CVC Thermoset Specialties
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CVC Thermoset Specialties We Offer Hypro™ Reactive Liquid Polymers Products that deliver enhanced performance Addition of our innovative Hypro™ Reactive Liquid Polymers (RLP) Application and technology expertise to your thermoset resin formulation will significantly enhance North American ISO-certified facilities performance such as fracture toughness, low temperature Global service with regional distribution partners mechanical properties, impact/crack/chip resistance, flexibility and adhesion to difficult to adhere-to substrates. Carboxy, Amine, Epoxy, Our Legacy Methacrylate(Vinyl), Glycidyl Ester and Hydroxy end-functionality allows for crosslinking in a variety of systems. Ideally suited for CVC Thermoset Specialties’ RLP Products are a unique, proprietary Epoxy, Vinyl Ester, UPE Urethane and Acrylic Resin Systems. Newer technology originally developed by BFGoodrich, which enhance low viscosity epoxy functional grades can be used for glass and performance in a wide array of technically challenging end-uses carbon fiber reinforced composites. around the world. The product family had been sold for many decades under the Hycar® tradename by predecessor corporations HYPOX™ Elastomer Modified Epoxy Resins – BFGoodrich, Noveon and Lubrizol. Following the formation of Emerald Performance Materials in 2006, the products were rebranded Elastomer modification of epoxy resins is a valuable way to further as Hypro™ Reactive Liquid Polymers. enhance performance features such as: fracture toughness, peel strength, flexibility, low temperature performance, durability and Prior to its acquisition by Emerald Performance Materials in 2008, CVC adhesion to non-polar surfaces versus unmodified products. Specialty Chemicals had been creating and manufacturing specialty Technologies include Dimer Acid and CTBN Adducts, and Urethane epoxy resins since 1982. Over the years, the company expanded its Modified Epoxy Resins. product offerings to coatings and adhesive formulators with the acquisition of the specialty epoxy resin line of CL Industries ERISYS™ Epoxy Functional Monomers and Modifiers (Georgetown, IL) and substituted urea accelerators from Omicron Monomers are used in epoxy formulations to reduce viscosity and Chemical. Manufacturing and R&D capabilities were enhanced by improve handling, processing, and application properties of formulations. the 1995 purchase and subsequent expansions of the Akzo Chemical Monomers and modifiers also enhance features, such as flexibility and plant in Maple Shade, NJ. toughness, and maintain chemical resistance and UV stability. Chemistries included Aromatic & Aliphatic Glycidyl Ethers, Glycidyl Amine and CVC Thermoset Specialty Product Lines Glycidyl Esters. Specialty Epoxy Resins Reactive Liquid Polymers OMICURE™ Catalysts and Accelerators Elastomer-modified Epoxy Resins Accelerating the cure speed and/or reducing the cure temperature Monomers and Modifiers are important to optimize productivity, energy use, and ultimate physical Catalysts and Accelerators properties. We offer Dicyandiamide and Boron-Based catalysts for Latent, one-component Heat Cured Epoxy Systems. Substituted Urea EPALLOY™ Specialty Epoxy Resins catalysts help to accelerate the cure speed and reduce cure temperatures Improved chemical resistance, thermal performance, modulus, of Dicyandiamide cured formulations and help to optimize productivity, cure speed, and UV stability over other standard resins for coatings, energy use, and ultimate physical properties. composite, and adhesive applications. Technologies include Epoxidized Phenol Novolacs, Resorcinol Modified Novolacs, Emerald Corporation Bis A Modified and Cycloaliphatic Epoxy Resins. CVC Thermoset Specialties is a division of Emerald Performance Materials (EPM). EPM produces a broad portfolio of additives and polymers used in diverse consumer and industrial products around the world. Thermoset Its products play a variety of roles in the products that are consumed and used every day enabling them to last longer, look, smell, taste or Specialties perform better. For more information, visit www.emeraldmaterials.com. An Emerald Performance Materials Company
Polymer Electrical / Coatings Adhesives & Sealants Composites Modification Electronic Wind Energy – Infusion, Hand Layup, Tooling and Adhesives Injection Molded Structural and Pumpable Pastes Topcoat – Automotive Refinish and UV Stable Civil Engineering – Floor Joints, Anchor Bolt Cross-linkers – Overprint Varnish and Other Filament Winding – Pipes/Valves/Tanks Aerospace and Recreational Prepregs Primers – Automotive and Aerospace Resin Infusion – Industrial and Wind Flooring and Concrete Coatings Tooling and Stereolithography Mastics and Sound Deadening Insulating Varnish – Dip & VPI Pressure Sensitive Adhesives Industrial and Maintenance Polyurethane Modification PVC Plastisol Modification Syntatic Foam Insulation SMC & BMC Modification Potting/Encapsulation Printed Circuit Boards Urethane Adhesives Window Sealants Powder Coatings Film Adhesives Vinyl Ester Pultrusion Product Line Hypro™ CT Series RLP Hypro™ AT Series RLP Reactive Hypro™ VT Series RLP Liquid Polymers Hypro™ ET Series RLP Hypro™ LV Series RLP Hypro™ HT Series RLP EPALLOY™ 8000 Series – Unmodified Phenol Novolac Resins Specialty ERISYS™ RN Series – Resorcinol Modified Novolacs Epoxy EPALLOY™ 7100 Series – Bis A Modified Novolacs Resins Resins & Blends EPALLOY™ 5000 Series – Hydrogenated Bis A Resins HyPox™ D-Series Dimer Acid Modified Epoxy Resins Elastomer Modified HyPox™ R-Series CT Modified Epoxy Resins Resins HyPox™ U-Series Urethane Modified Epoxy Resins ERISYS™ GE 5,6,7 and 8 Series – Aliphatic Glycidyl Ethers ERISYS™ GE 10 Series – Aromatic Monoglycidyl Ethers ERISYS™ GE 20 Series – Aliphatic Diglycidyl Ethers Monomers and ERISYS™ GE 30 Series – Aliphatic Triglycidyl Ethers Modifiers ERISYS™ GE 60 – Sorbitol Polyglycidyl Ether ERISYS™ GS Series – Glycidyl Esters ERISYS™ GA Series – Glycidyl Amines Omicure™ U Series – Substituted Urea Accelerators Catalysts and Omicure™ DDA Series – Dicyandiamide Accelerators Accelerators Omicure™ B Series – Boron-based Catalysts For more information on these products contact: CVC Thermoset Specialties Corporate Headquarters 844 N. Lenola Road Emerald Performance Materials, LLC Moorestown, NJ 08057 2020 Front Street 800.296.0040 (CVC) Cuyahoga Falls, OH 44221 856.533.3000 (CVC) 330.916.6700 856.533.3003 (Fax - CVC) 330.916.6737 (Fax) 888.889.9150 (RLP) 330.374.2766 (Fax - RLP) www.emeraldmaterials.com www.cvc.emeraldmaterials.com Thermoset Specialties An Emerald Performance Materials Company
