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MINISTRY OF PRIMARY AND SECONDARY EDUCATION CHEMISTRY SYLLABUS FORM 5–6 SUBJECT CODE: 2015 - 2022 Curriculum Development And Technical Services © All Rights Reserved P.O. Box MP 133 Copyright (2015) Mount Pleasant Harare i
ACKNOWLEDGEMENTS The Ministry of Primary and Secondary Education wishes to acknowledge the following for their valued contribution in the production of this syllabus: Panellists for Form 5 and 6 level Chemistry syllabus Zimbabwe School Examinations Council (ZIMSEC) Government Departments Ministry of Higher and Tertiary Education, Science and Technology Development United Nations Children’s Fund (UNICEF) United Nations Educational Scientific and Cultural Organisation(UNESCO) 1
Acknowledgements......................................... 1 1.0 Preamble .......................................... 1 1.1 Introduction ......................................... 1 1.2 Rationale ............................................ 1 1.3 Summary ............................................ 1 1.4 Assumptions ............................................ 2 1.5 Cross-cutting themes.............. ..................... 2 2.0 Presentation of Syllabus............................. 2 3.0 Aims .............................................. 2 4.0 Objectives ............................................... 3 5.0 Methodology and time allocation.................... 3 6.0 Topics ............................................... 4 7.0 Scope and Sequence...................................... 5 8.0 Competency matrix.......................................... 4 9.0 Assessment......................................................49 (a) Assessment Objective .....................................50 (b) Scheme of assessment ...................................51 (c) Specification ...................................................52 10.0 Glossary/Appendices .....................................55 2
1. PREAMBLE Problem solving Critical thinking 1.1. Introduction Decision making Production This two year syllabus is designed to put greater Research emphasis on the understanding and application Conflict resolution of chemistry concepts and principles in an Leadership environmental friendly and sustainable manner. Self-management It makes learners identify and solve problems Communication practically in a scientific manner. The Form 5 Technological innovation and 6Chemistry syllabus is inclusively made to Enterprise cater for all categories of learners in an increasingly technological world. 1.3. Summary of content 1.2. Rationale Form 5 and 6 Chemistry syllabus will cover Chemistry plays a pivotal role in the theory and practical activities in the following technological development of any country since areas: it is embedded in our everyday life. Physical Chemistry The study of Chemistry enables learners to be Inorganic Chemistry creative and innovative in industry and society Organic Chemistry by promoting the application of Chemistry in Applied Chemistry industrial processes for value addition, beneficiation of natural resources and harnessing of available opportunities for entrepreneurship. The Chemistry syllabus enables learners to develop the following skills: 1.4. Assumptions 3
The Form 5 and 6 Chemistry syllabus is a single It is assumed that learner: document covering Forms 5 and 6. have passed ‘O’ level Chemistry are familiar with ICT Tools and Braille/Jaws software 3.0 AIMS have passed ‘O’ level Mathematics are familiar with laboratory apparatus The aims are to: are aware of laboratory safety precautions enable learners to develop fundamental principles of Chemistry for application in life and as a basis for 1.5. Cross- Cutting Themes further studies in Chemistry and related disciplines. The Chemistry learning area encompasses the inculcate in learners the need for safety and cross cutting themes listed below: protection of the environment in the study of Inclusivity Chemistry. Environmental issues create opportunities for learners to acquire research, Indigenous knowledge system Enterprise Education experimental, practical, enterprising and Life skills technological skills in Chemistry. Team work Food security appreciate the usefulness and limitations of the Safety and health issues scientific method in the study of Chemistry. Disaster and risk management HIV/ AIDS stimulate in learners the desire to apply Chemistry for the benefit of society as guided by the principles of Unhu/Ubuntu/Vumunhu. 2.0 PRESENTATION OF THE SYLLABUS 4
promote awareness that the applications of 5.1 Methodology Chemistry may be both beneficial and detrimental to the individual and the community. Some of the learner centred and multi-sensory methodologies used in the teaching and learning of develop in learners the appreciation of the use of Chemistry are suggested below. The principles of Chemistry in value creation, addition and individualisation, concreteness, totality and wholeness, stimulation and hands-on experience should guide the beneficiation. teachers as they employ the suggested methods: Demonstrations Experimentation 2. SYLLABUS OBJECTIVES Research Models Learners should be able to: Site visits follow instructions in practical work Simulations make and record observations Seminars use ICT Tools and Braille/Jaws software to simulate Discovery Chemistry phenomena Exhibitions apply safety measures in all practical work Work related learning present, analyse and interpret data to establish 5.2 Time Allocation relationships demonstrate knowledge on facts, laws, definitions and For adequate coverage of the syllabus, a time allocation of 8 concepts of Chemistry theory 40minutes periods and a block of 4 practical periods measure and express quantities to a given level of per week is recommended. Learners should be engaged in at accuracy and precision least one Educational Tour per term, one exhibition per year, design a practical solution to a real life problem using and an attachment of one week in any chemical related knowledge of Chemistry industry during the course 5.0 Methodology and Time Allocation 5
6.0 TOPICS 6.1 Physical Chemistry: 6.3 Organic Chemistry: - Atoms, Molecules and Stoichiometry - Hydrocarbons - Atomic structure - Halogen derivatives - Chemical bonding - Hydroxy compounds - States of matter - Carbonyl compounds - Chemical energetics - Carboxylic acids and derivatives - Electrochemistry - Nitrogen compounds - Equilibria - Polymerisation - Reaction kinetics 6.4 Applied Chemistry 6.2 Inorganic Chemistry: - Transition Elements - Phase Equilibria - Chemical Periodicity of period 3 - Environmental Chemistry - Chemistry of Group II elements - Nano Chemistry - Chemistry of Group IV elements - Chemistry of Group VII elements 6
