A Review of Air Pollution and Solutions Way Management Related to Ribbed Smoked Sheets (RSS) Production of Community-Level Rubber Cooperatives in ...
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Pollution, 6(2): 267-284, Spring 2020 DOI: 10.22059/poll.2019.290078.690 Print ISSN: 2383-451X Online ISSN: 2383-4501 Web Page: https://jpoll.ut.ac.ir, Email: jpoll@ut.ac.ir A Review of Air Pollution and Solutions Way Management Related to Ribbed Smoked Sheets (RSS) Production of Community-Level Rubber Cooperatives in Thailand: Smoke, Soot and PAHs particles Kalasee, W. * and Teekapakvisit, C. King Mongkut’s Institute of Technology Ladkrabang, Prince of Chumphon Campus, 17/1 M.6 Pathiu District, Chumphon 86160, Thailand Received: 03.10.2019 Accepted: 18.02.2020 ABSTRACT: In Thailand, RSS chamber of community-level rubber cooperatives can be classified into two models: old and new model, named after the years of their establishment. Hot gas as a heat supply from Para-rubber (PR) wood (Hevea brasiliensis) combustion is used for removing moisture from the natural rubber (NR) sheets. Smoke and soot particles from PR wood burning has effected to the quality of the NR sheet and the pollution in the workplace area and lead to health problems of the worker. Cascade impactors are equipment for measuring the smoke and soot particles size distribution from PR wood combustion. PAHs compounds from PR wood combustion were found 15 different PAHs components (Tekasakul et al., 2005; Furuuchi et al., 2006). Important methods in decreasing smoke and soot particles from combustion of PR wood for rubber smoking chamber are separation equipment and ventilation designed by computational fluid dynamics (CFD) technique. In this article, the separation method is focused on smoke and soot particle collection to maintain the quality of the NR sheet. This equipment is reviewed both indoor and outdoor, for example, an impaction wall, electrostatic precipitator, stainless-wire, etc. This review indicates that the ESP installing between the furnace and the smoking chamber is suitable to eliminate aerosol particles at the rubber smoking industry. In addition, CFD technique reports is aimed at collecting aerosol particles for decreasing smoke and soot particles emission from rubber smoking chamber is presented. Keywords: Para-Rubber; wood combustion; Filtration; ESP; CFD. INTRODUCTION Thailand, PR wood has been immensely Smoke, soot and polycyclic aromatic used in multitudinous industries (Promtong hydrocarbons (PAHs) are produced by & Tekasakul, 2007; Kalasee, 2009; biomass burning of dried and cured the Chaivatamaset, 2015). Incomplete agriculture product (Ravindra et al., 2006; combustion of PR wood results in the great Wang et al., 2010), for example, ribbed emission of particles; smoke and soot; smoked sheet (RSS). They were resulted (Furuuchi et al., 2006; Phairuang et al., 2019) from the carbonaceous materials combustion and chemical compositions such as PAHs (Kalasee et al., 2003; Deng et al., 2006). (Chomanee et al., 2009; Keyte et al., 2013; In Southeast Asian countries, especially Hata et al., 2014; Chaivatamaset, 2015). Thailand is the biggest natural rubber * Corresponding Author, Email: arwkalasee@gmail.com 267
Kalasee, W. and Teekapakvisit, C. (NR) production and exportation country in precipitator) are appropriate to use in the Southeast Asian and the world. In year rubber smoking chambers (Tantichaowanan, 2016, Thailand produced natural rubber 2005; Tekasakul et al., 2005; Tekasakul et about 37.5% of the total world production al., 2006; Kalasee, 2009; Ruttanachot, et al., or about 4.5 million tons (Thailand Rubber 2011). Research Institute, 2017). More than 85% Recently, CFD technique is used to of NR products of Thailand are exported to decrease smoke and soot particles emissions China, Japan, USA and India. Generally, from the rubber smoking chamber to NR products include vehicle tires, toys, environment. The modified ventilation condoms, medical gloves (Kalasee, 2009; system which uses CFD technique Matiyanon et al., 2013; Rattanamechaiskul simulation and experiment is in good et al., 2016). agreement. Smoke and soot particles Currently in Thailand, More than 90% of ventilation would be pleasurably improved NR products are RSS, rubber concentrated by appropriate roof ridge exit (Purba, 2009; latex (RCL), and block rubber (Thailand Purba & Tekasakul, 2012). Thus, this review Rubber Research Institute, 2018). Now, RSS article focuses on the discussion of air and RCL consumption are increased in pollutants (smoke, soot and PAHs) from PR Thailand, Asia, and World. They are wood combustion in a NR sheet smoking followed by increasing numbers of the process and the different techniques to automotive industry. In RSS process, the decrease this effect. rubber sheets are washed and hung on bamboo bars to dry in the smoking Ribbed Smoked Sheets Chamber chambers. Hot gas production from Para Ribbed smoked sheets (RSS) chamber of rubber wood combustion is flowing to the community-level rubber cooperatives in rubber in smoking chamber via the tunnel Thailand can be classified into two models which is constructed under the floor of the (old and new model), named after the years chamber. When the wood is burned, the ash, of their