Hot-dip galvanized steel strip - Technical Terms of Delivery
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Hot-dip galvanized steel strip Technical Terms of Delivery voestalpine Stahl GmbH www.voestalpine.com/stahl
Contents T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Introduction 5 Hot-dip galvanized steel strip with zinc coating 6 Steel grades 6 Mild steels for cold forming 6 Structural steels 12 High-strength steels for cold forming 16 Micro-alloyed steels 17 Bake-hardening steels 22 High-strength IF steels 24 2 Dual-phase steels 28 Complex-phase steels 33 TRIP steels 35 Zinc coating groups 38 Surface 39 Surface of the zinc coating 39 Surface quality 39 Surface type 40 Subsequent surface treatment 41 Available dimensions 42 Inspection and Testing 43 Test unit 43 Sample-taking 43 Performance of tests 43 Repeat tests 44
Processing information 45 T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Forming 45 Joining 45 Thermal rating 46 Suitability for the application of coatings 46 General notes 47 Fretting corrosion 47 Darkening 47 Formation of white rust 47 Flatness 48 Hot-dip galvanized steel strip with zinc/iron-coating (Galvannealed) 49 3 Steel grades 49 ZF coating groups 50 Surface 51 Surface quality 51 Surface type 51 Subsequent surface treatment 52 Available dimensions 53 Inspection and Testing 54 Processing information 55 Joining 55 Forming 55 Suitability for the application of coatings 55
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 General notes 56 Fretting corrosion 56 Formation of white rust 56 Hot-dip galvanized steel strip with zinc magnesium coating 57 Steel grades 57 ZM coating groups 58 Terms of delivery 59 4 Surface 72 Subsequent surface treatment 72 Application and processing instructions 73 Appendix 74 Pertinent standards 74
Introduction T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip galvanized steel strip is a hot-dip refined product with Zn, ZnMg or ZnFe coating on both sides. The corresponding short forms are Z, ZM and ZF. Hot-dip refining is based on a modified Sendzimir process. This is a high-integration manufacturing process that consists of the following main process steps: Cleaning the full-hard strip (dry cleaning and/or cleaning with easy reducing furnace atmosphere), recrystallizing annealing, coating by dip- ping into a fusion-liquid bath and adjustment of the thickness with air or nitrogen blow-off, finishing and/or straightening by stretching for the adjustment of mechanical properties, surface and flatness, post-treatment, inspection and marking. All these processes run in continuous operation mode with a continuous steel strip. These Technical Terms of Delivery apply to hot-dip galvanized strip made of p Mild steels for cold forming, p Structural steels and p High-strength steels suitable for cold forming. 5 These terms of delivery are to provide information to the customer on the production program of our hot-dip galvanizing lines at the Linz site and serve as a guideline for ordering and processing. In accor- dance with these Technical Terms of Delivery, hot-dip coated and galvanized steel strip complies with generally applicable guidelines as described in the pertinent standards. You will find a comparison of the standards in the Appendix. Market requirements have reached a degree of complexity with regard to applications that would far exceed the limitations of these Terms of Delivery if every detail were taken into account. For this rea- son we ask that you address any questions to your respective commercial or technical contact partner. They will ensure that you receive an adequate answer.
Hot-dip galvanized steel strip T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 with zinc coating Steel grades The following contains a general description of the available steel grades and their respective areas of application.The chemical constitution depends on the selected steel grade and is available upon request. The mechanical properties, the available coatings and surfaces can be found in the respec- tive tables. Mild steels for cold forming DX51D (machine crimping quality) is suitable for the production of simple shapes such as trapezoid shapes and corrugated iron sheets as well as for simple manual forming procedures. 6 DX52D (drawing quality) can be considered for complex sections, embossing and drawn components. DX53D (deep-drawing quality) is used for medium requirements on formability such as deep drawing. DX54D (special deep-drawing quality) is designed for the special requirements of formability and deep drawability. DX56D (special deep-drawing quality) is designed for the most demanding forming requirements. DX57D (extra special deep-drawing quality) was developed for extremely high forming behavior requirements, in particular for extreme deep- drawing strain and for the manufacturing of complicated press parts in rapid processing and highly automated press lines. The DX51D, DX52D, DX53D, DX54D, DX56D and DX57D steel grades are delivered according to their mechanical properties. The values for the mechanical properties apply for a period of p One month for steel grades DX51D and DX52D from the time they are made ready for dispatch p Six months for steel grades DX53D, DX54D, DX56D and DX57D from the time they are made ready for dispatch Alternatively, agreement can be made on specific material properties for the manufacture of a parti- cular component.
