REENGINEERING BLUESCOPE STEEL'S PORT KEMBLA SINTER PLANT FOR HIGH PRODUCTIVITY AND REDUCED STEELWORKS GREENHOUSE EMISSIONS
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REENGINEERING BLUESCOPE STEEL’S PORT KEMBLA SINTER PLANT FOR HIGH PRODUCTIVITY AND REDUCED STEELWORKS GREENHOUSE EMISSIONS N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya BlueScope Steel Australia New Zealand Steel Manufacturing Business: PO Box 1854 Wollongong 2500 nick.digiorgio@bluescopesteel.com ABSTRACT Maximising the amount of highly reducible sinter in blast furnace feed is crucial to minimising blast furnace fuel rate; the chief source of CO2 emissions at an integrated steel plant. As part of the ongoing drive to improve process capability and reduce operating cost, BlueScope Steel in late 2009 upgraded the sintering capacity at its Port Kembla steelworks. The business case for upgrading the sinter plant was based on replacing high cost imported pellets with an increased amount of locally sintered iron ore. However the need to substantially re-engineer the plant presented the opportunity to build a lower carbon footprint into the Port Kembla steelworks as a whole through increased sinter make and to potentially lower the greenhouse intensity of the sinter plant itself through measures aimed at further increasing sinter plant productivity. Following commissioning of the upgraded sinter plant there has been an ongoing challenge to achieve design sinter production rates. It was found that high rates of goethitic ores in the sinter feed was detrimental to sinter plant productivity. However a previously undocumented relationship was found to exist between increased Goethitic ore content of the sintered ore blend and decreased blast furnace fuel rate. Overcoming decreased sintering productivity due to high goethitic ore rates represents an opportunity to lower steel plant greenhouse impact by lowering blast furnace fuel rate. The paper outlines the measures implemented to increase the sinter plant productivity in the context of high Goethite rate, and the correspondence between the observed increased sintering productivity and reduced sinter plant CO2 intensity. The newer technologies implemented within the scope of the sinter plant upgrade, that could further lower greenhouse intensity are described. Possible technologies that could be applied to reduce sinter plant greenhouse emissions in the longer term are also outlined. OVERVIEW Blast Furnace Sinter Burden, Fuel Rate and CO2 emissions BlueScope Steel’s Port Kembla works supplies in excess of 5Mt per annum of high grade flat steel products. The steel shop is supplied by iron from two modern blast furnaces: No.5, which was relined in 2009 to a fourth campaign inner volume of 3427m3 and No. 6, a 3208m3 furnace commissioned in 1996 which has to date produced in excess of 37.5 Mt of iron.
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya At normal production levels, the Port Kembla plant emits in excess of 10 million tonnes of CO2 equivalent per annum (National Greenhouse and Energy Reporting 2010) of which approximately 80% is due to the blast furnace iron making process, while the sintering process contributes approximately 10%. The blast furnaces use a combination of pulverised coal injection (PCI) and coke to supply the carbon required for heat and reduction of iron oxides. Minimising blast furnace fuel requirement is therefore central to minimising CO2 intensity of an integrated steel plant. 15000 90 Average Daily Ironmake (t) 14000 85 13000 80 Burden Sinter % 12000 75 11000 70 10000 65 9000 60 8000 55 7000 50 1982 1987 1992 1997 2002 2007 Year Daily Ironmake (t) Burden Sinter % Fig.1 Port Kembla average daily Blast Furnace iron production and sinter percentage in blast furnace burdens 1982 – 2011. No 5 Blast Furnace was relined in 1991 and 2009. 45 18000 43 Daily Sinter Production (t) 17000 Productivity (t/ m2/ d) 41 16000 39 37 15000 35 14000 33 13000 31 12000 29 27 11000 25 10000 1982 1987 1992 1997 2002 2007 Year Productivity Daily Sinter Production (t) Fig. 2 Port Kembla average daily sinter production and productivity (t/m2/day) 1983- 2011. The sinter plant was enlarged during 2009. 2
