POWDER COATINGS PRODUCT GUIDE - LANCO POWDERADD SOLPLUS
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GENERAL INDUSTRIAL METAL LANCO™ POWDERADD™ SOLPLUS™ POWDER Coatings Product Guide www.lubrizol.com/powder
WHAT WE ADD MAKES THE DIFFERENCE.™ As a global specialty chemical company, Lubrizol offers effective solutions to help powder coatings manufacturers enhance performance with an additives portfolio that empowers formulators to improve a broad range of functional and aesthetic properties. Our advanced technologies strengthen numerous powder coatings performance properties, such as gloss and matting, scratch and mar resistance, texturing, degassing and flow. We dedicate our global expertise to providing the powerful additives that give our customers a competitive edge when entering new markets and growing business in their existing areas of focus. 1
Innovative Products Our surface modifiers, flow modifiers and hyperdispersants provide manufacturers with the means to meet a diverse range of performance and production benchmarks. From increased durability to enhanced appearance to regulatory compliance, we can help manufacturers achieve all of their powder coating requirements. Equally important, with decades of experience, our team of technical service experts offers invaluable formulation insight to create solutions tailored to your unique application. Additionally, Lubrizol specializes in comprehensive development and testing to ensure reliable performance and manufacturing efficiency. Trusted Supplier Lubrizol powder coating specialists have a long track record of working side-by-side with customers to create individualized formulations for their needs. The result is an expansive product line and a wealth of knowledge that offers effective solutions for your company. Not only does Lubrizol deliver outstanding additives, we offer the reliability every operation needs from its suppliers. From product availability to timely delivery, our global network offers the distribution and service that manufacturers require to thrive in today’s competitive business environment. 2
Lubrizol Additives for Powder Coating Applications Matting/Gloss Control Scratch/Mar Resistance PowderAdd™ 9025/9027/9029 Lanco™ 1900 MF Polyolefin waxes that produce good matting This polymer compound provides both scratch/ while also offering increased scratch resistance mar resistance and reduction of coefficient of and improved slip. friction (COF) while offering FDA 21 CFR 175.300 compliance. Lanco™ 1900 MF offers minimal loss of PowderAdd™ 9094 gloss and minimal haze formation, with negligible A pure polypropylene wax for matting that impact on distinctness of image (DOI). meets FDA 21 CFR 175.300 compliance and supports adhesion of silicone sealants. It also Lanco™ 1910 MF provides superior scratch resistance and A polymer compound offering scratch/mar surface hardness. resistance as well as reduction of coefficient of friction (COF) with minimal loss of gloss, minimal haze formation and negligible impact on distinctness of image (DOI). Lanco™ PP 1350 F This PP modified polyethylene delivers high abrasion and scratch resistance, excellent scuff resistance and enhanced anti-blocking. In addition, it is FDA 21 CFR 175.300 compliant. Lanco™ TF 1725 A PTFE modified PE that increases scratch and abrasion resistance as well as slip properties. Lanco™ TF 1725 is an economical grade that offers good hardness. Lanco™ TF 1778 This PTFE modified PE increases scratch, scuffing and abrasion resistance. It also provides excellent slip and complies with FDA 21 CFR 175.300. PowderAdd™ 9078 This PTFE modified PE delivers excellent scratch/ mar resistance as well as good slip and abrasion resistance. With very good gloss retention, it complies with FDA 21 CFR 175.300. 3
Degassing Agents PowderAdd™ 9060 Lanco™ SM 2003 This amide wax ensures excellent degassing A modified PE wax providing excellent properties and enhanced air release to prevent degassing properties and enhanced air release cratering during curing. PowderAdd™ 9060 to prevent cratering during curing. Lanco™ also acts as a process aid and significantly SM 2003 also increases slip and reduces enhances slip. yellowing versus amides. In addition, it is PowderAdd™ 9423 FDA 21 CFR 175.300 compliant. A proprietary blend, PowderAdd™ 9423 Lanco™ PP 1362 D promotes effective degassing and adhesion, This modified polypropylene wax imparts i.e., of silicone sealants. It also offers good excellent degassing properties and reduced gloss retention and low haze. Complies with coefficient of friction (COF) while delivering good FDA 21 CFR 175.300. matting and improved scratch resistance. Surface Modifiers For Powder Coatings Scratch Resistance Matting Efficiency Degassing Post Addibility Micronized Products Lanco™ TF 1778 yes Lanco™ TF 1725 yes PowderAdd™ 9078 no Lanco™ 1900 MF yes Lanco™ 1910 MF no PowderAdd™ 9094 no PowderAdd™ 9025 no PowderAdd™ 9027 no PowderAdd™ 9029 no Lanco™ PP 1362 D yes Lanco™ SM 2003 yes PowderAdd™ 9060 yes PowderAdd™ 9423 yes low = high = 4