establishment. The old model so- carbon, water vapor, smoke and soot called model 1994 contains seven rubber particles are produced. Smoke and soot smoking chambers and each chamber has particles from wood combustion affect to the capacity 1.2-2.0 ton on a dried basis workplace environment and can cause the (Kalasee et al., 2003; Promtong, 2006; worker’s health problem. Study on the Choosong et al., 2010). The new model characteristics of smoke and soot particles is established in 1995. This model contains necessary. The important characteristics of four rubber smoking chambers and the the study are the physical and chemical capacity of each chamber is double of the properties. The physical properties of smoke old chamber model capacity. The old and soot particles from Para rubber wood chamber model has dimensions of 2.6 m combustion can be divided into two width, 6.2 m length, and 3.7 m height. It is characteristics; particles size distribution and constructed of brick, mortar and cement. A particles mass concentration. The chemical steel gate is built in the front wall for characteristics of smoke and soot particles loading and unloading rubber. At the from Para rubber wood combustion related ceiling of chamber, it has two ventilating mainly to chemical constituents of particles windows. Furnace is located at 0.5 m such as PAHs and organic compounds. For below the floor and it is constructed in the the smoke and soot particles collection rear of the chamber. Heat distributing apparatuses, three techniques (filtration by tunnels have 4 inch diameter and are built stainless-wire mesh, inertial impaction in twelve positions at the floor level of the (impaction wall) and electrostatic room. The bamboo bars are used to hang 268
Pollution, 6(2): 267-284, Spring 2020 the rubber sheets on a steel crate which has groups (primary and secondary particles). dimensions of 2.0 m width, 2.0 m length, In the combustion zone, the primary form and 2.0 m height. The old model can of combustion particles is occurred at high contain three crates, but the new model can temperature and the second form of contain six crates. PR woods consumption particles is discovering in the fuel gas, is about 0.8-1.2 ton per ton of dried chamber, chimney and atmosphere. products both old and new chambers The measurement of smoke and soot (Kalasee, 2009; Choosong et al., 2010). particles distribution from para-rubber wood burning appliances is very challenging. RSS Production Process and Monthly Many reports show that particles emissions RSS Production Changes from wood combustion on two main factors. In the RSS production process, the raw The first is particles size distribution and the material or fresh para-rubber latex; white second is mass concentration. liquid; is tapped and collected from Para- The particles size distribution measures rubber tree. The membered farmers of an aerosol size that can be superseded by rubber cooperative transport this latex to the diameter (Friedlander, 2000; Butler & RSS factory during 7 A.M.-11 A.M Mulholland, 2004; Riahi et al., 2013). (Choosong et al., 2010; Kalasee et al., 2012; According to Giechaskiel et al. (2014) report, Matiyanon et al., 2014; Rattanamechaiskul the particle size is determined based on et al., 2016). During 8 A.M.-12.00 A.M., characteristics, e.g. inertia, optical properties. this latex is poured to tanks which are Cascade impactors are apparatuses for located near the chamber. Until 2 P.M. measuring the particles size distribution in water and the acid such as formic and acetic mass that operates based on the is added to para-rubber latex. Aluminum categorization of inertial of aerosol particles spacers are immersed in this latex and used (Davies, 1966; Hinds, 1999). They are the as partitions to produce sliced slabs (around most appropriate equipment to achieve the 3 cm × 50 cm × 50 cm) of solidify the latex air quality measurements. These reports are (tofu-like slabs). These slabs are then described in both the European (Alonso et washed and squeezed to form thin layer al., 2017; Kesavan et al., 2017), Asian sheets which have a thickness about 3-4 mm (Cheng et al., 2007) and Australian (Gras & by a squeezing machine. Theses sheets are Michael, 1979). The testing method is set in hung on the bamboo bars which placed at STP555, STP1002 and STP1287. steel crate by the worker before they are One type apparatus of cascade transferred to dry in a smoke chamber. impactors is Andersen air sampler During the high season (December to (Andersen, 1956; Cheng et al., 2007; Hata February), the capacity of the factory is et al., 2014; Alonso et al., 2017; Kesavan more than 15000 sheets per week and it has et al., 2017). The Andersen sampler capacity about 7000-11000 sheets per week operates on the principle of inertial during June to September (moderate impaction. In each stage, the sampler season). This production is the lowest consists of a plate for collection surface during the deciduous fall season (March to and specification of nozzle arrangement. May) because the most of farmers stopped The sample air is flowed into the sampler to tap the para-rubber trees (Choosong et al., through stage by stage. The total nozzle 2010). area and nozzle size decrease with the stage from upstream to downstream. After Particles Distribution and Particles Sampling Method the particles pass through a nozzle, the Combustion particles from Para rubber particles that have diameter smaller than a wood burning can be divided into two cut-off diameter of stage remain in the air 269
