Practical work using low-level radioactive materials available to the public
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The inspiration of Marie Curie Practical work using low-level radioactive materials available to the public Ralph Whitcher ABSTRACT These notes describe six practical activities for supplementing standard practical work in radioactivity. They are based on a series of workshops given at ASE regional and national conferences by the ASE’s Safeguards in Science Committee. The activities, which demonstrate aspects of radioactivity, feature consumer items that happen to be radioactive at a low level. It is an opportunity to show that radioactivity is in some materials we can all encounter in our lives; low- level radioactivity is not something special or alien. These notes are based on a series of workshops are generally available to the public and present given at Association for Science Education negligible risk if used with straightforward safety (ASE) regional and national conferences by precautions. However, if the items are misused the ASE’s Safeguards in Science Committee to or damaged, it could lead to an unjustified demonstrate practical work that can help with exposure. For those teachers looking to extend teaching aspects of radioactivity. The low-level demonstrations or investigations beyond the radioactive items described in these notes practical work described here, there are some are currently conditionally exempt from the radioactive consumer items that are probably Environmental Permitting (England and Wales) best avoided because radioactive material Regulations 2010 and from the Radioactive could be easily released, even though in small Substances Act 1993 in Scotland and Northern quantities, for example some types of old Ireland. Thus buying and disposing of them thermionic valve and some types of compact does not require permitting (or registration and fluorescent lamp. authorisation in Scotland and Northern Ireland) The overall risk of detriment to human health by the regulatory authority for the environment. from exposure to ionising radiation is assessed However, their use does fall under the Ionising using a quantity called effective dose, expressed Radiations Regulations 1999 and, although the in the unit sievert (Sv). The quantity takes into risks are low, employers usually require you to account the relative biological effects of different obtain their permission before you acquire new types of ionising radiation and the susceptibility radioactive sources. Employers will also require of different parts of the body to radiation damage. you to follow suitable risk assessments, such as As an example of this quantity, people in the UK CLEAPSS L93 (2008), or, in Scotland, those receive an average annual effective dose from available through the Scottish Schools Equipment background radiation of 2.2 mSv. The unit is Research Centre (SSERC). Additional safety named after Rolf Sievert, a Swedish scientist and notes are included in this article. a leading pioneer in radiation protection. While teachers are usually aware that smoke Another radiological quantity is equivalent detectors and radioluminescent watches have dose. This relates to radiation damage to an organ radioactive components, there are other low-level or tissue where the relative biological effects radioactive consumer items that are useful in of different types of ionising radiation have demonstrating aspects of radioactivity. The been taken into account. This is also expressed items featured in the following practical work in sieverts. As an example of this quantity, the SSR June 2011, 92(341) 65
Practical work using low-level radioactive materials available to the public Whitcher current legal limit of the annual equivalent dose of mantle are not dispersed. The mantle does not to the lens of the eye for an adult employee is need to be taken out of the bag for use in this 150 mSv. Both effective dose and equivalent dose application. Do not use burnt mantles because are used in setting regulatory control limits. they crumble into fine ash very easily. Set a Geiger–Müller (GM) tube so that the end 1. Demonstrating randomness of window is uppermost and place the gas mantle radioactive emissions using a thoriated in the bag directly on the end (Figure 2). Record gas mantle the count rate at regular intervals. This can be This activity demonstrates the random nature of done by recording the counts every 10 seconds radioactive decay. A large variation in count rate and calculating the count rate over 10 seconds or, can be shown clearly using a low-level radioactive even better, by using a datalogger to measure and source such as a gas mantle. record the count rate at suitable short intervals. Butane and paraffin camping lamps have gas Real-time datalogging gives an immediate mantles that glow brightly when heated by the visual indication of the randomness, as shown in burning fuel. Some brands of gas mantle, such Figure 3. as the Tilley 164X gas mantle (Figure 