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10th International Symposium on Supercritical Fluids (ISSF 2012) The Versatility of Supercritical Fluid Technology - San Francisco, California ...
10th International Symposium on
Supercritical Fluids (ISSF 2012)

The Versatility of Supercritical
Fluid Technology

San Francisco, California, USA
13-16 May 2012

Volume 1 of 3

ISBN: 978-1-5108-0044-1
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TABLE OF CONTENTS
                                                                                      VOLUME 1

LECTURE SESSION 1: PLENARY LECTURE - I

(L-101) Supercritical Fluids for Effective Separation Processes................................................................................................................... 1
         Gerd Brunner

LECTURE SESSION 2A: BIOMASS AND ENERGY-RELATED CONVERSIONS - I

(L-102) Technology Innovation for the Next Generation Biodiesel Production.......................................................................................... 6
         Shiro Saka
(L-103) Paper Mill Sludge Hydrolysis using Hot Compressed Water for Biodiesel Production by Oleaginous Yeast......................... 14
         Ana Rita Rodrigues, Pedro Simoes, Alvaro Fonseca, Susana Barreiros, Alexandre Paiva
(L-104) One-Pot Algal Biodiesel Production in Supercritical Carbon Dioxide......................................................................................... 21
         Lindsay Soh, Julie Zimmerman
(L-105) Optimization of Non-catalytic Supercritical Dimethyl Carbonate for Biodiesel Production .................................................... 29
         Zul Ilham, Shiro Saka
(L-106) Chemical Conversion of Biomass under Subcritical/ Supercritical - Solvent Conditions Using a Pilot Scale
Flow Reactor: An Overview of the Iowa Center Energy-BECON Supercritical Fluids Program.......................................................... 37
         Sipho C. Ndlela, Norman K. Olson
(L-107) Supercritical Gasification of Biomass: Implementation of Experimental Results in a Process Simulation in
Order to Assess an Energetic Optimization .................................................................................................................................................. 40
         Olivier Boutin, Felicite Ondze, Jean-Henry Ferrasse, Jean-Christophe Ruiz, Frederic Charton

LECTURE SESSION 2B: THERMODYNAMICS-PHASE EQUILIBRIA-FLUID PROPERTIES

(L-108) Supercritical Processing of Fatty Oils: Phase Equilibrium Engineering ..................................................................................... 43
         Pablo Hegel, Guillermo Soto, Alexis Velez, Guillermo Mabe, Selva Pereda, Esteban Brignole, Susana B. Bottini
(L-109) Experimental Supercritical Phase Equilibria Measurements of Multi-component Systems ..................................................... 44
         Frederick Fourie, Cara E. Schwarz, Johannes Knoetze
(L-110) Measuring Reactions in SCF and Properties of SCF with Magnetic Suspension Balances ....................................................... 52
         Frieder Dreisbach
(L-111) Measurement and Correlation of Infinite Dilution Diffusion Coefficients in CO2 Expanded Liquids..................................... 56
         Toshitaka Funazukuri
(L-112) Modeling Tracer Diffusion Coefficients in Supercritical CO2 ....................................................................................................... 60
         Ana L. Magalhaes, Francisco A. Da Silva, Carlos M. Silva
(L-113) Numerical Simulation of Flow of Near-Critical Fluids .................................................................................................................. 66
         T. Laurila, A. Carlson, M. Do-Quang, T. Ala-Nissila, Gustav Amberg
(L-114) Thermodynamic Model for the Binary Solid Mixtures Solubilities in Supercritical Carbon Dioxide ..................................... 69
         Sivamohan N. Reddy, Giridhar Madras

LECTURE SESSION 2C: INDUSTRIAL APPLICATIONS OF CRITICAL FLUIDS - I

(L-115) Impregnation via Supercritical Fluids - Principles and Applications .......................................................................................... 76
         Eckhard Weidner
(L-116) Development of Pilot Scale Continuous Sub-Critical Water Plant to Produce Valuable Materials and
Energy from Organic Wastes and Their Dynamic and Kinetic Analyses.................................................................................................. 84
         Hiroyuki Yoshida
(L-117) Supercritical Water Oxidation – Current Status of Full-scale Commercial Activity for Waste Destruction.......................... 92
         Philip A. Marrone
(L-118) Supercritical CO2 Extraction of Omega-3 Oils from Disrupted Yarrowia Lipolytica Yeast................................................... 100
         Keith W. Hutchenson, William M. Jack II, Val Krukonis, Shu-Chien Liang, Robert D. Orlandi, Hans Schonemann, Gregg Sunshine
(L-119) Metal Extraction of Spiked Solid with Supercritical Carbon Dioxide ....................................................................................... 104
         Ming-Tsai Liang, Ru-Chien Liang, Chih-Hsiung Lin, Ping-Jui Hsu, Li-Yu Wu, Hong-Fa Chen, Yuh-Wern Wu
(L-120) Extraction of Natural Products for Industrial Applications........................................................................................................ 116
         Nadine Igl-Schmid, Andreas Wuzik
(L-121) Hanwha Chemical's Supercritical Hydro Technologies............................................................................................................... 118
         Keedo Han, Kyu-Ho Song, Sei-Ung Park, Chol-Woo Lee, Soo-Yeong Han

LECTURE SESSION 2D: NATURAL PRODUCTS, NUTRACEUTICALS AND FOOD RELATED
MATERIALS - I

(L-122) Recovery of Phytochemicals by Hybrid Extraction Process using Supercritical CO2 and Water .......................................... 119
         Motonobu Goto, Masahiro Tanaka, Armando Quitain, Mitsuru Sasaki, Ryuichi Fukuzato
(L-123) Extraction of Essential Oil and Oleoresin from Eucalyptus citriodora Leaves using Sub and Supercritical
CO2 ................................................................................................................................................................................................................... 125
          Mirelle Dogenski, Ana Carolina Velho, Debora Nascimento e Santos, Nilson Jose Ferreira, Alessandra Lopes Oliveira
(L-124) A Supercritical Fluid Based Approach to Sample Work-up, Analysis and Purification in Natural Products
Research .......................................................................................................................................................................................................... 133
          Rui Chen, Jacquelyn Runco, John P. McCauley Jr., Harbaksh Sidhu, Yongwei Xu, Lei Sang, Jing Huang, Li Yang, Zhengtao Wang,
          Liping Kang, Heshui Yu, Baiping Ma
(L-125) Supercritical Antisolvent Fractionation of Lignans from Ethanolic Extract of Flaxseed ........................................................ 141
          Giuseppe Perretti, Claudia Virgili, Ombretta Marconi, Gianfranco Regnicoli, Paolo Fantozzi
(L-126) Comparative Study Between the Supercritical Extraction and Soxhlet Extraction of Nutmeg Seed ..................................... 148
          Nik Norulaini Nik Ab Rahman, Sawsan Al Rawi, Md. Sohrab Hossain, Ahmad Ibrahim, Mohd Amin Abdul Majid, Mohd Omar Ab
          Kadir
(L-127) Lipase-catalyzed Transesterification of CO2-Expanded Canola Oil and Fully-hydrogenated Canola Oil to
Produce Base-stock for Zero-trans Margarines.......................................................................................................................................... 156
          Ehsan Jenab, Feral Temelli
(L-128) Production of Feruloylated Arabino-Polysaccharides and Oligosaccharides from Beet Fiber by using the
Hydrothermal Treatment .............................................................................................................................................................................. 161
          Nobuaki Sato, Yohei Takano, Shingo Umemura, Masahiro Mizuno, Kouichi Nozaki, Tsunetomo Matsuzawa, Yoshihiko Amano,
          Satoshi Makishima