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya A major determinant of blast furnace fuel rate is ferrous burden reducibility; the greater the rate and extent of reduction to Fe under standard test conditions (ISO Standard 7215), the more reducible the burden. Of the three types of ferrous burden charged to blast furnaces, namely sinter, pellets and lump iron ore, sinter is the most reducible. It is also the least costly. Integrated steel makers have known for some time that using sinter in place of lump ore and pellets can decrease blast furnace fuel rate. The ability to maximise sinter feed to the blast furnaces is therefore vital to integrated steel plant operation to minimise blast furnace fuel costs, associated greenhouse intensity and ferrous feed cost. From multiple linear regression analysis of long term blast furnace operating data it is observed, after correcting for other known influences on fuel rate (e.g slag rate) that • +1% Blast Furnace Sinter burden = -0.4 kg/t Fuel Rate, From a steel plant operating viewpoint, lower greenhouse gas emissions and lower fuel rate are the same objective. The large and increasing fraction of steel plant operating cost related to carbon fuels has driven significant reductions in both blast furnace and, to a lesser degree, sinter plant fuel rate over many years. Blast Furnace Fuel Rates are typically of the order of 500 kg/t. The scope for further blast furnace fuel rate reductions, though small in percentage terms, represent significant tonnages of CO2. Conversely, even large percentage reductions of sinter plant CO2 emissions represent small CO2 tonnages when compared to blast furnace operation. As such increased sinter productivity is likely to produce a net fuel rate and CO2 emission benefit even if sinter plant emissions rise with increased sinter make. The Port Kembla furnaces have operated with a sinter based burden supplied by a single sinter plant supplemented by purchased pellets and lump ore. The Port Kembla 3DL sinter plant was first commissioned in 1975 to supply sinter requirements for a then 3.8 million tonne steel make with a strand length and area of 84m and 420m2 respectively. As iron make increased, the fraction of sinter in the blast furnace burden decreased over time (Fig.1), with the shortfall being supplemented by increased amounts of lump iron ore, expensive imported pellets and party offset by increasing sinter plant productivity (Fig. 2). Despite the primary Ironmaking focus at Port Kembla having been blast furnace productivity, the sinter plant productive capability was significantly increased with the introduction of burnt lime in the late 1980’s. Despite its age, the sinter plant has achieved productivity well above international norms. Blast Furnace PCI operation Both blast furnaces were converted to the use of PCI in 2002. While this was done to decrease operating cost through the replacement of a portion of expensive coke with cheaper PCI coals, high PCI Blast Furnace operation offers the opportunity to increase productivity and hence decrease fuel rate. In addition, the PCI grinding and drying plant is less energy intensive than coke ovens. Obstacles to achieving the targeted PCI rate of 150 kg/t-HM have proven formidable chiefly due to blast furnace lower zone permeability issues driven by unique coke 3
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya quality challenges. However the amount and nature of sinter is also important in maximising PCI. A key factor in the improvement of PCI injection was a change in sintering philosophy in 2005 (Fig. 3) aimed at increasing the sinter hot strength, and in turn the ability of the blast furnaces to accept higher PCI rates. This involved increasing sinter FeO by increasing heat input to the strand. Part of the extra energy requirement for this would be supplied by operating at ignition gas rates above those needed for ignition alone. This approach places significant demands on the ignition and – especially- cooling capabilities of the sinter plant. These considerations influenced the nature of the sinter plant upgrade. 