Electric Mobility - Rethinking the Car - DEAS
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DEAS INNOVAT ON PROSPER TY The High-Tech Strategy for Germany Electric Mobility – Rethinking the Car HIGH-TECH STRATEGY
DEAS INNOVAT ON PROSPER TY The High-Tech Strategy for Germany Electric Mobility – Rethinking the Car HIGH-TECH STRATEGY
PREFACE Preface The move from conventional mobility to electric mobility with motors and batteries is revolutionising vehicles and, with them, the entire automotive indus- try. As a result, we need completely new ideas and tech- nologies if we are to make electric mobility an attrac- tive prospect. The programmes launched by Germany’s Federal Ministry of Education and Research (BMBF) back in 2008 to award financial assistance for research and development and initial and continuing training in the field of electric mobility are a significant contri- bution to efforts to shape the changes and give them a solid basis. The core areas on which the programmes focus are batteries, energy efficiency and training in the form of academic education and vocational training Aiming to make electric mobility a common feature of our roads. (initial and continuing). A particularly important aspect (Robert Bosch GmbH) is the need to closely dovetail the activities of academia and industry so that everyone – consumers included – This brochure outlines the challenges posed by electric can benefit from the good ideas yielded by research. mobility. It also presents selected research projects as an insight into the wide range of solutions being Internal combustion engines have been constantly developed in close cooperation at German universities, fine-tuned in a process lasting a hundred years so it research establishments and in industry. is bound to take more than a mere half-decade for electric mobility to be able to compete with them. The BMBF has provided the impetus for many promising developments over the past five years but rethinking the car will not happen overnight. The research and development required will take quite some time yet. The success achieved in recent years has been encour- aging and points to greater things to come and we are certain all the hard work will pay off. Why? Partly because electric vehicles (EVs) are clean, quiet, effective mobility providers and a bridge to new mobility strate- gies for a future in which the focus will not be solely on the car. But also because they present an opportunity for Germany’s automotive industry to maintain pole position on the global market. It will, after all, be the market that decides which tech- nologies are successful in the medium and long term. All the BMBF can do is help lay the foundations for an automotive future that benefits the environment and the economy.
CONTENTS 1 Contents Page Introduction ................................................................................................................................................................................................................. 2 Strategy and activities of the BMBF. 8 Batteries – no electricity, no electric mobility .............................................................................................................................. 10 The lithium-ion battery ............................................................................................................................................................................ 14 Alliance for the Battery of the Future (LIB2015)......................................................................................................................... 16 Pooling expertise .......................................................................................................................................................................................... 18 Manufacturing tomorrow’s batteries in Germany. 19 Spotlight on: Fraunhofer System Research for Electromobility. 20 Energy efficiency – How can we make EVs go further?......................................................................................................... 24 The electric motor....................................................................................................................................................................... 26 Efficient drivetrain technologies. 28 Intelligent power electronics for energy management. 30 Reliability. 32 Lightweight construction. 33 Comfort. 34 Vehicle concepts. 36 Spotlight on: The South-West Leading Edge Cluster ................................................................................................................. 38 Training for electric mobility – technology powered by people ......................................................................................... 40 National Education Conference.............................................................................................................................................. 41 Driving the next generation of research talent ............................................................................................................... 42 Experiment kits .............................................................................................................................................................................. 44 Electric car racing .......................................................................................................................................................................... 44 Electric mobility up close. 45 Spotlight on: e performance................................................................................................................................................................. 46 Summary . 48 Further information. 52
2 INTRODUCTION Introduction One only needs to take a quick look at the headlines in Germany to see electric mobility is a hotly debated We’ve always said it’s a marathon. We’re aware of issue. Hopes and expectations abound as to what it can that and we started it with the aim of finishing it suc- offer consumers and the opportunities it presents for cessfully. You can’t start complaining about stitch just German industry. But there are still major scientific, 100 metres into the race. technical and design challenges to be overcome before EVs can really take the market by storm. Current solu- Professor Henning Kagermann, Chairman of the tions do not yet provide the large range, acceptable National Platform for Electric Mobility (NPE) and cost, rapid charging and long battery life that custom- President of acatech – the National Academy of Sci- ers want. Infrastructure availability is also an issue. ence and Engineering In response, the BMBF is concentrating on ensur- ing initial and continuing training for bright minds, Combustion engines – setting the pace for systematic accumulation of expertise and fruitful 100 years collaboration between academia and industry to gear up for future EV generations. However, despite all the For more than 100 years, the internal combustion hopeful developments of the past five years, one thing engine defined the development of a technical feat that is quite clear: the technology race to optimise the EV is was a success story for engineering and for Germany. a marathon, not a sprint, so stamina is called for. But In fact, however, the car’s rise to widespread popularity that is no surprise; after all, the struggle to find an EV began with electric vehicles. In 1881, five years before solution that can satisfy future needs and the market the legendary Benz, Gustave Trouvé could be seen has only just begun. steering his electrically powered, low-noise tricycle through the streets of Paris. And in 1899 it was “La Jamais Contente” (“The Never Satisfied”), designed by Belgian engineer Camille Jenatzy, which became the