1), include The variation can be surprising. In the a small quantity of thorium oxide because it example shown here, 180 measurements were gives a brilliant white light when hot. Although taken by logging the count rate at 1 second thorium is radioactive, it has a low radiological intervals, and the range went from 9 counts s−1 to risk because it has a relatively low specific 37 counts s−1. activity. Thoriated gas mantles can be purchased More advanced work for under £2 each from hardware and camping Calculate the mean and the standard deviation and equipment stores. This ready availability for see how the standard deviation compares with public use implies that the risk is not high but the square root of the mean. The data can also be there is a small risk from inhalation or ingestion grouped and the frequencies of each group shown of gas mantle fragments, so keep the gas mantle on a chart, using a spreadsheet (Figure 4). in a sealable plastic bag to ensure that fragments The data distribution can be modelled as a Poisson distribution. The predicted value of the standard deviation is the square root of the mean. If the mean value is large, say more than 20, the distribution can be approximated to the normal (or Gaussian) distribution, which predicts that 99.7% of the data should fall within ± 3 standard deviations from the mean. Figure 1 A Tilley type 164X gas mantle in a sealed plastic bag; some other brands contain yttrium instead of thorium and are not radioactive Figure 2 The setup of the GM tube and counter 66 SSR June 2011, 92(341)
Whitcher Practical work using low-level radioactive materials available to the public Figure 3 The count rate shown by datalogging Frequency 20 16 12 8 4 0 0 5 10 15 20 25 30 35 40 Count rate/s –1 Figure 4 The distribution of count rates Table 1 Statistics from the data in Figure 4 Mean Maximum Minimum Standard Square root Mean + 3 × square Mean − 3 × square deviation of the mean root of the mean root of the mean 22.43 37 9 4.95 4.74 36.6 8.2 Table 1 relates to the data displayed in the This gives a rule of thumb to check whether frequency chart and shows how well this model a higher than expected count reading is no more works for large numbers of data. The predicted than randomness. Take the square root of the range based on the mean is 8.2–36.6, which fits expected (mean) value, multiply it by three and well with the measured range of 9–37. this gives the likely range about the mean due to SSR June 2011, 92(341) 67
Practical work using low-level radioactive materials available to the public Whitcher randomness. For example, say the background Figure 5 shows the α particle tracks; they appear count rate for a particular contamination monitor at a rate of about one or two every second. The α was well established as 36 counts per minute. tracks vary in length, up to a maximum length of If you were checking a surface and measured around 4 cm, because some α emissions come from 50 counts per minute with this monitor, is there just within the electrode surface and lose energy likely to be contamination? The expected range before emerging. Occasionally, a V-shaped emission is ± 18, so 50 counts per minute would be within appears from the rod surface. This is caused by the range due to randomness and not necessarily the decay by α emission of 220Rn (a product in the a sign of contamination, and another count would decay chain of 232Th) followed almost immediately be advisable. by the decay by α emission of 210Po. 2. An alternative source for the diffusion More advanced work (or Taylor) cloud chamber α particles are much more massive than electrons; for a particular velocity, α particles have much Diffusion cloud chambers are easy to use and have greater momentum than β particles and are great educational benefit in allowing students to deflected less on collision. α particles tend to observe directly the tracks of radioactive particles travel in straight lines through air except for as they are emitted. The diffusion cloud chambers occasional collisions with nuclei of atoms (which sold by school science equipment suppliers in the produce observable deflections, as in the α particle 1960s and 1970s used small radium paint sources track in the middle of Figure 6). of nominal activity about 1 kBq. These sources Low-energy β emissions produce tortuous are no longer available and suitable new sources tracks compared with α emissions because they are in the UK are not easy to obtain. Fortunately, deflected more readily by collisions. The tracks from a thoriated tungsten electrode can be used as a β radiation can be observed in the cloud chamber cloud chamber source. These are designed for but they are much fainter because β radiation is TIG (tungsten inert gas) welding fabrication and far less ionising than α radiation. A way to identify are commonly available from welding supplies β tracks is to take a number of photographs at shops. The type used in the test experiments was 1 second intervals with a digital camera and flash, an SWP