Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
Webinar:
Minimize Fire Risk in USB-C Conne ctors

John Hsieh
Advanced Engineering Manager, DSM Engineering Materials

April 14, 2021
Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
Introduction

                               • Taiwanese, lived in Shanghai for 15 years

                               • Master degree in Mechanical Engineering

                               • 20 years’ of experience in a broad range of electronics
                                 applications across the value chain (electronics devices PM,
                                 connector PM, industry marketing and then engineering material
                                 technical marketing)

                               • Joined DSM in 2013 at Shanghai, and then relocated to California
                                 in 2016, moved back to Shanghai again in 2018.
         John Hsieh
Advanced Engineering Manager
  DSM Engineering Materials
Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
Quick facts and figure s
DSM Engineering Materials and DSM overall

       DSM          Workforce       Ne t sale s        R&T Inve stme nt         Production                         Te chnology
    Engine e ring
     Mate rials     ~1,900        ~€ 1.4 bn               ~4.5%                     8                                  ~90%
                                  Figure s for 2019         of re ve nue        production               of all ne w cars and e le ctronics
                                                       re inve ste d in R&T      facilitie s              de vise s use DSM te chnology

       DSM          Workforce         Ne t sale s              Safe ty                                       Plane t
      ove rall
                    21,000        € 9.01 bn                    0.28                            #1                          AAA
                    e xcluding     Figure s for 2019       fre que ncy inde x               globally in                 rating in the
                    affiliate s                              of re cordable               sustainability                 MSCI inde x
                                                           injurie s for 2019            by Sustainalytics

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
Quick facts and figure s
Global footprint to support our customers

                                                                                                                                     Togliatti - Russia
                                                                               Emme n -            Düsse ldorf - Ge rmany
                                                                              Ne the rlands

                                                                                                                                                       Jiangyin - China
                                                                                                                                                                              Inche on – South Kore a
                                          Evansville - USA                                                 Sittard - Ne the rlands
                                                                         Ge nk - Be lgium                                                 Shanghai-China
                                                                                                                                                                                     Tokyo - Japan
                                                                                                       Ge le en - Ne the rlands
                                                                                                                                          She nze n-China
                                                             De troit - USA                                    Pantnagar - India
                  Silicon Valle y - USA
                                                                                                                 Gurgaon - India                                             Taipe i - Taiwan

                                                                                                                     Pune - India                                            Kaohsiung - Taiwan
                              Que ré taro - Me xico
                                                                                                                       Che nnai- India                               Ho Chi Minh City - Vie tnam

                                                                                                                                  Bangkok - Thailand          Singapore
DSM Engineering Materials
       Production locations
                                                                              São Paulo - Brazil
       R&D locations
       Office s

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
USB-C: The most popular data & powe rful inte rface in the
consume r e le ctronics industry
    One connector for many devices

        Tablet       Earphone        HDD   Power   TV   Laptop

      Smartphone                                        Desktop

     Smart speaker                                      AR / VR

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
The mobile phone e volution
Thinnovation & Integration
                            Evolution                                                Evolution
                            2007 - 2017                                              1988 - 2020

                                     Highe r Powe r
     Advance d Fe ature s                             Highe r Batte ry Capacitie s      Fast Charging
                                     Consumption

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
Fast Charging standards

                                                 Samsung                                          MediaTek    Qualcomm Motorola
                                USB 3.1                       Oppo       OnePlus      Huawei      PumpExpress Quick     TurboPower
Charging        USB 2.0 USB 3.0                  Adaptive
                                (USB-C +                      Super      WarpCharge   SuperCharge 4.0         Charge 5* 30
Technology      port    port                     Fast
                                USB PD)                       VOOC       30           2.0
                                                 Charger                                            (USB-PD)   (USB-PD)  (USB-PD)

Max Power       2.5W    4.5W        100W         45W          65W        30W          40W         25/ 30W         100W+       28.5W

