The Environmentally Responsible Dentist - Dental Amalgam Recycling: Principles, Pathways and Practice
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The Environmentally Responsible Dentist Dental Amalgam Recycling: Principles, Pathways and Practice 1
Presentation Topics • History of Amalgam • Related Mercury Actions • Mercury in Dental Amalgam • Government Regulation • Amalgam Use in the U.S. • Environmental Fate and Transport Mechanisms • Environmentally Responsible Practices 2
History of Amalgam • A Chinese medical text mentions using a “silver paste”, a type of amalgam, to fill teeth in the 7th century.1 Image courtesy of University of California Press. 5
History of Amalgam • Pierre Fauchard • b. 1678 - d. 1761. • The Age of Enlightenment. • Between 1650 and 1800, the science of modern dentistry developed. • Le Chirurgien Dentiste published in 1728. • He advocated the use of lead (plombagel) to fill cavities. 6
History of Amalgam • Joseph Fox - b. 1775 - d. 1816. • One of the most highly regarded English dentists of his time. • In 1803, he created fusible metal (bismuth, metal, and tin). • This metallic filling material when put in the cavity form and cooled, would solidify and replicate the shape of the cavity. • Had a relatively high melting point - 100°/212°- equivalent to that of Image courtesy of the OHSU Historical Collections & Archives, boiling water. Oregon Health & Science University. 7
History of Amalgam • “Most people may be deceived at the time of an operation; though woeful experience in a few months unfolds the deception. The impostor is sought for to make reparation, or to receive merited punishment; but the bird has flown; he is gone to practice his tricks and deceptions among those, who know not his character; until prudence drives him into another seclusion from revenge, into another ‘shoal of gudgeons.’ ” • Benjamin James MMSS - 1814 Image courtesy of Bernard Becker Medical 8 Library, Washington University School of Medicine, St. Louis.
History of Amalgam • Thomas Bell • b. 1792 – d. 1880. • Fox’s successor at Guy’s Hospital. • Around 1826, he invented an amalgam of coin silver and mercury which had a much lower melting point than Fox’s metal. 9
History of Amalgam • Crawcour brothers • In 1833, introduced Taveau’s amalgam in New York. • Traveling Dentists. • They did a remarkable job of advertising. • Decay was not removed before filling the teeth. 10
History of Amalgam • The Amalgam War • Local dentists organized to fight the use of this “execrable material by swindling villains.” • Crawcour brothers forced to flee America. • In 1843, the American Society of Dental Surgeons (ASDS) began a crusade to fight the use of amalgam. 11
History of Amalgam • The Amalgam War • In 1845, the ASDS passed a resolution compelling every member not to use amalgam. • In 1850, the ASDS rescinds its pledge requirement. • In 1855, the ASDS disbands. • If you can’t beat them, join them. 12
History of Amalgam • What ended the Amalgam War? • Professional and consumer demand. • In 1859, the leaders of the profession regrouped to form the American Dental Association. • Between 1860 and 1890, many experiments were done to improve amalgam filling materials. • Amalgam was here to stay. 13
History of Amalgam • G.V. Black • b. 1836 - d. 1915. • Developed a “good and workable” amalgam in 1895. • He believed amalgam should consist of 67% silver, 27% tin, 5% copper, and 1% zinc. • Use of amalgam gradually won acceptance as a cost effective way to restore teeth. Image was reproduced from Volume VII of the History of 14 Dental Surgery, Chicago National Art Publishing Company, 1909.