S U P P L Y I N G S P E C I A L T Y T H E R M O S E T S W O R L D W I D E Capabilities & Specialty Epoxy Resins Product Selection Guide Epoxy Functional Monomers and Modifiers Reactive Liquid Polymers Elastomer Modified Epoxy Resins Catalysts and Accelerators
Specialty Thermosets Table of Contents When your application requires high performance, turn to CVC Thermoset Specialties for resins, modifiers and additives. Company Overview Automobile and aircraft frames, corrosion resistant pipes and valves, graphite golf club and Technology.................................. 2-4 shafts and tennis racquet frames, electronic laminates, jet skis and marine hulls are just a few of the applications that benefit from our products. The beneficial characteristics CVC Thermoset Specialty of our materials in modified thermoset formulations have led to a growing use of Product Lines............................................5 adhesives to replace rivets, composites to cost effectively replace heavier steel and more durable, longer-lasting protective coatings. Specialty Epoxy Resins................... 6-9 CVC Thermoset Specialties – A Company with a Legacy of Value, Product Leadership, Innovation, Service and Operational Excellence for the Benefit Monomers & Modifiers.............10-12 of our Customers. Reactive Liquid Polymers........13-14 Our Legacy CVC Thermoset Specialties’ Reactive Liquid Polymer (RLP) products, a p roprietary Elastomer-Modified technology originally developed by BFGoodrich, enhance p erformance in a wide array of technically sophisticated end-uses around the world. The product family had been Epoxy Resins....................................15-16 sold for many decades under the Hycar® trade name by predecessor corporations – BFGoodrich, Noveon and Lubrizol. Following the formation of Emerald Performance Catalysts & Accelerators...........17-18 Materials in 2006, the p roducts were rebranded as Hypro™ Reactive Liquid Polymers. Prior to becoming an EPM company in 2007, CVC Specialty Chemicals had been creating Glossary...................................................... 19 and manufacturing specialty epoxy resins since 1982. Over the years, the company expanded its product offerings to coatings and adhesive formulators with the acquisition of the specialty epoxy resin line of CL Industries (Georgetown, IL) and Global Distribution..........Back Cover substituted urea accelerators from Omicron Chemical. Manufacturing and R&D capabilities were supplemented by the 1995 purchase and subsequent expansions of the Akzo Chemical plant in Maple Shade, NJ. From our automated, state-of-the-art, ISO-9001 certified operations in Maple Shade, NJ and Akron OH, we deliver proven high performance products to the most demanding applications world-wide. 2
Together – Unique Chemistry Delivering Performance Thermoset materials as epoxies represent a versatile chemistry useful in developing high performance maintenance/marine coatings, adhesives, encapsulants, c omposites, etc. CVC Thermoset Specialties p rovides suitable products to the epoxy technologist enabling the formulation of such m aterials. EPALLOY™ specialty epoxy technologies deliver improved performance over standard resins and include: Epoxidized Phenol Novolacs, Resorcinol Modified Novolacs, Bis A Modified and Cycloaliphatic Epoxy Resins. HyPox™ elastomer modified epoxy and Hypro™ reactive liquid polymers are effectively used to enhance toughness and/or flexibility of epoxy systems. Hypro reactive liquid polymers are butadiene homopolymers and butadiene-acrylonitrile copolymers having carboxyl (CT), amine (AT) and m ethacrylate (VT) functionalities to accommodate several chemistries. HyPox resins are modified with Hypro reactive liquid polymers, polyurethanes and dimer acid to achieve various degrees of viscosity, adhesion, flexibility and toughness in formulated epoxy systems. In addition to the reactive groups in both terminal positions of the polymer chain, select grades also have pendent reactivity as well. The microstructure and formation of rubbery domains in the thermoset resin matrix is key to delivering the significantly enhanced toughening and flexibility required in many demanding end-uses. Reactive diluents are monomers used in epoxy formulations for viscosity reduction and handling/processing purposes. ERISYS™ monomers and m odifiers are used in thermoset formulations to reduce viscosity and improve handling, processing, and application properties of formulations. They also enhance features, such as flexibility and toughness, and maintain chemical resistance and UV stability. ERISYS m odifiers and monomers are offered in a broad range of products from mono-epoxy functional to multi-epoxy functional materials. Chemistries include Aromatic & Aliphatic Glycidyl Ethers, Glycidyl Amines and Glycidyl Esters. Accelerating cure speed and/or reducing cure temperature are important to optimize productivity, energy use, and ultimate mechanical properties. We offer OMICURE™ Dicyandiamide and boron-based catalysts for latent, one-component heat cured epoxy systems. Substituted urea catalysts help to accelerate the cure speed and reduce cure temperatures of Dicyandiamide cured formulations and help to optimize productivity, energy use, and u ltimate physical properties. 3
Delivering Innovative Solutions. A company that delivers innovative solutions CVC’s specialty raw materials are used by formulators everywhere as critical building blocks for applications in coatings, adhesives and composites, civil engineering and electronics. With strong technical support and a diverse experience base, CVC can bring innovative products and technology to solve even the most demanding application. Whether you need to develop a 100% solids coating to eliminate solvents and meet new air emissions standards, or a high-build lining to withstand 98% sulfuric acid, CVC has proven products that will work first time, every time. From repair of architectural structures to storage-stable, one-component automotive assembly adhesives and reinforcing systems, CVC products meet your most demanding needs. Emerald Performance Materials EPM produces a broad portfolio of additives and polymers used in diverse consumer and industrial products around the world. Its products play a variety of roles in the products that are consumed and used every day enabling them to last longer, look, smell, taste or perform better. For more information, visit www.emeraldmaterials.com 4