Kalasee, W. and Teekapakvisit, C. stream sample and pass onto the next stage. PR wood samples had moisture content But the larger particles that have much ranging from 34.75 to 107.5% dry basis sufficient inertia are collected at plate or and the mass concentration of their collection surface. In the analysis, the stage combustion were 47 to 1358 mg/m3. cut-off diameter or d50 is defined as the Investigated by Furuuchi et al. (2006), the aerodynamic diameter at 50% cumulative characteristics of smoke and soot particles oversize percentage of particles. It is used from the Para rubber wood combustion had to find the size distribution of particles an impact on the workplace environment. which is known as the mass median Their results of the smoke and soot particles aerodynamics diameter (MMAD). The size distribution agreed with of Kalasee et geometric standard deviation (GSD) of the al., 2003 report. For inside the workplace, particles is defined as (Hinds, 1999): their result showed that the particles concentration was 0.33 mg/m3 and it was d84.1% d50% d higher than the acceptable limit by the GSD [ 84.1% ]1/2 (1) d50% d15.9% d15.9% Thailand Department of Pollution Control. In 2009, the study of Chomanee et al. where d15.9 , d50 and d84.1 are the showed that the smoke and soot particles diameters where cumulative oversize size distribution was similar to the results percentage of particles are 15.9, 50 and from Kalasee et al. (2003). In their 84.1, respectively. experiment, the air sampler was improved The normally used technique for appraisal to prevent its condensation. Their report particulate mass concentrations relates to showed that MMAD and GSD are found to filtration (Davies, 1966; Hinds, 1999; Murry, be 0.68 micron and 3.04, respectively. 2000; Letts et al., 2003). Under controlled The studies of Hata et al. (2014) relative humidity and temperature presented that the characteristics of conditions, filters are weighed before and particles emitted from the Para rubber after testing. Particles mass concentrations wood burning in a laboratory-scale (tubular are calculated from the volume of gas electric furnace). Their results showed that sampled and the filter mass increase. the increase of the heating rate had a In this section, the study of smoke and relative influence to an increase of the total soot particle characteristics from Para rubber particles mass concentration emissions wood combustion is reviewed. Many reports from the Para rubber wood combustion. of researchers are discussed as follows. For the graph relation between cumulative Kalasee et al. (2003) is the first report to mass fraction and aerodynamic diameter of study on smoke and soot particles the particles distribution from para-rubber distribution from para-rubber wood wood burning in their results indicated that combustion. The report showed that the MMAD and GSD were found to be about smoke and soot particles size distribution 0.7 micron and 2.6, respectively. Their was measured by an 8-stage cascade result was similar to the results from (Andersen) sampler. Studied by Kalasee et Kalasee et al., (2003); Chomanee et al., al. (2003), the particles size distribution (2009). was a single-model behavior. MMAD and GSD of smoke and soot particles were PAHs Concentration found to be 0.95 micron and 2.51, PAHs are organic compounds that consisted respectively. The moisture content of the of hydrogen and carbon atoms Para rubber wood had effected on the mass (Venkataraman et al., 2002; Tang et al., concentration of the smoke and soot 2005; Choosong et al., 2007, Salaudeen et particles. The result also showed that the al., 2017). PAHs have toxic effects on the 270
Pollution, 6(2): 267-284, Spring 2020 function of cellular membranes (Fang et al., burning had a single modal size 2004; Adeola et al., 2007; Amuda & distribution. The decomposition of PAHs Imeokparia, 2007) and can cause human’s particles from the rubber-woods health problems, e.g. cancer. PAHs are combustion happening using Soft X-rays emitted to an ambient air primarily from the with a wave length of 1.3 × 10-4 to 4.1 × incomplete of fuel combustion, for example, 10-4 micron. The increased total energy of petroleum (Bharti et al., 2019; soft X-rays had a relative influence to Motamedimehr et al., 2019) and wood increase the effective decomposition of (Tekasakul et al., 2008; Chomanee et al., PAHs particles. 