LECTURE SESSION 3A: BIOMASS AND ENERGY-RELATED CONVERSIONS - II

(L-129) Microwave-Mediated Non-catalytic Transesterification of Algal Biomass under Supercritical Ethanol
Conditions........................................................................................................................................................................................................ 169
          Prafulla D. Patil, Harvind Reddy, Tapaswy Muppaneni, Sundar Ponnusamy, Peter Cooke, Tanner Schuab, Shuguang Deng
(L-130) Influence of Impurities on Biodiesel Production from Jatropha Curcas L. by Supercritical Methyl Acetate
Process ............................................................................................................................................................................................................. 175
          Noorzalila Muhammad Niza, Keat Teong Lee, Zainal Ahmad, Kok Tat Tan
(L-131) Application of Subcritical Water Process on Bioenergy Production .......................................................................................... 180
          Aqsha Aqsha, Ranjani Kannaiyan, Nader Mahinpey, Robert Martinuzzi
(L-132) Hydrolysis Behaviors of Lignocellulosics as Treated by Two-Step Semi-Flow Hot-Compressed Water ............................... 187
          Natthanon Phaiboonsilpa, Shiro Saka

LECTURE SESSION 3B: POLYMER, MATERIALS APPLICATIONS AND PROCESSES - I

(L-133) Pressurized Hot Water Extraction After Pre-concentration of Organics on Electrospun Nanofiber
Molecular Imprinted Sorbents...................................................................................................................................................................... 193
          Nelson Torto, Janes Mokgadi, Shima Batlokwa, N. Ngomane, S. Chigome, Charlotta Turner
(L-134) High-Pressure CO2 Aided New Processes for PET Foams Preparation..................................................................................... 195
          Ling Zhao, Hua Zhong, Dachao Li, Chao Huang, Zhenhao Xi, Tao Liu
(L-135) Polymer Architectural Effects on Solution Behavior of High Pressures: Linear, Hyperbranched, and Star
Polymers in SCF and Liquid Solvents.......................................................................................................................................................... 202
          Yue Wu, Matthew S. Newkirk, Babatunde Bamgbade, Mark A. McHugh, Val Krukonis, Paula Wetmore
(L-136) Fundamental Mechanisms of Cell Nucleation in Plastic Foaming Processes Blown with Carbon Dioxide –
Effects of Stresses ........................................................................................................................................................................................... 208
          Anson Wong, Yanting Guo, Chul B. Park

LECTURE SESSION 3C: INDUSTRIAL APPLICATIONS OF CRITICAL FLUIDS - II

(L-137) Performance of CO2 Dry-cleaning with Cavitation ...................................................................................................................... 216
          Stevia Sutanto, Victoria Dutschk, Maaike van Roosmalen, Geert Jan Witkamp
(L-138) Extraction of Polyphenols from Maritime Pine Bark by Subcritical Water at Laboratory- and Industrial-
Scale: Application of an Experimental Design ............................................................................................................................................ 221
          Clement Celhay, Celine E. Mathieu, Gerard Vilarem, Luc Rigal
(L-139) Application of Supercritical Water Gasification to Municipal Wastewater Treatment Plant: Experimental
Studies and Operational Challenges............................................................................................................................................................. 228
          Osamu Sawai, Yasunobu Tanaka, Takashi Nishihara, Teppei Nunoura, Kazuo Yamamoto
(L-140) Engineering Micronization and Coating Applications with Dense Phase Carbon Dioxide ..................................................... 236
          Fenghui Niu, Jahna Howell, Charles Decedue, David Johnston, Bala Subramaniam

LECTURE SESSION 3D: NATURAL PRODUCTS, NUTRACEUTICALS AND FOOL RELATED
MATERIALS - II

(L-141) Supercritical Carbon Dioxide Inactivation of Solid Materials .................................................................................................... 238
          Sara Spilimbergo, Giovanna Ferrentino, Sara Balzan, Alberto Bertucco
(L-142) Formation of 5-(hydroxymethyl)furfural during Subcritical Water Extraction of Natural Matrices. Is It
Bioactivity-Relevant? ..................................................................................................................................................................................... 245
          Miguel Herrero, Maria Castro-Puyana, Lourdes Rocamora-Reverte, Jose A. Ferragut, Alejandro Cifuentes, Elena Ibanez
(L-143) Production of Supercritical Rosemary Extracts and their Effect on Tumor Progression ....................................................... 251
          Gonzalo Vicente, Susana Molina, Margarita Gonzalez-Vallinas, Monica Rodriguez Garcia-Risco, Tiziana Fornari, Guillermo
          Reglero, Ana Ramirez de Molina
(L-144) Evaluation of Essential Oil Extraction of Piptadenia gonoacantha and Piptadenia rígida using
Supercritical CO2............................................................................................................................................................................................ 258
          Bruna S. Moura, Francisco E.A.C. Junior, Mario G. Carvalho, Marisa F.Mendes

LECTURE SESSION 4A: BIOMASS AND ENERGY-RELATED CONVERSIONS - III

(L-145) Hydrothermal Conversion of Glucose. 1. Analysis of the Gas, Liquid and Solid Phases Generated by
Multiscale Batch Processes ............................................................................................................................................................................ 266
          Qian Wu, Elsa Weiss-Hortala, Radu Barna
(L-146) Carbochemical Production from Switchgrass using Carbonated Subcritical Water at High Temperatures........................ 274
          Rohit Dhamdere, Keerthi Srinivas, Jerry W. King
(L-147) Characterization and Electrochemical Properties of Lithium Titanate Synthesized using Supercritical
Fluid ................................................................................................................................................................................................................. 283
          Agung Nugroho, Jaehoon Kim
(L-148) Two-Step Biomass Hydrothermal Liquefaction Process through Acidic Subcritical- followed by Alkaline
Supercritical-Water Treatment .................................................................................................................................................................... 288
          Hema Ramsurn, Ram Gupta

