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NICKEL MAGAZINE T HE M AG A ZINE DE VOT ED TO NICK EL A ND I T S A PPLIC ATIONS NICKEL, VOL. 36, Nº 2, 2021 Critical nickel: providing sustainable solutions Carbon capture Clean energy Wind power in and storage What role does nickel play? the Arctic
EDITORIAL: SUSTAINABLE SOLUTIONS “Secure global net-zero by mid-century and keep 1.5 degrees within reach” SOURCE: IEA(2021)THE ROLE OF CRITICAL MINERALS IN CLEAN ENERGY TRANSITIONS. ALL RIGHTS RESERVED. is the call of the November 2021 COP26 climate change summit in Glasgow. Government policy changes, investment dynamics and consumer choices are increasingly driving a major overhaul in the energy systems and technologies that power the world. While energy demand from oil, gas CASE STUDY 22 Change in energy demand by type KWANSOO E&C CO. LTD in 2020 relative to 2019 and coal fell by 5% during 2020 compared with 2019, the energy TEMBURONG BRIDGE 5% demand from new energy systems, such as renewables remained “Stronger actions are required to counter the upward pressure on emissions from 0 mineral production, but the climate resilient. Considering 2020 was a advantages of clean energy technologies At 30 km (19 miles) in length, the Temburong Bridge is one of the longest year when most economic sectors remain clear.” over-sea bridges in south east Asia and is the largest infrastructure project -5% showed no growth or contraction — The Role of Critical Minerals in Clean ever undertaken by the Government of Brunei.The bridge spans a part of due to the Covid19 pandemic, a Energy Transitions International Energy Brunei Bay and connects the Brunei-Muara District with the Labu Forest Agency -10% 1% growth in the renewables sector Reserve on the eastern shore. Before the bridge was opened in March 2020, Total Oil Coal Gas Nuclear Modern vehicles were forced to drive through a part of Sarawak, Malaysia when Renewables paints a positive outlook. traveling between these two districts.The bridge has reduced travel time Despite needing energy to produce, nickel is one of the minerals that plays a from two hours to about 40 minutes.The Sultanate of Brunei foresees that critical enabling role in the energy transition required to reduce CO2 emissions. Opened in March 2020, the this massive US$1.6 billion project will lead to an increase in tourism to the Its unique properties facilitate the successful deployment of the spectrum of Temburong Bridge in Brunei beautiful Labu Forest Reserve. clean energy technologies such as geothermal, batteries for EVs and energy Darussalam spans part of Brunei Construction of the bridge, which box-girder structures. In order to storage, hydrogen, wind, concentrating solar power and nuclear. And as PHOTO BY JUSTIN BULOTA, © TUGLIK ENERGY Bay. It consists of massive viaducts started in 2014, was carried out by greatly extend service life in this nickel-enabled greener energy becomes more available, the carbon footprint and two cable-stayed navigation the Daelim-Swee Joint Venture of tropical marine environment, the bridges. Stainless steel rebar was of nickel production is also being reduced. South Korea and the China State use of stainless steel reinforcing bar selected for critical parts of the Construction & Engineering Corp. (rebar) was specified for critical In this edition of Nickel we take a close look at exactly where nickel is and its reinforced concrete structures. Their formidable task involved the parts of the reinforced concrete critical role in four of the technologies which will be part of the mix of solu- Strong and corrosion-resistant construction of a 12 km (7.5 miles) structures. This requirement led to tions for decarbonisation. stainless steel rebar is now in wide land viaduct to traverse the man- the selection of a reported total of use to extend the service lifetimes of Often a little nickel goes a long way in emissions-reducing technologies, grove swamps of the Labu Forest approximately 3,500 tons of stainless Cover: One of two wind turbines at the important concrete structures like helping provide sustainable solutions to help us get to net-zero. Reserve, a long marine viaduct steel rebar, including rebar made Glencore Raglan Mine with the Northern bridges, which must endure harsh and two navigation bridges. These from Type 304 (UNS S30400) and Clare Richardson Lights (Aurora Borealis). environments. spectacular bridges are cable-stayed, Type 2304 (S32304). Editor, Nickel 22 || NICKEL, NICKEL, VOL. VOL. 36, 36, Nº Nº 2, 2, 2021 2021 NICKEL, VOL. 36, Nº 2, 2021 | 3