2009; Choosong et al., 2010; Hata et al., Tekasakul et al. (2008) presented that 2014). Many reports are shown that the the size distribution of PAHs particles from PAHs are precursors of smoke and soot Para rubber wood combustion in ambient particle nuclei. Homann & Wagner (1966) air around the rubber smoking factory had and many researchers (Martinis et al., 2002; a single-model behavior. During the dry Venkataraman et al., 2002; Saez et al., 2003; season, PAHs concentration in ambient air Chao et al., 2008; Croft et al., 2016) studied was higher than their concentration during on PAHs components from an acetylene- the rainy season. oxygen diffusion flame and their results Chomanee et al. (2009) presented that showed that PAHs had two types of poly- sixteen PAHs compounds from Para rubber aromatic (PA) molecules. The first type of wood combustion were able to be classified PA molecular is compounds without side in two types: 2-3 rings and 4-6 rings. chain (acenaphthalene, naphthalene, Naphthalene, Acenaphthylene, phenanthrene and coronene) and the second Acenaphthene, Fluorene, Phenanthrene and one is PA compounds which have molecular Anthracene are 2-3 rings of PAHs weight of 150-500 or with side chain (Shin et compounds, while the 4-6 rings PAHs are al., 1988; Simonelt et al., 1991; Fenklach & Fluoranthene, Pyrene, Benz[a]anthracene, Wang 1991; Salaudeen et al., 2017; Chrysene, Benzo[b]fluoranthene, Mahmudi et al., 2019; Bharti et al., 2019). Benzo[k]fluoranthene, Benzo[a]pyrene, In this section, the reviewer studied Indeno[1,2,3-cd]pyrene, Dibenz[a,h] PAHs concentration from Para rubber anthracene, and Benzo[g,h,i]perylene. The wood combustion. Many reports are increasing of time period of combustion has discussed as follows. a relative influence to decrease PAHs Tekasakul et al. (2005) and Furuuchi et concentration. al. (2006) showed that 15 different PAHs Investigated by Choosong et al. (2010), components from the Para rubber wood the authors illustrated that wind direction, combustion are found in the aerosol seasonal changes, the geometry of the oven particles and ambient air at the workplace and rubber smoking chamber building and of RSS factory. ventilation type has a relative influence to The report of Furuuchi et al. (2006) change the particulate and PAHs showed that the total PAHs particles concentrations from Para rubber wood concentration from Para-rubber wood combustion. This report also depicted that combustion was very high. For the soot PAHs concentrations in the ventilation particle size larger than 3.3 micron, the zone was higher than their concentrations PAHs concentrations were smaller than 103 in the workplace. ng/m3 while the concentration for smaller The report of Hata et al. (2014) had particles was about 105 ng/m3. shown that the heating rate and the The report of Bai et al. (2007) showed combustion temperature had a significant that soot particles from Para rubber wood effect on PAH emissions. The soot 271
Kalasee, W. and Teekapakvisit, C. particles from Para rubber wood The collection efficiency of a filter combustion that was smaller than 0.43 decreases when the Pec increases and the micron made a large contribution to PAHs. Stk decreases. Thus, Stokes number (Stk) can be defined as (Hinds, 1999) Particles Collection Method Now, there have been many techniques to Dp2u f C Stk (3) catch the little particles, for example, 9 d ws where is particle density, Dp is particle filtration, cyclones separation, gravitational settling, etc. However, the major techniques are requiring a large space for installation. diameter, C is Cunningham slip correction The rubber smoking chamber is the wet factor, and is viscosity (Davies, 1966; areas. So, the installing various particles Hinds, 1999). collection apparatuses is constrained. The During working period, the pressure major reports show that there are only three drop increasing has a relative influence to techniques; filtration by stainless-wire mesh decrease the filter (mesh) collection (ASTM E11 & ISO 3310-1: 2016), inertial efficiency (Letts et al., 2003). Thus, the impaction (impaction wall) and electrostatic pressure drop across filters (P) can be precipitator (JB/T 12591-2016); which defined as (Davies, 1952): appropriates for using at the rubber smoking g uvg Ft chambers (Kalasee et al., 2003; Docherty et P d 2 64 Fs1.5 1 56 Fs3 (4) al., 2005; Tantichaowanan, 2005; Kalasee, ws 2009; Ruttanachot, et al., 2011). In this equation, µg is the gas viscosity, uvg is the face gas velocity, Ft is the Filtration by Stainless-Wire Mesh Because filtration by filters is simple to use thickness of filter, and Fs is the filter and effective, it is the most interest packing density. particles collection technology in the Studied by Kalasee (2003), the author present. Therefore many researchers have showed that the plate of mesh #200 wires- studied appropriate filter materials for stainless is installed on the frame above the removing smoke and soot particles from floor of the rubber smoking chamber. This wood combustion for filtration method. report showed that the particles collection Large particles from the Para rubber wood efficiency of this apparatus is about 50% burning are collected by a stainless-wire and the pressure drop is higher than 200 Pa mesh by inertial impaction method at a at an initial velocity value of 28 cm/s. The high velocity while the small particles are results of this report were similar to the removed from hot gas by Brownian results from Sirisantipong & diffusion method (Sippola, 2002; Kalasee, Tantichaowanan (2002). 2009; Sippola & Nazaroff, 2010). The Inertial Impaction parameters involved in Brownian Inertial impaction or impaction wall is an diffusion and inertial impaction are uncomplicated particle collection Peclet number (Pec) and Stokes number technique. For the rubber smoking factory, (Stk). Where u f is the filtration velocity, the flat plate is installed in the tunnel dws is the stainless-wire mesh diameter, and between a furnace and the rubber smoking DB is the particle Brownian diffusivity. chamber. The principle of this technique is Thus, Peclet number (Pec) is given by the large particles which are unable to pass through a nozzle. These particles are u f d ws clashed with a flat plate because they have Pec (2) DB 272