CVC Thermoset Specialty Coatings Adhesives & Sealants Composites Polymer Electrical / Modification Electronic Product Lines Wind Energy – Infusion, Hand Layup, Tooling and Adhesives Injection Molded Structural and Pumpable Pastes Topcoat – Automotive Refinish and UV Stable Civil Engineering – Floor Joints, Anchor Bolt Cross-linkers – Overprint Varnish and Other Filament Winding – Pipes/Valves/Tanks Aerospace and Recreational Prepregs Primers – Automotive and Aerospace Resin Infusion – Industrial and Wind Flooring and Concrete Coatings Tooling and Stereolithography Mastics and Sound Deadening Insulating Varnish – Dip & VPI Pressure Sensitive Adhesives Industrial and Maintenance PVC Plastisol Modification Syntatic Foam Insulation SMC & BMC Modification Potting/Encapsulation Printed Circuit Boards Powder Coatings Film Adhesives Vinyl Ester Pultrusion Product Line Hypro™ CT Series RLP Hypro™ AT Series RLP Reactive Liquid Hypro™ VT Series RLP Polymers Hypro™ ET Series RLP Hypro™ LV Series RLP EPALLOY™ 8000 Series – Unmodified Phenol Novolac Resins Specialty ERISYS™ RN Series – Resorcinol Modified Novolacs Epoxy EPALLOY™ 7100 Series – Bis A Modified Novolacs Resins Resins & Blends EPALLOY™ 5000 Series – Hydrogenated Bis A Resins HyPox™ D-Series Dimer Acid Modified Epoxy Resins Elastomer Modified HyPox™ R-Series CT Modified Epoxy Resins Resins HyPox™ U-Series Urethane Modified Epoxy Resins ERISYS™ GE 5,6,7 and 8 Series – Aliphatic Glycidyl Ethers ERISYS™ GE 10 Series – Aromatic Monoglycidyl Ethers ERISYS™ GE 20 Series – Aliphatic Diglycidyl Ethers Monomers and ERISYS™ GE 30 Series – Aliphatic Triglycidyl Ethers Modifiers ERISYS™ GE 60 – Sorbitol Polyglycidyl Ether ERISYS™ GS Series – Glycidyl Esters ERISYS™ GA Series – Glycidyl Amines Omicure™ U Series – Substituted Urea Accelerators Catalysts and Omicure™ DDA Series – Dicyandiamide Accelerators Accelerators Omicure™ B Series – Boron-based Catalysts 5
EPALLOY™ Specialty Epoxy Resins Improved chemical resistance, thermal performance, modulus, cure speed and UV stability are just a few of the performance advantages with EPALLOY™ Specialty Epoxy Resins and blends over other standard resins. These p roducts bring the critical difference to high performance coatings, composites and adhesives applications. Technologies and product lines include: Unmodified Phenol Novolac Epoxy Resins (EPALLOY™ 8000 Series) Resorcinol and Resorcinol Modified Novolac Epoxy Resins (ERISYS™ RDGE & RN Series) Bis A Modified Novolac Epoxy Resins (EPALLOY™ 7100 Series) Cycloaliphatic Epoxy Resins (EPALLOY™ 5000 Series) Unmodified Phenol Novolac Epoxy Resins Average Gardner Viscosity at EEW, HCC, max Product Name Epoxy Color, Description / Use 25°C, cps g/eq % Functionality max Lowest viscosity Bis F resin. Near monomeric product for EPALLOY 8220 2.05 1,800 - 2,800 164 - 176 0.10 2 Epoxy Resin Bisphenol F blends to prevent crystallization in Bis A resins. Standard low viscosity non-crystallizing resin for excellent EPALLOY 8230 2.15 3,500 - 4,700 164 - 176 0.10 3 100% solids coatings and composite applications. Resistant to 98% sulphuric acid and strong polar solvents. Lowest viscosity unmodified epoxy novolac available. Lower in viscosity than standard Bis A resin. EPALLOY 8240 2.35 6,000 - 7,100 164 - 176 0.10 3 EPALLOY 8240 is preferred for secondary containment tank linings and industrial flooring. Mid-range functionality epoxy novolac with viscosity only Epoxy Phenol Novolac Resin slightly higher than standard Bis A resin. For high temper- EPALLOY 8250 2.60 18,000 - 28,000 165 - 178 0.10 3 ature, highly corrosive applications. Preferred replacement for novolac based vinyl esters. Mid-range functionality for improved Tg and EPALLOY 8280 2.8 1,100-1,700(1) 172 - 179 0.15 2 corrosion resistance. Standard epoxy novolac for highest chemical resistance EPALLOY 8330 3.60 20,000 - 30,000(1) 171 - 183 0.10 3 and Tg. EPALLOY 8350 3.60 30,000 - 50,000 (1) 175 - 184 0.10 3 Higher viscosity equivalent to 8330. EPALLOY 8370 3.90 15,000 - 25,000(2) 205 - 212 0.10 3 Highest functionality epoxy phenol novolac resin. High functionality, low melt viscosity resin for high EPALLOY 9000 3.0 5,500-6,500(2) 160 - 180 0.4 2 temperature applications and Tg modification of other epoxy resins. (1) @ 52°C (2) @ 72°C Low HCC Bis F and novolac products are available for some materials above as made to order products. 6
EPALLOY™ Specialty Epoxy Resins (cont.) Resorcinol Epoxy Resins Average Gardner Viscosity at EEW, HCC, max Product Name Epoxy Color, Description / Use 25°C, cps g/eq % Functionality max Very low viscosity, high reactivity epoxy resin. Modifying resin Epoxy Resin ERISYS RDGE 2.0 300 - 500 120 - 135 0.10 2 Resorcinol for novolacs in corrosion resistant coatings and composites. Highest purity, lowest viscosity epoxidized resorcinol resin. ERISYS RDGE/H 2.0 200 - 325 115 - 122 0.10 2 Best stability in one component systems. Resorcinol Modified Phenol Novolac Epoxy Resins Average Gardner Viscosity at EEW, HCC, max Product Name Epoxy Color, Description / Use 25°C, cps g/eq % Functionality max Non-crystallizing lowest viscosity resorcinol/ phenol Resorcinol Epoxy Resin ERISYS RF50 2.0 700 - 1,400 140 - 155 0.15 2 novolac epoxy resin. Novolac Modified Non-crystallizing medium viscosity resorcinol/phenol novolac ERISYS RN25 2.4 5,000 - 6,500 152 - 165 0.10 5 epoxy resin. Highest functionality resorcinol modified phenol novolac epoxy ERISYS RN3650 2.8 7,000 - 9,000 141 - 156 0.10 3 resin. Maximum chemical resistance and Tg. Bisphenol A Modified Phenol Novolac Epoxy Resins Average Gardner Viscosity at EEW, HCC, max Product Name Epoxy Color, Description / Use 25°C, cps g/eq % Functionality max Low viscosity non-crystallizing novolac modified Bis A Epoxy Bisphenol F Modified Bisphenol Epoxy Novolac A Epoxy Resin EPALLOY 7138 2.0 5,500 - 7,500 175 - 185 0.10 1 Resin. Excellent replacement for high purity Bis A resins in filament winding applications. EPALLOY 7170 2.05 7,000 - 10,000 177 - 187 0.10 2 Non-crystallizing Bis A/F resin. 30% epoxidized Bis F content. Epoxy Resin Modified Non-crystallizing Bis A modified Bis F epoxy resin. Highest Bis EPALLOY 9237-70 2.10 5,000 - 7,000 170 - 181 0.10 4 F content and highest Tg in this class. 7
