OYSTER Big ideas from small particles

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OYSTER Big ideas from small particles
Delft University of Technology

                                 OYSTER
                                 Big ideas from
                                 small particles
OYSTER Big ideas from small particles
Neutron research in brief
     OYSTER                                                            Why neutron research?
                                                                       Neutrons are released when atomic
     a penetrating look                                                nuclei split. These extremely tiny
                                                                       particles penetrate deeply into material

     into matter                                                       exposed to them. By measuring changes
                                                                       in the neutrons’ speed and direction
                                                                       when they collide with atoms, we are
                                                                       able to look inside materials while the
                                                                       materials themselves remain intact. With
                                                                       the knowledge thus derived, we gain an
                                                                       idea of how materials originated and the
                                                                       processes which play a role. This allows
                                                                       us to change materials according to our
OYSTER is the project that will make the                               specifications and give them the best
                                                                       properties for their function.
research reactor of the Reactor Institute Delft
(RID) considerably broader and more precise                            How does this neutron research
                                                                       work now?
in its applicability. With OYSTER, the neutrons                        The neutrons produced through atomic
generated in the reactor are cooled by a device                        fission in the research reactor are ”let
containing liquid hydrogen, slowed down and                            loose” on materials. Around the research
                                                                       reactor are numerous extremely
made steerable in beams. This makes new and                            advanced and mostly unique instruments
better measurement techniques possible, even                           for making measurements. Neutrons
                                                                       have not only the desirable property
allowing us to monitor the production of materials                     of penetrating deeply into materials,
and nutrients in real time.                                            they also have the vexing trait of being
                                                                       difficult to control. They cannot be
                                                                       steered with electrical or magnetic fields.
                                                                       Focusing them with lenses also has very
     OYSTER offers enormous benefits for                               little effect. The neutrons simply go
                                                                       every which way.
     international science, health care and
     industry.                                                         What major improvements will
                                                                       OYSTER bring?
                                                                       These are numerous. There is
                                                                       enormous benefit in being able to
                                                                       better manipulate neutrons despite their
The RID is setting the pace worldwide with the development             physical elusiveness. New measurement
and production of instruments for research using neutrons.             possibilities arise and existing methods
These tools are widely used in research centers. Since                 will be improved a hundredfold.
experimental and fundamental research programs are
possible at the research reactor in Delft, the reactor plays an
indispensable role among major international institutions. After
OYSTER, this position will be strengthened by more research,
greater precision, and greater spin-off benefits for society.

OYSTER’s new capabilities ensure:
n continuation of our edge among top international institutes
n a boost for scientific research at the TU Delft
n a boost for product development in the Netherlands and far
  beyond
n development of more effective treatment methods in health
  care
n new possibilities for energy generation and storage

The OYSTER project (Optimized Yield – for Science, Technology
& Education – of Radiation) requires an investment of
approximately 20 million euros and will be operational in 2012.

                                                                   1   OYSTER
OYSTER Big ideas from small particles
RID: Knowledge Center &
                                                                                                                 The improved reactor
     OYSTER                                                           Innovator                                  better, faster and more precise                                                                                    Heat production
                                                                                                                                                                                                                                         3 MW

     what does it                                                     The Reactor Institute Delft is a magnet
                                                                      for scientists. Rising talent as well as
                                                                      esteemed scientists are attracted to
                                                                                                                 measurements                                                                                                            Speed
                                                                                                                                                                                                                                    of cold neutrons
                                                                                                                                                                                                                                         500 m/s