                                                                                                  3V - 6V         5V/ 9V(USB
Voltage         5V      5V          5V - 20V     5/ 9/ 20V    5/ 10V     5V           5/ 9/ 10V                   PD)        5/ 9/ 12V
                                                                                                  (10-20mV pe r   3.6V~20V
                                                                                                  ste p)
                                    0.5A/ 0.9A/ 2/ 1.67/ 2.25                                                                 5.7/ 2.85/ 2.15
Current         0.5A    0.5/ 0.9A                             10/ 6.5A   2/ 6A        2/ 2/ 4A    5A+             5A+
                                    1.5A/ 3A/ 5A A                                                                            A

    •   Qualcomm announced the Quick Charge 5 solution on July 27th , 2020. XiaoMi, ASUS, Lenovo and Samsung have
        announced to use this technology in their new flagship models.

    •   The USB PD and various fast charging standards increase the burning risk dramatically, and this brings a new
        challenge to smartphone and connector designers.

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
The diffe re nt ge ne rations of USB conne ctor
Available receptacles for each connector                                                                                                                          Connector type Zoom in
                   USB 1.0               USB 2.0               USB 2.0          USB 3.0            USB 3.1                   USB 3.2                   USB4
Generations         1996                  2001                 Revised           2011               2014                      2017                     2019
                  1.5 Mbit/ s                1.5 Mbit/ s (Low Spe e d)
                 (Low Spe e d)                       12 Mbit/ s                                                                                   40 Gbit/ s
                                                                                 5 Gbit/ s        10 Gbit/ s             20 Gbit/ s
Data rate                                          (Full Spe e d)                                                                             (SuperSpe ed+ and
                   12 Mbit/ s                                                 (SuperSpe ed)    (SuperSpe ed+)         (SuperSpe ed+)
                                                    480 Mbit/ s                                                                                 Thunde rbolt 3)
                 (Full Spe e d)                   (High Spe e d)

               Type A                                                       Type A
                                                                                                                                                  De pre cate d
Standard
               Type B                                                       Type B                                      De pre cate d

                                                       N/ A                                   Type C (e nlarge d)

                                    Mini A
                        N/ A
Mini                                Mini B                                                                   De pre cate d

                                  N/ A                    Mini AB

                                                                                                     N/ A

                                                          Micro B           Micro B                                                    De pre cate d
Micro                             N/ A

                                                          Micro AB                                           De pre cate d

                   USB 1.0               USB 2.0                USB 2.0         USB 3.0            USB 3.1                   USB 3.2                   USB4               Type C        Type C
Connectors                                                                                                                                                             re ce ptacle s    plugs
                    1996                  2001                  Re vise d        2011               2014                      2017                     2019

8USB type     C connector is the only one interface to support USB 4 and onward version’s USB devices.
Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
Thunde rbolt 3, 4 & USB 4

               Thunderbolt is used in high end laptop/ ultrabook.

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Webinar: Minimize Fire Risk in USB-C Connectors - John Hsieh Advanced Engineering Manager, DSM Engineering Materials - UL Prospector ...
USB4 SI analysis
Both ForTii Eco E11 and Stanyl HFX33S meet USB 4 standard

     Item      Plug (Dk, Df)        Rec (Dk, Df)
     1         LCP (3.4, 0.004)     LCP (3.4, 0.004)
     2         E11 (3.6, 0.01)      E11 (3.6, 0.01)
     3         HFX33 (3.48, 0.01)   HFX33 (3.48, 0.01)
     4         LCP (3.4, 0.004)     E11 (3.6, 0.01)
     5         LCP (3.4, 0.004)     HFX33 (3.48, 0.01)

10       * Performed by Dr. James Lin (Lotes Co., Ltd.)
USB type C conne ctor
challe nge s and solutions

11
Challe nge s with traditional mate rials
Thinner walls require high -strength and more durable materials

• Liquid crystal polymers (LCP) are widely used for micro -USB
  connectors

• USB-C connectors require thinner walls than previous
  generations

• Fast charging increases the risk of connector defect

• Alternative materials are needed to produce reliable thin   -
  walled connectors

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Addre ssing safe ty conce rns                                                           Re ce ntly Qualcomm re le ase d the late st
                                                                                        Quick Charge 5 solution, and se ve ral
New thinner devices pose fire risks                                                     smartphone companie s are using the
                                                                                        te chnology in ne w de vice s.

