Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech

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Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
Spring 2021
                                                                       Volume 43, Number 1

New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
Spring 2021
                                                                                           Volume 43, Number 1                           A publication of the
                                                                                                                          New Mexico Bureau of Geology and Mineral Resources
                                                                                                                                      A Research Division of the
                                                                                                                             New Mexico Institute of Mining and Technology
                                                                                                                                         Science and Service
                                                                                                                                          ISSN 0196-948X

                                                                                                                                   New Mexico Bureau of Geology and
                                                                                                                                           Mineral Resources
Contents                                                                                                                              Director and State Geologist
                                                                                                                                          Dr. Nelia W. Dunbar
Late Pennsylvanian Calcareous Paleosols from Central New Mexico: Implications                                                          Geologic Editor: Bruce Allen
for Paleoclimate                                                                                                                    Production Editor: Belinda Harrison
  Tanner, Lawrence H. and Lucas, Spencer G. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3–9
                                                                                                                                          EDITORIAL BOARD
                                                                                                                                         Dan Koning, NMBGMR
New Mexico Graduate Student Abstracts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10–16                            Barry S. Kues, UNM
                                                                                                                                         Jennifer Lindine, NMHU
                                                                                                                                        Gary S. Morgan, NMMNHS

                                                                                                                              New Mexico Institute of Mining and Technology
                                                                                                                                                President
                                                                                                                                        Dr. Stephen G. Wells

                                                                                                                                          BOARD OF REGENTS

                                                                                                                                                Ex-Officio
                                                                                                                                         Michelle Lujan Grisham
                                                                                                                                         Governor of New Mexico

                                                                                                                                          Stephanie Rogriguez
                                                                                                                               Acting Cabinet Secretary of Higher Education

                                                                                                                                                Appointed
                                                                                                                                           Deborah Peacock
                                                                                                                                     President, 2018–2022, Corrales

                                                                                                                                             Jerry Armijo
                                                                                                                                Secretary-Treasurer, 2015–2026, Socorro

                                                                                                                                             Dr. David Lepre
                                                                                                                                           2021–2026, Placitas

                                                                                                                                         Dr. Yolanda Jones King
                                                                                                                                           2018–2024, Moriarty

                                                                                                                                   Veronica Espinoza, student member
                                                                                                                                        2021–2022, Sunland Park

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                                                     Cover                                                                  Address inquiries to Bruce Allen, Geologic Editor,
                                                                                                                          New Mexico Bureau of Geology and Mineral Resources,
                                                                                                                           801 Leroy Place, Socorro, NM 87801. For telephone
Located about 5 miles northeast of Socorro, the Ojo de Amado is a spring that feeds a pool that is                           inquiries call 575-835-5177 or send an email to
an important source of water for local wildlife. “Ojo” literally means “eye” in Spanish, but the word                                 NMBG-NMGeology@nmt.edu
is used dialectically in New Mexico to refer to a spring. The Ojo de Amado is also known to locals                            geoinfo.nmt.edu/publications/periodicals/nmg
as Bursum Springs, one of several geographic features in the state named after Holm Bursum (1867–
1953), a longtime resident of Socorro and an important political figure of the New Mexico Territory
who ultimately served in the U. S. Senate from 1921 to 1925. The steeply dipping strata around the
Ojo de Amado are Upper Pennsylvanian clastic and carbonate rocks of the Atrasado Formation. They
are faulted up just east of the local eastern edge of the Rio Grande rift and along the western flank of
the Cerros de Amado, a set of rugged hills developed in Upper Paleozoic strata.
—Photograph by Spencer G. Lucas.
Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
Late Pennsylvanian Calcareous Paleosols from Central
       New Mexico: Implications for Paleoclimate
Spencer G. Lucas, New Mexico Museum of Natural History and Science, Albuquerque, NM 87104, spencer.lucas@state.nm.us
   Lawrence H. Tanner, Department of Biological Sciences, Le Moyne College, Syracuse, NY 13214, tannerlh@lemoyne.edu

                 Abstract                                        Introduction                             Lucas, 2013). Gypsum beds are rare,
                                                                                                          with one well documented example in
  We document calcareous paleosols from Upper        What have been called “climate-sensi-                early Late Pennsylvanian (Missourian)
  Pennsylvanian (lower Virgilian) strata of the      tive lithologies” are rock types specific            strata (Rejas, 1965; Lucas et al., 2009;
  Burrego Member of the Atrasado Formation
                                                     to a particular climate, the best known              Falcon-Lang et al., 2011). Paleosols
  in the Cerros de Amado of Socorro County,                                                               of Pennyslvanian age, especially cli-
  New Mexico. The Burrego paleosols are an           being coal (wet), gypsum (dry) and cal-
                                                     careous paleosols (seasonally wet/dry).              mate-sensitive calcareous paleosols,
  excellent example of a scarce, climate-sensitive
  lithology in the Pennsylvanian strata of New       Such rock types play a prominent role                have only been documented from two
  Mexico. These paleosols contain mostly             in the interpretation of past climates,              late Paleozoic basins in northern New
  stage II to III carbonate horizons, and their
                                                     constrain climate models and are crit-               Mexico (Tabor et al., 2008; Tanner and
  overall morphology suggests deposition and                                                              Lucas, 2017, 2018). Here, we add to
  pedogenesis under subhumid, seasonally dry         ical to paleogeographic reconstructions
                                                     (e.g., Boucot et al., 2013; Cao et al.,              this sparse record of climate-sensitive
  conditions. This conclusion is consistent with
  paleobotanical and other data that indicate        2019). However, the distribution of                  rocks in the New Mexican Pennsylva-
  such climate conditions were widespread on         climate-sensitive lithologies remains                nian strata a succession of calcareous
  Late Pennsylvanian Pangea. The mean value
                                                     unevenly and incompletely docu-                      paleosols in lower Virgilian strata of
  of the oxygen-isotope ratios from Burrego                                                               Socorro County (Fig. 1).
  paleosol carbonates compares well with the         mented, particularly in older geological
  values from Virgilian paleosols of the San         time periods.
  Juan, the eastern Midland and Chama basins              Indeed, in the Pennsylvanian                        Stratigraphic context
  of New Mexico-Texas, suggesting similar con-       sedimentary rocks of New Mexico, rel-
  ditions of temperature and paleoprecipitation.
                                                     atively few such rocks have been doc-                The calcareous paleosols documented
  Application of the diffusion-reaction model to
  the mean carbon-isotope composition of the         umented. Thus, coal beds are few and                 here are in the Burrego Member of
  carbonate suggests a paleo-pCO2 of approx-         mostly thin, localized and confined to               the Atrasado Formation, strata that
  imately 400 ppmV, which is also consistent         early Middle Pennsylvanian (Atokan)                  encompass the Missourian-Virgilian
  with estimates from correlative carbon-            strata (e.g., Armstrong et al., 1979;                boundary, in the Cerros de Amado of
  ate deposits that formed farther east in
                                                     Kues and Giles, 2004; Krainer and                    Socorro County (Figs. 1-2). Thompson
  Late Pennsylvanian Pangea.

Figure 1. Three late Paleozoic basins in New Mexico that have documented calcareous paleosols of Late Pennsylvanian-early Permian age. Relevant publica-
tions are A = Tanner and Lucas (2018); B= Tabor et al. (2008); C = Tanner and Lucas (2017); D = Mack (2003) and references cited therein; E = Tabor et al.
(2008); F = this paper.