NICKEL A surprising tail NOTABLES CONTENTS While it’s not unusual to find various metals in the dust tails of comets, nickel and iron have now been found in cold comets far from the Sun. 02 Case study no. 22 What’s unusual about this? Solid metals don’t normally ‘sublimate’ (become gaseous) in cold temperatures. Polish astronomers first identified Temburong Bridge nickel vapour in the tail of the icy interstellar comet 2I/Borisov in 2019. 03 Editorial Now Belgian astronomers J. Manfroid, D. Hutsemékers and E. Jehin have identified similar gaseous nickel in cold solar system comets, suggesting a Sustainable solutions possible organometallic origin. These vapours have been detected in comets 04 Nickel notables more than 480 million kilometres from the Sun, triple the Earth-Sun distance. 06 Wind and water Nickel in clean energy BALLYMORE PROPERTIES LIMITED 10 The Northern Lights project WIKIMEDIA COMMONS Carbon capture and storage 13 Nickel alloys A clearer solution ‘C’ Family of alloys Dive in JOONDONG KIM FROM INCHEON NATIONAL UNIVERSITY SMARTTIRECOMPANY.COM 14 Technical Q&A Architecture studio HAL has Tea staining created a ten-storey (35 metre) high transparent swimming 15 New publications pool that also acts as a bridge between two buildings at the 15 UNS details Embassy Gardens development in Battersea, London. Named Sky 16 King Abdulaziz Center Pool, the 25 metre-long swimming World culture pool is made from acrylic panels, allowing swimmers to enjoy sweeping views of the neighbourhood, Nickel magazine is published by Nickel Institute including the Thames. Mars to Earth www.nickelinstitute.org Dr. Hudson Bates, President Type 316L (UNS S31603) stainless Clare Richardson, Editor It’s a brilliant idea with a bright future. Glass with invisible solar panels steel tubs anchor the pool to communications@nickelinstitute.org that generate electricity. In a recent study published in the Journal of The Smart Tire Company, Los Angeles, California, is set to introduce Shape each building. The tubs are Contributors: Parul Chhabra, Gary Coates, Richard Matheson, Power Sources, Professor Joondong Kim and his colleagues at Incheon supported on bridge bearings Geir Moe, Kim Oakes, Frank Smith, Benoît Van Hecke, Memory Alloy Radial Technology (SMART) for bicycles. This revolutionary National University, Korea, detailed their latest invention: fully transpar- allowing the structure to respond Odette Ziezold new technology has evolved from shape memory alloy tires developed for ent solar cells that can be integrated into windows, buildings, or even to the buildings’ movement Design: Constructive Communications the next generation of Mars rovers and other Space Exploration Vehicles. mobile phone screens. Abundant and easily manufactured nickel oxide is and support the weight of the Material has been prepared for the general information of These tires incorporate the advanced material, advanced nickel-titanium the reader and should not be used or relied upon for specific playing a pivotal role. water. Two 38 mm diameter applications without first securing competent advice. While material, Nitinol (UNS N01555), a shape memory alloy (SMA) that’s elastic yet the material is believed to be technically correct, Nickel Until now, solar cells tended to be opaque, limiting their use. Professor high strength spring-tensioned Institute, its members, staff and consultants do not represent strong to handle the extreme challenges NASA faces on Mars, including no or warrant its suitability for any general or specific use and Kim and his team developed an innovative technique, zeroing in on the stainless steel rods run under assume no liability or responsibility of any kind in connection roads and extreme temperatures that can reach -100 °C. with the information herein. heterojunction, which comprises thin films of materials responsible for the pool to connect the two tubs ISSN 0829-8351 absorbing light. To make the junction, the researchers chose nickel oxide, Back on Earth, the patented load-bearing design takes advantage of to reduce loads on the acrylic a semiconductor known to have high optical transparency. By combining the unique properties of the SMAs, as these special metals can expand, structure. The result is not only Printed in Canada on recycled paper by Hayes Print Group titanium dioxide and nickel oxide semiconductors, they generated an contract, bend or unbend at a very rapid rate. Expected to be on the a marvel of architecture and Cover: Photo by Justin Bulota, © Tugliq Energy Stock image credits: pg. 3 iStock©Petmal, efficient, transparent solar cell. Says Prof. Kim, “These transparent market by 2022, the company claims they will be a life-of-the-bike tire that engineering; it is an amazing pg.7 iStock©Burben_Images, pg. 8 Shutterstock ©encikmohdfirdaus , pg. 13 iStock©typo-graphics photovoltaic cells could have various applications in human technology.” shouldn’t ever need replacing, just occasional retreading. sight to look up and see. 4 | NICKEL, VOL. 36, Nº 2, 2021 NICKEL, VOL. 36, Nº 2, 2021 | 5