- Chemistry of Nitrogen and Sulphur 7.0 SCOPE AND SEQUENCE CHART FORM 5 AND FORM 6 1
TOPIC FORM 5 FORM 6 7.1 PHYSICAL CHEMISTRY: Atoms, Molecules and Stoichiometry Relative masses of atoms and Stoichiometric reaction ratios molecules Titration Mass spectra Percentage yield and percentage The mole and Avogadro constant purity Empirical and molecular formulae Stoichiometric calculations Atomic structure Sub-atomic particles Electronic configurations Ionisation energy Chemical bonding Ionic bonding Covalent bonding Bond reactivity Dative bonding Shapes of molecules Metallic bonding States of matter Intermolecular forces Gaseous state Liquid state Solid state Chemical energetics Enthalpy changes Hess’ Law and Born-Haber cycles Charge density Electrochemistry Redox processes Redox titration Electrode potentials Fuel cells Electrolysis of acidified water Quantitative electrolysis Electrolytic purification of copper/nickel Extraction of aluminium 2
FORM 5 SYLLABUS 8.0COMPETENCY MATRIX 8.1 PHYSICAL CHEMISTRY TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) Atoms, Molecules and explain the terms relative Relative masses of Defining the terms relative A Level Stoichiometry atomic, isotopic, molecular atoms and atomic, isotopic, molecular Science Kit and formula masses. and formula masses. molecules Analysing mass spectra Periodic analyse mass spectra in Calculating relative atomic table charts terms of isotopic Mass spectra mass from given mass Mass abundances and molecular spectra and isotopic spectra fragments. abundances. charts Calculating number of relate a mole to Avogadro moles in relation to constant. Avogadro constant. Analysing combustion and The mole and composition data to deduce determine empirical and empirical and molecular 3
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) molecular formulae using Avogadro constant formulae. combustion data or Conducting practical composition by mass. analysis of stoichiometric construct balanced relationships involving acid- Dilute equations Empirical and base titrations and hydrochloric perform molecular formulae combustion acid and calculations.including the sodium use of mole concept hydroxide involving reacting masses, volumes of gasses, volumes and concentrations of solutions. Stoichiometric calculations Atomic structure describe the behaviour Sub-atomic particles Explaining the A -level of sub-atomic particles behavior of sub-atomic science kit in an electric field. particles and ions in an Periodic describe electronic Electronic electric field. table configuration of configurations Deducing electronic Graph elements in terms of s, configuration of atoms papers p and d orbitals for 1, and ions. ICT Tools 2, and 3 quantum Drawing and describing and numbers. shapes of orbitals. Braille/Jaws describe the shapes of software s and p orbitals. Analyzing successive explain the term Ionisation energy (IE) ionization energies to ionisation energy. deduce configuration. deduce the electronic configuration from successive Ionisation 4
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) energy (IE) data. Chemical bonding Describe ionic bonding Ionic bonding Discussing ionic bonding Form 5 and as in sodium chloride, Drawing ‘dot and cross’ 6 Science Kit magnesium oxide and diagrams. ICT Tools aluminium oxide. Discussing covalent and describe covalent Covalent bonding bonding. Braille/Jaws bonding as in Drawing ‘dot and cross’ software hydrogen, oxygen, diagrams. chlorine, carbon dioxide, hydrogen chloride, ethane, Relating bond reactivity ethene and benzene in Bond reactivity to bond energy, bond terms of orbital length and bond polarity. overlap. compare the reactivity of covalent bonds in terms of bond length, Discussing dative bond energy and bond Dative bonding bonding polarity. Drawing ‘dot and cross’ describe dative diagrams bonding as in the formation of Shapes of molecules Illustrating bonding and ammonium ion and shapes using models. aluminium chloride (Al2Cl6) explain the shapes of Metallic bonding and bond angles in 5
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) molecules using electron pair repulsion; Valency Shell Electron Pair Repulsion) (VSEPR) theory. Intermolecular describe metallic bonds bonding in terms of a lattice of positive ions that are surrounded by mobile electrons. describe, interpret or predict the effects of type of bonding on physical properties. States of matter describe Intermolecular forces: Experimenting to show Jet of water intermolecular forces -Van der Waals bond polarity. Paraffin based on permanent -Hydrogen bonding Plastic ruler and induced dipoles. -Permanent dipole – Polythene permanent dipole rod interaction Perspex rod outline the importance Experimenting with ice Ice of hydrogen bonding to and water to show Copper wire physical properties of Hydrogen-bonding. Tungsten substances. Discussing the wire importance of intermolecular forces to properties of 6
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) state the basic Gaseous state substances. assumptions of the kinetic theory as Discussing the applied to an ideal gas. assumptions of the explain the validity of kinetic theory as applied the kinetic theory of to ideal gases. gases as applied to Calculating using real gases general gas equation. Models use the general Illustratingthe behavior gas.equation pV=nRT, of particles using a in calculations Liquid state molecular model. describe using a Solid state kinetic molecular model, the liquid state, solid state and the interconversion of states. describe the lattice structure of a Discussing the lattice crystalline solid which structures of sodium is ionic, simple chloride, iodine, ice, molecular, giant copper, silicon dioxide, molecular, hydrogen diamond and graphite. bonded and metallic. Chemical Energetics explain that chemical Enthalpy changes of: Experimenting to show Form 5 and reactions are -Reaction energy changes 6 Science Kit accompanied by -Formation (exothermic and ICT Tools 7