     deliver?                                                         cutting edge research with unique
                                                                      instruments.
                                                                                                                   Water function 1: Water slows down fast neutrons                                                                 Intensity of cold
                                                                                                                                                                                                                                      neutron beam
                                                                                                                 One of the three neutrons [4] (on page 4) released by nuclear fission must split another uranium
                                                                      Through OYSTER, major limitations                                                                                                                              1 billion neutrons
                                                                                                                 atom to keep the chain reaction going (the other neutrons are available for experiments). The speed
                                                                      in the current neutron technology are                                                                                                                            per s per cm 2
                                                                                                                 of these fast neutrons is so great (20 million m/s) that almost all neutrons fly off without hitting a
                                                                      removed. Currently, ”warm” snapshots       uranium nucleus. When the reaction takes place in water, the neutrons
                                                                      are only made at a short distance from     collide with the water molecules and are slowed so dramatically
                                                                      the source because that is the only        (to 2000 m/s) that they are able to react with the uranium
                                                                      place enough neutrons can be captured.     nuclei. Without water no chain reaction occurs, and
More neutrons, more power, more speed, and                            Through OYSTER, scientists will be much    the nuclear fission stops.                                                                                                       Water pool
fundamentally better results. This is the best way                    less hindered by these limitations. With                                                                                                                           The reactor core sits
                                                                      the five existing and four advanced                                                                                                                                      in a water pool
to describe OYSTER. It is a logical consequence                       instruments still to be built, the                                                                                                                                  (depth 8 m, volume
of the success and the continuing further                             measurement capabilities will become                                                                                                                                            250 m3).
                                                                      more precise and more versatile.                                                                                                                                       The thickness of
development of the Hoger Onderwijs Reactor that                       Measurements can be made with both                                                                                                                                    the concrete wall
became operational in 1963.                                           ”warm” and ”cold” neutrons; snapshots                                                                                                                                   varies from 1 to
                                                                      as well as process-related findings can    Circa 10 m                                                                                                                      about 2.5 m.
                                                                      be established.
With OYSTER, the neutron source is coupled to a coolant of
liquid hydrogen. At extremely low temperatures (250 degrees           The RID is part of an international
below 0 Celsius), the properties of neutrons change in such a         network of top institutes that procure       OYSTER EXPANSION                                                                                                                 Neutrons
way that they can more easily be guided and directed. In a box        knowledge and instruments in Delft for
                                                                                                                   More power                                                                                                           The 100 million billion
a (production) process is simulated (temperature, pressure,           their own research. The RID has been                                                                                                                                   neutrons that are
                                                                      asked to contribute to the European
movement, mixing). The neutrons are steered crossways                                                            The thermal power (heat                                                                                                      generated every
                                                                      neutron institute under development, the                                                                                                                           second in the reactor
through the box, and we see how the material being studied                                                       production) of the reactor
                                                                      European Spallation Source. For a large                                                                                                                                 core fly off in all
reacts to the treatment – in some cases even when changes                                                        will be increased from 2 to
                                                                      group of (international) companies, the                                                                                                                             directions. Neutrons
occur quickly.                                                                                                   3 MW. By splitting more
                                                                      RID is of vital importance in developing                                                                                                                                  are uncharged
                                                                                                                 uranium per second, 1.5
                                                                      products for the food industry,                                                                                                                                             particles and
                                                                                                                 times more neutrons are
                                                                      microelectronics, steel and plastics                                                                                                                                therefore cannot be
                                                                                                                 generated. About 3 grams
What does OYSTER deliver?                                             production, etc.
                                                                                                                 of uranium are then used                                                                                                         steered with
                                                                                                                 per day.                                                                                                                             magnets.
The potential is vast. For example, through OYSTER we can see         In the health care sector, the Reactor
                                                                      Institute Delft works with research
in real time:
n how hydrogen is stored in special metallo-organic buffers
                                                                      hospitals in developing diagnostic
                                                                      methods and treatments for fighting
n how ultrathin coatings peel from surfaces                                                                      Beam tubes
                                                                      cancer and other diseases.
n how foods change their structure through movement, cooling                                                     Researchers want to conduct
                                                                                                                 experiments with neutrons. Six beam                                                                                                     Water vapor
   or heating. We therefore learn more about curdling and             In the energy sector, neutron research
   coagulation processes, important for the development of diet                                                  tubes (diameter 20 cm) must lead the
                                                                      leads to better methods of storing
   foods.                                                                                                        neutrons from the pool to the experiments.
                                                                      energy with hydrogen and batteries.
n under what circumstances types of steel and plastic attain                                                     Neutrons that fly more or less straight into the
   their optimal properties                                                                                      beam tubes will reach the experimental setup. All other
n under what circumstances and how the magnetic properties
                                                                                                                 neutrons fly through the tube wall and are absorbed by the tube
                                                                                                                 walls, the water and the concrete. Through OYSTER, about one in
   of materials change
                                                                                                                 every million neutrons will reach an experimental setup.
n how dune sand behaves under changing conditions so that
   we can make judgments about our sea walls
n how change processes occur in mixtures such as paint                                                                                                                                                  Primary cooling circuit      Secondary cooling circuit

                                                                                                                   Water function 2: Water cools the reactor core
                                                                                                                                                                                                   RESEARCH REACTOR
                                                                                                                 All heat released by the nuclear fission is led off through the water in the      In a normal nuclear plant, the heat released by nuclear
                                                                                                                 pool [5]. A pump ensures circulation (288 m3/h) through the pool. The             fission is used to generate steam. The steam drives
                                                                                                                 cooling water is suctioned off via a funnel along all the fuel plates. The        turbines which produce electricity.
                                                                                                                 warm water releases its heat in a heat exchanger [6] and once cooled              The goal of the Delft reactor is to generate neutrons
                                                                                                                 (max. 40 o C), flows back into the pool [7]. The secondary cooling system         for conducting scientific experiments.
                                                                                                                 discharges its heat to the environment [8] through evaporation into the air.

                                                                  2   OYSTER                                                                                                                          3     OYSTER
OYSTER Big ideas from small particles
COLD NEUTRONS                                                             New control rods                                                                Ventilation shaft                                   OYSTER EXPANSION
                                                                          Six aluminum tubes filled with boron carbide can be inserted into the reactor   Ventilators suck the air out of
The main advantage of ”cold” neutrons is their greater                    core. If two of these control rods are lowered completely into the core, they
                                                                                                                                                                                                              Result of planned expansion
                                                                                                                                                          the hall [2] and conduct it via a
tendency to remain in the beam guides; consequently, 100                  absorb all free-flying neutrons and thereby stop the nuclear fission. If a      filter and a ventilation shaft
times more neutrons reach the experiments than with ”warm”                                                                                                                                    Clean air   The total neutron intensity of the modified reactor will be
                                                                          power outage occurs, the control rods fall into the core by themselves.         (height 60 m) outside.
neutrons. A second advantage is that with the greater                                                                                                                                                     100 times greater than that of the current reactor, allowing
                                                                                                                                                          Detectors measure the vented
wavelength of ”cold” neutrons, larger structures become                                                                                                                                                   larger structures or smaller details in studied materials to
                                                                                                                                                          air for the presence of
visible. A third advantage is that the ”cold” neutrons move less                                                                                                                                          become visible than we can currently see. In addition,
                                                                                                                                                          radioactive compounds.
quickly through a test material, allowing more precise                                                                                                                                                    measurements can be taken 100 times more quickly than
                                                                                                                                                          As soon as radioactivity is
measurements. To make cold neutrons, the current reactor                                                                                                                                                  is currently the case.
                                                                                                                                                          measured, the gastight valves
must be fitted with a neutron cooler [1] which slows the fast,
                                                                                                                                                          close off the airflow and the
”warm” (40 o C) neutrons to slower, ”cold” neutrons (-250o C).
                                                                                                                                                          reactor is shut down.
The measurements will then take much less time and will yield
more information.

