Electron Backscatter Diffraction Study of Ultrahigh-Pressure Tso Morari Eclogites (Trans-Himalayan Collisional Zone): Implications for Strain ...
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GeoScienceWorld Lithosphere Volume 2022, Article ID 7256746, 20 pages https://doi.org/10.2113/2022/7256746 Research Article Electron Backscatter Diffraction Study of Ultrahigh-Pressure Tso Morari Eclogites (Trans-Himalayan Collisional Zone): Implications for Strain Regime Transition from Constrictional to Plane Strain during Exhumation Alosree Dey,1,2 Koushik Sen ,1,2 and Manish A. Mamtani3 1 Wadia Institute of Himalayan Geology, 33 GMS Road, Dehradun 248001, India 2 Academy of Scientific and Innovative Research, Ghaziabad, Uttar Pradesh 201 002, India 3 Department of Geology and Geophysics, Indian Institute of Technology, Kharagpur 721302, India Correspondence should be addressed to Koushik Sen; koushik.geol@gmail.com Received 9 November 2021; Accepted 19 February 2022; Published 16 March 2022 Academic Editor: Francis McCubbin Copyright © 2022 Alosree Dey et al. Exclusive Licensee GeoScienceWorld. Distributed under a Creative Commons Attribution License (CC BY 4.0). The Tso Morari Crystalline Complex (TMCC) of trans-Himalaya (eastern Ladakh, India) contains enclaves of ultrahigh-pressure eclogites that underwent deep burial (≥80 km) and subsequent rapid exhumation during continental subduction, collision, and final accretion of the Indian plate with the Eurasian plate. We present an electron backscatter diffraction (EBSD) study of eight eclogite samples to investigate the deformation mechanism and strain regimes active during peak (HP) metamorphism and subsequent postpeak rapid exhumation of the TMCC. Our study shows that the least retrogressed eclogite exhibits strong linear fabric (L tectonite) characterized by omphacite, having [001] axes parallel to and (110) poles perpendicular to lineation. These features concur with constrictional strain during peak (HP) metamorphism. A transitional planolinear fabric (LS tectonite) is shown by other eclogites that show petrographic evidence of omphacite alteration to amphibole and the presence of lower metamorphic grade minerals like actinolite and chlorite. Characteristics of lattice preferred orientation (LPO) of omphacite and quartz, indicated, respectively, by the LS and B indices, also suggest variation in strain regime from pristine eclogites to their altered counterparts. Based on these results, it is suggested that a constrictional strain regime prevailed during peak (HP) metamorphism in the TMCC due to the buoyant rise of TMCC in response to slab break-off and reverse slab pull during and after the deepest continental subduction. This buoyant rise was also facilitated by compression related to the ongoing India-Eurasia collision. This regime evolved later to plane strain that was superimposed on the UHP rocks at a shallower depth. It is plausibly associated with foliation-parallel extension during exhumation at midcrustal depths. A high- temperature prism c-slip in quartz shown by few samples is interpreted to have formed due to a subsequent granulite facies metamorphic overprint on the eclogite during collisional thickening. 1. Introduction by a subducting oceanic slab, and this transition of the con- tinental crust rocks at convergent margins, from subduction An important aspect regarding accretion and growth of con- to exhumation, can be explained by a single process that is tinents is continental subduction, which is often manifested breaking off of the subducting slab [3]. However, mecha- by the presence of high-pressure (HP) to ultrahigh-pressure nisms of continental crust exhumation to the surface are (UHP) rocks [1, 2]. The exposures of HP or UHP metamor- complex, varied, and currently debated. Numerous tectonic phic rocks on the Earth’s continental crust constitute an evi- models explaining exhumation of HP/UHP metamorphosed dence for their exhumation subsequent to deep subduction slices of continental crust have been proposed so far. These and continental accretion. It is generally accepted that conti- are exhumation by extension facilitated by detachment fault nental crust can be subducted to great depths if it is pulled [4, 5], extensional collapse [6], foreland propagating Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
2 Lithosphere thrusting [7], buoyancy assisted by erosional and tectonic processes [8], corner flow [9, 10], and channel flow [11]. L-type z Cloos and Shreve [12] introduced and described the organi- [001] [010] y x LS-type zation and dynamics of subduction channels to explain effi- [001] [010] cient exhumation of blueschists and eclogitic rocks and their structural/deformational relationships with the surrounding Prolate strain units from the footwall (downgoing plate) and hanging wall Plane strain (mantle wedge) realms. In this tectonic context, serpentinite, SL-type [001] [010] formed due to hydration of the overlying mantle wedge at sub-Moho depths of the subduction channel, acts like a lubricant and facilitates exhumation ([13] and references therein). Plane strain Field and microstructural studies conducted by various research groups have provided new insights into the kine- S-type [001] [010] matics and tectonic evolution of paleosubduction channels [14–17]. Most of these studies focus on exhumed HP rocks, which are highly strained [18] and often present as relics or inclusions within retrograded lithologies [19]. One of the Oblate strain most important devices used for the textural and microfabric Figure 1: The Flinn diagram representing L-type to S-type analyses of HP/UHP