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) energy changes mostly -Combustion endothermic). and in the form of heat -Neutralisation Discussing the various Braille/Jaws energy. -Hydration enthalpy changes software explain the terms -Solution Experimenting to make enthalpy changes, -lattice fertilizer and calculating standard enthalpy changes, -electron affinity heat changes. bond energy and lattice Carrying out energy thermometric titrations. calculate enthalpy Hess Law and Born- Plotting graphs of changes using vc∆ T Haber cycles quantity against apply Hess Law to temperature. construct energy Constructing and cycles and Born- Charge density analyzing Born-Haber Haber cycles. cycles. calculate enthalpy changes using energy cycles and Born-Haber Discussing factors cycles. affecting lattice energy. explain the factors affecting the size of lattice energy. Electrochemistry describe redox Redox processes Discussing reduction Form 5 and processes in terms of and oxidation in terms of 6 Science Kit electron transfer and electron transfers. changes in oxidation Experimenting on redox state. reactions. Electrode potentials 8
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) describe the terms standard electrode potential and standard Drawing the standard cell potential. hydrogen electrode. describe the measurement of electrode potentials using the standard hydrogen electrode. Calculating standard cell predict the feasibility of potentials. the reaction from Electrolysis of Experimenting on standard cell potential. acidified water electrolysis of acidified describe the Electrolytic purification water and copper production of of copper/nickel sulphate. hydrogen, oxygen, Extraction of Discussing electrolytic aluminium, copper, aluminium production of aluminum nickel and chlorine by Production of and chlorine. electrolysis. chlorinefrom brine predict the identity of the substance liberated during electrolysis from the 9
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) state of electrolyte, position in the redox series and concentration. Equilibria explain the terms Chemical equilibria Discussing reversible Form 5 and reversible reaction and Equilibrium constants reactions and dynamic 6 Science Kit dynamic equilibrium. equilibria. deduce expressions Deducing equilibrium for equilibrium expressions. constants in terms of concentrations (Kc) and partial pressures (Kp) calculate the values of Kc, Kp and the Calculating the values quantities present at ofKc, Kp and quantities equilibrium present at equilibrium state Le Chatelier’s Le Chatelier’s Deducing direction of principle and apply it principle and factors shift of equilibrium to deduce effects of affecting equilibrium position using Le changes in Chatelier’s principle. temperature, concentration or pressure on a system Ionic equilibria at equilibrium. Bronsted-Lowry apply the Bronsted- theory of acids and Lowry theory to define bases Discussing the 10
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) acids and bases Bronsted-Lowry theory, Distinguish between strengths of acids and Citrus fruits strong and weak acids bases. Vinegar and bases in terms of Flowers extent of dissociation pH and pOH Soft drinks Calculate [H+(aq)] and Acid and base Calculating pH, Ka, pKa, pH values for strong dissociation constants pOH, Kb, pKb, Kw, Ashes and weak acids and pKwvalues of acids and Household bases bases detergent Explain the terms pH, Ka, pKa, pOH, Kb, pKb, Choice of indicators Discussing the choice of Kw, pKw and apply suitable indicators for them in calculations. acid-base titrations. Explain the choice of suitable indicators for Titration curves Drawing titration curves acid-base titrations from experimental data. given appropriate data. Describe graphically the changes in pH during acid-base titrations. Reaction Kinetics device suitable methods of measuring Experimenting on Form 5 and experimental reaction rates techniques for studying 6 Science Kit techniques for studying the rate of reaction. ICT Tools the rate ofreaction Rate equations and from given information. Discussing the Braille/Jaws terms:rate of reaction, software 11
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) activation energy, rate explain the terms: rate equation order of of reaction, activation reaction; rate constant, energy, rate equation, half-life rate, determining order of reaction, rate Factors affecting rates step and catalysis. constant, half-life; rate of reactions Experimenting on factors determining step and affecting rates of catalysis. reactions. explain in terms of Drawing Boltzmann collisions the effect of distribution curves and concentration changes reaction profile and temperature on diagrams. the rate of a reaction. explain effect of temperature change in terms of the Graph books Boltzmann distribution on the rate of reaction explain that in the presence of a catalyst a reaction has a different mechanism Constructing rate i.e. one of lower equations from activation energy. experimental data construct rate equations of the form 12
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURCES to: AND KNOWLEDGE) rate =k[A]m[B]n for which m and n are 0, 1 or 2. Calculating initial rate, calculate initial rate, half-life and rate half-life and rate constant. constant deduce the order of Deducing the order of reaction using initial reaction using initial rate method and Mechanism of rate method and concentration time reactions concentration time graphs. graphs. show graphicallythat the half –life of a first order reaction is Constructing reaction constant. mechanisms. deduce a mechanism from the order of reaction and vice versa. 13
8.2 INORGANIC CHEMISTRY TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) Chemical describe the variations in Variation in Physical Discussing trends in Graphs Periodicity of atomic radius, ionic radius, properties physical properties. period 3 ionisation energy, melting Data booklets point and electrical. ICT Tools and conductivity of period 3 Analysing data and Braille/Jaws elements. sketching graphs software explain the variation in on variations in atomic radius, ionic radius physical properties. and first ionisation energy. interpret the variation in melting point and electrical conductivity in terms of bonding and structure. describe the reactions if Variation in Chemical any, of elements with properties oxygen, chlorine and water. explain the variation in Burning magnesium oxidation number of oxides 14
