NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute

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NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
NICKEL

                                                                                  MAGAZINE
                        T HE M AG A ZINE DE VOT ED TO NICK EL A ND I T S A PPLIC ATIONS

                                           NICKEL, VOL. 37, Nº 1, 2022

                      When strength matters

       Building codes                      Stainless steel cables                            New San Giorgio Bridge
safe buildings and structures             for harsh environments                                 stronger, safer
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
EDITORIAL:
                                                                                                                                                               ON THE STRENGTH OF NICKEL

                                                                                                                                                               Strength is vital, because when strength is lacking bad things happen. It is one
                                                                                                                                                               of the key attributes that nickel brings to materials.

                                                                                                                                                                   “The strength of a material is its
                                                                                                                                                                   ability to withstand an applied load
CHATTANOOGA BOILER & TANK COMPANY

                                                                              CASE STUDY 24                                                                        without failure or deformation.”

                                                                              WASHINGTON SUBWAY
                                                                                                                                                               Nickel provides a useful combination of strength, ductility and toughness. This
                                                                                                                                                               is essential in heavy duty applications like aircraft landing gear which need to
                                                                                                                                                               withstand repeated shocks. Here, nickel in maraging steel plays a critical role
                                                                              The Washington Metropolitan Area Transit Authority (WMATA) Metrorail             in preventing fatigue and avoiding catastrophic failure.

                                                                                                                                                                                                                                                                                                    NICOLE KINSMAN
                                                                              serves more than 600,000 customers a day and is the second busiest in            Nickel in stainless steel enhances corrosion resistance and allows tough,
                                                                              the United States, with 91 stations in Virginia, Maryland, and the District      ductile and strong welds which, in turn, ensure that stainless steel can be used
                                                                              of Columbia. As part of a maintenance programme to replace existing              in strong and durable structures. Structures like Italy’s new San Giorgio Bridge.
                                       The load-bearing elements of the
                                                                              escalators throughout its network, eye-catching stainless steel canopy           Designed by Renzo Piano, the use of stainless steel reinforcement guarantees
                                       canopy are rectangular, hollow
                                                                              structures are being installed over uncovered metro entrances to protect         mechanical strength and corrosion resistance. The reinforcement is critical
                                       structural sections made from
                                       austenitic stainless steel Type 316L   exterior escalators from rain, snow and salt during inclement weather,           for ensuring the durability of the bridge, which was constructed following the
                                       which contains 10% nickel.             improving escalator reliability and passenger convenience.                       catastrophic failure of its predecessor.
                                                                              Providing instantly recognisable         assembled in the fabrication shop, is   Stainless steel has been used effectively in landmark buildings for over a
                                                                              entries to the metro rail system, the    transported by road to the site and     century. But it is only now that specific stainless steel design codes have been      Type 316 (UNS S31600) cables
                                                                              graceful canopies incorporate stain-     then bolted together quickly during     published. These are necessary because the properties of stainless steel differ       and rods with Type 2205
                                                                              less steel and glass in a design that    night-time closures to minimise         from carbon steel. The American Institute of Steel Construction’s new design          (S32205) fittings and support
                                                                                                                       disruption to the metro operations.     standard provides user-friendly and economic design specifications to help            arms were used in China’s
                                                                              is reminiscent of the Metro stations’
                                                                                                                       The design is modified to meet each     designers and structural engineers use stainless steel easily and effectively for     Poly building’s stainless steel
                                                                              iconic vaulted and coffered ceilings.
                                                                                                                                                               strong structural projects.                                                           cable-net curtain wall.
                                                                              Each canopy includes a glazing           site’s unique characteristics.
                                                                              system supported on a stainless          Type 316L (UNS S31603) is ideally       And stainless steel is also a metaphor for strength. Spanish sculptor, Jordi Dìez
                                                                              steel torus-shaped frame with main       suited for structures in transport      says the uniqueness of stainless steel endows his works with power and expres-
                                                                              girders located directly above the       hubs because of its excellent           siveness. These attributes are personified to perfection in his recent sculpture of
                                                                              parapet walls on diagonally tapered      corrosion resistance, low mainte-       tennis legend Rafael Nadal playing to his strengths – his signature left forehand.
                                                                              struts. The modular design, with         nance requirements and attractive       Clare Richardson
                                                                              large sections of the roof being         surface finish.                         Editor, Nickel

                                    22 || NICKEL,
                                          NICKEL, VOL.
                                                  VOL. 37,
                                                       37, Nº
                                                           Nº 1,
                                                              1, 2022
                                                                 2022                                                                                                                                                                                             NICKEL, VOL. 37, Nº 1, 2022 | 3
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
NICKEL
                                                                                                                                                                                                                 Magnetic first                                                               Non-toxic