EPALLOY™ Specialty Epoxy Resins (cont.) Bisphenol A Epoxy Resin & Blends Gardner Viscosity at EEW, HCC, max Product Name Color, Description / Use 25°C, cps g/eq % max UNMODIFIED Epalloy 7190 11,000 - 15,000 182 - 192 0.1 2 Industry standard Liquid Epoxy Resin (LER) Epoxy Resin Bisphenol A Undiluted Undiluted high molecular weight semi-solid Bisphenol A epoxy resin Epalloy 7192 O - V (1) 230 - 280 0.1 3 well suited for tough, durable formulations with improved adhesion. MODIFIED Epoxy Resin Bisphenol A Modified Epoxy of BPA derivatives to provide for faster cure for all Epalloy 7200 2,000 - 4,000(2) 195 - 215 0.5 2 temperatures. Eliminates blushing in slower curing epoxies. HYDROGENATED UV Resistant, lower viscosity alternative to Standard Bis A resin. Epalloy 5000 1,300 - 2,500 210 - 230 0.2 100(3) Applications include weatherable coatings as replacement to urethane Hydrogenated Epoxy Resin Bisphenol A coatings. Excellent adhesion to metal. Faster cure version of Epalloy 5000 through increased epoxy Epalloy 5001 2,000 - 4,500 190 - 210 0.3 3 functionality. (Functionality = 2.4) Ideal for weatherable coatings. Cycloaliphatic Glycidyl Ester EPALLOY 5200 700 - 900 160 - 180 0.4 100(3) Electrical insulation. DILUTED Epalloy 7190 A83 500 - 700 185 - 198 0.1 2 LER diluted with 17% Erisys GE-6 Epoxy Resin Bisphenol A Epalloy 7190 G76 500 - 800 179 - 193 0.1 2 LER diluted with 24% Erisys GE-10 Diluted Epalloy 7190 J82 500 - 700 197 - 207 0.1 2 LER diluted with 18% Erisys GE-8 Epalloy 7190 N75 500 - 800 163 - 175 0.1 2 LER diluted with 25% Erisys GE-20 Other modifiers and/or resin blends available on special order. (1) Gardner-Holdt Viscosity - 70% in Butyl Carbitol (2) at 52°C (3) APHA Color 8
EPALLOY™ Specialty Epoxy Resins (cont.) Resin Solutions EEW Gardner Viscosity at HCC, max Product Name NV% on Solids, Color, Description / Use 25°C, cps % g/eq max EPALLOY 7200 SOLUTIONS Epoxy Resin Solutions Modified Bisphenol A Modifying resin for high solids primers with fast EPALLOY 7200MIBK90 89 - 91 3,000 - 8,000 195 - 215 0.5 2 tack free time. Modifying resin for high solids primers with fast EPALLOY 7200X90 89 - 91 3,500 - 7,500 195 - 215 0.5 2 tack free time. EPALLOY 8330 SOLUTIONS Solutions of high functionality epoxy novolacs in solvents for film coatings. EPALLOY 8330 A85 84 - 86 500 - 1,200 171 - 183 0.10 3 A85 – 85% in Acetone Epoxy Phenol Solutions Novolac EPALLOY 8330 MAK80 79 - 81 800 - 1,300 171 - 183 0.10 3 MAK 80 – 80% in Methyl n-Amyl Ketone EPALLOY 8330 MEK85 84 - 86 800 - 1,400 171 - 183 0.10 3 MEK 85 – 85% in Methyl Ethyl Ketone EPALLOY 8350 SOLUTIONS Epoxidized Phenol Novolac Solutions EPALLOY 8350 X80 79 - 81 1,200 - 3,000 175 - 184 0.1 3 80% solids in Xylene EPALLOY 8370 SOLUTIONS Epoxidized Phenol Novolac Solutions EPALLOY 8370 A85 84 - 86 5,000 - 7,000 205 - 212 — 3 85% solids in Acetone Other resin solutions are available upon request on a made-to-order basis. 9
ERISYS™ Epoxy Functional Monomers & Modifiers ERISYS™ GE Series glycidyl ether monomers and modifiers are low ERISYS™ GE 5, 6, 7 and 8 Series - Aliphatic Monoglycidyl Ethers molecular weight epoxy functional products based on alcohols, ERISYS™ GE 10 Series - Aromatic Monoglycidyl Ethers glycols and phenols. The product line covers a broad range of TSCA ERISYS™ GE 20 Series - Aliphatic Diglycidyl Ethers approved monomers from mono-epoxy functional to multi-epoxy ERISYS™ GE 30 Series - Aliphatic Triglycidyl Ethers functional materials. Classified at right. ERISYS™ GS Series - Glycidyl Esters ERISYS™ GA Series - Glycidyl Amines Mono-Epoxy Functional- Glycidyl Ethers Viscosity Specific APHA Flash EEW, HCC, Product Name at 25°C, Gravity Color, Point Description / Use g/eq max % cps at 25°C max °F ERISYS GE-4D 2 max 130-135 0.90 - 0.92 0.20 30 >114 Distilled t-Butyl Glycidyl Ether. n-Butyl Glycidyl Ether. Most efficient epoxy ERISYS GE-5 2 max 145-155 0.91 - 0.92 0.10 100 >129 functional diluent available. Distilled n-Butyl Glycidyl Ether. ERISYS GE-5D 2 max 130-135 0.91 - 0.92 0.10 50 >129 Distilled grade of Erisys GE-5. Aliphatic 2-Ethylhexyl Glycidyl Ether. Excellent replacement ERISYS GE-6 1-4 205-235 0.90 - 0.93 0.10 100 197 for BGE as a low viscosity reactive diluent. C8-C10 Aliphatic Glycidyl Ether. Natural alcohol based. Equivalent to Epoxide 7TM. Used for high ERISYS GE-7 1-6 220-235 0.89 - 0.91 0.05 100 >200 solids coatings, tooling and civil engineering applications. C12-C14 Aliphatic Glycidyl Ether. Natural alcohol ERISYS GE-8 5 - 10 275-300 0.88 - 0.90 0.05 100 >200 based. Equivalent to Epoxide 8TM. Used in flooring, aggregate bonding and adhesives. O-Cresyl Glycidyl Ether. Viscosity modifier for ERISYS GE-10 5 - 10 170-195 1.07 - 1.09 0.10 1(1) >250 construction, flooring and casting. Excellent moisture tolerance. P-tertiary Butyl Phenyl Glycidyl Ether. Modifier for Bisphenol A resins to eliminate crystallization. ERISYS GE-11 20 - 30 215-240 1.01 - 1.03 0.10 1(1) >250 Good electrical properties. Easier to handle vs. Aromatic GE-10 or GE-13. Nonyl Phenyl Glycidyl Ether. Excellent ERISYS GE-12 100 - 140 300-325 0.97 - 1.00 0.15 2(1) 482 compatibilizer for aliphatic curing agents. Reduced induction time with non-reactive modifier. Phenyl Glycidyl Ether. Lowest viscosity aromatic ERISYS GE-13 4-7 150-165 1.10 - 1.13 0.10 2(1) 237 modifier. Excellent for electrical applications and for preparing resin/curing agent adducts. (1) Gardner Color 10