INTRODUCTION 3 first car in the world to go faster than 100 kilometres not all big name car makers. There are also countless "per hour" and it did so by completely electrical means. small and medium-sized enterprises (SMEs) whose In the United States, there were actually more EVs on components are key to making cars successful prod- the roads in 1900 than there were internal combustion ucts. The work of the SMEs is vital to ensuring the high engine vehicles. Ultimately, however, vehicles fuelled quality, reliability and safety of German cars, so highly by petrol or diesel became the more popular choice. valued by customers the world over. Indeed, German The reasons back then were similar to today – they had manufacturers sell the lion’s share of their products a larger range and battery technology could not evolve (more than 60%) abroad. In 2011, the industry reported fast enough to keep up with the rising popularity of international sales revenues of approximately 223 bil- petroleum and the rapid proliferation of petrol stations. lion euros. 125 years ago the automobile was invented here in Germany and it’s reinvented here every day too. There is no other sector with such rapid innovation and such a global outlook. Matthias Wissman, President of the German Associa- tion of the Automotive Industry (VDA) The 1899 “La Jamais Contente” was ahead of its time with its fully More than a third of all industrial expenditure on electric drive system. (Museum Autovision) research and development takes place in the automo- tive sector. It is one of the It was the start of a revolution in individual mobil- EVs are both an oppor- top investors, making it ity. Instead of “boneshakers” or horsepower of the tunity and a challenge one of the top drivers of oat-eating variety, people could harness much more for the German auto- innovation in Germany. horsepower to get from A to B – more quickly and motive industry. And it will need to more comfortably. And that gradually made the world maintain that high level of “smaller”. When cars became generally affordable after commitment if it is to master the challenges ahead. the Second World War, many people fulfilled their dream of four-wheeled freedom with a vehicle stand- Petroleum – an economic and an ecological chal- ing ready outside the front door to take them on short lenge shopping sprees or even to the other end of Europe on holiday. Reliable, fast, safe, comfortable, good-looking Though the challenges for EVs are similar to those of mobility had arrived. 100 years ago, one crucial factor has changed complete- ly: the availability of petroleum. Once the turbo drive Driving the economy of an entire industry, it is now a braking force. The Earth’s petroleum reserves will not last forever. That is Cars became a major economic driving force, especially a fact that cannot be changed by tapping new deposits in Germany. According to Germany’s Federal Statisti- using complex, costly and environmentally controver- cal Office, more than one fifth (in excess of 317 billion sial methods such as fracking from shale rock or oil euros) of Germany’s total industrial turnover in 2010 sands. There is also a general consensus that prices for was generated by the automotive industry. Almost one this coveted commodity are more likely to rise than in seven jobs are directly or indirectly linked to vehicle fall, which means it will become considerably more making, be it in planning, component supply, produc- expensive to drive a conventional vehicle. tion or service provision. Around 1,000 companies work in the area of vehicle construction and they are
4 INTRODUCTION But it is not just economic uncertainties that are tive industry will have to tackle if it is to continue to be forcing the automotive Germany’s main export engine. But they also offer our EVs can help cut carbon industry to rethink things. automotive industry a prime opportunity. emissions and protect The new mentality has fossil resources. also been brought about What makes EVs appealing? by the ecological problems caused by the meteoric spread of cars powered by True, cars that run on natural gas or organic fuel can petroleum-based fuels across the globe. After all, 13% of help cut emissions too. But it is the excellent energy worldwide carbon dioxide emissions are attributable to efficiency and good controllability that make electric the transport sector and the figure looks likely to climb motors particularly appealing. Their efficiency rating is further. In Germany, it is approximately 20%, a whole higher than 90%, compared with approximately two thirds of which comes from passenger cars. 35% for internal combus- EVs are efficient, quiet tion engines. In other Number of cars continuing to rise and fast with it. words, 90% of the electri- cal power used can be Policymakers have taken steps to counter these prob- converted into mechanical power and hence into lems. The EU Commission, for instance, has issued driving force. Unlike with combustion engines, electric stricter environmental targets for car makers. They motors can run at full power from the very first are being asked to cut per kilometre carbon emissions revolution or “rev”. Furthermore, electric motors are from the 2007 level of 157 grams to 95 grams by 2020 low-maintenance, versatile and exceptionally quiet. – a reduction of 40%. Germany’s Federal Government And they have another very special advantage too: has also set its own climate protection targets, aimed at braking energy can be fed back into the vehicle’s decreasing carbon emissions in Germany by a total of energy supply whereas it just dissipates as heat in 40% (compared to the 1990 figure) by 2020, putting the conventional vehicles. onus on all stakeholders to take action. When run on electricity from renewable sources, elec- tric motors are a particularly environmentally friendly Cheap oil is a thing of the past. Even if there were option as they help reduce carbon emissions both at enough easily extractable oil, vehicles have to move the local and the global level. According to “Fraunhofer away from combusting liquid hydrocarbons. Traffic’s System Research”, studies show that supplying the contribution to climate risk is increasing. required electrical energy will not be an issue. They claim it will take less than a 5% rise in electricity supply Professor Andreas Knie, Managing Director of InnoZ to operate 15% of vehicles electrically. They also point (Innovation Centre for Mobility and Societal Change), out that, once there are one or two million EVs on the Professor at Technische Universität Berlin roads, the battery charging process will have to be coordinated to prevent evening load peaks and over- loading of local transformers as well as to avoid new The number of cars, however, will continue to rise. That peak load power stations having to be built. is particularly true in newly industrialising countries, especially China. Estimates suggest that 50% more pas- Electric mobility is more than just electric vehicles senger cars will be sold worldwide in 2020 than today. With regard to the EU, studies claim people will travel More and more people are moving to urban regions, roughly 30% more kilometres than now in 2030 and only to be greeted by permanent traffic congestion, in- that 75% of that will still be by car. adequate parking and a radical intensification of expo- sure to air pollution and noise. These problems will not These are the challenges (stricter climate protection be solved, especially not in large urban areas, simply by requirements combined with growing demand for switching to electric or hybrid vehicles. New mobility cars and scarcer resources) that the German automo- strategies are needed. EVs will be integrated into a good