Pollution, 6(2): 267-284, Spring 2020 too many the inertial forces (Hinds, 1999; a stove and the rubber smoking room. This Kalasee, 2009). report showed that the soot particles from According to the method, the para-rubber wood combustion size in 3.3 to dimensionless number which is described 4.7 micron size range were caught by a flat to the behavior of particles suspended in zinc plate. The impaction system was airflow is Stokes number (Stk) and it can shown in Fig. 1. In this system, the be defined as (Hinds, 1999) impaction wall has the length (liw) of 150 cm and height (hiw)of 60 cm. A hot gas Dp2UC Stk (5) flow in the throat tunnel (stopping 9W distance) was like as a rectangular In this equation, U is an air velocity in acceleration nozzle. The length (lth) and throat, and W is a width of throat. The slip width (Wth) of this throat were 30 cm and correction factor can be calculated from 60 cm, respectively. The stopping distance (Hinds, 1999) (Sd) was 30 cm. The ratio of Sd / wth was 0.390 0.5. Hence, the value of Stokes number in Dp ( ) C 1 (2.34 1.05e Dp ) (6) theory for the stopping distance was 0.5 (Hinds, 1999). The range of velocity values This equation should be placed when C of hot gas flowing in this throat tunnel was 200-500 cm/s. The result of this report appears first time and is a mean free showed that the dust-loading had no path in air molecule. influence to the collection efficiency and it Studied by Kalasee (2009), the was similar to the results from Phonchat & apparatus (inertial impaction or impaction Choowijit (2011). wall) in his research was a flat zinc plate. A plate was installed in the tunnel between Fig. 1. Schematic diagram of the impaction system 273
Kalasee, W. and Teekapakvisit, C. Electrostatic Precipitator qe is the particle charges, and it can be Many researchers have proposed many calculated from (Hinds, 1999) methods to improve the collection efficiency of electrostatic precipitator qe ne (9) (ESP) and electrode cleaning mechanisms where e is the electrical charges, and n is for removal of soot particles from wood the number of charge, and it can be combustion (Kalasee et al., 2003; Intra et calculated from (Hinds, 1999) al., 2005; Kocik et al., 2005; Tantichaowanan, 2005; Tekasakul et al., n n fc ndc (10) 2005; Tekasakul et al., 2006; Intra et al., 2007; Kalasee 2009; Intra et al., 2010; Lin In this equation, nfc is the number of et al., 2011; Ruttanachot et al., 2011; Ma et field charging, and ndc is the number of al., 2016; Lin et al., 2018). Firstly, ESP is diffusion charging. White (1951) has been installed in the 4 inch diameter tube which developing the equation of Fuchs (1947). is built in twelve positions at the floor level In order to calculate the charging rate of the room. ESP installation in the rubber expression can be described by a smoking room is very dangerous because differential equation of White (1951) as ESP works under an electric system, rubber given by smoking chamber has wetting area from dndc n e2 rubber sheet dehydration and the r 2Ci Ni .exp( Kcc dc ) (11) knowledge of worker is rather low. Thus, dt rkT ESP is installed in the tunnel between a In this equation, t is the charging time, r furnace and the rubber smoking chamber in is the particle radius, Ci is the average ion the present rather than installed ESP in the thermal velocity, Ni is the ion rubber smoking room. concentration, Kcc is Coulomb constant, k ESP has high collecting efficiency for a is Boltzmann constant, and T is the small particles and its pressure drop is low temperature. The integrated of the above (Kim & Lee, 1999; Tanaka, 2003; Tanaka, equation can be given by 2006; Long & Yao, 2010; Zhao et al., ndc t dndc r 2Ci Ni dt 2017). Collecting efficiency of ESP (µ) can be defined by using the Deutsch-Anderson ndc e2 (12) 0 exp( K cc ) 0 equation (White, 1963; Kihm, 1987; Hinds, rkT 1999). Thus, the number of diffusion charging AcsVpm (ndc) caused by the diffusion charging time 1 exp[ ] (7) by the particle diameter (Dp) can be Qg calculated from In this equation, Qg is the air flow rate, Dp kT Ni tKcc Dp Ci e2 Acs is the collection surface area, Vpm is the ndc ln 1 (13) 2 K cc e2 2kT particle migration velocity, and it can be calculated from For the number of field charging (nfc), qe E f Cs and it can be given by Ve (8) 3a Dp 3 Dp E f Ni tKcc Zi e 2 n fc (14) 2 4 K cc e 1 Ni tKcc Zi e where Ef is the electric field strength, Cs is the slip correction factor, µa is the air In this equation, α is the particle viscosity, Dp is the particle diameter, and dielectric constant, and Zi is the ion electrical mobility. 274