                                                                                                                                           NOTABLES
  CONTENTS                                                                                                                                                                                                       For the first time in the world, Denso Corporation has succeeded in         detector
                                                                                                                                                                                                                 artificially synthesising iron-nickel superlattice magnetic powder, which
   02     Case study no. 24
                                                                                                                                                                                                                 has magnetic properties due to the arrangement of iron and nickel atoms.
          Washington subway
                                                                                                                                                                                                                 The strong magnetism is equivalent or superior to that of neodymium
   03     Editorial
                                                                                                                                                                                                                 magnets. To enhance the competitiveness of their key components for
          On the strength of nickel
                                                                                                                                                                                                                 electric vehicles, the company plans to apply this less expensive, high
   04     Nickel notables
                                                                                                                                                                                                                 performance magnet to small motors as early as five years from now, and
   06     Building codes
                                                                                                                                                                                                                 in the future to drive motors. The
          Safe buildings, safe structures

                                                                                                                                                                                                                                                                                                                                              ADAPTED FROM NANO LETTERS 2021, DOI: 10.1021/ACS.NANOLETT.1C02336
                                                                                                                                                                                                                 global automotive components
   08     San Giorgio Bridge
                                                                                                                                                                                                                 manufacturer has started mass
          Stronger, safer
                                                                                                                                                                                                                 production while Aisin, part of
   10     Nickel cables
          Holding up in harsh conditions                                                                                                                                                                         the Toyota Group, will establish a
                                                                                                                                                                                                                 global supply system for electric
   11     Critical connections
                                                                                                                                                                                                                 units and other products by 2025.

                                                                    Super-elastic alloy
          Strong fasteners

   12     Maraging steel

                                                                    takes the heat
          High strength and toughness

   13
                                                                                                                                                                                                                 Riding high
          Nickel alloys
          Ferrium

   14     Technical Q&A
          Structural steel alloys                                                                                                                                                                                                                                                            When S. Chang, S. Ren and
                                                                                                                                                                                                                 South Korean company, SK On has successfully developed an
   15     New publications                                                                                                                                                                                       NCM9 battery, a world first in commercialising the 90 percent nickel        colleagues wanted to create
   15     Michael Orry Pearce                                                                                                                                                                                    content level. NCM (nickel, cobalt, manganese) identifies the three         heavy-metal-free metal – organic
          1934-2022                                                                                                                                                                                              main materials of the battery cathode, while number 9 indicates the         frameworks (MOF) for a flexible
   15     UNS details                                                                                                                                                                                            proportion of nickel. This award-winning innovation’s high nickel           X-ray detector and imager, they

                                                                                                                                                      CITY UNIVERSITY OF HONG KONG
                                                                                                                                                                                                                 content means higher energy and better battery output, a challenge          looked to nickel for an innovative
   16     Rafael Nadal statue
                                                                                                                                                                                                                 that required the company to develop advanced technology to
          A monument to human strength                                                                                                                                                                                                                                                       solution. Traditionally, radiation
                                                                                                                                                                                                                 ensure the safety of the end product. Tested and installed in Ford’s        detectors have contained restricted
                                                                                                                                                                                                                 F-150 Lightning, the first electric version of Ford’s legendary pickup      metals, such as lead and cadmium.
  Nickel magazine is published by Nickel Institute                                                                                                                                                               truck, it is ready to roll into the market. With nearly 200,000 vehicles    The researchers mixed a solution of
  www.nickelinstitute.org                                                                                                                                                                                        reserved before launch, all eyes will be on this model’s continued
                                                                                                                                                                                                                                                                                             nickel chloride salt and DABDT, a
  Dr. Hudson Bates, President
                                                                    Researchers at City University of Hong Kong (City U) and other                                                                               high performance and endurance.
  Clare Richardson, Editor                                                                                                                                                                                                                                                                   disulfide-reducing agent. The team
  communications@nickelinstitute.org
                                                                    collaborators have accidentally discovered a first-of-its-kind super-                                                                                                                                                    sandwiched the MOF, in which
  Contributors: Nancy Baddoo, Gary Coates,
                                                                    elastic alloy that retains its stiffness even after being heated to 1,000 K                                                                                                                                              nickel linked the DABDT molecules,
  Richard Matheson, Geir Moe, Kim Oakes, Benoît Van Hecke,
                                                                    (726.85 °C) or above.
  Odette Ziezold                                                                                                                                                                                                                                                                             between gold film electrodes on
                                                                    Professor Yang Yong and his team found that Co25Ni25(HfTiZr)50, or
  Design: Constructive Communications                                                                                                                                                                                                                                                        a flexible plastic surface, using
                                                                    “the high-entropy Elvinar alloy”, retains its modulus of elasticity when
  Material has been prepared for the general information of                                                                                                                                                                                                                                  copper wires to transmit current.
  the reader and should not be used or relied upon for specific     exposed to a very wide range of temperatures. This means the stiffness
                                                                                                                                                                                     © 2022 FORD MOTOR COMPANY