LECTURE SESSION 4B: POLYMERS, MATERIALS APPLICATIONS AND PROCESSES - II

(L-149) Influence of Macromolecular Characteristics of RAFT/MADIX Poly(Vinyl Acetate)-Based (Co)Polymers
on their Solubility in Supercritical Carbon Dioxide ................................................................................................................................... 291
          Etienne Girard, Thierry Tassaing, Jean-Daniel Marty, Mathias Destarac
(L-150) Miscibility and Kinetics of Phase Separation in Polymer Solutions in Dense Fluid Mixtures................................................. 298
          Erdogan Kiran
(L-151) Polymer Coatings Made by using sc-CO2 in High Pressure Techniques.................................................................................... 306
          Louise Ovaskainen, Irene Rodriguez Meizoso, Charlotta Turner, Lars Wagberg
(L-152) Fractionation of Synthetic Carbonaceous Oligomers by Supercritical Extraction using N-Methyl-2-
pyrrolidone/toluene Solvent Mixtures.......................................................................................................................................................... 309
          David F. Esguerra, Mark C. Thies

LECTURE SESSION 4C: INDUSTRIAL APPLICATIONS OF CRITICAL FLUIDS - III

(L-153) The Scale up of Continuous Hydrothermal Synthesis to Produce Industrial Quantities of Dispersed and
Formulated Nanomaterials............................................................................................................................................................................ 315
          Edward Lester
(L-154) Mixing of Hydrocarbon Droplets and Water at Supercritical or Near-Critical Conditions.................................................... 323
          Guang Wu Sadegh Dabiri, Michael T. Timko, Ahmed F. Ghoniem
(L-155) Brazilian Ginseng: Use of the Supercritical Technology to Produce the Extract ..................................................................... 331
          Marcelle Fernanda Carulo, M. Angela A. Meireles
(L-156) Investigation of Supercritical Water Phenomena for Space and Extraterrestrial Application............................................... 337
          Michael C. Hicks, Uday G. Hegde, John W. Fisher

LECTURE SESSION 4D: NATURAL PRODUCTS, NUTRACEUTICALS AND FOOD RELATED
MATERIAL - III

(L-157) A Simple Mathematical Model for Supercritical Extraction of Natural Matter....................................................................... 347
          Manuel Velasquez, Gustavo Bolanos
(L-158) Hydrolysis of Starch Processing Residues in Subcritical Water Optimal Conditions for Production of
Valuable Materials ......................................................................................................................................................................................... 355
          Junya Ishii, Hideyuki Saito, Koichi Fujie, Hiroyuki Daimon
(L-159) Recycling of Bovine Meat and Bone Meal and Inactivation of BSE Prion by Sub-Critical Water Treatment ..................... 362
          Yuji Tsutsumi, H. Bang, E. Takata, A. Fukuda, Y. Murayama, M. Yoshioka
(L-160) Subcritical Water Extraction/Reaction of Bio-Molecules from Lentil Husk ............................................................................. 367
          Marleny A. Saldana, Anupam Haldar, Víctor H. Alvarez

LECTURE SESSION 6: PLENARY LECTURE - II

(L-201) Supercritical Fluid Technology – Key to the Future .................................................................................................................... 375
          Youn-Woo Lee
LECTURE SESSION 7A: REACTIONS IN CRITICAL FLUIDS - I

(L-202) Valorization of Aquatic Biomass via Supercritical Fluid Processes ........................................................................................... 381
          Phillip E. Savage, Qingqing Guan, Jacob G. Dickinson, Peter J. Valdez, Shujauddin Changi
(L-203) Polypropylene Grafting in Supercritical Carbon Dioxide ........................................................................................................... 385
          Jacques Fages, Elisabeth Rodier, Jean-Jacques Letourneau, Martial Sauceau, Spiro Alexandratos
(L-204) Self-Optimizing Continuous Reactors: Accelerating Process Development in Supercritical Fluids....................................... 390
          Richard A. Bourne, Ryan A. Skilton, Andrew J. Parrott, Martyn Poliakoff
(L-205) Application of Supercritical Fluids in Power Engineering .......................................................................................................... 393
          Igor Pioro, Sarah Mokry, Wargha Peiman, Eugene Saltanov, Lisa Grande
(L-206) Intensified, Highly Selective Ethylene Epoxidation with Heterogeneous Catalysts in Gas-Expanded Liquids..................... 402
          Madhav Ghanta, Anand Ramanathan, Bala Subramaniam
(L-207) Chemical Modification of Natural Rubber under Supercritical Carbon Dioxide Based Hydroxy Telechelic
Liquid Natural Rubber and to Prepare the Polyurethane......................................................................................................................... 405
          Alif Duereh, Chockchai Boonchuay, Surat Areerat
(L-208) Coupling Microwave Irradiation with Supercritical Fluid Reaction System ............................................................................ 413
          Rolf Schlake, Ernest Schlegel, Al Kaziunas

