10th International Symposium on Supercritical Fluids (ISSF 2012) The Versatility of Supercritical Fluid Technology - San Francisco, California ...
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10th International Symposium on Supercritical Fluids (ISSF 2012) The Versatility of Supercritical Fluid Technology San Francisco, California, USA 13-16 May 2012 Volume 1 of 3 ISBN: 978-1-5108-0044-1
Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2012) by Critical Fluid Symposia (CFS) All rights reserved. Printed by Curran Associates, Inc. (2015) For permission requests, please contact Critical Fluid Symposia (CFS) at the address below. Critical Fluid Symposia (CFS) c/o Dr. Jerry King University of Arkansas College of Engineering 4183 Bell Engineering Center Fayetteville, AR 72701 Phone: (479) 575-5979 Jwking1@uark.edu Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2634 Email: curran@proceedings.com Web: www.proceedings.com
TABLE OF CONTENTS VOLUME 1 LECTURE SESSION 1: PLENARY LECTURE - I (L-101) Supercritical Fluids for Effective Separation Processes................................................................................................................... 1 Gerd Brunner LECTURE SESSION 2A: BIOMASS AND ENERGY-RELATED CONVERSIONS - I (L-102) Technology Innovation for the Next Generation Biodiesel Production.......................................................................................... 6 Shiro Saka (L-103) Paper Mill Sludge Hydrolysis using Hot Compressed Water for Biodiesel Production by Oleaginous Yeast......................... 14 Ana Rita Rodrigues, Pedro Simoes, Alvaro Fonseca, Susana Barreiros, Alexandre Paiva (L-104) One-Pot Algal Biodiesel Production in Supercritical Carbon Dioxide......................................................................................... 21 Lindsay Soh, Julie Zimmerman (L-105) Optimization of Non-catalytic Supercritical Dimethyl Carbonate for Biodiesel Production .................................................... 29 Zul Ilham, Shiro Saka (L-106) Chemical Conversion of Biomass under Subcritical/ Supercritical - Solvent Conditions Using a Pilot Scale Flow Reactor: An Overview of the Iowa Center Energy-BECON Supercritical Fluids Program.......................................................... 37 Sipho C. Ndlela, Norman K. Olson (L-107) Supercritical Gasification of Biomass: Implementation of Experimental Results in a Process Simulation in Order to Assess an Energetic Optimization .................................................................................................................................................. 40 Olivier Boutin, Felicite Ondze, Jean-Henry Ferrasse, Jean-Christophe Ruiz, Frederic Charton LECTURE SESSION 2B: THERMODYNAMICS-PHASE EQUILIBRIA-FLUID PROPERTIES (L-108) Supercritical Processing of Fatty Oils: Phase Equilibrium Engineering ..................................................................................... 43 Pablo Hegel, Guillermo Soto, Alexis Velez, Guillermo Mabe, Selva Pereda, Esteban Brignole, Susana B. Bottini (L-109) Experimental Supercritical Phase Equilibria Measurements of Multi-component Systems ..................................................... 44 Frederick Fourie, Cara E. Schwarz, Johannes Knoetze (L-110) Measuring Reactions in SCF and Properties of SCF with Magnetic Suspension Balances ....................................................... 52 Frieder Dreisbach (L-111) Measurement and Correlation of Infinite Dilution Diffusion Coefficients in CO2 Expanded Liquids..................................... 56 Toshitaka Funazukuri (L-112) Modeling Tracer Diffusion Coefficients in Supercritical CO2 ....................................................................................................... 60 Ana L. Magalhaes, Francisco A. Da Silva, Carlos M. Silva (L-113) Numerical Simulation of Flow of Near-Critical Fluids .................................................................................................................. 66 T. Laurila, A. Carlson, M. Do-Quang, T. Ala-Nissila, Gustav Amberg (L-114) Thermodynamic Model for the Binary Solid Mixtures Solubilities in Supercritical Carbon Dioxide ..................................... 69 Sivamohan N. Reddy, Giridhar Madras LECTURE SESSION 2C: INDUSTRIAL APPLICATIONS OF CRITICAL FLUIDS - I (L-115) Impregnation via Supercritical Fluids - Principles and Applications .......................................................................................... 76 Eckhard Weidner (L-116) Development of Pilot Scale Continuous Sub-Critical Water Plant to Produce Valuable Materials and Energy from Organic Wastes and Their Dynamic and Kinetic Analyses.................................................................................................. 84 Hiroyuki Yoshida (L-117) Supercritical Water Oxidation – Current Status of Full-scale Commercial Activity for Waste Destruction.......................... 92 Philip A. Marrone (L-118) Supercritical CO2 Extraction of Omega-3 Oils from Disrupted Yarrowia Lipolytica Yeast................................................... 100 Keith W. Hutchenson, William M. Jack II, Val Krukonis, Shu-Chien Liang, Robert D. Orlandi, Hans Schonemann, Gregg Sunshine (L-119) Metal Extraction of Spiked Solid with Supercritical Carbon Dioxide ....................................................................................... 104 Ming-Tsai Liang, Ru-Chien Liang, Chih-Hsiung Lin, Ping-Jui Hsu, Li-Yu Wu, Hong-Fa Chen, Yuh-Wern Wu (L-120) Extraction of Natural Products for Industrial Applications........................................................................................................ 116 Nadine Igl-Schmid, Andreas Wuzik (L-121) Hanwha Chemical's Supercritical Hydro Technologies............................................................................................................... 118 Keedo Han, Kyu-Ho Song, Sei-Ung Park, Chol-Woo Lee, Soo-Yeong Han LECTURE SESSION 2D: NATURAL PRODUCTS, NUTRACEUTICALS AND FOOD RELATED MATERIALS - I (L-122) Recovery of Phytochemicals by Hybrid Extraction Process using Supercritical CO2 and Water .......................................... 119 Motonobu Goto, Masahiro Tanaka, Armando Quitain, Mitsuru Sasaki, Ryuichi Fukuzato