                                                                                                                                                          Reactor building
                                                                                                                                                          In the airtight steel hall [3]
                                                                                                                                                          (diameter 25 m, height 28 m)
                                                                                                                                                          a lower air pressure ensures
                                          Reflector elements                                                                                              that no air can leak into the
                                          Beryllium reflectors                                                                                            environment.
                                          (a metal that absorbs
                                          almost no neutrons)
                                          must reflect as many
                                          free-flying neutrons as
                                          possible to the fuel
                                          elements.
                                                                                             Neutrons

                                                                                     Beam guides
                                                            Uranium
70 cm

  OYSTER EXPANSION                                                                                                 OYSTER EXPANSION

  New reactor configuration                                                                                        Neutron cooler

The new reactor core has nine fuel elements (instead of                                                         Right next to the nuclear reactor a
the current 20 elements).                                                                                       reservoir is placed containing liquid
                                                                                                                hydrogen (temperature -250 o C).
                                                                                                                The neutrons that are released in the
Current fuel plates                                                                                             reactor fly through the cold hydrogen,
Each fuel element (8 x 8 x 60 cm) consists of 19 fuel                                                           which slows their speed from 2000 m/s
plates. A fuel plate is an airtight aluminum box                                                                to 500 m/s. The reservoir consists of
containing a thin sheet of uranium silicide. The reactor                                                        an aluminum tank with inlets and
core contains a total of 4 kg of uranium.                                                                       outlets leading to a heat exchanger.

Nuclear fission in the fuel plates
Neutrons fly through the aluminum cladding and cause
nuclear fission of the uranium. All isotopes produced by
                                                                                                                High-energy radiation                                                                     Experimental hall
the fission reaction remain in the fuel plate and never
end up in the water. The high-energy radiation is largely
absorbed by the aluminum cladding (the rest by the
                                                                                                                                                                                                          Aim of the reactor: neutron research
water). The energy generated is released into the water            Uranium nucleus
                                                                                                                                                                                                          In the measurement instruments around the research
that flows between the plates (3 mm space between the
                                                                                                                                                                                                          reactor, neutrons are directed at a piece of test material.
plates).
                                                                                                                                                                                                          The neutrons change speed and direction as they collide
                                                                                                                                                                                                          with atoms in the test material. Through the diffraction or
Nuclear fission of uranium                                                                                                                                                                                scattering of the neutrons measured, we obtain an
                                                                                                                                          Three free
Atoms consist of a cloud of negatively charged particles                                                                                                                                                  ”image” of the composition and structure of materials at
                                                                                                                                           neutrons
(electrons) that orbit around a nucleus of positive particles                                                                                                                                             the atomic level which cannot be achieved in any other
(protons) and uncharged particles (neutrons). When a                                                                                                                                                      way.
neutron from outside collides with a uranium nucleus and
the atom takes that neutron into its nucleus, the uranium
                                                                                                                                                                                                              OYSTER EXPANSION
nucleus splits into two smaller nuclei and three neutrons.           Free neutron
The mass of the fission products is smaller than that of the                                                                                                                                                  New instruments
fissionable material because the reaction converts some
mass into energy. This energy is released as kinetic energy                                                                                                                                               In addition to the five existing instruments, three new
and high-energy radiation. Fission of one gram of uranium                           Proton                                                                                                                instruments will be built which only work with ”cold”
releases 24.000 kWh of energy. This is equivalent to                                                                                                                                                      neutrons. These new instruments will permit measure-
burning 2.500 liters of gasoline.                                                                                               Fission product                                                           ments that are currently impossible.

                                                                                         4      OYSTER                                                                                                    5    OYSTER
OYSTER Big ideas from small particles
ROG is an existing instrument that will             External radiation                                                                           Liposome
                                                                   perform 100 times better with OYSTER.               High-energy radiation [1]                                                                    Liposomes are small, hollow spheres
                                                                   Apart from layer thicknesses themselves, the        destroys tumor cells. External                                                               of fat (diameter about 0.01 mm).

     Better                                                        roughness of layer surfaces will also become
                                                                   visible.
                                                                                                                       radiation of a patient has the
                                                                                                                       major disadvantage that the
                                                                                                                       radiation also destroys healthy
                                                                                                                                                                                                                    The wall consists of a double layer of
                                                                                                                                                                                                                    molecules whose head dissolves in
                                                                                                                                                                                                                    water and whose tail dissolves in fat

     semiconductors                                                In the production of chips, mirrors are used
                                                                   for directing extreme-UV light. The coatings
                                                                                                                       cells.                                                                                       (comparable to a soap).
                                                                                                                                                                                                                    The hollow liposomes are well suited

     and artificial hips
                                                                                                                                                                                                                    to transporting a medicine [2]
                                                                   on these mirrors are extremely critical: the                                                                                                     through the body. The fat sphere
                                                                   slightest film or residue dramatically reduces      Making a liposome with a                                                                     then works as a packaging which

     with ROG
                                                                   the reflection. This can be examined using the      radioactive core                                                                             keeps the medicine isolated until it
                                                                   ROG.                                                A capsule of liposomes containing a                                                          arrives at a diseased cell. There the
                                                                   For an artificial hip, the quality of the coating   holmium atom, for example, in their                                                          package must open so that the
                                                                   determines whether or not it will be rejected       hollow interior, is placed next to the                                                       medicine can do its work.
                                                                   by the body. With ROG the quality of this sort      reactor core via a tube [3]. The neutrons
                                                                   of coating can be determined with extreme           make the holmium atom radioactive. The fat
An instrument that promises improved products in numerous          precision, and any deterioration can be             sphere absorbs almost no neutrons, and the
sectors is the Reflectometer for Surfaces and Interfaces           monitored.                                          radioactivity induced in the fat is so short-
Research (ROG). This instrument can look at the thinnest                                                               lived that it has already disappeared before
                                                                                                                       the sphere leaves the reactor.
layers and coatings. ROG measures how neutrons reflect at
a grazing angle of incidence. From this can be deduced how
carbohydrates bind to various materials, how magnetic layers
on tapes and hard drives behave and how coatings adhere to
materials for artificial hips.