LECTURE SESSION 7B: MATERIALS APPLICATIONS - I

(L-209) Unleashing the Potential of Supercritical Fluids for Polymer Processing in Tissue Engineering and
Regenerative Medicine................................................................................................................................................................................... 416
          Ana Rita Duarte, Victor E. Santo, Anabela Alves, Simone S. Silva, Joana Moreira-Silva, Tiago H. Silva, Alexandra Marques,
          Manuela E. Gomes, Rui A. Sousa, Joao F. Mano, Rui L. Reis
(L-210) Use of Supercritical Fluid Technology for the Production of Tailor-Made Aerogel Particles for Delivery
Systems............................................................................................................................................................................................................. 424
          Carlos A. Garcia-Gonzalez, Irina Smirnova
(L-211) DELOS-susp for the Production of Vesicles with Homogeneous Lipid Supramolecular Organization................................. 432
          Elisa Elizondo, Jannik Larsen, Nikos S. Hatzakis, Ingrid Cabrera, Thomas Bjoernholm, Dimitrios Stamou, Jaume Veciana, Nora
          Ventosa
(L-212) A Dense Gas Process for the Production of Liposomal Encapsulated Active Pharmaceutical Ingredients
Formulations ................................................................................................................................................................................................... 436
          Chau C. Beh, Thomas E. Jacobs, Raffaella Mammucari, Neil Foster
(L-213) Pressurized Fluid Technology in Extraction and Separation Processes – A Green Chemistry Approach ............................ 441
          Charlotta Turner, Victor Abrahamsson, Sofia Lindahl, Jiayin Liu, Firas Jumaah, Arwa Mustafa, Merichel Plaza, Abdelrahman
          Ismail, Irene Rodriguez-Meizoso, Margareta Sandahl
(L-214) Physical Stabilities of Indomethacin via Amorphization using Co-Milling and Supercritical Co-
Precipitation Processing................................................................................................................................................................................. 446
          Ron Tau Yee Lim, Wai Kiong Ng, Reginald B.H. Tan
(L-215) Microencapsulation of Proteins within Polymeric and Inorganic Particles using Supercritical CO2 Media......................... 453
          My Kien Tran, Leila Hassani, Brice Calvignac, Thomas Beuvier, François Hindre, Alain Gibaud, Frank Boury

LECTURE SESSION 7C: CO2 REMEDIATION AND ENVIRONMENTAL ASPECTS

(L-216) Pre-Combustion Capture of CO2 from Power Generation .......................................................................................................... 461
          David Luebke
(L-217) Applications of Reversible Ionic Liquids: CO2 Capture and Nanoparticle Synthesis .............................................................. 464
          Steven R. Saunders, Kyle Flack, Emily Nixon, Amy Rohan, Jackson Switzer, Elizabeth Biddinger, Pamela Pollet, Charles Liotta,
          Charles A. Eckert
(L-218) Thermodynamic Modeling of the Solubility of Supercritical CO2 and Other Gases on Ionic Liquids with
the soft-SAFT Equation of State ................................................................................................................................................................... 469
          Felix Llovell, M. Belo, Oriol Vilaseca, Joao A.P. Coutinho, Lourdes F. Vega
(L-219) NIR-inline-Monitoring for Micronization Processes in Supercritical CO2 ................................................................................ 475
          Dennis Bohm, Thomas Grau, Siegbert Johnsen, Ewelina Kaczowka, Alexander Klotz, Michael Tuerk, Gabriele Wiegand, Beat
          Zehnder
(L-220) Reversible Ionic Liquids for CO2 Capture from High Pressure Streams .................................................................................. 479
          Amy L. Rohan, Jackson R. Switzer, Kyle M. Flack, Emily C. Nixon, Amber C. Rumple, Elizabeth J. Biddinger, Manish Talreja,
          Pamela Pollet, Charles L. Liotta, Charles A. Eckert
(L-221) Photo-Reduction of CO2 to Fuel by Novel Nanocatalysts Produced using Continuous Hydrothermal
Synthesis .......................................................................................................................................................................................................... 485
          Haiping Shen, Edward Lester, Trevor Drage
(L-222) Pre-Combustion Capture of CO2 with Hydrophobic Polymers .................................................................................................. 493
          Robert Enick, Matt Miller, Sam McNulty, Hunaid Nulwala, David Luebke

LECTURE SESSION 7D: NOVEL SCF EXPERIMENTAL TECHNIQUES

(L-223) Complementarities Between Supercritical Micro- and Millifluidic Synthesis of Nanocrystals for Advanced
Nanostructured Materials ............................................................................................................................................................................. 499
          Cyril Aymonier, Yann Roig, Samuel Marre
(L-224) Jet Cutting with Liquid Carbon Dioxide ....................................................................................................................................... 504
          Lena Engelmeier, Stefan Pollak, Andreas Kilzer, Eckhard Weidner
(L-225) Novel Supercritical Fluid Deposition Technique of SiO2 using Flow Channel Reactor ........................................................... 508
          Takeshi Momose, Aiko Kondo, Hideo Yamada, Junji Ohara, Yasuhiro Kitamura, Hirohisa Uchida, Yukihiro Shimogaki, Masakazu
          Sugiyama
(L-226) Preparation of Supported Metallic Nanoparticles using Supercritical Fluids........................................................................... 515
          Michael Tuerk, Marlene Crone, Sabrina Mueller
(L-227) Enzimatic Synthesis of Poly(ε-caprolactone) in Supercritical Carbon Dioxide......................................................................... 520
          Sibele R. Rosso Comim, Emanuel Bianchin, Debora de Oliveira, J. Vladimir de Oliveira, Sandra R. S. Ferreira
(L-228) High-Pressure Microfluidics to Explore Multi-Phase Systems: A Study Towards the Supercritical Fluid
Extraction of Emulsions (SFEE)................................................................................................................................................................... 527
          Sebastian Luther, Andreas Braeuer
(L-229) In-situ Spectroscopic Ellipsometry of Cu Deposition Process from Supercritical Fluids - Evidence for a
Surface Condensation Layer Formation...................................................................................................................................................... 533
          Eiichi Kondoh, Takuya Sasaki, Yukihiro Tamegai, Mitsuhiro Watanabe, Lianhua Jin, Takahiro Ueno

LECTURE SESSION 8A: BIOMEDICAL APPLICATIONS - I

(L-230) New Insights in Drug Processing using Supercritical Fluids ....................................................................................................... 541
          Elisabeth Badens, Christelle Crampon, Laurene Lesoin, O. Boutin, Yasmine Masmoudi
(L-231) Supercritical CO2 Assisted Fabrication and Impregnation of PCL-Gelatin Based Scaffolds for Advanced
Biomedical Applications ................................................................................................................................................................................ 549
          Hrishikesh Munj, Tyler Nelson, John Lannutti, David Tomasko
(L-232) Compressed Carbon Dioxide - A Green Washing Fluid for Medical Parts ............................................................................... 554
          Sabine Kareth, Martin Bilz, J. Mankiewicz, M. Petermann, D. Rebien, M. Wehrl
(L-233) Development of a Supercritical Precipitation Process of Calcium Carbonate for Biomedical Applications ......................... 560
          Brice Calvignac, Thomas Beuvier, Leila N. Hassani, François Hindre, Alain Gibaud, Frank Boury