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) and chlorides. ribbon. Form 5 and 6 describe the acid base Science Kit behaviour of oxides Reacting sodium and magnesium describe the reactions of with cold water oxides and chlorides with water. *NB: Sodium suggest the type of bonding explodes in water present in chlorides and oxides from their physical Dissolving oxides and chlorides in water and and chemical properties. testing their pH. Sodium chloride Relating physical properties to bonding. Magnesium chloride Aluminium oxide Aluminium chloride Chemistry of interpret the trends in Trends in Physical Justifying trends in Data booklet Group II physical properties. properties physical properties elements using data booklet values. 15
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) Experimenting on describe the reactions of Trends in Chemical the reactions of the elements with oxygen properties elements with water A level Science and oxygen. kit and water. Dissolving oxides in water and testing describe the behaviour of for pH. pH meter oxides with water. Heating carbonates explain the variation in and nitrates;testing products produced. thermal decomposition of the carbonates and nitrates. Dissolving magnesium sulphate, calcium explain the variation in sulphate and barium sulphate in solubility of the sulphates. water. Discussing uses of state the properties and Properties and uses of magnesium oxide, uses of group II Group II compounds calcium oxide, magnesium 16
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) compounds. calcium carbonate, oxide, calcium magnesium.sulphat oxide, calcium e, calcium sulphate, carbonate, barium sulphate, magnesium magnesium sulphate, hydroxide and calcium magnesium sulphate, trisilicate(MMT) barium sulphate, magnesium hydroxide and magnesium trisilicate (MMT) Site visits Chemistry of explain the variations in Trends in Physical Discussing trends in Form 5 and 6 Group IV melting and in electrical properties physical properties. Science Kit elements conductivity of the Experimenting with Lead (IV) oxide elements. Lead (IV) oxide, explain the variations in charcoal and coal. ICT Tools and bonding, acid-base nature Braille/Jaws and thermal stability of the software oxides of oxidation states II 17
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) & IV. Constructing describe the bonding, molecular shapes molecular shape and using models. Site visits volatility of the Discussing the tetrachlorides. Trends in Chemical behaviour of explain reactions of the properties tetrachlorides with tetrachlorides with water in water and organic terms of structure and solvents. bonding. describe the relative Experimenting with Lead (IV) oxide. stability of higher and lower oxidation states of the elements in their oxides and aqueous solutions. recognise the properties Properties and uses of Discussing and uses of the elements Group IV elements and properties and uses compounds of elements and and their compounds. compounds such as glass, ceramics, tooth filler, diamond, graphite, carbon- tetrachloride. 18
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) Form 5 and 6 Trends in Physical properties Science Kit describe the trends in volatility Discussing the trends in ICT Tools and Braille/Jaws Chemistry of Group and colour of chlorine, bromine Trends in Chemical properties volatility and colour of software VII elements and iodine. chlorine, bromine and interpret the volatility of elements iodine. Site visits in terms of Van der Waal forces. explain the relative reactivity of elements as oxidising agents with reference to E0 values. explain the reactions of elements Calculating E0 cell values with hydrogen and changes in oxidation explain the relative thermal states for the reactions stabilities of the hydrides in terms between halogens and of bond energies. sodium thiosulphate. Discussing the reactions of elements with hydrogen and relative thermal describe the reactions of the stabilities of resulting halide ions with silver ions hydrides. Properties and uses of Group Testing for halide ions followed by aqueous ammonia VII elements and compounds and with concentrated sulphuric acid describe the reaction of chlorine 19
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) with cold and hot aqueous sodium hydroxide. explain the industrial importance and environmental significance Discussing the industrial of the halogens and their importance and compounds. environmental significance of halogens and their compounds (e.g. bleaches, PVC, halogenated hydrocarbons as solvents, refrigerants, aerosols and chlorine in purification of water). Chemistry of explain the lack of reactivity Chemical properties of Discussing the Form 5 and 6 Nitrogen and Nitrogen chemical properties Science Kit Sulphur of nitrogen. of nitrogen. ICT Tools and Discussing the Braille/Jaws describe the formation and formation and software structure of the ammonium structure of the ion and its reaction with ammonium ion. Site visits alkalis. Haber Process Experimenting on Resource explain the manufacture of the laboratory persons ammonia by the Haber preparation of 20
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) process in terms of the ammonia. principles of kinetics and equilibria. Contact Process explain the manufacture of Discussing the Haber process and sulphuric acid by the the Contact Contact process in terms of process(the kinetics the principles of kinetics and equilibria). and equilibria. recognise the industrial Preparing importance of sulphuric ammonium sulphate in the acid and ammonia. laboratory. Discussing the recognise the Environmental impacts of environmental environmental Nitrogen and Sulphur consequences of consequences of compounds nitrates, nitrogen oxides, sulphur compounds of nitrogen and oxides. sulphur. Discussing the explain the catalytic removal of oxides of removal of oxides of nitrogen from car 21
TOPIC OBJECTIVES CONTENT (ATTITUDES, SUGGESTED NOTES SUGGESTED Learners should be able to: SKILLS AND AND ACTIVITIES RESOURCES KNOWLEDGE) nitrogen. exhausts and use describe the use of sulphur of sulphur dioxide. dioxide in food preservation. FORM 6 SYLLABUS 8.3 PHYSICAL CHEMISTRY TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) Atoms, calculate, using the mole Stoichiometric Computing reacting masses, Form 5 and 6 Molecules and concept the reacting reaction ratios volumes of gases, volumes Science Kit 22