Pollution, 6(2): 267-284, Spring 2020 For the number of ion concentration reports of researchers are discussed as (Ni), it can be given by (Intra & follows. Tippayawong, 2011) Investigated by Tantichaowanan (2005) I ac dec and Tekasakul et al. (2006), the authors had Ni (15) shown that the ESPs could be employed to ZiVe hte remove smoke and soot particles from Para In this equation, dec is the equivalent rubber wood combustion. In the laboratory, cylindrical radius, Ve is the voltage of the ESPs were suitable for use at the high discharge electrode, µ is the gas velocity, h available voltage supply, which was constant is the height of the collection electrode, Iac at 15 kV. In a field experiment, the twelve is the average corona current, and it can be ESPs units of their design were installed in given by the rubber smoking chamber and each of them was operated at 30 minute periods LhZi 0 I ac d V V V e e c (16) when the fresh PR wood was burned. The 2 s c ln ec total time of the ESPs was operated about 10 r0 hours and the collecting efficiency of the ESPs was higher than 40%. In this equation, L is the length of the In 2009, Kalasee proposed new ESPs to collection electrode, α0 is the free-space improve the design by Tantichaowanan permittivity, Vc is the corona onset voltage, (2005) and Tekasakul et al. (2006). In S is a half of the gap between collection order to decrease the danger of the electrodes, C is a half of the distance installation and usability, the ESPs are between wire electrodes, and r0 is the installed in the tunnel between a stove and radius of the discharge electrode. the rubber smoking room. This report For the equivalent cylindrical radius showed that ESPs were operated longer (dec), it can be given by (Parker, 1997) than 120 hours and the collecting s efficiency of the ESPs was higher than d ac 2c 0.18exp 2.96 For 2c 50%. The result was similar to the results (17) from Kuarsakul et al. (2011). s 0.3 1.0 The report of Kim et al. (2010) 2c presented that CFD technique was For the corona onset voltage (Vc), it can appropriate to study and simulate the be given by aerosol distribution in the ESP system. The d recommendation of this report was shown Vc r0 Eoc ln ac (18) that simulation of the galvanic field and r0 space charge distributions of ESP system where Eoc is the corona onset electric field, was designed by the change of plasma and it can be given by region. An investigation by Ruttanachot et al. 0.864 x105 (2011) is improved ESPs technique of the Eoc 32.2 (19) r earlier design by Kalasee (2009). Their 0 ESPs contain fifteen collection plate where β is the density of gas. electrodes. The cleaning system has water In this section, the review of the study spray from a half of inch PVC pipes. The of the collecting efficiency of smoke and collecting efficiency of ESPs is higher than soot particle from Para rubber wood 60%. After ESPs was operated 120 combustion by ESP is presented. The minutes, the cleaning system is used to 275
Kalasee, W. and Teekapakvisit, C. clean the collection plate electrodes for a conservation for a steady incompressible life of ESP extending. flow can be given by The report of Park et al. (2018) presented that the k–ε model (standard ( ui ) 0 (20) xi model of CFD technique) based on Finite Volume Method and the Lagrangian where is the density, ui' is the velocity approach with the dynamic of particle fluctuation. charging were used to study the corona The differential equations for the discharge model of ESP to solve the conservation of momentum can be written turbulent air flow and the motion and as charging of aerosol particles in the ESP. This result showed that the differences in p ( ui u j ) size, relative permittivity and density had xi xi x j the highest effect on the particle charging, (21) u u j the particle trajectory and the ESP [ ( i ) ui'u 'j ] gi B(T T ref ) collecting efficiency. x j xi Computational Fluid Dynamics where u is the mean velocity components Technique (u, v, w), µ is the fluid viscosity. Here, xi is In the present, the CFD technique is utilized the coordinate axis (x, y, z), gi is the to investigate aerosol concentration, flow gravitational acceleration vector, p is the patterns, and particle motion (Loomans et al., pressure, B is the thermal expansion 2002; Kanaoka et al., 2006; Zhang et al., coefficient, T is the mean temperature, and 2006; Park et al., 2018; Rigopoulos, 2019). T ref is the system surrounding temperature CFD methods can be divided into two major is used in work (the reference temperature). groups: accelerated methods and convention The energy equation can be given by methods. The accelerated methods are then divided into two major groups: Hardware T ( uiT ) [ u 'jT ' ] (22) techniques and Advanced Numerical xi xi Pn xi Methods. For convention methods, Finite Volume Method (FVM), Finite Difference where Pn is the Prandtl number, T ' is the Method (FDM), Finite Element Method temperature fluctuation. The terms ui'u 'j (FEM), and Spectral Methods are the most popular methods. This methods are most and u 'jT ' are called the Reynolds stress highly accurate, widely used and normally (ij) and the diffusion term for the enthalpy, tend to use in most of the commercial respectively. The determination of these software packages, such as ANSYS CFX, terms requires extra equations, which based FLUENT, FLOVENT, STAR-CD and on the proposed by Boussinesq (1877). FEMLAB. The standard k- model is the most The Navier-Stokes equations either in widely used for modelling and simulation a Lagrangian approach or in Eulerian are variety of practical engineering flow. In used to solve in most of the CFD methods this model, the kinetic energy of turbulence (FVM, FDM, FEM and Spectral Methods). (k) equation is given by These equations are described in the k conservation of mass, momentum and ( ui ) energy. However, some methods solve the xi (23) Boltzmann equations instead of Navier- k Stokes equations. [ ( tb )] S p B p xi xi k The continuity equation describing mass 276