LECTURE SESSION 8B: GREEN CHEMISTRY, ENGINEERING AND SUPERCRITICAL FLUIDS - I

(L-234) Green Solvents for Catalysis: From Molecular Understanding to Continuous-Flow Processes ............................................. 567
          Walter Leitner
(L-235) Environmental Impact Assessment of Conventional and Supercritical Biodiesel Production Processes
using the Waste Reduction (WAR) Algorithm............................................................................................................................................ 569
          Victor F. Marulanda
(L-236) Water and Benzyl Alcohol in Subcritical and Supercritical Conditions as Means for Carbon Fiber
Recovery from Thermoset Composite Materials ........................................................................................................................................ 574
          Rodolfo Morales Ibarra, Antonio F. Garcia Loera, S. M. Garcia Montes, Armando T. Quitain, Mitsuru Sasaki, Motonobu Goto
(L-237) Greener Solvents for Old Challenges ............................................................................................................................................. 580
          Mohammad-Taghi Golmakani, Jose A. Mendiola, Karamatollah Rezaei, Elena Ibanez

LECTURE SESSION 8C: PROCESS DESIGN AND ECONOMICS - I

(L-238) Cost of Manufacturing of Vegetable Extracts Obtained by Supercritical Fluid Extraction and Pressurized
Liquid Extraction: Assisted or Not by Ultrasound ..................................................................................................................................... 585
          Priscilla C. Veggi, Juliana M. Prado, M. Angela Meireles
(L-239) Free of Water Tanning – Intensified by CO2 Parameter and Scale up Study ........................................................................... 593
          Manfred Renner, Eckhard Weidner, Helmut Geihsler, Thomas Heinen
(L-240) Economical Analysis of the Supercritical CO2 Fractionation of Capsicum Liquid Oleoresin................................................. 601
          Maria Pilar Fernandez-Ronco, Maria Teresa Garcia, Juan Francisco Rodriguez, Rosario Mazarro, Ignacio Gracia
(L-241) Modeling and Optimization of the Supercritical Wood Impregnation Process - Focus on Pressure and
Temperature.................................................................................................................................................................................................... 609
          Joao Fernandes, Anders W. Kjellow, Ole Henriksen

LECTURE SESSION 8D: SEPARATION PROCESSES - I

(L-242) Oxide Nanomaterials in Supercritical CO2 Phase: From Nano-powders to Membrane Preparation using
Original Supercritical Carbon Dioxide On-stream Deposition Process................................................................................................... 617
          Audrey Hertz, Veronique Durand, Jean-Christophe Ruiz, Stephane Sarrade, Christian Guizard, Anne Julbe
(L-243) Sequential Fractionation of Milk and Whey Proteins with Supercritical Carbon Dioxide for New Health-
Promoting Food Ingredients ......................................................................................................................................................................... 623
          Laetitia M. Bonnaillie, Peggy M. Tomasula
(L-244) Semi-Preparative Supercritical Chromatography Scale Plant for Polyunsaturated Fatty Acids Purification ..................... 629
          Fernando Montanes, Owen Catchpole, Stephen Tallon, Kevin Mitchell, Kirill Lagutin
(L-245) Supercritical Extraction and Fractionation of Biopolymers and Resins from Plant Materials .............................................. 634
          Rodger Marentis, Jeff Martin
LECTURE SESSION 9A: BIOMEDICAL APPLICATIONS - II

(L-246) Supercritical Development of Sustained Drug Delivery Intraocular Lenses ............................................................................. 642
          Yasmine Masmoudi, Abir Bouledjouidja, Olivier Forzano, Jean Marie Andre, Elisabeth Badens
(L-247) Fabrication of Porous Chitosan/Bioactive Glass Hydrogels in an Aqueous Media using CO2 as a Gas
Foaming Agent................................................................................................................................................................................................ 649
          Ali Fathi, Michael Bernard, Roya Ravarian, Fariba Dehghani
(L-248) Engineering Supercritical Carbon Dioxide Assisted Lipid Nanocarriers: Statistical Optimization....................................... 656
          Megha Swami, Vandana Patravale

LECTURE SESSION 9B: GREEN CHEMISTRY, ENGINEERING AND SUPERCRITICAL FLUIDS - II

(L-249) The Applicability of Subcritical Fluids to the Conservation of Actively Corroding Metallic Cultural
Heritage ........................................................................................................................................................................................................... 660
          Liisa Nasanen, Nestor Gonzalez-Pereyra, Stephanie Crette, Philippe DeVivies
(L-250) ScCO2/Glycerol: A Biphasic Green System for Process Intensification ..................................................................................... 668
          Yaocihuatl Medina-Gonzalez, Jean-Stephane Condoret, Thierry Tassaing, Severine Camy
(L-251) Supercritical Alcoholysis of Sunflower Wet Sludge to Produce Fatty Esters ............................................................................ 675
          Guillermo Soto, Alexis Velez, Pablo Hegel, Guillermo Mabe, Selva Pereda

LECTURE SESSION 9C: PROCESS DESIGN AND ECONOMICS - II

(L-252) De-Oiling of Raw Lecithin by High Pressure Extraction Processes............................................................................................ 683
          Volkmar Steinhagen, Christoph Luetge, Michael Bork, Masa Knez Hrncic, Zeljko Knez
(L-253) Costs Estimation for the Supercritical CO2 Extraction of Prepressed Oilseeds........................................................................ 687
          Jose M. del Valle, Gonzalo A. Nunez
 (L-254) Supercritical CO2 Extraction of Lipids Contained in Three Different Microalgae (Chlorella,
Nannochloropsis oculata and Dunaliella salina): Study of the Influence of Water Content and Pre-Treatment on
the Extraction Kinetics and Yields ............................................................................................................................................................... 688
          Adil Mouahid, Christelle Crampon, Elisabeth Badens

LECTURE SESSION 9D: SEPARATION PROCESSES - II

(L-255) Going Greener in Achiral and Chiral Separations: Employing Sustainable Technologies to Reduce our
Environmental Impact ................................................................................................................................................................................... 695
          Rachel M. Schmidt, Celia Ponder, Manon S. Villeneuve, Luke A. D. Miller
(L-256) Mathematical Modelling of Palm Kernel’s Oil-Bearing Cell during Supercritical Fluid Extraction: One
Dimensional Problem ..................................................................................................................................................................................... 701
          Abu Hanipah Nawi, Mohd Omar Ab Kadir, Nik Norulaini Nik Ab Rahman
(L-257) Adsorption of 2-Phenylethyl Alcohol from Supercritical CO2 on Silica Aerogel ...................................................................... 707
          Xiaohui Hu, Shengxuan Zheng, Wensheng Lv, Hongqiao Lan, Yanzhen Hong, Yuzhong Su, Hongtao Wang, Jun Li

LECTURE SESSION 11: PLENARY LECTURE - III

(L-301) Where Are We Today: May 2012? ................................................................................................................................................. 711
          Val Krukonis