INTRODUCTION 5 the Karlsruhe Institute of Technology , around 80% of Electric cars can only make a real contribution to passenger cars in Germany do not travel more than 60 protecting the climate if they’re charged with renew- kilometres per day anyway. able energy that would otherwise not have been used. In that respect, the emergence of electric mobility can Nonetheless, many people will continue to see the car only be considered a positive trend if it is part of the as a status symbol and energy revolution that aims to establish a renewable EVs are part of tomor- there will still be a need electricity system. row’s multi-faceted for individual mobility. On mobility system. top of that, people are Dr Karl-Otto Schallaböck, Wuppertal Institute for accustomed to a certain Climate, Environment and Energy, Project Manager level of comfort and safety, which new EVs must at for research activities supporting work undertaken least equal if they are to conquer the market. as part of the BMBF’s “Key technologies for electric mobility” (STROM) funding programme National and international development Despite the technological issues yet to be overcome, car local public transport structure and there will be a wide makers and governments around the globe are putting selection of electrically powered vehicles. They their money on electric mobility. In a wide-ranging will include two-wheeled vehicles and commercial programme, the US is providing 2.4 billion dollars for vehicles such as waste collection lorries or vans for city EV development. China plans to have five million EVs deliveries. The principle of borrowing instead of own- on its roads by 2020 and France and Japan have already ing, which is already making car sharing clubs popular launched their first completely battery-operated EVs. in German cities, may well become even more wide- So the technological race to create the best EV has long spread. EVs would be a good way of meeting that need since started and it offers tremendous opportunities for and they would also be suitable for corporate fleets, for Germany. example. The fact is that cars are actually only used for an average of two hours per day. Most of the time, they are idle. Range is often not a problem either. Accord- ing to a study by the Institute for Transport Studies at Various electric drivetrains already exist. This diagram shows how they compare to conventional drivetrain systems .(Fraunhofer IAO)
6 INTRODUCTION In its 2009 National Development Plan for Electric Mobility, the Federal Government set out its objective Germany has to play a leading role in e-mobility to make Germany a leading provider of electric mobil- because it is definitely coming. And jobs and prosper- ity. Since 2010, a prestigious group of experts from ity in Germany depend on it. So, though we mustn’t academia, industry, trade unions, environmental or- just start doing things for the sake of it, we should ganisations and other interest groups from society has take intelligent steps, early on, to secure progress in been pursuing that goal, at the invitation of Chancellor this area. That’s why it was certainly right to set up Merkel, in the National Platform for Electric Mobility the NPE. After all, the intention behind it is not only (NPE). Their in-depth consultations serve as the basis to build a lead market but also to continue to develop for an electric mobility roadmap as well as proposals Germany into a leading provider. for concrete action. Professor Henning Kagermann, Chairman of the National Platform for Electric Mobility (NPE) and Manufacturers in other countries already have President of acatech – the National Academy of production models on the market. However, the very Science and Engineering high prices indicate they haven’t found the right approach yet either to be able to offer EVs at competi- tive prices. But that’s the key, that’s where the true innovation lies. German manufacturers are seeking Solid foundations to deliver perfect, safe quality but they don’t want EVs to be the ruin of their businesses. The current strategy Germany is extremely well placed to become a world certainly makes sense. leader in electric mobility. It has a strong tradition of car and component making – two sectors that have Professor Markus Lienkamp, Head of Institute of demonstrated an impressive capacity for constant Automotive Technology and co-head of the Science innovation and market leadership for more than a cen- Center for Electromobility at the Technical University tury. But Germany also has a diverse landscape of uni- of Munich versities and non-university research establishments, giving it solid foundations in the realms of science and research too. The NPE’s recommendations have been incorporated into the government’s electric mobility programme. The BMBF has also signposted the way forward, both The main point the programme makes is that the focus in terms of structure and issues to be dealt with, in the in the coming years needs to be on promoting research form of its “high-tech strategy”. It places the research and development. Accord- focus on the five global challenges of our times, i.e. Electric mobility is ingly, the four ministries climate/energy, health/nutrition, mobility, security and gaining significance responsible for economics, communication. across the globe. transport, the environ- ment and education and Germany’s excellence in engineering, particularly research have coordinated their research programmes mechanical and electrical engineering, provides a fur- with the aim of translating engineers’ ideas into ther springboard for electric mobility. Interdisciplinary marketable innovations as effectively and swiftly as fields, such as mechatronics, have also been emerging possible. After all, ultimately it will be buyers who for some years now. We also have a good basis in IT decide who wins the race for the best EV. and the natural sciences but we lag way behind when it comes to electrochemistry, which is, however, crucial to battery research.
INTRODUCTION 7 A number of segments are already working around the clock on electric mobility research and the first vehicles are already on the market. (RWE) Outside the academic segment, the sound vocational training provided by Germany’s “dual system” (a combination of on the job and school-based training) plays a significant part in equipping the industry with an excellently trained technical workforce. But there is still much to do in the EVs are a technological area of training and challenge but one that research if we are to Germany can master. remain successful and master the huge techno- logical challenges posed by electric mobility. That is precisely the purpose of the BMBF’s electric mobility strategy, which is described in the following section.