Lubrizol Additives for Powder Coating Applications—CONT. Flow Modifiers General Purpose Lanco™ Flow P 10 PowderAdd™ 9016 This additive reduces or mitigates craters, A polyethylene wax that functions as a pinholes, fisheyes and other surface defects processing aid during powder production. as well as reducing orange peel and improving Designed for near universal use, PowderAdd™ substrate wetting. FDA 21 CFR 175.300 compliant. 9016 offers good surface properties such as slip, scratch and abrasion resistance. Lanco™ Flow P 30 FDA 21 CFR 175.300 compliant. An oleo-based modified wax that improves flow and leveling with minimal influence on gloss. Hyperdispersants With broad compatibility and easy dispersability, Solplus™ L300 it delivers degassing properties as well. FDA 21 A polymeric dispersant that improves pigment CFR 175.300 compliant. dispersion, stability and final film quality. Most pigments will also have better gloss, leveling Fluidizing Agents and flow, color development and jetness PowderAdd™ G130 (carbon black pigments). An inorganic surface-treated silica gel, PowderAdd™ G130 improves fluidization and Solplus™ L400 flow during powder coating application. It also This polymeric dispersant improves pigment provides improved storage stability and dispersion, stability and final film quality. When anti-caking properties. used with titanium dioxide, it improves additional gloss, leveling/flow and opacity characteristics. Antistatic Agents Lanco™ Stat 308 A conductivity promoter, Lanco™ Stat 308 minimizes Faraday cage effect while also improving coverage in recessed corners and on edges. It also aids dispersion of pigments and filler concentrates. FDA 21 CFR 175.300 compliant. 5
Texturing Agents PowderAdd™ 9080 A structuring agent that Lanco™ 1890 N provides a coarse, “long wave type” structure. A PTFE wax with excellent fine texture control PowderAdd™ 9080 also offers excellent control and increased matte appearance at low dosages. of hammertone type structuring and consistent It also enhances scratch resistance and slip. structure development. Complies with FDA 21 CFR 175.300. PowderAdd™ 9083 Lanco TF 1830 N ™ This PTFE modified PE wax gives excellent fine A PTFE modified PE wax that combines a uniform, texture control with uniform surface texture and fine surface texture with excellent abrasion significantly improved matte appearance. It also resistance. In addition, Lanco™ 1830 N increases enhances scratch resistance and complies with surface slip by reducing coefficient of FDA 21 CFR 175.300. friction (COF). Complies with FDA 21 CFR 175.300. Matting Efficiency of Lanco™ & PowderAdd™ Texturing Agents 25 20 15 10 5 0 Lanco™ TF 1830 N PowderAdd™ 9083 Lanco™ 1890 N Gloss 60˚ Addition level 2% on total formulation weight for Lanco™ TF 1830 N and PowderAdd™ 9083, 0.4% for Lanco™ 1890 N. Surface Modifiers for Texturing of Powder Coatings Description of Texture Matting Grade Minimum Addition Rate Product Lanco™ TF 1830 N Fine, Uniform Glossy to Semi-Matte 0.8 Lanco™ 1890 N Fine, Uniform Semi-Matte to DULL Matte 0.2 PowderAdd™ 9080 HAMMERTONE n/a 0.2 PowerAdd™ 9083 Fine, Uniform Semi-Matte to Matte 0.5 6
TYPICAL physical properties Matting/Gloss Control Particle Size as determined by Laser Diffraction Density (MM or Post Melting Point Product Name Description Primary Benefit Secondary Benefit Median (Dv50 µm) g/cm3) @ 20 ˚C Addibility ˚C (˚F) (68 ˚F) PowderAdd™ Polyolefin Matting Increased scratch No 15 0.96 105 (221) 9025 resistance, improved slip PowderAdd™ Polyolefin Matting Increased scratch No 470 0.95 105 (221) 9027 resistance, improved slip PowderAdd™ Polyolefin Matting Increased scratch No 15 0.95 105 (221) 9029 resistance, improved slip PowderAdd™ Pure PP Matting, FDA 21 CFR Superior scratch No 13 0.90 140 (284) 9094 175.300 compliance, resistance and supports adhesion, i.e., surface hardness of silicone sealants TYPICAL physical properties Scratch and Mar Resistance Particle Size as determined by Laser Diffraction Density (MM or Post Median Melting Point Product Name Description Primary Benefit Secondary Benefit Dv90 µm g/cm3) @ 20 ˚C Addibility (Dv50 µm) ˚C (˚F) (68 ˚F) Lanco™ 1900 