IAQ Assessment Manly State School-Library, GLA 20 & Music Room
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IAQ Assessment Manly State School- Library, GLA 20 & Music Room October 2010 Department of Education and Training Parsons Brinckerhoff Australia Pty Limited ABN 80 078 004 798 Level 4, Northbank Plaza 69 Ann Street BRISBANE QLD 4000 GPO Box 2907 BRISBANE QLD 4001 Australia Telephone +61 7 3854 6200 Facsimile +61 7 3854 6500 Email brisbane@pb.com.au U U Certified to ISO 9001, ISO 14001, AS/NZS 4801 RPT005Aaw - Manly State School - IAQ assessment - Stage 3 A+ GRI Rating: Sustainability Report 2009
Revision Details Date Amended By A Original ©Parsons Brinckerhoff Australia Pty Limited (PB) [2010]. Copyright in the drawings, information and data recorded in this document (the information) is the property of PB. This document and the information are solely for the use of the authorised recipient and this document may not be used, copied or reproduced in whole or part for any purpose other than that for which it was supplied by PB. PB makes no representation, undertakes no duty and accepts no responsibility to any third party who may use or rely upon this document or the information. Author: Anthony Warwick ......................................................................... Signed: ..................................................................................................... Reviewer: Michael Shepherd ........................................................................ Signed: ..................................................................................................... Approved by: Michael Shepherd ........................................................................ Signed: ..................................................................................................... Date: September 2010 .......................................................................... Distribution: DETA, Manly State School ..........................................................
IAQ Assessment Manly State School - Library, GLA 20 & Music Room Contents Page number Executive summary iii 1. Introduction 1 2. Glossary of terms 2 3. Methodology 4 3.1 Sampling strategy & rationale 4 3.1.1 Overview 4 3.1.2 TVOCs 5 3.1.3 Formaldehyde, Aldehydes and Ketones 6 3.1.4 Amino ethanol compounds 7 3.2 Test Methods 7 3.2.1 Methods for estimating Total Volatile Organic Compounds 7 3.2.2 Screening for the presence of aldehydes and ketones 8 3.2.3 Amino ethanol compounds 9 3.3 Odour thresholds and use of relevant standards for airborne contaminants 10 3.4 Limitations 10 4. Evaluation criteria 12 4.1 Overview of air quality standards 12 4.2 Occupational Exposure Standards (national exposure standards) 13 4.3 Airborne contaminant guidelines 14 5. Relevant legislation 17 6. Results and discussion 18 6.1 Visual inspection 18 6.2 A review of results by sampling location 18 6.2.1 Library & Computer Room 18 6.2.2 B Block GLA-20 19 6.2.3 C Block – Music room areas 20 7. Recommendations 22 8. Summary 24 PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page i
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 9. References 25 Appendices Appendix A ‐ Results tables – Chemical contaminants Appendix B ‐ Building Product ingredients disclosed in MSDSs PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page ii
IAQ Assessment Manly State School - Library, GLA 20 & Music Room Executive summary Parsons Brinckerhoff (PB) was commissioned by the Queensland Department of Education and Training (DETA) to undertake comprehensive screening for the presence of the airborne contaminants at Manly State School located at 63 Ernest Street, Manly. Sampling was undertaken within the A Block Library and Computer Room, the B Block GLA 20 Class Room, and C Block Music Room upstairs. These areas were identified for testing by the school employees due to the presence of irritating odours like those in the Uniform Shop tested 31 August 2010. Sampling was undertaken at Manly State School 15 September 2010. Laboratory analysis was undertaken at Leeder Consulting in Melbourne, a NATA accredited laboratory for the methods used. The sampling program included screening for the following groups of materials using sample tube and laboratory techniques: VOCs (e.g. benzene, toluene, styrene, alcohols, alkanes) Aldehydes and ketones (e.g. formaldehyde) Ethanolamines. The results of the sampling and analysis showed that formaldehyde was present at levels greater than those recommended in the rescinded NHMRC publication titled, NHMRC’s Interim National Indoor Air Quality Goals and the Canadian Health publication, titled, Exposure Guidelines for Residential Indoor Air in the following locations: B Block GLA 20 C Block Music Room (general class room). The formaldehyde levels were also above the concentration range found in typical Australian dwellings as documented in the CSIRO study report titled, Indoor Air Project Part 1: Main Report Indoor Air in Typical Australian Dwellings, 2010. Levels of formaldehyde above the recommended guidelines were not identified in the A Block (Library and Computer Room) or C Block, (Music Teacher’s Office). In the class rooms the formaldehyde emission sources included MDF panel used in the manufacture of portable shelving units, student desks, pin-boards, and white boards. The concentration levels of TVOCs and amino-ethanol compounds were found be within the range usually found in a residential dwelling or less than the concentration range found in a residential dwelling cited by the CSIRO Indoor Air Project. It is recommended that the rooms found to be affected by formaldehyde concentrations above the recommended guidelines be subjected to off-gassing of formaldehyde by heating of the rooms to above 40 degrees C and increasing the changes of fresh make-up air. At the time this report has been completed, it is expected that this recommendation will be completed. Long term strategies and procedural controls should be implemented to ensure low formaldehyde products are purchased such as E0 MDF panel instead of E1 MDF or higher. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page iii