8 STRATEGY AND ACTIVITIES OF THE BMBF Strategy and activities of the BMBF Turning Germany into a lead provider of electric high power, extremely safe, long life batteries. But it mobility is an ambitious objective. Indeed, for the takes more to create an EV than simply swapping the German automotive industry, electric mobility is tank for a battery and the combustion engine for an nothing less than a complete shift in paradigm. electric motor. The entire car has to be rethought be- It will need to continue developing vehicles that cause the new form of energy supply and the different drivetrain require a different control system and totally are reliable and offer high quality, making them new components to match. As a result, the entire auto- attractive and competitive, but it will have to do so motive value chain will change. using entirely new technology. Customers want optimum safety and an optimum We won’t really get anywhere if we just fit electric driving experience. On top of that, the electric mobility drivetrains in existing combustion engine vehicles. “package” will have to include outstanding service sol- We have to go right back to the drawing board. utions and a charging infrastructure with user-friendly billing methods. Electric mobility is a huge technical Professor Markus Lienkamp, Head of Institute of challenge cross-cutting a variety of disciplines and Automotive Technology and co-head of the Science sectors. The BMBF has therefore decided to focus its Center for Electromobility at the Technical University strategy on interdisciplinary research into new tech- of Munich nologies, particularly energy storage and more econ- omical use of energy. In addition, initial and continuing training are vital since Germany can only become a In particular, research now needs to focus more on the leading electric mobility provider if it has well-trained energy efficiency of the entire vehicle as a way of com- professionals. pensating for the limited amount of energy available. Lightweight construction is a must, as are components Strategic focus on batteries and energy efficiency – that work in perfect combination and intelligent we have to completely rethink the car! energy management (for requirements such as interior air conditioning) that does not detract from comfort. I know from personal experience how long true The energy distribution and data transfer between the innovations take to make it onto the market. Sadly, vehicle’s various components will have to be man- it’s not rare for 15 to 20 years to pass before they go aged by electronic and software-based vehicle control into line production. That in itself is reason enough systems, reflecting the general trend. Information and for us in “Autoland” to rev things up with whole- communications technology (ICT) will therefore play vehicle designs, infrastructure system solutions a key role in the car of the future too – not only inside and networked mobility systems tailored to electric the vehicle but also at the interface with the charging mobility. They need to be sustainable, work in terms infrastructure and, consequently, the electricity grid. of engineering and cost efficiency and appeal to ICT will also feature strongly in new service models people’s emotions as well as their ecological and transport solutions involving EVs, such as payment conscience! systems or automated traffic management based on the current traffic situation and battery status. Professor Johann H. Tomforde, owner of the Compe- tence & Design Center for Mobility Innovations and Today, the ability to innovate is crucial for growth inventor of the SMART and employment. But innovation can only bear fruit if technological developments can be combined with service and work processes to create added value. So The greatest technical challenge involved in electric new technologies, such as electric mobility, require mobility is the range that the new vehicles can cover. innovation-seeking research in other areas, in parallel To ensure a good range, it will be essential to develop with technological research, to meet that need.
STRATEGY AND ACTIVITIES OF THE BMBF 9 Strategic focus on initial and continuing training – be better integrated. A major prerequisite for receiving technology powered by people financial assistance is that the companies have to put up at least 50% of the project costs. However, SMEs can Highly motivated and qualified professionals are essen- access special grants to help them do this. tial if electric mobility is to enjoy long-term success. As well as the new initial and continuing training pro- The following sections present selected projects as an grammes, especially those delivered at “inter-company example of the activities funded by the BMBF in its vocational training centres”, the research projects priority areas of batteries, energy efficiency and initial supported by the BMBF also help ensure excellence in and continuing training. training. One example is the “e performance” research project, in which a modular EV was developed, provid- ing more than 70 young researchers from universities with input for their dissertations and theses. As a direct result of the first National Education Conference for Electric Mobility, funded by the BMBF, we are seeking to work with universities to identify ways in which the various existing programmes can be consolidated and better dovetailed. Existing methods and structures, both in higher education and voca- tional training, need to be brought together so that the electric mobility challenge can be tackled with inter- disciplinary solutions. Electric mobility – an interdisciplinary task Any attempt to rethink the car has to consider the entire value chain – from the raw materials to develop- ment, production, the various possible uses and, at the end of the road, recycling. All of these points are cov- ered by the activities of the governmental departments involved, which now provide over 900 million euros of financial support to far more than 100 collaborative research projects. That money comes on top of the 500 million euros already spent up to 2011 as part of the Second Economic Stimulus Package. At over 480 mil- lion euros, the BMBF’s share of that financial assistance is the largest. In view of the interdisciplinary nature of electric mo- bility, the BMBF provides support for efforts to form research alliances. The aim is to improve cooperation between the fields of basic research and application, between academia and industry, thus reducing the time to market for brilliant new ideas. These alliances also enable the various fields, e.g. mechanical and plant engineering, chemistry, power electronics and IT, and companies themselves (from SMEs to car makers) to