180 8.5 Blast Furnace 6 PCI Rate (kg/ t) 160 8 140 7.5 Sinter FeO (%) 120 7 100 6.5 80 6 60 40 5.5 20 5 0 4.5 01/ 01/ 04 19/ 07/ 04 04/ 02/ 05 23/ 08/ 05 11/ 03/ 06 27/ 09/ 06 BF6 PCI Rate (kg/ t) Sinter FeO (%) Fig.3 No. 6 Blast Furnace PCI rate, sinter FeO, 2004 – 2006. Sinter FeO target was increased in 2005 to enable sustained higher PCI rate operation. Sinter Plant Performance 2003 to 2009 The focus of capital expenditure at the Port Kembla sinter plant prior to 2009 was in areas of environmental impact. In 2003, a Sumitomo Heavy Industries (SHI) secondary Waste Gas Cleaning Plant (WGCP) was built at a cost of $93 Million to remove SOx, NOx, Volatile Organic Compounds (VOC’s) and any dust not captured by the precipitators. As a statutory licence condition, the WGCP is without the ability to be bypassed, as similar plants elsewhere can be. This creates the possibility of blockages in the char system limiting sinter plant productivity. After the commissioning of the WGCP sinter productivity became regularly limited by permeability of the activated char beds in the five adsorbers. From plant observation and process analysis it was found that alkali chlorides were largely responsible for blockages in the char beds causing production limitations in the period 2003 to 2008. These findings matched those reported by Kobayashi et al. (1980). The chief source of chlorides (more than 64% of the total) was found to be a particular Australian hematite used in the sinter blend. The significant reduction of chloride load in sinter feed with the removal of this high chloride ore in late 2008 resulted in a 4
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya significant reduction in differential pressure across the activated char adsorbers (Fig. 4). This has been taken as confirmation that alkali chlorides, together with the age and condition of the precipitators, were in fact causing blockages in the char adsorbers. This has alleviated a major cause of reduced sinter make at Port Kembla. 25 4.5 4 High Chloride Ore (%) 20 3.5 3 15 2.5 2 10 1.5 5 1 0.5 0 0 26/ 09/ 03 07/ 02/ 05 22/ 06/ 06 04/ 11/ 07 18/ 03/ 09 31/ 07/ 10 High Chloride Ore (%) Booster Outlet Pressure (kPa) Waste Gas Flow Nm3/ h (* 1000000) Fig. 4. High chloride ore % in blend, pressure and flow to WGCP 2003 – 2010. Permeability improved with high chloride ore removed from blend. Ore Preparation Upgrade Project (OPUP) 2009 The 2009 reline of No. 5 Blast Furnace presented the opportunity to upgrade the sinter plant & in turn lower operating cost and fuel rate by supplying more sinter to the furnaces. Known internally as OPUP, the Ore Preparation Upgrade Project involved the expenditure of approximately $140 Million to increase sinter make from 5.5Mt-annum to 6.6Mt-annum. Existing strand width and main fans were retained, but the strand was lengthened from 84 to 96 m to increase the grate area from 420 to 480m2. The strand was lengthened rather than widened, despite the higher capital cost, so that the original hot screen feeders could be removed and a full height cooler filling chute installed. This enabled minimisation of lateral segregation in the cooler pans, which had not been possible with the previous low height chute, as well as a reduced maintenance workload. To enable increased bed height, the strand sideplates were increased from 500mm to 700mm. The added cooling capacity required for higher sinter FeO levels was achieved through significantly improving the permeability of sinter on the cooler. This was done by widening the cooler, coupled with the improved size segregation mentioned previously, and the addition of a fourth cooler fan. An entirely new ignition furnace replaced the existing line burner. It is unusual in that it uses four burner rows instead of one, and so can be operated in various combinations to condition the strand prior to ignition, ignite the strand and sustain ignition. This offers considerable flexibility in both the profile and total amount of ignition heat that can be presented to the strand. Another difference is the use of Natural Gas instead of Coke Ovens Gas as fuel for the ignition furnace. 5