History of Amalgam Amalgam Composition • Modern Dental Amalgam • Manufactured product containing two nearly equal parts by weight. • First part: • a powder containing silver, tin, copper, zinc and other metals. • Second part: • liquid mercury (Hg). 15
History of Amalgam Amalgam Composition Mercury Silver 2% Tin 0% Copper 13% Zinc (Trace) Mercury 50% Silver 35% 16
Related Mercury Actions To Develop, Highlight and Teach Environmentally Responsible Dentistry 17
Related Mercury Actions-International • January 31, 2005 - European Union (EU) launched a comprehensive mercury strategy to reduce EU's and global emissions and use of mercury. • July 10, 2007 – EU banned the sale of thermometers and other instruments which contain mercury. • September 25, 2008 – EU adopted law that bans the export of elemental mercury, effective March 2011. • In 2008, Norway and Denmark banned the use of mercury in dental amalgam. • Effective June 1, 2009, Sweden banned the use of mercury in products, including mercury in dental amalgam, for environmental reasons. 18
Related Mercury Actions-U.S. • On October 14, 2008, President Bush signed into law the Mercury Export Ban Act of 2008. • Prohibits the sale, distribution, or transfer of elemental mercury by federal agencies. • It also prohibits the export of elemental mercury - The law is effective January 1, 2013. • Department of Energy - responsible for the management and long- term storage of the U.S. excess elemental mercury. 19
Related Mercury Actions-U.S. • February 16, 2009 - President Obama Shifts U.S. Policy and Supports Global Mercury Control Treaty • Covers reducing demand in products, processes and cutting Hg in international trade. • 120 countries expressed support for a legally binding agreement on Hg. 20
Related Mercury Actions-U.S. • August 2009 - the US Geological Service released study entitled: "Mercury in Fish, Bed Sediment, and Water from Streams Across the United States, 1998-2005." • The study found mercury contamination in every fish sampled in 291 streams across the country. • About a quarter of these fish were found to contain mercury at levels exceeding EPA’s criterion for the protection of people who consume average amounts of fish. 21
Related Mercury Actions-U.S. • October 2009 - EPA released Report to Congress on mercury compounds as required by Congress under Section 4 of the Mercury Export Ban Act of 2008. • The report identifies sources of mercury compounds in the U.S. and reports quantities in imports and exports, and uses of these compounds in products and processes. The report also assesses the potential for key mercury compounds to be exported for regeneration into elemental mercury. 22
Related Mercury Actions ADA/EPA/NACWA Publications and Partnerships • In 2007, ADA updated its Best Management Practices (BMPs) to include amalgam separators. (ADA first published its BMPs in January 2003.) • An amalgam separator is a capture device that collects amalgam particles. • The BMP for amalgam separators - the same as ANSI/ADA Specification #108 (American National Standards Institute) which delineates requirements and test methods for amalgam separators. • EPA published its "Health Services Industry Detailed Study" - August 2008. (In the document, EPA compiled information on mercury discharges from dental offices, best management practices, and amalgam separators.) • The EPA, ADA, and the National Association of Clean Water Agencies (NACWA) entered into a partnership in December 2008 to promote the ADA’s BMPs for amalgam waste, including amalgam separators. 23
Mercury in Dental Amalgam To Develop, Highlight and Teach Environmentally Responsible Dentistry 24
Mercury in Dental Amalgam • Mercury is persistent, bio-accumulative, and toxic and is responsible for significant environmental degradation around the world. • Although its use in most product applications does not present a risk, the subsequent disposal of any product containing mercury does. • Amalgam is no different. • Mercury poisoning affects about 5 million American women. 1 in 12 women have mercury levels above the levels considered safe. 25
Mercury in Dental Amalgam • Three Types of Mercury: 1. Elemental Hg (Elemental Hg Is Used in Dental Amalgam.) • Heavy, odorless, silver- colored liquid. • Inhalation is the main source of toxicity. (Mercury poisoning can also occur from dermal exposure.) This image is licensed under the Creative Commons Attribution- • Hg well absorbed by lungs. Share Alike 2.5 Generic license. • Need long-term exposure or 26 one large exposure.