Spring 2021, Volume 43, Number 1                                            3                                                       New Mexico Geology
Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
(1942) presented the first detailed litho-             into the Cerros de Amado region east                 section described here, though very
stratigraphy and biostratigraphy of the                of Socorro (also see Kottlowski, 1960).              close to one of the sections Lucas et
Middle-Upper Pennsylvanian strata that                 He used Burrego Member much as did                   al. (2009) published (their Minas de
crop out in central and southern New                   Thompson (1942), as a slope form-                    Chupadera section) was not studied by
Mexico. In this monograph, Thompson                    ing, mixed clastic-carbonate interval                them. We discovered this section during
(1942) named six formation-rank units                  between two prominent limestone units,               fieldwork in 2018.
in the northern Oscura Mountains of                    the Council Spring Member (below)                         In the Cerros de Amado, the
Socorro County that Lucas and Krainer                  and Story Member (above).                            Burrego Member is 13–55 m thick
(2009) reduced in rank to members of                        Lucas et al. (2009), Barrick et                 and consists mostly of slope-forming
the Atrasado Formation, including the                  al. (2013) and Krainer et al. (2017)                 mudstone and shale interbedded with
Burrego Member.                                        published stratigraphic sections of the              arkosic/micaceous      sandstone     and
     Rejas (1965), in an unpublished                   Burrego Member and adjacent strata                   limestone (Rejas, 1965; Lucas et al.,
master’s thesis, brought much of Thomp-                at several locations in the Cerros de                2009; Barrick et al., 2013; Krainer
son’s (1942) stratigraphic nomenclature                Amado and vicinity. However, the                     et al., 2017). Most limestone beds in
                                                                                                            the Burrego Member are evidently of
                                                                                                            marine origin, as they contain marine
                                                                                                            macrofossils, including algae, crinoids,
                                                                                                            molluscs and brachiopods. Conodont
                                                                                                            and fusulinid biostratigraphy indicates
                                                                                                            the Borrego paleosols are close in age
                                                                                                            to the Missourian–Virgilian boundary,
                                                                                                            and we consider them here to be of
                                                                                                            early Virgilian age (Lucas et al., 2009;
                                                                                                            Barrick et al., 2013).

                                                                                                              Material and methods
                                                                                                            We used standard field methods with a
                                                                                                            1.5-m staff, tape measure and Brunton
                                                                                                            pocket transit to measure the thickness
                                                                                                            of strata in the stratigraphic section
                                                                                                            discussed here, which is located in the
                                                                                                            SE ¼ sec. 26, T2S, R1E (UTM coordi-
                                                                                                            nates are in the caption to Figure 2),
                                                                                                            (Fig. 2). Samples were collected for
                                                                                                            petrographic and isotopic analysis.
                                                                                                            To confirm the pedogenic origin of
                                                                                                            the carbonate, standard 30 μm petro-
                                                                                                            graphic thin sections were examined
                                                                                                            for pedogenic fabrics and textures and
                                                                                                            for evidence of diagenetic effects.
                                                                                                                 Carbonate aliquots for isotopic
                                                                                                            analysis were obtained by selectively
                                                                                                            drilling micritic calcite in lapped slabs
                                                                                                            corresponding to prepared thin sections
                                                                                                            with an ultrafine engraving tool while
                                                                                                            viewing under a binocular microscope.
                                                                                                            The samples were analyzed for δ18O
                                                                                                            and δ13C by the Duke Environmental
                                                                                                            Stable Isotope Laboratory (Nicholas
                                                                                                            School of the Environment, Duke Uni-
                                                                                                            versity, Durham, North Carolina) using
                                                                                                            standard operating procedures (see
                                                                                                            Tanner and Lucas, 2018, for details).
Figure 2. Stratigraphic section of the Burrego Member of the Atrasado Formation near Minas de                    We calculated paleo-pCO2 using
Chupadera in Socorro County (base of section at UTM 333433, 3775122 and top at 333299, 3775300,
zone 13, datum NAD 83; inset map of New Mexico shows location of section in Socorro County). On
                                                                                                            the mean δ13C value from 8 samples
left, lithostratigraphy of the measured section with the calcareous paleosols in the section labeled A–E.   and the diffusion-reaction model of
On right, field photographs of the calcareous paleosols A–E.                                                Cerling (1991, 1999). But, as we did

Spring 2021, Volume 43, Number 1                                               4                                                  New Mexico Geology
Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
not obtain organic matter from the            section. These are marked by repetition      sparse fossils of marine gastropods,
samples for determination of δ13Com,          of specific types of B horizons (Bt, Btk     capped by a 0.2 to 0.3-m-thick dark
we applied values from the literature         or Bk) without an intervening A hori-        to light limestone bed that is nodular,
for formations of similar age and             zon, suggesting an erosional episode         and the weathered surface has vertical
geographic proximity (within 2 degrees        (Kraus and Hasiotis, 2006).                  channels up to 2.5 cm wide and 10 cm
latitude), primarily from the published            The stratigraphic section we            long that are filled with smaller calcare-
data supplements to Montañez et al.           measured encompasses ~ 40 m of most          ous nodules. We infer that these record
(2007, 2016).                                 of the Burrego Member and its upper          root channels formed during subaerial
                                              contact with the overlying Story Mem-        exposure and pedogenesis of the marine
                                              ber (Fig. 2). Most of this stratigraphic     carbonate. The top of the unit is a 0.1
    Outcrop description                       section is mudrock, about 82% of the         m mudstone/limestone breccia consist-
                                              thickness of the strata measured. Minor      ing of limestone blocks up to 4 cm in a
Where the paleosols in the section dis-       lithologies are sandstone/conglomerate       red mudstone matrix with root traces
play sufficiently distinctive pedogenic       (11% of the section) and limestone           and small calcareous nodules. This unit
features to allow classification, we apply    (7% of the section).                         represents a calcic Argillisol formed on
the terminology of Mack et al. (1993)              The section (Fig. 2) begins with red-   the reworked limestone surface.
in assigning names of paleosol orders,        bed mudstone overlain by a thin-bed-              Unit 14 is 2.9 m of dark brown,
modified by adjectives describing the         ded, ripple-laminated, very-fine grained     fine-grained mudstone with a crumb
most prominent subordinate charac-            sandstone that is 0.5 m thick (units         fabric, but the outstanding feature of
teristic. The most common paleosol            2–3). This sandstone has a platy fabric      the unit is the presence of numerous
types we found in the measured section        and contains some discrete calcareous        rhizoliths. These are calcareous masses
are calcic Argillisols and Calcisols to       nodules and scarce root traces that          that weather out of the outcrop face,
argillic Calcisols. The calcic Argillisol     increase in abundance upward and             mostly vertically oriented and irregular
denotes a paleosol horizon in which           has a bioturbated/pedoturbated top.          (noncylindrical) in shape. The masses
the defining characteristic is a clay-rich    The top 0.1 m is a well-developed            are up to 1.0 m long, 0.1 m in diameter
B horizon that is visibly enriched in         carbonate horizon (Stage II of Gile et       and have no internal structure. Most
CaCO3 in the form of nodules, i.e., a         al., 1966) with carbonate nodules 1 to       of these features have a rough, knobby
Btk horizon. In any paleosol profile          2 cm in diameter, drab root traces and       appearance because they consist of
with multiple defining characteristics,       rhizoliths up to 5 cm long. We consider      vertically stacked, calcareous oblate
such as illuviated clays and pedogenic        unit 2 a truncated Calcisol that is          spheroids of varying diameters. Many
carbonate, whether they occur in the          relatively immature, given the lack of       of them taper downward, and some
same horizon or in separate horizons,         coalescing nodules, consisting only of       exhibit branching, supporting their
a subjective judgement was made to            C and Bk horizons. It is overlain by 0.3     interpretation as rhizoliths. The unit
determine which feature is dominant           m of red mudstone (unit 4) followed          also contains subhorizontal arcuate
and which is subordinate. Thus, there         by a 0.3-m-thick bed of coarse-              soil fractures and irregular (botryoidal)
may be a fine distinction between a           grained, arkosic sandstone capped            calcareous masses up to 0.1 m wide.
calcic Argillisol and an argillic Calcisol.   by a 0.1-m-thick limestone-pebble            Unit 14 lacks any horizonation, so it
In profiles where development of the          conglomerate (units 5–6). Some of the        is interpreted to represent a single B
calcareous B horizons (Bk, or Btk if          limestone pebbles in this conglomerate       horizon containing calcareous nodules
argillic and calcic) is stronger than the     contain marine macrofossils, including       and vertic fractures. We classify this
argillic (Bt) horizons, we assign the des-    brachiopods and gastropods. The              unit as a calcic Vertisol that formed
ignation Calcisol or argillic Calcisol, as    overlying unit 7 is 11.3 m thick and is a    through an extended interval of con-
appropriate. In addition to Argillisols       red mudstone slope with its upper half       tinuous sedimentation (aggradation)
and Calcisols, and variations thereof,        covered by mostly colluvium. The lower       during pedogenesis, in other words, a
we recognize calcic Vertisols, paleosols      half of this unit has numerous carbonate     cumulative paleosol. The outcrop does
with prominent vertic fractures and           nodules isolated in the mudstone, but        not contain the top of the unit, and no
calcareous features in the B horizon.         lacks distinct horizonation. Therefore,      A-horizon is preserved.
Many mudstone beds of varying thick-          we consider this unit a calcic Protosol.          The overlying 5.4 m of red mud-
ness display pedogenic features, such              Above unit 7 is a nodular and           stone (unit 15) has clay-lined root traces
as calcareous nodules, drab colors and        bioturbated limestone (unit 8) rich          and numerous carbonate nodules that
root traces, but lack distinct horizona-      in marine macrofossils, including            increase upward to form a coalesced
tion. We term these units Protosols, and      echinoids, gastropods and nautiloids.        (Stage III to IV) layer 0.6 m thick that
where they contain calcareous nodules         A 1.2-m-thick, very coarse-grained,          is exposed over a lateral extent of 5 m.
we label them calcic Protosols. Most          arkosic sandstone bed (unit 9) above         We regard this unit as the Btk horizon
paleosol profiles in the section are          has limestone rip-ups at its base and        of an argillic Calcisol. The unit is
truncated in that they lack a discernible     displays somewhat indistinct, tabular        truncated above abruptly by a massive,
eluviated upper (A) horizon and display       bedding. The overlying interval of           0.5-m-thick sandstone ledge (unit
evidence of sediment removal. We also         limestone (units 10–13) begins with a        16). The sandstone is overlain by 1.7
recognize compound profiles in the            0.2-m-thick bed of lime mudstone with        m of red mudstone with drab-brown