                                                                                                                                                                                                              Liposome
                                                                                                                                                                                                           diameter 0.01 mm

                                                                                                                                                                                 Gamma radiation destroys liposomes
                                                                                                                                                                                 The reactor core gives off not only
                                                                                                                                                                                 neutrons but also gamma radiation.
                                                                                                                                                                                 This gamma radiation can destroy the
                                                                                                                                                                                 structure and the wall of the fat spheres,
                                                                                                                                                                                 releasing the holmium atoms [2] from
                                                                   OYSTER will give this medical development                                                                     their packaging. In order to prevent this,
                                                                   a substantial boost. CNIF allows extremely                                                                    the fat sphere is now irradiated at a site
                                                                   pure nuclear medicines or therapeutic                                                                         far from the reactor core where there is

     Better                                                        materials to be made. The current generation
                                                                   of radionuclides contains many inactive             Neutrons
                                                                                                                                                                                 little gamma radiation, but also few
                                                                                                                                                                                 neutrons. More neutrons would make the
                                                                   components. These sometimes have
     treatment of
                                                                                                                                                                                 holmium radioactive more quickly.
                                                                   undesirable chemical properties with adverse           Cold source
                                                                   health effects. Or they needlessly saturate
     cancer                                                        the tumor being treated, thus reducing the
                                                                   effectiveness of the radiation.
                                                                                                                         OYSTER EXPANSION: CNIF
                                                                                                                                                                       Liposomes
                                                                                                                         Cold neutron source
     with CNIF                                                     With CNIF we are able to separate out the
                                                                   inactive molecules in radionuclides, leaving
                                                                                                                        The new cold source [4] will
                                                                                                                                                                                                                              Internal radiation
                                                                                                                                                                                                                              A liposome containing a
                                                                                                                        fulfill a double function.
                                                                   behind a practically pure and extremely              First of all, the cold source slows
                                                                                                                                                                                                                              radioactive atom in its
                                                                   effective radioactive material. This allows for a                                                                                                          hollow interior is injected
                                                                                                                        down the neutrons so that they
                                                                   more effective combating of cancer cells and                                                                                                               into the body. Within a
                                                                                                                        collide more frequently with the
With the Cold Neutron Irradiation Facility (CNIF), materials can   a reduction in side effects.                                                                                                                               minute the liposome
                                                                                                                        holmium atoms.
be made radioactive. This instrument is placed strategically                                                                                                                                                                  arrives at its destination
                                                                                                                        Second, the reservoir of liquid
behind the cold source, where it receives many cold neutrons                                                                                                                                                                  and becomes wedged
                                                                   The manufacturing of this sort of ”nuclear           hydrogen functions as a shield
                                                                                                                                                                                                                              inside a tumor. The
and little gamma radiation. CNIF thus makes complex structures     medicine” must take place in close proximity         against gamma radiation. The
                                                                                                                                                                                                                              radioactive atom briefly
radioactive without destroying them.                               to treatment centers. The radioisotopes              quantity of neutrons reaching the
                                                                                                                                                                                                                              releases high-energy
                                                                   are often short-lived and must therefore be          liposomes is maximized without
                                                                                                                                                                                                                              radiation. The radiation
This capability offers useful perspectives for new treatment       applied in a treatment within a few hours;           destroying the fat sphere with
                                                                                                                                                                                                                              stops the growth of the
methods for serious forms of cancer. The Reactor Institute Delft   otherwise they lose their effectiveness.             the damaging gamma radiation.
                                                                                                                                                                                                                              tumor cells while the
is currently working with research hospitals in the development                                                         This allows more effective
                                                                                                                                                                                                      High-energy             surrounding, healthy cells
of a new generation of radioisotopes. These are, in a manner                                                            medicine packages to be
                                                                                                                                                                       Tumor cells                     radiation              remain unharmed.
                                                                                                                        produced.
of speaking, nuclear medicines that fight cancer cells very
precisely without damaging healthy tissue.
                                                                                                                                                                 Tumorcellen

                                                                   6    OYSTER                                                                                                                        7     OYSTER
OYSTER Big ideas from small particles
Texture in storage                    Scattering through fat                  OYSTER EXPANSION: SESANS
                                                                                                                                                              In the ideal case, the texture   When a neutron moves through
                                                                                                                                                              in a sealed tub of cheese        cheese spread and collides with a            Better measurement

     Innovative                                                                                                                                               spread is fixed (from the
                                                                                                                                                              factory to the consumer) [6],
                                                                                                                                                              so that all fat spheres remain
                                                                                                                                                                                               fat sphere, the neutron changes
                                                                                                                                                                                               direction [9]. The path length of
                                                                                                                                                                                               the neutron through the second
                                                                                                                                                                                                                                            With “warm” neutrons, SESANS
                                                                                                                                                                                                                                            can measure 10,000 times faster

     food products
                                                                                                                                                                                                                                            than the classical apparatus with a
                                                                                                                                                              in place and the cheese          magnetic field therefore changes,
                                                                                                                                                                                                                                            projection screen, allowing us to
                                                                                                                                                              cannot separate into a fat       making the neutron swing less to
                                                                                                                                                                                                                                            see structures 100 times greater
                                                                                                                                                                                               the right than to the left. The final
     with SESANS
                                                                                                                                                              later and a water layer.
                                                                                                                                                                                                                                            (to 10 micrometers). With long
                                                                                                                                                                                               orientation of the neutron
                                                                                                                                                                                                                                            wavelength “cold” neutrons the
                                                                                                                                                                                               has now changed.
                                                                                                                                                                                                                                            size becomes 20 micrometers;
                                                                                                                                          Polarized neutrons                                                                                OYSTER also allows a measure-
                                                                                                                                     Using a crystal and a mirror, all the                                                                  ment to be taken in 1/100th the
                                                                                                                                     neutrons of one speed and orientation                                                                  time.
                                                                                                                                     are selected [7].