Mechanical properties 1) T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Mild steels for cold forming Steel grade 0.2% Yield Tensile strength Fracture elongation 4) Vertical Work hardening Zinc coating point 2) Rm A80 anisotropy 5) 6) exponent 5) group Rp 0.2 [MPa] [%] r n10 – 20 (UE) [MPa] min. min. min. DX51D - 270 – 500 22 - - Z 70 – Z 600 7) DX52D 140 – 300 3) 270 – 420 26 - - Z 70 – Z 600 7) DX53D 140 – 260 270 – 380 30 - - Z 70 – Z 600 7) DX54D 120 – 220 260 – 350 36 1.6 0.18 Z 70 – Z 275 DX56D 120 – 180 260 – 350 39 1.9 5) 0.21 Z 70 – Z 275 DX57D 120 – 170 260 – 350 41 2.1 5) 0.22 Z 70 – Z 275 1) Values transverse to rolling direction. 2) If the yield point is pronounced, the lower yield point ReL applies. 3) This value applies only to re-rolled products (MB and MC surfaces). 4) Minimum fracture elongation values are minimized by 2 units for product thicknesses of ≤ 0.7 mm. 7 5) Warranty values for r are minimized by 0.2 for product thicknesses of > 1.5 mm and for product thicknesses of > 2.0 mm by 0.4. 6) Values for r are minimized by 0.2 for product thicknesses of > 0.7 mm and n by 0.01. 7) Coating profiles above Z 275 available upon request.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 DX51D, DX52D Available dimensions mild steels for cold forming Ordered strip thickness (mm) 4.00 3.50 MC surface for automotive industry not possible. 3.00 8 2.50 2.00 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 DX53D Available dimensions mild steels for cold forming Ordered strip thickness (mm) 4.00 3.50 3.00 9 2.50 2.00 1.50 MC surface up to a maximum of 1.2 mm in 1.00 thickness not possible for automotive industry. 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 DX54D, DX56D, DX57D Available dimensions mild steels for cold forming Ordered strip thickness (mm) 4.00 3.50 3.00 10 2.50 2.00 1.50 MC surface up to a maximum of 1.5 mm in thickness not possible for automotive industry. 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
Freedom of flow lines T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 It may be necessary to reroll the products in order to avoid the formation of flow lines during cold rolling. The tendency toward the formation of flow lines can occur once again after some time, for which reason it is in the interest of the user to process the products as soon as possible. Freedom of flowing figures on MB and MC surfaces is maintained for the following duration after the material has been made ready for dispatch: p One month for steel grades DX51D and DX52D p Six months for steel grades DX53D, DX54D, DX56D and DX57D Coil break freedom Rerolling or straightening through product stretching may be necessary for specific coil break freedom requirements. The order must specify any coil break freedom requirement. 11
Structural steels T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Structural steels are supplied with guaranteed minimum yield strengths in steel grades S220GD through S350GD. These steel grades are suitable for all easy forming procedures such as crimping, edging and profiling. They are not, however, intended for stresses such as those caused by deep drawing. Depending on the strength class, the increased tendency toward elastic recovery during the adjustment of machinery must be taken into consideration. Formability may be diminished when these grades are stored for a longer period of time. Prompt processing after the material has been made ready for dispatch is in the interest of the customer. The order must specify any coil break freedom requirement. Mechanical properties 1) Structural steels Steel grade 0.2% Yield point 2) Tensile strength 3) Fracture elongation 4) Zinc coating Rp 0.2 Rm A80 group [MPa] [MPa] [%] min. min. 12 S220GD ≥ 220 300 20 Z 70 – Z 600 5) S250GD ≥ 250 330 19 Z 70 – Z 600 5) S280GD ≥ 280 360 18 Z 70 – Z 600 5) S320GD ≥ 320 390 17 Z 70 – Z 600 5) S350GD ≥ 350 420 16 Z 70 – Z 600 5) 1) Values longitudinal to rolling direction. 2) The upper yield point ReH applies when the yield point is pronounced. 3) A maximum range of 140 MPa can be calculated for the upper limit of tensile strength. 4) Minimum fracture elongation values are minimized by 2 units for product thicknesses of ≤ 0.7 mm. 5) Coating profiles above Z 275 available upon request.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 S220GD, S250GD, S280GD Available dimensions structural steels Ordered strip thickness (mm) 4.00 3.50 MC surface for automotive industry not possible. 3.00 13 2.50 2.00 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 S320GD Available dimensions structural steels Ordered strip thickness (mm) 4.00 3.50 MC surface for automotive industry not possible. 3.00 14 2.50 2.00 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 S350GD Available dimensions structural steels Ordered strip thickness (mm) 4.00 3.50 MC surface for automotive industry not possible. 3.00 15 2.50 2.00 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
High-strength steels for cold forming T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 In addition to the mild steels, high-strength steel grades with yield strengths ranging from 160 to 500 MPa are available and are suitable for cold forming with less forming stress as well as for very difficult forming procedures. Based on specifically coordinated steel analyses and production conditions, vari- ous series of steel grades are available that lend themselves, depending on the steel grade, to specific applications, particularly in the automotive industry. The higher yield point and the excellent forming properties provide a significant potential for weight reduction. The chemical composition of the substrate is adapted to the welding properties and is available upon request. The maximum concentrations of base material elements correspond to the limit values determined in EN 10346 for the respective grades (tables available in the Appendix). The guaranteed mechanical parameters listed in the following sections are applicable to tests in transverse direction to rolling. The mechanical parameters apply for a time period of three months for all steels with guaranteed bake-hardening effect and six months for all other high-strength steel grades from the time they are made ready for dispatch. Freedom of flow lines is guaranteed for this period of time for Surface Type C orders. This does not apply to micro-alloyed steels. 16 The yield strength increased by the heat effect (so-called bake-hardening effect) is determined in accordance with DIN EN 10325. It can generally be assumed that increasing yield stress and decreasing sheet thickness lead to a tendency towards necking, wrinkling and tears as a consequence of forming, which also leads to form inaccuracy as a result of elastic recovery. In contrast with mild steels, the forming conditions must be adjusted to the respective steel grade. If the steel grades listed in the following sections do not fulfill customer requirements, please send a material inquiry. Many high-strength steel grades are still being developed. More innovative develop- ments will make additional steel grades available that have not yet been included in these Technical Terms of Delivery. Some of these steel grades have already been included in these Technical Terms of Delivery for infor- mation purposes only. Such products are delivered following technical review upon request.