(L-123) Extraction of Essential Oil and Oleoresin from Eucalyptus citriodora Leaves using Sub and Supercritical CO2 ................................................................................................................................................................................................................... 125 Mirelle Dogenski, Ana Carolina Velho, Debora Nascimento e Santos, Nilson Jose Ferreira, Alessandra Lopes Oliveira (L-124) A Supercritical Fluid Based Approach to Sample Work-up, Analysis and Purification in Natural Products Research .......................................................................................................................................................................................................... 133 Rui Chen, Jacquelyn Runco, John P. McCauley Jr., Harbaksh Sidhu, Yongwei Xu, Lei Sang, Jing Huang, Li Yang, Zhengtao Wang, Liping Kang, Heshui Yu, Baiping Ma (L-125) Supercritical Antisolvent Fractionation of Lignans from Ethanolic Extract of Flaxseed ........................................................ 141 Giuseppe Perretti, Claudia Virgili, Ombretta Marconi, Gianfranco Regnicoli, Paolo Fantozzi (L-126) Comparative Study Between the Supercritical Extraction and Soxhlet Extraction of Nutmeg Seed ..................................... 148 Nik Norulaini Nik Ab Rahman, Sawsan Al Rawi, Md. Sohrab Hossain, Ahmad Ibrahim, Mohd Amin Abdul Majid, Mohd Omar Ab Kadir (L-127) Lipase-catalyzed Transesterification of CO2-Expanded Canola Oil and Fully-hydrogenated Canola Oil to Produce Base-stock for Zero-trans Margarines.......................................................................................................................................... 156 Ehsan Jenab, Feral Temelli (L-128) Production of Feruloylated Arabino-Polysaccharides and Oligosaccharides from Beet Fiber by using the Hydrothermal Treatment .............................................................................................................................................................................. 161 Nobuaki Sato, Yohei Takano, Shingo Umemura, Masahiro Mizuno, Kouichi Nozaki, Tsunetomo Matsuzawa, Yoshihiko Amano, Satoshi Makishima LECTURE SESSION 3A: BIOMASS AND ENERGY-RELATED CONVERSIONS - II (L-129) Microwave-Mediated Non-catalytic Transesterification of Algal Biomass under Supercritical Ethanol Conditions........................................................................................................................................................................................................ 169 Prafulla D. Patil, Harvind Reddy, Tapaswy Muppaneni, Sundar Ponnusamy, Peter Cooke, Tanner Schuab, Shuguang Deng (L-130) Influence of Impurities on Biodiesel Production from Jatropha Curcas L. by Supercritical Methyl Acetate Process ............................................................................................................................................................................................................. 175 Noorzalila Muhammad Niza, Keat Teong Lee, Zainal Ahmad, Kok Tat Tan (L-131) Application of Subcritical Water Process on Bioenergy Production .......................................................................................... 180 Aqsha Aqsha, Ranjani Kannaiyan, Nader Mahinpey, Robert Martinuzzi (L-132) Hydrolysis Behaviors of Lignocellulosics as Treated by Two-Step Semi-Flow Hot-Compressed Water ............................... 187 Natthanon Phaiboonsilpa, Shiro Saka LECTURE SESSION 3B: POLYMER, MATERIALS APPLICATIONS AND PROCESSES - I (L-133) Pressurized Hot Water Extraction After Pre-concentration of Organics on Electrospun Nanofiber Molecular Imprinted Sorbents...................................................................................................................................................................... 193 Nelson Torto, Janes Mokgadi, Shima Batlokwa, N. Ngomane, S. Chigome, Charlotta Turner (L-134) High-Pressure CO2 Aided New Processes for PET Foams Preparation..................................................................................... 195 Ling Zhao, Hua Zhong, Dachao Li, Chao Huang, Zhenhao Xi, Tao Liu (L-135) Polymer Architectural Effects on Solution Behavior of High Pressures: Linear, Hyperbranched, and Star Polymers in SCF and Liquid Solvents.......................................................................................................................................................... 202 Yue Wu, Matthew S. Newkirk, Babatunde Bamgbade, Mark A. McHugh, Val Krukonis, Paula Wetmore (L-136) Fundamental Mechanisms of Cell Nucleation in Plastic Foaming Processes Blown with Carbon Dioxide – Effects of Stresses ........................................................................................................................................................................................... 208 Anson Wong, Yanting Guo, Chul B. Park LECTURE SESSION 3C: INDUSTRIAL APPLICATIONS OF CRITICAL FLUIDS - II (L-137) Performance of CO2 Dry-cleaning with Cavitation ...................................................................................................................... 216 Stevia Sutanto, Victoria Dutschk, Maaike van Roosmalen, Geert Jan Witkamp (L-138) Extraction of Polyphenols from Maritime Pine Bark by Subcritical Water at Laboratory- and Industrial- Scale: Application of an Experimental Design ............................................................................................................................................ 221 Clement Celhay, Celine E. Mathieu, Gerard Vilarem, Luc Rigal (L-139) Application of Supercritical Water Gasification to Municipal Wastewater Treatment Plant: Experimental Studies and Operational Challenges............................................................................................................................................................. 228 Osamu Sawai, Yasunobu Tanaka, Takashi Nishihara, Teppei Nunoura, Kazuo Yamamoto (L-140) Engineering Micronization and Coating Applications with Dense Phase Carbon Dioxide ..................................................... 236 Fenghui Niu, Jahna Howell, Charles Decedue, David Johnston, Bala Subramaniam LECTURE SESSION 3D: NATURAL PRODUCTS, NUTRACEUTICALS AND FOOL RELATED MATERIALS - II (L-141) Supercritical Carbon Dioxide Inactivation of Solid Materials .................................................................................................... 238 Sara Spilimbergo, Giovanna Ferrentino, Sara Balzan, Alberto Bertucco (L-142) Formation of 5-(hydroxymethyl)furfural during Subcritical Water Extraction of Natural Matrices. Is It Bioactivity-Relevant? ..................................................................................................................................................................................... 245 Miguel Herrero, Maria Castro-Puyana, Lourdes Rocamora-Reverte, Jose A. Ferragut, Alejandro Cifuentes, Elena Ibanez