rocks is electron backscatter diffraction omphacite fabrics along with their interpretation in terms of (EBSD) [20, 21]. Lattice preferred orientation (LPO) pat- strain geometry (after Keppler [7]). terns of omphacite in eclogite have been studied in the past by various workers using either the universal stage ([22, 23]; also see [24, 25] for reviews) or EBSD [26–37]. These studies into geodynamic processes operating during subduction have demonstrated that in omphacite LPOs, lineation- and exhumation of HP/UHP rocks. In this regard, the pet- parallel [001] maxima and foliation-parallel girdle distribu- rofabric study of UHP eclogites can contribute to fill the tion represent constriction and flattening strains, respectively gap, since it can shed light on the strain regime and defor- (Figure 1) ([25] and references therein). The two end- mation mechanisms that prevailed during different stages members, namely “L-type” (constrictional) and “S-type” of their tectonic evolution. (flattening), can be correlated with the prevailing strain regime during high-pressure deformation [23, 24, 26, 27, 2. Geological Setting 34, 38] . The LS and SL types show the poles to (010) planes clustered perpendicular to the foliation and the [001] axes The ISZ consists of various lithounits, namely the Zildat concentrated parallel to the lineation (Figure 1). Any Ophiolitic Mélange, which is present between the HP/UHP second-order variation in either “L-” or “S-” type LPOs in TMCC and remnant of the Tethyan Oceanic block or the omphacite can be used to identify coaxial and/or noncoaxial Nidar Ophiolitic Complex (Figure 2(b)) [49]. The TMCC strain regimes that might be associated to heterogeneous represents the north Indian continental margin that under- simple shear, plane strain, transpression, transtension, or went ultrahigh-pressure metamorphism during Indo- other specific deformation geometries [25]. Eurasian continent-continent collision [50]. It is a domal In the trans-Himalayan part of Ladakh (NW India), the structure and consists of both ortho- and paragneiss, locally Indus Suture Zone is present as a linear, Orogen-parallel called Puga Gneiss, along with metabasic enclaves and dikes. zone formed at ~50-55 Ma [39–43] after consumption of These enclaves and intrusions are garnet amphibolite to the Tethyan Oceanic plate during convergence between the eclogite in nature. Metamorphic studies carried out by previ- Indian and Eurasian plates. The Tso Morari Crystalline ous workers suggest the peak (HP) metamorphism of eclo- Complex (TMCC), lying to the west of the Indus Suture gite facies in the TMCC at ≥2.8 GPa [51–56]. Detailed Zone (Figures 2(a) and 2(b)), is composed of rocks of the petrochronological study [57] suggests that peak (HP) meta- Paleozoic north Indian continental margin. They were sub- morphism of TMCC took place at ~47-43 Ma. Based on the ducted, underwent UHP metamorphism, and were subse- P-T pseudosection modelling carried out by previous quently exhumed. Several previous studies of these units workers on the metabasic enclaves of TMCC [51–56] were devoted to characterizing their metamorphism and (Figure 3), it can be inferred that the high-pressure mineral discussing the mechanism of exhumation of the TMCC omphacite was stable from ≥2.8 GPa to ~1.5 GPa within a [7, 44–48]. However, geometry, kinematics, and dynamics temperature range of ~530°C to ~650°C defining the P-T of tectonic transport along the subduction channel that path from peak (HP) to postpeak (HP) metamorphic stages. accommodated deep burial and exhumation received less Quartz represents mostly the late garnet amphibolite and attention. Eclogite, specifically eclogitic lenses, are part of granulite facies of metamorphism at ≤1.5 GPa to ~0.5 GPa subduction channels, and they often exhumed in continen- with temperature ranging from ~500°C up to 750°C during tal collision zones ([25] and references therein). Therefore, granulite metamorphism. understanding the deformation mechanism of omphacite Various mechanisms have been postulated to explain the and eclogitic rocks as a whole is critical for gaining insight exhumation of the TMCC subsequent to ultrahigh-pressure Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 3 Figure 2: (a) Geological map of Himalaya and trans-Himalaya. Boxes present study area. (b) Geological map of the study area (after Epard and Steck [46]) showing major geological units and sample locations. (c) Outcrop of sample 6Y location having retrograded eclogite embedded within granitic gneiss. (d) Outcrop of sample 3XA near Sumdo. The outcrop showing granitic gneiss containing enclaves of eclogite within it. (c) Outcrop showing location of sample 8XB near Kiager Tso Lake. metamorphism such as propagation of the TMCC as a (Figure 4(c)) and shows evidence of dynamic recrystalliza- nappe towards the foreland or the Indian plate [7]. It was tion (Figure 4(b)). Quartz grains are present as inclusions also proposed that the TMCC moved upward along a low- in garnet and also occupy the interstitial spaces in the matrix. viscosity channel and that the ascent was facilitated by ser- It may be noted that quartz shows evidence of dynamic recrys- pentinite acting as lubricating material [45]. A tectonic tallization by bulging and subgrain rotation (Figure 4(g)). model was also proposed in which the “extrusion” of the Actinolite and chlorite replace both omphacite and amphibole TMCC was explained by a combination of pure and simple (Figure 4(h)) in highly retrogressed rocks (6Y). shear [46]. This was supported by EBSD studies of quartz Depending on the degree of retrogression, the samples in