Mercury in Dental Amalgam • Three Types of Mercury: 2. Inorganic Hg • Known as mercuric salts…i.e. mercuric chloride, mercuric iodide, cinnabar. • Found in many folk medicines. • Corrosive and can damage the kidneys. • Long-term exposure can cause skin irritation, staining, and nerve damage. 27
Mercury in Dental Amalgam Three Types of Mercury: 3. Organic Mercury = Methylmercury • More potent and more bioaccumulative than other forms of mercury. • Form to which humans are primarily exposed. • The EPA is most concerned about methylmercury in the environment. 28
Mercury in Dental Amalgam • Three Types of Mercury • Methylmercury (continued): • Organic Hg primarily found in fish. • Organic concentrations in large fish can be over a million times higher than in the surrounding water. Drawing courtesy of Fishbase. 29
Mercury in Dental Amalgam • Three Types of Mercury: • Methylmercury (continued): • Found in fungicides and antibacterials (mercurichrome). • The main source of Hg poisoning in humans is ingestion. • Small ingestions rarely cause problems. • Large ingestions or long-term ingestions can adversely impact all body systems. 30
Mercury in Dental Amalgam • Inorganic Mercury and Methylmercury • Inorganic Hg has a high affinity for particles. Therefore, the fate of most inorganic mercury in aquatic systems is sedimentation. • …...Methylmercury, in contrast, tends to be more soluble because of its affinity for organic compounds. It is the most risky type of mercury in the environment. 31
Mercury in Dental Amalgam • How is Methylmercury Formed? • When dental amalgam is released to the environment, the mercury component is transformed into methylmercury by microbial action. • Methylation is a product of very complex processes that transform mercury into more reactive species. 32
Mercury in Dental Amalgam - How Is Methylmercury Formed? 33
Mercury in Dental Amalgam • The Impact of Methylmercury in the Environment • Once formed, this new mercury compound is taken up more readily by aquatic organisms such as fish, particularly in waters higher in acidity. • Methylmercury uptake by fish leads to fish advisories of which there are 50 nationwide. As of 2008, all 50 states, one U.S. territory and three tribes have issued fish advisories. 34
Government Regulation To Develop, Highlight and Teach Environmentally Responsible Dentistry 35
Government Regulation • Why voluntarily act in an environmentally responsible fashion? • Amalgam separators are effective in reducing over 95% of the amalgam from dental office wastewater. • The mercury can then be recycled. • Currently, mercury releases to wastewater from dental offices are controlled through state mandates and voluntary actions; however, EPA does have the authority to issue regulations to control these releases. As respected community leaders, dentists need to do their part for the environment. 36
Government Regulation • Dental amalgam - is a dental medical device regulated by the Food and Drug Administration (FDA). • Since the 1990s, several federal agencies (FDA, Center for Disease Control and the U.S. Public Health Service) have reviewed the scientific literature looking for links between dental amalgam and health problems. • In September 2006, an FDA Advisory Council met to discuss the benefits and risks of mercury and amalgam. Their findings: • No evidence that amalgam use causes health problems in a majority of population. • Lack of knowledge regarding effects on pregnant women, children, and those who are sensitive to mercury. 37
Government Regulation • In 2008, FDA again reviewed the best available scientific evidence to determine whether low levels of mercury vapor associated with dental amalgam are a concern. Based on this evidence, FDA considers dental amalgam safe for adults and children aged six and older. • For individuals who have an allergy to mercury or the other components of dental amalgam (silver, tin, or copper) - FDA cautions these individuals not to get amalgam fillings. • On July 28, 2009, FDA issued a final regulation classifying dental amalgam and its component parts (elemental mercury and a powder alloy) as “Class II” medical devices. • Specifically the Center for Devices and Radiological Health (CDRH). By classifying a device as "Class II," the FDA can impose special controls to provide reasonable assurance of the safety and effectiveness of the device. The special controls contain, among other things, recommendations on performance testing, device composition, and labeling statements. 38 • It is considered to be a stable device for most applications and uses.
Government Regulation • EPA is concerned about amalgam discharges that enter the waste stream. • EPA regulates any waste generated from amalgam preparation and use. • Examples of amalgam waste: • Non-contact amalgam. • Excess left over after procedure. 39
Government Regulation • Examples of amalgam waste (continued): • Contact amalgam: • Has been in contact with human…extracted teeth, carving scrap, traps or filters. • Amalgam sludge: • Mix of liquid and solid collected within vacuum pump filters and chairside traps. • Amalgam capsules. 40
Amalgam Use in the U.S. To Develop, Highlight and Teach Environmentally Responsible Dentistry 41
Amalgam Use in the U.S. • Decline of Hg-containing products • Between 1980 and 2004, mercury usage in products declined substantially over the years – a decrease of roughly 95%. • This reduction in use was due in large part to federal legislation and state regulatory standards for mercury usage in batteries and to EPA’s regulatory ban on mercury in paint. • Mercury use in products accounted for an estimated 116 tons in 2004. Mercury usage in the form of dental amalgam was 30.4 tons or 26% of the total. (This is a high percentage of the total.) 42
Amalgam Use in the U.S. • Estimated 2004 U.S. mercury use in products1: • Switches & Relays – 44%. • Dental Amalgam – 26%. • Measuring and Control Devices - 17%. • Electric Lighting - 8%. • Other - 5%. • Among these products containing mercury, dental amalgam is a focus of concern. Relative to other sectors, dentists use large quantities of mercury in fillings and 43 they generate large amounts of waste.