(L-143) Production of Supercritical Rosemary Extracts and their Effect on Tumor Progression ....................................................... 251 Gonzalo Vicente, Susana Molina, Margarita Gonzalez-Vallinas, Monica Rodriguez Garcia-Risco, Tiziana Fornari, Guillermo Reglero, Ana Ramirez de Molina (L-144) Evaluation of Essential Oil Extraction of Piptadenia gonoacantha and Piptadenia rígida using Supercritical CO2............................................................................................................................................................................................ 258 Bruna S. Moura, Francisco E.A.C. Junior, Mario G. Carvalho, Marisa F.Mendes LECTURE SESSION 4A: BIOMASS AND ENERGY-RELATED CONVERSIONS - III (L-145) Hydrothermal Conversion of Glucose. 1. Analysis of the Gas, Liquid and Solid Phases Generated by Multiscale Batch Processes ............................................................................................................................................................................ 266 Qian Wu, Elsa Weiss-Hortala, Radu Barna (L-146) Carbochemical Production from Switchgrass using Carbonated Subcritical Water at High Temperatures........................ 274 Rohit Dhamdere, Keerthi Srinivas, Jerry W. King (L-147) Characterization and Electrochemical Properties of Lithium Titanate Synthesized using Supercritical Fluid ................................................................................................................................................................................................................. 283 Agung Nugroho, Jaehoon Kim (L-148) Two-Step Biomass Hydrothermal Liquefaction Process through Acidic Subcritical- followed by Alkaline Supercritical-Water Treatment .................................................................................................................................................................... 288 Hema Ramsurn, Ram Gupta LECTURE SESSION 4B: POLYMERS, MATERIALS APPLICATIONS AND PROCESSES - II (L-149) Influence of Macromolecular Characteristics of RAFT/MADIX Poly(Vinyl Acetate)-Based (Co)Polymers on their Solubility in Supercritical Carbon Dioxide ................................................................................................................................... 291 Etienne Girard, Thierry Tassaing, Jean-Daniel Marty, Mathias Destarac (L-150) Miscibility and Kinetics of Phase Separation in Polymer Solutions in Dense Fluid Mixtures................................................. 298 Erdogan Kiran (L-151) Polymer Coatings Made by using sc-CO2 in High Pressure Techniques.................................................................................... 306 Louise Ovaskainen, Irene Rodriguez Meizoso, Charlotta Turner, Lars Wagberg (L-152) Fractionation of Synthetic Carbonaceous Oligomers by Supercritical Extraction using N-Methyl-2- pyrrolidone/toluene Solvent Mixtures.......................................................................................................................................................... 309 David F. Esguerra, Mark C. Thies LECTURE SESSION 4C: INDUSTRIAL APPLICATIONS OF CRITICAL FLUIDS - III (L-153) The Scale up of Continuous Hydrothermal Synthesis to Produce Industrial Quantities of Dispersed and Formulated Nanomaterials............................................................................................................................................................................ 315 Edward Lester (L-154) Mixing of Hydrocarbon Droplets and Water at Supercritical or Near-Critical Conditions.................................................... 323 Guang Wu Sadegh Dabiri, Michael T. Timko, Ahmed F. Ghoniem (L-155) Brazilian Ginseng: Use of the Supercritical Technology to Produce the Extract ..................................................................... 331 Marcelle Fernanda Carulo, M. Angela A. Meireles (L-156) Investigation of Supercritical Water Phenomena for Space and Extraterrestrial Application............................................... 337 Michael C. Hicks, Uday G. Hegde, John W. Fisher LECTURE SESSION 4D: NATURAL PRODUCTS, NUTRACEUTICALS AND FOOD RELATED MATERIAL - III (L-157) A Simple Mathematical Model for Supercritical Extraction of Natural Matter....................................................................... 347 Manuel Velasquez, Gustavo Bolanos (L-158) Hydrolysis of Starch Processing Residues in Subcritical Water Optimal Conditions for Production of Valuable Materials ......................................................................................................................................................................................... 355 Junya Ishii, Hideyuki Saito, Koichi Fujie, Hiroyuki Daimon (L-159) Recycling of Bovine Meat and Bone Meal and Inactivation of BSE Prion by Sub-Critical Water Treatment ..................... 362 Yuji Tsutsumi, H. Bang, E. Takata, A. Fukuda, Y. Murayama, M. Yoshioka (L-160) Subcritical Water Extraction/Reaction of Bio-Molecules from Lentil Husk ............................................................................. 367 Marleny A. Saldana, Anupam Haldar, Víctor H. Alvarez LECTURE SESSION 6: PLENARY LECTURE - II (L-201) Supercritical Fluid Technology – Key to the Future .................................................................................................................... 375 Youn-Woo Lee
LECTURE SESSION 7A: REACTIONS IN CRITICAL FLUIDS - I (L-202) Valorization of Aquatic Biomass via Supercritical Fluid Processes ........................................................................................... 381 Phillip E. Savage, Qingqing Guan, Jacob G. Dickinson, Peter J. Valdez, Shujauddin Changi (L-203) Polypropylene Grafting in Supercritical Carbon Dioxide ........................................................................................................... 385 Jacques Fages, Elisabeth Rodier, Jean-Jacques Letourneau, Martial Sauceau, Spiro Alexandratos (L-204) Self-Optimizing Continuous Reactors: Accelerating Process Development in Supercritical Fluids....................................... 390 Richard A. Bourne, Ryan A. Skilton, Andrew J. Parrott, Martyn Poliakoff (L-205) Application of Supercritical Fluids in Power Engineering .......................................................................................................... 393 Igor Pioro, Sarah Mokry, Wargha Peiman, Eugene Saltanov, Lisa Grande (L-206) Intensified, Highly Selective Ethylene Epoxidation with Heterogeneous Catalysts in Gas-Expanded Liquids..................... 402 Madhav Ghanta, Anand Ramanathan, Bala Subramaniam (L-207) Chemical Modification of Natural Rubber under Supercritical Carbon Dioxide Based Hydroxy Telechelic Liquid Natural Rubber and to Prepare the Polyurethane......................................................................................................................... 405 Alif Duereh, Chockchai Boonchuay, Surat Areerat (L-208) Coupling Microwave Irradiation with Supercritical Fluid Reaction System ............................................................................ 413 Rolf Schlake, Ernest Schlegel, Al Kaziunas LECTURE SESSION 7B: MATERIALS APPLICATIONS - I (L-209) Unleashing the Potential of Supercritical Fluids for Polymer Processing in Tissue Engineering and Regenerative Medicine................................................................................................................................................................................... 416 Ana Rita Duarte, Victor E. Santo, Anabela Alves, Simone S. Silva, Joana Moreira-Silva, Tiago H. Silva, Alexandra Marques, Manuela E. Gomes, Rui A. Sousa, Joao F. Mano, Rui L. Reis (L-210) Use of Supercritical Fluid Technology for the Production of Tailor-Made Aerogel Particles for Delivery Systems............................................................................................................................................................................................................. 424 Carlos A. Garcia-Gonzalez, Irina Smirnova (L-211) DELOS-susp for the Production of Vesicles with Homogeneous Lipid Supramolecular Organization................................. 