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Corrosion-Fatigue Failure of Gas-Turbine Blades in an Oil and Gas Production Plant - MDPI
materials
Article
Corrosion-Fatigue Failure of Gas-Turbine Blades in an
Oil and Gas Production Plant
Mojtaba Rajabinezhad 1 , Abbas Bahrami 1 , Mohammad Mousavinia 2 , Seyed Jalil Seyedi 3 and
Peyman Taheri 4, *
 1   Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran;
     mojtabaa.rajabi22@gmail.com (M.R.); a.n.bahrami@iut.ac.ir (A.B.)
 2   Inspection and Corrosion Engineering Department, Pars Oil and Gas Company (POGC), Assalouyeh
     1414713111, Iran; m.mousavinia1986@gmail.com
 3   National Iranian South Oilfields Company (NISOC), South Turbine Maintenance Centeral Shop, Omidieh
     61735-1333, Iran; jalils198925s@gmail.com
 4   Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD
     Delft, The Netherlands
 *   Correspondence: P.Taheri@tudelft.nl; Tel.: +31-15-278-1683
                                                                                                    
 Received: 10 January 2020; Accepted: 14 February 2020; Published: 18 February 2020                 

 Abstract: This paper investigates the root cause of a failure in gas-turbine blades, made of
 Nimonic-105 nickel-based superalloy. The failure was reported in two blades in the second stage of a
 turbine-compressor of a gas turbine in the hot section. Two failed blades were broken from the root
 and from the airfoil. The failure took place after 20 k h of service exposure in the temperature range
 700–850 ◦ C, with the rotating speed being in the range 15,000–16,000 rpm. The microstructures of the
 failed blades were studied using optical/electron microscopes. Energy dispersive X-ray spectroscopy
 (EDS) was employed for phase identification. Results showed that failure first initiated from the
 root. The dominant failure mechanism in the root was concluded to be corrosion-fatigue. The failure
 scenario was suggested based on the results obtained.

 Keywords: gas turbine; corrosion-fatigue; blades; failure

1. Introduction
       Gas-turbine blades are known to be extremely critical and important components in power plants.
They are expected to operate in harsh working conditions, such as high temperature, high pressure
and complex dynamic loading conditions. Degradation and failure of gas-turbine blades can obviously
have severe negative implications for the integrity and functionality of gas turbines and hence the
output of a power plant. Failures of gas-turbine blades can be due to creep damage, high-temperature
corrosion, high-temperature oxidation, fatigue, erosion, and foreign object damage [1–15]. Obviously,
in most cases the failure is due to the interrelation of more than one failure mechanism [2]. As a case
in point, creep and fatigue can simultaneously result in failure in gas-turbine blades [2]. Increasing
the operating temperature in gas turbines has always been a target, given that any increase in service
temperature is associated with an increase in the efficiency and output of a turbine.
       Among different candidate materials for harsh high-temperature working conditions in turbines,
nickel- and cobalt-based superalloys have long been known as the best options on the grounds that
these alloys are capable of working at high temperature, while they keep their properties [16]. These
alloys benefit from a unique and exceptional combination of high-temperature mechanical properties
(i.e., superior creep resistance), excellent resistance to high-temperature degradation/oxidation, and
superior microstructural stability during high-temperature service [17]. Nickel-based superalloys

Materials 2020, 13, 900; doi:10.3390/ma13040900                               www.mdpi.com/journal/materials
Corrosion-Fatigue Failure of Gas-Turbine Blades in an Oil and Gas Production Plant - MDPI
Materials 2020, 13, 900                                                                                2 of 8