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 1. Introduction Parsons Brinckerhoff (PB) was commissioned by the Queensland Department of Education and Training (DETA) to undertake comprehensive screening for the presence of the airborne contaminants at Manly State School located at 63 Ernest Street, Manly. A third day of sampling was undertaken within the following areas on 15 September 2010: Library including computer laboratory Class room GLA-20 (Class 5H) C Block upstairs, Music Class Room. These additional areas were selected for testing by Manly State School employees due the presence of irritating odours like those found in the Uniform Shop, following after-hours discussions held on site with stakeholders in the school library in July 2010. The following contaminants were screened for using sorbent tubes designed to collect the following groups of airborne contaminants: VOCs (e.g. benzene, toluene, styrene, alcohols, alkanes) Aldehydes and ketones (e.g. formaldehyde, heptanal) Ethanolamine. This report documents the findings of the assessment including sampling methodologies, the evaluation criteria used to assess the results, a discussion and recommendations for remediation where required. The results of previous sampling in the Uniform Shop and ground level of C Block are provided in the report for the sampling undertaken 31 August 2010. No one section or part of a section, of this report should be taken as giving an overall idea of this report. Each section must be read in conjunction with the whole of this report, including its appendices and attachments. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 1
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 2. Glossary of terms AHU Air handling unit CSIRO Commonwealth Scientific and Industrial Research Organisation E0 MDF E0 MDF products are medium density formaldehyde resin particle-board with an emission rate that is less than 0.5 mg/L under AS/NZS 1859.2-2004, measured using AS/NZS 4266.16-2004. E1 MDF E1 MDF products are medium density formaldehyde resin particle-board with an emission rate that is less than 1.0 mg/L under AS/NZS 1859.2-2004, measured using AS/NZS 4266.16-2004. HVAC Heating, ventilation and air conditioning IAQ Indoor air quality ISO International Organisation for Standardisation mg/m3 milligrams per cubic metre µg/m3 micrograms per cubic metre NATA National Association of Testing Authorities National Exposure standard An airborne concentration of a particular substance, within the worker’s breathing zone, which according to current knowledge, should not cause adverse health effects or undue discomfort to nearly all workers. National exposure standards for the occupational environment are set by the National Occupational Health and Safety Commission. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 2
IAQ Assessment Manly State School - Library, GLA 20 & Music Room NIOSH National Institute for Occupational Safety and Health NHMRC National Health and Medical Research Council (Australia) NOHSC National Occupational Health and Safety Commission, redundant organisational name for the Australian Safety and Compensation Council (ASCC), currently called Safework Australia. MSDS Material Safety Data Sheet ppb Parts per billion ppm Parts per million NES National Exposure Standard TWA Time Weighted Average. NHMRC National Health and Medical Research Council VOC Volatile organic compound PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 3
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 3. Methodology The sampling was undertaken 15 September 2010 between 8:15 am and 4:30 pm within the school uniform shop, change room, uniform shop store room, and within C Block ground level in the open “class room” and storage areas which are all understood to be in use by the P&C Committee” for meetings and organising fund raising. 3.1 Sampling strategy & rationale 3.1.1 Overview The sampling was undertaken with a view to conducting a comprehensive and sensitive screening process for the presence of substances identified in building products material safety data sheets provided Dickinson Constructions Pty Ltd. It is understood that the construction of the class rooms in B Block and Music Room in C Block are similar to the lower level of C Block. The following groups of chemicals were identified to be present from a review of the material safety data sheets for the products used in the school: Volatile organic compounds, including but not limited to the following: toluene xylene methylene chloride perchloroethylene (dry cleaning fluid) styrene alkanes benzene. Aldehydes and ketones, including but not limited to the following: formaldehyde acetaldehyde heptanal acetone. Aminoethanol compounds were also screened for due to the presence of odours in the affected areas that are similar in characteristic to these substances which are used in plastics, foams, adhesives, surface coatings, some paints and cleaning chemicals. The groups of substances listed above are often emitted from modern building materials such as particle boards, resins, and adhesives. The substances have the potential to cause the following symptoms when present in excessive concentrations: PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 4
IAQ Assessment Manly State School - Library, GLA 20 & Music Room potential allergic reactions, sensitisation or exasperation of pre-existing asthma central nervous system effects from exposure to elevated levels or prolonged exposures to moderate or elevated exposure levels heath effect to the liver following prolonged and repeated exposures to the substances cancers and leukaemia when exposed to some substances (e.g. benzene) at very high level or repeatedly over prolonged periods. Some substances listed (e.g. formaldehyde) are suspected carcinogens believed to be capable of causing tumours or cancers in humans based on animal studies but these effects have yet to have been verified in humans. Persons with pre-existing asthma conditions or other underlying pulmonary disease are expected to be more sensitive than other healthy persons to acute exposures to indoor air contaminants and may experience coughing and wheezing at low levels of exposure. Acceptable airborne concentrations in sensitive persons will vary on the individual. Synergism may occur between chemical cocktails of contaminants and between exposure to some contaminants and sensitivity to other unrelated contaminants such as ozone, dusts, and vulnerability to microbial organisms. 3.1.2 TVOCs The VOC screen is intended to detect aromatic hydrocarbons (e.g. toluene, styrene, xylene, benzene), alkanes, alcohols, and ethers. The following products used in the building work were found to contain or likely to contain volatile organic compounds as significant (greater than 5%) proportions of their disclosed ingredients: Polymer 265 vinyl floor adhesive, contains: Between 75-95% of ingredients are trade secret ingredients including methyl methacrylate Aliphatic petroleum solvents (e.g. hexanes) Solvent (not disclosed) Petroleum light solvent Aromatic hydrocarbons (not disclosed) Interact carpet tile adhesive Ingredients not disclosed by manufacturer Polymer 1718 A & B (vinyl water resistant epoxy) Selley’s liquid nails, contains: n-hexane (1-10%) Naphtha (light petroleum solvent) Bostik Roof & Gutter PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 5
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 2-butanone oxime (methyl ethyl ketomine) Bostik Seal & Flex, contains: Toluene diisocyanate (
