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75th International Conference on ENVIRONMENTAL DEGRADATION _________ of Materials in Nuclear Power Systems-Water Reactors Proceedings of the 15th International Conference on ENVIROMENTAL DEGRADATION of Materials in Nuclear Power Systems - Water Reactors sponsored by TMS (The Minerals, Metals & Materials Society) NACE International ANS (American Nuclear Society) co-sponsored by The Japan Institute of Metals Japan Society of Corrosion Engineering held August 7-11,2011 at the Cheyenne Mountain Resort, Colorado Springs, Colorado Editedby Jeremy T. Busby, Gabriel lIevbare, and Peter L. Andresen
Editors Jeremy T. Busby Gabriel Ilevbare Peter L. Andresen ISBN 978-3-319-48569-0 ISBN 978-3-319-48760-1 (eBook) DOI 10.1007/978-3-319-48760-1 Chemistry and Materials Science: Professional Copyright © 2016 by The Minerals, Metals, & Materials Society Published by Springer International Publishers, Switzerland, 2016 Reprint of the original edition published by lohn Wiley & Sons, Inc., 2011, 978-1-11813-241-8 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer International Publishing AG The registered company address is: Gewerbestrasse 11, 6330 Charn, Switzerland
TABLE OF CONTENTS 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors Preface ........................................................................................................................................................................ xxi Conference Organizing Committee/Program Committee .........................................................................................xxiii Session Chairs and Technical Reviewers .................................................................................................................. xxv Student Volunteers .................................................................................................................................................. xxvii Financial Sponsors .................................................................................................................................................... xxix 15th International Conference on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors Opening Session Overview of NRC Proactive Management of Materials Degradation (PMMD) Program ............................................. 1 C. Carpenter, A. Hull, and G. Oberson Questions & Answers .................................................................................................................................................. 11 Conditions for Long Term Operation of Nuclear Power Plants in Sweden ................................................................. 13 P. Ekström, K. Gott, and B. Brickstad Alloy 690 and Its Weld Metals I Current NRC Perspectives Concerning Primary Water Stress Corrosion Cracking .................................................... 25 D. Alley, and D. Dunn Questions & Answers .................................................................................................................................................. 39 Evaluation of the Susceptibility to SCC Initiation of Alloy 690 in Simulated PWR Primary Water .......................... 41 T. Couvant, and K. Tsutsumi Questions & Answers .................................................................................................................................................. 53 Role of Cavity Formation on Crack Growth of Cold-Worked Carbon Steel, TT 690 and MA 600 in High Temperature Water ...................................................................................................................................................... 55 K. Arioka, T. Miyamoto, T. Yamada, and T. Terachi Crack Growth Testing on Cold Worked Alloy 690 in Primary Water Environment ................................................... 71 D. Tice, S. Medway, N. Platts, and J. Stairmand Questions & Answers .................................................................................................................................................. 89 One-Dimensional Cold Rolling Effects on Stress Corrosion Crack Growth in Alloy 690 Tubing and Plate Materials ...................................................................................................................................................... 91 M. Toloczko, S. Bruemmer, and M. Olszta Questions & Answers ................................................................................................................................................ 107 v
Alloy 690 and Its Weld Metals II Cyclic and SCC Behavior of Alloy 690 HAZ in a PWR Environment ..................................................................... 109 B. Alexandreanu, Y. Chen, K. Natesan, and W. Shack Questions & Answers ................................................................................................................................................ 127 Stress Corrosion Crack Growth Rate Testing of Novel Composite Arrest Specimens.............................................. 131 D. Morton, J. Mullen, E. Plesko, J. Sutliff, and N. Lewis Questions & Answers ................................................................................................................................................ 147 Environmentally Assisted Crack Growth in Cold Worked Alloy 690TT in Primary Water at Low and High Temperatures ............................................................................................................................................................. 149 Q. Peng, T. Shoji, J. Hou, Y. Takeda, and T. Yonezawa Questions & Answers ................................................................................................................................................ 159 SCC of Alloy 690 and Its Weld Metals ..................................................................................................................... 161 P. Andresen, M. Morra, and K. Ahluwalia Questions & Answers ................................................................................................................................................ 177 SCC Behavior of Alloy 152 Weld in PWR Environment .......................................................................................... 179 B. Alexandreanu, Y. Chen, K. Natesan, and W. Shack Alloy 690 and Its Weld Metals III Effect of Hot Cracks on EAC Crack Initiation and Growth in Nickel-Base Alloy Weld Metals .............................. 197 H. Hanninen, A. Toivonen, A. Brederholm, T. Saukkonen, W. Karlsen, U. Ehrnsten, and P. Aaltonen Questions & Answers ................................................................................................................................................ 223 Stress Corrosion Crack Growth of Alloy 52M in Simulated PWR Primary Water ................................................... 225 M. Toloczko, S. Bruemmer, and M. Olszta Cyclic and SCC Behavior of Alloy 52M/182 Weld Overlay in a PWR Environment .............................................. 245 B. Alexandreanu, Y. Chen, Y. Yang, K. Natesan, and W. Shack SCC of High Cr Alloys in BWR Environments ........................................................................................................ 267 P. Andresen Questions & Answers ................................................................................................................................................ 299 High-Resolution Characterizations of Grain Boundary Damage and Stress Corrosion Crack Tips in Cold-Rolled Alloy 690 ................................................................................................................................................................... 301 S. Bruemmer, M. Olszta, M. Toloczko, and L. Thomas Alloy 690 and Its Weld Metals IV Research and Evaluation of Low Temperature Crack Propagation of Ni Base Alloys in Actual Plants ................... 315 K. Sakima, H. Suzuki, and H. Fujiwara Questions & Answers ................................................................................................................................................ 327 vi