are extensively used in critical components in aerospace and gas-turbine engines. In fact, about
50 wt.% of aero/gas turbine-engines are made of nickel-based superalloys [18]. Other applications
of nickel-based superalloys include chemical/petrochemical plants, high-temperature reactors, and
marine applications. Different grades of nickel-based superalloys are now currently used in different
applications, amongst which Inconel 718 is one of the most widely used. Other widely used grades
include FGH95, ME-16, RR1000, IN-100, Udimet 720LI, Nimonic 80A, Inconel 825, Nimonic C-263,
Nimonic-75, and Nimonic-105 [19]. The latter alloy is extensively used in hot combustion chambers of
gas turbines [20], with service temperatures being as high as 950 ◦ C. Nimonic-105 is often cast in air.
For more demanding and sensitive applications, vacuum melting is highly recommended.
      This research investigates a failure in gas-turbine blades in the second stage of a turbine-compressor
of a gas turbine (i.e., the gas producer or hot section) in an oil and gas production plant. The failed
blades were made of Nimonic-105 nickel-based superalloy. The main focus in this investigation is on the
microstructural and metallurgical aspects of the failure. Even though the consequences of failures in the
third row might not be as severe as those in the first and second rows, they need to be evaluated and
analyzed carefully. Failures of blades in a gas turbine are often catastrophic in the sense that this causes
severe damages in the turbine, associated with a significant economic loss. Therefore, it is necessary
to conduct a failure investigation to analyze the root cause of failure and eventually to mitigate similar
failures in any oil- and gas-production and power plants. This certainly has positive implications for the
system reliability and service life of a gas turbine. Lessons learnt from a failure study will certainly be
useful in planning failure mitigation strategies in similar plants/set-ups [21–30]. It will be shown that the
failure, reported in this study, is a corrosion-fatigue failure. Given that not so many corrosion-fatigue
failures have been reported in the literature, this manuscript will certainly be useful, especially when it
comes to analyzing/controlling the same form of damage in similar gas turbines.

2. Experimental
     The microstructural analyses in this case were performed using scanning electron microscopy (SEM,
Philips, Eindhoven, The Netherlands) and optical microscopy (OM, Nikon, Japan). Energy-dispersive
X-ray spectroscopy (Philips, The Netherlands) was employed to study chemical compositions of
different phases in the microstructure. Failed blades were first visually evaluated. Macro images were
then taken by Stereo Microscope Nikon SMZ 800 (Nikon, Tokyo, Japan). For optical microscopy, samples
were first ground with grinding papers. Samples were then polished with diamond paste (3 and 1 µm).
Fractography was also performed on failed specimens to determine dominant failure mechanisms.