Micro-alloyed steels T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Refined micro-alloyed steels with a guaranteed yield strength of between 260 and 500 MPa cover the upper range of the conventional high-strength steel grade series and are suitable for moderate to medium forming stress. Steel grades HX260LAD through HX500LAD are generally based on the stability-increasing effect of micro-alloyed additions (niobium or niobium with titanium). Grain refinement, age hardening and the alloying of further strength-increasing elements, essentially manganese, are implemented in or- der to achieve the desired strength. The main areas of application for micro-alloyed steels are structural components in the automotive industry such as safety-related elements in the passenger compartment, side members or bumpers. Micro-alloyed steels are also excellently suited for the manufacturing of high-strength special sections. Upon special request, micro-alloyed hot-dip galvanized steel grades can be used as an alternative in guaranteeing the mechanical parameters in longitudinal direction. In this case the guaranteed range of yield strength correspondingly shifts to a lower range by around 20 MPa. The tensile strength values also change to lower values for longitudinal samples by around 10 MPa. The 17 guaranteed value for fracture elongation is correspondingly raised by 1%. Mechanical properties 1) Micro-alloyed steels Steel grade 0.2% Yield point 2) Tensile strength 3) Fracture elongation 4) Zinc coating Rp 0.2 Rm A80 group [MPa] [MPa] [%] min. min. HX260LAD 260 – 330 350 – 430 26 Z 70 – Z 600 4) HX300LAD 300 – 380 380 – 480 23 Z 70 – Z 600 4) HX340LAD 340 – 420 410 – 510 21 Z 70 – Z 600 4) HX380LAD 380 – 480 440 – 560 19 Z 70 – Z 600 4) HX420LAD 420 – 520 470 – 590 17 Z 70 – Z 600 4) HX460LAD 460 – 560 500 – 640 15 Z 70 – Z 275 HX500LAD 500 – 620 530 – 690 13 Z 70 – Z 275 1) Values transverse to rolling direction. 2) The lower yield point ReL applies when the yield point is pronounced. 3) Lower minimum values by two percent are permissible for thicknesses of ≤ 0.7 mm 4) Coating profiles above Z 275 available upon request.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HX260LAD, HX300LAD, HX340LAD Available dimensions micro-alloyed steels Ordered strip thickness (mm) 4.00 3.50 MC surface for automotive industry not possible. 3.00 18 2.50 2.00 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HX380LAD, HX420LAD Available dimensions micro-alloyed steels Ordered strip thickness (mm) 4.00 3.50 MC surface for automotive industry not possible. 3.00 19 2.50 2.00 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HX460LAD Available dimensions micro-alloyed steels Ordered strip thickness (mm) 4.00 3.50 3.00 20 2.50 2.00 MC surface for automotive industry not possible. 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
HX500LAD Available dimensions micro-alloyed steels Available dimensions upon request. 21 T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2
Bake-hardening steels T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 By fine-tuning alloy compositions and adapting process parameters it is possible to produce hot-dip coated bake-hardening steels that are characterized by their significant increase in yield strength in the course of paint baking (bake-hardening effect). This increase in yield strength in the series of steels from HX180BD to HX300BD is achieved by ensuring that a defined amount of carbon remains dissolved in the steel.This carbon is released during heat treatment in the course of paint baking, which leads to an increase in strength. The hot-dip coated bake-hardening steels are also characterized by a very high degree of forma- bility, which makes possible a wide range of applications in the manufacture of bodies in white. Depending on the forming stress, the entire range of yield strengths can be used in interior compo- nents for bodies in white. The HX180BD and HX220BD steel grades are also especially suitable for exterior bodies in white because the bake-hardening effect in these steels when compared to mild steels yields significantly improved dent resistance. Mechanical properties 1) Bake-hardening steels 22 Steel grade 0.2% Yield Tensile Fracture Vertical Work Bake- Zinc coating point 2) strength elongation 3) anisotropy hardening hardening group Rp 0.2 Rm A80 min. r exponent value BH2 [MPa] [MPa] [%] min. n10 – 20 (UE) [MPa] min. min. HX180BD 180 – 240 290 – 360 34 1.5 0.16 35 Z 70 – Z 200 HX220BD 220 – 280 320 – 400 32 1.2 0.15 35 Z 70 – Z 200 HX260BD 260 – 320 360 – 440 28 - - 35 Z 70 – Z 200 HX300BD 300 – 360 400 – 480 26 - - 35 Z 70 – Z 200 1) Values transverse to rolling direction. 2) The lower yield point ReL applies when the yield point is pronounced. 3) Lower minimum values by two percent are permissible for thicknesses of ≤ 0.7 mm.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HX180BD, HX220BD, HX260BD, HX300BD Available dimensions bake-hardening steels Ordered strip thickness (mm) 4.00 3.50 3.00 23 2.50 2.00 1.50 1.00 MC surface up to a maximum of 1.0 mm in thickness not possible for automotive industry. 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