alloys like C-22 (N06022), but most a hundred tons of nickel in the alloys others can use lower alloyed materials. used. These materials, all in their Take for example, the Hellisheiði correct application, provide corrosion Power Station in Iceland, near the resistance, strength and clean surfaces capital Reykjavik, ranked as the sixth for excellent heat transfer, resulting in WIND AND WATER largest geothermal power plant in the cost-effective service. world. It produces 303 MW of electric- Hydro-electric power ity and 400 MW of thermal energy used NICKEL IN CLEAN ENERGY Hydro-electric power is presently the to heat homes and businesses, carried largest source of renewable electricity. by a 19.5 km long pipe to the city. The Capacity is expected to grow 70 % by wells bring up water at a temperature 2040, mostly in the Asia Pacific region, Some of the geothermal waters of around 200 °C with a low amount according to the IEA. It will remain an are very corrosive as they of chloride and some hydrogen important renewable energy source contain high amounts of chlorides sulphide. The materials used in the for the future. There will be more plants and hydrogen sulphide. This system range from typical carbon steel but in addition, older plants will require is where the use of nickel- casing alloys through various types of refurbishment and efficiency improve- containing alloys is critical. Even small quantities of In its recent flagship report, The Role of Critical Minerals in Clean Energy stainless steels to high nickel alloys. ments offering the opportunity for nickel in an application can Transitions, the International Energy Agency documents the expected needs of Even titanium is needed for certain current technology to be incorporated make a big difference to different metals and minerals to enable low carbon-emitting technologies to critical components. Some of the key for longer life and greater energy replace existing non-sustainable electrical generation methods.The report shows components where nickel is found successful deployment. production. the importance of nickel (high, medium, low) for some of the clean technologies. are the turbines, condensers, heat exchangers, pumps and piping systems Most hydro-electric power systems Even a small amount of nickel can be pressurised hot water over about 150 °C have dams that feed turbines to which use, for example, stainless steels Clean Energy Importance critical in delivering resilience and is brought up in pipes to the surface Types 630 (S17400), 316L (S31603), generate the electricity. Nickel is Technology of Nickel enabling successful deployment of where it drives turbines to generate various duplex alloys, 6 %Mo (S31254) used in these systems for some key Solar Photo-Voltaic Low clean technologies. Take hydro-elec- electricity and then cools. The now and nickel alloy 625 (N06625). In the components and it looks like nickel tric for example. Even though nickel is lower temperature water is sent through power plant there may be as much as Concentrating Solar Moderate will play an even greater role in the Power (CSP) indicated to be of low importance pipes for district heating systems and (low quantity) in hydro-electric, its use subsequently returned to the source Wind Moderate is critical in weldability of turbine to be naturally reheated. One of the Hydro-electric Low blades and in the long life of other main advantages of geothermal is that Bioenergy Low components used in dam gates. In the energy obtained is reliable and Geothermal High some applications, we can even say available all the time, unlike solar or Nuclear Moderate that nickel is essential for these wind. Geothermal energy production technologies. While the IEA report today is quite limited, perhaps only EVs and Battery High Storage discusses only electrical power 16 GW capacity, limited to places generation, some other clean technol- where the water sources are relatively Hydrogen High ogies result in energy in the form of close to the earth’s surface, typically heat. The production of biofuels is a less than three kilometres deep. The case in point, relying heavily on the capital cost of a geothermal power use of nickel in the form of stainless plant tends to be higher than other steels. In fact, much of the energy mix sustainable technologies, however the requires nickel in one form or another, costs can be justified by the continuous and all the clean energy technologies operation of the system. use nickel. Here we take a closer look The quality of the water or steam varies at what nickel is doing in three of the considerably depending on location. clean energy technologies: geother- Some of the waters are very corrosive as mal, hydro-electric and wind power. they contain high amounts of chlorides Geothermal and hydrogen sulphide. This is where Heat from deep within the earth can be the use of nickel-containing alloys is used to generate electricity as well as critical. Some of the installations, such for heating homes and other buildings. as the Salton Sea project in California, The concept is simple – steam or make extensive use of nickel-base 6 | NICKEL, VOL. 36, Nº 2, 2021 NICKEL, VOL. 36, Nº 2, 2021 | 7