Spring 2021, Volume 43, Number 1                                  5                                              New Mexico Geology
Spring 2021 Volume 43, Number 1 - New Mexico Bureau of Geology and Mineral Resources / A Research Division of New Mexico Tech
mottling at the top (unit 17). The mud-                 Outcrop interpretation                           argillic Calcisols and Calcisols with
stone contains numerous rhizoliths                                                                       well-developed (Stage III to Stage IV
and calcareous nodules that increase in              As noted above, the Burrego Member                  sensu Gile et al., 1966; Machette, 1985)
abundance vertically to form two hori-               is a lithosome that includes a mixture              carbonate horizons hosted in argillic
zons, each approximately 0.3 m thick,                of sediments of marine and nonmarine                red beds. Examination of petrographic
of carbonate nodules up to 8 cm in                   origin, and the section we studied is               thin sections indicates that pedogenic
diameter, which coalesce to form Stage               representative of that. Thus, limestone             carbonate in the section consists of
II to III pedogenic carbonate horizons.              beds in the section with marine inver-              micritic calcite with displacive textures
Nodules decrease in abundance in the                 tebrate fossils (units 8, 12 and 18) are            and fabrics, including circumgranular
upper 0.4 m of the overlying mudstone                obviously of marine origin, whereas the             cracking, that demonstrate a lack
interval of unit 17. The transitional                other strata are of nonmarine origin.               of diagenetic replacement (Fig. 3).
nature of the underlying and overlying                    The relatively thick intervals of              Samples generally were selected from
mudstone intervals of unit 17 suggests               red mudstone that host the calcare-                 below the coalesced carbonate horizon
that this unit represents a calcareous               ous paleosols we studied are readily                to maximize depth below the original
paleosol, specifically a compound                    interpreted as nonmarine deposits of                soil surface.
argillic Calcisol with Btk (Stage II) and            alluvial floodplains that have under-
Bk (Stage III) carbonate horizons.                   gone variable amounts of pedogenesis.
     The overlying bed of limestone                  Sandstones in the section are likely of
                                                                                                                Paleosol analysis
(unit 18) is a 1.3 m thick, thickly bed-             fluvial origin, and limestone clasts in
ded, cherty bioclastic wackestone with               the conglomerate low in the section                 Four paleosols were sampled for isoto-
abundant crinoidal debris. Above that                (unit 6) contain marine invertebrate                pic analysis (labelled A, C, D and E in
is a covered slope 2.1 m thick overlain              fossils, which suggests proximity to                Figure 2). In ascending order these are:
by a very coarse grained, micaceous,                 marine carbonate beds. Thus, we                     (1) a thin Calcisol with Stage II calcar-
trough crossbedded sandstone (unit                   interpret the section as mostly repre-              eous paleosol developed in a blocky,
20) that is 1.7 m thick. The uppermost               senting floodplain deposition close to              very-fine grained sandstone containing
part of the Burrego Member is a 6.1 m                the shoreline and sea, interrupted by               calcareous rhizoliths (station A); sta-
thick slope, mostly covered, but where               marine incursions.                                  tion B is a nodular carbonate formed
bedrock is exposed on this slope it is red                The section we studied includes                on a marine limestone and was not
mudstone (unit 21). The base of the over-            meter-scale profiles of simple and                  sampled due to the likelihood of
lying Story Member is a medium-bedded,               cumulative paleosols, including calcic              incorporation of marine carbonate; (2)
cherty wackestone with fossils of algae,             Argillisols, argillic Calcisols, Calcisols          station C is a calcic Vertisol exposure,
crinoids and brachiopods.                            and calcic Vertisols. Most samples for              2.9-m thick, notable for the abundance
                                                     isotopic analysis were selected from                of calcite-cemented rhizoliths up to 1
                                                                                                         meter in vertical length in a mudstone
                                                                                                         matrix with blocky ped fabric; (3) sta-
                                                                                                         tion D is a Calcisol with a prominent
                                                                                                         Stage III nodular horizon; and (4) sta-
                                                                                                         tion E is a calcic Argillisol containing
                                                                                                         two nodular horizons exhibiting Stage
                                                                                                         II and Stage III morphology, likely
                                                                                                         representing stages in formation of a
                                                                                                         cumulative soil.
                                                                                                              Petrography reveals the presence
                                                                                                         of typical alpha-type fabrics in the car-
                                                                                                         bonate nodules sampled in the section,
                                                                                                         such as grain coronas and corroded
                                                                                                         floating grains that indicate that these
                                                                                                         nodules represent the accumulation of
                                                                                                         carbonate in the B horizon of paleosols
                                                                                                         (Fig. 3; Alonso-Zarza and Wright,
                                                                                                         2010). Thus, we are confident that
                                                                                                         these carbonates formed within soils
                                                                                                         developed on alluvial muds.
                                                                                                              Isotopic analysis of eight carbonate
                                                                                                         samples from the Burrego Member are
                                                                                                         tightly clustered and yielded δ13Ccarb
Figure 3. Petrographic features of Burrego Member calcic paleosols. A) Spar-filled voids and shrinkage   values ranging from -6.4 ‰ to -5.6 ‰
fractures (sf). B) Mudstone clast surrounded by circumgranular crack (cc). C) Mudstone matrix with       with a mean of -6.0 + 0.1 ‰ (VPDB)
displacive micrite (dm). D) Mudstone clast surrounded by sparry grain halo (gh).                         (Table 1). The isotopic composition of