brand 2% thoriated tungsten electrode, say 20 or so, and then download the images to a type WT20, with rod diameter 3.2 mm and length computer. Zoom in on the photographs and you 150 mm, conforming to ISO 6848 (see Websites). may be able to pick out some images that show β There are also 4% thoriated tungsten electrodes, radiation tracks. The contrast may be better if the but these are uncommon. The price of an electrode pictures are converted to greyscale. is about £3. The 2% thorium electrode has an identifying red colour tip. The electrode is put through the cloud chamber and corks/bungs placed firmly on each end to keep it in place. If you are modifying a cloud chamber for this source, holes drilled in the sides should be set so that the electrode centre is about 7 mm above the chamber floor. Put dry ice pieces in the lower chamber and replace the bottom lid. Dampen the felt inside the upper chamber with a few cubic centimetres of ethanol. Replace the lid and rub it clean with a soft duster. Within a few minutes you should see tracks. These are caused by condensation of ethanol. The low temperature in the chamber causes the ethanol vapour to become supersaturated and, in the absence of dust, the ions produced by the ionising radiation act as nucleation sites on which condensation forms. Figure 5 A thoriated tungsten WT20 electrode used as a source in a diffusion cloud chamber 68 SSR June 2011, 92(341)
Whitcher Practical work using low-level radioactive materials available to the public which happens when using the electrode as a cloud chamber source.) There are many welding accessory outlets and a search using the internet should find one in your area. When you purchase electrodes, check that they are type WT20 with the thorium sintered homogeneously in the tungsten and conforming to ISO 6848. Where permitted, it would be justifiable for responsible students under 16 to use the cloud chambers with this source fitted because the activity is low and the radiation risk is negligible. This activity was first explained by the author on the Practical Physics website (see Websites). 3. Using a uranium-glazed saucer or small plate to demonstrate β backscatter This demonstration uses a saucer (or small plate) manufactured by the Homer Laughlin China Co. It is the red/orange type from the Fiesta-ware Figure 6 The irregular track of a suspected low- range manufactured from 1936 to 1973 (not energy β emission, indicated by the upper arrow; the continuously) that contained uranium in the glaze. lower arrow indicates a deflection of an α emission; The Fiesta-ware emits β radiation from the the photograph has been digitally converted to 238 U decay chain. Little of the α radiation escapes greyscale and the contrast and brightness enhanced the surface glaze, and the γ emission from Fiesta- ware is low compared with the β emission, which Additional notes makes it suitable for this demonstration. The plate Diffusion cloud chambers normally work reliably or saucer should be retained in a sealable plastic if they are kept clean, so it is a good idea to bag so that if it breaks the fragments are retained; store the chambers in sealed bags between use. this demonstration works satisfactorily with the If they are allowed to become dusty they can saucer in the plastic bag. be very difficult to get working. Before storing Use an end-window GM tube such as the the chamber, allow the ethanol to evaporate ZP1481 (MX168) GM tube commonly used in completely to prevent the plastic crazing over time. schools connected to a counter or ratemeter. Place To store electrodes, they can be removed the GM tube on the bench so that the GM tube from the cloud chambers and kept with other window is pointing upwards. It works better if radioactive sources in a secure store. The you remove the spider-web protective cap, but be electrodes are usually supplied in a handy plastic careful as the GM tube window is easily damaged. storage case. Place the saucer flat on the bench (in its bag) next The equivalent dose rate to the hand when to the GM tube. Take a count for 30 seconds, holding the electrode is very low, no more than a or note the count rate. It will be a little above few microsieverts per hour, and the dose received background. The β radiation does not enter the during its use as a cloud chamber source will detector window. Although the GM tube detects be insignificant. In standard WT20 type TIG photons principally through its tube wall, the electrodes, thorium is evenly dispersed throughout efficiency is quite low, typically a few percent. the rod. During manufacture, tungsten and Place a large sheet of aluminium about 5 cm thorium oxide powder are sintered into a metal above the GM tube (Figure 7). A home-made alloy rod and the thorium is firmly bound in the wooden holder is useful to do this. The aluminium metal. It is almost inconceivable that thorium sheet should be large enough (approximately could become released from the electrode, even 150 × 300 mm) so that its footprint covers the if it were roughly handled. (Thorium is released saucer and GM tube. The count rate will rise in small quantities when grinding the electrode, noticeably. Replace the aluminium sheet with a or to a lesser extent during welding, neither of lead one (a piece of code 4 lead roof flashing from SSR June 2011, 92(341) 69