ERISYS™ Epoxy Functional Monomers & Modifiers (cont.) Multi-Epoxy Functional- Glycidyl Ethers Viscosity Specific APHA Flash EEW, HCC, Product Name at 25°C, Gravity Color, Point Description / Use g/eq max % cps at 25°C max °F Neopentyl Glycol Diglycidyl Ether. Aliphatic ERISYS GE-20 10 - 18 125 - 137 1.05 - 1.07 0.10 100 >230 difunctional modifier for filament winding, coatings and electrical applications. 1,4 Butanediol Diglycidyl Ether. Aliphatic ERISYS GE-21 10 - 18 120 - 130 1.09 - 1.11 0.10 100 >230 difunctional modifier for improved flexibility over GE-20 at comparable viscosity. Cyclohexanedimethanol Diglycidyl Ether. Cycloaliphatic difunctional modifier with ERISYS GE-22 45 - 75 145 - 165 1.07 - 1.09 0.10 100 >230 outstanding weatherability. Excellent for machinery grouts and adhesives. Aliphatic Diglycidyl Ether Modifiers Dipropylene Glycol DGE. Standard grade for higher tensile elongation and flexibility. GE23LV ERISYS GE-23 30 - 60 175 - 205 1.13 - 1.15 0.10 100 >300 is a lower viscosity and lower chloride version of GE-23. Polypropylene Glycol DGE. Diepoxide of an aliphatic polyglycol used as a diluent and/or ERISYS GE-24 60 - 70 310 - 330 1.05 - 1.07 0.10 60 >300 flexibilizer in high viscosity, brittle epoxy formulations. 1,6 Hexanediol Diglycidyl Ether. ERISYS GE-25 15 - 23 143 - 156 1.06 - 1.08 0.05 100 300 Alphatic difunctional epoxy reactive diluent. Dibromo Neopentyl Glycol Diglycidyl Ether. 275 - High bromine containing, low viscosity, ERISYS GE-29 250 - 300 1.46 - 1.51 0.50 5(1) >230 500 difunctional epoxy for flame retardant adhesives and encapsulants. Ethylene Glycol Digylcidyl Ether. Used as a ERISYS EGDGE 13 - 30 116 - 132 1.14 - 1.16 — 100 >266 crosslinker for acid functional acrylic polymers. (1) Gardner Color 11
ERISYS™ Epoxy Functional Monomers & Modifiers (cont.) Multi-Epoxy Functional- Glycidyl Ethers Viscosity Specific APHA Flash EEW, HCC, Product Name at 25°C, Gravity Color, Point Description / Use g/eq max % cps at 25°C max °F Trimethylolpropane Triglycidyl Ether. ERISYS GE-30 100 - 200 135 - 150 1.14 - 1.16 0.10 100 >200 Low viscosity, high functional epoxy modifier. Excellent for 100% solids, adhesives and coatings. Trimethylolethane Triglycidyl Ether. Low viscosity high Aliphatic Triglycidyl Ether Modifiers ERISYS GE-31 200 - 300 150 - 170 1.19 - 1.21 0.10 4(1) >200 functional epoxy modifier. Use to increase crosslink density and enhance chemical resistance. Castor Oil Triglycidyl Ether. Low viscosity trifunctional ERISYS GE-35 300 - 500 550 - 650 1.01 - 1.03 — 8(1) >200 flexibilizer. Provides increased impact and thermal shock resistance to epoxy formulations. Low moisture pick-up. ERISYS GE-35H 300 - 500 550 - 650 1.01 - 1.08 — 8(1) >200 Castor Oil Glycidyl Ether. Lower modulus version of GE-35. Propoxylated Glycerin Triglycidyl Ether. ERISYS GE-36 200 - 320 620 - 680 1.02 - 1.04 0.10 2(1) >200 Aliphatic trifunctional flexibilizer. Used in severe thermal cycling conditions. 1,070 - ERISYS GE-38 160 - 180 1.21 - 1.25 0.70 3(1) 200 Polyglycerol-3-Polyglycidyl Ether. Flexible epoxy. 1,390 Polyfunctional- Sorbitol Polyglycidyl Ether. Aliphatic polyfunctional diglycidyl 8,000 - modifier to impart higher reactivity and crosslink density ERISYS GE-60 160 - 195 1.27 - 1.30 0.50 2(1) >320 18,000 to epoxy resin formulations and crosslink acid functional polymers. (1) Gardner Color Multi-Epoxy Functional- Glycidyl Esters / Amine Viscosity Specific APHA Flash EEW, HCC, Product Name at 25°C, Gravity Color, Point Description / Use g/eq max % cps at 25°C max °F Glycidyl Ester of Neodecanoic Acid. Efficient and ERISYS GS-110 5 -15 238 - 256 0.95 - 0.97 0.30 50 >250 economical diluent for viscosity reduction. Amine Modifiers Glycidyl Ester/ Glycidyl Ester of Dimer Acid. Flexibilizing modifier for ERISYS GS-120 400 - 900 390 - 470 0.97 - 1.00 2.0 9(1) >200 rigid epoxy resin systems. Epoxidized meta Xylylenediamine. Low viscosity 1,600 - ERISYS GA-240 95 - 110 1.14 - 1.16 0.3 5(1) >420 tetrafunctional resin will increase crosslink density 3,000 of modified systems. (1) Gardner Color 12
Hypro™ Reactive Liquid Polymers Hypro™ Reactive Liquid Polymers (RLP) feature carboxyl, amine and methacrylate vinyl reactive functional groups. The letter designations below are the key to the RLP product nomenclature. Hypro polymers are 3,000-4,000 molecular weight liquids that vary in acrylonitrile and butadiene content. Acrylonitrile will increase resin compatibility, viscosity and raise Tg. Reactive liquid polymers are used as co-reactants in thermoset systems. At low levels they function as tougheners, improving impact resistance and peel strength while maintaining mechanical and thermal properties. At higher levels they provide high elastomeric properties to thermoset materials. End Group Back Bone C Carboxyl T Terminal Reactive Groups A Amine B Butadiene E Epoxy N Acrylonitrile V Methacrylate Vinyl X Pendent Reactive Groups Carboxyl Terminated Butadiene (CTB) and Butadiene-Acrylonitrile (CTBN) Polymers Hypro Hypro Hypro Hypro Hypro Hypro Hypro™ Polymers 2000X162 CTB 1300X31 CTBN 1300X8 CTBN 1300X13 (1) CTBN 1300X9 CTBNX 1300X18 CTBNX Acrylonitrile Content, % 0 10 18 26 18 21.5 Carboxyl Content Acid Number (2) 25 28 29 32 38 39 EPHR* 0.045 0.050 0.052 0.057 0.067 0.070 Brookfield Viscosity, mPa•s or cP @27°C (81°F) 60,000 60,000 135,000 500,000 160,000 350,000 Specific Gravity, 25°C (77°F) 0.907 0.924 0.948 0.960 0.955 0.961 Functionality 1.9 1.9 1.8 1.8 2.4 2.4 Molecular Weight, Mn 4,200 3,800 3,550 3,150 3,600 3,400 Glass Transition Temperature (Tg, °C)** -77 -66 -52 -39 -52 -46 (1) Low sodium 1300X13NA CTBN and low chloride 1300X13CL CTBN versions of this material are also available. (2) Acid Number = mg,KOH/gram *Equivalents per hundred rubber **Measured via DSC (Differential Scanning Calorimeter) 13
Hypro™ Reactive Liquid Polymers (cont.) Amine Terminated Butadiene-Acrylonitrile Polymers Hypro Hypro Hypro Hypro Hypro Hypro Hypro™ Polymers 2000X173 1300X21 1300X16 1300X45 1300X35 1300X42 ATB ATBN ATBN ATBN ATBN ATBN Acrylonitrile Content, % 0 10 18 18 26 18 Amine Equivalent Weight* 950 1,200 900 1,850 700 450 Amine Value 59 47 62 30 80 125 Brookfield Viscosity, mPa•s or cP @27°C (81°F) 180,000 180,000 200,000 375,000 500,000 100,000 Specific Gravity, 25°C (77°F) — 0.938 0.956 — 0.978 0.942 Glass Transition Temperature (Tg, °C)** — -65 -51 — -38 -59 Free Amine Levels, % 4 2 5