LECTURE SESSION 12A: SCF PARTICLE/FILM TECHNOLOGY - I

(L-302) Supercritical Route for Super Hybrid Materials .......................................................................................................................... 717
          Tadafumi Adschiri, S. Takami, K. Minami, T. Yamagata, K. Miyata, T. Morishita, M. Ueda, K. Fukushima, M. Ueno, T. Okada, H.
          Oshima, Y. Mitani, S. Asahina, S. Unno
(L-303) Reverse Micelle Synthesis of Monodispersed Metallic Nanoparticles in Gas Expanded Liquids ........................................... 722
          Ashley E. Hart, David B. Akers, Samuel Gorosh, Christopher Kitchens
(L-304) Synthesis of Nanocomposites using Supercritical Fluids.............................................................................................................. 729
          Zhimin Liu
(L-305) Supersaturation as Criterion for the Appearance of Amorphous Particle Precipitation or Crystallization in
the Supercritical Antisolvent (SAS) Process................................................................................................................................................ 730
          Matthias Rossmann, Andreas Braeuer, Alfred Leipertz, Eberhard Schluecker
(L-306) Tunable Steric Stabilization Effects on Size-Selective Nanoparticle Dispersability in Gas Expanded Liquid
Systems............................................................................................................................................................................................................. 736
          Pranav S. Vengsarkar, Jennifer N. Boice, Christopher B. Roberts
(L-307) Supercritical CO2 as a Tool for Nanodevice Formation using Sol-Gel Chemistry.................................................................... 741
          Paul A. Charpentier, Nasrin Farhangi, Serge Ayissi, Golam Moula, Adria Lotus, Qasem Alsharari
(L-308) Preparation and Evaluation of MnOx-CeO2 Nanospheres via a Supercritical Anti-solvent Process ..................................... 742
          Haoxi Jiang, Dongyu Jiang, Xiuqin Dong, Minhua Zhang
LECTURE SESSION 12B: PHARMACEUTICAL APPLICATIONS - I

(L-309) Process Intensification in the Pharmaceutical Sector using Alternative Media ........................................................................ 750
          Neil R. Foster, R. B. Yoganathan, Y. Pu, J. Lee, R. Mammucari
(L-310) One-step Methodology for Integration of Actives in Nanovesicles using Compressed Fluids ................................................. 757
          Ingrid Cabrera, Elisa Elizondo, Olga Esteban, Jose Luis Corchero, Marta Melgarejo, Daniel Pulido, Alba Cordoba, Evelyn
          Moreno, Esther Vazquez, Fernando Albericio, Miriam Royo, Antonio Villaverde, Maria Parajo, Nora Ventosa, Jaume Veciana
(L-311) CO2-assisted High Pressure Homogenization: A Solvent-free Process for Polymeric Microspheres ..................................... 761
          Johannes Kluge, Marco Mazzotti
(L-312) Encapsulation of Nanoparticles by Pressure Reduction Over CO2- Expanded Liquids .......................................................... 763
          Madhu Vinjamur, Mohd Javed, Mamata Mukhopadhyay
(L-313) Interpenetrating Polymer Networks for Drug Delivery Devices ................................................................................................. 771
          Martin Alm, Soern L. Steffensen

                                                                                                VOLUME 2

(L-314) Potential Technique for the Production of Micronized Lactose Crystals by Supercritical Fluid
Conditioning.................................................................................................................................................................................................... 778
          Syed Anuar Faua'ad Syed Muhammad, Patricia Tang, Hak-Kim Chan, Fariba Dehghani
(L-315) Supercritical Fluid Drying of High Molecular Weight Biopolymers for Particle Formation and Delivery of
Bioactives......................................................................................................................................................................................................... 785
          Bernhard Seifried, Feral Temelli

LECTURE SESSION 12C: SUPERCRITICAL FLUIDS-IONIC LIQUIDS/COUPLED MEDIA

(L-316) Engineering Reactions in Biphasic Ionic Liquid/CO2 Systems: Homogeneous Catalysis and Synthesis of
Ionic Liquids ................................................................................................................................................................................................... 793
          Aaron Scurto
(L-317) Limiting Partition Coefficients of Organic Solutes in Ionic Liquid–Supercritical Carbon Dioxide Systems
from Generalized Linear Solvation Energy Model..................................................................................................................................... 799
          Josef Planeta, Pavel Karasek, Barbora Hohnova, Lenka Stavikova, Michal Roth
(L-318) Development of Supported Ionic Liquid Membranes for High Pressure Separations ............................................................. 807
          Ricardo M. Tomas do Couto, Rui Ruivo, Pedro Calado Simoes
(L-319) Ion Aggregation During Ionic Liquid Co-Solvent Based Lipid Extraction ............................................................................... 813
          Santosh Bandlamudi, Kenneth M. Benjamin, Michael Cooney, Georgianna Martin
(L-320) A Low-Viscosity Family of Ionic Liquids Based on the Tetracyanoborate Anion for CO2 Capture ...................................... 819
          Maria Teresa Mota Martinez, Mamoun Althuluth, Maaike C. Kroon, Cor J. Peters
(L-321) Development of a Supercritical Assisted Particle-Agglomeration Method for the Preparation of Bioactive
Chitin-based Matrices .................................................................................................................................................................................... 822
          Simone S. Silva, Ana Rita C. Duarte, Joao F. Mano, Rui L. Reis
(L-322) Thermodynamic Prediction of Vapor-Liquid Equilibrium of Binary Systems of Ionic Liquids +
Hydrocarbons using Peng Robinson Equation of State ............................................................................................................................. 828
          Victor H. Alvarez, Marleny D. A. Saldana

LECTURE SESSION 12D: HYDROTHERMAL PROCESSING AND INORGANIC MATERIALS - I

(L-323) Hydrothermal Processing and In Situ Surface Modification of Metal Oxide Nanomaterials ................................................. 835
          K. Byrappa, K. Namratha
(L-324) Synthesis of Cathode/Anode Active Materials for Large-Scale Li 2nd Battery in Supercritical Fluids .................................. 843
          Jaehoon Kim, Agung Nugroho, Seung-Ah Hong, Eduardus Budi Nursanto
(L-325) Supercritical Production of Cubic Gadolinium Oxides for Real-Time Neutron Detection ..................................................... 851
          Peter Molnar, Jennifer I. Brand
(L-326) A Theoretical Study of Factors Affecting Corrosion in Supercritical Water Reaction Vessels............................................... 856
          Simon J. Halstead
(L-327) SCWO of Hydrocarbon-Contaminated Waters: Continuous Systems with Split-Entry Oxidant .......................................... 860
          Bushra Al-Duri, Iain Kings, Belen Garcia-Jarana, Juan Ramon Portels
(L-328) Hydroxide-Enhanced Hydrothermal Drilling and the Solubility of the Silica-NaOH-Sub and Supercritical
Water System .................................................................................................................................................................................................. 867
          Adam G. Carr, Jefferson W. Tester
(L-329) Large-Scale Synthesis of ZnO Nanocrystals with Size-controlled in Continuous Hot Compressed Water ........................... 875
          Zhiqiang Mao, Shining Li, Yaping Zhao