IAQ Assessment Manly State School - Library, GLA 20 & Music Room exist for all of these substances. Many aldehydes are also not included in the List of designated hazardous substances published by the NOHSC. Heptanal has no documented occupational exposure standard or indoor air quality target for comparison. Within B Block and C Block the class rooms a number of products were found to contain formaldehyde including the following items and materials: Smart desk table tops manufactured by Bizfurn which contain urea formaldehyde resin and melamine urea formaldehyde resin (
IAQ Assessment Manly State School - Library, GLA 20 & Music Room Sampling Onto Sorbent Tubes. This method is consistent or equivalent to NIOSH VOC Screening methodology NISOH Method #2549. Thermal desorption tubes were obtained from Leeder Consulting, a NATA Accredited analytical laboratory located in Melbourne. The tubes were kept inside a sealed glass container with activated carbon to protect the tubes absorbing any traces of extraneous volatile organic compounds and used within two weeks of supply. Sample pumps flow rates for VOC sampling were pre-calibrated at PB offices against a dry cell calibrator which had been calibrated against a primary bubble tube calibrator, (similar to an inverted burette). At the testing location, the tube and sampling pumps (the sampling train) were set up and the flow rate of the complete sample train finely adjusted to run as close to 50 mL per minute as practicably possible. The sample flows for each sample train were noted for each location and the pumps run for approximately 2 hours each location to ensure a target volume of around 6.0 L was collected (optimal sample volume and flow rate before theoretical breakthrough time occurs). At the end of each sampling period, the sample train flow rate was measured and recorded to allow the average flow rate and sample volume to be calculated later. The samples were sealed immediately, and placed in the glass storage container placed in an esky on ice. Tubes were identified for each location against the serial numbers provided by the manufacturer. Two tubes were reserved as field blanks for quality assurance purposes. After returning from site, the samples were packaged, chain of custody form completed and sent to the laboratory overnight for analysis in accordance with US EPA Method TO-17 using thermal desorption and gas chromatography and FID. The method allows for a limit of detection close to as low as 100ng per tube, at this sample volume. 3.2.2 Screening for the presence of aldehydes and ketones Screening for aldehydes and ketones was undertaken using NIOSH Method # 2539 “Aldehydes Screening”. Solid sorbent tubes (XAD-2 hydroxy methyl piperidine on XAD-2 tubes) were shipped from the supplier (SKC) based in the United States using expedited shipping services. The tubes were kept inside their sealed packagings with the glass seals left intact until the time of sampling. Tubes were stored in the refrigerator until used within two weeks of receipt of the sorbent tubes. Sample pumps flow rates for aldehyde screening were pre-calibrated to run at approximately 50 mL per minute at PB offices against a dry cell calibrator which had been calibrated against a primary bubble tube calibrator, (similar to an inverted burette). At the testing location, the glass tube ends were opened just prior to use and the sampling pumps (the sampling train) were set up with the flow rate of the complete sampling train finely adjusted to run as close to 50mL/minute as practicable. The sample flows for each sample train were noted for each location and the pumps run for approximately 1.5 hours each location to ensure a target volume of just less than 5.0 L was collected (optimal aldehyde screen sample volume and flow rate before theoretical breakthrough time occurs). PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 8
IAQ Assessment Manly State School - Library, GLA 20 & Music Room This sample volume (5L) should allow for a limit of detection as low as 2µg of aldehyde per sample. At the end of each sampling period, the sample train flow rate was measured and recorded to allow the average flow rate and sample volume to be calculated later. The samples were sealed immediately using plastic end caps provided by the manufacturer, and placed in the sample bags placed in an esky on ice. Tubes were identified for each location against the serial numbers provided by the manufacturer. Two tubes were reserved as field blanks for quality assurance purposes. After returning from site, the samples were packaged, chain of custody form completed and sent to the laboratory overnight for analysis in accordance with NIOSH Method 2539 using gas chromatography and FID. 3.2.3 Amino ethanol compounds Screening for the presence of amino ethanol compounds was undertaken using NIOSH Method # 2007 “Amino ethanol compounds screening”. Solid sorbent tubes (hollow glass tubes containing silica gel) were shipped from the supplier (SKC) based in the United States using expedited shipping services. The tubes were kept inside their sealed packagings with the glass seals left intact until the time of sampling. Tubes were stored in the refrigerator until used within two weeks of receipt of the sorbent tubes. Sample pumps flow rates for aldehyde screening were pre-calibrated to run at approximately 100mL per minute at PB offices against a dry cell calibrator which had been calibrated against a primary bubble tube calibrator, (similar to an inverted burette). For the method to be used correctly, a flow rate of between 0.01 to 0.2 L/min is acceptable. At the testing location, the glass tube ends were opened just prior to use and the sampling pumps (the sampling train) were set up with the flow rate of the complete sampling train finely adjusted to run at approximately 100 mL/minute. The sample flows for each sample train were noted for each location and the pumps run for approximately 3.0 hours at each location to ensure a target volume between 18 L to 24 L was obtained (most practicable sample size and flow rate to minimise contaminant break through whilst obtaining a an adequate sample size to obtain a low limit of detection). At the end of each sampling period, the sample train flow rate was measured and recorded to allow the average flow rate and sample volume to be calculated later. The samples were sealed immediately using plastic end caps provided by the manufacturer, and placed in the sample bags placed in an esky on ice. Tubes were identified for each location against the serial numbers provided by the manufacturer. Two tubes were reserved as field blanks for quality assurance purposes. After returning from site, the samples were packaged, chain of custody form completed and sent to the laboratory overnight for analysis in accordance with NIOSH Method 2007 using gas chromatography and FID. The estimated limit of detection can be as low as 0.005mg per sample when the full sample size is obtained. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 9