10 BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY Batteries – no electricity, no electric mobility The battery supplies the energy that keeps an EV’s For many years, battery research tended to be neg- heart beating. Battery performance is a make or lected in Germany. Thanks to the funding schemes it break factor for EVs’ user friendliness and for the introduced in 2008, the BMBF has managed to revive success of electric mobility. Battery research there- this important research and technology segment and fore has a pivotal role in the BMBF’s strategy. create incentives to establish new research groups and university departments and to secure new generations of researchers. The goal is to develop Germany into one of the leading centres of EV battery production technology while at The biggest problem with batteries is that their energy the same time pushing ahead research for the next gen- density is almost one hundred times lower than that of eration of batteries. petrol. This factor restricts the travel range significantly and even the highly efficient electric motors cannot Batteries are a significant source of added value and, if compensate for it. we want to create that value in Germany, they need to be produced here too. To date, battery production in Germany has been minimal. In the consumer electron- The energy density of batteries is one of the key ics segment (laptops, cameras and mobile phones, for parameters in electric mobility in that it still limits instance), Asia is the world leader, which is why EV bat- range and therefore has consequences for the design tery production has become established there too. and potential uses of EVs. Although lightweight con- struction and specially tailored vehicle design can solve the limitation problem, energy densities must The lion’s share of the added value offered by EVs be much higher if EVs are to achieve ranges compar- comes from batteries. Battery cell production is cur- able to those of internal combustion engines. High- rently firmly in the hands of Asian industrialised and voltage batteries and the post-lithium-ion batteries newly industrialising countries; German businesses (e.g. lithium-sulphur and metal air batteries) that play a minor role on the international market. It re- will be developed in the future are expected to help mains to be seen whether and when we can catch up ensure that electric mobility becomes a permanent and eliminate that competitive edge. In the medium fixture in transport systems in years and decades to to long term, Germany does have a good chance of come. tapping into this market through its already well- positioned chemical and materials research. Dr Axel Thielmann, Deputy Head of the Compet- ence Center for Emerging Technologies (CCT) at Professor Martin Wietschel, Deputy Head of the Com- the Fraunhofer ISI institute and Project Manager petence Center for Energy Technology and Energy LIB2015 Roadmapping Systems (CCE) at the Fraunhofer ISI institute and member of the NPE As a result, the EVs currently available on the market only have a range of somewhere between 100 and 150 Germany has a very strong manufacturing tradition. kilometres. Mechanical and plant engineering are cornerstones of the country’s economy, as is the chemical industry. Consequently, in addition to production technologies, These capabilities mean we are well-placed to embark cell chemistry is a research priority. The aim is to opti- on drivetrain battery production. Only if we produce mise good existing materials and develop new ones to them here in Germany can we guarantee valuable syn- enable more energy to be stored while keeping weight ergies in conjunction with the advances being made in to a minimum. Another objective is to lengthen battery the plant and production sectors. life and increase power density in order to speed up the charging process. The plan is to bring the battery life into line with the service life of the other vehicle
BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY 11 Analysis of raw materials for battery cell production (Li-Tec Battery GmbH)
12 BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY components by ensuring 3,000 to 5,000 charge cycles over ten to fifteen years. In addition, the batteries need to be safe not only during normal operation but also in the event of an accident. That poses quite a challenge, bearing in mind the high levels of energy, voltage and, in some cases, combustible chemicals. The battery management system, which manages the charge status in the battery system, therefore plays a crucial role. Last but not least, there is the cost factor. At the mo- ment, the battery accounts for around half of the overall vehicle cost. This figure has to be slashed; the initial target set is to have twice as much energy density at half the cost by 2015. So far, interest has focused on lithium-ion batteries. In principle, their relatively high energy and power densities, coupled with high cycle stability, make them suitable for use in EVs. However, they need to be made larger and provide more energy. But there is a whole range of requirements involved in increasing the energy levels, primarily with regard to safety. Battery research in Germany, which is constantly picking up momentum, is concentrating on future generations of this battery technology and the development of new battery types such as lithium-sulphur or metal-air cells based on totally new cell chemistry. The following sec- tions describe some of the BMBF research projects in this area. Researchers create electrodes with new battery materials using the coating facility at the University of Münster battery research centre – Münster Electrochemical Energy Technol- ogy (MEET). (WWU/MEET)
BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY 13
14 BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY The lithium-ion battery A lithium-ion battery is a rechargeable, electrochemical How the cell works energy storage unit, based on a battery cell. It is pos- sible to combine several battery cells to form modules, Voltage is applied to the electrodes in order to charge which are then coordinated and controlled by the bat- the battery (Fig. 1). In the cathode, positive lithium ions tery management system. and negative electrons break free from the lithium metal oxides. The electrons flow to the anode via the “Lithium-ion battery” is the generic term for various outer circuit. The lithium ions migrate through the different battery types. They use different electrode electrolyte to the anode, where they become embedded materials but they are all based on the idea that lithium in the gaps in the graphite layer (in a process known as ions, dissolved in the electrolyte, migrate between the “intercalation”). The lithium ions pick up the electron electrodes during charging and discharge. again and remain in the interlayer in the form of metal. The cell elements Cathode The cathode is the positive electrode (terminal). It is made of an aluminium foil, which is coated in different materials (known as “active materials”) depending on the battery type. The active materials