Penetrative Internal Oxidation from Alloy 690 Surfaces and Stress Corrosion Crack Walls during Exposure to PWR Primary Water ........................................................................................................................................................... 331 M. Olszta, S. Bruemmer, D. Schreiber, and L. Thomas Predicting Chromium Depletion of Nickel-Base Alloys ........................................................................................... 343 Y. Yin, F. Zhu, R. Faulkner, E. Miller, P. Moreton, I. Armson, and B. Borradaile Questions & Answers ................................................................................................................................................ 355 BWR Initiation and Oxide Film Characterization I In-situ and Ex-situ Oxide Characterization by Synchrotron X-ray (SPring-8) in Non-Sensitized 316 Stainless Steel and High Temperature Water Combination ............................................................................................................... 357 T. Yonezawa, M. Watanabe, T. Shobu, and T. Shoji Questions & Answers ................................................................................................................................................ 369 High Resolution Electron Microscopy Study on Oxide Films Formed on Nickel-Base Alloys X-750, 182 and 82 in Simulated High Flow Velocity BWR Water Conditions ........................................................................................... 371 J. Chen, F. Lindberg, L. Belova, B. Forssgren, K. Gott, J. Lejon, and A. Jasiulevicius Questions & Answers ................................................................................................................................................ 385 Destructive Examinations on Divider Plates from Decommissioned Steam Generators Affected by Superficial Stress Corrosion Cracks ....................................................................................................................................................... 389 E. West, D. Morton, and N. Lewis Questions & Answers ................................................................................................................................................ 405 Non-linear Dynamics of the Morphology at the Oxide / Metal Interface of Austenitic Steels in Simulated Light Water Reactor Environments and Its Implications for SCC Initiation ...................................................................... 409 Y. Takeda, T. Sato, D. Yamauchi, T. Shoji, and A. Ohji Questions & Answers ................................................................................................................................................ 421 BWR Initiation and Oxide Film Characterization II The Effect of Cold Work on Microstructure and SCC Susceptibility in Simulated BWR Environment for Non- Sensitized Austenitic Stainless Steels ........................................................................................................................ 425 Y. Sakakibara, and G. Nakayama Behavior of Stress Corrosion Cracking for Type 316L Stainless Steel with Controlled Distribution of Surface Work Hardened Layer in Simulated Boiling Water Reactors Environment ........................................................................ 439 Y. Miura, Y. Miyahara, M. Sato, K. Kako, and J. Tani Questions & Answers ................................................................................................................................................ 451 Influence of Bulk and Surface Cold Work on Crack Initiation and Crack Growth of Austenitic Stainless Steels under Simulated BWR Environment ................................................................................................................................... 453 B. Devrient, R. Kilian, K. Küster, and M. Widera Questions & Answers ................................................................................................................................................ 469 vii
BWR Stainless Steels CGR I Effect of Nitrogen Addition in 304 L Stainless Steel on the IGSCC Crack Growth Rate in Simulated BWR Environment .............................................................................................................................................................. 471 S. Roychowdhury, V. Kain, and R. Prasad Questions & Answers ................................................................................................................................................ 487 Characterization of Type 304L Stainless Steel: Comparison of ASTM A262 Practice A and Analytical Electron Microscopy Techniques ............................................................................................................................................. 491 B. Miller, and M. Burke Questions & Answers ................................................................................................................................................ 501 BWR Stainless Steels CGR II The Effect of Grain Size on IGSCC in SS 316L in Simulated BWR Environment ................................................... 505 J. Stjärnsäter, B. Bengtsson, B. Forssgren, and H. Johansson Questions & Answers ................................................................................................................................................ 519 An Investigation into Stress Corrosion Cracking of Dissimilar Metal Welds with 304L Stainless Steel and Alloy 82 in High Temperature Pure Water ............................................................................................................................... 521 T. Yeh, G. Huang, M. Wang, and C. Tsai Questions & Answers ................................................................................................................................................ 531 Deformation Mode and Microstructure on Stress Corrosion Cracking Path and Kinetics in High Temperature Water Environments ............................................................................................................................................................. 533 Z. Lu, T. Shoji, S. Yamazaki, F. Meng, T. Dan, Y. Takeda, and K. Negishi Questions & Answers ................................................................................................................................................ 545 Corrosion Fatigue - BWR, PWR Effect of Static Load Hold Periods on the Corrosion Fatigue Behavior of Austenitic Stainless Steels in Simulated BWR Environments ................................................................................................................................................... 547 H. Seifert, S. Ritter, and H. Leber Effects of Material Composition on Corrosion Fatigue Crack Growth of Austenitic Stainless Steels in High Temperature Water .................................................................................................................................................... 561 N. Platts, D. Tice, K. Mottershead, L. McIntyre, and F. Scenini Questions & Answers ................................................................................................................................................ 581 Fatigue Limit and Hysteresis Behavior of Type 304l SS in Air and PWR Water, at 150°C and 300°C ................... 583 H. Solomon, C. Amzallag, R. DeLair, and A. Vallee NRC Research Activities on Environmentally-Assisted Fatigue............................................................................... 605 G. Stevens, and R. Tregoning Questions & Answers ................................................................................................................................................ 617 viii