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 3.3 Odour thresholds and use of relevant standards for airborne contaminants It should be noted that many substances have odour thresholds that fall well below the relevant occupational exposure standards. For example, toluene has a detectable odour threshold of between only 0.16-37 ppm whereas the 8 hour time weighted exposure standard workers may be exposed to for 40 hrs a week is 50ppm. Many substances can elicit odours that are detectable by the human olfactory senses but are at concentrations that are unlikely to result in health effects. Odour thresholds have been provided below in Table 3.3-1 (AIHA, 1997). 3.3-1 Odour thresholds for selected VOCs Substance Odour threshold mg/m3 Odour threshold ppm Formaldehyde 0.033--0.036 0.027-0.029 Hexane (n-hexane) 875 248 Methyl methacrylate 0.057 0.014 MEK 63-70 21-24 Napthalene 0.05-0.055 0.0095-0.0105 Styrene 43-258 10-61 Toluene 3.5-3.6 0.93-0.06 Vinyl acetate 1.4 0.40 3.4 Limitations The assessment of indoor air contaminants was undertaken with the following limitations: Observations and sampling results were indicative of the conditions present at the time sampling for each contaminant was undertaken and may not be representative of previous or future conditions. Airborne contaminant levels were tested using static samplers placed within areas and are not necessarily representative of “breathing zone samples” workers or students are exposed to. The sampling strategy intended to find the highest possible levels of airborne contaminants. In all areas where sampling occurred, the rooms were sealed without HVAC systems or natural ventilation being provided, personnel were prevented from accessing the rooms and the doors and windows were kept closed. These factors are likely to over-estimate the contaminants present. The study was limited to airborne contaminants described in the methodology. It did not address radiological materials, contaminated land, psychosocial factors or personal factors. Asbestos and particulate (dusts) were was not included in the survey. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 10
IAQ Assessment Manly State School - Library, GLA 20 & Music Room No one section or part of a section, of this report should be taken as giving an overall idea of this report. Each section must be read in conjunction with the whole of this report, including its appendices and attachments. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 11
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 4. Evaluation criteria 4.1 Overview of air quality standards Evaluation criteria for indoor air quality assessments are nebulous in nature and few authors of publications or government agencies are willing to provide tangible reference ranges for the health and or comfort of the general community (workers and non working persons). Currently the only legislated exposure levels are provided in occupational exposure standards referenced under the Workplace Health and Safety Regulation 2008. Other local guidance provided by the Department of Environment and Resource Management in Schedule 1 of the Environmental Protection (Air) Policy 2008 relate to air quality goals to be achieved over time, as they pertain to extraneous airborne emissions from facilities off-site. These goals do not relate or apply to airborne contaminants released within buildings or within a workplace but may act as a reasonable measure of what the general public are permitted to be exposed to from extraneous emissions from industry from the boundaries of a site. The National Health and Medical Research Council (NHMRC) publication titled, Interim National Indoor Air Quality Goals Recommended By The National Health And Medical Research Council, 1996 was used as a valuable reference by environmental and occupational health practitioners. Regrettably, this publication has been rescinded by the NHMRC since the 19th of March 2006, with no alternative publication to replace it leaving many gaps in locally applicable air quality benchmarks requiring other publications and studies from Australia and abroad to be used as benchmarks. In addition to the MHMRC Interim Air Quality Goals (1996), the Canadian Health publication titled, Exposure Guidelines for Residential Indoor Air has also been used in this report, as a guide to determining what formaldehyde and VOC levels should not be exceeded in areas where the general community (including sensitive individuals) may occupy on a regular basis or for extended periods. These levels would be acceptable in the home and thus should represent a stringent benchmark for a school setting. In this survey the results have also been compared and contrasted against those contaminant concentration levels found in the “typical” Australian home as reported in the CSIRO study report titled, Indoor Air Project Part 1: Main Report Indoor Air In Typical Australian Dwellings, 2010. The study is useful as it demonstrates median, minimum and maximum mean concentration levels of contaminants found in a large cross section of sampling undertaking in residential dwellings for an extended period of time. The study report lists has mean concentration levels for TVOCs and other individual substances including xylenes, benzene, formaldehyde, toluene, and formaldehyde. Typical residential concentration levels of contaminants should be a reasonable benchmark for a school environment or other area where members of the public are allowed to be present. If members of the public (i.e. parents, teachers, students) accept that these levels are present in their homes then the levels should also be acceptable within a school if they do not exceed the median concentrations. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 12
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 4.2 Occupational Exposure Standards (national exposure standards) The values published on the Worksafe Australia’s “Hazardous Substances Information System” for atmospheric contaminants in the occupational environment are provided with other indoor air quality guidelines or goals in Table 4.2-1. Substances’ exposure standards provided in the Hazardous substances Information System (HSIS) are based on updated exposure standards provided in the publication, Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment, 1995. Under Part 16 of the Workplace Health and Safety Regulation 2008, workers are not permitted to be exposed to more than the national exposure standards for any listed hazardous substances. An exposure standard represents an airborne concentration of a particular contaminant in the worker’s breathing zone, exposure to which, according to current knowledge, should not cause adverse effects nor cause undue discomfort to nearly all workers. Exposure standards may take three forms listed: Time weighted average (TWA). Short term exposure limit Peak limit. The “peak exposure limit” means the maximum or peak airborne concentration of a particular substance determined over the shortest analytically practicable period of time which does not exceed 15 minutes. Substances with a peak airborne exposure limit do not also have a time