  applications without first securing competent advice. While
                                                                                                                                                                                                                                                                                             Placing an aluminium letter “H”
  the material is believed to be technically correct, Nickel
  Institute, its members, staff and consultants do not represent
                                                                    of the alloy remains invariant to temperature.
                                                                                                                                                                                                                                                                                             on the detector, they irradiated
  or warrant its suitability for any general or specific use and    This property is beneficial for devices that are expected to undergo
  assume no liability or responsibility of any kind in connection
  with the information herein.                                      drastic temperature changes. “We know that the temperature ranges                                                                                                                                                        it with X-rays, measuring a much
   ISSN 0829-8351                                                   from 122 to -232 °C on the surface of the moon. This alloy will remain                                                                                                                                                   lower current output underneath
  Printed in Canada on recycled paper by Hayes Print Group          strong and intact in an extreme environment, and so it would fit very                                                                                                                                                    the H. The researchers say that
  Cover: Shutterstock ©Harry Steele                                 well with future mechanical chronometers operating within a wide                                                                                                                                                         their proof-of-concept device is
  Stock image credits: pg. 3 iStock©Phantom1311
  pg 9. iStock©Luca Reina Mafaraci, iStock©Mara Duchetti            range of temperatures during space missions,” said Professor Yang.                                                                           SK On’s NCM9 battery won CES 2022 Innovation awards in two categories:      a promising advance for the next
  pg.10 iStock©BIHAIBO, iStock©trekandshoot
  pg. 12 iStock©Babayev pg. 13 iStock©Dmitrii Guldin                The work was published in the journal Nature.                                                                                                “In-Vehicle Entertainment & Safety”, and “Embedded Technologies”.           generation of radiation detection.

4 | NICKEL, VOL. 37, Nº 1, 2022                                                                                                                                                                                                                                                                             NICKEL, VOL. 37, Nº 1, 2022 | 5
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
to prepare a full ANSI (American           economic design specification will
                                                                                                                         National Standards Institute) design       remove significant long-standing
                                                                                                                         standard for structural stainless steel.   obstacles for structural stainless steel

                                                                                                                         Work began with the establishment          designs and expand global market

  BUILDING CODES                                                                                                         of the AISC Committee on Structural
                                                                                                                         Stainless Steel, which included stain-
                                                                                                                                                                    potential for nickel-containing
                                                                                                                                                                    austenitic and duplex stainless steels.

  SETTING HIGH STANDARDS FOR                                                                                             less steel fabricators and welding         The benefits of this standards work

                                                                                                                                                                                                                                                              STAINLESS STRUCTURALS
                                                                                                                         experts, metallurgists, designers, and     are not limited to buildings and

  STRUCTURAL STAINLESS STEEL
                                                                                                                         academics. The Steel Construction          related structures: it is expected that
                                                                                                                         Institute in the UK played a leading       these stainless steel design rules will
                                                                                                                         role in drafting the new design rules.     be referenced in ANSI/AISC N690,
                                                                                                                                                                                                               Austenitic stainless steel
                                                                                                                         These were based on the significant        Specification for safety-related steel
                                                                                                                                                                                                               laser welded I-shape
                                                                                                                         structural research which had been         structures for nuclear facilities, which
                                                                                                                                                                                                               beams and channels
                                                                                                                         carried out by universities around         is used globally, and currently does
                                    The sudden failure of a building or bridge is mercifully a rare event, thanks
                                                                                                                         the world over the last 30 years or so,    not give any stainless steel structural
                                    largely to international or national standards: structures are designed in
                                                                                                                         and had already been used as the           design information. Additionally,          A stainless steel support
                                    accordance with a design standard, using products conforming to a product
                                                                                                                         basis for developing the rules in the      work is starting under the auspices of     structure was used for the
                                    standard and manufactured using techniques and to a quality level defined in a
                                    construction standard.                                                               structural stainless steel Eurocode.       AASHTO (the American Association           passive cooling system in the
                                                                                                                         Three years later, the new design          of State Highway and Transportation        containment structure at the
                                    Building and construction design            This was the situation in the US until
                                                                                                                                                                                                               Vogtle Nuclear Power Plant
                                    standards codify best practices,            last year for designing structural       standard ANSI/AISC 370-21                  Officials) to modify the rules in
                                                                                                                                                                                                               (Units 3 and 4) in Burke County,
                                    methods, and technical requirements         stainless steel – there was no           Specification for structural stainless     ANSI/AISC 370 so that they can
                                                                                                                                                                                                               GA, USA. The tower is 9.1 m
                                    to create a safe and sustainable built      stainless steel design specification     steel buildings was published. It is       be used for the design of duplex           (30 ft) tall and 3.4 m (11 ft)
                                    environment for the community.              for mainstream structural sections,      expected that the availability of          stainless steel highway, pedestrian        square, and made from duplex
                                    Standards are developed through a           which are the majority of the market,    this up-to-date, user-friendly and         and rail bridges in the US.                stainless steel UNS S32101.
                                    process of consensus. In essence, they      such as welded, hot rolled or hollow
                                    are the distilled wisdom of people
                                                                                sections. Consequently, it was
                                    with expertise in their subject mat-
                                                                                much easier, cheaper, and faster for
                                    ter – material producers, fabricators,
                                                                                engineers and their clients to use
                                    manufacturers, designers, researchers,
                                                                                other steels, aluminium, wood, FRP,
                                    trade associations, users, or regulators.
   ANSI/AISC 370 – is the first                                                 and concrete, which have structural
                                    The requirements in design                  standards and code acceptance.
   US design specification for
                                    standards are often hard-fought
   structural stainless steel. It                                               This situation presented a significant
                                    compromises between economy and
   was published in 2021.                                                       barrier to stainless steel’s market
                                    ease-of-use. It is also important that
                                                                                growth and broad acceptance.
                                    design standards are comprehensive
                                    and cover the range of structures,          The structural design standards
                                    materials and loading scenario              produced by the American Institute
                                    frequently encountered, and that            of Steel Construction (AISC), or
                                    they are not unduly conservative,           closely related specifications, are
                                    resulting in over-design and the            used throughout North and South
                                    waste of valuable finite resources.         America, as well as in the Middle