future. At the heart of the power plant to where 10 MW and larger turbines is the generator, which consists of a are being offered today. Larger wind turbine (runner) driven by flowing turbines result in lower intensity of water under pressure, with a moving material use, meaning less material per Hydropower is the largest rotor containing magnets inside a MW of energy is used, an important source of renewable electricity. fixed stator with copper wire windings sustainability criterion. Here nickel is And the most durable turbines also playing a critical role. which then produces electricity. are made from nickel- Usually, the turbine is made from Nickel use is most often associated containing stainless steel. nickel-containing stainless steel. It with stainless steels, and in wind needs both corrosion and cavitation turbines, many safety-critical features resistance. Turbines vary in size but such as ladders, control panels and are often very large, and their ability fasteners will indeed use stainless steel to be welded and be weld-repaired is alloys. But the main use of nickel in critical to material selection. For these wind power will be small quantities reasons, the most durable turbines are to increase the strength and improve made from nickel-containing martensi- the toughness of low alloy steels. tic and austenitic stainless steels such Many alloying elements will increase 410NiMo (UNS S41500), EN 1.4488 (no the strength and hardness of steel, UNS), Type 304 (S30400) and their but nickel is one of the few that also cast equivalents. improves toughness – the ability to Stators are also large and here the non- absorb mechanical energy without magnetic qualities of nickel-containing fracturing – which is critical to wind austenitic stainless steel is key to their turbine operation. JUSTIN BULOTA performance, particularly alloys such The gearbox of a turbine contains the as XM-19 (S20910). most critical moving parts. A gearbox With increasing water pressures and for an 8 MW turbine can weigh 86 tons. Wind power in the Arctic volumes, other system components can If something major fails, replacing be lowered in weight and increased parts or even the whole gearbox in durability with nickel. High strength on a land-based wind turbine is a low alloy (HSLA) steels remain a great very costly exercise, but for offshore Providing electric power and heat with a sophisticated energy storage installations, the costs and downtime to remote sites in northern Canada system that includes lithium-ion bat- candidate for future development of can be enormous. Thus, reliability penstocks (large diameter pipes that is always a challenge, especially if teries. Integration of the wind turbine and long life are essential factors in feed water to the turbine). Penstocks there are no roads to the site. Such and diesel energy systems was also making wind power economically can be up to 10 m in diameter. Higher feasible. The weight of the gearbox is is the case for the Raglan Mine, a mandatory. These first steps were strength steel reduces weight and Each turbine allows savings also important, as the structure must nickel mine owned by Glencore in very successful, proving the concept, has the advantage of increasing the of over 3,600 tons of CO2 support the weight of the nacelle, Nunavik, which encompasses the and now studies are underway to internal diameter. Nickel in these alloys annually and requires where the gearbox is located, in the northern third of the province of promotes martensite formation needed potentially install two new 3 MW wind about 2,000 kg of nickel strongest of wind conditions. A one to obtain the high strength. Nickel has Quebec. A large supply of diesel fuel turbines. Each turbine allows savings kilogram weight reduction in the the added advantage of improving is brought in by sea during a short nacelle can save as much as 10 kg of over two million litres of diesel weldability of the penstock materials. of material in the support structure. shipping season. The winters are dark annually resulting in the reduction of These advantages, lower cost, lower Design is critical, but so is alloy selec- and bitterly cold, so having heat and 3,600 tons of carbon dioxide. Nickel steel usage and improved efficiency, tion. Much of the steel in the gearbox power is absolutely essential. Wind are key to the future of this important contributes to the success. In each We often refer to nickel as the today contains nickel, as much as 2 % renewable sector. energy is one of the few potential wind turbine, about 2,000 kgs of ‘hidden metal.’ In wind turbines, for certain components. Even higher Wind Power nickel alloy steels are being suggested alternative sources of energy. But nickel are used. Applications relying it is indeed hidden, but it is The use of wind to generate energy has as turbine sizes as high as 20 MW are can that technology work safely in on nickel in the nacelle area include also an enabler of reliable and accelerated recently to where nearly being considered. Components that extreme Arctic conditions including cost-efficient energy generation. bearings, shafts, gears and hydraulic 750 GW of capacity exists worldwide. today contain no nickel may in the blizzards? components, and in other areas for The cost of energy from wind turbines future contain about 0.5 %, in order has gone down while the size of to decrease weight and increase Two wind turbines were constructed fasteners, control cabinet housings individual turbines has increased reliability. and installed in 2014 and 2018, along and many other components. 8 | NICKEL, VOL. 36, Nº 2, 2021 NICKEL, VOL. 36, Nº 2, 2021 | 9
Permanently stored CO2 received and temporarily stored Exported via pipeline offshore Permanently stored resevoir (2,500-3000 metres THE NORTHERN LIGHTS PROJECT Transport below seabed) Compressed CO2 transportd by ship CARBON CAPTURE AND STORAGE CO2 Capture Capture from Liquid CO2 TO REDUCE GREENHOUSE GAS industrial plants Compressed and temporarily stored Carbon capture and storage (CCS) is a vital part of decarbonising society. One such process involves the capture of carbon dioxide (CO2) from large industrial plants, transported in pipelines or ships, and deposited, generally Liquid CO2 NORTHERN LIGHTS underground, to prevent it from entering the atmosphere. It has a role to play in energy transition because renewable energy sources alone will not meet international 2050 energy and climate targets and completely stop greenhouse gas emissions. Firstly, there is the (slow) speed at which greening the energy for food and beverage applications liquid gas ensures a constant flow into The proposed maritime CCS or fuel mix is taking place. Secondly, carbon dioxide can be emitted for and pressurised products such as the pipeline and the seabed and is value chain from emission reasons unrelated to energy consumption, such as in the production of cement. fire extinguishers. Nickel is essential preferable to a start-stop feed which to subsea storage. Places where carbon dioxide can be (atmospheric) and semi-refrigerated for strength and toughness in these would occur without this onshore EQUINOR safely stored are not generally in the (semi-pressurised). Liquid CO2 can thick-walled pressure vessels at below terminal. areas where it is produced. Offshore only exist at a combination of low zero temperatures. As part of the first phase of opera- storage – despite its complexity – temperature and pressures well above About Northern Lights tions, Northern Lights is building seems to be gaining over onshore atmospheric pressure. Hence, a CO2 Despite the challenges, CCS projects two dedicated 130 m long, 7,500 m3 storage, which is often resisted by cargo tank should be of the pres- are beginning to materialise. Northern capacity CO2 carriers. These will take local residents. To bridge the distance sure-type or semi-refrigerated. Lights is the transport and storage captured and liquefied CO2 from between the place of emission and The semi-refrigerated type, including component of the Longship project, several emitters and transport it to the the place of storage, two options the few existing CO2 carriers, is promoted and supported by the onshore storage site before it is piped are available: shipping by vessel or designed to take into consideration the Norwegian government, which 100 kilometres offshore and 2,600 m A fleet of dedicated CO2 transportation by pipeline. Shipping is combined conditions of temperature includes capture of CO2 from indus- beneath the seabed for permanent transport vessels will be more economical at low volume and and pressure necessary for cargo gas trial sources in the south-eastern part storage. The first phase aims at required for maritime CCS long distance, while pipelines are the to be kept as a liquid. Ship designers of Norway (Brevik and Oslo). When gradually storing up to one and a to reach its full potential. most viable option for large volumes prefer this type as it enables larger and it starts operations in 2024, Northern half million tons per year under the at distances below 700 km. Also, in less expensive ships to be built. The Lights, owned by Equinor, Shell and seabed, which is the amount the two an emerging activity, such as CCS, cargo tank must operate at around Total, will be the first-ever cross- ships can transport annually. shipping requires less capital expendi- -54 °C / 6 bar to -50 °C / 7 bar. This is border, open-source CO2 transport Essential nickel ture, making