Slug Injection Using Salt in Solution
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Volume 8 Number 2 Spring 2005 Introduction to Salt Dilution Gauging for Streamflow Measurement Part III: cloud will cause EC to increase from its background value to a peak value, Slug Injection Using Salt in corresponding to the passage of the core of the cloud, followed by a Solution decline to background EC as the trailing edge of the cloud passes, resulting in a characteristic salt wave R.D. (Dan) Moore (Figure 2). Longitudinal dispersion reduces the peak EC of the salt wave as it travels downstream. The time Introduction Conceptual Basis required for the peak of the wave to P revious Streamline articles introduced the general principles of stream gauging by salt dilution In this approach, a volume of salt solution, V (m³), is injected as a move past an observation point will depend inversely on the mean near-instantaneous slug or gulp at one velocity of the streamflow, while the (Moore 2004a) and the procedure for location in the stream. Following duration of the salt wave will depend constant-rate injection (Moore injection, the salt solution mixes Continued on page 2 2004b). While constant-rate injection rapidly throughout the depth of the is best suited for use in small streams stream and less rapidly across the Inside this issue: at low flows (discharges stream width as it travels less than about 100 L/s downstream with the Introduction to Salt or 0.1 m³/s), slug Slug injection general flow of water. Dilution Gauging for injection can be used to works well in Because some portions of a Streamflow Measurement gauge flows up to 10 stream flow faster than Part III: Slug Injection steep, highly Using Salt in Solution m³/s or greater, others (e.g., flow tends to depending upon turbulent be faster in the centre than streams. An Inexpensive, channel characteristics. near the banks), the cloud Automatic Gravity-fed Slug injection works of salty water “stretches” Water Sampler for well in steep, highly downstream in a process Investigating Water turbulent streams, such as the called longitudinal dispersion. This bouldery mountain channel dispersion results in the cloud having Quality in Small Streams shown in Figure 1. This article a leading edge with relatively low Live Gravel Bar Staking introduces the conceptual concentrations of salt solution, a Channel Stabilization in basis and field procedures central zone of high concentrations, the Lower Elk River for slug injection using followed by a trailing edge of salt in solution. decreasing concentration. A Qualitative Hydro-Geomorphic Risk If the electrical conductivity (EC) is Analysis for British recorded at some point downstream, Columbia’s Interior where the tracer has been completely Watersheds: A Discussion mixed across the stream width, the passage of the salt Paper Re-creating Meandering Streams in the Central Oregon Coast Range, USA Results of Streamline Reader Survey 2004 Update
Continued from page 1 Published by: FORREX–Forest Research Extension Partnership Suite 702, 235 1st Avenue Kamloops, BC V2C 3J4 Project Manager: Robin Pike Tel: (250) 387-5887 Distribution/Mailing List: Janet Jeffery Tel: (250) 371-3923 Technical review committee: R. Scherer, R.D. Moore, R. Pike John Heinonen Technical reviewers this issue: S. Babakaiff, L. Barr, R. Doucet, B. Eaton, T. Giles, B. Grainger, D. Hutchinson, P. Jordan, M. Miles, R.D. Moore, R. Pike, D. Figure 1. Place Creek at high flow during summer glacier melt. Polster, P. Raymond, R. Scherer, M. Schnorbus, K. Swift, P. Teti, R. Winkler on the amount of longitudinal where T represents the salt wave Publication and Web Site Support: dispersion, which, in turn, depends on Jesse Piccin, Satnam Brar, Julie Schooling duration (s). Equation [2] can be how variable the stream velocities are rearranged to solve for Q: Graphic Layout: SigZag Design across the stream. The author has V Editing: Ros Penty found that the time required for the Q= [3] Cover Illustration: William McAusland salt wave to pass typically varies from a couple of minutes (e.g., Figure 2) to ò RC (t)dt McAusland Studios, Kamloops, B.C. over 20 minutes. Under low-flow T Streamline is published twice a year by conditions with low velocities, the In practice, RC(t) is determined at the FORREX. All articles published in duration can be longer than desired downstream measurement point at a Streamline are reviewed to ensure reliable and technically sound information is for accurate measurements (e.g., well discrete time interval Dt (e.g., 1 or 5 extended to our readers. Content over 30 minutes). s), and the integral is usually published in Streamline reflects the approximated as a summation: opinions and conclusions of the At any time (t) during the salt wave ò RC (t)dt @ å RC (t)Dt contributing author(s), not those of passage, the discharge of tracer FORREX, our editorial staff, or our funding [4] partners. Please contact Robin Pike, solution q(t) (L/s or m³/s) past the Streamline Project Manager, for further point will be approximated by: T n guidelines on article submission or with where n is the number of your comments and suggestions. q(t ) = Q × RC (t ) [1] measurements during