                                                                                                                                                                                                                                                              PREMIER INDUSTRIAL/WESTINGHOUSE
                                    In the absence of a standard, time          East and also for about 30% of the
                                    and cost-consuming code exceptions          projects in China. In 2018, ten years
                                    must be obtained from the relevant          after the stainless steel industry had
                                    building authorities and this often         started discussions with them, AISC
                                    cannot be justified by busy designers.      finally announced their intention

6 | NICKEL, VOL. 37, Nº 1, 2022                                                                                                                                                                                             NICKEL, VOL. 37, Nº 1, 2022 | 7
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
is not an issue (such as in the bulk      is also beneficial to the total cost of
                                                                                                                                      of the concrete), carbon steel rebar      ownership of infrastructure projects.
                                                                                                                                      ensures the structural integrity of the   When dealing with the challenges
                                                                                                                                      concrete.                                 of harsh marine environments,
                                                                                                                                      Long-term value                           stainless steel provides significant

                THE NEW SAN GIORGIO BRIDGE                                                                                            The San Giorgio Bridge features
                                                                                                                                      9000 t of carbon steel rebar and an
                                                                                                                                                                                savings overall in maintenance costs
                                                                                                                                                                                for bridges, proving to be the most

                STRONGER, MORE DURABLE
                                                                                                                                      additional 250 t of stainless steel       economical solution in the long
                                                                                                                                      rebar. This ratio of (only) 3% is         term. Other important advantages
                                                                                                                                      typical of the 1 to 5% range that         in marine settings include superior
                                                                                                                                      characterise reinforced concrete          mechanical strength, high ductility
                                                                                                                                      projects exposed to corrosive             and excellent energy absorption
                                                                                                                                      conditions. Observing such a ratio        capacity during seismic events.

                                                   After the collapse of Genoa’s Ponte Morandi in August 2018, an independent
                                                   report indicated poor maintenance and flaws in the design and construction
                                                   of the bridge as the likely causes behind the deadly accident. Corrosion of
                                                   the cables on the top of the southern stay of one of the towers was cited
                                                   as the main culprit. Also, regular inspections were said to be insufficient
                                                   to allow for an adequate level of knowledge on the effective state of
                                                   degradation of the cables.
                                                   Awareness about robustness and           Reinforced where it’s needed
CENTRO INOX

                                                   durability of bridge design has grown    Stainless steel acts as a protection
                                                   since Morandi’s time. The new San        against corrosion and cracking or
                                                   Giorgio Bridge (its successor) in        spalling of the structure elements
                                                   Genoa was designed by Renzo Piano        most exposed to atmospheric agents;
                The combined use of carbon steel
                                                   and inaugurated in 2020. Unlike the      in fact, in very aggressive environ-
                and stainless steel, in contact
                with each other when immersed      original bridge’s cable-stayed design,   mental conditions, such as marine
                in concrete, does not lead to      it uses stainless steel reinforcement,   and port structures, it is necessary to
                an increased risk of corrosion.    which not only guarantees mechan-        use materials with the right charac-
                                                   ical strength, but also corrosion        teristics. In the absence of stainless
                                                                                                                                                                                                                          The stylish San Giorgio Bridge,
                                                   resistance.                              steel, external agents would trigger
                                                                                                                                                                                                                          shown completed (above) and
                                                   Stainless steel was specified in the     the corrosion of the carbon steel                                                                                             under construction (left), uses
                                                   most critical areas at the design        reinforcement, leading to an increase                                                                                         about 250 t of Type 304L stainless
                                                   stage. For example, stainless steel      of its volume, causing the concrete to                                                                                        steel rebar in critical areas only.
                                                   rebar was chosen for the pedestrian      crack over time and the structure to
                                                   zone of the bridge and positioned        deteriorate further.
                                                   next to steel rebar which is located     Type 304L (UNS S30403)/1.4307
                                                   closer to the bridge deck core.          stainless steel reinforcement of
                                                   When immersed in the concrete, the       different diameters was positioned
                                                   combined use of carbon steel and         at the outer surfaces of the concrete
                                                   stainless steel, in contact with each    structure, in the sections of the
                                                   other as the image shows, does not       structure which have a thinner con-
CENTRO INOX

                                                   lead to an increased risk of corrosion   crete cover and are more exposed
                                                   of the carbon steel.                     to the corrosion. Where exposure

              8 | NICKEL, VOL. 37, Nº 1, 2022                                                                                                                                                                                          NICKEL, VOL. 37, Nº 1, 2022 | 9
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
STAINLESS STEEL CABLES                                                                                                 CRITICAL CONNECTIONS
  HOLDING UP IN HARSH CONDITIONS                                                                                         ADVANTAGES OF STRONGER BOLTS