it the preferred option to near the ‘triple point’ of CO2, where and storage infrastructure network. Because very few dedicated CO2 ship the initially low volumes of CO2 gas, liquid and solids coexist, but the It will ship captured CO2 to an carriers exist, the design of the two to the few available storage facilities. technology is not currently at the point onshore terminal on the Norwegian Northern Lights carriers required How to build a carbon dioxide ship? where this design can be implemented west coast and, from there, transport engineers and the shipping classi- There are three types of tank struc- efficiently and safely. Currently CO2 it by pipeline to an offshore subsur- fication societies to agree on the tures for liquid gas transport ships: carriers operate at higher pressure and face storage location in the North Sea. construction material for the onboard fully pressurised, low temperature around -20 °C. They carry liquid CO2 This intermediate onshore storage of pressure vessels. It had to be easy to 10 | NICKEL, VOL. 36, Nº 2, 2021 NICKEL, VOL. 36, Nº 2, 2021 | 11
fabricate and capable of accommo- line pipe steel (similar to API 5L dating high pressure and low temper- X65) with 0.50 % nickel. With most ature. The result was the selection of the length having a thickness of of a 50 mm thick, up to 2.50 % Ni about 16 mm, this represents about pressure vessel steel P690QL2 (EN 10028-6 type 1.8888). Two pressure 13,000 tons of steel and 65 tons of nickel. NICKEL ALLOYS: WORKHORSE ‘C’ FAMILY NICKEL-BASE ALLOYS vessels on each ship operate at 15 bar • Managing such a long pipeline in an and -26 °C, safely away from the triple offshore environment requires a set point. This represents about 3,000 tons of ancillary tubes that are bundled of steel containing 75 tons of nickel. into an ‘umbilical.’ The small tubes The CCS value chain further inside the umbilical carry the consists of: hydraulics for remote operation of • Onshore storage: 12 pressure vessels valves and other chemicals. These In the early 1930s, the first Ni-Cr-Mo alloy, known as alloy C (UNS N10002), was introduced. It was an optimisation of the Ni-Cr alloys which had good resistance with a total capacity of 8,250 m3. tubes with a wall thickness of only to oxidising acids, such as nitric acid, and Ni-Mo alloys with superior resistance CO2 emitted from sites in South Nickel is again needed to cope 1.42 mm are hard to access once to reducing acids, such as hydrochloric acid. This combination resulted in an East Norway will be shipped to with pressure and low temperature. installed and must resist seawater. alloy family with exceptional corrosion resistance in a wide variety of severe an onshore temporary storage The entire tank farm represents For resilience they are fabricated corrosive environments typically encountered in chemical and petrochemical facility before being transported 2,000 tons of pressure vessel steel from Type 2507 (S32750) super processing, exceeding that of stainless steels which had been discovered in 1913. by pipeline to offshore subsea P460ML1 (EN 10028-5) and P355NL1 duplex stainless steel. 35 km of In the mid-1960s, advances in both power plants. These units needed to PENTICTON FOUNDRY storage in the North Sea. (EN 10028-3) containing up to 0.50% an umbilical with four 2507 tubes nickel. represents about 10 tons of nickel. melting technology (namely the be resistant to the corrosive acids development of argon-oxygen formed by the flue gases. Alloy C-276 • A 100 km 323.8 mm outside diameter According to the Northern Lights decarburisation) and corrosion was used in many of these critical pipeline keeps the CO2 in the liquid model, CCS will start to deliver science (knowledge of the influence applications. Also, at this time alloy phase. This again means pressure its promise by 2024. About 150 to of minor element additions) led to C-4 (N06455) designed for the and low temperature. It runs on 200 tons of nickel are essential to the development of alloy C-276 European chemical industry, was the seabed, to reach the offshore capture and store 1.5 million tons (N10276), a low-carbon, low-silicon introduced. location from where the CO2 is of CO2 per year this way. To achieve wrought version of alloy C. Alloy The early 1980s saw the introduction injected into a geological reservoir, climate goals with CCS and other C-276 is now an industry standard for of Alloy 22, with a higher chromium 2.6 km under the seabed. The technologies, nickel is clearly an use in chemical and petrochemical content increasing corrosion resist- pipeline is made of DNV 450 FPDS essential component. processing. ance in oxidising media. In the 1990s The 1970 United States Clean Air Act this was followed by Alloy 59 led to the widespread adoption of (N06059), Alloy 686 (N06686) and Onshore facility at NORTHERN LIGHTS Naturgassparken near