Amalgam Use in the U.S. • The use of dental amalgam has declined in the past two decades. It continues, however, to be placed in teeth. Currently accounts for 30% of dental fillings in the US.1 • In 1999, US dentists placed an estimated 71 million amalgam restorations.2 • 29% reduction from 1990.3 • Reductions can be attributed to decrease in cavity rate and increased use of mercury-free fillings.4 44
Amalgam Use in the U.S. • Data indicate that there were 163,181 individual dentists in 2004.1 In 2005, EPA estimates that there were 122,918 dental offices that used or removed dental amalgam that year. 2 • 340 mg of mercury used in an average placement with 9% or 30 mg resulting in non-contact scrap and/or carving waste.3 • Estimated that 300 mg of mercury results from each removal.4 45
Amalgam Use in the U.S. • Amalgam Waste Contributions to Wastewater • Major studies show impact on water quality from dental amalgam waste: • A 2002 study by the New York Academy of Sciences indicated as much as 40% of the New York Harbor mercury loadings were from dental offices.1 • A report released in 2002 by NACWA indicated that dental clinics are the largest single source of mercury in wastewater. NACWA estimated that 36% of the mercury in the nation's wastewater system came from dental offices. Mercury discharges from dental offices far exceeded all other commercial and residential sources, each of which was below 10 percent.2 46
Amalgam Use in the U.S. • Data Show Impact on Water Quality from Dental Amalgam Waste (Continued): • In 2003, dental offices were found to be the source of 50% of all mercury pollution entering Publicly Owned Treatment Works (POTWs).1 • EPA estimated in 2008 that the approximately 162,000 dentists who use or remove dental amalgam in the U.S. discharge approximately 3.7 tons of mercury each year to POTWs.2 47
Amalgam Use in the U.S. • With dental amalgam's associated mercury contamination problems, why is amalgam still being used? • Relatively easy to place and low cost. • Good resistance to compressive forces, especially for posterior teeth. • Insurance plans have traditionally covered placement procedures. • No current, adequate substitute. 48
Amalgam Use in the U.S. • Past Management Practices = More Pressure on Dentists Today • Despite its continued use, management of amalgam waste has created substantial environmental contamination and has created more pressure on the industry to recycle amalgam to prevent it from getting into the environment. 49
Amalgam Use in the U.S. • Best Management Practices • In January 2003, the American Dental Association (ADA) released Best Management Practices (BMPs) . • The BMPs are a set of guidelines about capturing and recycling dental amalgam waste. Guidelines include use of such items as collection boxes for excess amalgam and chairside traps to retain amalgam. Noncommercial use, reproduction and distribution of all or any portion of the American Dental Association's Best Management Practices for Amalgam Waste is permitted solely for educational or scientific purposes, provided that this copyright notice is prominently displayed on each copy of the work. Third parties are expressly prohibited from creating derivatives of this work without the prior written permission of the American Dental Association. This work is educational only and does not constitute legal or professional advice. 50
Amalgam Use in the U.S. • Best Management Practices: • All state and local voluntary programs are based on or derived from the guidance provided in the ADA's BMPs. • The 2003 BMPs stressed recycling of amalgam collected in the dental office. But no mention of installing amalgam separators to remove amalgam particles from wastewater. Noncommercial use, reproduction and distribution of all or any portion of the American Dental Association's Best Management Practices for Amalgam Waste is permitted solely for educational or scientific purposes, provided that this copyright notice is prominently displayed on each copy of the work. Third parties are expressly prohibited from creating derivatives of this work without the prior written permission of the American Dental Association. This work is educational only and does not constitute legal or professional advice. 51
Amalgam Use in the U.S. • Best Management Practices • In October 2007, the American Dental Association revised “Best Management Practices for Amalgam Waste.” • Added language on amalgam separators: • Amalgam Separators • Select an amalgam separator that complies with ISO 11143. • Follow the amalgam separator manufacturer’s recommendations for maintenance and recycling procedures. • The BMPs recommend two important and effective "best practices": the use of dental amalgam separators, and the recycling of captured amalgam solid waste. 52