The Spin Echo Small Angle Neutron Scattering facility (SESANS)                                       Fat spheres in water
is a neutron polarizer. This instrument measures the scattering                                      Cheese spread consists of
of the neutrons. The polarized neutrons change direction                                             small spheres of fat and
through collision with atoms in the research material. This                                          water. The size and
scattering angle is measurable through the trick of converting                                       consistency of the fat
it into rotation. This trick allows supersmall scattering angles to                                  spheres determine whether
be measured, shedding light on the larger-scale structure within                                     cheese tastes ”creamy.”
the research material.                                                                               A loose distribution of fat
                                                                                                     spheres [1] of about 1
                                                                                                     micrometer is experienced
Food products are being prepared at ever greater distances
                                                                                                     as creamy, while a clump of
from the places where they are consumed. The composition of
                                                                                                     spheres [2] larger than 10
foods is also being more precisely tuned to the dietary needs of                                     micrometers is experienced               Guide field
western consumers. With SESANS, we can look into the food to                                         as grainy. It is not possible
observe how it is affected by preparation.                                                           with a microscope to see the
                                                                                                     behavior of fat spheres                         Inclined
With OYSTER the possibilities are greatly increased because we                                       inside cheese because it is                   magnetic field                                   Cheese                                       Neutron counter
can observe changes in real time. We can, for example, literally                                     not transparent. But with
watch milk turn into cheese and thus learn to predict what                                           SESANS, it is possible.
the effect of a given treatment on this food will be. Cooling,                                                                            Opposite fields                                          Seeking maximum polarization                   Size of spheres
heating, stirring and shaking, centrifuging or ripening. With this                                                                   The polarized neutrons move through two inclined          By increasing the strength of the            From the size of the magnetic field, the
knowledge we can also take post-manufacturing effects into            Unsteerable neutron                   Magnetic field           planes with opposite magnetic fields. Regardless of       magnetic fields, a moment arises when        speed of the neutrons and their speed
account.                                                              A neutron has no charge and                                    the neutrons’ angle of incidence, the path traveled       the scattered neutron has swung              of rotation, the difference in path
                                                                      does not change its direction of                               in both planes is equally long, thus a neutron swings     exactly one time fewer to the right          length through the magnetic fields and
                                                                      movement [3] when it moves                                     just as often to the left as to the right in the two      than to the left. When the neutrons          therefore the scattering angle      of
With OYSTER we can ensure that an ice cream bar tastes even
                                                                      through a magnetic field.                                      fields. At the end of the measurement device [8],         were selectively scattered at that           the neutron can be calculated. The
better after it has left the factory. The manufacturer can make
                                                                                                                                     the number of neutrons having the starting                angle, SESANS sees a maximum                 distribution of preferred angles reveals
more intelligent use of the knowledge that the ice cream leaves
                                                                                                                                     orientation is measured (= polarization). If the          polarization from the scattered              the size of the spheres in the sample,
a cooled space several times during transport, so that when we
                                                                                                                                     neutrons have not collided, all neutrons will still be    neutrons       having taken on the           the distances between the spheres and
consume the ice cream, it is in optimal condition.                                                                                   pointing in the same direction, and the polarization      same orientation as the unscattered          the wall thickness of a hollow fat
With OYSTER the composition of food can also be changed and                                                                          is maximal.                                               neutrons.                                    sphere.
adapted for a healthier diet. Food manufacturers are currently
investing in research on whether fat spheres can be replaced by
bubbles containing no fat but only water. Food then becomes
cheaper, because fat is more expensive than water. At the same
time, these ”light” food products will taste good because they                                                                       NEUTRONS                                                                                               Deriving sphere size from shadow
are perceived as creamy. This is both a commercially interesting                                                                                                                                                                            pattern
and a healthy development.
                                                                                                                                     RESEMBLE LIGHT                                                              Scattering                 Because light is a wave, light shining
                                                                                                                                                                                                                   angle                    through the slit casts a pattern of shadows
                                                                                                                                     SESANS measures the                        Slit                                                        on the screen behind much larger than the
                                                                                                                                     scattering (change in                                                                                  slit. From the distances between the
                                                                                Neutron
                                                                                                                                     direction) of neutrons                                                                                 ”scattering angle of maximum light
                                                                                                                                     resulting when a neutron                                                                               intensity,” the size of the slit can be
                                                                                                                                     (for example) collides with                                                                            calculated. If there are several slits, the
                                                                                                                                     a fat sphere.This scattering                                                                           wave patterns of the slits intensify (much
                                                                      Neutron spin                                                   is comparable to the                                                                                   light) or dim (less light) one another. The
                                                                      Because a neutron consists of a positive, a negative and       scattering of light through                                                                Sphere      preferred angles then provide information
                                                                      a neutral quark, a neutron changes orientation (like a         a slit: a neutron behaves                                                                 distance     on the distances between the slits and their
                                                                      compass needle) [4] in a magnetic field. A neutron also        as a particle but also                                                                                 arrangement (ordering). This works just
                                                                      has an inherent spin, an angular momentum of constant          has wave properties,                                                                                   the same with SESANS, except that light
                                                                      size. When a neutron enters a magnetic field, the              just like light.                                                                                       intensity is not measured, but the number
                                                                      ”spinning compass needle” swings (precession) [5]                                                                                                                     of neutrons (=intensity) that has changed
                                                                      around the direction of the magnet’s field.                                                                                                                           direction and therefore orientation.

                                                                      8     OYSTER                                                                                                                                            9        OYSTER
OYSTER Big ideas from small particles
OYSTER EXPANSION: NDF

                                                                                                                           New instrument

     Better                                                                                                                Porous metallo-organic frameworks are composed
                                                                                                                           of organic molecules bound together by metal                                                         Hydrogen is a promising

     solar cells                                                                                                           atoms. Hydrogen atoms [1] end up in the open
                                                                                                                           spaces in the framework. Researchers want to
                                                                                                                           understand how the hydrogen atoms nestle in
                                                                                                                                                                                                                                energy storage material for
                                                                                                                                                                                                                                the future. Hydrogen can be
                                                                                                                                                                                                                                stored as a gas or liquid in
     with                                                                                                                  these hollow spaces. Specific atoms can stimulate
                                                                                                                           [2] or block the storage of hydrogen atoms. With
                                                                                                                                                                                                                                a tank (like liquid propane).
                                                                                                                                                                                                                                It is also possible to store

     POSH 2D-ACAR                                                                                                          a microscope we cannot look into a material at
                                                                                                                           the atomic level. With NDF we can.
                                                                                                                                                                                                                                hydrogen in solids, such as
                                                                                                                                                                                                                                metallo-organic materials.