the passage of This publication is funded in part by the the salt wave. The relative where Q is the stream discharge (L/s British Columbia Ministry of Forests concentration can be determined through the Forest Investment Account, or m³/s) and RC(t) is the relative from EC: Forest Science Program, and by the concentration of tracer solution (L/L) USDA Forest Service. in the flow at time (t). Equation [1] RC (t ) = k[ EC (t ) - ECbg] [5] assumes that q(t) is much smaller than ISSN 1705-5989 Q, which should be true in virtually all where EC(t) is the electrical Printed in Canada cases. If the tracer discharge is conductivity measured at time t, ECbg © FORREX–Forest Research Extension integrated over the duration of the is the background electrical Partnership salt wave, and if the stream discharge conductivity of the stream, and k is a Printed on recycled paper is constant over that time, then the calibration constant. The calibration http://www.forrex.org/streamline following equation should hold for a constant, k, depends primarily on the conservative tracer (i.e., one that does salt concentration in the injection not react with other chemicals in the solution and secondarily on the water, bind to sediment, or otherwise chemical characteristics of the change as it flows downstream): streamwater. Combining Equations [3], [4], and [5], the following V = ò q(t ) dt = Q ò RC (t ) dt [2] practical equation can be derived for computing discharge: T T 2 Streamline Watershed Management Bulletin Vol. 8/No. 2 Spring 2005
V available. In addition, the salt solution is mixed in one container Q= [6] kDt å[ EC (t ) - ECbg] concentrations and durations of exposure normally involved in then decanted into a second, pre-calibrated container (e.g., Østrem n discharge measurement are less than 1964). This procedure ensures that To apply Equation [6], we need to thresholds associated with deleterious the salt in the injection solution is know V, the volume of salt solution effects on organisms (Moore 2004a). completely dissolved, and allows injected; measure the resulting Wood and Dykes (2002) observed accurate measurement of the injection transient increases in invertebrate drift volume. changes in EC at intervals of Dt until during slug injection, but concluded EC returns to background levels; and Required Volumes of Injection that salt injection had a relatively determine the calibration constant, k. Solution short-term effect and is unlikely to Field Procedures have any long-term deleterious The accuracy of a measurement Choice of a Measurement Reach impacts on invertebrate communities depends on how much EC increases at most locations. above background during the salt Successful application of the slug wave passage, relative to the accuracy injection technique requires a stream The salt concentration in the injection of the conductivity probe. The change reach that generates complete lateral solution should be high enough to in EC during the salt wave passage mixing in a short distance. Selected increase EC reasonably when using depends, in turn, on the volume of reaches should have as little pool volumes of solution that can be easily handled, but it also needs to remain salt solution and its concentration, as volume as possible because the slow less than the solubility. Given the low well as the mixing characteristics of exchange of tracer between the pool temperatures often associated with the stream. Those streams with less volume and the flowing portion of the field conditions, the maximum longitudinal dispersion will exhibit a stream will greatly increase the time concentration that will dissolve readily more peaked salt wave with higher required for the salt wave to pass. An is about 20%, or about 1 kg of salt in concentrations, and will require lower ideal reach begins with an injection 5 L of water (Østrem 1964; Kite injection volumes. site upstream of a flow constriction (e.g., where the flow narrows around 1993). We have found that a mixture Kite (1993) suggested that peak EC a boulder, promoting rapid lateral of 1 kg of salt with 6 L of water should be 50% higher than (roughly a 17% solution) provides a background, while Hudson and Fraser 30 suitable (2002) suggested that peak EC should compromise be at least 5 times higher than 25 between strength background. Background EC in B.C. and ease of streams typically ranges from about 20 dilution. 10 mS/cm for stormflow conditions in EC (mS/cm) 15 The injection streams draining catchments solution does not underlain by granitic bedrock, to over 10 need to be mixed 400 mS/cm for low-flow conditions in from local streams sustained by groundwater 5 streamwater. discharge. The author suggests that Where access to increasing EC by 100–200% of 0 0 60 120 180 240 the stream does background should be adequate for Time (s) not involve a long streams with low background EC (less hike, it is often than about 50 mS/cm), while Kite’s Figure 2. Example of salt wave in Place Creek. convenient to (1993) guideline should be reasonable mixing) and contains no pools or pre-mix the for streams with background EC backwater areas below the injection solution to allow generous greater than about 100 