432 Elisa Elizondo, Jannik Larsen, Nikos S. Hatzakis, Ingrid Cabrera, Thomas Bjoernholm, Dimitrios Stamou, Jaume Veciana, Nora Ventosa (L-212) A Dense Gas Process for the Production of Liposomal Encapsulated Active Pharmaceutical Ingredients Formulations ................................................................................................................................................................................................... 436 Chau C. Beh, Thomas E. Jacobs, Raffaella Mammucari, Neil Foster (L-213) Pressurized Fluid Technology in Extraction and Separation Processes – A Green Chemistry Approach ............................ 441 Charlotta Turner, Victor Abrahamsson, Sofia Lindahl, Jiayin Liu, Firas Jumaah, Arwa Mustafa, Merichel Plaza, Abdelrahman Ismail, Irene Rodriguez-Meizoso, Margareta Sandahl (L-214) Physical Stabilities of Indomethacin via Amorphization using Co-Milling and Supercritical Co- Precipitation Processing................................................................................................................................................................................. 446 Ron Tau Yee Lim, Wai Kiong Ng, Reginald B.H. Tan (L-215) Microencapsulation of Proteins within Polymeric and Inorganic Particles using Supercritical CO2 Media......................... 453 My Kien Tran, Leila Hassani, Brice Calvignac, Thomas Beuvier, François Hindre, Alain Gibaud, Frank Boury LECTURE SESSION 7C: CO2 REMEDIATION AND ENVIRONMENTAL ASPECTS (L-216) Pre-Combustion Capture of CO2 from Power Generation .......................................................................................................... 461 David Luebke (L-217) Applications of Reversible Ionic Liquids: CO2 Capture and Nanoparticle Synthesis .............................................................. 464 Steven R. Saunders, Kyle Flack, Emily Nixon, Amy Rohan, Jackson Switzer, Elizabeth Biddinger, Pamela Pollet, Charles Liotta, Charles A. Eckert (L-218) Thermodynamic Modeling of the Solubility of Supercritical CO2 and Other Gases on Ionic Liquids with the soft-SAFT Equation of State ................................................................................................................................................................... 469 Felix Llovell, M. Belo, Oriol Vilaseca, Joao A.P. Coutinho, Lourdes F. Vega (L-219) NIR-inline-Monitoring for Micronization Processes in Supercritical CO2 ................................................................................ 475 Dennis Bohm, Thomas Grau, Siegbert Johnsen, Ewelina Kaczowka, Alexander Klotz, Michael Tuerk, Gabriele Wiegand, Beat Zehnder (L-220) Reversible Ionic Liquids for CO2 Capture from High Pressure Streams .................................................................................. 479 Amy L. Rohan, Jackson R. Switzer, Kyle M. Flack, Emily C. Nixon, Amber C. Rumple, Elizabeth J. Biddinger, Manish Talreja, Pamela Pollet, Charles L. Liotta, Charles A. Eckert (L-221) Photo-Reduction of CO2 to Fuel by Novel Nanocatalysts Produced using Continuous Hydrothermal Synthesis .......................................................................................................................................................................................................... 485 Haiping Shen, Edward Lester, Trevor Drage (L-222) Pre-Combustion Capture of CO2 with Hydrophobic Polymers .................................................................................................. 493 Robert Enick, Matt Miller, Sam McNulty, Hunaid Nulwala, David Luebke LECTURE SESSION 7D: NOVEL SCF EXPERIMENTAL TECHNIQUES (L-223) Complementarities Between Supercritical Micro- and Millifluidic Synthesis of Nanocrystals for Advanced Nanostructured Materials ............................................................................................................................................................................. 499 Cyril Aymonier, Yann Roig, Samuel Marre
(L-224) Jet Cutting with Liquid Carbon Dioxide ....................................................................................................................................... 504 Lena Engelmeier, Stefan Pollak, Andreas Kilzer, Eckhard Weidner (L-225) Novel Supercritical Fluid Deposition Technique of SiO2 using Flow Channel Reactor ........................................................... 508 Takeshi Momose, Aiko Kondo, Hideo Yamada, Junji Ohara, Yasuhiro Kitamura, Hirohisa Uchida, Yukihiro Shimogaki, Masakazu Sugiyama (L-226) Preparation of Supported Metallic Nanoparticles using Supercritical Fluids........................................................................... 515 Michael Tuerk, Marlene Crone, Sabrina Mueller (L-227) Enzimatic Synthesis of Poly(ε-caprolactone) in Supercritical Carbon Dioxide......................................................................... 520 Sibele R. Rosso Comim, Emanuel Bianchin, Debora de Oliveira, J. Vladimir de Oliveira, Sandra R. S. Ferreira (L-228) High-Pressure Microfluidics to Explore Multi-Phase Systems: A Study Towards the Supercritical Fluid Extraction of Emulsions (SFEE)................................................................................................................................................................... 527 Sebastian Luther, Andreas Braeuer (L-229) In-situ Spectroscopic Ellipsometry of Cu Deposition Process from Supercritical Fluids - Evidence for a Surface Condensation Layer Formation...................................................................................................................................................... 533 Eiichi Kondoh, Takuya Sasaki, Yukihiro Tamegai, Mitsuhiro Watanabe, Lianhua Jin, Takahiro Ueno LECTURE SESSION 8A: BIOMEDICAL APPLICATIONS - I (L-230) New Insights in Drug Processing using Supercritical Fluids ....................................................................................................... 541 Elisabeth Badens, Christelle Crampon, Laurene Lesoin, O. Boutin, Yasmine Masmoudi (L-231) Supercritical CO2 Assisted Fabrication and Impregnation of PCL-Gelatin Based Scaffolds for Advanced Biomedical Applications ................................................................................................................................................................................ 549 Hrishikesh Munj, Tyler Nelson, John Lannutti, David Tomasko (L-232) Compressed Carbon Dioxide - A Green Washing Fluid for Medical Parts ............................................................................... 554 Sabine Kareth, Martin Bilz, J. Mankiewicz, M. Petermann, D. Rebien, M. Wehrl (L-233) Development of a Supercritical Precipitation Process of Calcium Carbonate for Biomedical Applications ......................... 560 Brice Calvignac, Thomas Beuvier, Leila N. Hassani, François Hindre, Alain Gibaud, Frank Boury LECTURE SESSION 8B: GREEN CHEMISTRY, ENGINEERING AND SUPERCRITICAL FLUIDS - I (L-234) Green Solvents for Catalysis: From Molecular Understanding to Continuous-Flow Processes ............................................. 