HyPox™ Elastomer Modified Epoxy Resins Elastomer modification to epoxy resins is a valuable way to merge These are grouped under the series designation: the benefits of alternate polymer chemistry with the convenience of D Series - Dimer Acid Modified Epoxy Resins conventional 1 or 2 part epoxy handling and performance. Currently, CVC offers CTBN modification for toughening and chip resistance, U Series - Urethane Modified Epoxy Resins Dimer Acid modification for flexibility and Urethane modification for R Series - CTBN Modified Resins adhesion to difficult surfaces. Each resin system is further divided by resin base: “A” for Bisphenol A, “F” for Novolacs and “M” for Glycols Dimer Acid Modified Epoxies Elastomer Viscosity EEW, Gardner Color, Acid No., Product Name Description / Use Content % at 52°C, cps g/eq max max Dimer Acid Modified Bisphenol A modified Dimer Acid for HyPox DA323 40 40,000 - 60,000 600 - 725 12 0.1 Epoxy Resin improved flexibility. Urethane Modified Epoxies Elastomer Viscosity EEW, Gardner Color, Acid No., Product Name Description / Use Content % at 25°C, cps g/eq max max Improved adhesion to vinyl and other HyPox UA10 12 500,000 - 800,000 210 - 220 2 — Urethane Modified elastomers. Epoxy Resin Improved adhesion to vinyl and other HyPox UA11 5 25,000 - 45,000 210 - 220 2 — elastomers. 15
Compact tension specimens exemplify toughening. Stress whitening is seen in the sample with HyPox™ indicative of a toughened system. The sample without HyPox does not demonstrate any stress whitening, thus is quite brittle. HyPox™ Elastomer Modified Epoxy Resins (cont.) CTBN Modified Epoxies Elastomer Viscosity Gardner Acid EEW, Product Name Content at Color, No., Description / Use g/eq % 25°C, cps max max Very High Acrylonitrile Containing Solid Elastomer Modified Bisphenol A 15,000 - HyPox RA 95 5-7 195 - 210 4 0.2 Epoxy Resin. Useful as a reactive toughener and tackifier for adhesive and 30,000(1) composite applications. Acrylonitrile Containing Liquid Elastomer Modified Bisphenol A Epoxy Bisphenol A Modified 150,000 - HyPox RA 840 40 325 - 360 10 0.1 Resin. Useful as a reactive toughener to increase toughness, impact 230,000 resistance, and peel adhesion in liquid Bisphenol A type systems. High Acrylonitrile Containing Liquid Elastomer Modified Bisphenol A 300,000 - Epoxy Resin. Useful as a reactive toughener to increase toughness, impact HyPox RA 1340 40 325 - 375 10 0.1 600,000 resistance, and peel adhesion in liquid Bisphenol A type systems. Shows improved compatibility vs. RA 840. Combining Hypro’s 2000X162 CTB and 1300X13 CTBN make 16213 a 180,000 - HyPox RA 16213 29 245 - 285 — 5 unique epoxy adduct with superior low temperature (-40°C) properties to 300,000 HyPox RA 840 in dicyandiamide cured epoxy adhesives. High Acrylonitrile Containing Liquid Elastomer Modified Epoxy Phenol 25,000 - Novolac Resin. Useful as a reactive toughener to increase toughness, HyPox RF 1320 20 210 - 220 6 0.1 50,000 impact resistance, and peel adhesion in low viscosity epoxy phenol novolac resin systems. Bisphenol F Modified 150,000 - Higher Rubber Content Version of HyPox RF 1320. Higher rubber content HyPox RF 1341 40 285 - 330 — 0.2 300,000 allows for lower dosing levels vs. HyPox RF 1320. High Acrylonitrile Containing Liquid Elastomer with Higher Functionality 35,000 - Epoxy Phenol Novolac Resin. Useful as a reactive toughener to increase HyPox RF 928 20 210 - 225 10 0.1 75,000 toughness, impact resistance, and peel adhesion in medium viscosity, higher Tg, epoxy phenol novolac resin systems. High Acrylonitrile Containing Liquid Elastomer with Highest Functionality 120,000 - Epoxy Phenol Novolac Resin. Useful as a reactive toughener to increase HyPox RF 933 20 212 - 231 10 0.1 180,000 toughness, impact resistance, and peel adhesion in higher viscosity, highest Tg, epoxy phenol novolac resin systems. Acrylonitrile Containing Liquid Elastomer Modified Low Viscosity Difunctional Epoxy Monomer. Useful as a lower viscosity reactive HyPox RM 20 50 4,000 - 8,000 275 - 305 10 0.1 Glycol Modified toughener to increase toughness, impact resistance, and peel adhesion in epoxy resin systems. High Acrylonitrile Containing Liquid Elastomer Modified Low Viscosity 15,000 - Difunctional Epoxy Monomer. Useful as a lower viscosity reactive HyPox RM 22 50 320 - 360 10 0.1 25,000 toughener to increase toughness, impact resistance, and peel adhesion in epoxy resin systems. Ring and Ball High Acrylonitrile Containing Elastomer Modified Solid Bisphenol A Epoxy Softening 1200 - Solid Bisphenol A HyPox RK 84 32 Amber — Resin. Useful as a reactive toughener to increase applications for structural Point 1800 reinforcement in solid Bisphenol A resin systems. Modified 85 - 105°C High Acrylonitrile Containing Elastomer Modified Solid Bisphenol A Epoxy 300 - 500 @ 1250 - — Resin. Useful as a reactive toughener to increase applications for structural HyPox RK 84L 32 Amber 100°C(2) 1500 reinforcement in solid Bisphenol A resin systems. Made to a different viscosity specification as compared to HyPox RK 84. (1) @ 52°C (2) Bohlin Viscosity (Pa•s) 16
OMICURE™ Catalysts and Accelerators Accelerating the cure speed or lowering the cure temperature is the role of these versatile additions. Whether the need is for acceleration of dicy and anhydrides or catalytic cures of epoxy resins, a CVC product is available to fit your needs for latency or cure profile. These products include: OMICURE™ DDA Series - Dicyandiamide OMICURE™ U Series - Substituted Urea Accelerators for Dicy OMICURE™ B Series - Boron-Based Catalysts Curing Agents / Accelerators Dicyandiamide Curing Agent – Typical use levels in DGEBA from 5-10 phr. Onset Particle Size Typical Flow Melting Mean Product Name Color Control Point Particle 10% 50% 90% Description / Use Content (°C) Size Ultra-Fine particle size Dicyandiamide for the most critical applications. Provides for excellent Omicure DDA 5 207- 212 4μ