mS/cm. constriction. A rough guideline is that time for dissolution and to minimize Table 1 summarizes the the mixing length should be at least time spent at the field site. masses/volumes of injected salt/salt 25 stream widths, but complete Note that the volume of the injection solution used by various authors. The mixing may require much longer or solution will be greater than the range reflects the diversity of channel shorter distances, depending on volume of water used to mix it. We morphologies and discharges stream morphology (Day 1976). have found that when a 1-kg box of encountered in the different studies. Mixing the Injection Solution salt is mixed with 6 L of water, the The author recommends starting with We use NaCl (table salt) as a tracer resulting solution has a volume of 1 L of 15–20% solution per m³/s. because it is inexpensive and readily 6.36 L (±0.01 L). Commonly, the salt Greater volumes of injected salt Continued on page 4 Streamline Watershed Management Bulletin Vol. 8/No. 2 Spring 2005 3
Continued from page 3 placed cobbles) so that it will not detailed description of the procedure solution may be appropriate for wider move during the measurement. To and the calculation of k. streams that require longer mixing position the probe in a strong current, Although ideally the calibration is reaches, while lower volumes may it may be useful to attach the probe performed in the field, particularly to work for narrower streams. To avoid to a rod weighted at the end that is maintain water temperature as close excessive salt concentrations in the placed in the water. to stream temperature as possible, it stream, one or more trial injections In some cases, the background EC can also be conducted in the should be conducted with low may vary. One possible cause is an laboratory. To perform the calibration volumes, working up to larger overly sensitive conductivity meter. off site, two 1-L samples of volumes as required. streamwater should be measured Table 1. Volumes/masses of injected salt used in different studies accurately into sample bottles using a Author Mass of salt Equivalent volume (L) volumetric flask. A sample of the injected per m³/s of 20% salt solution injection solution should also be taken streamflow (kg) (1 kg salt in 5 L water) in a small glass (not plastic) bottle to Østrem (1964) 0.5 2.5 avoid potential problems with salt Church and Kellerhals (1970) 0.2 1 sorbing onto the walls of a plastic Day (1976) 0.3 1.5 bottle. The calibration can then be Elder et al. (1990) 5 25 conducted following the procedure Hudson and Fraser (2002) 2 10 described by Moore (2004b). Figure 2 illustrates a salt wave for Another cause of varying background Summary of Field Place Creek, where the author has EC is incomplete mixing of Procedures found the salt waves to be highly streamwater and groundwater (which Table 2 lists the equipment required. reproducible. Injecting 6.35 L of a typically has higher EC than the Suggested steps for conducting field roughly 17% solution into a flow of streamwater) within and immediately measurements are as follows: 2.66 m³/s produced a peak EC about downstream of groundwater 100% higher than background. discharge zones. Similar problems 1. Mix injection solution (either at with incomplete mixing can occur office or on site). Recording Electrical Conductivity downstream of tributaries. In these 2. Select measurement reach. Ideally, a data logger should be used latter cases, find an observation point to record the passage of the salt wave. where background EC is uniform 3. Use a pipette to extract a known Some conductivity meters have volume of injection solution (e.g., 10 across the channel and constant in built-in data logging, while others can time. mL) and add to the secondary output a signal that can be recorded solution bottle. Cap the bottle and using a separate data logger. If you do Determining k by Calibration store upright. not have data logging capacity, To determine k, a known volume of 4. Record background EC and water record EC manually at 5-s intervals. injection solution (typically 5 or 10 temperature at the downstream end Although this approach may not be as mL) is added to a known volume of of the measurement reach, and accurate as using a data logger and a streamwater (typically 1 L) to produce upstream of the injection point. 1-s recording interval, it can produce a secondary solution. Known satisfactory results. In most cases, two increments of this secondary solution 5. Set up the conductivity probe at people are required to conduct a salt the downstream end of the mixing are then added to a second known dilution measurement with manual reach. Record the background EC and volume of streamwater (typically 1 L), water temperature. If you have a data recording, while the use of a data to generate a set of EC values logger allows a single person to make corresponding to different values of logger, start recording EC. the measurement. relative concentration. The slope of 6. Inject a known volume of salt The conductivity probe should be the relation between relative solution at the upstream end of the placed within the main part of the concentration and EC provides the mixing reach. flow, not in a backwater. Avoid required value for k. This two-step 7. Record the passage of the salt locations with substantial aeration, as procedure dilutes the injection wave, continuing until EC returns to air bubbles passing through the probe solution to the relative concentrations background. If EC does not return to cause spurious drops in conductivity. observed during the salt wave without background, measure EC upstream of The probe should be firmly emplaced using large volumes of streamwater. the injection point again to determine (e.g., by wedging it between carefully See Moore (2004b) for a more whether the background changed. 4 Streamline Watershed Management Bulletin Vol. 8/No. 2 Spring 2005