High-strength IF steels T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip coated, higher-strength, interstitial-free steels are based on a vacuum-decarburized IF base material stabilized with Ti and/or Nb, which leads to an ideal condition for extremely difficult forming procedures with deep-drawing stresses. The adjustment of the required ranges of strength is carried out by alloying P and Mn in the course of solid-solution strengthening. This basic IF analysis lends this group of steel grades higher values of vertical anisotropy (r value) when compared to other steel grades of similar strength. This vertical anisotropy value is an important parameter for deep-drawing strain. The high r values in diagonal direction lead to a certain degree of isotropic behavior during the forming of this series of steel grades. The main area of application for high-strength interstitial-free steels is found in formed automotive components, such as in the interior wheel arch, side members that are difficult to form, or in bottom plates in the area of the tunnel. For this reason, profiling applications seem to be less sensible because no deep-drawing stress occurs. Mechanical properties 1) High-strength IF steels 24 Steel grade 0.2% Yield point Tensile strength Fracture Vertical Work hardening Zinc coating Rp 0.2 Rm elongation 2) anisotropy 3) exponent group [MPa] [MPa] A80 r n10 – 20 (UE) [%] min. min. min. HX160YD 160 – 220 300 – 360 37 1.9 0.20 Z 70 – Z 200 HX180YD 180 – 240 330 – 390 34 1.7 0.18 Z 70 – Z 200 HX220YD 220 – 280 340 – 420 32 1.5 0.17 Z 70 – Z 200 HX260YD 260 – 320 380 – 440 30 1.4 0.16 Z 70 – Z 200 HX300YD 300 – 360 390 – 470 27 1.3 0.15 Z 70 – Z 200 1) Values transverse to rolling direction. 2) Lower minimum values by two percent are permissible for thicknesses of ≤ 0.7 mm. 3) The guaranteed value is minimized by 0.2 units for product thicknesses > 1.5 mm.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HX160YD, HX180YD, HX220YD Available dimensions higher-strength IF steels Ordered strip thickness (mm) 4.00 3.50 3.00 25 2.50 2.00 1.50 1.00 MC surface up to a maximum of 1.0 mm in thickness not possible for automotive industry. 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HX260YD Available dimensions higher-strength IF steels Ordered strip thickness (mm) 4.00 3.50 3.00 26 2.50 2.00 1.50 1.00 MC surface up to a maximum of 1.0 mm in thickness not possible for automotive industry. 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
HX300YD Available dimensions higher-strength IF steels Available dimensions upon request. 27 T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2
Dual-phase steels T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Dual-phase steels consist of a multi-phase base material microstructure of which the main com- ponents are ferrite (80–90%) and martensite (10–20%). Other phases may be included in smaller amounts. The special characteristic of dual-phase steels is that particularly low yield ultimate ratios can be ob- tained with high ultimate tensile strengths. As related to the high level of tensile strength, high de- grees of fracture elongation and hardening exponents can also be achieved. Because of pronounced offset strain hardening, particularly at the beginning of forming, dual-phase steels are especially predestined for forming stress in the stretch forming area. An additional positive characteristic is the achievable bake-hardening effect, which leads to an additional increase in the yield strength after forming during paint baking. Based on the characteristic property profile of dual-phase steels, this series of steel grades is especially suitable for crash-relevant structural parts such as side members, crossmembers, and stiffeners for A, B or C columns. Dual-phase steels demonstrate special potential in significantly contributing to weight reduction as well as increased passive safety in automotive structures. Mechanical properties 1) 28 Dual-phase steels Steel grade 0.2% Yield Tensile strength Fracture Work hardening Bake-hardening Zinc coating point 2) Rm elongation 3) exponent value group Rp 0.2 [MPa] A80 n10 – 20 (UE) BH2 [MPa] [MPa] min. [%] min. min. min. HCT450X 260 – 340 450 27 0.16 30 Z 70 – Z 200 HCT500X 300 – 380 500 23 0.15 30 Z 70 – Z 200 HCT600X 340 – 420 600 20 0.14 30 Z 70 – Z 200 HCT780X 450 – 560 780 14 - 30 Z 70 – Z 200 HCT980X 4) 600 – 750 980 10 - 30 Z 70 – Z 200 1) Values transverse to rolling direction. 2) The lower yield point ReL applies when the yield point is pronounced. 3) Lower minimum values by two percent are permissible for thicknesses of ≤ 0.7 mm. 4) Available dimensions upon request.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HCT450X Available dimensions dual-phase steels Ordered strip thickness (mm) 4.00 3.50 3.00 29 2.50 2.00 MC surface for automotive industry available upon request. 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HCT500X Available dimensions dual-phase steels Ordered strip thickness (mm) 4.00 3.50 3.00 30 2.50 2.00 MC surface for automotive industry available upon request. 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HCT600X Available dimensions dual-phase steels Ordered strip thickness (mm) 4.00 3.50 3.00 31 2.50 2.00 MC surface for automotive industry available upon request. 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
HCT780X, HCT980X Available dimensions dual-phase steels Available dimensions upon request. 32 T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2