                                                                                                                         Bolt failures, arising from overload, fatigue or corrosion, can be very costly;
                                                                                                                         especially when they necessitate the shut-down of key operations whilst repair
                                                                                                                         work is undertaken.
                                                                                                                         Fasteners come in a variety of steel      galvanised steel and aluminium
                                                                                                                         alloys, so it is important to know the    members. For example they are used
                                                                                                                         specifics of the application to ensure    to connect the structural members
                                                                                                                         the correct steel is selected for the     in aluminium helidecks on offshore
                                                                                                                         intended use to avoid failure. As well    platforms.
                                                                                                                         as the loads to be carried, issues to     Long-term cost advantages
                                                                                                                         consider include accessibility of the     Although they are more expensive
                                                                                                                         connection, environment (temper-          than their carbon steel equivalents,
                                                                                                                         ature, water exposure, corrosivity),      the savings arising from long life with
                                    When it comes to hoisting heavy weights and defying gravity, it is critical to
                                                                                                                         and the materials being joined.           low maintenace can easily outweigh
                                    get the equipment right. Hardworking metal wire cables and ropes play an
                                                                                                                         Reusability and the installation          the initial costs in demanding
  Stainless steel wire rope         everyday role in efficiency and safety in the construction industry, offshore                                                                                            Bracing connection in a
                                                                                                                         process are also important consid-        applications. For example, in 2019
  and cable is used in many         operations, oilfield drilling platforms, architecture, and automotive applications                                                                                       stainless steel canopy at
                                                                                                                         erations. To guarantee a trouble-free     about 6000 duplex and super duplex
  industries such as oil and gas,   to name a few.                                                                                                                                                           Porto Airport, Portugal
                                                                                                                         lifespan and low lifecycle cost, it is    stainless steel fasteners were used
  construction, architecture,       The term wire rope is often used          (S31600) stainless steel wire rope         essential to select the right grade and   to construct a stainless steel bridge
  automotive, pulp and paper,       interchangeably with wire cable.          has even better resistance to pitting      properties for the application.           and integral liner to strengthen an old
  food processing and textiles.     However, in general, wire rope refers     corrosion and acids. Useful for
                                                                                                                         Essential for demanding                   Victorian sewer tunnel in London, UK.
                                    to diameters larger than 3/8 inch         marine applications, it also performs
                                                                                                                         applications                              Due to the disruption caused by the
                                    (9.5 mm). Sizes smaller than this are     well in industries where chemicals
                                    designated as cable.                                                                 Stainless steel fasteners are widely      project and accessibility difficulties,
                                                                              are predominant such as pulp and
                                                                              paper, food processing, and textiles.      used in many demanding industrial         a low-maintenance solution with
                                    The industry is divided into stainless
                                                                              Stainless steel wire rope and cable        applications where carbon steel           a 120-year design life was essential.
                                    steel and galvanised carbon steel.
                                                                              can also be used in temperatures up        fasteners would be simply inadequate,     Additionally, the structure was
                                    In comparison to galvanised carbon
                                                                              to 480 °C (900 °F).                        such as water treatment, wind energy,     required to be very compact and
                                    steel, stainless steel wire ropes are
                                    more durable and corrosion-resistant                                                 chemical process, marine, and also        carry high loads. High strength
                                                                              Environmental conditions, workload

                                                                                                                                                                                                                                                            NANCY BADDOO
                                    in harsh conditions, such as marine                                                  for subsea equipment. They are            duplex stainless steel bolts, typically
                                                                              limits (WLL) and tensile strength
                                    and saltwater environments.                                                          available in a range of alloys and con-   containing between 5 and 7% nickel,
                                                                              all play a role in choosing the right
                                                                                                                         ditions, offering different strengths,    were the obvious choice. Utilising the
                                    Nickel-containing Type 304 (UNS           stainless steel cable for every project.
                                                                              From oil riggings to bridge barriers,      levels of corrosion resistance, and       high strength of duplex stainless steel
                                    S30400) is the most used stainless
                                    steel grade in wire rope and cable.       children’s playgrounds to yachts,          also the ability to operate at both       also meant the connections could be
                                    It has about the same strength as         stainless steel cable is a hardwearing     high and low temperatures. As well as     downsized, saving materials and cost,
                                    galvanised wire rope but is much          material that provides a practical,        being essential for connecting stain-     and improving constructability on site,
                                    more corrosion resistant. For highly      robust solution as well as contributing    less steel members, stainless steel       with health and safety benefits due to
                                    corrosive environments, Type 316          aesthetically towards the design.          bolts are also suitable for connecting    reduced material handling.