Spring 2021, Volume 43, Number 1                                             6                                                 New Mexico Geology
two samples from rhizoliths at Station     from the Virgilian paleosols of the                                        2005). Thus, paleosol morphology
C (-6.0 ‰, -5.6 ‰ (VPDB)) is the same      Chama Basin of northern New Mexico                                         supports the isotopic analyses in
as measured in samples of carbonate        (Tanner and Lucas, 2018), suggesting                                       suggesting sediment deposition and
nodules, suggesting micritization of the   similar conditions of temperature and                                      soil formation under widely varying
root casts in the deep (>50 cm depth)      paleoprecipitation.                                                        moisture conditions.
soil environment and therefore repre-           Overall, the morphology of the
sentative of the isotopic composition      paleosols in the Burrego Member sug-                                            Table 1. Isotopic analyses of Burrego
of soil respired CO2. Values of δ18O       gests deposition and pedogenesis under                                          calcareous paleosol samples. Values
have a wider spread, ranging from -5.7     subhumid, seasonally dry conditions.                                            in units ‰ VPDB.
to -1.8 ‰, with a mean value of -3.4       The calcareous paleosol horizons vary
+ 0.5‰ (VPDB). The greater range                                                                                           Unit              δ18O        δ13C
                                           in maturity from Stage II to IV, and
for δ18O likely records pedogenic          both cumulate and composite paleosol
carbonate precipitation under a range      profiles are present, suggesting higher                                         Station A         -3.8        -5.8
of temperature and/or precipitation        rates of sedimentation during some
conditions. The composition of the car-    intervals, alternating with slow sedi-                                          Station C-1       -3.5        -5.6
bonate is determined by a combination      mentation during others (e.g., Deutz
of factors in the diffusion model: plant   et al., 2002; Monger et al., 2009). In                                          Station C-2       -4.0        -6.0
respiration rate, isotopic composition     particular, the “mega-rhizolith” horizon
of the plant organic matter (OM),          at Station C appears to be a single,                                            Station D-1       -2.6         -6.2
atmospheric isotope composition and        undifferentiated B horizon with an
pCO2. The isotopic composition of the      exposed thickness of 2.9 m. This attests                                        Station D-2A      -4.0        -6.1
plant OM tells us about the vegetation,    to continuous aggradation of the sur-
but only in the most general sense (C3     face contemporaneous with pedogenic
vs C4), and nothing is known about                                                                                         Station D-2B      -5.7        -6.4
                                           processes, particularly root turbation.
any possibly unique isotopic aspects of    The interplay of sedimentation and
Pennsylvanian plant OM.                    biological activity with pedogenesis                                            Station E-1       -1.8        5.9
     The lack of δ13Com measurements       suggests meteoric precipitation at the
in this study makes application of the     higher end of the range for which calcar-                                       Station E-2       -2.1        -5.6
diffusion-reaction model of Cerling        eous paleosol formation is considered
(1991; 1999) somewhat problematic.         possible (Birkeland, 1999; Retallack,
However, the datasets of Montañez
et al. (2007, 2016) provide useful         Ma
measurements of δ13Com that allow          299       series               N AM         "global"
us to at least make an approximation                                      stage         stage

of paleo-pCO2. Temperature of soil
carbonate formation, the isotopic
composition of atmospheric CO2 and
                                                                                       Gzhelian
                                                                          Virgilian

the contribution of soil-respired CO2
                                                     Late Pennsylvanian

(the S(z) term) are also required for
                                                                                                                                                    Burrego
application of the model. We assumed                                                                                                                Member
                                                                                                               Burrego
values based on (but not identical to)                                                                         Member
                                                                                                                                                    paleosols
                                                                                                                                                    δ13 C
those of Montañez et al. (2007, 2016),                                                                         paleosols
                                                                                                               pCO2
using values δ13Com = -21.0 ‰, δ13Ca       304
= -2.5 ‰ (composition of atmospheric
                                                                                       Kasimovian
                                                                          Missourian

CO2), T = 25oC and S(z) = 3000 ppmV.
The S(z) value reflects the fact that
carbonate precipitation mainly occurs
during the drier months when plant
productivity is decreased (Breecker,
2013). The Borrego carbonates yielded      307
                                                    Middle

a mean δ13Ccarb of -6.0 ‰. Using the
                                                                          Desm.
                                                    Penn.

                                                                                        Mosc.

values cited above we obtained a
paleo-pCO2 for the early Virgilian of ~
400 ppmV. This estimate accords well                                                                δ13 C
                                                                                                         -12    -10               -8         -6           -4              -2
with values presented by Montañez et                                                                           pCO 2
al. (2016) for the late Missourian, and                                                                             300           600      900         1200        1500

the early Virgilian (Fig. 4). The mean     Figure 4. Compilation of Late Pennsylvanian δ13Ccarb data from Montañez et al. (2016), the pCO2 curve
δ18O value of -3.4 + 0.5 ‰ (VPDB)          of Chen et al. (2018) calculated from the Montañez et al. data, δ13Ccarb values obtained in this study, and
obtained compares well with the values     the calculated pCO2 value from the Burrego Member.

Spring 2021, Volume 43, Number 1                                                   7                                                              New Mexico Geology
Discussion                       Climate models, paleosol data and                       References
                                             paleobotany converge to identify a
In New Mexico, sedimentary rocks             distinct monsoonal pattern of moisture    Alonso-Zarza, A.M. and Wright, V.P., 2010b,
of late Paleozoic age are synorogenic        in western Pangea during the Late            Calcretes; in Alonso-Zarza, A.M. and Tanner,
deposits of the Ancestral Rocky Moun-        Pennsylvanian–early Permian, with            L.H., eds., Carbonates in Continental Envi-
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Gondwana–Laurussia collision that            (e.g., Parrish, 1993; Tabor and Mon-         Developments in Sedimentology 61: Elsevier,
                                             tañez, 2004; Tabor and Poulsen, 2008).       Amsterdam, p. 226–267.
amalgamated late Paleozoic–Mesozoic                                                    Armstrong, A.K., Kottlowski, F.E., Stewart, W.J.,
Pangea (e. g., Kluth and Coney, 1981;        There was a global shift from wetter
                                                                                          Mamet, B.L., Baltz, E.H., Jr., Siemers, W.T. and
Dickinson and Lawton, 2003), the             Middle Pennsylvanian climates to drier
                                                                                          Thompson, S., III, 1979. The Mississippiian
ARM in New Mexico produced a                 Late Pennsylvanian climates that began
                                                                                          and Pennsylvanian (Carboniferous) systems
series of basement-cored uplifts sur-        in New Mexico during the Middle              in the United States—New Mexico. U. S. Geo-
rounded by sedimentary basins during         Pennsylvanian (Desmoinesian) when            logical Survey, Professional Paper 1110-W, p.
Middle Pennsylvanian (Atokan)-early          floras with seasonally dry elements          W1–W27.
Permian (Wolfcampian) time (e.g.,            begin to appear and then become more      Barrick, J., Lucas, S .G., and Krainer, K., 2013,
Kues and Giles, 2004; Brotherthon et         common during the Late Pennsylva-            Conodonts of the Atrasado Formation (upper-
al., 2020). The result was an archipel-      nian and early Permian (DiMichele et         most Middle to Upper Pennsylvanian), Cerros