Fuel and Fuel Related Materials I PWR Fuel Deposit Analysis at a B&W Plant with a 24-Month Fuel Cycle .............................................................. 621 M. Pop, L. Lamanna, R. Harne, and J. Riddle Questions & Answers ................................................................................................................................................ 627 Effect of DH Concentration on Crud Deposition on Heated Zircaloy-4 in Simulated PWR Primary Water ............ 633 H. Kawamura Questions & Answers ................................................................................................................................................ 645 Use of AREVA BWR CRUD Model To Study High Zinc Operation at a US Plant ................................................. 649 M. Pop, L. Lamanna, M. Bell, J. Riddle, and A. Hoornik Electrochemical Study of Pre- and Post-Transition Corrosion of Zr Alloys in PWR Coolant .................................. 655 J. Macak, R. Novotny, P. Sajdl, V. Renciukova, and V. Vrtílková AREVA Fuel Condition Index for a Pressurized Water Reactor ............................................................................... 665 M. Pop, M. Bell, and B. Lockamon Fuel and Fuel Related Materials II Structure and Thermodynamical Properties of Zirconium Hydrides from First-Principle ........................................ 671 J. Blomqvist, J. Olofsson, A. Alvarez, and C. Bjerken Questions & Answers ................................................................................................................................................ 681 Hydride Behavior in Zircaloy-4 during Thermomechanical Cycling ........................................................................ 683 K. Colas, A. Motta, M. Daymond, J. Almer, and Z. Cai Fuel and Fuel Related Materials III PWR-BWR Development of a Method for Studying the Influence of Stress State on the Iodine-Induced Stress Corrosion Cracking of Zirconium Alloys ................................................................................................................................... 689 N. Mozzani, E. Andrieu, Q. Auzoux, C. Blanc, and D. Leboulch Wear of Zircaloy-4 Grid Straps Due to Fretting and Periodic Impact with RV Internals Baffle Plates .................... 703 S. Davidsaver, S. Fyfitch, B. Friend, and J. Hyres Questions & Answers ................................................................................................................................................ 717 Alloy 718 and X-750 Microstructure and SCC of Alloy X-750 ................................................................................................................... 719 P. Andresen, M. Morra, B. Carter, and J. Flores-Preciado Questions & Answers ................................................................................................................................................ 741 Stress Corrosion Cracking and Crack Tip Characterization of Alloy X-750 in Boiling Water Reactor Environments ............................................................................................................................................... 745 J. Gibbs, R. Ballinger, J. Jackson, D. Isheim, and H. Hanninen Questions & Answers ................................................................................................................................................ 761 ix
SCC Properties of Modified Alloy 718 in BWR Plant .............................................................................................. 763 Y. Katayama, M. Tsubota, Y. Saito, N. Tanaka, and S. Tanaka Questions & Answers ................................................................................................................................................ 777 Influence of Chloride Ions as Contaminants on the Corrosion Behavior of Alloy 718 in Pool Water of Nuclear Power Plants .............................................................................................................................................................. 781 J. Hugues, C. Blanc, E. Andrieu, and J. Cloué BWR Low Alloy Steel Stress Corrosion Cracking Behavior near the Fusion Boundary of Dissimilar Weld Joint with Alloy 182 - A533B Low Alloy Steel ......................................................................................................................................................... 791 H. Abe, M. Ishizawa, and Y. Watanabe Questions & Answers ................................................................................................................................................ 803 Effect of Chloride on Environmentally Assisted Cracking of Low Alloy Steels in Oxygenated Hightemperature Water - General Corrosion......................................................................................................................................... 805 M. Herbst, A. Roth, E. Nowak, and U. Ilg Questions & Answers ................................................................................................................................................ 821 BWR Stainless Steels CGR III The Effect of Temperature on the Crack Growth Rate in Simulated BWR Environment ......................................... 827 J. Stjärnsäter, A. Jenssen, C. Jansson, K. Gott, B. Bengtsson, B. Forssgren, and H. Johansson Questions & Answers ................................................................................................................................................ 839 Effects of Temperature and Corrosion Potential on SCC .......................................................................................... 849 P. Andresen, and R. Seeman Questions & Answers ................................................................................................................................................ 879 Effect of Thermal Aging on SCC, Material Properties and Fracture Toughness of Stainless Steel Weld Metals ..... 883 T. Lucas, R. Ballinger, H. Hanninen, and T. Saukkonen Questions & Answers ................................................................................................................................................ 901 Flow Assisted Corrosion Flow Accelerated Corrosion of Carbon Steel in the Feedwater System of Pwr Plants - Behaviour of Welds and Weld Assemblies ................................................................................................................................................ 907 C. Mansour, E. Pavageau, A. Faucher, F. Inada, K. Yoneda, C. Miller, and J. Bretelle Questions & Answers ................................................................................................................................................ 921 Modelling Material Effects in Flow-Accelerated Corrosion ..................................................................................... 925 P. Phromwong, D. Lister, and S. Uchida x
PWR Oxide Films and Characterization 3D Atom-Probe Characterization of Stress and Cold-Work in Stress Corrosion Cracking of 304 Stainless Steel ... 939 K. Kruska, S. Lozano-Perez, T. Terachi, T. Yamada, D. Saxey, and G. Smith Questions & Answers ................................................................................................................................................ 947 Effect of Dissolved Hydrogen, Surface Conditions and Composition on the Electronic Properties of the Oxide Films Formed on Nickel-Base Alloys in PWR Primary Water ................................................................................. 953 A. Loucif, J. Petit, Y. Wouters, and P. Combrade Questions & Answers ................................................................................................................................................ 965 Influence of Primary Water Chemistry on Oxides Formed on Alloy 600 and Alloy690........................................... 967 T. Devine Characterizing Environmental Degradation in PWRs by 3D FIB Sequential Sectioning ......................................... 993 S. Lozano-Perez, N. Ni, K. Kruska, C. Grovenor, T. Terachi, and T. Yamada Questions & Answers .............................................................................................................................................. 1005 PWR Secondary Side/Balance of Plant I On the Microstructure of Alloy 600 SCC Cracks Observed by TEM on PWR SG Pulled Tubes and on Laboratory Specimens ............................................................................................................................................. 