Pollution, 6(2): 267-284, Spring 2020 In the standard k- model, the In this equation, a is the density of air, dissipation rate () equation is given by Mf is the mass fraction of smoke aerosol particles, Va is the velocity of air, Ji is the ( ui ) [ ( tb )] local flux for i component, and it can be xi xi xi calculated from (24) 2 C1 ( S p C2 B p ) C3 M f k k J i tb a Dco (29) Sch xi where µtb is the turbulent viscosity and it is calculated from where µtb is the turbulent viscosity, Sch is the Schmidt number, and Dco is the k2 tb Cu (25) diffusion coefficient. When smoke aerosol particles flowing The model constants, proposed by are assumed to be continuous. The Launder and Spalding (1974), are Cu= trajectory of smoke aerosol particle can be 0.09, C1= 1.44, C2= 1.0, C3= 1.92, k= 1.0 known by representing them in the discrete and = 1.217, respectively. phase The trajectory of particles phase is In equation (23), is the destruction predicted by integration of the force rate, Sp is the shear production and it is balance on this particle, which is calculated calculated from by a Lagrangian frame of reference (Tian et al., 2007; Rigopoulos, 2010; Donde et ui ui ui al., 2013; Raman & Fox, 2016). This force S p tb ( ) (26) x j x j xi balance equates the particle inertia with the forces acting on the particle. So, it can be In equation (23), Bp is the buoyancy presented for the x direction in the production term and it is calculated from Cartesian coordinates, the force balance is calculated from ui ui ui Bp tb ( ) (27) gi p a x j x j xi dVpi FDi Va Vpi (30) dt p In the presence of the theory involved in smoke aerosol particles transport, the only where Vpi is the velocity of particle, gi is of particulate phase of smoke aerosol is a the gravitational acceleration vector, p is very small fraction (less than 0.0001%) of the particle density, FDi is the drag force, its total mass and volume. Bulk properties and it is calculated from of smoke aerosol differ imperceptibly from 3 g Re CD those of pure air. So, one must adopt a FDi (31) 4 p Dp2 microscopic point of view in the study of the properties of smoke aerosols (White, where µg is the velocity of air, Dp is the 1963; Kihm, 1987; Hinds, 1999). particle diameter, Re is the Reynolds By assuming smoke aerosol particle- number, CD is drag efficiency, and it can be laden air is a fluid with the density of air. given by (Haider & Levenspiel, 1989) Diffusion of smoke aerosol particles is determined by the convective diffusion CD 24 1 1 Re 2 3 Re (32) equation and it is given by (Kanaoka et al., Re 4 Re 2006) In this equation, β1, β2, β3, and β4 is the J t a M f xi aVa M f i xi (28) constant value and the Reynolds number (Re) is written as 277
Kalasee, W. and Teekapakvisit, C. a Dp Vpi Va wood combustion. The study of particles Re (33) concentration distribution on modification g of the rubber smoking chamber by CFD technique field is very interesting in the Lu et al. (1996) described the CFD future. technique using a single phase to represent the aerosol particle and air flow. Air CONCLUSION continuity was used to calculate the set of This review focuses on literature findings equations for the control volumes and concerning RSS chamber of community- Lagrangian method was employed in the level rubber cooperatives in Thailand, RSS tracking model of particles. production process and monthly RSS Purba & Tekasakul (2012) presented that production change, Particles size distribution CFD technique was used to examine and particles sampling method, PAHs temperature, velocity, smoke and soot concentration, the particles separation particles concentration, and particles apparatuses reports and the decrease of the trajectories in the rubber smoking chamber. quantity smoke and soot particles by The resulting figures such as pressure, ventilation designed by computational fluid temperature, particle path lines and dynamics (CFD) technique. The following streamline contours are also referred to the are the conclusions and recommendations authors or the publication (Particulate from the review: Science and Technology). The high particles - RSS chamber of community-level concentration occurred above the ceiling rubber cooperatives in Thailand can be areas. However, the particles concentration classified into two models: old and new was decreased along the height in a model. The capacity of each chamber of downward direction. The smoke and soot new model (1995) is double in capacity of particles concentration was largely decreased old model (1994). by a modified ridge vents increasing at roof - Fresh rubber latex is poured to tanks. of the rubber smoking chamber. Water and the acid are added to para- The report of Dejchanchaiwong et al. rubber latex to solidify the latex (tofu-like (2017) has presented that a new rubber slabs). These