can be made, for example, of lithium metal oxides (LiMeO4) or lithium metal phosphates (LiMePO4). Anode Fig. 1: Charging process for an LiMnO2 battery; left: graphite anode, The anode is the negative electrode. It is made of a cop- into which the lithium ions are inserted (or “intercalated”, from the Latin “intercalare”); right: LiMnO2 cathode, from which lithium ions per foil, usually coated in graphite. migrate (Professor Marco Oetken and Martin Hasselman, Depart- ment of Chemistry, Freiburg University of Education) Electrolyte The electrolyte is the substance in which the lithium During discharge (Fig. 2), a load is connected. The ions are dissolved and migrate back and forth from the lithium releases the electron, dissolves and migrates cathode to the anode. It is normally a liquid, organic back to the cathode in the form of an ion. There, it solvent but it can also be made of (synthetic) polymer bonds with the metal oxide and an electron in the crys- or ceramic material. tal structure of the lithium metal oxide. Separator The separator is made of a porous material, often a plastic or fine ceramic material, which only allows the positive lithium ions to pass and blocks the electrons’ path. By doing this, it separates the electrodes mechani- cally and electrically, thus preventing short circuiting. Fig. 2: Discharge process for an LiMnO2 battery; left: graphite anode, from which lithium ions migrate; right: LiMnO2 cathode, into which the lithium ions are intercalated (Professor Marco Oetken and Martin Hasselman, Department of Chemistry, Freiburg University of Education)
BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY 15 Increasing power density To achieve this, the ions in the various materials must be made more mobile so that they are transferred faster. This could be done, for example, by increasing the reactive surface area between the electrode and electrolyte. Increasing battery life This can be done by minimising the materials’ reac- tivity, thereby slowing down the ageing process. The cycle stability, i.e. the possible number of charge and discharge cycles, would also need to be increased. Inside of a high-power cell; the two electrodes can be seen at the top. (Fraunhofer ISIT) Increasing safety Attempts to improve safety cover a wide range of Research aspects aspects. Crash safety, for instance, can be improved through new designs and more stable or more flexible Increasing energy density materials. In the cell field, researchers are endeavouring Here, the aim is to store more ions in the electrodes to remove toxic, highly flammable and explosive chem- while keeping volume and weight to a minimum. One icals from the equation. Flexible separators with a high way to do this is to use more or more absorbent active melting point can prevent short circuiting, and reliable material, e.g. nanoparticles or nanocomposite materi- monitoring of temperature and charge status provides als. Another possibility would be to switch to materials protection against overheating and overcharging. that allow a higher voltage level (5 volts instead of the present level of, for example, 3.6 volts). Battery production The first step is to mix the chemical components used to coat the electrode foils. The electrode sheets are then A composite is a material composed of two or cut out of the film and dried. Next, the anode, separator more joined materials. In battery production, an and cathode are assembled in stacks, after which the example would be electrodes made of a combination cells can be wound, folded or stacked themselves. Then of silicon and carbon. If a material can absorb more the cell stack is filled with the electrolyte and sealed. lithium, the battery charge can be increased, thus in- Finally, the battery is “formed”, i.e. charged for the first creasing the amount of energy stored in the battery. time, by hooking it up to a power source. Research is Nanoparticles are particles no bigger than approxi- required on all of these production steps. mately 100 nm. They are particularly interesting in battery research as possible cathode and anode materials. Their surface is larger compared to their volume and they have short diffusion paths, making higher charge and discharge rates possible. Professor Martin Winter, Project Manager LIB2015 and Co-Head of Münster Electrochemical Energy Technology (MEET), University of Münster
16 BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY Alliance for the Battery of the Future (LIB2015) Founded back in 2008, the Lithium-Ion Battery vent high reactivity as it speeds up the battery ageing Alliance (LIB2015) now has some 60 partners process. One possible option is to use polymer electro- from the academic and industrial spheres. With lytes to avoid the risk of short circuiting and potential an industrial consortium comprising BASF, Bosch, leakage of liquid electrolyte. Evonik, Li-Tec and Volkswagen at the helm, the aim The KoLiWin project is looking at the properties of is to develop future generations of high power, af- such electrolytes and how they interact with nano- fordable lithium-ion batteries by 2015. With its mix structured electrodes. There is also a BMBF group of of several joint industry projects, inter- young researchers examining new types of gel polymer institutional alliances and young researcher electrolytes, which offer exceptionally high conductiv- groups, the alliance covers all aspects of research ity and good mechanical stability. and development on lithium-ion batteries. The HE-Lion project, the largest and most comprehen- LIB2015 Innovation Alliance sive in the alliance, is also working on lithium-ion bat- teries with high energy densities (>300 Wh/kg). Other • Time frame: 2008 – 2015 objectives are a high level of safety, long battery life and • BMBF funding: approx. € 60 million environmental friendliness. • Partners: approx. 60 companies, universities and research establishments One trend intended to boost the amount of stored energy is to raise voltage levels. The LiFive project is developing new materials for cathodes and electrolytes One of the alliance’s activities is the development of so that lithium-ion cells can be built with a voltage new materials for the electrodes and electrolyte, with level of 5 volts instead of the present 3.6 volts. In addi- the aim of improving energy and power density plus tion, the team is devising models with which battery safety. The work on electrodes is intended to increase life can be predicted when the batteries are actually still their ability to absorb lithium. One strategy being in development. pursued is to make the electrodes out of composite materials with nanoparticles. As vehicle batteries become bigger, there will be new tasks for the battery management system. Where there Introducing nanostructures means the lithium ions are lots of cells interacting electrically, they need to be can be transported through the material more