LECTURE SESSION 13A: SCF PARTICLE/FILM TECHNOLOGY - II

(L-330) Rapid Expansion of Supercritical Solutions from Ternary Mixtures: Towards a Green Production of
Microcomposite Surfaces............................................................................................................................................................................... 881
          Irene Rodriguez Meizoso, Pontus Olin, Josefin Illergard, Lars Wagberg, Charlotta Turner
(L-331) Binary Adsorption of Platinum and Copper Complexes from Supercritical Carbon Dioxide on Carbon
Aerogels for the Synthesis of Supported Bimetallic Nanoparticles........................................................................................................... 885
         Selmi Erim Bozbag, Svetlana O. Kostenko, Michael A. Kurykin, Lichun Zhang, Mark Aindow, Can Erkey
(L-332) Development of Aerogel Catalyst with Tunable Nanoporosity and Photocatalytic Activity through
Supercritical Drying and Impregnation....................................................................................................................................................... 893
         Haitao Li, Sermin Sunol, Aydin K. Sunol
(L-333) Strategies for Nanoparticle Design of Racemic Ibuprofen by Rapid Expansion of Supercritical Solutions
(RESS) Technique Using Supercritical Carbon Dioxide............................................................................................................................ 901
         Hirohisa Uchida, Junichi Sakabe, Kohei Demoto, Ryota Nakazawa, Daisuke Kondo, Ayumu Kataoka, Takashi Kokubun, Masayoshi
         Ito, Nobuhiro Sugimoto

SESSION 13B: PHARMACEUTICAL APPLICATIONS - II

(L-334) Utilization of sc-CO2 in the Preparation of Hemocompatible, Cell Scaffolding Cellulose Phosphate
Aerogels for In vivo Preparation of Bone Tissue ........................................................................................................................................ 909
         Christian Schimper, Ramona Dunareanu, Emmerich Haimer, Martin Wendland, Dieter Loidl, Manfred Maitz, Philipp Seib,
         Carsten Werner, Maia-Alexandra Neouze, Jean-Marie Nedelec, A. Hardy-Dessources, Antje Potthast, Thomas Rosenau, Falk
         Liebner
(L-335) Fabrication of Lipid Nanocarrriers of Levodopa using Supercritical Fluid Technology......................................................... 912
         Clara B. Fernandes, Vandana B. Patravale
(L-336) SC-CO2 Processing of Biodegradable Nanoparticles with Sustained Release of Functional siRNA....................................... 914
         Gunilla B. Jacobson, Emilio Gonzalez-Gonzalez, Roger L. Kaspar, Christopher H. Contag, Richard N. Zare
(L-337) Development of Supercritical Fluid Extraction and Supercritical Fluid Chromatography Purification
Methods using Rapid Solubility Screening to Support Drug Discovery .................................................................................................. 919
         Kyung Gahm, Ke Huang

LECTURE SESSION 13C: REACTIONS IN CRITICAL FLUIDS - II

(L-338) Kinetic Resolution in sc-CO2 - Design of Continuous Reactor Based on Results of Batch Experiments ............................... 920
         Edit Szekely, Margita Utczas, Bela Simandi
(L-339) Advancement of Fischer-Tropsch Synthesis with Integrated Product Upgrading via Utilization of
Supercritical Fluid Reaction Media ............................................................................................................................................................. 922
         Sihe Zhang, Rui Xu, Christopher B. Roberts
(L-340) Simultaneous Assessment of Intrapellet Heat and Mass Transfer Limitations for Supercritical Phase
Fischer-Tropsch Synthesis............................................................................................................................................................................. 927
         Aswani K. Mogalicherla, Elfatih E. Elmalik, Nimir O. Elbashir
(L-341) Reversible Reactions of Carbon Dioxide with Amines Employing a Protection/Deprotection Mechanism........................... 936
         Fiaz S. Mohammed, Christopher L. Kitchens

LECTURE SESSION 13D: HYDROTHERMAL PROCESSING AND INORGANIC MATERIALS - II

(L-342) New Methane Fermentation Process using Subcritical Water Treatment for Sewage Sludge ................................................ 943
         Eiichi Hasegawa
(L-343) Production of Nano-Oxides with a Continuous Supercritical Water Device ............................................................................. 946
         Frederic Demoisson, Moustapha Ariane, Romain Piolet, Antoine Leybros, Coralie Quadri, Frederic Bernard
(L-344) Hydrothermal and Solvothermal Syntheses, In situ Surface Modification and Antioxidant Activity of Co-
Doped Advanced ZnO Nanoparticles........................................................................................................................................................... 950
         Namratha Keerthiraj, K. Byrappa, S. Rajesh, V. Ravishankar Rai
(L-345) Determination of the Equilibrium Constant for the Decomposition of Potassium Bicarbonate in Water at
Near-Critical Conditions ............................................................................................................................................................................... 958
         Maider Legarra Arizaleta, Ashley Blitz, Daniel Kahoonei, Zsuzsanna Czegeny, Michael Antal

LECTURE SESSION 14A: SCF PARTICLE/FILM TECHNOLOGY - IIII

(L-346) Hollow Fibers by Electrospinning in Supercritical CO2 .............................................................................................................. 961
         Detlef Freitag, Alexander Guenther, Wolfgang Arlt, Mark Mc Hugh
(L-347) Dielectric Property of Titanium Dioxide Thin Films Fabricated by Supercritical Fluid Deposition...................................... 964
         Hiroshi Uchida, Yuuki Nakagawa, Yuma Hayakawa, Kazuyuki Sekino, Seiichiro Koda
(L-348) A New Supercritical Assisted Atomization Layout for the Micronization of Thermolabile Compounds .............................. 972
         Renata Adami, Sara Liparoti, Ernesto Reverchon
(L-349) Effect of Solvent Condensation During Rapid Expansion of Supercritical Solutions .............................................................. 979
         Victor Stepanov, Lev Krasnoperov