Curing Agents / Accelerators (cont.) Accelerators used with Dicyandiamide to lower required cure temperatures and increase speed of reaction Particle Size Time to Cure Typical Time to (percent through to 95% Peak PHR Double in 325 screen) Full Cure(3) Tg Product Name Melting Color with Viscosity Description M (°C)(2) Point Dicyandiamide(1) Regular @ 25°C(2) at at Grade (°C) Grade (weeks) 120°C 140°C (micronized) 126 - Omicure U-405 off-white 1-5 80 95 10 22 9 118 Phenyl Dimethyl Urea 136 2,4 Toluene bis 180 - Omicure U-24 off-white 1-5 80 95 10 20 7 127 Dimethyl Urea - 195 Isomer Grade Substituted Urea Accelerators 80/20 Toluene bis 180 - Omicure U-410 off-white 1-5 80 95 10 18 7 123 Dimethyl Urea - 195 Technical Grade 4,4’ Methylene bis 220 - Omicure U-52 off-white 1-5 80 95 55 27 12 127 (phenyl dimethyl urea) 230 Isomer Grade 4,4’ Methylene bis 190 - Omicure U-415 off-white 1-5 80 95 20 33 12 128 (phenyl dimethyl urea) 220 Technical Grade 190 - Omicure U-35 off-white 1-5 80 95 134 46 15 124 Cycloaliphatic bisurea 210 Omicure U-210 172 - N-(4-chlorophenyl) N, off-white 1-5 80 95 16 29 15 121 (Monuron) 182 N Dimethyl Urea (1) with DGEBA (EEW=190) and dicy (2) substituted urea @ 3phr; dicy @ 8phr; with DGEBA (EEW=190) (3) Cure - DSC scan at 20°C/minute to 275°C, substituted urea @ 3phr; dicy @ 8phr, with DGEBA (EEW=190) Miscellaneous Curing Agents Gardner Use Level Product Name MP, °C Color Color, Tg, °C Description / Use PHR max Accelerator for anhydrides and catalyst for high temperature Curing Agents and OMICURE 24EMI liquid Brown 0.1-10(1) 16 — epoxies. Faster reactivity vs. BDMA or tertiary amine Accelerators substituted phenols. Can be used as sole curing agent or as accelerator for Anhydrides, Dicyandiamide or Aromatic Amines. Clear, OMICURE BC-120 25-35 Tan 0.1-10(1) — 130(2) compatible formulations. Very long room temperature shelf life. (1) low levels to accelerate acid anhydrides, mid-range or higher levels as sole curing agent. Determine optimum concentration empirically. (2) with DGEBA, EEW=190; @ 8phr 18
Glossary Acid Number – Acid number describes the number of equivalents HCC – HCC refers to the Hydrolyzable Chloride Content of an epoxy per liter of KOH (potassium hydroxide) required to neutralize the acid functional material. It is usually referred to as a weight % of the contained in a given sample. Thus it is an indication of the quantity of compound in question, or in parts per million (ppm). Hydrolyzable acid present in a given material. The higher the acid number, the chloride refers to the chlorine left in a compound from non- greater the amount of acid in the product. With respect to its use in dehydrohalogenated moieties (or unclosed rings) and is liable to this brochure, acid number is used to describe the properties of HyPox liberation via simple hydrolysis reaction. With respect to the products made from Carboxylic Acid containing raw materials. The compounds shown in this brochure, most have relatively low HCC acid number is used as a gauge to determine the completion of contents on the order of 0.10%. HCC should not be confused with reactions where epoxy containing materials are adducted, or bound chloride (which is not subject to liberation via simple added to carboxylic acid functional resins. In general, an acid number hydrolysis) or ionic chloride (from sodium chloride or other salts of 0.10 or less is used to determine the practical end point of these present as a by product of reaction). Another measure of chlorides of reaction processes. particular importance to the electronics industry is “total chloride” which is a measure of all types of chloride present in the product APHA Color – APHA Color is a color scale used for clear, light yellow (hydrolyzable + bound + ionic). colored liquids such as ground water, light oils and chemicals. This test method uses specific dilutions of a platinum-cobalt stock solution NV – NV refers to the non-volatile component of a resin or resin to give numeric values from 0 (the lightest) to 500 (the darkest) to a solution, is usually expressed as a percentage (%), and is usually used given sample. Samples are compared against the standard to as a reportable component of solvent cut resins or diluents such determine which standard most closely matches the sample. Because as 8330MAK80 for example. However, most epoxidation processes of the standards used, this scale is sometimes referred to as Platinum- are performed in solvent which is removed via distillation at the Cobalt color. With CVC products it is used to define the color of our completion of reaction. Therefore, %NV is sometimes reported to lighter, more colorless products. An APHA color of 150 roughly certain customers utilizing resins or diluents for outgas sensitive corresponds to a Gardner Color of 1 (See Gardner Color below.) applications, and would be a relatively small number, such as 0.10%. Average Epoxy Functionality – Epoxy Functionality refers to the Particle Size – Particle size refers to the actual size of solid number of reactive epoxy groups present in a particular epoxy resin. particulates, such as dicyandiamide or substituted urea, that are used With respect to Epoxy Phenol Novolacs, we see molecules with a in the formulation of epoxy compounds. Particle size is an important range of functionalities. In resins such as the 8000 series there are property of powdered reactive materials because as the p articles in a molecules that are 2, 3, 4, 5, and etc., functional. A product like Epalloy given weight of material are made smaller, the effective surface area of 8220 will contain almost all 2 functional material with very little that weight of material increases e xponentially, providing much product of higher functionality. As we progress up the series, there are greater contact area with the liquid components of the formulation. greater amounts of multifunctional materials present and lesser Particle Size is usually reported in units of microns. One Micron is amounts of difunctional materials. Average Epoxy Functionality is the 10-6 meters or approximately 0.04 mils. The unit for microns is μ. average functionality by weight % composition of epoxy molecules with Particle size can be quantified by use of standard sieves which are different functionalities in a listed product. precisely manufactured screens of various sizes made for this purpose. For the purpose of powdered materials CVC sells such as the urea EEW – EEW stands for Epoxy Equivalent Weight and is measured in accelerators, particle size is often quantified based on the amount of grams/equivalent. This method utilizes a titration with perchloric acid material that passes through a 325 mesh screen. A 325 mesh screen and tetraethylammonium bromide, to produce Hydrogen Bromide, has openings that are about 44 microns wide. Standard grade which reacts quantitatively with epoxy groups to determine the materials require 80% by weight of a sample