1007 L. Legras, F. Delabrouille, S. Miloudi, E. Fargeas, O. De Bouvier, and Y. Thebault Balance of Plant Corrosion Issues in Aging Nuclear Power Plants ......................................................................... 1023 G. Licina, and D. Dedhia Questions & Answers .............................................................................................................................................. 1035 Containment Liner Corrosion .................................................................................................................................. 1037 D. Dunn, A. Pulvirenti, and P. Klein Questions & Answers .............................................................................................................................................. 1049 PWR Secondary Side/Balance of Plant II Electrochemical Studies of Steam Generator Tube Degradation in the Presence of Thiosulphate .......................... 1051 L. Chi, and Y. Lu Questions & Answers .............................................................................................................................................. 1063 X-Ray Photoelectron Study of the Oxides Formed on Nickel Metal and Nickel-Chromium 20% Alloy Surfaces under Reducing and Oxidizing Potentials in Basic, Neutral and Acidic Solutions ................................................. 1065 S. McIntyre, B. Payne, and P. Keech Questions & Answers .............................................................................................................................................. 1083 xi
SCC of Alloy 82, 182 Welds I Interaction of Microstructure, Composition, and Cold Work on the Stress Corrosion Cracking of Alloy 82 Weld Metal .............................................................................................................................................................. 1087 D. Paraventi, and W. Moshier Questions & Answers .............................................................................................................................................. 1103 Stress Corrosion Cracking Behavior of Dissimilar Metal Weldments in High Temperature Water Environment.................................................................................................................................................. 1105 J. Huang, S. Jeng, J. Huang, R. Kuo, and M. Chiang Questions & Answers .............................................................................................................................................. 1123 SCC Crack Growth Rate of Alloy 82 in PWR Primary Water Conditions - Effect of a Thermal Treatment .......... 1127 M. Le Calvar, C. Guerre, C. Duhamel, M. Sennour, and J. Crepin SCC of Alloy 82, 182 Welds II Initiation of PWSCC of Weld Alloys 182 ............................................................................................................... 1141 T. Couvant, and F. Vaillant Questions & Answers .............................................................................................................................................. 1153 NRC/EPRI Welding Residual Stress Validation Program (Phase III) ..................................................................... 1155 M. Kerr, L. Fredette, H. Rathbun, and J. Broussard Questions & Answers .............................................................................................................................................. 1167 IASCC Stainless Steels CGR I Crack Growth Behavior of Irradiated Type 316 SS in Low Dissolved Oxygen Environment ................................ 1169 Y. Chen, B. Alexandreanu, Y. Yang, W. Shack, K. Natesan, E. Gruber, and A. Rao Questions & Answers .............................................................................................................................................. 1183 Stress Corrosion Crack Initiation Susceptibility of Irradiated Austenitic Stainless Steels ...................................... 1187 K. Stephenson, Y. Ashida, J. Busby, and G. Was Questions & Answers .............................................................................................................................................. 1201 Stress Corrosion Cracking Behavior of Type 304 Stainless Steel Irradiated under Different Neutron Dose Rates at JMTR ......................................................................................................................................................... 1203 Y. Kaji, K. Kondo, Y. Aoyagi, Y. Kato, T. Taguchi, F. Takada, J. Nakano, H. Ugachi, T. Tsukada, K. Takakura, and H. Sakamoto Questions & Answers .............................................................................................................................................. 1217 In-Pile Tests for IASCC Growth Behavior of Irradiated 316L Stainless Steel under Simulated BWR Condition in JMTR ................................................................................................................................................................... 1219 Y. Chimi, S. Kasahara, H. Ise, Y. Kawaguchi, J. Nakano, and Y. Nishiyama Crack Growth Rates of Irradiated Commercial Stainless Steels in BWR and PWR Environments ........................ 1229 A. Jenssen, J. Stjärnsäter, and R. Pathania xii
IASCC Stainless Steels CGR II The Key Factors Affecting Crack Growth Behavior of Neutron-Irradiated Austenitic Alloys ............................... 1241 Y. Ashida, A. Flick, P. Andresen, and G. Was Questions & Answers .............................................................................................................................................. 1255 Irradiation-Assisted Stress Corrosion Cracking of Austenitic Stainless Steel WWER Reactor Core Internals ...... 1257 A. Hojna, M. Ernestova, O. Hietanen, R. Korhonen, L. Hulinova, and F. Oszvald Questions & Answers .............................................................................................................................................. 1273 Slow Strain Rate Tensile Tests of Irradiated Austenitic Stainless Steels in Simulated PWR Environment ............ 1277 Y. Chen, B. Alexandreanu, W. Soppet, W. Shack, K. Natesan, and A. Rao Questions & Answers .............................................................................................................................................. 1291 Irradiation Assisted Stress Corrosion Cracking of Stainless Steels in a PWR Environment (A Combined Approach) ......................................................................................................................................... 1293 M. Le Millier, O. Calonne, J. Crépin, C. Duhamel, F. Gaslain, E. Héripré, O. Toader, and Y. Vidalenc A Preliminary Hybrid Model of Irradiation-Assisted Stress Corrosion Cracking of 300 Series Stainless Steels in PWR Primary Environments ................................................................................................................................... 1309 E. Eason, G. Ilevbare, and R. Pathania Questions & Answers .............................................................................................................................................. 1325 Irradiation Effects - General I Oxidation of a Proton-irradiated 316 Stainless Steel in Simulated BWR NWC Environment ................................ 1329 Z. Jiao, and G. Was Irradiation Creep and Irradiation Stress Relaxation of 316 and 304l Stainless Steels in Thermal and Fast Neutron Spectrum Reactors ..................................................................................................................................... 1339 J. Foster, and T. Karlsen Questions & Answers .............................................................................................................................................. 1351 Recent Insights on the Parametric Dependence of Irradiation Creep of Austenitic Stainless Steels ....................... 1355 F. Garner, E. Gilbert, and V. Neustroev Questions & Answers .............................................................................................................................................. 1369 Cluster Dynamics Prediction of the Microstructure Evolution of 300-series Austenitic Stainless Steel under Irradiation: Influence of Helium .............................................................................................................................. 1371 M. Zouari, L. Fournier, A. Barbu, and Y. Brechet Irradiation Effects on Deformation Role of Slip Behavior in the Irradiation Assisted Stress Corrosion Cracking in Austenitic Steels ......................... 1383 M. McMurtrey, and G. Was Questions & Answers .............................................................................................................................................. 1395 xiii