3. Case Background
      This failure is related to a gas turbine where its input air volume can be as high as 5220 m3 /h.
Approximately 40% of this sucked-in air is used for combustion. The sucked-in air pressure is close to
100 psi. The combustion air to fuel ratio is 15. The fuel is a methane/ethane gas mixture which has
been dried before entering into the gas turbine. The failure in this case was in blades in the second
stage in which 69 blades are assembled on a disk. Based on the available specification, blades are
made of Nimonic-105. Nickel-based rotating blades are expected to operate under extreme working
conditions, where erosion and corrosion phenomena come into play. Besides, blades in nickel-based
superalloys in aggressive working conditions are expected to show great resistance against cavitational
erosion. Blades in the second stage are expected to have service life over 100 k h up to 120 k h. In this
case, blades failed after approximately 20 k h service, which makes this failure a typical premature
incident. A major drawback of having a blade fail in a whole assembly is that all the blades have to
be replaced with brand new blades or blades with similar service lifetime. This has to do with the
fact that it is a routine practice to make sure all blades are in similar conditions in terms of service
life. This makes the interpretation of non-destructive testing (NDT) results much easier. The working
temperature in the hot section of the turbine is 700–850 ◦ C. The rotating speed of the blades is in
Corrosion-Fatigue Failure of Gas-Turbine Blades in an Oil and Gas Production Plant - MDPI
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the range   15,000–16,000
      Materials                 rpm.
                2020, 9, x FOR PEER   The blades are made of Nimonic-105 nickel-based superalloy3with
                                    REVIEW                                                       of 8 the
following chemical composition (Table 1).
      easier. The working temperature in the hot section of the turbine is 700–850 °C. The rotating speed of
      the blades is Table
                    in the1.range 15,000–16,000
                             Chemical           rpm.
                                       composition    The blades are
                                                   of Nimonic-105      made of Nimonic-105
                                                                    nickel-based  superalloy. nickel-based
      superalloy with the following chemical composition (Table 1).
   Element      C     Si     Cu      Fe    >Mn        Cr       Ti       Al      Co       Mo       Zr      Ni
                           Table 1. Chemical composition of Nimonic-105 nickel-based superalloy.
    wt. %        0.1   0.5       0.1     0.5       0.6      15.0  1.0            4.5  19.0          5.0    0.1          Bal.
                    Element       C    Si Cu       Fe    Mn Cr     Ti         Al Co Mo            Zr Ni
                     wt. %       0.1   0.5 0.1     0.5   0.6 15.0 1.0         4.5 19.0 5.0        0.1 Bal.
4. Results and Discussion
      4. Results
4.1. Visual      and Discussion
            Observations
      4.1. Visual
      The         Observations
           reported    failure in this case was related to two turbine blades as shown in Figure 1, with one
failing fromThe reportedand
               the   root        the in
                            failure   other
                                        this from   therelated
                                              case was  airfoil.toThese    two blades
                                                                     two turbine    bladeswere    located
                                                                                            as shown         in the1,vicinity
                                                                                                        in Figure       with of
each other.   There
      one failing      arethe
                    from    a few
                              root observations      worth
                                    and the other from    thementioning.       Firstblades
                                                               airfoil. These two     of all,were
                                                                                              there   was no
                                                                                                   located      severe
                                                                                                            in the       surface
                                                                                                                    vicinity
corrosion   on other.
      of each   eitherThere
                         side ofarethe  blades,
                                     a few        except for
                                             observations       a brownish
                                                             worth             spotFirst
                                                                      mentioning.     shown     in Figure
                                                                                           of all,  there was1. This    does not
                                                                                                                 no severe
appearsurface
         to becorrosion
                 a severely on corroded
                                either side spot.
                                             of the Also,
                                                     blades,there
                                                              exceptwasfor no
                                                                           a brownish
                                                                               excessive spot  shown in Figure
                                                                                             deformation      (i.e., 1. This
                                                                                                                      noticeable
thinning or buckling) in the profile of the failed airfoil. One can also see that there was no(i.e.,
      does   not  appear   to  be  a severely   corroded    spot.  Also,  there  was   no  excessive    deformation      surface
      noticeable
irregularity       thinning
              observed     inor  buckling)
                               the           in the profile
                                   failed blades.            of the failed
                                                     This includes         airfoil.
                                                                        surface     One canor
                                                                                 cracking     also  see that
                                                                                                 pitting.  Inthere
                                                                                                               one was
                                                                                                                     edgenoof the
failedsurface
       airfoil,irregularity
                one can seeobserved       in the failed blades. This includes surface cracking or pitting. In one
                                a dent, which     seems to be due to the collision of a high-energy flying object.
      edge of the failed airfoil, one can see a dent, which seems to be due to the collision of a high-energy
The last important visual observation to mention is that the fracture in the airfoil has two areas: the flat
      flying object. The last important visual observation to mention is that the fracture in the airfoil has
surface  and the part with 45-degree inclination. This is clearly shown in Figure 1c.
      two areas: the flat surface and the part with 45-degree inclination. This is clearly shown in Figure 1c.

      FigureFigure   1. Visual
               1. Visual       observation
                          observation    of of brokenblade,
                                            broken      blade,(a)
                                                               (a)and
                                                                   and overview
                                                                       overview ofofblades
                                                                                     bladesin in
                                                                                               thethe
                                                                                                   assembled condition,
                                                                                                      assembled condition,
            (b) failed
      (b) failed  bladeblade
                         fromfrom
                                the the root,
                                    root, andand  (c,d)
                                               (c,d)    brokenblade
                                                     broken      bladefrom
                                                                       from the
                                                                            the airfoil.
                                                                                airfoil.

      4.2. Microstructure
4.2. Microstructure       of Failed
                      of Failed     Blades
                                Blades
          Figure
     Figure       2 depicts
             2 depicts  the the typical
                             typical    microstructurein
                                     microstructure    in the
                                                           the failed
                                                               failed blades.
                                                                      blades.The
                                                                              Themicrostructure
                                                                                  microstructureis a is
                                                                                                     typical
                                                                                                        a typical
     dendritic cast structure where dendrites have grown from two sides towards the centerline of the
dendritic cast structure where dendrites have grown from two sides towards the centerline of the blade,
     blade, as expected. Fine white particles in-between dendrites are carbide particles.
as expected. Fine white particles in-between dendrites are carbide particles.
Corrosion-Fatigue Failure of Gas-Turbine Blades in an Oil and Gas Production Plant - MDPI
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                              Figure
                           Figure     2. (a)
                                  2. (a)     Macro
                                          Macro    and(b)
                                                 and   (b)optical
                                                           optical microscope
                                                                   microscope images
                                                                               imagesofof
                                                                                       failed blades.
                                                                                          failed blades.