Complex-phase steels T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 The availability of complex-phase steel grades with increased yield point and minimum tensile strength is a meaningful addition to the dual-phase range of steels. These steel grades are defined with minimum yield strengths from 780 to 980 MPa. The microstructure of these advanced high- strength steels is characterized by the fact that the martensite particles are distributed in the soft ferrite matrix, whereas bainite phases can also occur in addition to the martensite. In comparison to the dual-phase steels, this series of steel grades is characterized by a higher yield strength at the same tensile strength and thus a higher yield-strength ratio and a somewhat lower possibility of guaranteeing certain levels of fracture elongation. The complex-phase steels are also characterized by pronounced work-hardening behavior, even though this is not as noticeable as it is with the dual-phase steels. The additional benefit that strength increases in the course of heat treat- ment during paint baking, remains as it does in dual phase steels. Structural parts with lower forming stress show higher yield strengths with this series of steel grades in comparison to the dual-phase grades. This can be compensated through a simpler component design aimed at increasing strength resulting from stronger deformation. Partially martensitic steels are predestined for high-strength special sections and safety-related structural components with lo- 33 wer forming stresses. This grade also lends itself well to the manufacture of foldable parts and roll-formed components. Mechanical properties 1) Complex-phase steels Steel grade 0.2% Yield point Tensile strength Fracture elongation Bake-hardening Zinc coating Rp 0.2 Rm A80 value group [MPa] [MPa] [%] BH2 [MPa] min. min. min. HCT780C 2) 600 – 750 780 10 30 Z 70 – Z 200 HCT980C 2) 800 – 950 980 6 30 Z 70 – Z 200 1) Values transverse to rolling direction. 2) Available dimensions upon request.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HCT780C, HCT980C Available dimensions complex-phase steels Available dimensions upon request. 34
TRIP steel T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 TRIP (transformation-induced plasticity) steels are comprised of a ferritic matrix (roughly 75%), bainite (approximately 10%) and metastable residual austenite (up to 15%). The hard phase (bainite) and stabi- lity of the austenite during forming influence the spectrum of mechanical properties. Transformation-induced plasticity means that the metastable “soft” austenite is transformed into “hard” martensite during plastic forming (deep drawing). This makes local constriction difficult and increases the values for uniform elongation. This is the basis for the well-known excellent formability of TRIP steels with high initial tensile strength of the respective basic strength. The increased bake-hardening effect achieved by temperature treatment additionally increases the potential weight savings. This se- ries of steel grades is available in two classes with minimum tensile strengths of 690 MPa and 780 MPa. TRIP steels with 980 MPa are currently under development and can be delivered upon request. TRIP steels are particularly suited to crash-relevant applications or safety parts with increased forming stress in the manufacturing process. Mechanical properties 1) TRIP steels 35 Steel grade 0.2% Yield point Tensile strength Fracture Work hardening Bake-hardening Zinc coating Rp 0.2 Rm elongation exponent value BH2 group [MPa] [MPa] A80 min. n10 – 20 (UE) [MPa] [MPa] min. min. [%] min. HCT600T 400 – 520 600 25 - 40 Z 70 – Z 200 HCT690T 430 – 550 690 23 0.18 40 Z 70 – Z 200 HCT780T 470 – 600 780 21 0.16 40 Z 70 – Z 200 1) Values transverse to rolling direction.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 HCT600T, HCT690T Available dimensions TRIP steels Ordered strip thickness (mm) 4.00 3.50 3.00 36 2.50 2.00 MC surface for automotive industry not possible. 1.50 1.00 0.50 0.00 700 800 900 1000 1100 1200 1300 1400 1500 1600 Ordered strip width (mm) The graphics refer to thickness values with symmetrical thickness tolerances. The maximum width is reduced by 20 mm if the width tolerance is limited or if the edge is cut. Please contact our sales departments for widths below 900 mm (production scheduling for center slitting and longitudinal slitting lines).
HCT780T Available dimensions TRIP steels Available dimensions upon request. 37 T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2
Zinc coating groups T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 The available zinc coatings and their respective minimum values are shown in the following table. The desired zinc coating group (corresponds to the zinc coating in g/m 2 on both sides) is specified in the order. Coating groups Zinc coating in g/m2 on both sides min. Zinc coating thickness in µm per side Zinc coating group Triple surface test Single surface test Typical value Area Z 100 100 85 7 5 – 12 Z 140 140 120 10 7 – 15 Z 200 200 170 14 10 – 20 Z 225 225 195 16 11 – 22 Z 275 275 235 20 15 – 27 Z 350 350 300 25 19 – 33 38 Z 450 450 385 32 24 – 42 Z 600 600 510 42 32 – 55 A zinc coating of 100 g/m 2 (on both sides) corresponds to a zinc layer thickness of approximately 7 µm per side. The respective possibilities for delivery, depending on the steel grade, are shown in the steel grade tables. The Z350–Z600 zinc coating group can only be delivered with an NA surface. Special coatings are available upon request in special cases only. Different zinc coating for each side (different degree of galvanization) can be delivered upon reque- st. In the event of differential galvanizing, in consequence of production, the surface of the side with the lesser amount of zinc coating may have a different appearance than the side with the greater amount of zinc coating. The zinc coating is monitored continuously by means of an x-ray fluorescent technique.