Amalgam Use in the U.S. • Some states have mandatory dental amalgam program requirements, including installation of amalgam separators. • Specifics on state requirements can be found in EPA's Health Services Industry Detailed Study: Dental Amalgam (August 2008). • Additionally, The National Conference of State Legislatures lists state legislature internet links, including links to information on state laws requiring dentists to install amalgam separators. 53
Amalgam Use in the U.S. • Amalgam Separator Sales • 2001-2009 data provide estimates on the numbers of separators sold in regulated, partially regulated, and non-regulated states.1 • Based on the number of sales by one manufacturer, only 13% of separators were sold in non-regulated states from 2004-2009.2 This photo is used for illustrative purposes only. EPA cannot endorse any particular amalgam separator. 54
Environmental Fate & Transport Mechanisms To Develop, Highlight and Teach Environmentally Responsible Dentistry 55
Environmental Fate & Transport Mechanisms • How Does Amalgam Waste Reach the Environment? 1. From Publicly Owned Treatment Works (POTWs) connected to dental offices which receive amalgam through office piping and sewer discharges…. 2. From medical waste companies who pick up red bags at dental offices containing amalgam waste and subsequently treat the medical waste in incinerators….. 3. From landfills which receive amalgam waste from disposal companies which take waste from dentists who place it in office municipal trash…. 56
Environmental Fate & Transport Mechanisms 1. Publicly Owned Treatment Works • Dental Amalgam Waste • Into vacuum line. • Not captured by office traps or amalgam separators. • Released to the sewer. • Into POTWs. 57
Environmental Fate & Transport Mechanisms • Publicly Owned Treatment Works • Not 100% efficient. (POTWs have a roughly 90% efficiency rate of removing amalgam from wastewaters.) • Thus, about 10% gets into lakes, rivers, and streams. 58
Environmental Fate & Transport Mechanisms inm Environmental Fate & Amalgam Waste Entry into Ecosystem Transport Mechanisms Diagram is included in "ASSESSMENT OF MERCURY IN THE FORM OF AMALGAM IN DENTAL WASTEWATER IN THE UNITED STATES," Jay A. Vandeven and Steve L. McGinnis, 2005. 59
Environmental Fate & Transport Mechanisms 2. Medical Waste Incinerators • Red medical bags. • Mercury released when: Amalgam waste is treated by medical waste companies with incinerators which are not designed to handle the mercury component of amalgam.. • With precipitation, airborne Hg gets deposited into water bodies. 60
Environmental Fate & Transport Mechanisms • Medical Waste Incinerators • Dental Amalgam Waste • In October 2009, EPA published a regulation that limits emissions from medical waste incinerators. EPA estimates that this rule will cut mercury emissions by 605-682 pounds annually of Hg emitted to the atmosphere through the stacks. 61
Environmental Fate and Transport Mechanisms • Landfills • Dental Amalgam Waste Goes: • Into garbage. • To landfills. • Landfill leachate may enter groundwater. • Your amalgam waste could reach groundwater if you dispose of it in the trash. 62
Environmental Fate and Transport Mechanisms • Sludge from POTWs • Dental Amalgam Waste • Sludge from POTWs may be applied to agricultural land as fertilizer. • Some of the mercury in the fertilizer may also evaporate to the atmosphere. Through precipitation, the airborne mercury eventually gets deposited into water bodies, land and vegetation. • Sludge from POTWs may also be incinerated. Once incinerated, the mercury may volatilize to the atmosphere. Mercury may then be deposited into lakes and streams via precipitation. 63
Environmentally Responsible Practices To Develop, Highlight and Teach Environmentally Responsible Dentistry 64
Environmentally Responsible Practices • Strategies for Proper Amalgam Waste Management in Your Office • The EPA recommends four specific actions to manage your amalgam waste. • The first letters of each action form the acronym...G.R.I.T. • Gray Bag It. • Recycle It. • Install It. • Teach It. 65