567 Walter Leitner (L-235) Environmental Impact Assessment of Conventional and Supercritical Biodiesel Production Processes using the Waste Reduction (WAR) Algorithm............................................................................................................................................ 569 Victor F. Marulanda (L-236) Water and Benzyl Alcohol in Subcritical and Supercritical Conditions as Means for Carbon Fiber Recovery from Thermoset Composite Materials ........................................................................................................................................ 574 Rodolfo Morales Ibarra, Antonio F. Garcia Loera, S. M. Garcia Montes, Armando T. Quitain, Mitsuru Sasaki, Motonobu Goto (L-237) Greener Solvents for Old Challenges ............................................................................................................................................. 580 Mohammad-Taghi Golmakani, Jose A. Mendiola, Karamatollah Rezaei, Elena Ibanez LECTURE SESSION 8C: PROCESS DESIGN AND ECONOMICS - I (L-238) Cost of Manufacturing of Vegetable Extracts Obtained by Supercritical Fluid Extraction and Pressurized Liquid Extraction: Assisted or Not by Ultrasound ..................................................................................................................................... 585 Priscilla C. Veggi, Juliana M. Prado, M. Angela Meireles (L-239) Free of Water Tanning – Intensified by CO2 Parameter and Scale up Study ........................................................................... 593 Manfred Renner, Eckhard Weidner, Helmut Geihsler, Thomas Heinen (L-240) Economical Analysis of the Supercritical CO2 Fractionation of Capsicum Liquid Oleoresin................................................. 601 Maria Pilar Fernandez-Ronco, Maria Teresa Garcia, Juan Francisco Rodriguez, Rosario Mazarro, Ignacio Gracia (L-241) Modeling and Optimization of the Supercritical Wood Impregnation Process - Focus on Pressure and Temperature.................................................................................................................................................................................................... 609 Joao Fernandes, Anders W. Kjellow, Ole Henriksen LECTURE SESSION 8D: SEPARATION PROCESSES - I (L-242) Oxide Nanomaterials in Supercritical CO2 Phase: From Nano-powders to Membrane Preparation using Original Supercritical Carbon Dioxide On-stream Deposition Process................................................................................................... 617 Audrey Hertz, Veronique Durand, Jean-Christophe Ruiz, Stephane Sarrade, Christian Guizard, Anne Julbe (L-243) Sequential Fractionation of Milk and Whey Proteins with Supercritical Carbon Dioxide for New Health- Promoting Food Ingredients ......................................................................................................................................................................... 623 Laetitia M. Bonnaillie, Peggy M. Tomasula (L-244) Semi-Preparative Supercritical Chromatography Scale Plant for Polyunsaturated Fatty Acids Purification ..................... 629 Fernando Montanes, Owen Catchpole, Stephen Tallon, Kevin Mitchell, Kirill Lagutin (L-245) Supercritical Extraction and Fractionation of Biopolymers and Resins from Plant Materials .............................................. 634 Rodger Marentis, Jeff Martin
LECTURE SESSION 9A: BIOMEDICAL APPLICATIONS - II (L-246) Supercritical Development of Sustained Drug Delivery Intraocular Lenses ............................................................................. 642 Yasmine Masmoudi, Abir Bouledjouidja, Olivier Forzano, Jean Marie Andre, Elisabeth Badens (L-247) Fabrication of Porous Chitosan/Bioactive Glass Hydrogels in an Aqueous Media using CO2 as a Gas Foaming Agent................................................................................................................................................................................................ 649 Ali Fathi, Michael Bernard, Roya Ravarian, Fariba Dehghani (L-248) Engineering Supercritical Carbon Dioxide Assisted Lipid Nanocarriers: Statistical Optimization....................................... 656 Megha Swami, Vandana Patravale LECTURE SESSION 9B: GREEN CHEMISTRY, ENGINEERING AND SUPERCRITICAL FLUIDS - II (L-249) The Applicability of Subcritical Fluids to the Conservation of Actively Corroding Metallic Cultural Heritage ........................................................................................................................................................................................................... 660 Liisa Nasanen, Nestor Gonzalez-Pereyra, Stephanie Crette, Philippe DeVivies (L-250) ScCO2/Glycerol: A Biphasic Green System for Process Intensification ..................................................................................... 668 Yaocihuatl Medina-Gonzalez, Jean-Stephane Condoret, Thierry Tassaing, Severine Camy (L-251) Supercritical Alcoholysis of Sunflower Wet Sludge to Produce Fatty Esters ............................................................................ 675 Guillermo Soto, Alexis Velez, Pablo Hegel, Guillermo Mabe, Selva Pereda LECTURE SESSION 9C: PROCESS DESIGN AND ECONOMICS - II (L-252) De-Oiling of Raw Lecithin by High Pressure Extraction Processes............................................................................................ 683 Volkmar Steinhagen, Christoph Luetge, Michael Bork, Masa Knez Hrncic, Zeljko Knez (L-253) Costs Estimation for the Supercritical CO2 Extraction of Prepressed Oilseeds........................................................................ 687 Jose M. del Valle, Gonzalo A. Nunez (L-254) Supercritical CO2 Extraction of Lipids Contained in Three Different Microalgae (Chlorella, Nannochloropsis oculata and Dunaliella salina): Study of the Influence of Water Content and Pre-Treatment on the Extraction Kinetics and Yields ............................................................................................................................................................... 688 Adil Mouahid, Christelle Crampon, Elisabeth Badens LECTURE SESSION 9D: SEPARATION PROCESSES - II (L-255) Going Greener in Achiral and Chiral Separations: Employing Sustainable Technologies to Reduce our Environmental Impact ................................................................................................................................................................................... 695 Rachel M. Schmidt, Celia Ponder, Manon S. Villeneuve, Luke A. D. Miller (L-256) Mathematical Modelling of Palm Kernel’s Oil-Bearing Cell during Supercritical Fluid Extraction: One Dimensional Problem ..................................................................................................................................................................................... 701 Abu Hanipah Nawi, Mohd Omar Ab Kadir, Nik Norulaini Nik Ab Rahman (L-257) Adsorption of 2-Phenylethyl Alcohol from Supercritical CO2 on Silica Aerogel ...................................................................... 