weighted average. The time weighted average exposure standard - time-weighted average (TWA)' means the average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week (up to 40 hours per week). The short term exposure limit (STEL) means a 15 minute TWA exposure which should not be exceeded at any time during a working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive exposures at the STEL. The use of occupational exposure standards although applicable to workers employed at the school are clearly not considered suitable for areas where school children may be present continuously or for prolonged periods. Occupational exposure standards are suitable for “nearly all workers”. However, there is likely to be a sub-set of the working population for whom the exposure standards may not be effective at preventing discomfort or work caused illness. Occupational exposure standards do not guarantee protection from exposed to formaldehyde in sensitive individuals or those who suffer chronic respiratory illness or asthma. Indoor air quality guidelines would be more suitable criteria for the protection of these persons. In the case of formaldehyde, which is a suspected carcinogen and known respiratory sensitiser, respiratory exposure should be kept as low as reasonably achievable. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 13
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 4.3 Airborne contaminant guidelines The relevant exposure levels for airborne contaminants are stated in Table 4.3-1. Table 4.3-1 Relevant Exposure Standards and Air Quality Guidelines Contaminant Qld DERM National Workplace CSIRO Indoor Air NHMRC Exposure Air quality Environment Exposure Project – Indoor Air Interim Guidelines for 1 objectives -0F Protection - Air Standards in Typical Dwellings Ambient Air Residential 3 for health Toxics ,mg/m Quality Goals Indoor Air and well measure (rescinded) Quality being (Canada) 3 3 3 Total VOC n/a n/a n/a Median: 150 µg/m 500 µg/m 500 µg/m (TVOC) Min-max: 56-717 3 µg/m 3 ethanolamine 280 µg/m n/a TWA8hr: 7.5 n/a n/a n/a (1 week TWA) STEL: 15 Benzene n/a 0.003 ppm, TWA8hr : 3.2 Median: 0.29 ppb , n/a n/a 3 0.93 µg/m 3 9.57 µg/m , (annual Min-max:0.09-1.35 3 average) ppb, (0.29-4.3 µg/m ) Ethyl benzene n/a n/a TWA8hr: 432 Median: 0.19 ppb, n/a n/a 3 (0.82 µg/m ) STEL: 543 Min-max: 0.06-1.7 3 ppb (0.26-7.37 µg/m ) 4-isopropyl n/a n/a TWA8hr: 125 n/a n/a n/a toluene (cumene) STEL: 375 Naphthalene n/a n/a TWA8hr: 52 n/a n/a n/a STEL: 79 1 Schedule 1 of the Environmental Protection (Air) Policy 2008, values at zero degrees Celsius. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 14
IAQ Assessment Manly State School - Library, GLA 20 & Music Room Contaminant Qld DERM National Workplace CSIRO Indoor Air NHMRC Exposure Air quality Environment Exposure Project – Indoor Air Interim Guidelines for 1 objectives - 0F Protection - Air Standards in Typical Dwellings Ambient Air Residential 3 for health Toxics ,mg/m Quality Goals Indoor Air and well measure (rescinded) Quality being (Canada) 3 Styrene 280 µg/m 1 n/a TWA8hr: 213 n/a n/a n/a week TWA STEL: 426 3 3 Toluene 4.1 mg/m 3.77 mg/m (24 TWA8hr: 377 Median: 1.5 ppb, n/a n/a 3 (24 hour hour annual (2.31 µg/m ) TWA) average) STEL: 574 Min-max: 0.73-36.5 ppb, (2.75-137.6 3 µg/m ) 3 3 Xylene 1.2 mg/m 1.1 mg/m (24 TWA8hr: 350 Median: 0.97 ppb n/a n/a 3 24 hour hour annual (4.21 µg/m ) TWA average) STEL: 655 Min-max: 0.4-8.7 ppb, 3 (1.73-37.4g/m ) 1,2,4-trimethyl n/a n/a TWA10hr: 123 n/a n/a n/a benzene (NIOSH) Dichlorodifluorom n/a n/a TWA8hr: 4950 n/a n/a n/a ethane Trichlorofluoromet n/a n/a 5620 Peak n/a n/a n/a hane limitation 3 Tetrachloroethene 0.27mg/m n/a TWA8h: 3450 n/a n/a n/a (perchloroethylene (1 year or TWA) STEL:1020 tetrachloroethylen e) 3 acetaldehyde n/a n/a TWA8hr: 36 n/a n/a 9000 µg/m not to be STEL: 91 exceeded, 5 minute measurement. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 15
IAQ Assessment Manly State School - Library, GLA 20 & Music Room Contaminant Qld DERM National Workplace CSIRO Indoor Air NHMRC Exposure Air quality Environment Exposure Project – Indoor Air Interim Guidelines for 1 objectives -0F Protection - Air Standards in Typical Dwellings Ambient Air Residential 3 for health Toxics ,mg/m Quality Goals Indoor Air and well measure (rescinded) Quality being (Canada) 3 3 3 formaldehyde 54.2 µg/m 49.2 µg/m TWA8hr: 1.2 Median: 11.7 ppb, 120 µg/m not Action level: 3 3 24 hour (14.39 µg/m ) to be exceeded 120 µg/m not TWA (0.04 ppm), 24 STEL: 2.5 to be hr TWA) Min-max: 3.6-24.8, exceeded, 5 3 (4.42-30.5 µg/m ) minute measurement. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 16
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 5. Relevant legislation The relevant legislation, codes of practice and industry standards applicable to this investigation are listed: Workplace Health and Safety Act 1995. Workplace Health and Safety Regulation 2008 Environmental protection (Air) Policy 2008. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 17
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 6. Results and discussion 6.1 Visual inspection The following observations were made on the 15 September 2010: a. The library was not occupied by any staff or students at the time sampling was undertaken. The library and computer room within the library was not accessible to any members of staff of students. Windows and doors within the areas sampled were closed during sampling without any mechanical ventilation. b. There were no obvious signs of new furniture or shelving that would give rise to formaldehyde levels in the library. Based on information provided by the Dickinson Constructions Pty Ltd the new carpet should not have contained formaldehyde or other volatile contaminants. c. The general learning area GLA-20 used by class 5H was not used by staff or students at the time of sampling with access to persons denied. The room was closed up during the sampling period without any natural or mechanical ventilation. d. The GLA-20 was observed to have a discernable, unpleasant odour similar to the uniform shop. The class room contained new carpets, new loose furnishings (desks made from laminated reconstituted timbers, plastic chairs, white-boards, fabric pin boards, cardboard pigeon holes, and student tidy bags on the backs of each chair). e. The music room was not occupied at the time sampling was conducted. The music room consisted on a single, open plan class room without chairs or desks. The room contained new carpet and a variety of musical instruments (xylophone, piano, keyboard instrument, sound system, drums, etc). At the rear of the music room towards the south, a separate partitioned office was present which contained older laminated particle board desks, a bar refrigerator on the floor, sink and windows. There was no evidence of any obvious signs of VOCs or aldehyde emission sources in this area. 6.2 A review of results by sampling location The results of airborne sampling undertaken to screen for all major peaks of volatile organic compounds, aldehydes, ketones and amino ethanol compounds are provided in Appendix A. The results are tabulated against all relevant exposure standards and indoor air quality parameters for comparison. 