THE PRESENCE OF THE NEW P089A GROUP 9 CATALYSTS FOR THE PREPERATION OF N-SUBSTITUTED IRIDIUM COMPLEXES POLYAMINOBORANES Konrad Stęsik Mathew Cross P126A MANGANESE(I) CARBONYL ALYKL COMPLEXES: FROM P090A SYNTHESIS AND FUNCTIONALIZATION OF MANGANESE(I) COMPLEXES HYDROGENTION TO HYDROFUNTIONALIZATION CONTAINING SIGMA-B-H-BONDS Stefan Weber Ines Blaha P127A REDUCTION OF N2O WITH HYDROSILANES CATALYSED BY RuSNS P091A SOLID-STATE MOLECULAR ORGANOMETALLIC CHEMISTRY NANOPARTICLES OF MANGANESE(I) PINCER COMPLEXES Nuria Rendón Joe Goodall P128A A REDOX-SWITCHABLE GOLD(I) CATALYST: A CONVENIENT WAY P092A CONVENIENT ACCESS TO TETRAAMINOCYCLOBUTADIENE SPECIES FOR STUDYING LIGAND-DERIVED ELECTRONIC EFFECTS FROM DIMORPHOLINOACETYLENE César Luís Ruiz-Zambrana Lukas Körner P129A NOVEL SYNTHETIC APPROACHES TOWARD AMARYLLIDACEAE P093A N-HETEROCYCLIC CARBENE AND CYCLIC (ALKYL)(AMINO)CARBENE ALKALOIDS AND THEIR DERIVATIVES STABILIZED EARLY TRANSITION METAL COMPLEXES Stefanie Magela Perdomo Günther Horrer P094A METAL COMPLEXES WITH POLYFLUORINATED NHCS 36 37
29th International Conference on Organometallic Chemistry 29th International Conference on Organometallic Chemistry Prague Congress Centre | July 17–22, 2022 Prague Congress Centre | July 17–22, 2022 P130A MECHANISTIC INVESTIGATIONS INTO (ASYMMETRIC) OLEFIN P143A HYDROBORATION OF ALKENES AND TRANS-1,2-DIBORATION HYDROGENATION CATALYSED BY LOW-VALENT COBALTATE SALTS OF ALKYNES CATALYZED BY A WELL-DEFINED MANGANESE(I) ALKYL Franziska Gilch COMPLEX P131A DFT STUDY OF CO2 CONVERSION TO CYCLIC CARBONATES CATALYZED Daniel Zobernig BY IONIC IRON(II) COMPLEXES P144A NEW GENERATION OF NITROGEN LEWIS ACIDS FOR THE CATALYTIC Alejandro Yañez-Cabrera HYDROSILYLATION OF IMINES P132A MODIFIED POLYETHYLENES AS A PROMISING SUPPORT Kuldeep Singh FOR CATALYTICALLY ACTIVE SPECIES P145A MECHANISTIC STUDY OF CO2 REDUCTION INSIDE OF IRON PORPHYRIN Václav Ráliš CAGE P133A THE CATALYTIC USE OF P-ANISYL-TUNGSTEN TRIS TERT. BUTOXY Adarsh Koovakattil Surendran SILOXY LIGAND CATALYST P146A TUNING ACTIVITY AND SELECTIVITY OF DIIODO LATENT OLEFIN Han Thanh Tran METATHESIS CATALYSTS P134A SYNTHESIS AND REACTIVITY OF A LEWIS-BASE-STABILIZED Keren Iudanov TERT-BUTYL ARSANYLBORANE: A VERSATILE BUILDING BLOCK P147A SWITCHING BETWEEN HYDROGENATION AND OLEFIN TRANSPOSITION FOR ARSENIC BORON OLIGOMERS CATALYSIS VIA NH COOPERATIVITY IN Mn(I) PINCER COMPLEXES Felix Lehnfeld Wenjun Yang P135A NHC COORDINATED CYCLOMETALATED PALLADIUM(II) COMPLEXES P168A URANIUM(IV) CHLORO AND ALKYL COMPLEXES OF A RIGID BULKY CATALYZED 1,2-ADDITION OF ARYLBORON COMPOUNDS SELENOETHER-CONTAINING SeNSe-DONOR PINCER LIGAND TO ALDEHYDES OR KETONES Novan Gray Isami Nakajima P169A UNUSUAL BEHAVIOR OF N-HETEROCYCLIC PHOSPHINE IODIDE P136A BIFUNCTIONAL DIRHODIUM(II,II) COMPLEXES CONTAINING UREA CONTAINING THE SNOOPY LIGAND IN REACTIONS WITH CHALCOGENS MOIETY IN CATALYSIS Maksim A. Samsonov Poovannan Ravichandran P170A SELECTIVE C-H FUNCTIONALISATION OF METHANE BY A Pb(IV) P137A CYCLOPENTADIENYLMAGNESIUM COMPLEXES IN HOMOGENEOUS COMPLEX AT LOW TEMPERATURES AND PRESSURES CATALYSIS Liam Parkin Lisa Wirtz P171A PREPARATION AND DIENE-TRANSMISSIVE DIELS-ALDER REACTIONS P138A UNVEILING THE ROLE OF IRON(0) AND COPPER FOR C-N COUPLING OF ELECTRON-POOR [3]DENDRALENES OF AMINES AND ARYL CHLORIDE BENEATH BASE & SOLVENT Brůža Zbyněk AND INERT GAS-FREE CONDITION P172A ISOINDOLES AS VARIABLE LIGANDS FOR COORDINATION Charu Sharma AND ORGANOMETALLIC CHEMISTRY P139A PHOTOREDOX-CATALYZED DEFLUORINATIVE FUNCTIONALIZATIONS Stanislava Čiefová OF POLYFLUORINATED ALIPHATIC AMIDES AND ESTERS P173A HIGHLY REACTIVE FERROCENE-BASED N-HETEROCYCLIC SILYLENES Corinna Heusel Hannes Lukas Jacob P140A REDUCTION OF ELECTRON-DEFICIENT [3]DENDRALENES BY HYDRIDE P174A SINGLE ELECTRON TRANSFER IN PHOSPHINE-QUINONE SYSTEMS: REAGENTS AVENUE TO FRUSTRATED RADICAL PAIRS? Ondřej Kratochvíl Christoph Helling P141A BINUCLEAR KETODIIMINATE MAGNESIUM COMPLEXES P175A HALOGEN PHOTOELIMINATION FROM A GEOMETRICALLY FOR THE SYNTHESIS OF CYCLIC L-LACTIDE AND ε-CAPROLACTONE CONSTRAINED PHOSPHORUS CENTRE Eduard Glöckler Aaron King P142A S-BLOCK METAL-CATALYZED HYDROPHOSPHORYLATION OF ALKYNES P176A NOVEL RARE-EARTH METAL COMPLEXES WITH REDOX-ACTIVE Benjamin Fener FORMAZANATE LIGANDS Da Jin 38 39
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