707 Xiaohui Hu, Shengxuan Zheng, Wensheng Lv, Hongqiao Lan, Yanzhen Hong, Yuzhong Su, Hongtao Wang, Jun Li LECTURE SESSION 11: PLENARY LECTURE - III (L-301) Where Are We Today: May 2012? ................................................................................................................................................. 711 Val Krukonis LECTURE SESSION 12A: SCF PARTICLE/FILM TECHNOLOGY - I (L-302) Supercritical Route for Super Hybrid Materials .......................................................................................................................... 717 Tadafumi Adschiri, S. Takami, K. Minami, T. Yamagata, K. Miyata, T. Morishita, M. Ueda, K. Fukushima, M. Ueno, T. Okada, H. Oshima, Y. Mitani, S. Asahina, S. Unno (L-303) Reverse Micelle Synthesis of Monodispersed Metallic Nanoparticles in Gas Expanded Liquids ........................................... 722 Ashley E. Hart, David B. Akers, Samuel Gorosh, Christopher Kitchens (L-304) Synthesis of Nanocomposites using Supercritical Fluids.............................................................................................................. 729 Zhimin Liu (L-305) Supersaturation as Criterion for the Appearance of Amorphous Particle Precipitation or Crystallization in the Supercritical Antisolvent (SAS) Process................................................................................................................................................ 730 Matthias Rossmann, Andreas Braeuer, Alfred Leipertz, Eberhard Schluecker (L-306) Tunable Steric Stabilization Effects on Size-Selective Nanoparticle Dispersability in Gas Expanded Liquid Systems............................................................................................................................................................................................................. 736 Pranav S. Vengsarkar, Jennifer N. Boice, Christopher B. Roberts (L-307) Supercritical CO2 as a Tool for Nanodevice Formation using Sol-Gel Chemistry.................................................................... 741 Paul A. Charpentier, Nasrin Farhangi, Serge Ayissi, Golam Moula, Adria Lotus, Qasem Alsharari (L-308) Preparation and Evaluation of MnOx-CeO2 Nanospheres via a Supercritical Anti-solvent Process ..................................... 742 Haoxi Jiang, Dongyu Jiang, Xiuqin Dong, Minhua Zhang
LECTURE SESSION 12B: PHARMACEUTICAL APPLICATIONS - I (L-309) Process Intensification in the Pharmaceutical Sector using Alternative Media ........................................................................ 750 Neil R. Foster, R. B. Yoganathan, Y. Pu, J. Lee, R. Mammucari (L-310) One-step Methodology for Integration of Actives in Nanovesicles using Compressed Fluids ................................................. 757 Ingrid Cabrera, Elisa Elizondo, Olga Esteban, Jose Luis Corchero, Marta Melgarejo, Daniel Pulido, Alba Cordoba, Evelyn Moreno, Esther Vazquez, Fernando Albericio, Miriam Royo, Antonio Villaverde, Maria Parajo, Nora Ventosa, Jaume Veciana (L-311) CO2-assisted High Pressure Homogenization: A Solvent-free Process for Polymeric Microspheres ..................................... 761 Johannes Kluge, Marco Mazzotti (L-312) Encapsulation of Nanoparticles by Pressure Reduction Over CO2- Expanded Liquids .......................................................... 763 Madhu Vinjamur, Mohd Javed, Mamata Mukhopadhyay (L-313) Interpenetrating Polymer Networks for Drug Delivery Devices ................................................................................................. 771 Martin Alm, Soern L. Steffensen VOLUME 2 (L-314) Potential Technique for the Production of Micronized Lactose Crystals by Supercritical Fluid Conditioning.................................................................................................................................................................................................... 778 Syed Anuar Faua'ad Syed Muhammad, Patricia Tang, Hak-Kim Chan, Fariba Dehghani (L-315) Supercritical Fluid Drying of High Molecular Weight Biopolymers for Particle Formation and Delivery of Bioactives......................................................................................................................................................................................................... 785 Bernhard Seifried, Feral Temelli LECTURE SESSION 12C: SUPERCRITICAL FLUIDS-IONIC LIQUIDS/COUPLED MEDIA (L-316) Engineering Reactions in Biphasic Ionic Liquid/CO2 Systems: Homogeneous Catalysis and Synthesis of Ionic Liquids ................................................................................................................................................................................................... 793 Aaron Scurto (L-317) Limiting Partition Coefficients of Organic Solutes in Ionic Liquid–Supercritical Carbon Dioxide Systems from Generalized Linear Solvation Energy Model..................................................................................................................................... 799 Josef Planeta, Pavel Karasek, Barbora Hohnova, Lenka Stavikova, Michal Roth (L-318) Development of Supported Ionic Liquid Membranes for High Pressure Separations ............................................................. 807 Ricardo M. Tomas do Couto, Rui Ruivo, Pedro Calado Simoes (L-319) Ion Aggregation During Ionic Liquid Co-Solvent Based Lipid Extraction ............................................................................... 813 Santosh Bandlamudi, Kenneth M. Benjamin, Michael Cooney, Georgianna Martin (L-320) A Low-Viscosity Family of Ionic Liquids Based on the Tetracyanoborate Anion for CO2 Capture ...................................... 819 Maria Teresa Mota Martinez, Mamoun Althuluth, Maaike C. Kroon, Cor J. Peters (L-321) Development of a Supercritical Assisted Particle-Agglomeration Method for the Preparation of Bioactive Chitin-based Matrices .................................................................................................................................................................................... 822 Simone S. Silva, Ana Rita C. Duarte, Joao F. Mano, Rui L. Reis (L-322) Thermodynamic Prediction of Vapor-Liquid Equilibrium of Binary Systems of Ionic Liquids + Hydrocarbons using Peng Robinson Equation of State ............................................................................................................................. 828 Victor H. Alvarez, Marleny D. A. Saldana LECTURE SESSION 12D: HYDROTHERMAL PROCESSING AND INORGANIC MATERIALS - I (L-323) Hydrothermal Processing and In Situ Surface Modification of Metal Oxide Nanomaterials ................................................. 835 K. Byrappa, K. Namratha (L-324) Synthesis of Cathode/Anode Active Materials for Large-Scale Li 2nd Battery in Supercritical Fluids .................................. 843 Jaehoon Kim, Agung Nugroho, Seung-Ah Hong, Eduardus Budi Nursanto (L-325) Supercritical Production of Cubic Gadolinium Oxides for Real-Time Neutron Detection ..................................................... 