the Puga Gneiss [47, 48]. collected across the strike of the TMCC from eight locations (Figure 2(b)) can be divided into three subtypes. Sample 3. Petrography 7XA belongs to type-1, which is the most pristine and rela- tively unaltered type of eclogite consisting dominantly of The studied metabasic rocks are variably retrogressed eclo- garnet (23.39% phase fraction), omphacite (21.44% phase gites. They consist of garnet, omphacite, amphibole, white fraction), and amphibole with least amount of alteration mica, epidote, quartz/coesite, plagioclase, biotite, and acces- and symplectites (Figure 5). Samples 3XA (13.23% and sory phases like rutile, ilmenite, apatite, and zircon. Garnet 15.22% phase fraction of garnet and omphacite, respectively, porphyroblasts either are inclusion free or contain inclusions with 5.39% of quartz), 8XB (11.63% and 9.26% phase frac- of omphacite, epidote, amphibole, quartz, white mica, etc. tion of garnet and omphacite, respectively, with 9.67% Garnets are often rimmed by thin amphibole rich layers. quartz), 1YA, 1YB, 8YA, and 8YB belong to type-2 eclogite Clinopyroxenes belong to the omphacite group according to and are characterized by abundant symplectites and signif- Quad-Na classification [58] (Figure 3(b)). Omphacite and icant amounts of garnet and omphacite (garnet varying amphibole are present as inclusions in garnet and also as from 4.71% to 11.63% and omphacite from 3.98% to individual grains in the matrix (Figures 4(a), 4(b), and 4(d)) 9.26% phase fractions) (Figure 5) with moderate replace- and as symplectites. Omphacite margins are often amphiboli- ment of omphacite by amphibole. Sample 6Y is the most tized, indicating partial retrogression (Figures 4(c), 4(e), and retrogressed sub type-3, and here, omphacite (4.05% phase 4(f)). Omphacite also occurs as inclusions in amphibole fraction) is almost completely retrogressed to actinolite Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
4 Lithosphere Figure 3: (a) A comparative diagram showing metamorphic P-T paths of Tso Morari eclogite obtained by various workers (compiled and modified after Pan et al. [56]). The P-T paths compared are of Wilke et al. (W) [54], Pan et al. (Pa) [56], Palin et al. (P) [87], Konrad- Schmolke et al. (K) [51], St. Onge et al. (St.) [52], de Sigoyer et al. (de) [44], Guillot et al. (G) [88], and Warren et al. (Wa) [89]. Metamorphic facies boundaries are drawn after Gilotti [1] and Hacker et al. [2]. (b) Classification diagram of clinopyroxene. (a) Quad- Na classification according to Morimoto et al. [58] (Quad represents the Ca-Mg-Fe pyroxene area) from samples 3XA and 8XB. Abbreviations: AM: amphibolite; Amp-EC: amphibolite-eclogite; BS: blueschist; EA: epidote amphibolite; EC: eclogite; Ep-EC: epidote eclogite; GR: granulite; GS: green schist; HGR: high-pressure granulite; Law-EC: lawsonite eclogite. (33.79% phase fractions) and chlorite (8.18% phase frac- nal sections of the rock, and the shape preferred orientation tions) (Figure 5) with almost negligible amount of garnet of omphacite was observed for each section through optical (0.64% in phase fraction). Relic omphacite is present in microscopy. The preferred orientation of omphacite in 2 minor amounts among symplectites/break down products. orthogonal planes helped trace the foliation, and a section Phase fractions of garnet, omphacite, quartz, actinolite, along the foliation was cut. Finally, a section perpendicular and chlorite detected by HKL CHANNEL 5 are provided to the inferred foliation plane (parallel to preferred orienta- in Supplementary Table. 1. tion of omphacite observed in petrography on the foliation plane) was prepared for EBSD analyses. For preparing sam- 4. Analytical Techniques ples for EBSD analyses, Mamtani’s Fabric Analysis Lab (MFAL) protocol was adopted [59]. Accordingly, conven- As most of the eclogite samples have poorly developed tional polishing of slides by colloidal silica gel is followed mesoscopic fabric (Figure 2), we have oriented the rock sur- by broad ion beam polishing (BIBP). The latter was done faces geographically and marked the strike and dip of the in two steps: cleaning of the slide for 5 minutes followed exposed surface of the samples before collecting them from by polishing for 30 minutes using the Leica EM TIC 3X the outcrops. Thin sections were prepared from 2 orthogo- triple broad ion beam milling system housed in the Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 5 Figure 4: Photomicrographs representing petrographic and microstructural features of the studied Tso Morari eclogite samples. (a) Sample 7XA showing dominantly garnet omphacite assemblage with presence of some amphibole, rutile, and epidote. Garnet cores are rich in inclusions. (b) Omphacite showing evidence of dynamic recrystallization and alteration to amphibole (sample 7XA). (c) Relict omphacite presents as inclusions in amphibole (sample 7XA). (d) Sample 3XA showing preferred orientation of omphacite and amphibole inclusions in garnet with the presence of amphibole, white mica, and epidote in the matrix. (e) BSE image of sample 1YA showing symplectite containing omphacite, amphibole, white mica, and rutile near the grain boundary of garnet. (f) BSE image from sample 8XB showing symplectite colony and replacement of omphacite by amphibole. (g) Evidence of subgrain rotation and recrystallization in quartz grain present within an amphibole-rich matrix (8XB). (h) Sample 6Y showing evidence of intense retrogression by presence of actinolite and chlorite with very minor amounts of relict omphacite. Mineral abbreviations: gt: garnet, omph: omphacite, amph: amphibole, wm: white mica, ep: epidote, ru: rutile, act: actinolite, chl: chlorite, q: quartz, sg: subgrain. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