flue gas desulfurisation technology, C-2000® (N06200), with additional 90 years after the introduction Bergen mostly in the form of wet scrubbing improvements in corrosion resist- of alloy C, the C family of nickel- PROJECT MAP Fortum Oslo Varme units, to reduce sulfurous gas emis- ance that expanded the range of base alloys finds extensive use waste-to-energy plant sions from the nation’s coal-fired more demanding applications. in applications such as pollution Norway control, petrochemical/chemical, Offshore subsea storage Typical composition of the C family alloys production of various acids, metal location in the North Sea processing, and pharmaceutical. Norcem Alloy (UNS) Decade Ni Cr Mo W Cu Fe cement factory introduced C (N10002) 1930s Bal. 16 16 4 - 6 C-276 (N10276) 1960s Bal. 16 16 4 - 5 Northern Lights consortium is handling transportation and storage C-4 (N06455) 1970s Bal. 16 16 - 2 22 (N06022) Mid 1980s Bal. 21 13 3 - 3 59 (N06059) Early 1990s Bal. 23 16 - -
ASK AN EXPERT FAQ FROM NEW PUBLICATIONS THE NICKEL INSTITUTE Stainless steel infrastructure: studies that the total cost of owner- a lifetime of savings explains how ship over the life of a stainless steel TECHNICAL ADVICE LINE the unique properties of nickel-con- asset can be highly competitive, taining stainless steel make it a despite its higher initial investment cost-effective choice of material for cost compared with less durable a wide range of structural appli- alternatives. Available for download cations. It demonstrates through from the Nickel Institute website. a selection of international case nickelinstitute.org Geir Moe P.Eng. is the Technical Inquiry Service Coordinator at the Nickel Institute. Along with other material specialists situated around the world, Geir helps Q Q: The stainless steel railing outside our building is showing rusty spots after a couple of years. Was the wrong grade of stainless steel installed? A: This is likely atmospheric corrosion related to the presence of salts Refreshed INCO publications Twenty-eight significant technical publications, originally produced by INCO, and maintained by the Nickel relevant today. This high-quality technical information will give practitioners confidence in working with nickel-containing materials SO CRHER STA R T ISM A INNLIO TO N OS IN-5 R CE GR N IU ESB MCE-N S IU RTOIN IS T UG R OICK E STM H SIG MA INA IN E OCH L L N AST 19 FC EL- EAT- STINEELING AND MACHINING LEYRG E REL DIN GRINDING K E INNI STA G YSISAND IELSL-RE O T NI-RESIST CTILE A —AE NN IC ATPEAN R D ATES LDU IN NG W PRSOTEELSP AND DUCTILE and is commonly known as ‘tea staining.’ It is most often seen near the URR I U E NI U S -RE E SIST NI-RESIST end-users and specifiers of nickel- Institute have been refreshed and and to harness their benefits in a OCC HE THSE TO TE TO IDLEGUID GU LOEYATO ALID TIGCUA TIC THSE US LLOY ALGININ E GGUIDUSE 2 GE YS THE 3LO 8TO seashore or in locations where road salt is used. Tea staining occurs PR ACLPR AC ICAA AACT ICCKOENI A PR IC NA L-TCK C OFKENL-OF OF NICK INANINCTIC PRA AO TA EL-CON AL N TA PRACTICAL26IN O 1IN EL-CONTAINI 3AL NO 4GUIDE NONG TO 08THE 11ALL OYSUSE re-published. The digital quality of wide range of applications. This OF NICKEL-CONTAINING NO ALLOYS 242 containing materials seeking OF N NO 242 when local conditions (such as temperature, relative humidity and pres- technical support. The team is on the guides has been improved and information is of value to materials ence of corrosive substances on the surface) are too aggressive for that hand to provide technical advice all publications are searchable. The specifiers, welders, fabricators and stainless steel alloy in its installed condition. The potential for staining Dist ribut ed by NICK ELd by bute free of charge on a wide range original publications were written engineers, and is available for free Distri ITUTEKEL NIC dE by INST trib by uced d by Dis TITuteUT INS NICKEL ProdProduce TEby is increased in sheltered areas, such as under eaves, that do not benefit ed by Distrib uted INCO O duc INSTITU INCPro NICKEL O Produc ed by Distributed INC INSTITUTEby of applications such as stainless by experts in their field and the download from the Nickel Institute Produced by INCO NICKEL INCO INSTITUTE from rinsing by rain allowing concentration of corrosive substances. steel, nickel alloys and nickel information they provide is still very website. nickelinstitute.org Also, horizontal and rougher surfaces can more easily retain corrosive plating to enable nickel to be used with confidence. substances, thus smoother surfaces and surfaces that can easily drain UNS DETAILS https://inquiries.nickelinstitute.org/ are less susceptible to corrosion. Chemical compositions (% by weight) of the alloys and stainless steels mentioned in this issue of Nickel. Type 304L (UNS S30403) is typically suitable away from the