851 Peter Molnar, Jennifer I. Brand (L-326) A Theoretical Study of Factors Affecting Corrosion in Supercritical Water Reaction Vessels............................................... 856 Simon J. Halstead (L-327) SCWO of Hydrocarbon-Contaminated Waters: Continuous Systems with Split-Entry Oxidant .......................................... 860 Bushra Al-Duri, Iain Kings, Belen Garcia-Jarana, Juan Ramon Portels (L-328) Hydroxide-Enhanced Hydrothermal Drilling and the Solubility of the Silica-NaOH-Sub and Supercritical Water System .................................................................................................................................................................................................. 867 Adam G. Carr, Jefferson W. Tester (L-329) Large-Scale Synthesis of ZnO Nanocrystals with Size-controlled in Continuous Hot Compressed Water ........................... 875 Zhiqiang Mao, Shining Li, Yaping Zhao LECTURE SESSION 13A: SCF PARTICLE/FILM TECHNOLOGY - II (L-330) Rapid Expansion of Supercritical Solutions from Ternary Mixtures: Towards a Green Production of Microcomposite Surfaces............................................................................................................................................................................... 881 Irene Rodriguez Meizoso, Pontus Olin, Josefin Illergard, Lars Wagberg, Charlotta Turner
(L-331) Binary Adsorption of Platinum and Copper Complexes from Supercritical Carbon Dioxide on Carbon Aerogels for the Synthesis of Supported Bimetallic Nanoparticles........................................................................................................... 885 Selmi Erim Bozbag, Svetlana O. Kostenko, Michael A. Kurykin, Lichun Zhang, Mark Aindow, Can Erkey (L-332) Development of Aerogel Catalyst with Tunable Nanoporosity and Photocatalytic Activity through Supercritical Drying and Impregnation....................................................................................................................................................... 893 Haitao Li, Sermin Sunol, Aydin K. Sunol (L-333) Strategies for Nanoparticle Design of Racemic Ibuprofen by Rapid Expansion of Supercritical Solutions (RESS) Technique Using Supercritical Carbon Dioxide............................................................................................................................ 901 Hirohisa Uchida, Junichi Sakabe, Kohei Demoto, Ryota Nakazawa, Daisuke Kondo, Ayumu Kataoka, Takashi Kokubun, Masayoshi Ito, Nobuhiro Sugimoto SESSION 13B: PHARMACEUTICAL APPLICATIONS - II (L-334) Utilization of sc-CO2 in the Preparation of Hemocompatible, Cell Scaffolding Cellulose Phosphate Aerogels for In vivo Preparation of Bone Tissue ........................................................................................................................................ 909 Christian Schimper, Ramona Dunareanu, Emmerich Haimer, Martin Wendland, Dieter Loidl, Manfred Maitz, Philipp Seib, Carsten Werner, Maia-Alexandra Neouze, Jean-Marie Nedelec, A. Hardy-Dessources, Antje Potthast, Thomas Rosenau, Falk Liebner (L-335) Fabrication of Lipid Nanocarrriers of Levodopa using Supercritical Fluid Technology......................................................... 912 Clara B. Fernandes, Vandana B. Patravale (L-336) SC-CO2 Processing of Biodegradable Nanoparticles with Sustained Release of Functional siRNA....................................... 914 Gunilla B. Jacobson, Emilio Gonzalez-Gonzalez, Roger L. Kaspar, Christopher H. Contag, Richard N. Zare (L-337) Development of Supercritical Fluid Extraction and Supercritical Fluid Chromatography Purification Methods using Rapid Solubility Screening to Support Drug Discovery .................................................................................................. 919 Kyung Gahm, Ke Huang LECTURE SESSION 13C: REACTIONS IN CRITICAL FLUIDS - II (L-338) Kinetic Resolution in sc-CO2 - Design of Continuous Reactor Based on Results of Batch Experiments ............................... 920 Edit Szekely, Margita Utczas, Bela Simandi (L-339) Advancement of Fischer-Tropsch Synthesis with Integrated Product Upgrading via Utilization of Supercritical Fluid Reaction Media ............................................................................................................................................................. 922 Sihe Zhang, Rui Xu, Christopher B. Roberts (L-340) Simultaneous Assessment of Intrapellet Heat and Mass Transfer Limitations for Supercritical Phase Fischer-Tropsch Synthesis............................................................................................................................................................................. 927 Aswani K. Mogalicherla, Elfatih E. Elmalik, Nimir O. Elbashir (L-341) Reversible Reactions of Carbon Dioxide with Amines Employing a Protection/Deprotection Mechanism........................... 936 Fiaz S. Mohammed, Christopher L. Kitchens LECTURE SESSION 13D: HYDROTHERMAL PROCESSING AND INORGANIC MATERIALS - II (L-342) New Methane Fermentation Process using Subcritical Water Treatment for Sewage Sludge ................................................ 943 Eiichi Hasegawa (L-343) Production of Nano-Oxides with a Continuous Supercritical Water Device ............................................................................. 946 Frederic Demoisson, Moustapha Ariane, Romain Piolet, Antoine Leybros, Coralie Quadri, Frederic Bernard (L-344) Hydrothermal and Solvothermal Syntheses, In situ Surface Modification and Antioxidant Activity of Co- Doped Advanced ZnO Nanoparticles........................................................................................................................................................... 950 Namratha Keerthiraj, K. Byrappa, S. Rajesh, V. Ravishankar Rai (L-345) Determination of the Equilibrium Constant for the Decomposition of Potassium Bicarbonate in Water at Near-Critical Conditions ............................................................................................................................................................................... 958 Maider Legarra Arizaleta, Ashley Blitz, Daniel Kahoonei, Zsuzsanna Czegeny, Michael Antal LECTURE SESSION 14A: SCF PARTICLE/FILM TECHNOLOGY - IIII (L-346) Hollow Fibers by Electrospinning in Supercritical CO2 .............................................................................................................. 961 Detlef Freitag, Alexander Guenther, Wolfgang Arlt, Mark Mc Hugh (L-347) Dielectric Property of Titanium Dioxide Thin Films Fabricated by Supercritical Fluid Deposition...................................... 964 Hiroshi Uchida, Yuuki Nakagawa, Yuma Hayakawa, Kazuyuki Sekino, Seiichiro Koda (L-348) A New Supercritical Assisted Atomization Layout for the Micronization of Thermolabile Compounds .............................. 972 Renata Adami, Sara Liparoti, Ernesto Reverchon (L-349) Effect of Solvent Condensation During Rapid Expansion of Supercritical Solutions .............................................................. 979 Victor Stepanov, Lev Krasnoperov LECTURE SESSION 14B: PHARMACEUTICAL APPLICATIONS - III (L-350) Preparation of Biodegradable Alginate Aerogels Used as Carriers for Drug Delivery............................................................ 980 Zoran Novak, Anja Veronovski, Zeljko Knez