Surface T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Zinc coating surface The surface of the zinc coating is determined by the design, type and surface treatment. Hot-dip galvanized steel strip Zn with surface NA and chemically passivated is delivered in the event the order does not contain any additional information on the desired surface. Possible dimension-related limitations with respect to the surface can be found in the limit curves. The zinc coating does not include intentionally added lead concentrations (lead-free hot-dip galva- nized strip). Finally, with respect to the environmental compatibility of the product, this measure was implemented by voestalpine Stahl GmbH and excludes the delivery of hot-dip galvanized strip with distinctive spangle formation (large spangles). 39 Surface quality Normal quality (N) Zinc crystals occur in varying brightness and size, depending on prevalent galvanizing conditions. The usability of the product is not influenced by these crystals. The grade is delivered even if no pre- ferences regarding surface quality are specified. We reserve the right to ship rerolled material. Small spangle (M) The surface shows small to macroscopic non-visible spangles caused by targeted influence on soli- dification. The products may show a slightly different body structure on the surface from coil to coil and as well as in one coil. Delivery of slightly rerolled strip in surface type MA (explicitly not desired by the customer) must be specified in the order.
Surface type T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 There are three different surface types. Typical surface A Small pits, different spangle sizes, dark spots, stripe-shaped marks, and small passivation defects are acceptable on this type of surface. Straightening and bending fractures and zinc runoff waves may be visible. Improved surface B This type of surface is attained by rerolling. A small number of fractures in stretch forming direction, finishing imprints, scratches, impressions, spangle structures, zinc runoff waves and slight passiva- tion errors may occur on the inspected side. The uninspected side of the material must at least meet the requirements of Surface Type A. Best surface C This type of surface is also attained by rerolling. The inspected side does not negatively impact the uniform appearance of a paint coat. The other side of the material must at least meet the require- ments of Surface Type B. Surface Type C is available for delivery up to a maximum of 1.5 mm. 40 Roughness As a standard, Surface Types B and C are delivered with a medium roughness value ranging bet- ween 0.6 and 1.9 µm. Determination of the mean Ra roughness value is subject to a wavelength limit of 2.5 mm in accordance with EN 10049 (standard length of 12.5 mm). Where specially required, the delivery of limited roughness values may be specified. Special qualities include smooth, half mat or mat. Roughness Design Median roughness value Ra (µm) Standard 0.6 – 1.9 Special design: smooth 0.9 max. Special design: half-mat 0.6 – 1.4 Special design: mat 1.0 – 1.9 The desired quality must be specified in the order. Discussion of requirements with regard to surface appearance is recommended when a smooth surface has been selected. Smooth surface with glossy appearance (especially smooth) is subject to specification in the order.
Subsequent surface treatment T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip galvanized steel strip is delivered only with surface protection on account of the increased pro- pensity toward white rust. The following surface treatment procedures are usual: p Chromium-free passivated (C) p Oiled (O) p Chromium-free passivated and oiled (CO) Chromium-free passivated (C) To the extent not specifically agreed, hot-dip galvanized steel strip is delivered with normal sur- faces (NA) with small spangles (MA) and chromium-free passivated. Local discoloration caused by chromium-free passivation is permitted and does not negatively influence other quality properties. Chromium-free passivation may influence further surface treatments carried out by the customer, for example phosphating. Another surface treatment is recommended in such cases. Oiled (O) Surfaces MB and MC are usually delivered in oiled condition. The oil layer can be removed with suitable zinc-sparing degreasing agents. Depending on the intended treatment stress, two different 41 standard coatings can be ordered: slightly oiled as a temporary form of corrosion protection and as a forming aid for medium forming stress, oiled for very heavy forming stress. Although the oil is distributed evenly, a certain degree of oil will invariably spread across the length and width of the strip and some oil from heavily oiled strip will be shed from the surface during transportation and storage. This is technically unavoidable. Oil amounts Slightly oiled approx. 0.7 g/m2 per side Oiled approx. 1.2 g/m2 per side Chromium-free passivated and oiled (CO) This combination of surface treatment can be agreed upon where increased protection against white rust or oiling as a means to aid in forming is required.
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip galvanized steel strip in coils Thickness Width Maximum outside diameter Inner diameter Coil weight [mm] [mm] [mm] roughly [mm] 3) [t] max. ≥ 0.45 ≤ 3.5 ≥ 600 ≤ 800 2000 600 - ≥ 0.45 ≤ 3.5 > 800 1) < 900 1) 2000 600 - ≥ 0.45 ≤ 3.5 ≥ 900 ≤ 1600 2) 2000 600 32 1) Width range between > 800 and < 900 mm only upon request. 2) With limited width tolerance of 1,580 mm max. 3) Inner diameter of 500 mm upon request. 42
Inspection and Testing T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 The products can be delivered with or without any test of compliance with the requirements of these Technical Terms of Delivery and/or ordering standards. Material test certificates In the event a certificate is desired, one of the test certificates defined in EN 10204 is subject to agree- ment at the time of the order. Test unit Specific tests are restricted to a test unit of 20 tons or a portion of 20 tons of hot-dip galvanized steel strip of the same rolling unit. In the case of strip, a coil of more than 20 tons is considered as a test unit. Scope of testing: For each test unit, a series of tests is conducted to determine the following: 43 p Mechanical properties p Coating adhesion p Coating weight Sample taking Rolls from which samples are taken remain a constituent of the order. The right to select samples from sheets is reserved by the employee responsible for the delivery certificate. Performance of tests Substrate testing The tensile test is conducted in accordance with EN 10002-1 with samples of Form 2 (sample width w = 20 mm, initial measured length L0 = 80 mm). Samples of mild steels, high-strength steels suita- ble for cold forming and advanced high-strength steels are taken crosswise with respect to the di- rection of rolling at a distance of at least 50 mm from the product edges. Structural steel samples are taken in the longitudinal direction of rolling.
