Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved

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Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
ImerCare                         ®

PerlWhite 19
  A natural, perlite-based
    whitening booster
      for toothpaste
Stain removal

Effective at low concentrations

Low dentin and enamel abrasion

Cosmos approved
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
ImerCare® PerlWhite 19 is a perlite-
                                            based product that has been specifically
                                            engineered to optimise its particle size and
                                            shape, making it an ideal gentle abrasive for
                                            toothpaste.
                                            Toothpaste containing PerlWhite 19 cleans
                                            and polishes the surface of the teeth
                                            without scratching, minimising damage to
                                            enamel and dentin.

   ImerCare® PerlWhite 19: the optimised perlite grade for toothpaste

Imerys has developed a perlite grade                                                                  Pellicle Cleaning Ratio
specifically for toothpaste. Typical                                               150

toothpaste formulations with different
                                                  Pellicle Cleaning Ratio (PCR)

                                                                                          No significant difference in terms of cleaning efficiency
grades of perlite were tested at the
Oral Health Research Institute at Indiana
University, USA.                                                                   125

Compared to conventional perlite grades
available on the market today, ImerCare®
PerlWhite 19 offers the ideal balance                                              100
between effective stain removal (Pellicle                                                 Formulation containing         Formulation containing
                                                                                          2% conventional perlite           2% ImerCare®
Cleaning Ratio stable) and minimum                                                        grade (ImerCare® 30P)              PerlWhite 19
tooth wear (reduction in Relative Dentin
Abrasion).

                                                                                                    Relative Dentin Abrasion
                                                                                   270
                                                                                                                                           RDA limit
                                                  Relative Dentin Abrasion (RDA)

                                                                            202.5

                                                                                   135
                                                                                                       RDA decreases significantly
                                                                                                            with optimised
                                                                                                        ImerCare® PerlWhite 19.
                                                                                   67.5

                                                                                     0
                                                                                          Formulation containing         Formulation containing
                                                                                          2% conventional perlite           2% ImerCare®
                                                                                             (ImerCare® 30P)                 PerlWhite 19
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
ImerCare® PerlWhite 19’s efficiency is due to its optimised particle size distribution and unique
particle shape. Imerys’ innovative, proprietary grinding process enables large particles to be
removed and actually modifies particle morphology, transforming 3-dimensional particles into
2-dimensional, platy particles.

Standard perlite
Standard perlite                                                                          ImerCare®® PerlWhite
                                                                                         ImerCare    PerlWhite1919

   Comparison of standard perlite (large, three dimensional particles with sharp ridges) and ImerCare® PerlWhite 19 (small, two dimensional, platy particles)

       Cleaning performance of a formulation containing 2% ImerCare®
       PerlWhite 19 and calcium carbonate

To demonstrate the performance of ImerCare® PerlWhite 19 in association with calcium carbonate,
two formulations were prepared:

                                           Toothpaste formulation with ImerCare® PerlWhite 19

 Phase                   Ingredients                              INCI name                            Function                   A % wt            B % wt
                  Carbopol 974P NF Polymer
                                                                     Carbomer                             Binder                      0.7               0.7
                          (Lubrizol)
   A
                                 -                                      Aqua                             Solvent                     20.0              20.0

                         Oral care grade
                                                                   Xanthan gum                          Thickener                     0.7               0.7
                         (Jungbunzlauer)

   B                             -                                    Glycerin                         Humectant                      4.9               4.9

                    C*Sorbidex NC 16200                                                                Humectant
                                                                Sorbitol (and) Aqua                                                  43.0              43.0
                          (Cargill)                                                                    Sweetener
                     Surfac SMFP Pharma                             Sodium
                                                                                                 Anti tooth decay agent               0.8               0.8
                         (Surfachem)                          Monofluorophosphate

   C                             -                               Sodium Saccharin                      Sweetener                      0.2               0.2

                                 -                                      Aqua                             Solvent                     15.0              15.0

            ImerCare® PerlWhite 19 - Imerys                           Perlite                      Abrasive agent                    0.0               2.0
   D
                                 -                              Calcium carbonate                    Abrasive agent                  14.5              12.5

                    Surfac SLS/BP Powder                                                               Surfactant
                                                              Sodium Lauryl Sulfate                                                   4.8               4.8
                         (Surfachem)                                                                 Foaming agent
                      Color’N cap sil Blue
                                                               CI 42090 (and) Silica                       Dye                        0.3               0.3
                          (Sensient)
   E
                                 -                                    Flavour                            Flavour                     QSP               QSP

                                 -                                 Preservative                       Preservative                   QSP               QSP
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
Due to its inertness, ImerCare® PerlWhite 19 is compatible with other toothpaste ingredients and
                         particularly therapeutic agents such as fluoride.
                         Only 2% ImerCare® PerlWhite 19 is necessary to boost calcium carbonate performance (Pellicle
                         Cleaning Ratio: +15%), helping to clean the teeth without resulting in premature erosion of the
                         enamel and dentin.