Practical work using low-level radioactive materials available to the public Whitcher 4. Detecting radon in a building using a charged rubber balloon and showing radioactive decay This experiment was explained by Austen and Brouwer (1997). It can be used to show how the air has naturally low levels of radioactive material in it, and that this decays over time. It is also a demonstration that our environment has low levels of radioactivity to which we are exposed continuously. Inflate a rubber balloon, clamp the neck with Figure 7 The setup of the GM tube and uranium- something like a freezer bag resealing clip, attach glazed saucer a piece of string and suspend it somewhere in the room. It does not have to be high up, but you tend a local builder is suitable) in the same position. to get better results if the balloon is hung in a place The count rate rises even further. You can show away from draughts. Rub the balloon vigorously that it is not the lead or the aluminium that is for a few moments with woollen gloves until the radioactive by moving the saucer away. balloon is friction charged. Leave the balloon for β backscatter from the sheet causes the about 30 minutes (although if you are really keen detection rate to rise. The saucer is such a wide- to see the results, 15 minutes may be sufficient). area source that there is plenty of scatter that gets Set up a counter with the GM tube upright. to the GM tube window –no careful setting up Take a piece of rigid plastic, as in Figure 8, or is needed. The scatter depends on the superficial card about 100 mm square with a 25 mm hole in density of the sheet, so it is a good way of showing the centre, and place it so that the hole is about a method for non-destructive testing of material 10 mm above the GM tube window. Take care as thickness. You can extend the investigation by the GM tube end-window is fragile and easily trying various materials for the sheet and various broken by carelessness. Take the background thicknesses of the same material, and by changing count for 1 minute. Put on a pair of disposable the height of the sheet above the GM tube. gloves (this is not for radiological protection; see additional notes below) and take down the Additional notes balloon. Deflate it by removing the clip, and put it Saucers and small plates can be obtained from across the hole in the plastic sheet as in Figure 9. chinaware antique dealers, including those on eBay. Avoid the balloon sagging and touching the GM The modern orange colours do not use uranium. tube. Remove and discard your gloves into the When uranium is extracted chemically, it contains equal activities of 238U and 234U, with a small percentage of 235U (the percentage of 235U is even lower in depleted uranium, which was used by Homer Laughlin from 1959 onwards). The β radiation comes principally from 234Th and 234mPa in the 238U decay chain. The 238U decay chain pretty much comes to a stop after 234U because there are two successive radionuclides with long half-lives. On measurements taken from a saucer by the author, the equivalent dose rate to the hand from the β and γ radiation was roughly 30 µSv h−1. The information in a report from the U.S. Nuclear Regulatory Commission (2001) indicates that the dose rate measurements vary, with an equivalent dose rate as high as 320 µSv h−1 being measured from the surface of a tea cup. However, handling this chinaware for less than a minute will only give a trivial dose to the hand. Figure 8 The setup for counting from the balloon 70 SSR June 2011, 92(341)
Whitcher Practical work using low-level radioactive materials available to the public If you record the count over 1 minute at 20 minute intervals without disturbing the balloon and GM tube equipment, you should obtain a decreasing count rate. The initial decay is roughly exponential. The initial decay curve, mainly from the decay of 214Pb and 214Bi, gives an average ‘half-life’ of about 50 minutes. If there is sufficient activity on the balloon such that there is a measurable count rate from it after 24 hours, the decay of the 220Rn progeny 212Pb and 212Bi predominate to give an average half-life of about 11 hours. When you have finished, discard the balloon in the waste bin, wipe down the plastic and then Figure 9 Counting emissions from the balloon wash your hands. More advanced work waste bin. Take a count for 1 minute to find the Using Excel’s ‘Add Trendline’ facility and average count rate over the minute. The result can choosing the exponential trendline option, the be quite astonishing. If time allows, take 1 minute exponential equation of best fit can be displayed counts about every 20 minutes and plot the on the graph (Figure 10). The half-life can