6 Lithosphere Quartz Garnet Omphacite Omphacite Garnet Quartz Garnet Garnet Omphacite Omphacite Quartz Quartz IImenite IImenite Quartz Garnet Omphacite Omphacite Garnet Quartz Garnet Quartz Omphacite Omphacite Quartz Garnet Actinolite Chlorite Figure 5: Phase maps for all the analyzed samples. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 7 Department of Geology and Geophysics, Indian Institute of Boundaries of the selected grains were also smoothed. These Technology (IIT) Kharagpur, India (see [59] for detailed steps for grain segmentation were used for phase mapping, parameters of the MFAL protocol). After sample prepara- grain orientation spread (GOS) mapping, and preparing his- tion, EBSD patterns were acquired at 30 kV accelerating tograms for both grain size distribution (GSD) and angle of voltage, 1:49 × 10−6 mbar system vacuum, and ~15 mm misorientation for omphacite grains. Since these samples working distance using the Carl Zeiss Auriga Compact have weakly developed foliation and the XZ sections were FEG-SEM fitted with the NordlysMax2 EBSD detector determined using petrographic observations alone, we also (Oxford instruments, UK) housed in Central Research Facil- employed crystallographic vorticity analyses (CVA) [61, ity (IIT Kharagpur, India). Thin sections were placed in the 62]. CVA analyses utilize crystallographic orientation of SEM sample chamber and tilted to 70° before the EBSD individual grains and apply rotation statistics to determine analyses. Data acquisition and indexing of EBSD patterns their dispersion axes. The objective is to determine the vor- were carried out automatically using the AZtec software ticity normal surface (VNS), which is the most reliable plane (Oxford Instruments, UK). Step size in the range of 2-6 μm to study shear kinematics (Figure 6; [61]). CVA analyses are was taken for EBSD mapping, which is at least one-third advantageous in terms of providing objective quantitative in size than the smallest of grains. 2 μm was used only for determination of the vorticity vector orientation. Moreover, some individual omphacite grain for intragrain misorienta- it does not depend on the relationship between vorticity tion analysis along a line profile. and fabric elements like lineation and foliation [61, 62]. Additional backscattered electron (BSE) images were All the pole figures for lattice preferred orientations obtained by the Scanning Electron Microscope Zeiss EVO (LPO) for both omphacite and garnet were determined 40 US at the Wadia Institute of Himalayan Geology, Dehra- after CVA analyses and on the VNS where the Z axes of dun. To withstand the vacuum conditions and high-energy the stereoplot correspond to the bulk vorticity axes beam of electrons, the polished thin section was mounted (Figure 6), along which the rotation related to simple rigidly to an aluminum stub using a conductive cohesive shear occurs [62]. For CVA analyses, only grains with a then it was gold coated up to 10-30 A0. GOS > 1° were selected. Additionally a ratio of 1 : 4 for The electron probe micro analyzer (EPMA) CAMECA magnitude of principal and secondary axes of each grain SX-Five instrument was used to obtain the mineral chemis- scale dispersion was kept as a threshold to ignore analyses try data at the DST-SERB National Facility, Department of points with insignificant dispersion of lattice (https:// Geology (Center of Advanced Study), Institute of Science, github.com/zmichels/CVA). Indexed points, thus filtered, Banaras Hindu University. Polished thin sections were were used for pole figure analyses including low-angle coated with a 20 nm-thin layer of carbon for the analyses (2°-10°) inner and outer “neighbour-to-neighbour” grain using the LEICA-EMACE200 instrument. The CAMECA boundary misorientation analyses. LPOs of quartz were SX-Five instrument was operated by the SX-Five Software plotted with a halfwidth of 15°, and halfwidth of 10° was at a voltage of 15 kV and current 10 nA with a LaB6 source used for all the other minerals. in the electron gun for generation of electron beam. Natural LPOs of the minerals (omphacite, garnet, quartz, and silicate mineral andradite was used as internal standard to also actinolite and chlorite for retrograded metabasic sam- verify positions of crystals (SP1-TAP, SP2-LiF, SP3-LPET, ples) are shown in the lower-hemisphere equal area projec- SP4-LTAP, and SP5-PET) with respect to corresponding tions. Pole figures were plotted using one point per grain wavelength dispersive (WD) spectrometers (SP#) in the to avoid oversampling bias of large grains. Eigenvalue anal- CAMECA SX-Five instrument. The following X-ray lines yses [63, 64] were used to quantify the orientation distribu- were used in the analyses: F-Kα, Na-Kα, Mg-Kα, Al-Kα, tion data in terms of point maxima or clustering and girdle Si-Kα, P-Kα, Cl-Kα, K-Kα, Ca-Kα, V-Kα, Ti-Kα, Cr-Kα, distribution. To quantify and characterize symmetry of ori- Mn-Kα, Fe-Kα, and Ni-Kα. Natural mineral standards fluo- entation of omphacite, the LS index was used [38]. The rite, halite, apatite, periclase, corundum, wollastonite, ortho- index is based on the eigenvalues (λ1 > λ2 > λ3 ) of the orien- clase, rutile, chromite, rhodonite, hematite, and pure metals tation tensor calculated from the individual vectors of the V and Ni were used for routine calibration and X-ray ele- directions (010) and [001] axes in sample coordinates. The mental mapping and quantification. Routine calibration, value of the LS index varies from 0 for end-member S-type acquisition, quantification, and data processing were carried to a value of 1 for the end-member L-type. out using SxSAB version 6.1 and the SX-Results software of CAMECA. Calibration for analyses was done by using a 1 P010 G001 number of natural and synthetic standards. Precision of LS − index = 2− − , ð1Þ 2 G010 + P010 G001 + P001 analyses for major oxides is less than 1%. EPMA data are provided in Supp. Table. 