ago of islands (the uplifts) surrounded      al., 2011, 2017).                            de Amado region, central New Mexico, USA:
                                                  In central New Mexico, the              New Mexico Museum of Natural History and
by shallow-marine sedimentary basins                                                      Science, Bulletin 59, p. 239–252.
during the Middle–Late Pennsylva-            Atrasado Formation, including the
                                                                                       Birkeland, P.W., 1999, Soils and Geomorphology,
nian, followed by mostly nonmarine           Burrego Member, contains a succession
                                                                                          3rd ed., Oxford, New York, 536 pp.
deposition in these and reconfigured         of paleofloras that are all of “mixed”
                                                                                       Boucot, A.J., Chen, X., Scotes, C.R. and Morley,
sedimentary basins during the early          composition. This means that plants          R.J., 2013, Phanerozoic paleoclimate: an atlas
Permian culmination of the ARM               that favored wet substrates and those        of lithologic indicators of climate: SEPM
orogeny. Around the fringes and on the       from habitats with seasonal moisture         Concepts in Sedimentology and Paleontology,
flanks of the uplifts, nonmarine fluvial     limitations are mixed together in            no. 11, Map Folio, 28 maps.
deposition took place in some locations      the fossil assemblages and evidently      Breecker, D.O., 2013, Quantifying and under-
during the Pennsylvanian, such as the        grew in close proximity. These floras        standing the uncertainty of atmospheric

section described here, and by early         indicate climates that varied from           CO2 concentrations determined from calcic
                                             subhumid to semiarid and arid                paleosols: Geochemistry, Geophysics, Geosys-
Permian time fluvial deposits (largely                                                    tems, v. 14, p. 3210–3220.
siliciclastic red beds) were filling the     (DiMichele et al., 2017).
                                                                                       Brotherton, J.L., Chowdhury, N.U.M.K., and
formerly marine basins.                           The Burrego paleosols formed in a
                                                                                          Sweet, D.E., 2020, Synthesis of late Paleozoic
     Calcareous paleosols are compara-       subhumid climate under seasonally dry
                                                                                          sedimentation in central and eastern New
tively common in lower Permian strata        conditions. The pCO2 value of ~ 400          Mexico: Implications for timing of ancestral
in New Mexico (particularly in the           ppm we calculate is within the range of      Rocky Mountains deformation: SEPM
Abo Formation: Mack, 2003 and refer-         values given by Montañez et al. (2016,       Special Publication 113. doi: 10.102110/
ences cited therein), but a few Virgilian    fig. 2) across the Missourian–Virgilian      sepmsp.113.03.
calcareous paleosols are the only Penn-      boundary. Thus, the Burrego paleosols     Cao, W., Williams, S., Flament, M., Sahirovic, S,
sylvanian examples that have been doc-       indicate a climate within the range of       Scotese, C. and Müller, R.D., 2019, Palaeolat-

umented prior to the Burrego Member          what were thought to be the climates         itudinal distribution of lithologic indicators
                                             of equatorial Pangea during the Late         of climate in a palaeogeographic framework:
record documented here. Thus, Tabor                                                       Geological Magazine, v. 156, p. 331–354.
et al. (2008) briefly discussed a few late   Pennsylvanian—subhumid and season-
                                                                                       Cerling, T.E., 1991, Carbon dioxide in the atmo-
Virgilian calcareous paleosols in the        ally dry. The Burrego paleosols thus
                                                                                          sphere: evidence from Cenozoic and Mesozoic
Rowe–Mora basin (Taos trough) and            add an important data point of climate
                                                                                          paleosols: American Journal of Science, v. 291,
in the Bursum Formation of southern          sensitive lithologies from what was far      p. 377–400.
New Mexico, and Tanner and Lucas             western, tropical Pangea during the       Cerling, T.E., 1999, Stable carbon isotopes in
(2018) documented similar late Vir-          Late Pennsylvanian.                          palaeosol carbonates; in Thiry, M. and Simon-
gilian paleosols in part of the Paradox                                                   Coinçon, R., eds., Palaeoweathering, palae-
basin (Fig. 1). These workers concluded           Acknowledgments                         osurfaces and related continental deposits:
                                                                                          International Association of Sedimentologists,
that the Virgilian paleosols indicate
                                                                                          Special Publication 27, p. 43–60.
highly variable climate ranging from         The comments of the reviewers, D. O.      Chen, J., Montañez, I.P., Qi, Y., Shen, S., and
subhumid to semiarid with extremes           Breecker and H. C. Monger, and the           Wang, X., 2018, Strontium and carbon
in seasonal precipitation, which is          editor, B. D. Allen, improved the con-       isotopic evidence for decoupling of pCO2
consistent with our interpretation of        tent and clarity of the manuscript.          from continental weathering at the apex of
the Burrego paleosols.                                                                    the late Paleozoic glaciation: Geology, v. 46,
     New Mexico was located near the                                                      p. 395–398.
western end of the Pangean tropical
belt during the Late Pennsylvanian.