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya The ageing strand feeder was replaced with a POSCO-designed feed unit with the ability to improve particle size segregation for increased through-thickness permeability in the sinter bed, and to minimise lateral size segregation across the strand. This in turn makes burn – through at the end of the sintering strands more uniform, in turn improving productivity through the minimisation of return fines. Lastly the electrostatic precipitators were rebuilt after thirty years of service to include a fourth zone and minimise the particulate load to the WGCP. Sinter Plant Performance Post-Upgrade The sinter plant upgrade was justified on the basis of increased sinter productivity at a rate of 40.5 t/m2/d at 93% availability. Plant operating data showed that such productivities could be achieved. The operating data in Fig. 6 shows periods of operation at or above the intended target for short periods. That sinter plant productivity was generally below this target in the years leading to the upgrade was mainly due to the age and condition of the sinter plant coupled with periods of high WGCP permeability resistance, and underpinned the need for a larger, more modern sinter plant. Sintering Fundamentals Sinter plants are relatively simple in concept. Granulated iron ore fines are mixed with suitably sized coke and fluxes, ignited under suction on a moving grate. The speed of the strand is adjusted to ensure the “burn through point” is at the end of the strand. This is achieved in practice by controlling the temperature of the waste gas into the precipitators within a narrow band. However fundamental sinter productivity (P) considerations, as outlined by Loo (1993) re-expressed as a mass balance in equation 1, reveal some of the complexity behind the simple concept. 42 Sinter Productivity Upgrade Target 40.5 40 38 36 34 Degraded Machine condition and Waste Gas Cleaning Plant permeability prior to 32 Sinter plant upgrade Global median productivity 37 t/m3/d 30 17/11/2003 17/11/2004 17/11/2005 17/11/2006 17/11/2007 17/11/2008 17/11/2009 17/11/2010 Fig. 5 Sinter plant productivity 2003 – 2011, blended bed average basis. Post upgrade period circled. 6
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya P= (1-LOI) ρ (1-%H2O) (1-ε) H(L/T) W/(1+ CRF) (1) Where LOI denotes Loss on Ignition being either CO2 or chemically combined water, %H2O is “free” (not LOI) moisture, ρ denotes feed particle density, ε denotes bed voidage. The terms H(L/T)W refer to bed height, strand speed and strand width respectively. Over a fixed time the product of the three is “sintered volume”. At fixed length it relates to “flame front speed”. CRF denotes the recirculating cold return fines load. Essentially productivity is maximised by minimising the ignition loss in the feed materials, maximising the density of the feed materials, minimising the granulation moisture requirement and maximising the flame front speed. Contradictions arise and need to be managed between, say, the need for a high flame front speed and low CRF rate on the one hand, and the fact that increased flame front speed generally increases CRF. Similarly high productivity requires a permeable bed which calls for more, not less, voidage. Viewed from another perspective the Flame Front Speed (FFS) is fundamental to sintering productivity, as described in equation 2 below, outlined by Blaskett (1958) using data published by Voice and Wild (1956). hg W FFS = (2) hc (1 − ε ) Where hg denotes the heat available from the gas stream, W denotes the waste gas rate, hc, denotes the heat requirement of the solid stream. OPUP Goethite 1 High Chloride Hematite 2 Hematite 1 Sth American Hematite 1 Hematite Goethite blend Goethite 2 Sth American Hematite 2 Sth American Hematite 3 Fig. 6 Sintering ore blended bed makeup through 2010 compared to planned post upgrade “OPUP” blend (LHS Column) 7