 •   Connectors with higher voltage rates and smaller pitch
     are more likely to result in electrical breakdown

 •   The tracking resistance of the insulator plastic is
     essential to reducing fire hazards
 Source capabilities organized as profiles
 Hand-held devices,                                       10W
                           Profile 1    5V @ 2A      Default start -up
 today’s peripherals                                     profile

 Tablets, VR/AR devices,                5V @ 2A
                           Profile 2                      18W
 most peripherals                      12V @ 1.5A                          Requires
                                                                             new
 Thinner notebooks,                    5V @ 2A                           detectable
                           Profile 3                      36W
 larger peripherals                    12V @ 3A                           cables for
                                                                         >1.5A or >5V
                                        5V @ 2A           60W
 Larger notebooks, hubs,
                           Profile 4   12V @ 3A         Limit for
 docks
                                       20V @ 3A         micro A/B

                                        5V @ 2A          100W
 Workstations, hubs,
                           Profile 5   12V @ 5A     Limit for standard
 docks
                                       20V @ 5A             A/B

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Unde rstanding tracking
Insulating plastics may create fire risks

Potential real -life failure mode
• The build -up of dust, sweat or moisture creates a
  conductive track on plastic materials – increasing the
  risk of fire

                                    LCP after testing with 12 droplets —
                            significant burn marks and electrical breakdown
14
Tracking re sistance te sting
High CTI material decreases safety risks
for connectors and devices
• Materials need a high comparative tracking index (CTI) to
  ensure products are safe
• Higher CTIplastic remains structurally intact even after
  testing of 60 droplets!

15
Insights
Charging electronics have been linked to device fires

• Some fires may result in property
  damage or injury
                                                                                            Charging cell phone blamed for
• If liable, manufacturers risk recalls, damage                                             fire that destroyed Frayser home

  to their reputation and legal action

• Tracking posed fire risks with the previous
  generations of USB connectors. With USB-C,       Cell phone charger not ruled out as
  the smaller pitch and increased power            cause of Tuesday house fire in Redding
  density may further increase the risk of fire.

• “Home fires due to electrical failure or
  malfunction primarily involve some form
  of arcing. Arc faults can be produced by
  damaged connectors…”
Source: “Home Electrical Fires” report by NFPA

16
USB type C Re ce ptacle structure and challe nge s
     1st part (grey)
                                                                                                               Challenge 4
                                                                   3rd part Over mold (purple)

                                                                                                                Challenge 3

     2nd part (black)
                                      Challenge 1                  Challenge 1                            Challenge 2

 Challenge 1: the over mold parts need to be bounded with 1   st   and 2nd parts well
 Challenge 2: Very thin wall in the both sides (0.1~0.2mm only), need very high flow material
 Challenge 3: front end plastics to protect metal contact, need high wear resistance material to ensure the reliability and
 durability during mating/ un-mating cycles.

 Challenge 4: inappropriate tooling design may cause other issues such as void inside the housing or delamination

17
USB type C Plug structure and challe nge s

                    1st part (green)
                                                   2nd part (light green)
     Challenge 6
                                                                  EMI
                                                                springs

                                                                            Challenge 7
      Challenge 5                             3rd part (grey)

 Challenge 5: There is welding line in the front end and very easy to be broken. The broken parts may cause connector
 malfunction. Need high welding line strength material
 Challenge 6: The ribs are very thin (~0.15mm) and very easy to break during EMI spring assembly. Need high stiffness
 material
 Challenge 7: Deformation in the front end of plug housing, need higher strength material

18
Ove rcoming plug housing challe nge s
Meeting all durability, flow and toughness needs

• Molding thin ribs requires high flow, highly durable materials

• Final components must retain a balance between toughness and
  stiffness

• High-strength weldlines are very durable

 Stanyl shows the highest weldline strength among competitors
                                                                                          Normal           Weldline
                                                                                        tensile bar       tensile bar
 Base polyme r                 [-]              PA46            PA9T   PA6T/ 66   LCP