Spring 2021, Volume 43, Number 1                               8                                                  New Mexico Geology
Deutz, P., Montañez, I.P. and Monger, H.C.,          Kues B.S., and Giles K.A., 2004, The late Paleo-      Tabor, N.J. and Poulsen, C.J., 2008, Palaeocli-
  2002, Morphology and stable and radiogenic            zoic Ancestral Rocky Mountains system in              mate across the Late Pennsylvanian–early
  isotope composition of pedogenic carbonates           New Mexico; in Mack G.H., and Giles, K.A.,            Permian tropical palaeolatitudes: a review
  in late Quaternary relict soils, New Mexico,          eds., The Geology of New Mexico, A Geologic           of climate indicators, their distribution, and
  USA: an integrated record of pedogenic over-          History: New Mexico Geological Society,               relation to palaeophysiographic climate
  printing: Journal of Sedimentary Research, v.         Special Publication 11, p. 95–136.                    factors: Palaeogeography, Palaeoclimatology,
  72, p.809–822.                                      Lucas, S.G. and Krainer, K., 2009, Pennsylvanian        Palaeoecology, v. 268, p. 293–310.
Dickinson, W.R., and Lawton, T.F., 2003,                stratigraphy in the northern Oscura Moun-           Tabor, N.J., Montañez, I.P., Scotese, C.R.,
  Sequential intercontinental suturing as the           tains, Socorro County, New Mexico: New                Poulsen, C.J. and Mack, G.H., 2008, Paleosol
  ultimate control of Pennsylvanian Ancestral           Mexico Geological Society, Guidebook 60, p.           archives of environmental and climatic history
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  31, p. 609–612.                                     Lucas, S.G., Krainer, K., and Barrick, J.E., 2009,      latest Pennsylvanian through Early Permian:
DiMichele, W.D., Cecil, C.B., Chaney, D.S., Elrick,     Pennsylvanian stratigraphy and conodont bio-          Geological Society of America, Special Paper
  S.D., Lucas, S.G., Lupia, R., Nelson, W.J. and        stratigraphy in the Cerros de Amado, Socorro          441, p. 291–303.
  Tabor, N.J., 2011, Pennsylvanian-Permian              County, New Mexico: New Mexico Geologi-             Tanner, L.H., and Lucas, S.G., 2017, Paleosols
  vegetational changes in tropical Euramerica;          cal Society, Guidebook 60, p. 183–212.                of the Upper Paleozoic Sangre de Cristo For-
  in Harper, J.A., ed., Geology of the Pennsyl-       Machette, M.N., 1985, Calcic soils of the south-        mation, north-central New Mexico: Record
  vanian-Permian in the Dunkard basin: 76th             western United States: Geological Society of          of early Permian palaeoclimate in tropical
  Annual Field Conference of Pennsylvania               America, Special Paper 203, p. 1–21.                  Pangea: Journal of Palaeogeography, v. 6, p.
  Geologists Guidebook, Washington, PA, p.            Mack, G.H., 2003, Lower Permian terrestrial             144–162.
  60–102.                                               palaeoclimate indicators in New Mexico and          Tanner, L.H., and Lucas, S.G., 2018, Pedogenic
DiMichele, W.A., Chaney, D.S., Lucas, S.G.,             their comparison to palaeoclimate models:             record of climate change across the Pennsyl-
  Nelson, W.J., Elrick, S.D., Falcon-Lang, H.J.         New Mexico Geological Society, Guidebook              vanian–Permian boundary in red-bed strata
  and Kerp, H., 2017, Middle and Late Penn-             54, p. 231–240.                                       of the Cutler Group, northern New Mexico,
  sylvanian fossil floras from Socorro County,        Mack, G.H., James, W.C., and Monger, H.C.,              USA: Sedimentary Geology, v. 373, p. 98–110.
  New Mexico, U.S.A: New Mexico Museum                  1993, Classification of paleosols: Geological       Thompson, M.L., 1942, Pennsylvanian System in
  of Natural History and Science, Bulletin 77,          Society of America Bulletin, v. 105, p. 129–136.      New Mexico: New Mexico School of Mines,
  p. 25–99.                                           Monger, H.C., Cole, D.R., Buck, B.J. and                State Bureau of Mines and Mineral Resources,
Falcon-Lang, H.J., Jud, N.A., Nelson, W.J.,             Gallegos, R.A., 2009, Scale and the isotopic          Bulletin 17, 92 p.
  DiMichele, W.A., Chaney, D.S. and Lucas,              record of C4 plants in pedogenic carbonate:
  S.G., 2011, Pennsylvanian coniferopsid forests        from the biome to the rhizosphere: Ecology, v.
  in sabkha facies reveal the nature of seasonal        90, p.1498–1511.
  tropical biome: Geology, v. 39, p. 371–374.         Montañez, I.P., Tabor, N.J., Niemeier, D., DiMi-
Gile, L.H., Peterson, F.F., and Grossman, R.B.,         chele, W.A., Frank, T.D., Fielding , C.R., and
  1966, Morphological and genetic sequences             Isbell, J.L., 2007, CO2-forced climate and
  of accumulation in desert soils: Soil Science, v.     vegetation instability during late Paleozoic
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Kluth, C.F. and Coney, P.J., 1981, Plate tectonics    Montañez, I.P., McElwain, J.C., Poulsen, C.J.,
  of the Ancestral Rocky Mountains: Geology,            White, J.D., DiMichele, W.A., Wilson, J.P.,
  v. 9, p. 10–15.                                       Griggs, G., and Hren, M.T., 2016, Climate
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  Bureau of Mines and Mineral Resources,              Parrish, J.T., 1993, Climate of the superconti-
  Bulletin 66, 187 p.                                   nent Pangaea: Journal of Geology, v. 101, p.
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  sylvanian Sandia Formation in northern and          Rejas, A., 1965, Geology of the Cerros de Amado
  central New Mexico: New Mexico Museum                 area, Socorro County, New Mexico: [M.S.
  of Natural History and Science, Bulletin 59,          thesis]: New Mexico Institute of Mining and
  p. 77–100.                                            Technology, Socorro, 128 p.
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  A., 2017, Microfacies and sedimentary                 ies for amount and seasonality of precipitation
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  633–646.

Spring 2021, Volume 43, Number 1                                              9                                                       New Mexico Geology
New Mexico Graduate Student Abstracts
     New Mexico Geology recognizes the important research of graduate students working in M.S. and Ph.D. programs.
   The following abstracts are from M.S. theses and Ph.D. dissertations completed in the last 12 months that pertain to the
                                     geology of New Mexico and neighboring states.