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya Essentially flame front speed is the ratio of the heat available from the gas stream to the heat required by the solid stream. For the flame front to progress through the bed “equality of heat capacity between gas and solid is required” (Ball et al. 1973) or restated, increasing the available heat in the gas stream increases driving force for the progress of the flame front, with a higher waste gas rate implying a higher flame front speed. However permeability considerations as outlined by Ergun (1952) indicate that increased waste gas rate, all else being equal, will result in higher local gas velocities and increased pressure drop. As such, considering both equations (1) and (2), if the specific waste gas rate is increased due to increase ignition losses in the charged blend a lower flame front speed will result unless heat input and voidage are increased. Sinter productivity challenges & responses Figs. 2 and 5 show sinter plant productivity falling short of the expected rate in the post OPUP period. The main reasons for this were found to be related to the change in iron ore blend in use compared to that assumed during the preparation of feasibility studies in 2005. At Port Kembla, iron ores are blended in beds of approximately 220,000 tonnes and consumed by the sinter machine over approximately 20 days. Fig. 6 shows both the difference between the planned blend ( the “OPUP” blend) and what actually prevailed in the period following start up of the upgraded sinter machine, on a blended bed basis. The difference between the planned and actual blends, as well as the apparent large bed-to-bed variation was driven by rapid change in iron ore supply circumstances driven by high demand for iron ore worldwide. This lead to the use of Goethitic ores in place of the Hematites, at rates well above previous experience. The magnitude and pace of change in blend makeup, and the degradation of quality of the individual ores, were in sharp contrast to the incremental changes that had prevailed over many years. Coupled with newly upgraded equipment the Port Kembla sinter plant was in a new and unexpected operating regime. 115 110 Relative CO2 (% of aim) 105 100 95 90 85 Dec-10 Oct-10 Aug-10 Apr-10 Apr-11 Jan-10 Feb-10 May-10 Sep-10 Nov-10 Jan-11 Feb-11 Mar-10 Jun-10 Jul-10 Mar-11 Relative CO2 Equivalent 100% Fig. 7 Sinter CO2 intensity relative to aim January 2010 – April 2011 (includes process fuels and electricity). 8
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya Numerous changes were made to the sintering process to increase productivity in the face of these challenges. These changes and the corresponding process response are outlined in Table 1, which groups daily sinter plant operating data from the period August 2010 to March 2011; the period over which the major process adjustments were made. Data is grouped by sinter plant productivity, with days of abnormal operation removed. The correspondence between increasing productivity and decreased waste gas rate stemming from reduced LOI, brought about by ore blend and waste material rate adjustments are apparent in Table 1. Increases in limestone size, coke size and favourable changes in iron ore sizing resulted in decreased permeability resistance through the sinter bed and increased flame front speed. The rate of cold return fines decreased despite increased flame front speed. This was partly achieved through adjustments to fluxing rate and a lower sinter Al2O3 (not shown) resulting from the ore blend adjustments. Decreased ultrafine coke fraction improved green feed permeability and combustion efficiency. This is consistent with previously published literature [Loo (1991), Peters et al. (1990) Ball et al. (1973)]. These changes, which target sintering fundamentals as outlined in equations 1 and 2, simultaneously resulted in increased sinter plant productivity and decreased sinter plant CO2 intensity as seen in Table 1 and Fig. 7. Moreover, it was shown that sinter plant productivity at or above 39 t/m2/day - a figure well above the international norm of 37 – can be achieved with 45% Goethite in the blend and, importantly, a lower fuel requirement. 9