4. Plots of lattice preferred orientation (LPO) were calcu- where P = ðλ1 – λ2 Þ is the point maximum parameter and lated using the MTEX 5.7.0, an open source MATLAB tool- G = 2ðλ2 – λ3 Þ represents the girdle distribution. For charac- box for quantitative texture analyses, available at http:// terizing orientation distribution of quartz c-axes, the cylin- mtex-toolbox.github.io [60]. MTEX was also used for eigen- dricity index (B) is used [65]. This value ranges between 0 value analyses. For grain segmentation, a 5° threshold angle for completely random fabric and 1 representing a was used, and only grains bigger than 5 μm in size and hav- completely nonrandom fabric. B represents the sum of the ing more than three orientation solutions were selected. point (P) and girdle (G) end-member fabric components. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
8 Lithosphere Figure 6: (a) Diagram showing the kinematic reference frame of the sample after computing rotation in terms of crystallographic vorticity axes (CVA) (taken from Michels et al. [61]). (b–i) Vorticity normal section (VNS) and bulk vorticity axis for all the eight samples. x-axes are parallel to lineation (E-W), and Z/CVA is perpendicular to foliation. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 9 Fabric strength of the indexed phases was calculated using analyses helps identify the slip systems that are active during the M index [66]. The M index is defined as: deformation (see [25, 35] and references therein for detailed descriptions of identifying slip systems from grain boundary ð 1 misorientation analyses), and in some cases, especially for M= IRT ðθÞ − R0 ðθÞ∣dθ, ð2Þ quartz, the identified slip systems can also provide an assess- 2 ment of the temperature of deformation [67]. LPOs of sample 3XA show girdle distribution of (010) poles perpen- where RT ðθÞ is the theoretical distribution of misorientation dicular to the foliation (Z) with a maximum MUD (multi- angle for a random fabric and R0 ðθÞ is the distribution for ples of uniform distribution) of 6.6. The [001] axes are observed misorientation angles. oriented parallel to the lineation (X) with a maximum Low-angle boundary (2°-10°) misorientation analyses for MUD of 7.1. Misorientation analyses of low-angle grain both inner (subgrain boundaries) and outer grain bound- boundaries of 3XA shows maximum concentration near aries were carried out for all the eight samples and are plot- [010] and (110) that indicates slip/edge dislocation along ted following the principles and methodologies described by [001](100) tilt boundaries. The LS index of 0.46 indicates a [35], and the slip systems were inferred from [24–26]. For planolinear fabric. Sample 7XA shows strong girdle distribu- misorientation analyses of low-angle grain boundaries of tion of (010) polls perpendicular to the foliation. The [001] quartz, the plotting convention of [67] was followed. axes show strong LPOs parallel to the lineation (X) with a Intracrystalline deformation for few individual ompha- maximum MUD of 8.3. Low-angle boundary misorientation cite grains was also identified. The grain having maximum plot shows maximum concentration at [010] that indicates GOS was selected from each of the samples. The image of slip/edge dislocation along [001](100) tilt boundaries. The the grains was smoothened, and points with missing index LS index of 0.82 indicates a strongly linear/constrictional were filled using a half quadratic filter (https://mtex- fabric. Samples 1YA and 1YB both show a distribution of toolbox.github.io/HomepageOld/files/doc/EBSDsmoothing [001] parallel to the lineation and that of (010) poles perpen- .html). A line profile across the grains was made to obtain a dicular to the foliation plane. Low-angle boundary misorien- misorientation angle gradient along the profile and also the tation plot for 1YA shows concentrations near both [001] distribution for axes of misorientation for low-angle (2°- and [010] suggesting [100](010) and [001](100) slips, 10°) inner grain boundaries. respectively. Low-angle boundary misorientation plot for Phase fractions (in percentage) of all the indexed phases 1YB shows maximum concentration near [001] that indi- are provided in Supp. Table. 1. The P, G, and R values of cates slip/edge dislocation along [100](010). Sample 1YA omphacite and quartz for all the samples are given in Supp. has an LS index of 0.51 that indicates a planolinear fabric. Table. 2 and Supp. Table. 3, respectively. Supp. Table. 