quickly, balanced out. The most important job for the battery resulting in faster charging and discharging. Another management system is controlling the charge and dis- advantage is the higher mechanical flexibility of charge processes. The cells do not have any overcharge nanostructured electrodes and their ability to absorb protection of their own so their charge status has to more lithium, which increases the available energy. In be monitored constantly. Another important aspect addition, by using a combination of different nano- is thermal management. Depending on the ambi- particles, the properties of the electrode materials can ent conditions, the cells have to be cooled or heated be adjusted as required. to optimise the electrical properties (which are very temperature-sensitive) and to slow down ageing. New In the following, we present details of some of the battery management systems are being developed on research projects being carried out by the LIB2015 the BatMan and Li-Mobility projects. Innovation Alliance. For more information, please visit www.lib2015.de. Utmost priority is being given to battery safety. The The LIB-NANO and LiVe projects are carrying out shift to systems with high quantities of energy entails fundamental research work to determine which significant risks, especially in terms of temperature and particle sizes and make-ups are suitable and how they charge stability. The mandate of the Li-Redox project interact with the electrolytes. A further aim is to pre- is to improve the cells’ overcharge protection. The idea
BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY 17 A chemistry lab technician assembling a lithium-ion test battery inside a glove box. The battery will be used to examine various new cathode materials. (BASF) is to add components to the electrolyte to enable it to absorb any excess charge and essentially carry it in the The approximately 60 project partners in LIB2015 circuit so that it does not destroy the electrodes. And on actively collaborate on interdisciplinary projects, to the SLIB project the team is drawing up standardised which they contribute their specific expertise. Thanks to methods and rules for testing battery and component this set-up, we have been able to successfully link up and safety. pool knowledge. The LIB2015 Alliance is being given direction by a road Professor Martin Winter, Project Manager LIB2015 and map prepared by the Fraunhofer Institute for Systems Co-Head of Münster Electrochemical Energy Technol- and Innovation Research (ISI), which takes into account ogy (MEET), University of Münster the ecological, economic and political parameters. The road mapping process places the latest project develop- ments in context with the other activities being carried out in this field around the world. It also identifies new technology pathways and compiles forecasts and scenarios for future developments.
18 BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY Pooling expertise Expanding university research Enhancing battery excellence “Electrochemistry for electric mobility” compe- Excellence and technological implementation of tence networks battery research (ExcellentBattery) Time frame: 2009 – 2011 Time frame: 2012 – 2016 BMBF funding: North: approx. € 13 million BMBF funding: approx. € 28 million South: approx. € 22 million The ExcellentBattery call for proposals is a continu- Project partners ation of the strategy started with the competence • North: four universities and two research establish- networks, the objective being to fund excellent battery ments research activities. Battery research centres are to be set • South: four universities and five research establish- up at establishments with the relevant expertise and ments a number of research groups will collaborate within those centres. What makes this approach special is that One of the first steps the BMBF took to systematically the groups will be headed by internationally renowned revive battery research in Germany was to launch two researchers and bring together expertise from the large competence networks in 2009 using funds from worlds of chemistry, materials research and engineer- the Second Economic Stimulus Package. The “Compe- ing. A core interest of ExcellentBattery is transferring tence Network North” is centred around the For- research findings to industrial application. To achieve schungszentrum Jülich research centre and the “Com- this, industry projects are running alongside the petence Network South” has what is now the Karlsruhe research project and there is an emphasis on patent ap- Institute of Technology (KIT) at its hub. Both networks plications and licensing agreements for commercial use have played a key role in helping to link up and expand of research outcomes. Creation of spin-off businesses is the existing expertise in battery research at universities another explicit aim. and research establishments. This is reflected in such things as the joint research projects that have been The first project to get off the ground, in 2012, was the initiated, equipment and plant that has been installed Center of Excellence for Battery Cells at the Technical and is used jointly and concerted efforts to provide University of Munich (ExZellTUM). Its primary goal is initial and continuing training for the new generation to design new material systems that will help increase of researchers. batteries’ energy density. ExZellTUM is a joint project by the institutes for Electrical Energy Storage Technol- The equipment available at the various establish- ogy, Technical Electrochemistry and Machine Tools and ments has been hugely improved with the help of Industrial Management plus the Heinz Maier-Leibnitz the funding from the Second Economic Stimulus research neutron source (FRMII). The Fraunhofer-Ge- Package. That really kick-started electrochemistry, sellschaft, BMW, Manz Tübingen and TÜV SÜD Battery awakening it from its long slumber and rapidly Testing are also involved. spawning a whole range of high-intensity activities generating high awareness. Now we have to keep the momentum going – scientific success can only be attained through years of painstaking research. Ten years is nothing when it comes to developing new scientific expertise. Professor Werner Tillmetz, member of the Board of Directors of the Centre for Solar Energy and Hydro- gen Research Baden-Württemberg (ZSW) and spokes- man for the Competence Network South Dry room for battery cells (Li-Tec Battery GmbH)