This series of existing and well-known instruments works with                                                                                                                                             Neutron beam                           Detectors
antimatter. The acronym stands for POSitrons at the Higher                                                               Measuring the distances between atoms
education reactor 2-Detector Angular Correlation Annihilation                                                            A warm neutron beam is aimed at a crystalline
Radiation. This instrument uses primarily gamma radiation close                                                          test material. Two ”choppers” [3] (spinning
                                                                                                                                                                                                                                             Test material
to the reactor core to generate positrons.                                                                               wheels with holes in them) allow regular
Energy is converted into antimatter that triggers an annihilation                                                        pulses of neutrons through (= start time).
reaction in the sample to be studied. This is when a particle
(electron) comes in contact with its antiparticle (positron)                                                             The neutrons are reflected by the planes of
and they destroy each other. The energy released from this is                                                            the crystal and are absorbed by a number of
measurable. Very small variations in the results consequently                                                            detectors [4] (=stop time). From the distance
shed light on the movement of electrons in close proximity to                                                            traveled and the time of flight (=stop time
irregularities in the material being examined.                                                                           plus start time), the wavelength of each
                                                                                                                         neutron is calculated. The wavelength, the
                                                                                                                         reflection angle [5] and the intensity of the
This is good news for the solar cell. Performance would be             less energy will be lost due to reflection. The
                                                                                                                         reflection show which distances occur between
much improved if the solar cell were completely black instead          behavior of the electrons close to the defects
                                                                                                                         the crystal planes in the test materials. Special
of predominantly blue. With POSH 2D-ACAR we can look into              is therefore of great importance.                 software can then calculate the entire crystal
ways to make solar cells black by means of ”defects” in the                                                              lattice.
crystal lattice. This will also improve the energy efficiency, since

                                                                                                                                             Reflection angle
                                                                                                                                                                                Detector
                                                                                                                         Neutron

                                                                       OYSTER makes new energy techniques
                                                                       possible. With NDF we can see how and
                                                                       under what conditions hydrogen is stored in

     More                                                              metallo-organic materials. These have the
                                                                       remarkable property of being able to store a
                                                                       larger volume of hydrogen than a hydrogen
     efficient energy                                                  tank. NDF shows where the hydrogen stays in
                                                                       the crystalline structure of the material.
     storage                                                           NDF is also used in research on energy
                                                                                                                                                                                                              Kitchen salt
                                                                                                                                                                                                              Measurement of a single crystal of kitchen
                                                                                                                                                                                                              salt reveals just one distance [6], so that the

     with NDF                                                          storage in batteries. Knowledge and
                                                                       understanding of crystalline structures and
                                                                       the working of various parts of superbatteries
                                                                                                                                                                                                              crystal lattice is immediately known.

                                                                       are crucial in the development of electric
                                                                       vehicles and decentralized (mobile!)              Lattice surface                                                                      CHARGING AND
                                                                       availability of electrical power.                                                                                                      DISCHARGING
The Neutron Diffraction Facility (NDF) is playing an important                                                           Neutrons reflect strongly off crystalline materials                                  With NDF, the ”empty” crystal lattice of a
role in the development of our future energy supply. NDF is a                                                            A signal of a reflection off a single atom is not detected. If the atoms are         metallo-organic material is measured first,
new instrument that works with the characteristic wavelength of                                                          arranged in a regular way in crystal planes, and if the pathlength difference        and thereafter the situation if hydrogen is
”warm” neutrons. By measuring the reflection of the neutrons                                                             between the reflections off the different planes is a multiple of the neutron        added. The extra distances ”show” where
as a function of the angle it is possible to unravel the structure                                                       wavelength, the reflections intensify each other and are measured as an              and how the hydrogen atoms are located in
of crystals.                                                                                                             intense signal by the detectors.                                                     the lattice.

                                                                       10   OYSTER                                                                                                                       11   OYSTER
OYSTER Big ideas from small particles
With OYSTER these possibilities are expanded             Positron source                                 Repair of cracks at the atomic level
                                                                      much further. OYSTER allows us to observe                The positron source is                     Small clusters of copper atoms in the atomic
                                                                      the faster processes in steel production and             shoved close to the                      lattice of aluminum give aluminum alloys their

     Stronger                                                         see the appearance and disappearance of
                                                                      smaller grains. We see in real time what
                                                                                                                               reactor core via a
                                                                                                                               beam tube.
                                                                                                                                                                      mechanical strength. If not all the copper atoms
                                                                                                                                                                       clump together during manufacturing, the free
                                                                                                                                                                                        copper atoms can act as a filler.

     steel
                                                                      happens in the formation of steel and how
                                                                                                                                                                                As soon as cracks appear at the atomic
                                                                      changes affect it.
                                                                                                                                                                                       level, for example in an airplane
                                                                      This is interesting to steel manufacturers.
     with PANDA
                                                                                                                                                                                           wing, free copper atoms [1]
                                                                      Because steel undergoes extensive processing                                                                                          fill the gaps.
                                                                      after manufacture, the properties of the
                                                                      product also change. The ability to predict
                                                                      these changes allows one to take them into
                                                                      account in advance. Steel can thus acquire
                                                                      its optimal properties only after pressing and
                                                                      treatment in zinc baths and paint lines. And
                                                                      maintain these properties for years in summer                                             Positrons
The Poly Axis Neutron Depolarization Analysis (PANDA)                 and winter.
apparatus is a ”neutron aligner.” Every neutron is a little magnet
that can be pointed. The ”aligned neutrons” are sent through                                                             Neutrons                                                                                                                      Magnetic
the research material. The exiting neutrons are measured to                                                                                                                              Test material                                                 fields
see how much they have ”swung.” We are then able to look into                                                                                                                          vacuum test space                                               A long coil is
materials and see their magnetic structure.                                                                                                                                                                                                            wrapped
                                                                                                                                                                                                                                                       around the
The composition of steel thus becomes visible: tightly packed                                                                                                                         Lifetime detector                                                vacuum tube.
grains, some of which are magnetic. The size and composition                                                                                                                                                                                           This coil
of the grains change during solidification, but also afterwards                                                                                                                                                                                        creates the
from rolling and further working. This whole process can be                                                                                                                                                                                            magnetic field
                                                                                                                                         Gamma radiation                                                                                               that guides
simulated in the PANDA. Through a better understanding of the
processes we can optimize production methods. We can make                                                                                                                                                                                              the positrons
                                                                                                                                                                                                                                                       to the test
judgments about the steel’s strength and even predict when                                                                     Tungsten grid
                                                                                                                                                                                                                                                       material.
steel will fail. This will allow us to build better bridges and put                                                            The positron source consists of a series of
safer crumple zones in cars.                                                                                                   tungsten grids close to the reactor core.
                                                                                                                               Gamma radiation from the core produces
                                                                                                                               positrons and electrons in the tungsten. An
                                                                                                                                                                                                                                  Energy detector
                                                                                                                               electrical field leads the positrons into the
                                                                                                                               magnetic field.