Effect of Environment and Prestrain on IASCC of Austenitic Stainless Steels ....................................................... 1397 W. Lai, Z. Jiao, and G. Was Questions & Answers .............................................................................................................................................. 1413 Influence of Localized Plasticity on IASCC Sensitivity of Austenitic Stainless Steels under PWR Primary Water ......................................................................................................................................................... 1417 S. Cisse, E. Andrieu, B. Tanguy, L. Laffont, M. Lafont, and C. Guerre Deformation Microstructures of 30 dpa AISI 304 Stainless Steel after Monotonic Tensile and Constant Load Autoclave Testing .................................................................................................................................................... 1429 W. Karlsen, J. Pakarinen, A. Toivonen, and U. Ehrnstén Questions & Answers .............................................................................................................................................. 1445 PWR Alloy 600 Oxidation and Mechanisms I Degradation of Grain Boundary Strength by Oxidation in Alloy 600 ..................................................................... 1447 K. Fujii, T. Miura, H. Nishioka, and K. Fukuya Questions & Answers .............................................................................................................................................. 1459 Evaluation of the Oxygen Diffusion Coefficient in Nickel-Base Alloys ................................................................. 1463 H. Nam, J. Yoon, J. Kim, I. Hwang, and K. Lee Stress Corrosion Cracking of Alloy 600 in PWR Primary Water: Influence of Chromium, Oxygen and Hydrogen Diffusion .......................................................................................................................................... 1477 C. Guerre, P. Laghoutaris, J. Chêne, L. Marchetti, R. Molins, C. Duhamel, and M. Sennour Questions & Answers .............................................................................................................................................. 1489 Grain Boundary Oxidation and Embrittlement Prior to Crack Initiation in Alloy 600 in PWR Primary Water ...... 1491 L. Fournier, O. Calonne, P. Combrade, P. Scott, P. Chou, and R. Pathania PWR Alloy 600 Oxidation and Mechanisms II Electron Microscopy Characterizations and Atom Probe Tomography of Intergranular Attack in Alloy 600 Exposed to PWR Primary Water ............................................................................................................................. 1503 M. Olszta, D. Schreiber, L. Thomas, and S. Bruemmer Questions & Answers .............................................................................................................................................. 1517 Grain Boundary Oxidation and Stress Corrosion Cracking in Nickel-base Alloys Strained in Supercritical Water .................................................................................................................................................. 1519 T. Moss, M. Olszta, W. Grant, and G. Was Questions & Answers .............................................................................................................................................. 1531 Quantitative Micro-nano (QMN) Approach to SCC Mechanism and Prediction-Starting a Third Meeting ........... 1535 R. Staehle Questions & Answers .............................................................................................................................................. 1627 xiv
PWR Alloy 600 SCC I Strain Path Effect on IGSCC Initiation and Oxidation of Alloy 182 Exposed to PWR Primary Water .................. 1631 T. Couvant, L. Legras, T. Ghys, P. Gambier, N. Huin, and G. Ilevbare Questions & Answers .............................................................................................................................................. 1645 Experimental Study of Short Crack Coalescence in Nickel-Base Alloys In PWR Primary Water ......................... 1647 O. Calonne, L. Fournier, P. Combrade, P. Scott, and P. Chou Questions & Answers .............................................................................................................................................. 1665 Mechanistic Study on PWSCC of Ni-Based Alloys Using Hump-SSRT Tests under Dry Hydrogen Gas Environment, Simulated Primary Water and Rapid Straining Electrode Test in Simulated Primary Water ........... 1667 N. Totsuka, T. Terachi, and K. Takakura Questions & Answers .............................................................................................................................................. 1683 Crystallographical Characterization of Initiation of Intergranular Stress Corrosion Cracking of Alloy 600 in PWR Environment ............................................................................................................................................... 1685 S. Fujimoto, M. Mochizuki, Y. Morita, Y. Mikami, H. Tsuchiya, and K. Nishimoto Questions & Answers .............................................................................................................................................. 1697 Environmental Effects on PWSCC Initiation and Propagation in Alloy 600 .......................................................... 1699 A. Molander, K. Norring, P. Andersson, and P. Efsing Questions & Answers .............................................................................................................................................. 1713 PWR Alloy 600 SCC II Probabilistic Environmentally-Assisted Cracking Modeling for Primary Water Stress Corrosion Cracking of Alloy 600 ........................................................................................................................................................................... 1715 T. Lee, J. Yoon, H. Nam, and I. Hwang Questions & Answers .............................................................................................................................................. 1729 The Role of Lattice Curvature on the SCC Susceptibility of Alloy 600 .................................................................. 1731 F. Leonard, F. Di Gioacchino, R. Cottis, F. Vaillant, J. Quinta da Fonseca, F. Carrette, and G. Ilevbare Questions & Answers .............................................................................................................................................. 1745 PWSCC Susceptibility in Heat-Affected Zones of Alloy 600 ................................................................................. 1747 T. Couvant, T. Brossier, and C. Cossange Questions & Answers .............................................................................................................................................. 1757 Quantitative Residual Strain Analyses on Strain Hardened Nickel Based Alloy .................................................... 1759 T. Yonezawa, T. Maeguchi, T. Goto, and H. Juan The Study of Stress Corrosion Cracking on Alloy 600 C-Ring Samples by Polychromatic X-Ray Microdiffraction....................................................................................................................................................... 1773 S. McIntyre, J. Chao, M. Suominen Fuller, R. Newman, A. Carcea, M. Kunz, and N. Tamura Questions & Answers .............................................................................................................................................. 1783 xv