slabs are then washed and smoking chamber was constructed by the squeezed to form thin layer sheets which designed and simulated model of have a thickness about 3-4 mm by a Tekasakul & Promtong (2008). The squeezing machine. Theses sheets are then resulting figures; hot air velocity and hung on a cart and they are dried in a temperature contours; are also referred to smoke chamber by hot gas from PR wood the authors or the publication (Applied combustion. During the high season, the Thermal Engineering). Although, the Para capacity of the factory is more than 15000 rubber wood consumption, the uniform sheets per week and it has capacity about temperature and hot air velocity, and 7000-11000 sheets per week during the reduction of drying time are the main moderate season (Choosong et al., 2010). objective of this research. But the indirect - In the rubber smoking factory, smoke benefit of this research is the reduction of and soot particles from PR wood smoke and soot particles from Para rubber combustion contribute to pollution in the wood combustion by hot air reusing. industry area, workplace and neighboring Recommendation of this review, CFD atmosphere. Smoke, soot, and PAHs technique is very interesting method to concentration is very high for the furnace, improve the rubber smoking chamber. The chamber and workspace. Cascade CFD technique can be used to decrease impactors such as Andesen sampler are aerosol concentration from Para rubber 278
Pollution, 6(2): 267-284, Spring 2020 equipment for measuring the smoke and CFD technique can be used to decrease the soot particles size distribution from para- Para rubber wood consumption, energy rubber wood combustion. MMAD and decreased by a uniform velocity and GSD of smoke and soot particles were temperature in the smoking chamber found to be 0.95 micron and 2.51, (Promtong & Tekasakul, 2007; Tekasakul & respectively (from Kalasee et al., 2003 Promtong, 2008; Tanwanichkul et al., 2013; report). But the report from Chomanee et Dejchanchaiwong et al., 2014; Tekasakul et al., 2009 presented that MMAD and GSD al., 2015; Dejchanchaiwong et al., 2016 and were found to be 0.68 micron and 3.04, Dejchanchaiwong et al., 2017). respectively after improvement the air This review would be very helpful to condensation. the scientists and researchers who are - PAHs are emitted to an ambient air learning and working on a field in the primarily from the incomplete of fuel aerosol technology, the reduction of smoke combustion. PAHs had two types of poly- and soot particles and PAHs concentration aromatic (PA) molecules: with and without from Para rubber wood combustion, and side chain. PAHs compounds from Para improving the rubber smoking chamber by rubber wood combustion were found 15 CFD technique. different PAHs components (Tekasakul et al., 2005; Furuuchi et al., 2006) and then Conflict of Interest able to be classified in two types: 2-3 rings The authors declare no conflict of interest. and 4-6 rings (Chomanee et al., 2009). - Three aerosol collecting techniques; ACKNOWLEDGEMENTS The authors thank King Mongkut’s filtration by stainless-wire mesh, inertial Institute of Technology Ladkrabang impaction (impaction wall) and ESP; are (KMITL), Prince of Chumphon Campus installed to remove the smoke and soot for giving an opportunity on this research. particles from the Para wood burning. This review indicates that the ESP installing REFERENCES between the furnace and the smoking Adeola, A., Dena, M., John V. and Kerry, M. chamber is suitable to eliminate aerosol (2007). Environmental impact of polynuclear particles at the rubber smoking industry. aromatic hydrocarbons: Extraction of polycyclic Ruttanachot et al. (2011) was improved aromatic hydrocarbon (PAHs) from solid materials. Water Sci. & Tech., 11: 277-294. ESPs technique of the earlier design by Kalasee (2009). Their result was shown Alonso, C., Olson, B., Goyal, S., Raynor, P., Davies, P. and Torremorell, M. (2017). Comparison that the collecting efficiency of ESPs was of two size-differentiating air samplers for detecting higher than 60%. airborne swine viruses under experimental - CFD technique is used to study smoke conditions. Aerosol Sci. Technol., 51: 198–205. and soot particles concentration, flow Amuda, O. and Imeokparia, F. (2007). Polycyclic patterns, and particle motion. Modification of aromatic hydrocarbons in municipal waste ashes the ridge vents increased at roof of the rubber from three waste dumps in Lagos Nigeria. Chem. smoking chamber by CFD modeling and Soc. Ethiopia, 21: 141-144. simulation could decrease the large particles Andersen, A. (1956). Developmental work on the concentration from the Para rubber wood Andersen sampler. (Utah: Dugway Proving Ground combustion at the workplace and Research Report). neighboring atmosphere (Purba & ASTM E11, specifically governs the production of Tekasakul, 2012). In the future, CFD test sieves. technique is very interesting method to Bai, Y., Firuuchi, M., Tekasakul, P., Tekasakul, s., improve the rubber smoking chamber. In Choosong, T., Aizawa, M., Hata, M. and Otani, Y. addition to reduced the aerosol particles, (2007). Application of soft X-rays in the decomposition of polycyclic aromatic hydrocarbons 279
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