10 | NICKEL, VOL. 37, Nº 1, 2022                                                                                                                                                                                         NICKEL, VOL. 37, Nº 1, 2022 | 11
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
MARAGING STEEL                                                                                                                                         THE QUEST FOR
  HIGH STRENGTH AND TOUGHNESS                                                                                                                            USEFUL NEW ALLOYS

                                                          Demand for high tensile strength steel with good elongation properties led                     Historically, development of new metal alloys was a costly, inefficient, and
                                                          to the development in the late 1950’s of maraging steels by C. Bieber of the                   time-consuming trial and error process. Metallurgical knowledge would be
                                                          International Nickel Company (INCO).                                                           used to formulate new alloy compositions, and determine forming and heat
                                                          The term ‘maraging’ is a combination               Due to the low carbon content, marag-       treatment procedures in an attempt to achieve enhanced properties relative to
                                                                                                                                                                                                                                                        Nickel-containing Ferrium 64,
                                                          of the words ‘martensite’ and ‘ageing’.            ing steels have good machinability.         established alloys. A series of trial heats would be melted and tested to fine                 with ultra-high strength and
                                                          They are a class of low carbon steels              When heat treated, the alloy has very       tune the properties.                                                                           high fracture toughness, finds
                                                          with a martensitic microstructure that             little dimensional change, so it is often   Approximately two decades ago,                  applications where AISI 4340 is                application in transmission gears.
                                                          are strengthened by a heat treatment               machined close to its final dimensions      integrated computational materials              typically used. Ferrium S53 has
                                                          process (ageing). This results in the              prior to heat treatment.                    engineering (ICME) was developed                mechanical properties comparable
                                                          precipitation of various intermetallic             Maraging steel’s high strength, tough-      to shift from physical experimenta-             with these alloys, but with the added
                                                          particles within the martensite micro-             ness and good ductility are utilised in     tion to virtual simulation. Questek             benefit of atmospheric corrosion
                                                          structure. There are several variants,             the following applications:                 Innovations has applied this method-            resistance which eliminates the need
                                                          but the principal alloying element is              • Missile and rocket motor cases that      ology to develop several nickel-                for cadmium coating.
                                                          ~18% nickel and secondary alloying                   are thinner than when made with           containing alloys with enhanced
                                                          elements are cobalt, molybdenum,                     lower strength steels                                                                     Another development is nickel-
                                                                                                                                                         properties.
                                                          titanium and aluminium. This family                • Aircraft – landing gear components,                                                      containing Ferrium C64, which is
                                                          is known as the 18Ni maraging steels.                high performance shafting, gears,         Ferrium takes flight                            an alternative to high performance
                                                          There is also a family of cobalt-free                and fasteners                             Questek developed Ferrium S53, a                gear steels such as AISI 9310. It offers
  The high strength-to-weight                             maraging steels which are cheaper but              • Recreational – bicycle frames, golf      nickel-containing, high-strength,
                                                                                                                                                                                                         ultra-high strength and high fracture
  ratio of maraging steels                                not quite as strong. The most common                 club heads, fencing blades                corrosion-resistant steel. It was
                                                                                                                                                                                                         toughness, combined with excellent
  makes them a prime choice                               18Ni maraging grades, with their typi-             • Motorsports – crankshafts, gears,        the first ICME-designed material
                                                                                                                                                                                                         fatigue and heat resistance. It finds
  for aircraft landing gear.                              cal composition and aged mechanical                  chassis components, torsion bars          to receive Aerospace Material
                                                                                                                                                                                                         application in critical aerospace
                                                          properties, are shown below. They are              Additional info will be available in our    Specification (AMS) and Metallic
                                                                                                                                                                                                         and automotive applications such as
                                                          identified by a number which indicates             new publication Maraging steels –           Materials Properties Development
                                                                                                                                                                                                         rotorcraft and race car transmission
                                                          the approximate tensile strength in                A review of commercial alloys and           and Standardisation (MMPDS)
                                                                                                                                                                                                         gears as well as energy applications.
                                                          thousands of pounds per square inch.               their properties.                           qualifications and fly as a safety-
                                                                                                                                                         critical landing gear on the US Air             ICME methodology allows for
    Maraging steels – Significant alloying elements and mechanical properties – Aged condition                                                           Force T-38 training jet. Ferrium                more rapid development of nickel-
                 UNS                                                     Tensile strength   Yield strength     Elong.   Charpy notch impact   Hardness   S53 is an ultra-high strength steel             containing multi-alloys for critical
    Grade        No.        Ni      Co     Mo      Ti       Al     Fe       MPa (ksi)         MPa (ksi)          %            J(ft-lb)          HRc      for structural aerospace and other              applications.
                           17.0-   8.0-    3.0-   0.15-    0.05-
    C-200       K92820                                             bal      1448(210)         1413(205)          12           49(36)           43-48
                           19.0    9.0     3.5    0.25     0.15
                                                                                                                                                         Typical
                           17.0-   7.0-    4.6-   0.30-    0.05-                                                                                         composition     UNS     C     Cr     Ni    Co      Mo     W      V     Si    Mn     Cu   Fe
    C-250       K92890                                             bal      1793(260)         1758(255)          11            27(20)          48-52
                           19.0    8.5     5.1    0.50     0.15
                                                                                                                                                         Ferrium S53   S10500   0.21   10.0   5.5   14.0    2.0    1.0   0.30    -     -     -    bal
                           18.0-   8.0-    4.6-   0.55-    0.05-
    C-300       K93120                                             bal      2035(295)         2000(290)          11           23(17)           50-55     Ferrium C64   K92731   0.11   3.5    7.5   16.3    1.75   0.2   0.02                -    bal
                           19.0    9.5     5.2    0.80     0.15
                           18.0-   11.5-   4.6-   1.25-    0.05-                                                                                         4340          G43400   0.40   0.8    1.8    -      0.25    -     -     0.2   0.7    -    bal
    C-350       K93540                                             bal      2413(350)         2344(340)          7             11(8)           55-60
                           19.0    12.5    5.2    1.50     0.15                                                                                          9310          G93106   0.10   1.2    3.2    -      0.11    -     -     0.2   0.55   -    bal