PWR Degradation Management Proposed Coordinated U.S. PWR Reactor Vessel Surveillance Program: An Updated Summary Including Program Optimization ............................................................................................................................................. 1787 R. Hosler, S. Davidsaver, T. Hardin, D. Weakland, and G. Troyer Developing PWR Aging-Management Strategies for Reactor Vessel Internals ...................................................... 1801 S. Davidsaver, S. Fyfitch, and H. Xu Development of the Extremely Low Probability of Rupture (xLPR) Code ............................................................. 1811 D. Rudland, and C. Harrington Questions & Answers .............................................................................................................................................. 1827 Databases of Operationally Induced Damage .......................................................................................................... 1829 K. Gott Questions & Answers .............................................................................................................................................. 1843 PWR Water Chemistry and Mitigation Introduction to a New Real-Time Water Chemistry Measurement System ............................................................. 1847 J. Yeon, K. Song, and M. Yun Questions & Answers .............................................................................................................................................. 1855 Comparison of DBU, NH3, DMA, ETA, and Morpholine Interactions with Ferrous Chloride Solution and Carbon Steel Surfaces ....................................................................................................................................... 1859 S. Nasrazadani, A. Reid, J. Stevens, R. Theimer, and B. Fellers Questions & Answers .............................................................................................................................................. 1877 Role of Dissolved Hydrogen in Water in Corrosion of Alloy 600 in High Temperature Water ............................. 1879 Q. Peng, T. Shoji, J. Hou, K. Sakaguchi, and Y. Takeda Questions & Answers .............................................................................................................................................. 1889 Quantifying the Benefit of Chemical Mitigation of PWSCC via Zinc Addition or Hydrogen Optimization .......... 1893 C. Marks, M. Dumouchel, R. Reid, and G. White Questions & Answers .............................................................................................................................................. 1907 Super Critical Water Computational Thermodynamics for Interpreting Oxidation of Structural Materials in Supercritical Water ......... 1909 L. Tan, Y. Yang, T. Allen, and J. Busby Questions & Answers .............................................................................................................................................. 1919 Stress Corrosion Cracking of Austenitic Alloys in Supercritical Water .................................................................. 1923 G. Cao, V. Firouzdor, and T. Allen Questions & Answers .............................................................................................................................................. 1937 xvi
Comparison of the Oxidation Behavior of the 14CrODS Alloy in Steam and Supercritical Water ........................ 1939 J. Bischoff, and A. Motta Questions & Answers .............................................................................................................................................. 1949 Grain Boundary Engineering and Air Oxidation Behavior of Alloy 690 ................................................................ 1951 P. Xu, L. Zhao, K. Sridharan, and T. Allen Questions & Answers .............................................................................................................................................. 1965 BWR Water Chemistry and Mitigation I Developments in SCC Mitigation by Electrocatalysis ............................................................................................. 1967 P. Andresen, and Y. Kim Questions & Answers .............................................................................................................................................. 1989 Use of Noble Metal Nanoparticle for SCC Mitigation in BWRs............................................................................. 1993 Y. Kim, P. Andresen, and S. Hettiarachchi Questions & Answers .............................................................................................................................................. 2003 The Influence of Minor Additions of Platinum Group Metals on Stress Corrosion Cracking in Austenitic Stainless Steels ........................................................................................................................................................ 2005 K. Govender, F. Scenini, S. Lyon, O. Necib, and A. Sherry Questions & Answers .............................................................................................................................................. 2021 The Effect of On-Line Noble Metal Addition on the Shut Down Dose Rates of Boiling Water Reactors .............. 2023 R. Cowan, J. Varela, and S. Garcia Questions & Answers .............................................................................................................................................. 2037 Effects of Hydrogen on SCC Growth Rate of Ni Alloys in BWR Water ................................................................ 2039 P. Andresen, and P. Chou Technical Basis for Water Chemistry Control of IGSCC in Boiling Water Reactors ............................................. 2061 B. Gordon, and S. Garcia Questions & Answers .............................................................................................................................................. 2077 BWR Water Chemistry and Mitigation II Water Chemistry in the Primary Coolant Circuit of a Boiling Water Reactor during Startup Operations .............. 2079 T. Yeh, and M. Wang Simulation of Water Radiolysis by Sonochemistry: Effects on the Electrochemical Behavior of a Stainless Steel ....................................................................................................................................................... 2091 O. Lavigne, Y. Takeda, and T. Shoji Questions & Answers .............................................................................................................................................. 2101 Protective Insulated Coating for SCC Mitigation in BWRs .................................................................................... 2103 Y. Kim, and P. Andresen Questions & Answers .............................................................................................................................................. 2117 xvii