8. Measure a volume V0 (e.g., 1 L) of streamwater using the volumetric flask Worked Example and pour into the secondary solution Figure 2 shows a salt wave recorded during a slug-injection measurement bottle, which already contains the at Place Creek, located about 30 km northeast of Pemberton, B.C. Place sample of injection solution. Cap the Creek, a steep, bouldery mountain stream, would be impossible to gauge bottle and shake vigorously to mix the accurately using a current meter (Figure 1). The volume of injection streamwater and injection solution. solution was 6.35 L. This volume resulted from mixing 1 kg of salt with 6 L This mixture is the secondary solution. of water (to produce 6.36 L of solution), followed by extracting 10 mL 9. Measure a volume Vc (e.g., 1 L) of (0.01 L) of injection solution for use in the calibration procedure. The streamwater using the volumetric flask stream EC data were logged at 1-s intervals, and the calibration constant and pour into the calibration tank. was 2.99·10–6 cm/mS. Immerse the calibration tank in a V 6.35 ×10 -3 m 3 shallow pool at the stream’s edge. Q= = -6 = 2.66 m 3 /s k Dt S[ EC(t) - EC bg ] ( 2.99 ×10 cm/mS)(1 s)(797mS/cm) Keep the temperature in the tank as close to stream temperature as possible (Moore 2004b). To where the salt plasticware into the field as a backup help hold the calibration tank in Under suitable wave is recorded. in case of breakage. place, position a “corral” of In addition, cobbles around it. conditions, discharge should If it is raining during the streamflow measurement, ensure that the 10. Perform the calibration and not change measurements calibration tank is sheltered. determine k using the appreciably Otherwise, rain falling into the tank procedure described by Moore made by slug during the may dilute the concentrations below (2004b), then compute the injection can be injection trial. the calculated values, producing discharge using Equation [6]. precise to within Errors may arise biased calibrations. Errors and Limitations about ±5%. through The slug injection method may not be inaccuracies in Under suitable conditions, appropriate when the channel measuring the streamflow measurements contains ice and (or) snow. In such volumes of made by slug injection can be precise streamwater, injection solution, and cases, low velocities may result in to within about ±5% (Day 1976). poor lateral mixing and excessively secondary solution. These errors can Accurate measurements require that long salt wave durations, particularly if be effectively minimized if a (1) the salt in the injection solution be volumetric flask is used to measure salt solution flows into slush zones completely dissolved, and (2) the within the measurement reach. streamwater and glass pipettes used injection solution be fully mixed to measure the injection and The method will be subject to across the channel at the location secondary solutions. However, take substantial errors if the measurement Continued on page 6 Table 2. Equipment list for field measurement of streamflow using slug injection of salt Item Purpose 1-L volumetric flask Measuring streamwater 1-L plastic graduated cylinder Backup in case volumetric flask breaks Plastic measuring cup with handle Pouring streamwater into volumetric flask Squirt bottle Topping up streamwater in volumetric flask 1,2 5- and 10-mL pipettes Measuring injection solution to mix secondary solution Pipette filler (rubber squeeze bulb) Drawing water into pipettes 1- or 2-L wide-mouth Nalgene water bottle Mixing the secondary solution 1- or 2-L Nalgene beaker or pail Calibration tank 2-, 5-, and 10-mL pipettes1,2 Measuring secondary solution Plexiglas rod or tubing, 30 cm long Stir stick for calibration tank Conductivity probe and meter Measuring EC during salt wave passage and for calibration Data logger (desirable but optional) Recording EC during salt wave passage 1 Separate sets of pipettes need to be used for measuring the injection and secondary solutions. 2 Spare pipettes should be carried in case of breakage in the field. In addition, 10-mL plastic graduated cylinders or graduated pipettes could be carried as backups Streamline Watershed Management Bulletin Vol. 8/No. 2 Spring 2005 5