(L-351) Use of Supercritical Fluid Chromatography (SFC) to Support in Rapid Development of Pharmaceutical Candidates ....................................................................................................................................................................................................... 985 Jimmy O. DaSilva, Derek Henderson, Amanda M. Makarewicz (L-352) Precipitation of Ultra-fine Particles by Pressure Reduction of Gas Expanded Liquids: Experiments and Mathematical Modeling ................................................................................................................................................................................. 987 K. Arjun Kumar, Mamata Mukhopadhyay, Madhu Vinjamur, Sameer Dalvi (L-353) Expanding the Versatility of SFC through New Enhancements to MS Directed, Open Bed Fraction Collection Systems .......................................................................................................................................................................................... 995 Steven Zulli, Jonathan L. Jones, Chuping Luo, Timothy P. Martin, Ziqiang Wang, Harbaksh Sidhu LECTURE SESSION 14C: MATERIALS APPLICATIONS - II (L-354) Bioactive Glasses Loaded with Dexamethasone by a Supercritical Carbon Dioxide Deposition Process ............................ 1001 Luisa Filipe, Ana Paula Piedade, James J. Watkins, Mara E. Braga, Herminio C. de Sousa (L-355) Stable Emulsions in Biphasic Whole-cell Biocatalysis: The Potential of sc- CO2 for an Industrial Scale DSP ................... 1007 Christoph Brandenbusch, Jonathan Collins, Bruno Buehler, Andreas Schmid, Gabriele Sadowski (L-356) Chiral Resolution of Ibuprofen via Diastereomeric Salt Formation in Supercritical Carbon Dioxide ................................ 1008 Gyorgy Bansaghi, David Mendez Sevillano, Bela Simandi, Zoltan Juvancz, Edit Szekely (L-357) Formation of Drug-Cyclodextrin Inclusion Compounds via Melting in Carbon Dioxide + Co-Solvent Mixtures......................................................................................................................................................................................................... 1010 Heather E. Grandelli, Abby Whittington, Erdogan Kiran LECTURE SESSION 14D: HYDROTHERMAL PROCESSING AND INORGANIC MATERIALS - III (L-358) Etching of Silicon under Subcritical Conditions: A Greener Approach .................................................................................. 1018 Nestor G. Gonzalez-Pereyra, Stephanie A. Crette, Olin Thompson Mefford (L-359) Applications of Supercritical Water Technologies in Advanced Energy Systems .................................................................. 1025 Morgan L. Thomas, Gaelle Dupouy, Ian S. Butler, Ajay K. Dalai, Janusz A. Kozinski (L-360) Hydrothermal Processing of Oxide Materials for Functionalities ............................................................................................ 1027 Guangshe Li, Liping Li (L-361) The Synthesis of Novel BaTeM2O9 (M = Mo or W) Ultrafine Particles in Supercritical Water System .............................. 1030 Bo Li, Rong Zhang, Xutang Tao POSTER SESSION P-0100: BIOMASS AND ENERGY-RELATED CONVERSIONS Production of Biodiesel with Glycerol Carbonate by Non-Catalytic Supercritical Dimethyl Carbonate .......................................... 1033 Zul Ilham, Shiro Saka Effect of Purification of Waste Cooking Oil using Supercritical CO2 Extraction on the Production of Hydrotreated Biodiesel (HBD) ............................................................................................................................................................................................ 1038 Seok Ki Kim, Jae Young Han, Seung-Ah Hong, Jaehoon Kim Wood Liquefaction in Supercritical Alcohol ............................................................................................................................................. 1043 Steffen Brand, Jaehoon Kim Subcritical Water Pretreatment of Lignocellulosic Biomass ................................................................................................................... 1048 Hun Wook Lee, Aye Aye Myint, Dae Sung Kim, Junho Yoon, Youn-Woo Lee Continuous Biosynthesis of Biodiesel from Lipids of Corn Distillers’ Dried Grains in Supercritical Carbon Dioxide ................... 1052 Ozan Nazim Ciftci, Feral Temelli Biodiesel Production from Vegetable Oil using Sulfated Zirconia via Supercritical Transesterification: Optimization Study ...................................................................................................................................................................................... 1057 Sheila Adell, Aline Santana, Cristian Ledesma, Eliana Ramirez, Jordi Llorca, Maria Angeles Larrayoz Optimization of Biodiesel Production by Supercritical Transesterification of Edible, Non-edible and Algae Oils .......................... 1058 Aline Santana, S. S. Jesus, M. A. Larrayoz, R. M. Filhol A Greener Approach to Biodiesel Production........................................................................................................................................... 1060 Pedro Lisboa, Jose Martin, Ana Rita Rodrigues, Pedro Simoes, Susana Barreiros, Alexandre Paiva Biomass Conversion for the Microalgae Slurry using the Supercritical Methanol Method................................................................ 1066 Atsushi Kishita, Diah Ajeng Setiawati, Gede Suantika Liquid and Supercritical CO2 Extraction of Fat from Rendered Materials and Solubility Correlation ........................................... 1071 Jose Luis Orellana, Tyler Smith, Christopher L. Kitchens Aqueous Reactive Pretreatment of Switchgrass for Oligomeric Sugar Production ............................................................................. 1077 Yu-Wu Lu, Keerthi Srinivas, Jerry W. King Carbochemical Production from Switchgrass using Carbonated Subcritical Water at High Temperatures.................................... 1083 Rohit Dhamdere, Keerthi Srinivas, Jerry W. King Transesterification of Rapeseed Oil with Supercritical Ethanol at Low Molar Ratios. Extraction of Valuable Components................................................................................................................................................................................................... 1092 Farid Gumerov, Rustem Usmanov, Radif Gabitov, Chamil Biktach, Ilmutdin Abdulagatov Cellulose and Sugarcane Bagasse Hydrolysis using Subcritical Water.................................................................................................. 1097 Juliana M. Prado, Luiz A. Follegatti-Romero, Fiorella P. Cardenas-Toro, Tania Forster-Carneiro, M. Angela A. Meireles, Mauricio A. Rostagno
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