be average count rate against time on a graph. determined from the exponent of base e, in this The cause of the radioactive contamination of case −0.0119. The half-life is ln(2)/−0.0119, the balloon which is 58.2 minutes in this example. The radioactivity arises from the decay products Additional notes of radon. Radon comes from the decay chains of The gloves are principally to stop nuisance naturally occurring uranium and thorium in the contamination from the balloon onto the GM tube environment. Measurements by Austen and Brouwer and counter. If you do contaminate the equipment revealed that most of the radioactivity was due to with low levels of radon progeny and someone 214 Pb and 214Bi, both 222Rn progeny, and from 212Pb, else uses the equipment soon after, they are likely one of the progeny of 220Rn. 214Pb has a half-life of to obtain erroneous results that can adversely 26.8 minutes, 214Bi 19.7 minutes and 212Pb 10.6 hours. affect their investigations or cause false alarm. Figure 10 Graph of the decay of the contamination on the balloon SSR June 2011, 92(341) 71
Practical work using low-level radioactive materials available to the public Whitcher This experiment is an opportunity to introduce some of which can also appear brownish – the a sense of proportion to the risks from low-level indicative tea-coloured tint only shows when radioactivity. If you had a party at home, would looking through the lens. you ask the people clearing away the party The lens is mounted in a holder with the radio balloons to wear disposable gloves? Of course not! active lens element facing the GM tube (Figure 12). Place a plate holder between the lens and the GM 5. Using a thoriated lens as a source to tube. Plates of material such as aluminium of investigate emissions by absorption varying thickness (‘absorbers’) are placed between Thorium was added to some camera lens elements the lens and the GM tube. Measure the counts to give a high refractive index, For example, per minute detected by the GM tube for varying versions of the Yashinon-DS 50 mm f1.7, Canon thickness or superficial density of plates. FL 58 mm f1.2 and Pentax Super-Takumar A piece of paper placed between the lens and 50 mm f1.4 lenses. Such lenses have long been GM tube has a small effect on the count rate, discontinued but they can be obtained from second- showing that the α radiation emission is small. hand camera dealers and eBay. The rear element of Aluminium plates have a greater impact on the Pentax Super-Takumar 50 mm f1.4 (Figure 11) count rate, showing that there is a considerable β is radioactive and can be used as a source to radiation field from the lens. Suitably thick plates investigate the emissions by placing plates of of aluminium will block all β radiation, but the varying thickness between the source and detector. GM tube will continue to detect the γ radiation A thoriated lens can generally be identified from the lens. A typical graph of count rate versus by looking through the lens (but keeping it away plate superficial density (milligrams per square from your eye) at white paper, which will appear centimetre of plate) is shown in Figure 13. to have a slight tea-coloured tint. This is caused From these results, an aluminium plate of by a gradual darkening of the glass from the roughly 800 mg cm−2 stopped the β field. This self-irradiation of the lens. Ionising radiation would correspond to a maximum β energy of displaces some electrons in the glass, forming about 2.0 MeV. (In fact, the most energetic β in the defect sites that affect the absorption of light and 232 Th decay chain is 2.25 MeV from 212Bi.) cause darkening within the glass (Speit, 1998). Thick lead stops β radiation but does not stop Be careful not to confuse this with lens coatings, the detection completely when placed between the lens and GM tube, showing the penetrating characteristics of the γ radiation from the lens. The emission of α radiation can be demonstrated with a spark counter (Figure 14). The spark counter detects only the α emissions at the surface of the glass lens that escape the glass. A two-dimensional Figure 11 The thoriated rear lens element of the Pentax Super-Takumar lens M42 screw-mount f1.4 Figure 12 The setup for placing absorbers in front 50 mm type II, manufactured between 1965 and 1971 of the thoriated lens 72 SSR June 2011, 92(341)