6.2.1 Library & Computer Room 6.2.1.1 VOC levels The results of the VOC screen within the library and computer room located in the library demonstrated that none of VOCs or TVOC concentration levels exceeded any of their respective occupational exposure standards or IAQ guidelines cited from the other literature. The TVOC concentration levels also fell well below the TVOC target levels recommended in the NHMRC’s Interim Ambient Air Quality Goals and the Canadian Health’s Exposure Guidelines for Residential Indoor Air Quality. Both the individual VOC contaminant levels and the TVOC levels also were found to be within the normal concentration level range found in typical Australian dwellings as published in the CSIRO Indoor Air Project, (2010). Toluene PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 18
IAQ Assessment Manly State School - Library, GLA 20 & Music Room was slightly higher than the median value found in residential dwellings but still far less than the upper concentration limit in homes reported by CSIRO of 36.5 g/m3. The likely source of toluene is from adhesives. 6.2.1.2 Aldehydes and Ketones The formaldehyde and other aldehyde levels (acetaldehyde and heptanal) in the library areas tested were less than the limit of detection and thus ought to have been acceptable for ensuring indoor comfort and wellbeing of occupants. 6.2.1.3 Amino ethanol compounds The screening for amino ethanol compounds (ethanolamine) in the uniform shop did not find these substances to be present at concentration levels above the limit of detection 2 (
IAQ Assessment Manly State School - Library, GLA 20 & Music Room The median (14.4 g/m3) and maximum concentration range (30.5 g/m3) of formaldehyde levels found in typical Australian dwellings published by the CSIRO from their Indoor Air Project (2010). The Air Quality objectives for “health and well being” stated in the Environmental Protection (Air) Policy 2008 (although not applicable within a workplace where emissions are present within the workplace). On this occasion acetaldehyde was not detected but heptaldehyde (heptanal) was identified at levels between 85-232 g/m3. There are no published indoor air quality guidelines or occupational exposure standards for heptanal. Additionally, the CSIRO (Indoor Air Project, 2010) report did not investigate the presence of this substance in dwellings. In the absence of recommended exposure standards for heptanal, toxicological information indicates that the product is a strong respiratory irritant and exposure to this substance should be Detection of formaldehyde in class room GLA 20 was not unexpected due to the high proportion of formaldehyde containing materials in the class room from melamine-urea- formaldehyde products used in Smart Desk table tops, mobile shelving units, MDF pin boards lining the walls, and MDF backing in white boards. The construction of the class room was undertaken using formaldehyde products compliant with E1 formaldehyde emission standards. The Customwood E1 MDF panel’s MSDS states that formaldehyde may be emitted when heated. It also claims that in a well ventilates environment, formaldehyde is unlikely to exceed the World Health Organisation standard of 0.1ppm (120g/m3) for the general environment. Emission rates are usually stated in terms of an amount of vapour emitted per square metre of materials. The larger the surface area of MDF panel placed within an unventilated room volume, then the greater the resultant concentration of formaldehyde present. Under most situations the claims in the MSDS are likely to be correct but do not apply to situations such as the testing environment in GLA 20 where the room is closed during sampling, not provided with mechanical or other ventilation during sampling, and the room contains such a relatively large surface area of MDF products together in a relatively small room volume. These factors make it likely that areas such as GLA 20 and the uniform shop (tested on 31 August 2010) will have a relatively higher formaldehyde concentrations compared with more spacious rooms (e.g. the library) where formaldehyde is likely to be emitted, but the emissions are diluted below acceptable levels by the comparatively large room volume. 6.2.2.3 Amino ethanol compounds The screening for amino ethanol compounds (ethanolamine) within the change room and storage room did not identify amino ethanol compounds to be present at levels above the limit of detection (
IAQ Assessment Manly State School - Library, GLA 20 & Music Room recommended target TVOC levels provided in the NHMRC’s Interim Ambient Air Quality Goals and the Canadian Health’s Exposure Guidelines for Residential Indoor Air Quality. Within the Music Teacher’s Office, the TVOC levels were found to be 31 g/m3, slightly higher than the levels in GLA 20. The toluene levels were also higher at 22 g/m3. However, both of these values are still consistently within typical household concentrations of between 2.75-137.6 g/m3 for toluene and 56 to 717 g/m3 for TVOCs and less than the recommended limits of the NHMRC and Canadian Health publication of 500 g/m3. In summary, the TVOC levels do not represent any significant cause for concern and without exception are consistent with the concentration levels expected in the typical Australian home and in most cases are lower than those expected in the typical home. 6.2.3.2 Aldehydes and Ketones The aldehyde and ketone screen undertaken in the Music Room in the upper storey of C Block was successful in detecting up to 192 g/m3 of formaldehyde in the general music class room area and up to 102 g/m3 within the separately enclosed, teacher’s office. The music office formaldehyde concentrations are within the acceptable limits recommended by the NHMRC and Canadian Health target values and do not warrant further discussion other than to comment that the furniture in the office was not new and unlikely to emit formaldehyde. Levels of formaldehyde in the Music Class Room were found not to exceed the eight hour, time weighted average (NES TWA 8hr) of 1.2 mg/m3 lawfully permitted under occupational health and safety legislation in Australian workplaces. However, the concentrations exceeded the following parameters: The NHMRC’s Interim Ambient Air Quality Goals which requires that no person be exposed to a brief exposure of more than 120 g/m3. An action limit of 120 g/m3 is used by Canadian Health in their Exposure Guidelines for Residential Indoor Air Quality publication. The median (14.4 g/m3) and maximum concentration range (30.5 g/m3) of formaldehyde levels found in typical Australian dwellings published by the CSIRO from their Indoor Air Project (2010). The Air Quality objectives for “health and well being” stated in the Environmental Protection (Air) Policy 2008 (although not applicable within a workplace where emissions are present within the workplace). 6.2.3.3 Amino ethanol compounds The screening for amino ethanol compounds (ethanolamine) in the uniform shop did not find these substances to be present at concentration levels above the limit of detection 3 (