4 con- On the other hand, 1YB has an LS index of 0.29 indicating tains the mineral chemistry data (EPMA) of clinopyroxene/ a planar fabric. Sample 8XB shows a very weak girdle distri- omphacite for samples 3XA and 8XB. bution of [001] axes parallel to lineation and a strong con- centration of (010) poles perpendicular to the foliation 5. EBSD Analyses plane with a maximum MUD of 5.6. Axes of misorientation 5.1. Grain Orientation Spread and Grain Size Distribution. A for low-angle grain boundaries for 8XB are concentrated at grain map of omphacite colored by orientation spread of [001] as well as at [010] suggesting [100](010) and each grain (GOS) is presented for each eclogite sample [001](100) slips, respectively. LPO is further characterized (Figure 7). The map represents the angular spread of orien- by an LS index of 0.55 suggesting a planolinear fabric. Both tation for each grain. This intragranular curvature is dictated 8YA and 8YB show a strong concentration of (010) poles by the presence of internal lattice curvature of a grain. perpendicular to foliation with respective maximum MUD Therefore, a map showing higher GOS of a particular phase of 6.2 and 4.4. They both have comparatively weaker distri- will indicate higher intragranular distortion. GOS for the bution of [001] axes parallel to lineation. Both these samples Tso Morari eclogite samples show a variation of maximum have concentration of low-angle grain boundary misorienta- GOS from ≥3 (sample 6Y) to ≥7 (sample 7XA). Histograms tion axes at [001] suggesting [100](010) slip. The LS index of for grain size distribution and misorientation angles for these samples are 0.53 (8YA) and 0.47 (8YB) indicating an omphacite grains are also presented (Figure 7) to provide a LS pattern. Sample 6Y has much less number of point anal- visual representation of variation in the grain size of ompha- yses and shows the concentration of (010) poles perpendic- cite for different samples and also the angular deviation for ular to foliation and that of [001] axes parallel to lineation. each omphacite grain from the mean orientation on the 6Y also has concentration of low-angle grain boundary mis- grain. orientation axes at [001] suggesting [100](010) slip. In general, our LPO data indicate that the retrogressed 5.2. LPOs and Low-Angle Grain Boundary Misorientation samples have weak LPO patterns and that there is a transi- Analyses of Omphacite. Figure 8 shows the stereoplots (lower tion from L-type to LS-type fabrics from pristine to more hemisphere) of LPOs for omphacite, and Figure 9 shows the retrograded eclogite samples. This weakening of LPO can inverse pole figures for misorientation analyses of low-angle be attributed to retrogression, omphacite breakdown, and (2°-10°) inner and outer “neighbour-to-neighbour” grain its replacement by amphibole, symplectite formation, and boundaries in crystallographic reference frame. This late-stage fluid infiltration. Low-angle grain boundary mis- “neighbour-to-neighbour” grain boundary misorientation orientation analyses (Figure 9) overall show a transition Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
10 Lithosphere Figure 7: Grain orientation spread (GOS) map of omphacite for all the samples along with histograms of grain size distribution and misorientation angle for omphacite. Magenta-colored lines in the GOS map represent the subgrain boundaries in omphacite. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 11 Figure 8: (a–h) Omphacite, (i), actinolite, and (j) chlorite LPOs of all the samples shown in lower-hemisphere equal area projections (halfwidth = 10° ). x-axes are parallel to lineation (E-W), and Z/CVA is perpendicular to foliation. Contours are shown in multiples of uniform distribution (MUD). n: number of grains. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
12 Lithosphere 1.8 3 1.8 3 2.5 1.6 1.6 2.5 2.5 2 1.4 1.4 2 2 1.2 1.2 M.U.D. M.U.D. M.U.D. M.U.D. M.U.D. 1.5 1 1 1.5 1.5 0.8 1 0.8 1 1 0.6 0.6 0.5 0.5 0.4 0.5 0.4 2.2 4.5 3.5 2.5 2 4 2.5 3 1.8 3.5 2 2.5 1.6 3 2 1.4 2.5 2 M.U.D. M.U.D. M.U.D. M.U.D. 1.5 M.U.D. 1.2 1.5 2 1.5 1 1 1.5 1 1 0.8 1 0.6 0.5 0.5 0.5 0.5 0.4 0 Figure 9: Inverse pole figures showing low-angle (2°-10°) “neighbour-to-neighbour” inner and outer grain boundary misorientation analyses for (a–h) omphacite, (i) actinolite, and (j) chlorite. from [001](100) to [100](010) slip from most pristine to ever, the patterns obtained for all the poles and planes are most retrograded eclogite samples. The fabric strength very random with numerous point maxima. Due to this ran- defined by the M index for omphacite is strong for 7XA dom distribution, no crystallographic inferences could be (0.12) but overall is weak for other samples (0.022-0.055). made, and implications, if any, of garnet LPOs are not dis- In type-1 and most of the type-2 samples, the presence of cussed any further. Garnet LPOs are shown in Supplemen- recrystallized grains and subgrains of omphacite (Figures 4, tary Figure 1. 5, and 7) suggests deformation by dislocation creep [23, 26, 68–76]; also see review by [25]). On the other hand, weak 5.5. LPOs of Quartz. LPOs of quartz for both a-axes (1120) CPO and comparatively low GOS (Figure 7) in the most ret- and c-axes (0001) are shown in Figure 10 along with the B rogressed samples (8YB and 6Y) may suggest that in these index (see also Supp. Table 3) and inverse pole figures for eclogites, omphacite may have accommodated strain by low-angle inner and outer “neighbour-to-neighbour” grain dominantly grain size sensitive (GSS) creep processes such boundaries in the crystallographic reference frame. 