Environmentally Responsible Practices • Strategies for Proper Amalgam Waste Management in Your Office • Gray Bag It - Discard excess amalgam wastes into a gray bag. Never dispose of dental amalgam wastes in medical red bags or in your office trash containers. • Recycle It - Select a responsible dental amalgam recycler - who will manage your waste amalgam safely to limit the amount of mercury which can go back into the environment. List of Recyclers • Install It - Install an amalgam separator in the office to capture up to 95% of the mercury leaving a dental office through drains. This is the KEY to success. • Important to note - A very small amount of dental amalgam waste will be released to waterways given the high capture rate of amalgam separators (95%), coupled with the approximate 90% efficiency rate of POTWs. • Teach It - Educate and train staff about the proper management of dental amalgam in the office. 66
Environmentally Responsible Practices • Gray Bag It • Environmentally responsible amalgam waste control begins in the dental office. • In September 2006, EPA and the ADA developed a voluntary standard for storing (and shipping to recyclers) excess dental amalgam not needed by dentists during filling placement and/or removal procedures. Standard was developed through ANSI (American National Standards Institute.) • The EPA refers to this as “Gray This photo is used for illustrative purposes only. Bag” collection. (The containers EPA cannot endorse any particular gray bag. are gray in color.) 67
Environmentally Responsible Practices • Recycle It • Most important step: • Selection of a responsible company to manage your waste once you have properly controlled it in your office. List of Recyclers • It makes no sense to handle your waste properly yourself and then turn it over to someone who can't properly manage Hg waste. • It is important to recycle both the amalgam waste captured by amalgam waste separators and the amalgam discarded in "gray bags." • Gray bags serve a dual purpose: to both hold excess amalgam and as a container to send to recyclers. 68
Environmentally Responsible Practices • Recycle It • Mercury cannot be destroyed, so waste managers must rely on various methods to treat or recover it, depending on: • the mercury species present. • its concentration. • the waste matrix or media involved. 69
Environmentally Responsible Practices • Recycle It • One of the most effective processes to handle mercury wastes is called “retorting.” • Process especially designed to capture the mercury from mercury-containing items, such as dental amalgam. • Retorting operations separate the mercury from the rest of the waste stream and condense it for recovery. • Select a retorting company which is subject to regulatory oversight under the Resource Conservation and Recovery Act (RCRA). Such companies are classified as hazardous waste treatment, storage and disposal facilities that require a RCRA hazardous waste permit during the active stage (including the closure period) of waste management at the facility. A RCRA permit needs to be approved by state or federal officials and ensures that specific requirements are met, such as monitoring the groundwater under the facility to ensure that this valuable resource is not getting contaminated. 70
Environmentally Responsible Practices • Recycle It • Bottom Line: • The end point to responsible waste management is ensuring that mercury is collected and recycled and not released to the environment during or after treatment. 71
Environmentally Responsible Practices • Install It • Installing an Amalgam Separator • Removes amalgam from dental wastewater discharges prior to it leaving the office. • Over 95% effective!1 • In 2003, it was estimated that dental offices were the source of 50% of all mercury pollution This photo is used for illustrative purposes entering POTWs.2 only. EPA cannot endorse any particular amalgam separator. 72
Environmentally Responsible Practices • Install It • Installing an Amalgam Separator • Separators vary in complexity, cost and efficiency. • Even “low tech” systems appear to be effective…. • Select one which will provide adequate removal based on the number of operatories in your practice. 73
Environmentally Responsible Practices • Teach It • Educate and train your staff. • You can know everything about proper amalgam management….but does your staff? • It is the responsibility of everyone to manage amalgam properly. 74
Environmentally Responsible Practices • The Environmentally Aware Dentist Knows.... • ...why • dental amalgam (Hg) is a hazard to the environment. • ...how • dental amalgam waste reaches the environment. • ...what • you can do to minimize its release to the environment. 75
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