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya Table 1. Sinter plant process changes daily data August 2010 – March 2011 >32- >34.5- >36- >37.5- Productivity t/m2/d 34.5 36 37.5 39 >=39 Aim 40.5 days 15 58 63 39 13 Sintered volume (m3) (strand speed*time*w*h) 15276 16053 16737 17138 17368 16070 Net Waste Gas Rate (Nm3/t) 1795 1723 1691 1648 1599 1543 Coke & Anthracite rate (kg/t) 57.7 56.7 55.7 54.3 53.8 Sinter plant process fuel CO2 (kg-CO2/t- sinter)* 192 190 187 182 180 Permeability Resistance 33.6 33.5 32.3 31.6 31 Flame Front Speed (mm/min) 21.5 22.4 23.2 23.9 24.3 24.5 Cold Return Fines (%) 34.1 33.6 33.7 32.8 31.2 27 South American Hematites (%) 14 14.2 15.5 16.9 18.4 Hematite 1 (%) 15.2 16.2 16.2 16.4 14.9 Goethitic Ore 1 (%) 40.1 38.8 39.7 43 45 Hematite/Goethite blend (%) 11.3 7.9 5 1.7 - Sth American Hematite 1 LOI (%) 2.2 2.1 2 1.9 1.8 Hematite 1 LOI (%) 3.1 3.1 2.9 2.8 2.8 Virgin Ore Weighted LOI (%) 5.25 5.27 5.17 5.09 4.94 4.28 Waste Material Rate (wet % ) 0.94 0.97 0.9 0.47 0.44 Ore feed LOI (%) 6.91 6.81 6.69 6.34 6.3 6.0 Blend Mean Size (mm) 3.67 3.25 3.36 3.36 3.64 3.55 min Blend %+250micron- 1mm 13.7 13.5 13.2 13.2 12.8 13.6 max Blend ratio -250/+1mm 0.32 0.31 0.3 0.32 0.25 0.3 max Blend %-63 Micron 11.1 10.7 10.9 12 9.6 13 max Limestone % +4mm 7.6 7.1 9.8 15.6 15.8 Limestone % -125 Micron 17.9 18.3 17.3 15.8 15.2 Coke % +4 mm 13.7 12.7 14.4 16.9 21.3 Coke % -250 Micron 21.4 20.6 20.2 19.3 17 *Natural Gas, Coke and Anthracite: Ore blend and sinter plant performance The ore blend characteristics are fundamental to the sintering process. Fig. 8 shows both the particle (true) density of ores in the blend, and the LOI of the ores as functions of typical Fe content. It is clear that higher grade ores are denser and contribute less waste gas per tonne than lower grade ores. This effect was the main process cause of the productivity shortfall at the newly upgraded sinter plant. From 2004 the quantity of goethite in the blend had been gradually increased. The rate of Goethite use further increased to offset decreased rates of Hematite ore brought about by alumina, alkali chloride content, cost and other supply constraints. Goethite 1 is an Australian ore that offers the benefits of low alumina and phosphorus required by the blast furnaces and 10
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya steelmaking shop. Fig. 9 shows the sinter plant productivity response to increasing amounts of Goethite 1 and the corresponding increase in weighted ore LOI. The effect of partially reversing this trend is apparent in Table 1. It is also apparent that the “sintered volume” required to achieve a given sinter productivity is higher than that assumed in the plant design, reflecting the lower density of the current ore blend. 5.1 Sth American Hematite 1 4.9 Sth American Hematite 3 4.7 Hematite 1 4.5 High Chloride Ore Density 4.3 Goethite/Hematite 4.1 3.9 Goethitic 1 3.7 3.5 %Fe 10.0 Goethite 1 9.0 8.0 7.0 Ignition Loss (wt%) 6.0 Goethite / Hematite 5.0 4.0 Hematite 1 3.0 High Chloride Ore 2.0 Sth American Hematite 3 1.0 Sth American Hematite 1 0.0 57 58 59 60 61 62 63 64 65 66 %Fe Fig 8 Ignition Loss (waste gas rate) and Particle Density t/m3 of various iron ores as a function of typical Fe content (Density Data C/- Dr. D. Maldonado BlueScope Steel). Burnt lime is used in many sinter plants worldwide to increase productivity by improving on-strand permeability. Fig. 10 shows the rate of burnt lime consumption at Port Kembla since it’s introduction in the late 1980’s. Compared with recent experience at comparable sinter plants the burnt lime rate at Port Kembla is low, and represents an opportunity to offset the detrimental productivity impact of Goethitic ores, however the current burnt lime rate represents the full productive capability of the supplier. 11
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya % Goethite 1 Virgin Ore Blend Weighted LOI 60 6.5 % Goethite 1 in sintering blend 55 Weighted Virgin Ore LOI (%) 6 50 5.5 45 5 40 4.5 35 4 30 25 3.5 20 3 1/ 4211/ 200315/ 03/ 200528/ 07/ 200610/ 12/ 200723/ 04/ 20095/ 09/ 2010 41 Sinter Productivity (t/ m2/ d) 40 39 38 37 36 35 34 33 32 1/ 11/ 03 15/ 3/ 05 28/ 7/ 06 10/ 12/ 07 23/ 4/ 09 5/ 9/ 10 Sinter Productivity Fig. 9 Goethite 1 percentage in sintering blend, weighted average Iron Ore LOI and corresponding sinter plant productivity 2003 – 2011 14 12 10 8 6 4 2 0 1981 1986 1991 1996 2001 2006 2011 Burnt Lime Rate (kg/ t) Fig 10. Burnt lime rate (kg/t-sinter) at the Port Kembla Sinter Plant 1989 – 2011. Burnt lime feed rate has been at the limit of the feeding system since 2007. Typical burnt lime rate for comparable plants is 15 – 20 kg/t-sinter. 12