3XA as diffusion creep [33]. It may be noted that diffusion creep shows a weak girdle distribution of a-axes at a high angle in omphacite has been suggested to play a major role in low- to the foliation plane and distribution of c-axes nearly temperature conditions [23]. perpendicular to the foliation plane with a maximum MUD of 3.8. The B index of 0.28 indicates very low 5.3. LPOs of Actinolite and Chlorite. These two minerals are eccentricity of the c-axes. Low-angle grain boundary low-grade alteration products of preexisting omphacite and/ misorientation analyses suggest the dominance of a rare or amphibole and are observed and indexed for only sample rhomb slip. 7XA shows strong LPOs of c-axes 6Y. Actinolite shows strong concentration of [001] axes perpendicular to the foliation plane with a maximum along the Z plane, perpendicular to the foliation plane hav- MUD of 11 and girdle distribution of a-axes. A B index of ing a maximum MUD of 10. In chlorite, the [001] axes show 0.77 indicates a highly eccentric c-axis distribution. Grain polar distribution along the lineation with a maximum boundary misorientation analyses indicate a basal slip MUD of 12, and the (010) poles are perpendicular to the along low-angle inner and outer grain boundaries. Both foliation plane (Figure 8). Low-angle grain boundary misori- 8XB and 8YB have strong LPOs of c-axes parallel to the entation analyses of actinolite suggest a slip along [100](010) lineation with maximum MUD of 3 and 5.8, respectively. boundaries while that of chlorite indicates dominance of the This pattern of c-axes LPO for both these samples, along [001](100) slip system (Figure 9). with grain boundary misorientation plot, indicates high- temperature prism slip. A B index of 0.52 and 0.58 also 5.4. LPOs of Garnet. Garnet LPOs were prepared for poles to suggest a strong LPO of c-axes. 8YA and 1YA on the other (100) and (110) and the [111] crystallographic planes for all hand show polar and girdle distribution of c-axes, the samples except 6Y; the latter has almost no garnet. How- respectively, with a maximum MUD of 7.1 and 2.2, Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 13 Figure 10: Quartz LPOs are shown in lower-hemisphere equal area projections (halfwidth = 15° ) (x-axes are parallel to lineation (E-W), and Z/CVA is perpendicular to foliation) along with inverse pole figures for low-angle (2°-10°) inner and outer grain boundary misorientation analyses. Cartoon plotting conventions and slip systems of quartz are also shown following Neumann [67]. n: number of grains. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
14 Lithosphere respectively. Grain boundary misorientation analyses of both ing the postpeak (HP) decompression stage. A similar kind these samples suggest the most common prism slip. 1YB of transition has been observed by various workers in also shows LPOs of c-axes with a maximum MUD of 2.4, omphacite from eclogite in different tectonic settings around and its low-angle grain boundary misorientation analyses the world [29, 35, 36, 80]. Detailed LPO analyses of ompha- suggest both basal and prism slips. The M index is cite from different eclogite-bearing nappes of Alps [80] show moderate to weak for most of the samples (0.01 to 0.05), that an L-type fabric in omphacite is formed in the constric- apart from strong fabric strength for 3XA (M index = 0:10) tional field during the high-pressure metamorphism and and 7XA (M index = 0:16). subsequent retrogression stage. On the other hand, S-type LPOs of omphacite were observed in a prograde path owing 5.6. Intragranular Misorientation Analyses of Omphacite. To to the initial burial/subduction. LPOs and shape preferred understand intragranular deformation and misorientation in orientation analyses of omphacite carried out on eclogitic omphacite, misorientation line profiles for the grain with the rocks from the Tauern Window of Eastern Alps [29] suggest maximum orientation spread are shown from 5 representa- flattening the strain during prograde evolution that changed tive samples (Figure 11). Line segments were drawn across to constrictional strain regime during peak (HP) metamor- domains of different angular orientations across the grain, phic and exhumation stages. EBSD analyses on omphacite- and a profile for angular discordance with mean orientation bearing eclogite of the Sanbagawa metamorphic belt of and a misorientation gradient were obtained (Figure 11). Japan [35] reveal a strong L-type fabric in omphacite with The angular misorientation profile ranges from 8° to 10° a very high LS index and transitional LS-type fabric with a with an abrupt change in the orientation gradient, possibly moderate LS index for retrograded/altered eclogites. Study related to intracrystalline deformation, can be inferred in on eclogitic rocks of Malpica-Tui Allocthonous Complex samples 1YA, 8XB, and 6Y. of Spain [36] also has shown two types of LPOs in ompha- cite owing to noncoaxial constrictional strain and noncoax- 6. Discussion ial flattening strain. By comparing our results with those discussed above, a 6.1. Variation in Strain Regime Inferred from EBSD Patterns. conclusion can be drawn that a constrictional strain regime The Tso Morari Crystalline Complex, especially its metaba- prevailed during peak (HP) metamorphism and subsequent sic patches, bears signatures of a complex metamorphic his- exhumation of the TMCC along a subduction channel. Inte- tory with imprints of continental subduction, accretion/ grated metamorphic modelling and U-Pb geochronology of collisional thickening, and rapid exhumation stages zircon [77] suggest subduction of the TMCC along a steep (Figure 12). Detailed petrochronological study [52] suggests to almost vertical channel into the mantle that was followed ~2.1 GPa pressure and ~535°C temperature for prograde by extrusion that coincided with oceanic slab break-off (also metamorphism at 58 Ma, followed by peak (HP) metamor- see [44, 81]). Constrictional L-type fabric in omphacite can phism at 51 Ma in the P-T range of 2.5-2.7 GPa and 630- develop due to buoyancy driven extrusion of continental 645°C and finally retrogression at ~45 Ma (7-8 kbar and material between two lithospheric plates [29]. Therefore, 700-750°C). The prograde and peak (HP) metamorphic the constrictional strain regime during peak (HP) metamor- stages of the TMCC are