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) Stoichiometry masses, volumes of gases, Titration and concentrations of ICT Tools and volumes and concentrations solution from given data Braille/Jaws of solution. Performing acid-base software titrations’. determine stoichiometric Deducing stoichiometric relationships from relationships from titration calculations. results. calculate percentage yield Percentage yield Constructing balanced and percentage purity. and percentage equations. purity Electrochemistr use redox titration results in Redox titration Performing redox titrations Form 5 and 6 y quantitative analysis. Discussing the composition Science Kit describe how the hydrogen and electrode reactions of ICT Tools and oxygen fuel cell operate. fuel cells. Braille/Jaws deduce electrode reactions software from a given fuel cell. Fuel cells Citing advantages and compare fuel cells with disadvantages of fuel cells conventional cells. over conventional cells. calculate the quantity of Quantitative Determining the quantity of charge, mass and or volume electrolysis charge, mass and or volume of substance liberated during of substance liberated electrolysis using the during electrolysis relationship, F=Le (Faraday constant, the Avogadro constant and the charge on 23
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) the electron) describe how to determine a determining experimentally value of Avogadro constant the value of the Avogadro by an electrolytic method. constant. Equilibria explain how buffer solutions Buffer solutions Discussing buffer solutions Form 5 and 6 control pH. including their role in Science Kit calculate the pH and/or pOH controlling blood and soil ICT Tools and of buffer solutions. pH. Braille/Jaws apply the concept of Solubility products Preparing buffer solutions software solubility product, Ksp Determining pH and pOH of calculate Ksp from buffer solutions concentrations and vice Calculating solubility versa products from explain the common ion concentrations and vice effect versa including common ion effect Reaction Outline the different modes of Catalysis Discussing the different modes of Form 5 and 6 kinetics action of homogeneous and -Homogeneous action of homogeneous and Science Kit heterogeneous catalysis as heterogeneous catalysis such as exemplified in the Haber process, -Heterogeneous Fe in the Haber process and Fe2+ ICT Tools and catalytic removal of oxides of in I-and S2O82- reaction. Braille/Jaws nitrogen in the exhaust gases from Carrying out experiments on software car engines, the redox reaction decomposition of hydrogen between I- and S2O82- and catalytic peroxide catalysed by manganese role of NOxin the oxidation of (IV) oxide. atmospheric sulphur dioxide. 24
8.4 ORGANIC CHEMISTRY TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) Hydrocarbons use the nomenclature,structural Nomenclature Discussing nomenclature, Form 5 and 6 formulae and displayed formulae for general formula and displayed Science Kit hydrocarbons from C1 to C10 formulae for hydrocarbons from C1 to C10 ICT Tools and describe the forms of isomerism Illustrating forms of isomerism Braille/Jaws found in hydrocarbons using molecular models software Isomerism Molecular 25
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) explain the use of crude oil and Discussing the process of models natural gas as sources of fractional distillation of crude oil Cooking oil hydrocarbons Discussing the physical Paraffin explain the decrease in volatility properties of hydrocarbons with increasing carbon chain Preparation and occurrence Experimenting with cooking oil or paraffin to demonstrate cracking Discussing the chemistry of describe the chemical reactions of alkanes as exemplified by the Physical properties alkanes, alkenes and arenes following reactions of ethane: Combustion Free radical substitution by describe the mechanism of free chlorine and its mechanism radical substitution, electrophilic addition and electrophilic Chemical properties Discussing the chemistry of substitution alkenes as exemplified by the following reactions of ethene: Electrophilic addition of steam, hydrogen halides and halogens including mechanism Catalytic addition of hydrogen Oxidation by cold dilute Reaction manganate (VII) ions to form diol mechanisms Oxidation by hot concentrated manganate (VII) ions Polymerisation Discussing the chemistry of arenes as examplified by the 26
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) following reactions of benzene and methyl benzene : Electrophilic substitution with bromine including mechanism Nitration including mechanism Oxidation of the side chain Predicting whether halogenation will occur on the side chain or on the aromatic nucleus in arene Halogen use the nomenclature and Nomenclature Drawing displayed Form 5 and 6 derivatives displayed formula of structures and naming Science Kit halogenoalkanes and them ICT Tools and halogenoarenes Braille/Jaws describe the isomerism software associated with halogen Isomerism Discussing isomerism Journals derivatives associated with halogen Bromoethane derivatives Silver nitrate Aerosols describe the following Experimenting with Plastics nucleophilic substitution Chemical properties bromoethane, silver reactions of halogenoalkanes nitrate and hot water to as exemplified by the show substitution reactions of bromoethane: hydrolysis, formation of nitriles Writing equations and and formation of primary amines formulae of products by reaction with ammonia from nucleophilic substitution describe the mechanism of 27
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) nucleophilic substitution in Describing the halogenoalkanes mechanism of nucleophilic substitution in terms of SN1 and SN2 explain the elimination of Experimenting with hydrogen bromide from 2- ethanolic sodium bromopropane hydroxide and bromopropane to show elimination interpret the different reactivities of halogenolkanes Comparing the strengths of and chlorobenzene with the C-Hal bonds and particular reference to relating them to reactivity hydrolysis and to the relative strengths of the C-Hal bonds explain the uses of fluoroalkanes and Discussing the uses of fluorohalogenoalkanes in fluoroalkanes and terms of their relative fluorohalogenoalkanes and chemical inertness their effects on the recognise the concern about environment the effect of chlorofluoroalkanes on the Uses and ozone layer environmental impact Hydroxy use the nomenclature and Nomenclature Discussing the structure, Form 5 and 6 28