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 7. Recommendations Based on the results of the survey the following recommendations are provided: The general learning area GLA-20 in B Block and music room should be subjected to off-gassing. The following methodology is provided 4: 3F The class room should be closed and heated to between 40 degrees C to no more than 50 degrees C, without ventilation, for not less than 4 hours duration. Once the target temperature has equilibrated throughout the affected areas, the rooms should be vented using mechanical extraction ventilation or if this cannot be obtained, forced ventilation should be provided with windows and doors open and ceiling fans running to try to increase the number of changes of air within the affected room. During the off-gassing heating process, personnel may be exposed to elevated levels of VOCs and aldehydes as well as heat stress. An organic vapour cartridge respirator is recommended to be worn as a general precaution when entering the rooms during heating. Whilst venting the room, the room should be heated to maintain the temperature as far as practicable within the constraints of the electricity power supply. During the process a fire watch should be provided to monitor any power overloads or fire. After heating and venting the affected area should be left to vent as long as practicable before allowing occupants to re-enter. Other general learning areas with the same fixtures and fittings as GLA 20 should be considered for remediation using the above protocols. It should be noted that at the time Manly State School purchased its new class room desks, shelving and other materials used in the construction of the general learning areas, DETA did not have a formal standing offer in place for the purchase of furniture and building materials. E1 MDF has been used throughout the new building materials, shelving, white boards, pin boards and loose class room furniture (desks). These products have collectively contributed to formaldehyde concentrations that are greater than the concentration levels recommended in the NHMRC and other indoor air quality benchmarks used in this report. The Department of Education, Training and the Arts (DETA) has a current standing offer arrangement that DETA schools are able to access. It is understood that the standing offer allows schools to purchase E0 MDF products such as desks and shelving from selected suppliers. It is also understood that this standing offer is available for schools to utilise but is not mandatory as schools are able to utilise their own initiative to obtain a better offer. DETA should consider making the purchasing of all E0 formaldehyde MDF products or non-MDF products (e.g. natural timber) mandatory as a purchasing policy in an effort to reduce the potential for exposure to formaldehyde in schools. The use of E0 MDF products do not guarantee that that formaldehyde levels will be less than the recommended levels suitable 4 At the time of writing this report, remediation of B Block, C Block and other general learning areas are understood to have undergone remediation prior to school returning from mid-semester recess. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 22
IAQ Assessment Manly State School - Library, GLA 20 & Music Room for a class room or area where school children are expected to be present. The resultant formaldehyde concentrations depend of the collective surface areas of materials emitting formaldehyde, the age of the materials, the ambient temperature in the room, the size of the room and the numbers of changes of air provided to dilute any emissions. However, the use of E0 MDF products conforming to AS/NZS 1859.2-2004 provides the most stringent benchmark available for use as a purchasing control. Based on the results of the sampling conducted at Manly State School it is evident that when large quantities of E1 MDF are used in a room together without good ventilation, that formaldehyde concentration levels can be produced that are above NHMRC Guidelines and other indoor air quality benchmarks. It is further recommended that E1 MDF not be purchased for use in new furniture, fixtures or construction materials in schools without a protocol in place to test for indoor formaldehyde air concentrations to ensure they are below 120 g/m3 prior to occupancy of personnel in that space. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 23
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 8. Summary In summary, the indoor air quality assessment included screening for the following groups of materials using sorbent tubes sent for laboratory analysis: VOCs (e.g. benzene, toluene, styrene, alcohols, and alkanes) Aldehydes and ketones (e.g. formaldehyde) Ethanolamines. The sampling was conducted in the additional areas not initially identified for air sampling for the testing undertaken 31 August 2010. These areas were identified following additional people coming forward to volunteer areas they thought might be of concern. The results of the sampling in B Block (GLA-20), and C Block, (Music Class Room) identified that formaldehyde concentrations were present in concentration levels greater than those recommended in the following guidance publications: the rescinded NHMRC publication titled, NHMRC’s Interim National Indoor Air Quality Goals Recommended by The National Health And Medical Research Council, 1996 the Canadian Health publication, Exposure Guidelines for Residential Indoor Air. The formaldehyde levels in these areas also were above the concentrations typically found in Australian dwellings as documented in the CSIRO study report titled, Indoor Air Project Part 1: Main Report Indoor Air in Typical Australian Dwellings, 2010. Formaldehyde emission sources are likely to occur from multiple sources including MDF panels used in pin boards, white boards, portable shelving units, and student desks. The levels of VOCs and amino-ethanol compounds were either within or less than acceptable levels typically found in an Australian residential dwelling. Recommendations provided include the baking out of the formaldehyde from all student class rooms or other rooms occupied by students and known to be fitted with similar furnishings, fixtures and fittings containing MDF or particle board. At the time this report has been completed, it is expected that these recommendations will have been implemented before students return from mid semester recess. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 24