                                                                                                         Pellicle Cleaning Ratio (PCR)
                                                                                       125
                                                       Pellicle Cleaning Ratio (PCR)

                                                                                                                      +15%

                                                                                       100

                                                                                       75
                                                                                                           83                                                 92

                                                                                       50
                                                                                                      Formulation A                        Formulation B with 2%
                                                                                                                                          ImerCare® PerlWhite 19

                                            Relative Dentin Abrasion                                                                                               Relative Enamel Abrasion (REA)
                                 300                                                                                                                     50
                                                                                                                        Relative Enamel Abrasion (REA)
Relative Dentin Abrasion (RDA)

                                                                                                         RDA limit                                                                                 REA limit
                                 250
                                                                                                                                                         40

                                 200
                                                                                                                                                         30
                                 150
                                                                                                                                                         20
                                 100

                                  50                                                                                                                     10
                                            81                                                   86                                                                      1                   4

                                   0                                                                                                                      0
                                       Formulation A                                     Formulation B with 2%                                                     Formulation A    Formulation B with 2%
                                                                                        ImerCare® PerlWhite 19                                                                     ImerCare® PerlWhite 19
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
Cleaning and polishing performance of ImerCare® PerlWhite 19 in a
                                      silica based toothpaste formulation

                         ImerCare® PerlWhite 19 was tested in conjunction with a synthetic silica in a typical whitening
                         toothpaste formulation.
                         The formulation containing 2% ImerCare® PerlWhite 19 and synthetic silica showed better cleaning
                         and polishing performance compared with the reference formulation containing only synthetic
                         silica (Pellicle Cleaning Ratio: +3%, Enamel Polishing Potential: +30%). Relative Dentin Abrasion
                         values (-10%) demonstrated that the toothpaste with PerlWhite 19 is less damaging in terms of
                         dentin wear than the reference.
                                             Pellicle Cleaning Ratio (PCR)                                                                                                    Enamel Polishing Potential (EPP)
                                125                                                                                                                               50
                                                                                                                               Enamel Polishing Potential (EPP)
Pellicle Cleaning Ratio (PCR)

                                                                                                                                                                  40
                                                                                                                                                                                                +30%
                                100
                                                                                                                                                                  30

                                               109                                                 113                                                            20
                                75
                                                                                                                                                                                    25                          37
                                                                                                                                                                  10

                                50                                                                                                                                 0
                                         Formulation with   Formulation with 18% silica and                                                                                  Formulation with     Formulation with 18% silica and
                                            20% silica        2% ImerCare® PerlWhite 19                                                                                         20% silica          2% ImerCare® PerlWhite 19

                                                                                                          Relative Dentin Abrasion (RDA)
                                                                                             300
                                                            Relative Dentin Abrasion (RDA)

                                                                                                                                                                              RDA limit
                                                                                             250

                                                                                             200

                                                                                             150

                                                                                             100               221                                                     195

                                                                                              50

                                                                                               0
                                                                                                          Formulation        Formulation with 18% silica and
                                                                                                         with 20% silica       2% ImerCare® PerlWhite 19

All the in vitro tests were carried out at the Oral Health Research Institute                                              Pellicle Cleaning Ratio (PCR) A key function of toothpaste is to remove
of Indiana University, Indianapolis, USA. The complete protocol and report                                                 stains. Certain stains are so tenacious that they require toothpaste
are available upon request.                                                                                                containing high performance abrasives with a Pellicle Cleaning Ratio value
                                                                                                                           of at least 50 to remove them. Method: the surface of teeth specimens was
Relative Dentin Abrasion (RDA) To avoid premature deterioration of                                                         stained using a staining solution (tea, coffee, mucin, FeCl3 and Micrococcus
dentin due to highly abrasive toothpastes, the Relative Dentin Abrasion is                                                 Luteus). The specimens were then brushed using a standard method. Stain
measured. For customer health and safety, the American Dental Association                                                  removal performance was determined by measuring tooth colour before and
recommends a RDA value below 250. The Hefferren Abrasivity method                                                          after brushing with a spectrophotometer.
in compliance with ISO 11609, recommended by the American Dental
Association, was used in this study.                                                                                       Enamel Polishing Potential (EPP) Polishing is important for two reasons.
                                                                                                                           Firstly, it contributes to brightening teeth and secondly a smooth tooth
Relative Enamel Abrasion (REA) To avoid premature deterioration of                                                         surface reduces stain molecule adhesion. Method: enamel polishing was
enamel due to highly abrasive toothpastes, the Relative Enamel Abrasion                                                    determined on bovine enamel specimens using a gloss meter.
is measured. The REA abrasivity safety limit is 40. The Hefferren Abrasivity
method in compliance with ISO 11609, recommended by the American                                                           A high-performance toothpaste should provide maximum cleaning (high
Dental Association, was used in this study. This method is very similar to the                                             PCR) and polishing (high EPP) performance with minimum abrasion to dental
RDA measurement method; only the preparation of the samples is different.                                                  hard tissue (low RDA and low REA).
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
About Imerys
                                             The world leader in mineral-based specialty solutions
                                             for industry, Imerys delivers high value-added,
                                             functional solutions to diversified set of industrial
                                             sectors, from processing industries to consumer
                                             goods. The Group draws on its knowledge of
                                             applications, technological expertise and its material
                                             science know-how to deliver solutions based on
                                             beneficiation of its mineral resources, synthetic
                                             minerals and formulations. These contribute
                                             essential properties to customers’ products and
                                             performance. Imerys is determined to develop
                                             responsibly, in particular by fostering the emergence
                                             of environmentally-friendly products and processes.