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) compounds displayed formulae to nomenclature and Science Kit describe the structure of classification of alcohols ICT Tools and primary, secondary and Braille/Jaws tertiary alcohols Drawing structures of software describe the isomerism Isomerism optical and structural associated with alcohols isomers describe the manufacture of Manufacture of Preparing of ethanol by ethanol using fermentation ethanol fermentation using process locally available resources Marula explain the physical Physical properties Discussing the solubility Baobab Fruits properties of hydroxy and volatility of alcohols Grapes compounds in terms of bonding describe the reactions of Chemical properties Discussing reactions of alcohols as exemplified by of alcohols alcohols ethanol during combustion, Distinguishing between substitution to give primary, secondary and Ethanol halogenoalkanes, reaction tertiary alcohols by Acidified with sodium, oxidation to oxidation reactions potassium carbonyl compounds and dichromate carboxylic acids, dehydration Propan – 2-ol and ester formation 2methylpropan 29
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) – 2-ol describe the reaction of the Deducing the presence of methyl secondary alcohol CH3 CH (OH) – group in an with alkaline iodine alcohol using alkaline aqueous iodine describe the reactions of Chemical properties Discussing the reactions of phenol with bases, sodium of phenols phenol and during nitration and bromination of the aromatic ring Comparing the acidity of explain the relative acidities water, phenol and ethanol of water, phenol and ethanol Carbonyl use the nomenclature and Nomenclature Discussing the Form 5 and 6 compounds displayed formulae to nomenclature and Science Kit describe the structure of displayed formulae of ICT Tools and aldehydes and ketones aldehydes and ketones Braille/Jaws software explain the isomerism Isomerism Drawing structures to associated with aldehydes illustrate the isomerism in and ketones carbonyl compounds Ethanol Acidified describe the formation Preparation Preparing aldehydes and potassium aldehydes and ketones from ketones from respective dichromate primary and secondary alcohols Propan – 2-ol 30
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) alcohols respectively outline the mechanism of Chemical properties Analysing the mechanism nucleophilic addition reaction of nucleophilic addition of hydrogen cyanide with reaction of hydrogen aldehydes and ketones cyanide with aldehydes and describe the reduction of ketones aldehydes and ketones using Discussing the reactions of NaBH4 carbonyl compounds, with suggest a suitable test for a NaBH4, 2.4-DNPH, given carbonyl compound Fehling’s solution, alkaline iodine and Tollens reagent Carboxylic acids interpret the nomenclature Nomenclature Drawing displayed formulae Form 5 and 6 and derivatives and formulae of carboxylic for carboxylic acids and Science Kit acids and their derivatives their derivatives ICT Tools and Braille/Jaws Preparation and Preparing carboxylic acids software describe the formation of occurrence and esters carboxylic acids from alcohols, aldehydes and nitriles Chemical properties Constructing equations for recall the reactions of the reactions of carboxylic carboxylic acids in the acids 31
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) formation of salts, esters and acyl chlorides Comparing the acidity of explain the acidity of carboxylic acids and carboxylic acids and of substituted carboxylic acids chlorine substituted ethanoic acids in terms of their structures Discussing the reactions of Vinegar describe the reactionsof acyl acyl chlorides with water, chlorides with water, alcohols, alcohols, phenols and phenols and primary amines primary amines Discussing the relative explain the relative ease of ease of hydrolysis of acyl hydrolysis of acyl chlorides, chlorides, alkyl chlorides alkyl chlorides and aryl and aryl chlorides chlorides Preparing esters from illustrate the formation of carboxylic acids or acyl esters from carboxylic acids chlorides or acyl chlorides using ethyl ethanoate and phenyl benzoate as examples Manufacturing soap from fats and oils describe the acid and base hydrolysis of esters Investigating uses of carboxylic acids and esters 32
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) state the uses of carboxylic acids and esters Fats Uses of carboxylic Oils acids and esters Ash Nitrogen describe the formation of Preparation and Discussing the formation of Form 5 and 6 compounds ethylamine by reduction of occurrence ethylamine by reduction of Science Kit nitrile and of phenylamine by nitrile and of phenylamine ICT Tools and reduction of nitrobenzene by reduction of Braille/Jaws nitrobenzene software explain the relative basicity Chemical properties Comparing the relative of ammonia, alkylaminesand basicity of ammonia, phenylamines in terms of alkylamines and their structures phenylamines in terms of their structures describe the reaction of Discussing the reactions of phenylamine with: phenylamine with aqueous - aqueous bromine bromine and with nitrous - nitrous acid acid Discussing the hydrolysis of diazonium salt to give phenol describe the coupling of Synthesizing dyestuff benzenediazonium chloride 33
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) and phenol and the use of Dyestuff similar reactions in the Discussing the formation Nitrous Acid formation of dyestuff and hydrolysis of amides describe the formation of amides from the reaction between RNH2 and R’COCl describe acid-base hydrolysis amides Deducing the product of of amides hydrolysis of amides investigate the acid/base Analysing the acid/base properties of amino acids and properties of amino acids the formation of zwitterions i.e. from titration curves illustrate the formation of Constructing equations to peptide bonds in protein and show formation of peptide polypeptide formation bonds describe the hydrolysis of Drawing structures of the proteins products of hydrolysis Polymerisation Describe the characteristics Types of Polymerisation Classifying polymers Samples of of addition polymers as -addition polymers - condensation examplified by polythene and PVC ICT Tools and explain condensation Drawing repeat units Braille/Jaws 34
TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKILLS ACTIVITIES AND NOTES RESOURSES AND KNOWLEDGE) polymerisation as in from given monomers or software polyesters and polyamides sections of polymers predict the type of and vice versa Molecular polymerisation reaction for a models given monomer or pair of monomers deduce the repeat unit of a Building models of polymer obtained from a polymers given monomer or pair of monomers identify the monomer(s) present in a given section of a Uses of polymers polymer molecule recognise the uses of polymers Discussing uses of polymers Visiting sites 8.5 APPLIED CHEMISTRY TOPIC OBJECTIVES CONTENT SUGGESTED LEARNING SUGGESTED Learners should be able to: (ATTITUDES, SKIILS ACTIVITIES AND NOTES RESOURSES 35