 GF conte nt                  [%]          20              35    45      35       35

 Mechanical property
                             [MPa]         60              50    22      40       17
 we ldline stre ngth
                                                                                        Low weldline strength material
Weldline strength measurement is based on UL tensile bar                                shows cracking in plug designs

19
Diffe re nt polyme r structure le ads to diffe re nt mate rial
characte ristics

 LCP has very rigid molecular structure in both solid and melt state,   Stanyl/PA46 has flexural molecular chain, easier for
 therefore the very few entanglements and chemical interactions cause   entanglement, and Fast crystallization to solidify the
 the very low weldline strength                                         entanglement area

20
We ar re sistance comparison of Haloge n Fre e V0 grade s
Stanyl shows the highest wear resistance

                      Stanyl
                                       ForTii F11 GF30%       PA9T GF45%          PA6T GF35%          LCP GF+MD35%
                   HFX33S GF20%

     Wear &
     Friction

      Depth             8μm                  22μm                47μm                 36μm                 23μm

21        * Test Condition: 20g, Stroke 40mm, Speed 70cycle/min, 100Kcycles. Probe Pin Front end R 0.4mm
Full product portfolio for diffe re nt de sign

 Supplie r                               DSM              Compe titor A   Compe titor B   Compe titor C   Standard
 Grade                 [-]     HFX33S   HFX61S   HFX82S   GP2450NH-2      FR52G35NHF           E471i
 base polyme r         [-]              PA46                 PA9T           PA6T/ 66            LCP
 GF conte nt           [%]       20       35       45          45              35               35
 Mechanical property
 TM                    [MPa]    7400    11500    15000       15100          12800             13800       ISO 527-1/ -2
 TS                    [MPa]    110      145      180         146             135              130        ISO 527-1/ -2
 EAB                   [%]      2.7      2.1      2.2          1.5            1.4              2.5        ISO 527-1/ -2

 • Stanyl HFX33S has highest elongation at break ration and ductility among
   competitions

 • DSM provides the product portfolio solution to meet different connector
   design needs

22
Bliste ring fre e solution
JEDEC MSL-1 test
 Sample: Connectors
 Material: Stanyl HFX 31S/33S/61S BK
 pre-dried: 105℃*16hrs
 Preconditioning: MSL-1(85℃×85%RH×168hrs) MSL-2(85℃×60%RH×168hrs)
 Reflow profile:Sony profile with peak temp. 260℃
 Reflow time: one time pass

                     Material                         Sample type        Pre-conditioning          Water absorption(%)   Blistering

             HFX 61S with metal shell                                                                        0.4            0/9
                                                                       85℃*85%RH*168hrs
           HFX 61S without metal shell                                                                       1.7            0/9
                                                       connectors
             HFX 61S with metal shell                                                                        0.2            0/9
                                                                       85℃*60%RH*168hrs
           HFX 61S without metal shell                                                                       0.8            0/9
 Note: The moisture absorption was measured by weight gain, which is only for reference due to metal pin included.
                                                                                                                                      Thermocoup
                                                                                                                                       le position
                   Material                           Sample type       Pre-conditioning           Water absorption(%)   Blistering
             HFX 31S/33S with metal                                   85℃*85%RH*168hrs                     1.95             0/4
                                                       Connector
            HFX 31S/33S without metal                                 85℃*60%RH*168hrs                     3.89             0/4

23            * No blistering at the both receptacle and plug connectors test
Choosing the be st mate rial
Robust plastics reduce fire risk            COMPONENT                       MATERIALS
                                            Cable                           Conductor: coppe r with tin or silve r plating
                                                                            SDP Shie ld: AL foil or AL/ mylar foil
                                                                            Coaxial shie ld: coppe r strand
• Multiple considerations go into picking                                   Braid: Tin-plate d coppe r or aluminum