LECTURE SESSION 14B: PHARMACEUTICAL APPLICATIONS - III

(L-350) Preparation of Biodegradable Alginate Aerogels Used as Carriers for Drug Delivery............................................................ 980
         Zoran Novak, Anja Veronovski, Zeljko Knez
(L-351) Use of Supercritical Fluid Chromatography (SFC) to Support in Rapid Development of Pharmaceutical
Candidates ....................................................................................................................................................................................................... 985
          Jimmy O. DaSilva, Derek Henderson, Amanda M. Makarewicz
(L-352) Precipitation of Ultra-fine Particles by Pressure Reduction of Gas Expanded Liquids: Experiments and
Mathematical Modeling ................................................................................................................................................................................. 987
          K. Arjun Kumar, Mamata Mukhopadhyay, Madhu Vinjamur, Sameer Dalvi
(L-353) Expanding the Versatility of SFC through New Enhancements to MS Directed, Open Bed Fraction
Collection Systems .......................................................................................................................................................................................... 995
          Steven Zulli, Jonathan L. Jones, Chuping Luo, Timothy P. Martin, Ziqiang Wang, Harbaksh Sidhu

LECTURE SESSION 14C: MATERIALS APPLICATIONS - II

(L-354) Bioactive Glasses Loaded with Dexamethasone by a Supercritical Carbon Dioxide Deposition Process ............................ 1001
          Luisa Filipe, Ana Paula Piedade, James J. Watkins, Mara E. Braga, Herminio C. de Sousa
(L-355) Stable Emulsions in Biphasic Whole-cell Biocatalysis: The Potential of sc- CO2 for an Industrial Scale DSP ................... 1007
          Christoph Brandenbusch, Jonathan Collins, Bruno Buehler, Andreas Schmid, Gabriele Sadowski
(L-356) Chiral Resolution of Ibuprofen via Diastereomeric Salt Formation in Supercritical Carbon Dioxide ................................ 1008
          Gyorgy Bansaghi, David Mendez Sevillano, Bela Simandi, Zoltan Juvancz, Edit Szekely
(L-357) Formation of Drug-Cyclodextrin Inclusion Compounds via Melting in Carbon Dioxide + Co-Solvent
Mixtures......................................................................................................................................................................................................... 1010
          Heather E. Grandelli, Abby Whittington, Erdogan Kiran

LECTURE SESSION 14D: HYDROTHERMAL PROCESSING AND INORGANIC MATERIALS - III

(L-358) Etching of Silicon under Subcritical Conditions: A Greener Approach .................................................................................. 1018
          Nestor G. Gonzalez-Pereyra, Stephanie A. Crette, Olin Thompson Mefford
(L-359) Applications of Supercritical Water Technologies in Advanced Energy Systems .................................................................. 1025
          Morgan L. Thomas, Gaelle Dupouy, Ian S. Butler, Ajay K. Dalai, Janusz A. Kozinski
(L-360) Hydrothermal Processing of Oxide Materials for Functionalities ............................................................................................ 1027
          Guangshe Li, Liping Li
(L-361) The Synthesis of Novel BaTeM2O9 (M = Mo or W) Ultrafine Particles in Supercritical Water System .............................. 1030
          Bo Li, Rong Zhang, Xutang Tao

POSTER SESSION P-0100: BIOMASS AND ENERGY-RELATED CONVERSIONS

Production of Biodiesel with Glycerol Carbonate by Non-Catalytic Supercritical Dimethyl Carbonate .......................................... 1033
          Zul Ilham, Shiro Saka
Effect of Purification of Waste Cooking Oil using Supercritical CO2 Extraction on the Production of Hydrotreated
Biodiesel (HBD) ............................................................................................................................................................................................ 1038
          Seok Ki Kim, Jae Young Han, Seung-Ah Hong, Jaehoon Kim
Wood Liquefaction in Supercritical Alcohol ............................................................................................................................................. 1043
          Steffen Brand, Jaehoon Kim
Subcritical Water Pretreatment of Lignocellulosic Biomass ................................................................................................................... 1048
          Hun Wook Lee, Aye Aye Myint, Dae Sung Kim, Junho Yoon, Youn-Woo Lee
Continuous Biosynthesis of Biodiesel from Lipids of Corn Distillers’ Dried Grains in Supercritical Carbon Dioxide ................... 1052
          Ozan Nazim Ciftci, Feral Temelli
Biodiesel Production from Vegetable Oil using Sulfated Zirconia via Supercritical Transesterification:
Optimization Study ...................................................................................................................................................................................... 1057
          Sheila Adell, Aline Santana, Cristian Ledesma, Eliana Ramirez, Jordi Llorca, Maria Angeles Larrayoz
Optimization of Biodiesel Production by Supercritical Transesterification of Edible, Non-edible and Algae Oils .......................... 1058
          Aline Santana, S. S. Jesus, M. A. Larrayoz, R. M. Filhol
A Greener Approach to Biodiesel Production........................................................................................................................................... 1060
          Pedro Lisboa, Jose Martin, Ana Rita Rodrigues, Pedro Simoes, Susana Barreiros, Alexandre Paiva
Biomass Conversion for the Microalgae Slurry using the Supercritical Methanol Method................................................................ 1066
          Atsushi Kishita, Diah Ajeng Setiawati, Gede Suantika
Liquid and Supercritical CO2 Extraction of Fat from Rendered Materials and Solubility Correlation ........................................... 1071
          Jose Luis Orellana, Tyler Smith, Christopher L. Kitchens
Aqueous Reactive Pretreatment of Switchgrass for Oligomeric Sugar Production ............................................................................. 1077
          Yu-Wu Lu, Keerthi Srinivas, Jerry W. King
Carbochemical Production from Switchgrass using Carbonated Subcritical Water at High Temperatures.................................... 1083
          Rohit Dhamdere, Keerthi Srinivas, Jerry W. King
Transesterification of Rapeseed Oil with Supercritical Ethanol at Low Molar Ratios. Extraction of Valuable
Components................................................................................................................................................................................................... 1092
          Farid Gumerov, Rustem Usmanov, Radif Gabitov, Chamil Biktach, Ilmutdin Abdulagatov
Cellulose and Sugarcane Bagasse Hydrolysis using Subcritical Water.................................................................................................. 1097
          Juliana M. Prado, Luiz A. Follegatti-Romero, Fiorella P. Cardenas-Toro, Tania Forster-Carneiro, M. Angela A. Meireles,
          Mauricio A. Rostagno
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