12 | NICKEL, VOL. 37, Nº 1, 2022                                                                                                                                                                                                                                    NICKEL, VOL. 37, Nº 1, 2022 | 13
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
ASK AN EXPERT FAQ FROM                                                               Michael Orry Pearce
                                                                 THE NICKEL INSTITUTE                                                                 1934-2022
                                                                 TECHNICAL ADVICE LINE                                                                Michael Pearce died in his 88th year
                                                                                                                                                      on 7 January 2022. He had a long
                                                                                                                                                                                               1958. He is held in high esteem by
                                                                                                                                                                                               former colleagues. He was highly
                                                                                                                                                      career at Falconbridge Nickel Mines      ethical, always respectful, and ever
                                                                                                                                                      and played a key role in establishing    courteous with the ability to bring out
                                                                                                                                                      the Nickel Institute in 1984 as          the best in others. He is remembered

                                                                 Q
                                                                                                                                                      Executive Director, later serving as
                                                                                                                                                                                               for being a consummate professional
                                                                                                                                                      President from 1996 to 2000. He was
   Geir Moe P.Eng. is the Technical                              Q: I am fabricating a component using a structural steel alloy and                                                            as well as a thoughtful mentor and
                                                                                                                                                      responsible for building international
   Inquiry Service Coordinator at                                painting it. I would like to use stainless steel, but 304L and 316L                                                           leader. Current Nickel Institute
                                                                                                                                                      awareness and membership for the
   the Nickel Institute. Along with                              are not as strong so the plate needed would have to be thicker, and                  organisation where he was fondly         President, Dr. Hudson Bates said,
   other material specialists situated                           that makes the stainless version very expensive. Are there other                     known simply as M.O.P. Michael was a     “Michael Pearce’s vision for the nickel
   around the world, Geir helps                                  more suitable stainless alloys?                                                                                               industry’s Institute in 1984 helped

                                                                 A
                                                                                                                                                      metallurgical engineer and graduated
   end-users and specifiers of nickel-                                                                                                                in engineering from the University of    create the blueprint on which the
                                                                 A: Types 304/304L (S30400/S30403)         stainless steels possess minimum
   containing materials seeking                                                                                                                       Toronto in 1957, completing his MA in    Nickel Institute operates today.”
                                                                 and 316/316L (S31600/S31603) are          yield strengths about double that of
   technical support. The team is on
                                                                 nickel-containing austenitic stainless    Types 304/304L and 316/316L. These
   hand to provide technical advice
                                                                 steels, that in the annealed condition    duplex stainless steels have been
   free of charge on a wide range

                                                                                                                                                      NEW PUBLICATIONS
                                                                 only have a minimum yield strength        used in many bridge constructions
   of applications such as stainless
                                                                 of 30 ksi (205 MPa). While carbon         throughout the world in mountain,
   steel, nickel alloys and nickel
   plating to enable nickel to be used                           and high-strength low alloy struc-        urban and seaside locations.
   with confidence.                                              tural steels can have a minimum                                                      Austenitic chromium-nickel               this informative publication about
                                                                 yield strength that can range from        Three duplex grades are shown in
   https://inquiries.nickelinstitute.org/                                                                                                             stainless steels – engineering           Ni-Hard castings. Ni-Hard castings
                                                                 36 (250) to 50 ksi (345 MPa).             the following table in comparison to
                                                                                                                                                      properties at elevated tem-              are known for their extreme abra-
                                                                                                           two steel grades.
                                                                 There is a family of nickel-contain-                                                 peratures (2980) is a reprint of         sion resistance used in applications
                                                                 ing stainless steels known as duplex      Additional information about               the original INCO publication. It

      NICKEL
                                                                                                                                                                                               such as mining, power, cement,
                                                                 which possess a microstructure            duplex stainless steels can be             provides the material properties for
                                                                                                                                                                                               dredging and steel industry.
                                                   O N L I N E

                                                                 composed of approximately equal           found in the Nickel Institute              the common austenitic stainless
                                                                                                           publication Practical guide to using       steels up to 1080 °C (2000 °F).          They are valuable references for
                                                                 quantities of austenite and ferrite
                                                                 microstructure. These duplex              duplex stainless steels (10044).           Properties and applications              engineers, designers, and end
      WWW.NICKELINSTITUTE.ORG                                                                                                                         of Ni-Hard alloys (11017) is the         users. Download from
      SUBSCRIBE to Nickel magazine free of charge and             Common                                                        Tensile properties    newly updated second edition of          www.nickelinstitute.org
      receive a printed copy or an e-mail notice when a           name          UNS            Typical composition,%              ksi (MPa) min.
      new issue is published. www.nickelinstitute.org
                                                                                         C     Cr     Ni   Mo      Mn     N     Y.S.    T.S.    EL%