Influence of Treating Temperature on the Deposition of TiO2 on Type 304 Stainless Steels for Corrosion Mitigation in High Temperature Pure Water ........................................................................................................... 2121 T. Yeh, Y. Huang, and C. Tsai Questions & Answers .............................................................................................................................................. 2135 Irradiation Effects - General II Irradiation Microstructure of Austenitic Steels and Cast Steels Irradiated in the BOR-60 Reactor at 320°C ......... 2137 Y. Yang, Y. Chen, Y. Huang, T. Allen, and A. Rao Questions & Answers .............................................................................................................................................. 2149 PWR Field Experience I Laboratory Stress Corrosion Cracking Propagation in a Superficial Cold-Worked Layer in SG Divider Plates in Alloy 600 ............................................................................................................................................................. 2151 F. Vaillant, T. Couvant, S. Miloudi, Y. Thebault, D. Deforge, E. Lemaire, C. Leseigneur, and P. Le-Delliou Destructive Examinations on Divider Plates from Decommissionned Steam Generators Affectined by Superficial Stress Corrosion Cracks ........................................................................................................................ 2171 S. Miloudi, E. Firmin, D. Deforge, F. Vaillant, and E. Lemaire Questions & Answers .............................................................................................................................................. 2185 Investigations on Core Basket Bolts from a VVER 440 Power Plant ..................................................................... 2189 U. Ehrnsten, P. Kytömäki, and O. Hietanen Questions & Answers .............................................................................................................................................. 2201 Laboratory Analysis of a Reactor Coolant Pump Seal ............................................................................................ 2207 M. Sullivan, and J. Hyres PWSCC of Thermocoax Pressurizer Heaters in Austenitic Stainless Steel and Remedial Actions to Preventing SCC ................................................................................................................................................... 2219 J. Champredonde, Y. Thebault, P. Moulart, T. Couvant, K. Dubourgnoux, Y. Neau, J. Fageon, D. Lecharpentier, A. Breuil, and V. Derouet PWR Field Experience II Residual Stress Measurement and the Effect of Heat Treatment in Cladded Control Rod Drive Specimens ......... 2231 E. Kingston, A. Bowman, J. Katsuyama, M. Udagawa, and K. Onizawa Questions & Answers .............................................................................................................................................. 2245 Detailed Root Cause Analysis of SG Tube ODSCC Indications within the Tube Sheets of NPP Biblis Unit A .... 2247 R. Kilian, J. Beck, H. Lang, T. Schönherr, and M. Widera Questions & Answers .............................................................................................................................................. 2261 Laboratory Investigation of a Leaking Type 316 Socket Weld in a Boron Injection Tank Sampling Line ............. 2263 H. Xu, S. Fyfitch, R. Hosler, and J. Hyres xviii
Pressure Tests on SG Pulled Tubes at TSP Level .................................................................................................... 2275 M. Boccanfuso, and C. Mathon Implications of Steam Generator Fouling on the Degradation of Thermal and Material Performance ................... 2287 C. Turner Questions & Answers .............................................................................................................................................. 2301 Key Issues Related to Corrosion Protection of Brackish Water and Sea Water Bearing Components in Cooling Water Systems ......................................................................................................................................................... 2303 E. Nowak, B. Bengtsson, B. Forssgren, B. Hall, and E. Johansson PWR Initiation and CGR Stainless Steels I Understanding the Limits of Lattice Orientation Data Analysis in Environmental Degradation Studies ................ 2321 F. Di Gioacchino, J. Quinta da Fonseca, D. Wright, and F. Scenini Questions & Answers .............................................................................................................................................. 2333 A Microstructural Investigation on the Effect of Cold Work on Environmentally Assisted Cracking of Austenitic Stainless Steels ....................................................................................................................................... 2335 D. Wright, F. Di Gioacchino, J. Quinta da Fonseca, F. Scenini, S. Nouraei, K. Mottershead, and D. Tice Questions & Answers .............................................................................................................................................. 2347 Plastic Strain and Residual Stress Distributions in an AISI 304 Stainless Steel BWR Pipe Weld .......................... 2351 T. Saukkonen, M. Aalto, I. Virkkunen, U. Ehrnsten, and H. Hanninen Assessment of Lean Grade Duplex Stainless Steels for Nuclear Power Applications............................................. 2369 G. Young, J. Tucker, D. Eno, N. Lewis, E. Plesko, and P. Sander PWR Initiation and CGR Stainless Steels II Effects of Thermo-Mechanical Treatments on Deformation Behavior and IGSCC Susceptibility of Stainless Steels in PWR Primary Water Chemistry ................................................................................................................ 2381 S. Nouraei, D. Tice, K. Mottershead, and D. Wright Questions & Answers .............................................................................................................................................. 2403 Previously Unpublished Manuscripts from the 14th International Conference on Environmental Degradation of Materials in Nuclear Power Systems, 23-29th August 2009, Virginia Beach, VA, USA SCC Initiation Testing of Alloy 600 in High Temperature Water ........................................................................... 2407 R. Etien, E. Richey, D. Morton, and J. Eager The Effects of Deaerated Water on the Toughness of Nickel-based Alloys ............................................................ 2419 E. Richey, and G. Young Physical Metallurgy, Weldability, and In-service Performance of Nickel-chromium Filler Metals Used in Nuclear Power Systems ........................................................................................................................................... 2431 G. Young, R. Etien, M. Hackett, J. Tucker, and T. Capobianco xix
Author Index ............................................................................................................................................................ 2443 Subject Index ........................................................................................................................................................... 2447 xx
Preface The production of electricity from light water nuclear reactors occupies a central role in meeting worldwide energy requirements. The importance of nuclear power is expected to increase as worldwide demand for energy increases because of relatively cheap electricity generating cost, and near zero carbon emissions. If nuclear power is going to continue making a contribution to worldwide energy demands, power plants must be operated in a safe and cost effective nature. Central to these safety and reliability goals is effective materials degradation management. Effective materials management must include both the maintenance of existing plants and in the choice and use of materials in the new plants. 3DUWLFXODUDWWHQWLRQPXVWEHSDLGWRWKHFXUUHQWO\DJLQJZRUOGZLGHÀHHWRIUHDFWRUV DQGSRZHUSODQWVDVWKHVHFRQVWLWXWHDVLJQL¿FDQWSRUWLRQRIWKHZRUOG¶VQXFOHDU power generating assets. As at January 2011, 174 of the 442 reactors currently in operation worldwide (representing ~39%) are 30 years or older, compared with only 84 (representing 19%) 20 years or younger. Many of these aging plants are being considered for extended service to 60 or even 80 years. Materials degradation issues sensitive to long term operation therefore need to be part of current proactive asset management plans. The goals of any good materials degradation management plan must include the following elements: Maximization of the Operating Life and Reliability of Water Passive Long-lived Components to Support Current and Extended Operations Prediction of Component Degradation Mechanisms and Their Rate of Occurrence to Estimate Inspection Frequency and the End of Component Useful Life Anticipation of Impacts on Plant Operations Related to Implementing Materials Management Activities Performance of Proactive Fundamental Research to Understand the Physical Bases of Degradation Mechanisms and Development of Physically Based Models, and Where Possible Development of Mitigation Techniques to Retard or Prevent Degradation Consistent with its tradition since inception, this 15th Edition of the International Conference on Materials Degradation in Light Water Reactors focuses on subject DUHDVFULWLFDOWRWKHVDIHDQGHI¿FLHQWUXQQLQJRIQXFOHDUUHDFWRUV\VWHPVWKURXJK WKH H[FKDQJH DQG GLVFXVVLRQ RI UHVHDUFK UHVXOWV DV ZHOO DV ¿HOG RSHUDWLQJ DQG management experience. These exchanges and discussions contribute to all four elements listed above for effective asset management. xxi