  materials for USB-C components:                                           Jacke t: PVC or haloge n-fre e substitute mate rial
                                            Cable Ove rmold                 The rmose t or the rmoplastic
  – Receptacle tongues                      Conne ctor She lls              Stainle ss ste e l or phosphor bronze
                                            Plug Side Latche s              Stainle ss ste e l
  – Plug housings
                                            Re ce ptacle Mid-Plate          Stainle ss ste e l
                                            Plug inte rnal EMC Spring       Stainle ss ste e l or phosphor bronze
• Choosing a halogen-free polyamide         Re ce ptable EMC Pad            Stainle ss ste e l or phosphor bronze
  material reduces the risk of fire         Re ce ptable She ll             Stainle ss ste e l or phosphor bronze
                                            Re ce ptable Tongue             Glass-fille d nylon
                                                                            The rmoplastics capable of withstanding le ad-fre e
                                            Housing
                                                                            solde ring te mpe rature
                                            Note : Haloge n-fre e mate rials should be conside re d for all plastics

                                            *Source : USB Type C spe cification re le ase 1.0
Stanyl: Be st polyamide for incre ase d product safe ty and
re liability
Highest weldline strength and best wear resistance
 • High CTI reduces the risk of electrical tracking by
                                                                   PA46             PA9T           PA6T           LCP
   50%
                                                                                    CTI 400V or avove
 • Excellent flow properties ensure high yields to                                         (Q)
                                                                                      5.0
   lower molding costs                                        Colorability (Q) in     4.0                    Blister
                                                                some OEM                                Performance (Q)
 • Up to 50% more wear resistance than competing                                      3.0
                                                                                      2.0
   high temperature polyamides                                                        1.0
                                                         Processability (D)           0.0                    Flow (D)
 • Unmatched reliability during use ensured by
   extensive mating cycle testing
 • Proven track record of more than 300 million                Wear Resistance
                                                                     (D)
                                                                                                        Weld Line Strength
                                                                                                               (D)
   USB-C connectors with zero blistering or quality
                                                                                    Overmold Bonding
   complains made by Stanyl for major OEMs                                              Force(D)

25
DSM Engine e ring Mate rials
Your be st partne r for conne ctor de ve lopme nt

26
Bright Scie nce in advance d mate rials
Co-developing throughout the value chain
                    High-Performance Materials

                                                                                  System                               End
     Monomer           Polymer         Compound                Convertor                              OEM
                                                                                  Supplier                             User

                                       24/ 7 Science, Expertise & Global Support

                                           Measure                         Production
                  Design                                                                             Compliance
                                         Performance                        Support

        •   Re vie w application   •   Te mpe rature               •   Quality control       •   Docume ntation
            re quire me nts        •   Me chanical                 •   Ide ntify             •   Data she e ts
        •   Analyze datase ts      •   Che mical re sistance           production            •   Re gulatory affairs
        •   CAE support            •   UL and othe r global            e fficie ncie s           state me nts
                                       safe ty standards                                     •   Life cycle analysis

27
Bright Scie nce in advance d mate rials
Delivering advanced material solutions for the world’s leading manufacturers

                                                              DSM
                                                            Material
                                                             Science
                                                           Innovation

                                                                          End-User
                                              OEM Design                Expectations:
                                               challenge                Performance
                                                                             and
                                                                        Sustainability

28
Summary
Why DSM Engineering Materials?

    Materials trends in              DSM Engineering Materials          Delivering:         A trusted partner with a
    sustainability and                   supports with:                                       strong track record
technology evolve rapidly

Engineers face challenges        •    Global footprint            Security in selecting     A preferred partner of
in staying up to date with       •    Broad materials portfolio   the right materials for   leading multinationals,
advanced materials               •    Application expertise       applications with         with a strong track record
science, innovations and         •    Design support              speed and agility.        in automotive, electronics
shifts in legislation - and in   •    Materials innovation                                  & electricals and food
choosing the right solution      •    Sustainable solutions                                 packaging.
for their design challenges      •    Security of supply

29
DSM Engine e ring Mate rials
Contact us and stay up to date

                      Homepage
              DSM.com/EngineeringMaterials

        Product and             Ask a question or
       technical data           request a quote
     PlasticsFinder.com       DSM.com/ContactDEM

30
Que stions and Answe rs
John Hsieh
John.Hsieh@dsm.com
+86 13818977651
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