                                                                                                                                    OYSTER EXPANSION: POSH-PALS                                                                   Recipe for aluminum
                                                                                                                                    More positrons                                                                                What is the right manufacturing
                                                                                                                                                                                                                                  method? At what temperature and
                                                                                                                                    A cadmium hood [2] absorbs the                                                                for how long should aluminum be
                                                                                                                                    neutrons that originate from the core.                                                        heated? How much copper should
                                                                                                                                    This releases extra gamma radiation                                                           be added? Or does another metal
                                                                      From the data provided, the size of the
                                                                                                                                    that is converted in the tungsten grids                                                       work better? With positrons these
                                                                      hollow spaces in a structure can be deduced.                                                                     Free                 Positron
                                                                                                                                    into extra positrons, making the positron                                                     questions can be answered.
                                                                      Potential fractures then become visible at a                                                                  copper atom              beam

     Self-healing
                                                                                                                                    beam seven times more powerful.
                                                                      very early stage. The instrument can also be
                                                                      used in the development of ”smart” materials.

     aluminum                                                         When free copper atoms are added to
                                                                      aluminum, they fill up the beginning of
                                                                                                                               Positron and electron disappear
                                                                                                                               A positively charged positron is repelled by
                                                                                                                                                                                                                                  Lifetime of positrons
                                                                                                                                                                                                                                  With the new PALS apparatus, the

     with POSH-PALS                                                   hairline cracks. In theory, this leads to ”self-
                                                                      healing” aluminum: as soon as a fracture
                                                                                                                               the positive atomic nuclei. After the positron
                                                                                                                               has been shot into the test material and
                                                                                                                                                                                                                                  lifetime of positrons in defects can
                                                                                                                                                                                                                                  be measured. The larger the
                                                                      begins, copper atoms repair the damage.                  slowed down, it then seeks places where                                                            defect, the longer it takes for a
                                                                                                                               atoms are missing. This can be a gap of a                                          +               positron to meet an electron and
                                                                      This continues until the copper atoms are
                                                                                                                               single atom [3] but also the beginning of a                                    +                   annihilate. With extra detectors
                                                                      used up.
                                                                                                                               crack.                                                                                             that can precisely measure the
                                                                      With POSH-PALS this process can be followed
                                                                                                                                                                                                                                  annihilation radiation, it can be
                                                                      in real time so that the optimal composition
                                                                                                                               Finally the positron annihilates [4] with one                                                      discovered which atoms play a role
                                                                      and lifespan of this self-healing aluminum can           of the electrons present around the defect.                                                        in the repair.
Positrons Higher Education Reactor – Positron Annihilation            be determined.                                           This causes both particles to disappear and                                                        PALS measurements of self-healing
Lifetime Spectrometry: this new instrument shoots antimatter                                                                   two photons (annihilation radiation [5]) are                                                       aluminum will show how many and
into a sample to see how long it takes before it meets and                                                                     released. The existing ACAR-measurement                                                            how quickly free copper atoms [6]
destroys its negative counterpart. The larger the spaces in a                                                                  device gives information about the energy                                                          reach and fill the open spaces in
structure, the longer it will take for this to happen.                                                                         levels of the electrons in the test material.                                                      aluminum.

                                                                      12   OYSTER                                                                                                                                     13     OYSTER
OYSTER Big ideas from small particles
Determining chemical                            Detector                           OYSTER EXPANSION: SNM
                                                                                   composition
                                                                                   The chemical composition                                                           Directing neutrons

     The                                                                           of objects is interesting to
                                                                                   figure out - for example,
                                                                                   to determine whether the
                                                                                                                                                                      With neutrons the composition
                                                                                                                                                                      of an object can be determined

     lie detector                                                                  pigment of a painting was
                                                                                   really made 300 years ago.
                                                                                                                                                                      without destroying it.
                                                                                                                                                                      To analyze a specific piece it is
                                                                                                                                                                      necessary to aim the neutrons
     SNM                                                                           It is possible to scrape a small
                                                                                   piece of paint off the canvas to
                                                                                   analyze it chemically, but this
                                                                                                                                                                      precisely. This is possible with
                                                                                                                                                                      cold neutrons because they are
                                                                                   damages the painting slightly.                                                     steerable with hollow glass
                                                                                                                                                                      fibers.