MF Polymer Scratch & mar resistance; Minimal loss of Yes 15 - 1.12 60 (140) Compound reduction of coefficient gloss, minimal haze of friction (COF) with formation, and FDA 21 CFR 175.300 negligible impact compliance on distinctness of image (DOI) with FDA 21 CFR 175.300 compliance Lanco™ 1910 MF Polymer Scratch & mar resistance; Minimal loss of No 70-120 - 1.01 63 (145) Compound reduction of coefficient gloss, minimal haze of friction (COF) formation, and negligible impact on distinctness of image (DOI) Lanco™ PP 1350 F PP Modified High abrasion and scratch Enhances antiblock- Yes 9 22 0.94 150 (302) PE resistance, excellent ing properties, FDA scuff resistance 21 CFR 175.300 compliant Lanco™ TF 1725 PTFE Increased scratch and Economical grade Yes 6 14 1.01 125 (257) Modified PE abrasion resistance as with good hardness well as slip Lanco™ TF 1778 PTFE Enhances scratch Excellent slip, Yes 6 14 1.04 102 (216) Modified PE resistance, increases complies with FDA resistance to scuffing, 21 CFR 175.300 improves abrasion resistance PowderAdd™ PTFE Excellent scratch and Very good gloss No 90 - 1.01 115 (239) 9078 Modified PE mar resistance, good slip retention, and abrasion resistance complies with FDA 21 CFR175.300 7
TYPICAL physical properties Texturing Agents Particle Size as determined by Laser Diffraction Density (MM or Median Melting Point Product Name Description Primary Benefit Secondary Benefit Dv90 µm g/cm3) @ 20 ˚C (Dv50 µm) ˚C (˚F) (68 ˚F) Lanco™ 1890 N PTFE Excellent fine texture Enhances scratch 15 - 2.20 - control, increased resistance, matte appearance at increased slip low dosages Lanco™ TF 1830 N PTFE Uniform, fine surface Increases surface 9 22 1.04 125 (257) Modified PE texture, excellent slip by reduction abrasion resistance of the coefficient of friction PowderAdd™ Structuring Provides coarse, long Excellent control - - 1.10 - 9080 Agent wave type structure of hammertone type structuring, consistent structure development PowderAdd™ PTFE Excellent fine texture Enhances scratch 100 - 1.02 110 (230) 9083 Modified PE control with uniform resistance surface texture, significantly improved matte appearance TYPICAL physical properties Degassing Agents Particle Size as determined by Laser Diffraction Density (MM or Post Median Melting Point Product Name Description Primary Benefit Secondary Benefit Dv90 µm g/cm3) @ 20 ˚C Addibility (Dv50 µm) ˚C (˚F) (68 ˚F) Lanco™ SM 2003 Modified PE Excellent degassing Improves slip and Yes 9 19 0.97 140 (284) properties, improves air reduced yellowing release during cure to versus Amides avoid cratering Lanco™ PP Modified PP Excellent degassing Matting, improves Yes 9 22 0.9 140 (284) 1362 D properties, reduces scratch resistance coefficient of friction PowderAdd™ Amide Excellent degassing Acts as process Yes 9 22 0.98 143 (289) 9060 properties, improves air aid, improves slip release during cure to significantly avoid cratering PowderAdd™ Proprietary Effective degassing, Good gloss retention Yes 7.5 16 - 140 (284) 9423 Blend provides adhesion, i.e., and low haze of silicone sealants Flow Modification TYPICAL physical properties Density (MM or Activity Level Non-Volatile Product Name Description Primary Benefit Secondary Benefit g/cm3) @ 20 ˚C (%) Content (68 ˚F) Lanco™ Flow P 10 Acrylic/Silica Eliminates surface defects Improves substrate wetting 1.49 @ 15.6 ˚C 66 99 such as craters, pinholes (66 ˚F) and fisheyes, reduces orange peel Lanco™ Flow P 30 Oleo-Based Improves flow and leveling, Wide compatibility, easy 0.9 @ 20 ˚C 100 - Modified Wax minimal influence on gloss dispersability, degassing (68 ˚F) 8
Antistatic Agents TYPICAL physical properties Density (MM or g/cm3) Product Name Description Primary Benefit Secondary Benefit Non-Volatile Content @ 20 ˚C (68 ˚F) Lanco™ Stat 308 Conductivity Minimizes Faraday cage Acts as dispersion aid 0.95 69 (156) Promoter effect improving coverage for pigments or filler in recessed corners and concentrates on edges General Purpose TYPICAL physical properties Post Density (MM or g/ Melting Point Product Name Description Primary Benefit Secondary Benefit Addibility cm3) @ 20 ˚C (68 ˚F) ˚C (˚F) PowderAdd™ 9016 PE Acts as a processing aid For universal use showing No 0.93 109 (228.2) during powder production good surface properties such as scratch resistance, slip, and abrasion resistance Hyperdispersants TYPICAL physical properties Density (MM or Melting Point Non-Volatile Product Name Description Primary Benefit Secondary Benefit g/cm3) @ 20 ˚C Pigment ˚C (˚F) Content (68 ˚F) Solplus™ L300 Polymeric Improves pigment Improves gloss, 1.16 50-55 (122-131) 