New Mexico Institute of                               shelf to basin sandy turbidites and carbonate
                                                      mass-transport deposits sourced from the north
                                                                                                             as the Nitt Monzonite. The Nitt Monzonite is
                                                                                                             pervasively potassically and phyllically altered
Mining and Technology                                 and northeastern shelf margins during Leonard-         with local late-stage vein-controlled propylitic
                                                      ian time (275 Ma). Compositional heterogeneity         alteration assemblages. Carbonate-phyllic alter-
TWO-STAGE LANDSLIDE EMPLACEMENT                       within this unit is poorly understood but strongly     ation observed in the Nitt Monzonite consists
ON THE ALLUVIAL APRON OF AN                           impacts the spatial and temporal distribution of       of sericite + carbonate + quartz + chlorite ±
EOCENE STRATOVOLCANO                                  reservoir forming elements. Substantial research       pyrite. This alteration style is atypical of the
Chirigos, Michael G., M.S.                            has focused on the Bone Spring Formation, but          classic quartz-sericite-pyrite (QSP) type phyllic
                                                      little work has been undertaken to understand          alteration of porphyry copper deposits.
The Sawtooth Mountains, western New Mex-              the depositional controls on intramember min-             The Nitt Monzonite exhibits an inherently
ico, comprise erosionally isolated klippen of         eralogy and compositional heterogeneity of the         low permeability (
initial development of a graben associated with       of 81.9 ka, the calculated intra-dome eruptive       vanadium and arsenic are released under
collapse of the Magdalena caldera during the          frequency is 1 eruption event per 5.5 ka for when    oxidizing, alkaline conditions. Groundwater
mid-Tertiary. This study infers that, although        Valles caldera enters periods of sustained dome      leaching experiments showed appreciable release
not exposed at present erosion levels, a magma        emplacement. Volume estimations, along with          of uranium and vanadium, but not arsenic. The
intruded the fault zone associated with the           published volumes of the youngest eruptions,         third study investigates the leachability of redis-
graben and generated a magmatic hydrothermal          indicate that the post-caldera dome and vent         tributed-type ores from the Westwater Canyon
fluid which interacted with indigenous carbonate      complexes range in volume from 0.8 km3 to            Member, and primary-type ores of the Jackpile
strata in the subsurface. The dissolution of car-     14.1 km3 and have both increased and decreased       Sandstone and Brushy Basin members. Here,
bonate resulted in modification of the magmatic       throughout post-caldera evolution. In contrast,      leaching tests using alkaline lixiviants and ambient
fluid which rose to upper structural levels and       eruptive flux following caldera collapse has sys-    groundwater showed that gangue mineralogy and
reacted with the Nitt Monzonite, producing the        tematically increased between each post-caldera      the non-mineral hosts of uranium produce leach-
carbonate phyllic alteration. This process may        volcanic complex from 0.09 to 2.56 km3/ka            ing trends entirely discordant to those of stoichio-
be related to underlying calcsilicate alteration in   during post-caldera evolution. Using new ages of     metric minerals previously identified as important
the subsurface rock units, with the potential for     the caldera-forming ignimbrite, a syn-resurgent      components in these deposits (meta-tyuyamunite,
accompanying base metal mineralization.               lava, and the oldest post-resurgent ring-fracture    meta-autunite, uraninite).
                                                      eruption, the resurgence durations at Valles
QUANTIFYING THE TIMESCALES OF                         caldera are constrained to be between 74.4 ±         RAINFALL-RUNOFF RELATIONSHIPS IN
ERUPTIONS AND RESURGENCE FOL-                         3.3 ka and 41.8 ± 6.7 ka. The average magmatic       THE ARROYO DE LOS PINOS, SOCORRO,
LOWING CALDERA COLLAPSE: 40AR/39AR                    flux during resurgence is between 0.52 and 0.92      NEW MEXICO
DATING AND VOLUME ESTIMATIONS OF                      km3/ka, which is similar to pluton-filling rates,    Richards, Madeline A., Ph.D.
POST-CALDERA VOLCANISM AT VALLES                      suggesting that resurgence is partially explained
CALDERA, NORTHERN NEW MEXICO                          by a significant decrease in magmatic flux follow-   The Arroyo de los Pinos is an ephemeral tribu-
Nasholds, Morgan Wade Maynard, Ph.D.                  ing the large fluxes that sustain caldera-forming    tary to the Rio Grande located in central New
                                                      magma bodies. Establishing an accurate timing        Mexico, draining an area of 32 km2. In 2018 the
Despite recognition as one of the greatest            of rapid events during post-caldera evolution is     US Bureau of Reclamation funded a sediment
volcanic hazards in the southwestern United           possible due to the combination of dating only       transport study at the confluence of the arroyo
States, many aspects of the post-caldera history      sanidine grains without melt inclusion-hosted        and the Rio Grande, with the goal of monitoring
of Valles caldera are poorly constrained. This        excess 40Ar and the ability of ARGUS VI mass         sediment influx to the mainstream channel
study provides 49 new high-precision 40Ar/39Ar        spectrometer to identify problematic grains that     in order to better inform sediment transport
sanidine ages and surface volume estimations to       skew the weighted mean ages. The eruptive fre-       models. To supplement this study and to enable
reveal insights into lifespans of dome emplace-       quency during dome activity and increasing flux      generalization to other ephemeral tributaries,
ment as well as resurgence. Caldera collapse          has important implications should Valles caldera     more information was needed on up-basin flow
and deposition of the Tshirege Member of the          enter a new phase of volcanic activity. Likewise,    generating processes. This thesis focuses on these
Bandelier Tuff at 1231.6 ± 1.0 ka was followed        developing similar comprehensive age and             efforts to characterize the runoff generating
by emplacement of 34 volcanic units erupted           volume datasets is necessary to assess hazards at    mechanisms.
from vents on the resurgent dome and along the        other Quaternary volcanic systems.                      A network of eighteen pressure transducers
caldera-ring fracture. New ages indicate vent and                                                          and five rain gauges were installed throughout
dome complexes that followed collapse were            IMPLICATIONS OF CRYPTIC, NONSTOI-                    the arroyo’s watershed in various subbasin trib-
emplaced during polygenetic and monogenetic           CHIOMETRIC URANIUM MINERAL-                          utaries. Pressure transducers monitored water
eruptive events. The Deer Canyon rhyolite             IZATION ON THE FORMATION AND                         stage data, and these were converted to discharge
eruptions began immediately following caldera         LEACHABILITY OF SANDSTONE-HOSTED                     hydrographs for each flow event. The runoff
formation and lasted until 1220.5 ± 3.6 ka for a      URANIUM ORES, GRANTS DISTRICT,                       events monitored this way were all small, close
total lifespan of 11.4 ka. Similarly, the Redondo     NEW MEXICO                                           to the threshold of runoff generation, and did
Creek Member erupted between 1199.0 ± 5.9             Pearce, Alexandra Rose, Ph.D.                        not fully activate the channel network. Tipping
ka and 1186.3 ± 2.9 ka for a lifespan of 12.7                                                              bucket rain gauges monitored rainfall. Data
ka. Cerro del Medio, the oldest post-resurgent        This dissertation consists of three studies exam-    collected from this network show that rainfall
dome, is also the longest-lived ring-fracture         ining sandstone-hosted uranium ores from the         intensity, subbasin lithology and antecedent soil
complex, erupting seven units in 25.2 ka between      Grants uranium district in northwestern New          moisture conditions are the primary factors that
1157.2 ± 3.1 and 1132.0 ± 4.7 ka. Following           Mexico. The first investigates the mineralogy        control runoff initiation, while total rainfall
Cerro del Medio, Cerros del Abrigo erupted at         of primary-type uranium ores from the Jackpile       depth and lithology are the main controls on run-
least twice between 1009.8 ± 1.7 and 997.0 ±          Sandstone and Brushy Basin members of the            off ratio, and subbasin area is the main control
1.6 ka. These longer-lived dome complexes are         Jurassic Morrison Formation. These ores are          on lag time.
located within structurally-complex zones of the      characterized by cryptic mineral and mineraloid         Prior to transducer installation, a particularly
caldera suggesting the dense network of faults        mixtures, and uranium hosted by “uraniferous         large flood on 7/26/2018 left behind high-water
promote magma transport to the surface, pro-          organic matter.” The host organic matter and the     marks at several locations throughout the water-
ducing long-lived eruptions. Conversely, the six      uranium mineralization is interpreted as having      shed. These high-watermarks were surveyed and
dome and vent complexes that erupted between          been fixed within the sediments during multistage    used as a proxy for maximum flood stage at
804.7 ± 1.9 ka and 68.7 ± 1.0 ka have shorter         groundwater mixing episodes involving one            each location. Peak stage comparisons show that
eruptive lifespans than the early post-caldera        or more brines and humic acid-bearing fluid(s)       maximum infiltration occurs in the lower third of
eruptions. Three of the complexes—San Antonio         that resulted in humate flocculation. The second     the watershed that is dominated by alluvial cover
Mountain, South Mountain, and the East Fork           study evaluates the environmental geochemistry       and where the channel develops a multi-threaded
Member—are polygenetic with lifespans between         of ores of the Jackpile Sandstone sampled from       planform. Results from a relative gravity survey
5.2 and 5.5 ka. The Cerro Santa Rosa 2, Cerro         the St. Anthony Mine in Cibola County, NM.           conducted in 2018 confirm that maximum
San Luis, and Cerro Seco domes are either mono-       The site, slated for remediation, was assessed       infiltration occurs in the lower elevations of the
genetic or polygenetic with lifespans less than       by its responsible party using a geochemical         watershed, where the channel is multi-threaded
the associated age uncertainties.The mapped           model which used the uranylsilicate mineral          and flows over alluvium.
post-caldera units are grouped into a total of 15     uranophane to determine alternate abatement
eruptive events, bracketed by measurable intra-       standards for uranium in groundwater. In our
and inter-dome repose periods. Combined with          examination, we did not find uranophane. Batch
the total duration of dome and vent lifespans         leaching tests showed that significant uranium,