Our
Expertise
With over two hundred years’ experience in the minerals
business, Imerys refines and engineers its minerals
through various—often proprietary—processes that
influence their concentration, size, shape, structure
and surface chemistry to obtain the properties our
customers require and to the highest standards of
                                                                       About ImerCare®
quality, consistency and reliability.
Our Personal Care team has in-depth knowledge of                       ImerCare ® minerals benefit from all the
how minerals interact in cosmetic applications and a                   experience and expertise of Imerys group.
proven track record for developing new, value-added                    The ImerCare® product range is derived from
solutions for customers.                                               100% natural kaolin, perlite, diatomaceous
Our applications laboratories are equipped with a full                 earth and talc grades which have been
range of analytical and cosmetics-specific equipment,                  engineered to provide exactly the right
enabling us to provide customers with bespoke                          properties in terms of exfoliation, matting,
formulation services and technical support.                            transparency, coverage, rheology absorption,
                                                                       and skin feel.
                                                                       ImerCare® minerals are ideal for use in skin care,
                                                                       make-up, toiletries, hair care and oral care.
                                                                       All ImerCare® grades are natural, chemically
                                                                       inert and can be used in bio cosmetics. They are
                                                                       processed so as to provide specific functional
                                                                       benefits in cosmetic formulations.
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
Integrating
Sustainable
Development
into all we do

At Imerys, we respect the world in                    • Reducing the impact of climate change
                                                      through the implementation of a long-term
which we operate. We are committed                    climate change strategy in line with the COP21
to our role in society, to meeting                    2°C trajectory as well as developing innovative
                                                      solutions at the service of a low-carbon
our obligations to the countries and                  economy.
communities in which we do business,
as well as to acting as responsible                   Building for the future
environmental stewards.                               • Ensuring exemplary Business Conduct by
                                                      maintaining the highest standard of corporate
                                                      governance; respecting and implementing fair
Our Corporate Social Responsibility                   operating practices and ensuring a responsible
policy is built upon three mainstays:                 supply-chain with all our partners; and engaging
                                                      with local communities to create shared value
                                                      in particular through education and skills
                                                      development.
Empowering our people                                 • Ensuring that our products are safe for
• Ensuring that health and safety come first          people and the environment and developing
by developing and continually improving our           sustainable solutions that make positive
health and safety culture and systems so as to        contributions to society from both life cycle
achieve an injury-free workplace.                     assessment as well as long term sustainability
                                                      perspectives.
• Developing our human capital by respecting
internationally   recognized   human    rights
and labor practices as set out in our Code of
Business Conduct and Ethics; investing in the
talent and skills of our employees; engaging
in constructive social dialogue, and fostering
a culture of workplace diversity and inclusion
based on mutual respect.

Caring for our planet
• Acting as responsible environmental
stewards by assessing environmental risks
and continually improving control measures
to reduce adverse environmental impacts;
maximizing the efficient use of natural
resources, and preserving biodiversity.
                                                 More information about our sustainable development
                                                        policies and practices can be found on:

                                                                www.imerys.com
Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
Compliance
                                    All Imerys cosmetic products are natural, pure and chemically
                                    inert. These attributes enable them to be used in cosmetic
                                    products that comply with European cosmetic directive (EC)
                                    n°1223/2009.

                                    Cosmos
                                    ImerCare ® PerlWhite 19 complies with industry
                                    microbiological standards without resorting to
                                    irradiation. It is not treated with chemicals during
                                    processing. It is Cosmos approved. This accreditation

                                                                                                                                                                                Design couleur-citron.com
                                    underscores the naturalness of the minerals selected
                                    and produced by Imerys for the cosmetics industry.

                                                                                                                                                                                Revised Jan 2022
                                                                                                                                                                                PERC_GB_92_15

www.imerys.com

1
    OECD Guideline N°439 (July 2010) for testing chemicals in vitro skin irritation. Reconstructed human epidermis test method. (Certificate available upon request)
                                                                                                                                                                         Mini
                                                                                                                                                                        16 mm

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Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved Stain removal Effective at low concentrations Low dentin and enamel abrasion Cosmos approved
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