                                                                                                                                                        UNS DETAILS
      READ Nickel magazine online in several languages.
      www.nickelinstitute.org/nickel-magazine/
                                                                                                      Duplex                                                                                      Chemical compositions (% by weight) of the alloys and stainless steels
                                                                                                                                  65      94                                                      mentioned in this issue of Nickel.
      SEARCH BACK ISSUES of Nickel magazine from our                           S32101   0.02   21    1.5    0.4     5    0.22   (450)   (650)   30
      online archive, going back to 2009.
                                                                                                                                  58      87           UNS           C        Cr       Cu         Fe        Mn         Mo            N      Ni       P               S           Si
      www.nickelinstitute.org/nickel-magazine/
                                                                  2304         S32304   0.02   23     4     0.3     2    0.14   (400)   (600)   25
                                                                                                                                                       S30400       0.08     18.0-      -         bal       2.00        -            -     8.0-     0.045          0.030        1.00
      FOLLOW US on Twitter @NickelInstitute                                                                                                            pg 10,14     max      20.0                           max                            10.5      max            max         max
                                                                                                                                  65     95
                                                                  2205         S32205   0.02   22     5     3.0    1.5   0.18   (450)   (655)   25     S30403       0.03     18.0-      -         bal       2.00        -            -     8.0-     0.045          0.030        1.00
      JOIN US on LinkedIn –                                                                                                                            pg 8,9,14    max      20.0                           max                            12.0      max            max         max
      visit the Nickel Institute’s page                                                             Carbon steel                                       S31600       0.08     16.0-      -         bal       2.00      2.00-          -     10.0-    0.045          0.030        1.00
                                                                                                                                                       pg 3,10,14   max      18.0                           max       3.00                 14.0      max            max         max
      WATCH nickel-related videos on                                                                                             36       58
      the Nickel Institute YouTube channel
                                                                  ASTM A36              0.20   -      -      -     1.0    -     (250)   (400)   23     S31603       0.030    16.0-      -         bal       2.00      2.00-          -     10.0-    0.045          0.030        1.00
                                                                                                                                                       pg 14,16      max     18.0                           max       3.00                 14.0      max            max         max
      www.youtube.com/user/NickelInstitute
                                                                  ASTM                  0.20   -      -     -s     1.0    -      50       65    21     S32205       0.030    22.0-      -         bal       2.00      3.00-        0.14-   4.50-    0.030          0.020        1.00
                                                                  A572 Gr 50                                                    (345)   (450)          pg 3          max     23.0                           max       3.50         0.20    6.50      max            max         max

14 | NICKEL, VOL. 37, Nº 1, 2022                                                                                                                                                                                                                            NICKEL, VOL. 37, Nº 1, 2022 | 15
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
XAVIER PLADELLORENS

                        A MONUMENT TO HUMAN STRENGTH
                                                              With a record 21 grand slam men’s singles titles in tennis, the most in history,
                                                              Rafael Nadal knows how to shine, both on the courts and off.
                                                              Unveiled at Roland Garros in 2021,           helps me express the inner energy of
                                                              a gleaming statue captures Nadal             the person I am depicting. I wanted
                                                              hitting his signature lefty forehand.        to depict Rafael as a synthesis of all
                                                              It is constructed entirely of nickel-        his attributes, which I boiled down to
                                                              containing Type 316L (UNS S31603)            one: strength. This sculpture is in fact
                                                              stainless steel. Standing 3 m tall, 4.89 m   a monument to human strength.”
XAVIER PLADELLORENS

                                                              wide and 2 m deep, it pays tribute           Getting up at 6:30 am and working
                                                              to the Spanish player who has won            10-to-12-hour days, the sculpture took
                                                              13 titles on the clay courts in Paris,       nearly eight months to complete.
                                                              scoring his first win there in 2005.
                         Says Nadal, “The statue is                                                        “Stainless steel has some special qual-
                                                              The sculptor, Jordi Díez is known for         ities I respect. It’s colourless. It’s very
                         spectacular. It’s a clean, modern
                                                              playing with the limits of figurative art.    light. When you work with it you feel
                         statue and I’m very pleased.
                                                              Looking beyond the traditional and            like you are escaping reality. Then
                         It’s really difficult to build a
                                                              studying new techniques, he came to           there’s that magical moment when
                         statue with that material and
                                                              love working with stainless steel.            you finish the work and it takes you
                         be so real as this one is.”
                                                              “As a material it is limitless. It really     by surprise. That gives me strength.”

                      16 NICKEL,
                         | NICKEL,VOL.
                                   VOL.37,37,NºNº1, 1,2022
                                                       2022
NICKELM When strength matters - THE MAGAZINE DEVOTED TO NICKEL AND ITS APPLICATIONS - Nickel Institute
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