to pass through the amount of epoxy groups present in solution. The result is reported in screen while M-Grade or micronized material requires 95% of the grams of epoxy compound containing one equivalent of epoxy sample to pass through the screen meaning 95% of the particles are groups. It is a basic property of epoxy resin compounds and is used by less than 44 microns in dimension. formulators to determine proper combining ratios to use with epoxy curing agents. Particle Size Distribution – Particle Size Distribution defines the range and magnitude of all the different sized particles in a given Flash Point – Flash point is used to measure the flammability of an sample. For properly ground and graded materials the distribution organic substance (usually a liquid). Most substances are tested via a curve is usually Gaussian or “Bell Shaped”. A typical PSD (Particle Size “closed cup” determination whereas a sample is heated at a specified Distribution) will give the average particle size, standard deviation, and rate and vapors are allowed to build up in a closed headspace. other useful statistical data such as the p ercentage of particles less The closed headspace is exposed to a flame. The temperature than a given value; for example 90% of the particles are less than 6.9μ, where the flame is able to ignite the vapor is the Flash Point. This or 50% are less than 3.5μ; such values are often referred to as the d90 property is particularly important in determining transportation or d50 respectively. classifications of substances. Viscosity – Viscosity is a property of fluids that is described as the Gardner Color – Gardner Color is a color scale used for liquid resistance to flow. There are a variety of ways to measure and report materials that range from water white through yellow, to deep amber. viscosity. Most of the values in this brochure were taken by The scale ranges from 1 to 18. The lower end of the scale (1 - 8) uses measurement with an instrument known as a Brookfield Viscometer standard potassium chloroplatinate solutions to provide various which measures viscosity in Centipoise (cps) or Poise (P). shades of yellow. The upper end (9 - 18) uses solutions of ferric (1 Poise = 100 centipoise.) Water, by definition, has a viscosity of 1 cps. chloride and cobalt chloride. Samples are compared to the standards For illustration purposes #10 motor oil will measure about 400 cps, to determine the correct color designation. Castor Oil will measure 1,000 cps; Karo Syrup - 3,500 cps. 19
CVC Thermoset Specialties Sales & Distribution Network United States West EUROPE Northeast Dowd and Guild, Inc. Azelis Nordic – Broste AS Bedford Specialty Sales, Inc. San Ramon, CA Lyngby, Denmark Shirley, MA Tel (800) 959-8222 Tel +45 4526 3333 Tel (978) 425-6214 Web: www.dowdandguild.com Web: www.broste.com Web: www.bedfordsales.com The NP Group, LLC Azelis Italia S.p.A. E.M. Sullivan Associates, Inc. Dallas, TX Milan, Italy Broomall, PA Tel (972) 386-5442 Tel +39 02 48479.1 Tel (610) 725-8717 Web: www.npgroupinc.com Web: www.azelis.it Web: www.emsullivan.com CANADA Hubron Speciality Ltd. Gillen Company, LLC Chemroy Canada, Inc. Manchester, UK Cuddy, PA Brampton, Ontario Tel +44 (0) 161 681 2691 Tel (412) 257-3300 Tel (905) 789-0701 Web: www.hubronspeciality.com Web: www.chemroy.ca Southeast IMCD Benelux BV Kohl Marketing FAR EAST Rotterdam, The Netherlands Roswell, GA Heng Hsin Company, Ltd. Tel +31 10 290 8600 Tel (770) 753-4979 Taiwan, R.O.C. Web: www.imcd.nl Web: www.kohlmarketing.com Tel (886) 2 2541 8641 Web: www.henghsin.com.tw IMCD Benelux NV Midwest Mechelen, Belgium Cal-Chem PTI Japan, Ltd. Tel +32 15 29 49 50 Troy, MI Tokyo, Japan Web: www.imcd.be Tel (248) 743-0248 Tel (81) 3 3213 2542 Web: www.cal-chemusa.com Web: www.ptij.co.jp IMCD Deutschland GmbH & Co. KG Cologne, Germany Cemsac Corporation Shenzhen Jiadida Chemical Co., Ltd. Tel +49 221 77 65 0 Ellisville, MO Shenzhen, China Web: www.imcd.de Tel (636) 391-2600 Tel (86) 755 8212 4697 Web: www.cemsac.com Web: www.jiadida.com IMCD Espana Especialidades Quimicas, S.A. Barcelona, Spain Chem/Serv, Inc. Trachem Tel +34 93 241 38 58 Minneapolis, MN Seoul, Korea Web: www.imcd.es Tel (612) 379-4411 Tel (82) 2 2248 6290 Web: www.chemserv.com Web: www.trachem.com IMCD France SAS Cedex, France Dar-Tech, Inc. Australia / NEW ZEALAND Tel +33 1 49 33 31 31 Cleveland, OH International Sales & Marketing Web: www.imcd.fr Tel (800) 228-7347 South Hurstville, Australia Web: www.dar-techinc.com Tel/Australia (61) 2 9580 2400 IMCD Switzerland AG Tel/New Zealand (64) 9 275 0745 Zurich, Switzerland Resin Sales, Ltd. Web: www.ismaus.com Tel +41 43 244 8000 Northbrook, IL Web: www.imcd.ch Tel (847) 564-0248 Web: resinsalesltd.com USNER GmbH Hallein, Austria Tel +43 6245 81 516 Nanoresins AG Geesthacht, Germany Tel +49 4152 1390 0 Web: www.nanoresins.com Corporate Headquarters Division Headquarters The information contained herein is believed to be reliable, but no representa- tions, guarantees or warranties of any kind are made as to its accuracy, suitability Emerald Performance Materials, LLC CVC Thermoset Specialties for particular applications or the results to be obtained. The information is based on laboratory work with small-scale equipment and does not necessarily indi- 2020 Front Street, Suite 100 844 N. Lenola Road cate end product performance. Because of the variations in methods, conditions and equipment used commercially in processing these materials, no warranties Cuyahoga Falls, OH 44221 Moorestown, NJ 08057 or guarantees are made as to the suitability of the products for the applications disclosed. Full-scale testing and end product performance are the responsibil- ity of the user. Emerald Performance Materials shall not be liable for and the Tel (330) 916-6700 Tel (856) 533-3000 customer assumes all risk and liability of any use or handling of any material be- yond Emerald Performance Materials’ direct control. The SELLER MAKES NO WAR- Fax (330) 916-6737 Fax (856) 533-3003 RANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED Web: www.emeraldmaterials.com Web: www.cvc.emeraldmaterials.com WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without permission of the patent owner. 001-September 10
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