AND KNOWLEDGE) Transition explain what is meant by Characteristic Discussing characteristic Form 5 and 6 Elements transition, in terms of d- properties properties of transition Science Kit block element forming one elements or more stable ions with ICT Tools and incomplete d-orbitals Braille/Jaws analyse the electronic Working out the electronic software configuration of the first row configuration of the first row transition elements and transition elements and their ions their ions recognise that the atomic radii, ionic radii and first Analyzing atomic radii, ionisation energies of the ionic radii and first transition metals are ionisation energies data of relatively invariant the transition metals contrast qualitatively the Comparing the melting melting point, density, points, densities, atomic atomic radius, first radii, first ionisation ionisation energy and energies and conductivities conductivity of the transition of the transition elements elements with those of with those of calcium as a calcium as a typical s-block typical s-block element element describe the tendency of Experimenting to show transition elements to have variable oxidation states variable oxidation states explain the formation of Discussing formation of complexes in terms of co- Variable oxidation complexes ordinate bonds and the state splitting of d orbitals 36
describe the shape of four- fold and six fold complexes Complex formation explain the types of Drawing shapes of isomerism that complexes complexes and showing may exhibit isomerism explain ligand exchanges in terms of competing Experimenting on ligand equilibria and stability exchange constants explain redox reactions of complexes in terms of E0 Calculating E0 cells to values predict feasibility of reactions interpret the effect of ligand exchange on E0 values explain, in terms of d orbital splitting, why transition Discussing the splitting of element complexes are d-orbitals in colour formation of complexes usually coloured explain changes in colour of complexes as a result of ligand exchange explain the magnetic 37
properties of transition metals and their complexes Experimenting on magnetic in terms of paired and properties of transition unpaired d electrons. metals and their complexes Deducing magnetic describe the occurrence, properties from electronic relative stability and colour Colour concept configurations of vanadium ions and its Catalysis investigating the compounds occurrence relative stability and colour of describe the uses of vanadium ions and Magnetism compounds vanadium and its compounds discussing the uses of describe the occurrence, vanadium and compounds relative stability and colour of chromium aqueous ions and compounds containing investigating the the metal in the +3 and +6 occurrence relative oxidation states. stability and colour of Ammonium chromium ions and its vanadate (V), explain uses of chromium compounds and its compounds describe the use of discussing the uses of dichromate (VI) as an chromium and its oxidising agent Chromium compounds occurence testing for alcohol and for describe the chromate (VI) sulphur dioxide using 38
to dichromate (VI) dichromate (VI) interconversion demonstrating the interconversion of describe the occurrence chemical chromate (VI) to and relative stability and properties and dichromate (VI) using dilute colour of manganese ions its uses acids and alkalis and compounds containing Investigating the the metal in the +2, +4, +6 occurrence relative and +7 oxidation states stability and colour of manganese compounds demonstrate redox reactions involving MnO2, MnO42- and MnO-4 Experimenting on the describe the occurrence, manganese disproportionation of relative stability and colour occurrence MnO42- of ironcompounds, Investigating the describe the effect of pH occurrence relative and the cyanide ligand on stability and colour of iron stability of iron and its ions compounds Manganese chemical Experimenting on the effect dioxide explain the biochemical properties and of pH on stability of iron Hydrogen importance of iron in uses and its ions peroxide haemoglobin and in Sodium hydroxide cytochrome analyse the rusting of iron Discussing the biochemical iron and its prevention importance of iron in occurrence and haemoglobin and in 39
extraction cytochrome distinguish between Fe2+ Investigating conditions for (aq) and Fe3+ (aq) using iron to rust and its Fe(CN)63- (aq) and SCN - prevention (aq), respectively Testing for Fe2+ (aq) and Fe3+ (aq) using Fe(CN)63- (aq) and SCN -(aq), describe the use of iron and respectively its compounds chemical Discussing the use of iron properties and uses and its compounds Describe the occurrence, relative stability and colour of cobalt ions and compounds containing the Investigating the metal in its +2 and +3 occurrence relative oxidation states, stability and colour of cobalt compounds explain the effect of ligands Iron nails and/or temperature on the Magnesium stability and geometry of ribbon cobalt complexes, using as Experimenting on the Potassium examples cobalt effects of temperature on hexacyanoferrate [Co(H2 O)6]2+ [CoCl4]2, and Occurrence stability of cobalt (III) [Co(NH3)6]2+ [Co(NH3)6]3+ complexes Potassium Thiocyanate explain the uses of cobalt as in alloys, anhydrous cobalt (II) ions as a test for 40
water and its biochemical importance Chemical properties Discussing the uses of and uses cobalt and its compounds describe the occurrence, production and purification of nickel from its sulphide ore explain the use of nickel in Discussing the occurrence, alloys(e.g. alnico)and as a production and purification hydrogenation catalyst of nickel from its sulphide ore describe the occurrence, Discussing the use of production and purification nickel in alloys of copper, describe the occurrence Discussing the occurrence, and relative stability of ions production and purification and compounds containing Nickel of copper, the metal in the +1 and +2 Occurrence and oxidation states, including extraction the disproportionation and Chemical properties stabilisation of Cu+ (aq) and uses Investigating the describe the reaction of copper occurrence, relative Cu2+(aq) with I-(aq) Occurrence and stability and colour of extraction copper compounds explain uses of copper and its compounds as in brass, 41