100% Organic and Dispersant dispersion, stability leveling/flow and color organic/inorganic and final film quality strength development mixtures, for most pigments, as especially carbon well as jetness with black carbon black pigments Solplus™ L400 Polymeric Improves pigment Improves gloss, 1.13 48 (118) 100% Inorganic, Dispersant dispersion, stability leveling/flow and especially TiO2 and final film quality opacity with titanium dioxide TYPICAL physical properties Fluidizing Agents Particle Size as determined by Laser Diffraction Density (MM or Median Si O2 (%; Product Name Description Primary Benefit Secondary Benefit Dv90 µm g/cm3) @ 20 ˚C (Dv50 µm) ignited basis) (68 ˚F) PowderAdd™ Inorganic Improves fluidization Improved storage 5.5 - 2.10 97.8 G130 surface treated and flow during powder stability and anticaking silica gel coating application properties MAIN FDA – COMPLIANT PRODUCTS Product Name Description FDA 21 CFR 175.300 Lanco™ 1550 Matting Agent Yes PowderAdd™ 9027 Matting Agent Yes PowderAdd™ 9029 Matting Agent Yes Lanco™ TF 1725 Scrath & Mar Resistance Yes Lanco TF 1830 N ™ Texturizing Agent Yes Lanco 1890 N ™ Texturizing Agent Yes PowderAdd™ 9083 Texturizing Agent Yes Lanco™ SM 2003 Degassing Agent Yes Lanco PP 1362 D ™ Degassing Agent Yes PowderAdd™ 9060 Degassing Agent Yes PowderAdd™ 9423 Degassing Agent Yes Further FDA approved products are available. Please contact your Lubrizol representative. 9
A DEEPER UNDERSTANDING OF POWDER COATING NEEDS Lubrizol is your single source for unmatched powder coating innovation and application expertise. Whether you need a custom formulation or an off-the-shelf solution, we have the technical understanding, real-world experience and wide-ranging product catalog to enable you to reach all of your manufacturing and efficiency goals. Powder Coating Performance Enhancements • Uniform matting/gloss control • Enhanced scratch and mar resistance • Fine and coarse texturing • Excellent degassing properties • Flow modification • Antistatic agents to improve coverage • Improved pigment dispersion and stability • Increased fluidization and flow during powder coating application The Lubrizol Advantage • A recognized leader in advancing coating technologies • Global research and analytical resources • Product selection and formulation guidance 10
North America Lubrizol Advanced Materials, Inc. 9911 Brecksville Road Brecksville, OH 44141 USA 1.800.380.5397 Europe Lubrizol Limited PO Box 42, Hexagon Tower Blackley, Manchester WHAT WE ADD MAKES THE DIFFERENCE.™ M9 8ZS United Kingdom +44 161 721 6800 At Lubrizol, we innovate coatings solutions that help our customers balance Asia-Pacific the aesthetics, durability and functionality needs of their products for a Lubrizol Specialty Chemicals wide array of surfaces and substrates. Our strength is in collaborating with (Shanghai) Co., Ltd customers to solve their toughest challenges—such as making coatings 10/F, Park Center International safer, enhancing production efficiency and reducing environmental impact— No. 1088 Fang Dian Road Shanghai 201204, PR China without compromising performance. To learn more, contact your Lubrizol +8621-3866-0366 representative or visit www.lubrizol.com/coatings. South America The information contained herein is believed to be reliable, but no representations, guarantees or warranties of any kind are Lubrizol do Brasil Aditivos Ltda made as to its accuracy, suitability for particular applications or the results to be obtained. The information is based on laboratory Avenida Nove de Julho, 3653 work with small-scale equipment and does not necessarily indicate end product performance. Because of variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the Jardim Paulista suitability of the products for the applications disclosed. Full-scale testing and end product performance are the responsibility of the user. Lubrizol Advanced Materials, Inc. shall not be liable for and the customer assumes all risk and liability of any use or Sao Paulo – SP handling of any material beyond Lubrizol Advanced Materials, Inc.’s direct control. The SELLER MAKES NO WARRANTIES, EXPRESS 01407-000 OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Nothing contained herein is to be considered as permission, recommendation nor as an inducement to practice any +55.11.4082.1330 patented invention without permission of the patent owner. Visit us at: © Trademarks owned by The Lubrizol Corporation or its affiliates. www.lubrizol.com/powder The Lubrizol Corporation 2015. All Rights Reserved. 15-0608
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