Zinc coating test T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 The zinc coating is generally determined in the course of a continuous and non-destructive test. The zinc coating is generally determined in the course of a continuous and non-destructive test. The following procedure is followed for special tests and in cases of arbitration. The samples for the gravimetric test of the zinc coating are taken across the width of the strip (see Figure 1). The samples can be round or square and must have a surface of at least 50 cm 2. The gravimetric test is carried out in accordance with the methods described in EN 10292, EN 10326, EN 10327 and EN 10336. The weight of the zinc coating is determined during this test by chemical dissolution of three samples ta- ken from an area of distribution across the width of the strip. The final value is the arithmetic mean derived from the three surface samples. The lowest value from the three surface samples is the value for the single surface sample. Figure 1: Gravimetric test 44 50 50 50 b/ b/ 2 2 Strip width B Zinc adhesion test Zinc coating adhesion is determined in a drop-ball impact test in accordance with SEP 1931/version 1991. Judgment is made based on a qualitative standard series, whereas the criterion of quality is based on proper workability according to the respective application. In cases of arbitration the zinc test is carried out by means of a bending test in accordance with EURONORM 12. The diameter of the bending block or bending roll is applied in accordance with Table 5. The bending angle is always 180°. The sample legs are pressed together in such a manner that the coating is not damaged. Repeat tests EN 10021 applies. Repeat tests on coils are carried out at a distance of at least one coil turn, however from 20 meters at the most from the end of the strip.
Processing information T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 The following brief instructions are intended to provide assistance in processing hot-dip galvanized steel strip. Our technical staff members are at your disposal to answer any of your questions. Forming Depending on the particular grade of hot-dip galvanized strip, it can be used for conventional for- ming processes such as edging, bending, curling, flanging, stamping, crimping, roll-profiling, stretch forming and deep drawing. The selection of materials depends on the demands on formability as well as the final geometry and function of the work piece. The zinc coating and the surface are adapted to the processing parameters. The properties of the zinc require that the drawing gap and the retraction radius are enlarged in certain cases as compared to uncoated thin sheet. Altered flow behavior ma- kes it necessary in some cases to adapt the hold-down force in forming processes. Joining 45 Conventional thermal and mechanical joining and gluing processes are used as connecting tech- niques, some of which, however, require adaptation of the processing parameters in order to take into account special physical and chemical properties of the coatings. Hot-dip galvanized steel strip is suitable for welding with common welding techniques. Special adjustment of the welding para- meters and electrodes is necessary for this material when resistance welding (spot, projection or stitch welding) is used. Thin zinc coatings simplify the welding process. The fumes generated during welding should be exhausted. Corrosion protection in the welding area is optimized by means of a suitable post-treatment process (such as zinc dust paint coating). Hot-dip galvanized sheet can be soft-soldered or brazed. A metallically clean surface is a precondition that can be achieved with sui- table fluxing agents. Proper filling of the joint is achieved with respective brazing metals. Corrosive fluxing agents are to be carefully washed off after soldering. Mechanical joining techniques such as screwing, riveting, crimping, flanging and clinching are not problematic and have the advantage that they preserve the surface and maintain the anticorrosive properties. It is necessary to consider possi- ble problems of contact corrosion when different materials are combined. The significance of metal gluing is increasing in combination with other methods of joining. High- strength connections are achievable with modern adhesives, even between oiled sheets. An examina- tion of the surface systems, possible treatment processes and the adhesives themselves is advisable.
Thermal rating T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Structural parts made of hot-dip galvanized steel strip can undergo long-term heat treatment up to roughly 200–250 °C. Temperature stress that lasts longer than this can lead to negative effects in the substrate and surface materials because of the diffusion reaction between the zinc coating and the substrate. Suitability for the application of coatings Hot-dip galvanized steel strip in all of its surface grades lends itself well to the application of organic coatings (such as paints or films). Surface MB or MC is the correct selection in the event of high or higher demands on a uniform surface appearance after coating. Proper pretreatment is required in order to achieve perfect adhesion. Surface phosphating pretreatment in the works provides an excel- lent base for the adhesion of conventional organic coatings as long as the surfaces are clean. 46
General notes T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Fretting corrosion Mutual friction between strips of hot-dip galvanized steel during transportation can cause dark spots on the zinc surface. These affect the appearance but do not adversely affect the quality of the corrosion protection. The tendency toward fretting corrosion can be minimized by oiling the hot-dip-galvanized steel strip. Darkening Hot-dip galvanized steel strip is generally intended for short-term processing. The degree of surface darkening may vary when these grades are stored for a longer period of time. This affects the appea- rance of the surface but does not adversely affect corrosion protection. 47 Formation of white rust When hot-dip galvanized steel strip is subjected to humidity for a longer period of time with reduced ventilation, a loose, mat gray to reddish material called white rust forms on the surface. Wide areas of the material are attacked particularly when condensation water forms and wetness occurs between the sheets or the coil layers. There is no danger of white rust forming as long as the coils are stored properly. Temperature changes during transportation and storage are critical.