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya Sinter reducibility, Goethitic ores and Blast Furnace Fuel Rate. While high goethite rate is detrimental to sinter productivity, it is also known to be beneficial for sinter reducibility [Loo (1991)]. Fig. 11 shows sinter reducibility at Port Kembla, determined by the standard test, as a function of the amount of Goethite 1 in the blend. This plot corresponds to the time period from 2004 shown in Fig. 8. 69 68 67 Sinter Reducibility (%) 66 65 64 63 62 61 60 59 58 20 25 30 35 40 45 50 55 60 %Goethite 1 in sintering blend Fig. 11 Sinter reducibility as a function of Goethite 1 content in the sintering blend 2003 – 2011 blended bed (~20 day) average basis. As part of the analysis that yielded the relationship between sinter burden and blast furnace fuel rate, mentioned previously in the present work, it was also found that for a given amount of sinter in blast furnace feed • + 1% “Goethite 1” in sintering blend = -0.15 kg/t Blast Furnace Fuel Rate While such a relationship is not unexpected given the relationship in Fig. 10, and previous findings by Loo (1991) a direct relationship between an individual ore type in the sinter and blast furnace fuel rate performance has not previously been documented. Moreover multiple linear regression analysis showed, somewhat surprisingly, that correlation between Goethite 1 in sinter and blast furnace fuel rate was stronger and of higher confidence than the correlation between sinter reducibility and blast furnace fuel rate. This means that different sinters with similar physical standard reducibility test results may in fact respond very differently in the blast furnace due to the mineralogy of the ores they were made from. This finding is highly significant. It means that the goals of maximising both the reducibility and the amount of sinter are in conflict with each other. However the present work shows that overcoming productivity impediments associated with the use of Goethite can yield an additional blast furnace fuel rate benefit beyond that accruing from the use of more sinter alone. Present challenges and future opportunities. The largest opportunity to decrease fuel rate on the upgraded sinter machine, and with it greenhouse emissions, is by making full use the natural gas capability of the new 13
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya ignition furnace. At the time of writing, the natural gas rate is approximately 50GJ/t- sinter, or little over half of the available natural gas capability. Analysis of fuel consumption data shortly after commissioning showed that increasing the natural gas rate could permit decreases in solid fuel rate at a replacement ratio of 1.7:1 joules coke/joule gas at constant sinter FeO. This equates to a decrease in solid fuel rate of up to 2.4 kg/t-sinter or about 4% of current sinter machine solid fuel requirement. The ability to increase natural gas above current levels is presently limited by the need to fully optimise solid fuel size distribution and through-thickness placement on the sinter strand with the upgraded feeder. It has been found that the sinter plant solid fuel rate is sensitive to the settings of the new feeder, with lower solid fuel rates being associated with improved uniformity of lateral material placement. Lower solid fuel rates are also associated with a shallower charging angle on the lower feed plate that is the departure point for material directly on to the strand. The mechanism for this is thought to be more even placement of solid fuel and fluxes through the thickness of the bed. Increased sinter productivity through the addition of sugar or molasses (Loo 1995) to granulation water was successfully tested at Port Kembla in short term plant trials in the 1990’s. However sugar is costly and molasses had negative environmental consequences. With the subsequent installation and successful de-bottlenecking of the Waste Gas Cleaning Plant, and limitations to burnt lime supply, revisiting the use of sugars as sintering accelerants to supplement burnt lime and decrease granulation