This Conference featured the presentation of about 150 papers, spread over 40 sessions in about 20 different areas relevant to LWRs including SCC of nickel alloys and stainless steels, fuel and fuel related materials, corrosion fatigue, ÀRZDVVLVWHGFRUURVLRQ,$6&&DQGLUUDGLDWLRQHIIHFWVVXSHUFULWLFDOZDWHUDQG materials degradation management. The conference was attended by over 200 scientists and engineers from 17 countries, representing power plant operators, NSSS vendors, regulators, national laboratories, research institutes, universities, DQGRWKHURUJDQL]DWLRQVDI¿OLDWHGZLWKWKHQXFOHDUDQGQXFOHDUVHUYLFHLQGXVWULHV The organizers recognize the help of a dedicated group of individuals who made this 15th Edition of the Conference a success and these proceedings possible. The Program Committee, Session Chairs and Technical Reviewers listed below played VLJQL¿FDQWUROHVLQRUJDQL]LQJWKHVHVVLRQVFRQGXFWLQJSDSHUUHYLHZVDQGFKHFNV and facilitated near-perfect technical presentation sessions. These activities UHTXLUHGDVLJQL¿FDQWFRPPLWPHQWRIWKHLUWLPHDQGWKH\DUHJUHDWO\DSSUHFLDWHG The Organizers are thankful to their respective employers for making them available for participating in planning, organizing and serving at the conference. The assistance of the University of Michigan students who facilitated the question-and-answer element in each session is acknowledged. Felicia Bellamy- Roseberry and Nancy Ward, both of Oak Ridge National Laboratory, USA are acknowledged for their assistance in generating electronic copies of the question and answer sheets. We thank The Minerals, Metals, and Materials Society (TMS) for their assistance with conference planning, paper review, and publication of these proceedings. Special thanks go to the Conference General Chair, Jeremy Busby of Oak Ridge National Laboratory, and the Assistant Technical Program Chair Peter Andresen of GE Global Research Center for their tireless efforts in ensuring the success of this conference. Gabriel Ilevbare Technical Program Chair xxii
Conference Organizing Committee Conference General Chair: Jeremy Busby, Oak Ridge National Laboratory, USA Technical Program Chair: Gabriel Ilevbare, Electric Power Research Institute, USA Assistant Technical Program Chair: Peter Andresen, GE Global Research Center, USA Program Committee Todd Allen, University of Wisconsin, USA Koji Arioka, Institute of Nuclear Safety System, Inc, Japan Peter Andresen, GE Global Research Center, USA Steve Bruemmer3DFL¿F1RUWKZHVW1DWLRQDO/DERUDWRU\86$ Jeremy Busby, Oak Ridge National Lab, USA Gene Carpenter, U.S. Nuclear Regulatory Commission, USA Pål Efsing, Ringhals AB, Sweden Ulla Ehrnsten, VTT Technical Research Centre, Finland 6WHYH)\¿WFK, Areva, USA Barry Gordon, Structural Integrity Associates, Inc, USA Ron Horn, GE Power and Water, USA Il Soon Hwang, Seoul National University, Korea Gabriel Ilevbare, Electric Power Research Institute, USA Rich Jacko, Westinghouse Electric Corp., USA Christer Jansson, Vattenfall Power Consultant AB, Sweden Anders Jenssen, Studsvik AB, Sweden Renate Kilian, Areva GmbH, Germany Hong Pyo Kim, Korea Atomic Energy Research Institute, Korea Peter King, Babcock & Wilcox, Canada Bill Mills, Bechtel Bettis Inc., USA Dave Morton, Bechtel KAPL, USA Larry Nelson, JLN Consulting, USA Hans-Peter Seifert, Paul Scherrer Institute, Switzerland Robert Tapping, Atomic Energy of Canada Limited, Chalk River Nuclear Labs, Canada Francois Vaillant, Electricité de France, France Gary Was, University of Michigan, USA TK Yeh, National Tsing Hua University, Taiwan Toshio Yonezawa, Tohoku University, Japan xxiii
Session Chairs and Technical Reviewers Al Ahluwalia, Electric Power Research Institute, USA Bogdan Alexandreanu, Argonne National Laboratory, USA Todd Allen, University of Wisconsin, USA David Alley, U.S. Nuclear Regulatory Commission, USA Peter Andresen, GE Global Research Center, USA Koji Arioka, Institute of Nuclear Safety System, Inc, Japan Ian Armson, Rolls Royce, UK Jean-Luc Bretelle, Electricité de France, France Stephen Bruemmer,3DFL¿F1RUWKZHVW1DWLRQDO/DERUDWRU\86$ Jeremy Busby, Oak Ridge National Laboratory, USA Art Byers, Westinghouse, USA Gene Carpenter, U.S. Nuclear Regulatory Commission, USA Bob Carter, Electric Power Research Institute, USA Yiren Chen, Argonne National Laboratory, USA Bo Cheng, Electric Power Research Institute, USA Peter Chou, Electric Power Research Institute, USA Thierry Couvant, Electricité de France, France Al Csontos, U.S. Nuclear Regulatory Commission, USA Damien Daforge, Electricité de France, France Anne Demma, Electric Power Research Institute, USA Darell Dunn, U.S. Nuclear Regulatory Commission, USA Kurt Edsinger, Electric Power Research Institute, USA Ernest Eason, Modeling & Computing Services, LLC, USA Pål Efsing, Ringhals AB, Sweden Ulla Ehrnsten, VTT Technical Research Centre, Finland Lionel Fournier, Areva NP SAS, France Katsuhiko Fujii, Institute of Nuclear Safety System, Inc, Japan Frank Garner, Radiation Effects Consulting LLC, USA Jeff Gorman, Dominion Engineering, USA Karen Gott, MatSafe AB, Sweden Catherine Guerre&RPPLVVDULDWjO¶eQHUJLH$WRPLTXH)UDQFH Hannu Hanninen, Helsinki University of Technology, Finland Ron Horn, GE Power and Water, USA James Hyres, Babcock and Wilcox, USA Gabriel Ilevbare, Electric Power Research Institute, USA John Jackson, Idaho National Laboratory, USA Anders Jenssen, Studsvik AB, Sweden xxv
Session Chairs and Technical Reviewers (continued) Wade Karlsen, VTT Technical Research Centre, Finland Matthew Kerr, U.S. Nuclear Regulatory Commission, USA Renate Kilian, Areva GmbH, Germany Young Kim, GE Global Research Center, USA Laurent Legras, Electricité de France, France Tiangan Lian, Electric Power Research Institute, USA George Licina, Structural Integrity Inc, USA Derek Lister, University of New Brunswick, Canada Carine Mansour, Electricité de France, France David Morton, Bechtel KAPL, USA Larry Nelson, JLN Consulting, USA Roger Newman, University of Toronto, Canada Samaneh Nouraei, Serco, UK Matt Olszta3DFL¿F1RUWKZHVW1DWLRQDO/DERUDWRU\86$ Denise Paraventi, Bechtel Bettis, USA Raj Pathania, Electric Power Research Institute, USA Qunjia Peng, Institute of Metals Research, China Richard Reid, Electric Power Research Institute, USA Raul Rebak, GE Global Research Center, USA In Hyoung Rhee, Soon Chun Hyang University, Korea Hans-Peter Seifert, Paul Scherrer Institute, Switzerland Tetsuo Shoji, Tohoku University, Japan Harvey Solomon, Retired GE GRC, currently Solomon Metallurgical Consulting LLC Jean Smith, Electric Power Research Institute, USA Johan Stjarnsater, Studsvik AB, Sweden Yoichi Takeda, Tohoku University, Japan Bob Tapping, Atomic Energy of Canada Limited, Canada Kurt Terrani, Oak Ridge National Laboratory, USA Sebastian Teysseyre, Idaho National Laboratory, USA Mychailo Toloczko3DFL¿F1RUWKZHVW1DWLRQDO/DERUDWRU\86$ François Vaillant, Electricité de France, France Juan Varela, GE Power and Water, USA Gary Was, University of Michigan, USA Eric Willis, Electric Power Research Institute, USA TK Yeh, National Tsing-Hua University, Taiwan Toshio Yonezawa, Tohoku University, Japan George Young, Bechtel Knolls, USA xxvi
Student Volunteers Thomas Eiden, University of Wisconsin, USA Wei-Jen Lai, University of Michigan, USA Tyler Moss, University of Michigan, USA Mike McMurtrey, University of Michigan, USA Brandon Semerau, University of Wisconsin, USA Kale Stephenson, University of Michigan, USA xxvii
Financial Sponsors xxix
Financial Sponsors (continued) xxx
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