Diagram used to determine danger of white rust caused by condensation T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Example 1: Strip temperature of 8 °C, room temperature of 21 °C, relative humidity of 55% danger of white rust. Example 2: Storage area of 19 °C, relative humidity of 50% minimum strip temperature of 11 °C required. Temperature (°C) Relative air humidity 40% 50% 60% 70% 100% 25 1 20 2 15 10 48 Area of condensation 5 0 -5 Flatness The strip is placed under tension when it is coiled. This tension causes deviations in the flatness of the strip when it is downcoiled. A suitable straightening machine must be used to achieve flat condition of the strip when delivered in coils. In some cases it improves the flatness of the material when paper in- serts are applied during coiling. These are marked by flags placed on the end face. If paper inserts are not desired or permitted, please specify this in the order.
Hot-dip galvanized steel strip with T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 zinc/iron-coating (Galvannealed) Hot-dip galvanized steel strip is a hot-dip refined product with Zn or ZnFe coating on both sides. The strip is subjected to heat treatment immediately after being galvanized. The zinc coating reacts with the substrate material and forms a ZnFe coating with approximately 8–12% Fe. This manufacturing process was the forerunner of the generally known product name GALVANNEALED (= GALVanized and ANNEALED). Steel grades All steel grades described in the section entitled Hot-dip galvanized steel strip are available with the exception of complex-phase and TRIP steels. The same guarantees apply to mechanical parameters, with the following exceptions: 49 p Statistical values lower by two units apply to the minimums for mild steels from grade DX54D and high-strength steels. p The guaranteed r values are decreased for all steel grades by 0.2. p The guaranteed n90 value for steel grades DX56D and DX57D is decreased by 0.01. The available dimensions are limited to a thickness range of 0.5 to 2.0 mm.
ZF coating groups T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Coating groups Zinc Coating in g/m2 on both sides min. Zinc coating thickness in µm per side ZF coating group Triple surface test Single surface test Typical value Area ZF 80 80 70 5.5 4 – 10 ZF 100 100 85 7.0 5 – 12 ZF 120 120 100 8.0 6 – 13 A ZF coating of 100 g/m2 (on both sides) corresponds to a ZF layer thickness of approximately 7 µm per side. 50
Surface T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip galvanized steel strip with a zinc/iron coating is delivered in Surface RA, RB and RC. Surface quality Surface quality R Hot-dip galvanized steel strip with a zinc/iron coating is characterized by a mat gray surface that is free of spangles. Surface type Typical surface A Small pits, dark spots, stripe-shaped marks, and small passivation defects are acceptable on this type of surface. Straightening and bending fractures and runoff waves may be visible. Improved surface B 51 This type of surface is attained by rerolling. The inspected side may be characterized by a small number of occurrences of fractures in stretch forming direction, finishing imprints, scratches, im- pressions and slight passivation errors. The uninspected side of the material must at least meet the requirements of Surface Type A. Best surface C This type of surface is also attained by rerolling. The inspected side does not negatively impact the uniform appearance of a paint coat. The other side of the material must at least meet the requirements of Surface Type B. Surface Type C is available for delivery up to 1.5 mm. Roughness As a standard, Surface types B and C are delivered with a medium roughness value ranging bet- ween 1.0 and 1.9 µm. Determination of the mean Ra roughness value is subject to a wavelength limit of 2.5 mm in accordance with EN 10049 (standard length of 12.5 mm).
Subsequent surface treatment T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip galvanized steel strip with a zinc/iron coating is normally delivered with an oiled (O) zinc/ iron coating. Galvannealed can be delivered upon request in chromium-free passivated (C) or chro- mium-free passivated and oiled (CO). Depending on the defined micro-topography, difficult forming stresses may make it necessary to increase the oil coating. Oil amounts Oiled approx. 1.2 g/m2 per side Heavily oiled approx. 1.6 g/m2 per side 52
Available dimensions T echnic a l T e rm s o f D e l i v e ry • H o t-di p g a l v a ni z e d s te e l s tri p • 0 2 /2 0 1 2 Hot-dip galvanized ZF hot-rolled strip in coils Thickness Width Maximum outside diameter Inner diameter Coil weight [mm] [mm] [mm] roughly [mm] [t] max. ≥ 0.50 1) ≤ 2.0 ≥ 600 ≤ 800 2000 600 - ≥ 0.50 1) ≤ 2.0 > 800 2) < 900 2) 2000 600 - ≥ 0.50 1) ≤ 2.0 ≥ 900 ≤ 1600 3) 2000 600 32 1 ) Thicknesses below 0.5 mm only upon request. 2) Width range between > 800 and < 900 mm only upon request. 3) With limited width tolerance of 1,580 mm max. 53
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