BATTERIES – NO ELECTRICITY, NO ELECTRIC MOBILITY 19 Manufacturing tomorrow’s batteries in Germany Prerequisites in place for series production of Testing platform for production technologies lithium-ion batteries KliB – Ulm research production line Production research for high power lithium-ion batteries for electro mobility (ProLiEMo) Time frame: 2012 – 2014 BMBF funding: approx. € 24 million Time frame: 2009 – 2011 BMBF funding: approx. € 20 million Project partner: • Centre for Solar Energy and Hydrogen Research Project partners: Baden-Württemberg (ZSW) • Daimler AG • DeutscheACCUmotive GmbH & Co. KG Battery technologies are constantly evolving and giv- • Evonik Litarion GmbH ing rise to new challenges for production. With this • Li-Tec Battery GmbH in mind, the BMBF is supporting the installation of a research pilot production line for large, vehicle-ready In 2012, the first German series production line for lithium-ion cells at the Centre for Solar Energy and large-format lithium-ion batteries began operation Hydrogen Research Baden-Württemberg (ZSW) in Ulm. in Kamenz, in the East German state of Saxony. Since The aim is to systematically cultivate expertise to gain then, the batteries for the smart fortwo electric drive a better understanding of process control and para- have been produced there using a ceramic separator meters so as to improve cell quality, minimise wastage developed by Evonik – testimony to the success of the and cut production costs. The team will pilot new ideas ProLiEMo project, which was coordinated by Daim- for materials, explore technical production issues and ler AG. In a team that also included cell and battery collect information about production times, quality specialists from Evonik Litarion, Li-Tec Battery and management and safety. The research production line Deutsche ACCUmotive, the project successfully con- is intended as a platform upon which companies can ducted research into and optimised the prerequisites test and evolve materials and components in con- for industrial series production of high power lithium- ditions akin to those of mass production. The ZSW ion batteries. The four project partners cover key parts is being advised by the Competence Network for of the value chain in Kamenz, from cell component Lithium-Ion Batteries (KliB), which brings together (electrode and separator) production to cell manufac- around 50 companies from across the value chain turing to the finished batteries ready for use in vehicles. plus a number of research establishments. The work is Thanks to the cells’ modular structure, the process scheduled for completion in 2014. steps have been considerably streamlined and through- put is up. Energy requirements and material wastage have been significantly reduced, resulting in a major decrease in production costs too. The calender, a system composed of several rollers, and the roller cutting machine for electrode production on the research production line in Ulm. (ZSW/M. Duckek)
20 SPOTLIGHT ON: FRAUNHOFER SYSTEM RESEARCH FOR ELECTROMOBILITY Spotlight on: Fraunhofer System Research for Electromobility Electric mobility in Germany needs to be promoted in a systematic, comprehensive approach. To this end, the Fraunhofer-Gesellschaft has harnessed the expertise of 33 institutes, pooling it in what it has called “Fraunhofer System Research for Electromobility”. Supported by BMBF funding from the Second Economic Stimulus Package, researchers worked together on an interdisciplinary basis from 2009 to 2011. This en- abled all of the parts in the electric mobility value chain to be assessed and researched in a coordinated manner. In addition to the “FreccO” and “AutoTram” demonstration vehicles created on the project, it also led to a unique knowledge and expertise platform for product development undertaken with industry part- ners based on projects past and future. The BMBF awarded around 34 million euros in financial assistance for Fraunhofer System Research for Electromobility. The five core areas of Fraunhofer System Research for Electromobility 1 –Power generation, energy Core research areas: distribution and conversion • Connection to the electricity grid With EVs, electricity (ideally • Hardware and software components for stationary from renewable sources) can be and mobile charging devices used extremely efficiently. For • Analyses of the load on electricity grids that to happen, charging has to • Modular power electronics be easy, flexible and quick and • Integrated independent axle drive for twin motor the energy has to be able to be control distributed within the vehicle as required. 2 –Energy storage technology Core research areas: Demonstrator cells based on • New active materials such as a core shell silicon new materials since vehicle per- carbon composite for the anode formance and range will be key • New cathodes for next-generation lithium-sulphur to ensuring widespread uptake cells based on carbon nanotubes of EVs. Storage and supply of • Sensors and electronics for monitoring pressure and electrical energy are pivotal. temperature in the cell • Development of modular and flexibly scalable battery systems
SPOTLIGHT ON: FRAUNHOFER SYSTEM RESEARCH FOR ELECTROMOBILITY 21 3 –Vehicle design Core research areas: The switch from internal • Wheel hub motors with integrated power elec- combustion engines to electric tronics and cooling motors paves the way for a re- • Lightweight multi-material systems and manufac- volution in vehicle design. With turing methods using fibre composites distributed engines, there is no • System for battery replacement by motor work- longer any need for mechanical shops/garages transmission elements, which • Whole-vehicle testing using four complementary means extra space. test rigs 4 –Technical system integra- Core research areas: tion and socio-political • “Frecc0” demonstration vehicle, based on a sports aspects car Development of two demon- • “AutoTram” demonstration vehicle – a type of tram stration vehicles, in which the that does not depend on the track network components developed on the • Investigation of vehicle designs and potential uses project were tested to establish how they worked as part of the overall system and how they dealt with real conditions. 5 –Function, reliability, testing Core research areas: and production • Recommendations for evolving test methods and When it comes to reliability, standards safety and comfort, EVs have • Assessment of component reliability and safety to meet the same high require- • Studies on the availability of raw materials and re- ments that apply to today’s source efficient production conventional vehicles. And • Ecological footprints, especially for batteries they have to be economical to • Development of a precision casting method for mo- produce. tor windings The results achieved in the space of just two years were pioneering in many ways. Technically acclaimed stud- ies and demonstration vehicles were created around the topic of electric mobility, and the system research model proved so successful that it has been continued since the beginning of 2013 under the new president of the Fraunhofer-Gesellschaft. Professor Holger Hanselka, Chief Coordinator, Fraunhofer System Research and Director of the Fraunhofer Institute for Structural Durability and System Reliability (LBF)
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