also characterized by rapid exhuma- phism and subsequent rapid exhumation of the TMCC can tion [44, 57, 77] in the order of 3 mm/year [46] to as high as be explained by fast near-vertical subduction followed by 10 mm/year [78]. Plastic deformation and rheology of the slab break-off and extrusion of continental material along a eclogites at the base of the continent or subducting slab or narrow path, squeezed out between two lithospheric plates in the mantle, at a pressure > 1:5 GPa, are most likely to be (Figure 12). Transition of this constrictional strain regime accommodated in omphacite [23, 24, 79]. It is therefore to plane strain regime, as shown by retrograded type-2 and argued that the strain regime or deformation geometry/ type-3 eclogites, can be explained by a gradual decrease in nature during peak (HP) metamorphism and postpeak the steepness of the channel angle at a shallower depth and (HP) isothermal decompression/rapid exhumation stages layer parallel transport of the TMCC (Figure 12). This stage of the TMCC can be best identified in the omphacite grains is similar to the “transport parallel lengthening” [47]. Our of the eclogite lenses. LPOs of omphacite from eight eclogite study also shows a transition in activation of dominant slip samples of the TMCC in the present study show that the systems in omphacite during the exhumation history of the type-1 or the least altered omphacite-bearing sample 7XA TMCC. Grain boundary misorientation analyses show a shows a strong L-type fabric (Figure 8) with an LS index of change from [001](100) to [100](010) slip systems in 0.82. Therefore, it can be inferred that the peak (HP) meta- omphacite from peak (HP) to postpeak (HP) metamorphic morphic stage or stage of deepest continental subduction of stage (type-1) to subsequent exhumation, retrogression, the TMCC is characterized by constrictional strain. On the and alteration stage (type-2 and type-3). other hand, type-2 (partly altered) eclogites have varying EBSD analyses for LPOs of quartz have been done on the degree of alteration of omphacite, and type-3 (almost Puga Gneiss, host of the TMCC metabasic rocks, in the completely retrogressed) eclogites are characterized by a recent past [47, 48]. A prolonged top-to-the-east shearing transitional type of LPOs (Figure 8) with an LS index vary- was inferred to be responsible for exhumation of the TMCC ing between 0.29 and 0.55. In brief, the omphacite LPOs to shallow crustal depths till 30 Ma [47]. It may be noted that indicate transition from constrictional strain regime at peak the Puga Gneiss is essentially a quartzofeldspathic gneiss (HP) metamorphic conditions to a plane strain regime dur- devoid of any high-pressure mineral assemblage, and its Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
Lithosphere 15 b 12 10 misorientation angle in degree 8 6 4 a 2 b a 0 (3XA) 550 600 650 700 750 800 850 900 b y 10 9 8 misorientation angle in degree 7 6 5 4 3 a 2 1 b (1YA) 0 a 1200 1250 1300 1350 1400 1450 1500 1550 y 10 9 b 8 misorientation angle in degree 7 6 5 4 3 2 1 (8XB) a b a 0 320 330 340 350 360 370 380 390 400 410 y b 9 a 8 7 misorientation angle in degree 6 5 4 3 a 2 1 b (8YB) 0 365 370 375 380 y 9 b 8 7 misorientation angle in degree 6 5 4 a 3 b 2 (6Y) 1 a 0 1900 1950 2000 2050 2100 2150 2200 2250 y To reference orientation Orientation gradient Figure 11: Intragranular misorientation analyses for single-omphacite grains from representative samples showing a misorientation line profile along a line segment. Grain with maximum orientation spread is selected from each sample. Downloaded from http://pubs.geoscienceworld.org/gsa/lithosphere/article-pdf/doi/10.2113/2022/7256746/5569363/7256746.pdf by guest
16 Lithosphere 50 45 W Peak to post peak metamorphism (Pressure: 25.5-27.5 kbar Type-1 omphacite with L-type 40 Temperature: 630-645 °C LPO Age- 58.0 ± 2.2 Ma ) Continental subduction, slab nd break off and buoyancy driven mo e Diaraphit extrusion along a vertical channel. 35 G km Dry-EC C/ 5° 30 Lws-EC Coe Pressure (Kbar) Qtz Isothermal decompression during exhumation characterized by Type-2 and Type-3 omphacite Ep-EC omphacite breakdown, having L-S type LPO and 25 weakening of the LPO with symplectite formation, fluid infiltration increase in alteration of omphacite (Pressure: 27-12 kbar Amp-EC Temperature: 660-680°C 20 Age: 50.8 ± 1.4 ma BS 15 High temperature HGR metamorphism related Prism slip in quartz St. to collisional thickening (Pressure: 12.5 ± 0.5 kba 10 Temperature: 690 ± 25°C EA Age: 45-48 Ma) Retrogression down to slip in quartz 5 greenschist GR (Pressure: 7-8.4 kbar AM Temperature:
Lithosphere 17 omphacite to amphibole and symplectite formation suggest Supplementary 3. Table showing the P, G, and R values for that fluid infiltration played a major role in omphacite quartz. breakdown and the overall exhumation of the TMCC. Past Supplementary 4. Table showing the EPMA data of clinopyr- studies also suggest the infiltration of fluid from the adjacent oxene from samples 3XA and 8XB. Nidar Ophiolite and Zildat Ophiolitic Mélange within the TMCC at various stages of its exhumation [84–86]. We con- Supplementary 5. Garnet LPOs shown in lower-hemisphere clude that fluid infiltration, symplectite formation, and equal area projections (halfwidth =10°). Orientations and breaking down of omphacite during isothermal decompres- contours similar to that of Figure 7. n: number of grains. sion/exhumation played a major role in weakening of LPO in the retrogressed eclogite of TMCC. References [1] J. A. Gilotti, “The realm of ultrahigh-pressure metamor- 7. 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