water load is opportune. These materials also afford the advantage of being renewable substitutes for some of the solid fuel. In the longer term, more extensive use of renewable biomass derived products, as outlined by Dell’ Amico et al. (2004), Lovel et al. (2005) and Mathieson et al. (2011), warrant vigorous exploration. CONCLUSIONS Maximising the amount of highly reducible sinter in the blast furnace feed is a key part of decreasing operating cost and CO2 emissions at an integrated steel plant. Measures taken to maintain and enhance sinter plant productivity fundamentally assist these objectives. The Port Kembla sinter plant was upgraded in 2009 from 420 to 480 m2 to enable production of sinter at a rate in excess of 40.5 t/m2/d. The major cause of initial productivity shortfalls post upgrade was the requirement to use more goethitic ore than originally planned owing to iron ore supply constraints. The negative effects of this were identified, and successfully offset through means directed at fundamentally improving sintering permeability and flame front speed; measures which also decreased sinter plant CO2 intensity. A previously undocumented relationship was found between the extent of Goethite used in making sinter and blast furnace fuel rate. This relationship was found to be stronger than the relationship between sinter reducibility as measured in standard tests and Blast Furnace fuel rate further highlighting the value in offsetting negative sintering productivity due to Goethite. 14
N. Di Giorgio, D. Brace, A. Bennett, K. Wijekulasuriya REFERENCES Ball D.F, Dartnell J, Davison J, Grieve A, Wild R, “Agglomeration of Iron Ores” Heinemann Books ISBN 0 435 720104 , 1973. Blaskett D.R Sintering symposium, Port Pirie 1958 Australas. Inst. Min.Metall., 1960 61-70 Dell’Amico M, Fung P, Lovel, R, Manuel J, O’Connor M, Green Iron Ore Sintering; Green Processing Conference, AusIMM Fremantle 10-12 May 2004 pp73-80 Ergun S. , Chem. Process Eng. London 48, 89 1952 Greenhouse and Energy Information 2009 – 2010. Australian Government Department of Climate Change and Energy Efficiency, National Greenhouse and Energy Reporting ISO Standard 7215 Ore reducibility by final degree Kobayashi, Okamoto, Miura “Behavior of Alkali Compounds in the Sintering Process” Trans ISIJ, Vol. 20, (1980) Loo C.E. “The role of coke size in sintering of a hematite ore blend” – Ironmak. Steelmak., 18. No 1 1991, 33 Loo C.E “ Influence of a pisolitic limonite on sintering of an Australian iron ore blend “ Trans. Instn Min. Metall. (Sect C: Mineral Process Extr. Metall.), 100 Sep-Dec 1991 Loo C.E Proc. 6th Int. Symp on Agglomeration 93, The Society of Powder Technology, Kyoto, (1993), 170 Loo CE, Penny GC and Witchard D, "Effective Sintering of Iron Ore Blends Containing Porous Ores at Low Moisture", Trans. Inst. Min. Metall. (Sect. C: Mineral Process. Extr. Metall.) Vol 105, 1995, pp.C22-36. Lovel R, Vining K., Dell’Amico M; Iron ore sintering with charcoal; Iron Ore Conference, AusIMM. Fremantle, 19-21 September 2005 pp1-9 Mathieson J.G, Rogers H, Somerville M, Ridgeway P and Jahanshahi S, “Use of Biomass in the Iron and Steel Industry – An Australian Perspective”, 1st International Conference on Energy Efficiency and CO2 Reduction in the Steel Industry, Düsseldorf, 27 June – 1 July 2011, Session 9, pp.1-10. Peters K.H, Beer H, Kropla H.W, Muller H . Proc. 6th International Iron & Steel Congress 1990 Nagoya ISIJ 103-109 Voice E.W, Wild R. JISI 1956, 183, 404-10 BRIEF BIOGRAPHY OF PRESENTER Nicholas Di Giorgio BE Eng Materials (Hons) MSc (UNSW) is a Senior Development Engineer in Ironmaking Technology at BlueScope Steel’s Port Kembla Steelworks. He has extensive experience in Process Operation, Process Analysis and Improvement in the Blast Furnace and Sinter plant realms having driven numerous improvements & undertaken extensive plant based Research in the areas of blast furnace operation, iron and slag product quality, blast furnace and sinter plant productivity, fuel consumption, Blast Furnace PCI capability, the impact and nature of carbonaceous and ferrous raw materials and Ironmaking Greenhouse impact. 15
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