IAQ Assessment Manly State School - Library, GLA 20 & Music Room 9. References American Conference of Governmental Industrial Hygienists Committee, February 2007, Industrial Ventilation: A Manual of Recommended Practice, 26th Edition Chapter 8, Ventilation Aspects of Indoor Air Quality American Industrial Hygiene Association, 1997, Odour Thresholds for Chemicals with Established Occupational Health Standards, AIHA, Fairfax, Virginia Australia/New Zealand Standard, AS/NZS 1668.1:1998, The use of ventilation and air- conditioning in buildings, Part 2: Ventilation design for indoor air containment control (excluding requirements for the health aspects of tobacco smoke exposure), Standards Australia, Sydney. Australia/New Zealand Standard, AS/NZS 4266.16-2004 Reconstituted wood-based panels-Methods of test Method 16: Formaldehyde emission- desiccators method, Standards Australia, Sydney Australia/New Zealand Standard, AS/NZS 1859.2:2004 Reconstituted wood-based panels-Specifications Part 2: Dry Processed fibreboard, Standards Australia, Sydney. Australia/New Zealand Standard 1668.2-2002, The use of ventilation and air- conditioning in buildings Part 2: Ventilation design for indoor air contaminant control (excluding requirements for the health aspects of tobacco smoke), Standards Australia, Sydney. CSIRO, 2010, Indoor Air Project Part 1: Main Report, Indoor Air in Typical Australian Dwellings- A report to the Air Quality Section, Environment Standards Branch, Department of the Environment, Water, Heritage, and the Arts. Commonwealth of Australia, Canberra. Health Canada, 1995, Exposure Guidelines for Residential Indoor Air Quality – A Report of the Federal-Provincial Advisory Committee on Environmental and Occupational Health, Minister of Supply and Services Canada. Indoor Air Quality in Office Buildings: A Technical Guide, A report of the Federal- Provincial Advisory Committee on Environmental and Occupational Health, Public Works and Government Services Canada, 1995 Jon H Ruth, 1986, Odour thresholds and irritation levels of several chemical substances- A review, Volume 47, American Industrial Hygiene Association Journal. NHMRC, 1996, Interim National Indoor Air Quality Goals Recommended by the National Health and Medical Research Council. National Occupational Health and Safety Commission, 1995, Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment' [NOHSC:1003(1995)], in Exposure Standards for Atmospheric Contaminants in the Occupational Environment: Guidance Note and National Exposure Standards, Australian Government Publishing Service, Canberra. United States Environmental Protection Agency, 2006, Fact Sheet – Final Revisions to the National Ambient Air Quality Standards for Particulate Pollution (Particulate Matter), http://www.epa.gov/ttn/naaqs/standards/pm/s_pm_index.html U U PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 25
IAQ Assessment Manly State School - Library, GLA 20 & Music Room World Health Organisation (WHO) 2005, WHO Air quality guidelines for particulate matter, ozone, nitrogen dioxide and sulphur dioxide. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page 26
Appendix A Results tables – Chemical contaminants Appendix A Results tables – Chemical contaminants PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page A.1
Appendix A Results tables – Chemical contaminants Table A-6.2-1 Airborne gas and vapour contaminants TEST Tube Serial Building Location Substances at Airborne Method No. detectable Sample Qld DERM National Workplace CSIRO Indoor NHMRC Exposure levels in screen Concentration Air quality Environment Exposure Air Project – Interim Guidelines 5 objectives - 4F Protection - Standards Indoor Air in Ambient Air for for health Air Toxics (8hour TWA, Typical Quality Residential 3 and well measure mg/m ) Dwellings mean Goals Indoor Air 3 being values, µg/m ) (rescinded) Quality (Canada) VOC Mi 155369 Library Centre area dichlorodifluorom 7.5 µg/m 3 n/a n/a 4950 n/a n/a n/a SCREEN NIOSH ethane #2549 3 trichlorofluoromet 1.5 µg/m n/a n/a n/a n/a n/a n/a hane 3 toluene 2.9 µg/m 3 3 4.1 mg/m (24 3.77 mg/m 150 Median:2.31 n/a n/a hour TWA) (24 hour annual Min-max: 2.75- average) 137.6 3 Xylenes 1.0 µg/m 3 3 1.2 mg/m 24 1.1 mg/m (24 350 Median: 4.21 n/a n/a 3 hour TWA hour annual µg/m average) Min-max: (1.73- 3 37.4g/m ) 3 TVOC (major 12.9 µg/m n/a n/a n/a 3 3 Median: 150 500 µg/m 500 µg/m peaks) 5 Schedule 1 of the Environmental Protection (Air) Policy 2008, values at zero degrees Celsius. PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page A.1
Appendix A Results tables – Chemical contaminants TEST Tube Serial Building Location Substances at Airborne Method No. detectable Sample Qld DERM National Workplace CSIRO Indoor NHMRC Exposure levels in screen Concentration Air quality Environment Exposure Air Project – Interim Guidelines 5 objectives - 4F Protection - Standards Indoor Air in Ambient Air for for health Air Toxics (8hour TWA, Typical Quality Residential 3 and well measure mg/m ) Dwellings mean Goals Indoor Air 3 being values, µg/m ) (rescinded) Quality (Canada) Min-max: 56-717 VOC Mi Library Computer lab. dichlorodifluorom 7.7 µg/m 3 n/a n/a 4950 n/a n/a n/a SCREEN 155258 NIOSH ethane #2549 3 toluene 3.6 µg/m 3 4.1 mg/m (24 n/a TWA8hr: 350 Median: 2.31 n/a n/a hour TWA) Min-max: 2.75- 137.6 3 Trichlorofluorome 1.6 µg/m n/a n/a 5620 Peak n/a n/a n/a thane limitation 3 Xylenes 1.3 µg/m 3 3 1.2 mg/m 24 1.1 mg/m (24 350 Median: 4.21 n/a n/a 3 hour TWA hour annual µg/m average) Min-max: (1.73- 3 37.4g/m ) 3 TVOC (major 14.2 µg/m n/a n/a 3 3 Median: 150 500 µg/m 500 µg/m peaks) Min-max: 56-717 VOC Mi Library Veranda dichlorodifluorom 4.0 µg/m 3 n/a n/a 4950 n/a n/a n/a SCREEN 155276 (outside) NIOSH ethane #2549 PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page A.2
Appendix A Results tables – Chemical contaminants TEST Tube Serial Building Location Substances at Airborne Method No. detectable Sample Qld DERM National Workplace CSIRO Indoor NHMRC Exposure levels in screen Concentration Air quality Environment Exposure Air Project – Interim Guidelines 5 objectives - 4F Protection - Standards Indoor Air in Ambient Air for for health Air Toxics (8hour TWA, Typical Quality Residential 3 and well measure mg/m ) Dwellings mean Goals Indoor Air 3 being values, µg/m ) (rescinded) Quality (Canada) 3 Trichlorofluorome 0.9 µg/m n/a n/a 5620 Peak n/a n/a n/a thane limitation 3 TVOC (major 4.9 µg/m n/a n/a n/a 3 3 Median: 150 500 µg/m 500 µg/m peaks) Min-max: 56-717 VOC Mi 155392 B Block GLA-20 dichlorodifluorom 4.9 µg/m 3 n/a n/a 4950 n/a n/a n/a SCREEN northern NIOSH aspect ethane #2549 3 toluene 1.5 µg/m 3 4.1 mg/m (24 n/a TWA8hr: 350 Median: 2.31 n/a n/a hour TWA) Min-max: 2.75- 137.6 3 Trichlorofluorome 1.0 µg/m n/a n/a 5620 Peak n/a n/a n/a thane limitation 3 Xylenes 1.3 µg/m 3 3 1.2 mg/m 24 1.1 mg/m (24 350 Median: 4.21 n/a n/a 3 hour TWA hour annual µg/m average) Min-max: (1.73- 3 37.4g/m ) 3 Total VOC 8.7 µg/m n/a n/a n/a 3 3 Median: 150 500 µg/m 500 µg/m PARSONS BRINCKERHOFF 2160857A-RPT005-A-aw Page A.3
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