The Scanning Neutron Microscope (SNM) requires a ”cold”                            Neutron beam
neutron beam. Via hollow glass fibers the SNM focuses neutrons
at a point on the material to be examined. Some neutrons are
absorbed there. The energy released manifests itself as flashes
of light. These can be measured. The analysis reveals the                                                                                                             Analysis with neutrons
details of the composition of the material in the focal point: in                                                                                                     When a neutron beam [1] is
theory, all elements in the periodic system can be made visible                                                                                                       directed at a painting, some
in this way.                                                                                                                                                          pigment atoms take a neutron
                                                                                                                                                                      into their nucleus and send out
This new measuring instrument will make entirely new                                                                                                                  a very short flash of light [2]
applications of neutron research possible. ”Authentication
                                                                                   Non-destructive research                                                           (high-energy radiation).
                                                                                   The main advantage of analysis with                                                The painting does not change
research” in the world of art and cultural heritage is a promising
                                                                                   neutrons is that it causes no damage to                                            detectably as a result of the
field. With SNM, pigments in paintings can be analyzed to
                                                                                   the test material, allowing the entire                                             analysis because the neutrons
determine whether they came from the master’s palette or                           surface of a painting to be analyzed                                               only hit one out of every 100
from an art forger of a later period. The same holds true for the                  millimeter by millimeter.                                                          billion pigment atoms.
composition of bronze, glass and pottery.
Another area of research concerns the organic breakdown of
contaminants. It is known that certain organisms (vegetation,
bacteria) feed on chemical contaminants. With SNM we can
examine how, why and under what conditions organic tissue                          Glass fibers                                                    Focal point        Gamma radiation
takes up chemical elements and what happens to them                                The neutrons are led through a bundle of                    cross-section 0,2 mm
subsequently. This also opens up new pathways for medical                          hollow glass fibers (fiber diameter a few
research, such as research into the absorption of contaminated                     micrometers) to a focal point on the test
compounds by the liver and their effects.                                          material. It is impossible to steer warm
                                                                                   neutrons with glass fibers.

                                                                                   A germanium crystal as a detector
                                                                                   The gamma radiation is absorbed by a
                                                                                   germanium crystal [3] (diameter 10 cm).
                                                                                   Each chemical element emits a different
                                                                                   color of gamma radiation. The relationship
                                                                                   between the gamma colors and the
                                                                                   elements is known. Germanium can detect
                                                                                   very precisely the differences in color and
                                                                                   intensity of gamma radiation.
                                                                                   The germanium crystal converts the
                                                                                   gamma radiation into electrical signals
                                                                                   which are measured.

                                                                                   Liquid nitrogen
                                                                                   The germanium crystal is cooled with
                                                                                   liquid nitrogen [4] (-196 o C) to ensure that         Neutron
                                                                                   only electrical pulses occur as a result of            beam
                                                                                   the gamma radiation absorbed.

                                                                     14   OYSTER                                                                   15   OYSTER
OYSTER Big ideas from small particles
Inter-
     nationalization

Neutron research has yielded many benefits to modern life.          ISIS, Oxford, England &
International particle research, such as that conducted in Delft
since 1963, has contributed to more effective health care,
                                                                    ILL, Grenoble, France
better materials and more precise control of (production)
                                                                    The largest pulsed neutron source in the
processes. Through these benefits, our quality of life has
                                                                    world is located in England, while France has
improved considerably.
                                                                    the most powerful research reactor in the
                                                                    world. The two enormous research complexes
                                                                    host the world’s top scientists in the field of
     Within the international particle research community,          neutron research.
     Delft has come to play a unique and indispensable role.
                                                                    ISIS commissions instruments, developed and
                                                                    built for this institute, from the RID. ILL also
                                                                    makes use of Delft knowledge and ideas.
RID, Delft
                                                                    The RID complements ISIS through its goals
In the Netherlands, the Reactor Institute Delft (RID) is the
                                                                    and capabilities. In Delft, fundamental and
academic center for radiation-related research and education.
                                                                    experimental research is conducted that
The RID is a partner with national and international academic
                                                                    would not be suitable for ISIS and ILL. On the
institutions and contributes to fundamental research in a variety
                                                                    career ladder, RID serves as a portal for ISIS
of fields. Through a combination of expertise, the reactor
                                                                    and ILL.
itself, the right instruments and a low-threshold accessibility,
the RID is also the contact point of businesses seeking
innovative applications to enhance the efficiency, safety, and
innovativeness of products. The RID employs 150 people.             NRG, Petten
                                                                    Our country has two research reactors. The
                                                                    reactor of the European Commission in Petten
European Spallation Source                                          is operated by the Nuclear Research and
                                                                    consultancy Group (NRG). With the reactor’s
Europe has so far enjoyed a head start on the rest of the world
                                                                    high power and high radiation levels, the
when it comes to neutron research, with ISIS and ILL as trump
                                                                    primary research there is materials research
cards. But the United States and Japan are on the verge of
                                                                    into radiation damage, in which materials are
completing neutron sources that will be stronger than ISIS.
                                                                    tested for application in high radiation fields.
                                                                    Petten is also a supplier of radioisotopes
The European neutron community is preparing to build a pulsed
                                                                    for the medical industry and operates on a
neutron source that will surpass all existing sources by a factor
                                                                    commercial basis.
of ten: the European Spallation Source. Combining knowledge
and expertise on a European scale makes it possible to maintain
                                                                    The research reactor of the RID is oriented
our leading position in the world.
                                                                    towards scientific research, the uses of
                                                                    radiation to develop better functional
The Netherlands has been asked to contribute to this project
                                                                    materials and compounds. Delft also develops
via the RID. The Netherlands will therefore, through the RID,
                                                                    new applications and optimal production
play an important role in the development of this European
                                                                    methods for medical radioisotopes. Delft thus
research facility.
                                                                    supplies knowledge that can be applied in
                                                                    Petten.

                                                                    16   OYSTER
TU Delft
                                 Reactor Instituut Delft
Delft University of Technology

                                 P.O. Box 5042 - 2600 GA Delft
                                 Mekelweg 15 - 2629 JB Delft
                                 T +31 015 27 86744
                                 F +31 015 27 86422
                                 I www.rid.tudelft.nl

                                 Colofon
                                 Coördination & text      Zuid-West 3 Communicatie
                                 Translation              Roberta Hardy
                                 © Illustrations & text   Verdult - Kennis in Beeld, www.kennisinbeeld.nl
                                 © Design cover           Verdult - Kennis in Beeld
                                 Graphic lay out          Chris Cras Reclame
                                 Production date          Februari 2009
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