Whitcher Practical work using low-level radioactive materials available to the public Count rate/min Ð1 the lens for a minute gives a trivial dose to the hand. This measurement accords with the information 3000 in the report from the U.S. Nuclear Regulatory Commission (2001). Do not bring the lens up to the 2500 eye, for example to use it as a magnifying glass, because the eye is more susceptible to harm from 2000 radioactive exposure than the hand. 1500 6. Measuring the distribution of times between emissions 1000 The distribution of times between emissions can be determined using a low-level radioactive source 500 such as a gas mantle. The result is surprising to many because it is not intuitive. People generally 0 expect some kind of bell distribution centred on a 0 500 1000 1500 2000 mean time between emissions. Superficial density/mg cm Ð2 Keep the gas mantle in a sealable plastic bag so that fragments of mantle are not dispersed. The Figure 13 Graph of the count rate with absorbers of mantle does not need to be taken out of the bag for differing superficial density use in this experiment. The equipment is set up in a similar way Count rate/min Ð1 to that measuring randomness. However, the 3000 practical demonstration needs a datalogger with a function for measuring time between successive 2500 pulses, such as those from a slotted barrier going through a light gate. The time between successive 2000 pulses from a GM tube can be very short, less than 1 ms, and the datalogger needs to capture 1500 these. The Data Harvest EasySense datalogger has a switched input for recording times between 1000 successive closures of the input. However, it is not a good idea to connect the pulse output of the 500 GM counter directly to the datalogger switched input, as the input could be damaged in some 0 circumstances. The switched inputs can be open Figure014 Thoriated lens 1000 on a spark1500 counter, 2000 and closed safely using a photoswitch such as a 500 showing α emissions Panasonic (Matsushita) PhotoMOS relay. Ð2 Superficial density/mg cm Some GM counters have a pulse output; the three considered here are the Philip Harris spark counter is better than a single-wire version Digicounter (B8H29280), the Unilab GeigerTeller for this demonstration. The detection was roughly (F4H29371) and the Unilab modular GM EHT 1 spark per second. Placing a sheet of paper unit (411.010; no longer available). between the lens and detector wires stops the sparks A PhotoMOS relay AQV251 connected to and confirms that the α emissions are from the lens. the pulse output from the Digicounter worked Additional notes satisfactorily, and you can use the loudspeaker The thorium is bonded in the glass so the release output. Connect a 1 kΩ resistor in series with the of any significant thorium dust will be unlikely. PhotoMOS input (Figures 15 and 16). Nonetheless, caution is needed to avoid breaking The pulse output from the Unilab GeigerTeller the lens. In storage, keep the rear lens caps on until and the Unilab modular GM EHT unit is about needed for use. In measurements carried out by the 100 µs, which is too short to switch the standard author on a Pentax lens, the equivalent dose rate at type of PhotoMOS relay. The circuit shown in the lens surface was roughly 15 µSv h−1, so handling Figure 17 uses a faster PhotoMOS relay, AQV259, SSR June 2011, 92(341) 73
Practical work using low-level radioactive materials available to the public Whitcher and a speed-up circuit. This worked reliably expected, and the relationship between the mean (Figure 18). The transistor type is not critical – and standard deviation is interesting. any high-gain general-purpose small-signal npn Using EasySense software version 2.2 and transistor will work. connecting to the EasySense switch input labelled The switched output in the PhotoMOS relay is ‘5A’, select ‘Timing’ (the ‘Time’ radio button will connected to the switch sensor of the datalogger then appear selected) and then choose ‘From A to and the times between successive switch opening A (stopwatch)’. and closing are recorded. The recorded data can then be copied to an Excel spreadsheet, grouped into time intervals and displayed as a frequency chart. The distribution is not what might be Figure 17 Circuit diagram for the outputs from the Figure 15 Circuit diagram for the Digicounter output GeigerTeller and Unilab modular units Figure 16 The setup with the Digicounter and Figure 18 Using a fast solid-state relay with the datalogger Unilab GeigerTeller References Austen, D. and Brouwer, W. (1997) Radioactive balloons: radiological assessment of exemptions for source and experiments on radon concentration in schools or homes. byproduct materials. NUREG 1717. Washington, DC: U.S. Physics Education, 32, 97–100. Nuclear Regulatory Commission [www.nrc.gov/reading- Speit, B. (1998). Special glasses for nuclear technologies. rm/doc-collections/nuregs/staff/sr1717/nureg-1717.pdf]. In The properties of optical glass (Schott series on glass Websites and glass ceramics), ed. Bach H. and Neuroth, N. pp. 343–348. Berlin: Springer. Practical Physics: www.practicalphysics.org. U.S. Nuclear Regulatory Commission (2001) Systematic SWP TIG Welding catalogue: www.specialisedwelding. co.uk/tig-welding.html. Ralph Whitcher is chair of the ASE Safeguards in Science Committee. He is one of the CLEAPSS radiation protection advisers and a chartered radiation protection professional. He is also the chair of the Research and Teaching Sectorial Committee of the Society for Radiological Protection. He was formerly an advisory teacher for science. Email: rwhitcher@btinternet.com 74 SSR June 2011, 92(341)
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