bronze, other alloys, and in Chemical properties Experimenting on the the test for aldehydes and uses reaction of Cu2+(aq) with I- (aq) Discussing the uses of copper and its compounds describe the occurrence and extraction of platinum identify elements which occur together with platinum suggest the uses of Investigating the platinum group metals occurrence and extraction of platinum Visiting sites Platinum group metals (PGM) -occurrence -extraction -uses Phase Equilibria explain steam distillation of Steam Distillation experimenting on steam Form 5 and 6 two immiscible liquids distillation Science Kit 42
demonstrate an awareness discussing methods of ICT Tools and of the applications of steam distillation Braille/Jaws distillation software explain the term partition coefficient Distribution between calculate partition phases coefficient for a system in working out partition which the solute is in the coefficient for a system same molecular state in the two solutions explain solvent extraction carrying out solvent extraction explain: paper, high Performing thin layer, performance liquid, ion column and paper exchange, thin layer, Chromatography chromatography column and gas/liquid chromatography in terms of absorption and/or partition, based on appropriate practical experience demonstrate an awareness Discussing industrial and of the applications of these medical applications of methods of chromatography Chromatography chromatography in industry kit and and medicine chromatograms describe the process of Resource electrophoresis, and the persons effect of pH describe the hydrolysis of electrophoresis Discussing electrophoresis proteins, separation and and genetic fingerprinting 43
detection of the products by electrophoresis outline the process of genetic analysis of genes and fingerprinting genetic fingerprinting Environmental 7.0 outline the main industrial Air Pollution and Discussing the main ICT Tools and Chemistry methods of controlling Control causes of air pollution Braille/Jaws sulphur dioxide emission software (flue gas desulphurisation, Resource alkaline scrubbing, use of persons limestone-based fluidised beds) 8.0 recognise the use of lean- Discussing the methods of burn engines and catalytic controlling pollution converters in reducing pollutant emissions from petrol-driven cars 9.0 deduce environmental Discussing environmental considerations related to impact of power the usage and generation generation of power (with particular Visiting sites reference to fossil fuels and nuclear energy) 10.0 identify other potential Case studying power sources recognise the hazards 44
associated with random emission from uranium-bearing rocks and with nuclear accidents 11.0 recognise the potential application and risks of applications of Discussing the concepts nanomaterials nanomaterials of nanoscience and - medicine nanotechnology - water purification Predicting the potential - environmental applications and risks of pollution control nanomaterial and remediation Resource persons 12.0 outline the use of ion exchange in the treatment of industrial waste Waste management 13.0 recognise the potential Ion exchange consequence of the use of Incineration land-filling and incineration Land filling Discussing the various (including the importance of Recycling methods of waste temperature control and the management possible release of dioxins) for the disposal of solid waste 14.0 outline the advantages and disadvantages of 45
dumping waste at sea and in rivers (including sewage and the problems associated with oil spillages) Discussing advantages 15.0 recognise the problems and disadvantages of associated with heavy different methods of waste metals in the environment, management e.g. lead, mercury and chromium 16.0 recognise the problems Case studying associated with the disposal of radioactive waste and mine waste Visiting sites 46
9.0 ASSESSMENT (a) ASSESSMENT OBJECTIVES The scheme of assessment is grounded in the principle of inclusivity and equalisation of opportunities hence does not condone direct or indirect discrimination of learners. Modifications of arrangements to accommodate candidates with special needs must be put in place in both continuous and summative assessments. These modifications must neither give these candidates an undue advantage over others nor compromise the standards being assessed. NB: For further details on arrangements, accommodations and modifications refer to the assessment procedure booklet. The three assessment objectives in A - Level Chemistry are: 1: Knowledge with understanding 2: Handling information and problem solving 3: Experimental skills, investigations and applications 47
1: Knowledge with understanding Candidates should be able to demonstrate knowledge and understanding of: • scientific phenomena, facts, laws, definitions, concepts, theories • scientific vocabulary, terminology, conventions (including symbols, quantities and units) • scientific instruments and apparatus, including techniques of operation and aspects of safety • scientific quantities and their determination • scientific and technological applications with their social, economic and environmental implications. 2: Handling information, problem solving, synthesis, analysis and evaluation In words or using other written forms of presentation (e.g. symbolic, graphical and numerical), candidates should be able to: • locate, select, organise and present information from a variety of sources • translate information from one form to another • manipulate numerical and other data • use information to identify patterns, report trends and draw inferences • present reasoned explanations of phenomena, patterns and relationships • make predictions and hypotheses • solve problems, including some of a quantitative nature. 3: Experimental skills, investigations and applications Candidates should be able to: • know how to use techniques, apparatus, and materials (including following a sequence of instructions, where appropriate) • make and record observations and measurements • interpret and evaluate experimental observations and data • plan investigations, evaluate methods and suggest possible improvements (including the selection of techniques, apparatus and materials). 48
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