seashore and in areas not exposed to road salts. Otherwise 316L (S31603) is UNS Al C Co Cr Cu Fe Mn Mo N Nb Ni P S Si Ti V W usually adequate, however there are some coastal areas where more NICKEL N01555 - 0.07 0.05 0.01 0.01 0.05 - - - 0.025 54.0- - - - bal - - pg 5 max max max max max max 57.0 corrosion-resistant grades, such as 2205 (S32205) and super duplex O N L I N E N06022 - 0.015 2.5 20.0- - 2.0- 0.50 12.5- - - bal 0.02 0.02 0.08 - 0.35 2.5- (S32750 or S32760) may be required. pg 7 max max 22.5 6.0 max 14.5 max max max max 3.5 N06625 0.40 0.10 - 20.0- 5.0 0.50 8.0- 3.15- bal 0.015 0.015 0.50 0.40 An appropriate stainless steel alloy pg 7 max max 23.0 max max 10.0 4.15 max max max max is a low maintenance material but S17400 - 0.07 - 15.00- 3.00- bal 1.00 - - 0.15- 3.00- 0.040 0.030 1.00 WWW.NICKELINSTITUTE.ORG pg 7 max 17.50 5.00 max 0.45 5.00 max max max is not always maintenance-free. S20910 - 0.06 - 20.5- - bal 4.00- 1.50- 0.20- 0.10- 11.5- 0.040 0.030 0.75 - 0.10- - SUBSCRIBE to Nickel magazine free of charge and pg 8 max 23.5 6.00 3.00 0.40 0.30 13.5 max max max 0.30 receive a printed copy or an e-mail notice when a Natural rain washing may be S30400 - 0.08 - 18.0- - bal 2.00 - - - 8.0- 0.045 0.030 1.00 - - - new issue is published. www.nickelinstitute.org pg 2, 8 max 20.0 max 10.5 max max max sufficient, otherwise manual READ Nickel magazine online in several languages. S30403 - 0.030 - 18.0- - bal 2.00 - - - 8.0- 0.045 0.030 1.00 - - - washing may be needed. pg 14 max 20.0 max 12.0 max max max www.nickelinstitute.org/nickel-magazine/ S31254 - 0.020 - 19.5- 0.50- bal 1.00 6.0- 0.18- - 17.5- 0.030 0.010 0.80 - - - SEARCH BACK ISSUES of Nickel magazine from our Tea staining is discussed pg 7 max 20.5 1.00 max 6.5 0.22 18.5 max max max online archive, going back to 2009. in greater detail in the NI S31603 - 0.030 - 16.0- - bal 2.00 2.00- - - 10.0- 0.045 0.030 1.00 - - - www.nickelinstitute.org/nickel-magazine/ pg 5, 7, 14 max 18.0 max 3.00 14.0 max max max publication Stainless Steels S32205 - 0.030 - 22.0- - bal 2.00 3.00- 0.14- - 4.50- 0.030 0.020 1.00 - - - FOLLOW US on Twitter @NickelInstitute pg 14, 16 max 23.0 max 3.50 0.20 6.50 max max max in Architecture, Building and S32304 - 0.030 - 21.5- 0.05- bal 2.50 0.05- 0.05- - 3.0- 0.040 0.040 1.00 - - - JOIN US on LinkedIn – Construction – Guidelines for pg 2 max 24.5 0.60 max 0.60 0.20 5.5 max max max visit the Nickel Institute’s page S32750 - 0.030 - 24.0- - bal 1.20 3.0- 0.24- - 6.0- 0.035 0.020 0.80 - - - FROM PUBL 11 024 BY TMR Corrosion Prevention (11 024) pg 12, 14 max 26.0 max 5.0 0.32 8.0 max max max WATCH nickel-related videos on the Nickel Institute YouTube channel available for download from the S32760 - 0.030 - 24.0- 0.50- bal 1.00 3.0- 0.20- - 6.0- 0.030 0.010 1.00 - - 0.50- pg 14 max 26.0 1.00 max 4.0 0.30 8.0 max max max 1.00 www.youtube.com/user/NickelInstitute Nickel Institute website: S41500 - 0.05 - 11.5- 0.50- bal - 0.50- - - 3.5- 0.030 0.03. 0.60 - - - pg 8 max 14.0 1.00 1.00 5.5 max max max nickelinstitute.org/library 14 | NICKEL, VOL. 36, Nº 2, 2021 NICKEL, VOL. 36, Nº 2, 2021 | 15
KING ABDULAZIZ CENTER FOR WORLD CULTURE Located in Dhahran, Saudi Arabia, the Center was designed by architects from Snøhetta of Norway and was completed in 2017. Resembling five smooth ‘boulders’ randomly piled together, this spectacular building complex contains libraries, educational facilities, exhibition halls, theaters, museums, a mosque, and dining facilities. At the lowest point in the Center, an exhibit acknowledges oil as the historical foundation of the Kingdom’s economic prosperity. History gives way to the present at ground level where the Great Hall showcases the best of world cultural experiences. The future is then contemplated and forecast in the 90 m (295 ft) high Knowledge Tower. The boulders are covered with and clean appearance. Each tube closely-spaced stainless steel tubes section is unique and was bent to fit to create a veil that stands proud of its precise position using a computer- the building’s weather-proof panels. controlled machine. If placed end-to- ©SNØHETTA Fabricated by Seele of Germany, end, the 93,000 plus tube sections, the tubes (7.6 mm diameter x 2 mm weighing over 1,000 tons, would The ‘boulders’ are covered wall thickness) are made of duplex Alloy 2205 (UNS S32205) stainless have a total length of 360 km with closely-spaced stainless steel. This alloy, containing 5.5 % (220 miles). The tubes help to keep steel tubes to create a veil that nickel, was selected for its excel- the building cool by shading the stands proud of the building’s lent strength, ductility, long-term exterior surfaces and by reflecting weather-proof panels. abrasion and corrosion resistance, and conducting away heat. 16 NICKEL, | NICKEL,VOL. VOL.36,36,NºNº2,2,2021 2021
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