Spring 2021, Volume 43, Number 1                                             11                                                        New Mexico Geology
PENNSYLVANIAN-PERMIAN EVOLUTION                      gene and Quaternary Puysegur Subduction Zone         arc zircons (92–223 Ma). Isolated, secondary
OF THE DARWIN BASIN OF EASTERN                       of New Zealand. The formation of a subduction        Cambrian peak ages occur at the 2.0 Ma strati-
CALIFORNIA: BASIN DEVELOPMENT                        zone on the southwestern margin of Laurentia         graphic horizon in the Mesilla basin and 3.1 Ma
IN THE BACK-ARC OF THE INCIPIENT                     would end the transmission of transpressional        stratigraphic horizon in the Socorro basin and
CORDILLERAN SUBDUCTION ZONE.                         stress from the California-Coahuila Transform        overlap in age with Cambrian intrusions that
Vaughn, Lochlan Wright, Ph.D.                        Fault that drove Ancestral Rocky Mountains           have been reported from parts of New Mexico
                                                     uplift. Our timeline for the onset of Cordilleran    and southern Colorado (519–516 Ma). All strati-
The Pennsylvanian-Permian Darwin Basin of            Subduction is independently supported by detailed    graphic horizons record contributions derived
Eastern California records the abrupt onset of       studies of ARM basins which indicate that the slip   from Precambrian basement sources that were
large-magnitude subsidence of the southwestern       on high-angle faults that drove ARM uplift ended     being exhumed during Oligocene–Miocene rifting.
margin of Laurentia. The basin formed in the         at the Pennsylvanian-Permian boundary.                  Mixing models were determined from the Rio
late Pennsylvanian but continuously expanded                                                              Grande rift corridor in southern Colorado and
during the early Permian as subsidence and
extensional faulting allowed calciclastic base-of-   New Mexico State                                     throughout New Mexico and used with detrital
                                                                                                          zircon provenance trends to better understand
slope apron depositional systems to retrograde       University                                           the timing and nature of drainage development.
on to the subsided slope and shelf. Areal expan-                                                          Inputs for mixing models required grouping
sion of the Darwin Basin propagated east and                                                              source areas into three primary provinces that
                                                     PROVENANCE AND SEDIMENT MIXING
southeast through time and is marked by the first                                                         included detritus from (1) late Cenozoic volcanic
                                                     TRENDS OF THE PLIO–PLEISTOCENE
deposition of deep-water facies in areas that had                                                         fields primarily associated with the San Juan
                                                     ANCESTRAL RIO GRANDE FLUVIAL
been carbonate shelves since the Ordovician. A                                                            and Mogollon Datil volcanic fields, (2) recycled
                                                     SYSTEM, RIO GRANDE RIFT, NEW MEXICO
nearly identical stratigraphic and structural evo-                                                        Mesozoic strata (reflecting previously determined
                                                     Parker Ridl, Shay, M.S.
lution is present in the Pennsylvanian-Permian                                                            Mesozoic eolianite provenance signatures); and
of southern California, indicating that the driver                                                        (3) recycled Paleozoic and Precambrian basement
of subsidence in the Darwin Basin was able to        Pliocene–Pleistocene strata that record axial-flu-   that crop out along the Rio Grande rift flanks.
affect a large swath of the southwestern margin      vial sedimentation of the ancestral Rio Grande          The earliest phase of drainage development
of Laurentia at once. Furthermore, subsidence in     fluvial system crop out in New Mexico and            (~5.0–4.5 Ma) in northern New Mexico was
the Pennsylvanian-Permian of California coin-        southern Colorado, and they preserve the history     characterized by elevated detrital contributions
cides with a significant change in deformation       of drainage evolution and late-stage exhumation      from recycled Mesozoic stratigraphy likely
style of Ancestral Rocky Mountains basins and        of the Rio Grande rift. Presented here are new       derived from the Colorado Plateau, whereas
uplifts, suggesting that the driver of subsidence    U-Pb detrital zircon data (N=8 samples; n=2382       basins in central and southern New Mexico were
in California may have affected tectonics across     analyses) from the Camp Rice and Palomas             receiving detritus largely from rift flanks (i.e.,
southwestern Laurentia. Speculative basin            formations collected at two to three stratigraphic   Paleozoic and Precambrian sources) and late
evolution models invoke tectonism associated         intervals in the Socorro, Hatch-Rincon, Jornada      Cenozoic volcanic-field sources. The late Pliocene
with the Late Paleozoic continent-truncating         del Muerto, and Mesilla basins. U-Pb ages were       (3.1–2.6 Ma) phase of drainage development in
California-Coahuila transform fault as the           then integrated with similar, previous studies       northern New Mexico was marked by a relative
principal driver of subsidence in the Darwin         from age-equivalent strata that are exposed in       decrease in detrital contributions from recycled
Basin and southern California. However, the          southern Colorado and northern New Mexico to         Mesozoic strata. The model shows nearly equal
onset of large-magnitude subsidence in southern      develop sedimentary mixing models for the entire     detrital contributions from recycled Mesozoic
and eastern California is spatially and tempo-       Rio Grande rift corridor in this region.             strata, rift flank, and volcanic field sources at the
rally associated with the first appearance of           New U-Pb detrital zircon data from the central    3.1–2.6 Ma stratigraphic horizon in central and
magmatism and volcaniclastic sedimentation in        and southern portion of the Rio Grande fluvial       southern New Mexico. The Pleistocene (2.0–1.6
the Late Paleozoic of the southwestern U.S. The      system record peak ages at 34, 167, 519, 1442,       Ma) phase of drainage development records a
geochemistry of these early to middle Permian        and 1686 Ma, suggesting that the ancestral Rio       shift in provenance in the southern rift basins
igneous rocks, which include plutons and lavas       Grande was receiving detritus from late Ceno-        and models suggest decreased contributions
in southern California and newly identified tuffs    zoic volcanic fields (e.g., San Juan and Mogollon    from late Cenozoic volcanic field and rift flank
in eastern California, demonstrates that these       Datil volcanic fields), recycled Mesozoic stra-      sources, and increased contributions from recy-
rocks formed in a continental subduction zone.       tigraphy (Mesozoic eolianites), and Proterozoic      cled Mesozoic stratigraphy.
The presence of continental arc-derived igneous      basement provinces (e.g., A-Type granitoids and         Provenance data and mixing trends that
rocks in the early Permian of California is inter-   the Mazatzal and Yavapai provinces). Although        demonstrate increased detrital contributions
preted to indicate that the onset of Cordilleran     peak ages across the southern Rio Grande rift        from recycled Mesozoic strata of the Colorado
Subduction occurred earlier than has previously      are similar across all basins and stratigraphic      Plateau support a model of headward erosion
been recognized.                                     horizons in this study, there are distinct spatial   of the Rio Puerco into the Jemez Lineament and
   We present 15 new measured sections, facies       and temporal, up-section changes in provenance       southwestern margin of the Colorado Plateau
analysis, clast and point counts, and new cono-      recorded across the southern Rio Grande fluvial      during the Plio–Pleistocene. Headward erosion
dont biostratigraphy that document the Pennsyl-      system in central and southern New Mexico.           and possibly minor exhumation along the west-
vanian-Permian evolution of the Darwin Basin.        Basal strata (~5.0–4.5 Ma) record the largest        ern margin of the rift resulted in increased detrital
We also report on whole-rock geochemistry and        contributions of detritus derived from the San       contributions from the oldest and deepest parts
XRD analysis of five previously unknown tuffs        Juan and Mogollon Datil volcanic fields (34–29       of caldera sources between the Pliocene and late
identified in the Darwin Basin. We propose that      Ma) and lesser occurrences of recycled Cordille-     Pliocene. These same caldera source areas were
subsidence in the Darwin Basin and southern          ran arc zircons derived from recycled Mesozoic       less of a source for the system by the Pleistocene.
California was caused by extension and dynamic       stratigraphy from the Colorado Plateau. The
topography above the incipient Cordilleran Sub-      late Pliocene phase (3.1–2.6 Ma) marks similar       ERUPTIVE VOLUME AND EXPLOSION
duction Zone. We further suggest that the first      contributions of detritus derived from late Ceno-    ENERGY ESTIMATES FROM KILBOURNE
appearance of this subsidence dates the onset of     zoic volcanic fields and marks the emergence of      HOLE MAAR, SOUTH-CENTRAL
subduction, which appears to have begun shortly      peaks that overlap with recycled Cordilleran arc     NEW MEXICO
before the Pennsylvanian-Permian boundary. Arc       sources (217–82 Ma). Pleistocene (2.0–1.6 Ma)        Vitarelli, Daniela C., M.S
magmatism may have begun as early as 290 Ma,         stratigraphic horizons show a relative decrease
but was likely low-volume and confined to small      of zircons that overlap in age with the San Juan
portions of the southwestern plate margin during     and Mogollon Datil volcanic field sources and an     Maar-diatremes are a common type of mono-
the Permian, as is the case for the nascent Neo-     increase in contributions of recycled Cordilleran    genetic volcano defined by ascending magma

Spring 2021, Volume 43, Number 1                                            12                                                        New Mexico Geology
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