Continued from page 5 reach is not sufficiently long to ensure higher flows (e.g., >5–10 m³/s), it is For further information, contact: complete lateral mixing. Unlike easier to inject dry salt than to mix Dan Moore, Ph.D., P.Geo. constant-rate injection, where lateral and inject adequate volumes of Associate Professor mixing can be verified once solution. However, a disadvantage of Departments of Geography and Forest steady-state conditions have been the dry salt method is that an Resources Management achieved, assessing mixing is more accurate scale to measure the mass of difficult with slug injection. If two salt or an adequate supply of 1984 West Mall University of British Columbia probes are available, then the salt pre-weighed salt in a range of Vancouver, BC V6T 1Z2 wave can be recorded at two quantities is needed. Where an downstream distances or on either Tel: (604) 822-3538 accurate scale and pre-weighed side of the stream. If mixing is E-mail: rdmoore@geog.ubc.ca quantities of salt are unavailable (e.g., complete, discharge calculated from at a remote site over an extended field References both probes should be in reasonable season), the slug injection method agreement. If this is not the case, a using salt solution would still be Church, M. and R. Kellerhals. 1970. Stream longer mixing reach is required. possible because the precise mass of gauging techniques for remote areas Alternatively, if only one probe is using portable equipment. Department salt in the injection solution does not of Energy, Mines and Resources Inland available, successive measurements need to be known, just the volume of Waters Branch, Ottawa, Canada. can be made during periods of steady the solution (Equation [6]). Technical Bulletin No. 25. flow using different distances. Day, T.J. 1976. On the precision of salt dilution gauging. Journal of Hydrology Problems can occur if the conductivity Summary 31:293–306. does not return to background. If the Streamflow measurement by slug Elder, K., R. Kattelmann, and R. Ferguson. measurements taken upstream show injection of salt solution has been 1990. Refinements in dilution gauging for mountain streams. In Hydrology in that the background has truly successfully applied in many locations Mountainous Regions. I - Hydrological changed, then an average of the around the world. It is particularly Measurements; the Water Cycle. original and final background values suitable for steep, bouldery mountain International Association for may be used in Equation [6]. It is streams, which are unsuitable for Hydrological Science (Proceedings of more problematic if EC has not two Lausanne symposia, August 1990). gauging by conventional current IAHS Publication No. 193, pp. returned to background due to a slow metering techniques. This article has 247–254. release of stored salt solution within described procedures that the author Hongve, D. 1987. A revised procedure for the mixing reach, as can occur in has found useful at sites throughout discharge measurements by means of reaches with pools, particularly at British Columbia. However, there is the salt dilution method. Hydrological lower flows. In such cases, one Processes 1:267–270. great scope to vary the details to suit Hudson, R. and J. Fraser. 2002. Alternative solution would be to extend the tail of individual circumstances and users are methods of flow rating in small coastal the salt wave by fitting an exponential encouraged to experiment with the streams. B.C. Ministry of Forests, decline to the values, although the outlined procedure. Vancouver Forest Region. Extension actual form of the decline will still be Note EN-014 Hydrology. 11 p. uncertain (Elder et al. 1990). Ideally, Kite, G. 1993. Computerized streamflow Acknowledgements measurement using slug injection. one should find a reach with minimal Hydrological Processes 7:227–233. George Richards helped me storage. Moore, R.D. 2004a. Introduction to salt experiment with variations on the slug dilution gauging for streamflow injection method while working at Injection of Salt in Solution Place Creek. Tim Giles, Dave measurement: Part 1. Streamline Watershed Management Bulletin Versus Injection of Dry Salt: Hutchinson, Scott Babakaiff, and John 7(4):20–23. A Comparison Heinonen helped refine the methods Moore, R.D. 2004b. Introduction to salt A number of authors have advocated by asking valuable questions and dilution gauging for streamflow measurement Part II: Constant-rate the use of dry salt injection as an bringing relevant articles to my injection. Streamline Watershed alternative to injection of salt in attention. Comments on earlier Management Bulletin 8(1):11–15. solution (Hongve 1987; Elder et al. versions of this article by John Østrem, G. 1964. A method of measuring 1990; Kite 1993; Hudson and Fraser Heinonen, Russell White, Michael water discharge in turbulent streams. Church, Robin Pike, and four Geographical Bulletin 21:21–43. 2002). A future Streamline article will Wood, P.J. and A.P. Dykes. 2002. The use focus on streamflow measurement by anonymous reviewers helped improve of salt dilution gauging techniques: dry salt injection. The key advantage its clarity. However, any errors remain ecological considerations and insights. of the method is that, for gauging my sole responsibility. Water Research 36:3054–3062. 6 Streamline Watershed Management Bulletin Vol. 8/No. 2 Spring 2005
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