4.3. Fractography
      4.3. Fractography of Figure
                    of Failed     2. (a) Macro and (b) optical microscope images of failed blades.
                               Blades
                           Failed Blades

     Figure  Figure
                3 shows3 shows
       4.3. Fractography            stereomicroscope
                              stereomicroscope
                               of Failed  Blades        andand SEM SEM   micrographsofofthe
                                                                      micrographs                thefracture
                                                                                                      fracturesurface
                                                                                                                  surface from
                                                                                                                             from the
                                                                                                                                    the blade
                                                                                                                                          blade that
      that   failed   from    the   root.  As  shown      in Figure    3a,  the   fracture    surface
failed from the root. As shown in Figure 3a, the fracture surface has two areas: the dominant grayish    has   two    areas:  the   dominant
      grayish Figure
                  area3 and
                          shows  thestereomicroscope
                                       rest of the surface.  and SEM
                                                                   This micrographs          of the fracture
                                                                          is a typical fracture          surfacesurface
                                                                                                                     when fromfatiguetheisblade
                                                                                                                                             the
area and
       that the  restfrom
             failed     of the thesurface.
                                    root.   AsThis
                                                shownis aintypical
                                                              Figure  fracture
                                                                        3a,  the   surface surface
                                                                                  fracture     when fatigue
                                                                                                          has  two  isareas:
                                                                                                                       the governing
                                                                                                                               the  dominant damage
      governing damage mechanism. Figure 3b,c show SEM micrographs of two areas, highlighted in
mechanism.
       grayish3a. Figure
                  area        3b,ctheshow     SEM themicrographs    This ofis two     areas,fracture
                                                                                               highlighted inwhen      Figure 3a. The         former
      Figure          Theandformer     rest of
                                       image    (Figure surface.
                                                            3b) shows          a typical
                                                                          typical     beach marks, surfaceindicating thatfatiguefatigue isis the
                                                                                                                                              an
imageactive
        (Figure
       governing     3b)  shows
                       damage        typical
                                    mechanism.  beach
                                                    Figuremarks,
                                                               3b,c  indicating
                                                                      show    SEM    that   fatigue
                                                                                       micrographs      isof
               mechanism. Further down to the edge, there is a clear change in the fracture surface (Figure an  active
                                                                                                              two         mechanism.
                                                                                                                     areas,   highlighted     Further
                                                                                                                                               in
down3c).to the
            The surface at the edge of the failed blade is covered with some deposits, which were analyzed of
       Figure    edge,
                 3a.  The there
                             former is a  clear
                                        image    change
                                                 (Figure     in
                                                            3b)  the  fracture
                                                                  shows    typical surface
                                                                                       beach   (Figure
                                                                                               marks,       3c).  The
                                                                                                           indicating    surface
                                                                                                                          that      at
                                                                                                                                fatigue theis edge
                                                                                                                                               an
       active
the failed
      by EDS.   mechanism.
              blade            of Further
                       is covered
                  Results          EDSwith   down
                                               some
                                         analysis     todeposits,
                                                     of   the microstructure
                                                         the   edge,which
                                                                       there iswereaatclear  change
                                                                                         analyzed
                                                                                        the             in
                                                                                                        bythe
                                                                                             edge (presented EDS.fracture
                                                                                                                     Results
                                                                                                                     in      surface
                                                                                                                         Figure  of4)EDS(Figure
                                                                                                                                      showedanalysis
       3c).
of thethat  The   surface
        microstructure
             surface deposits at  the
                                at the edge
                                     areedge  of  the  failed
                                                (presented
                                          rich in               blade
                                                    Cl, K, Na,inand    is covered
                                                                     Figure            with
                                                                                4) showed
                                                                         Ca. This,            some
                                                                                       together that
                                                                                                   withdeposits,
                                                                                                       surface      which
                                                                                                                   deposits
                                                                                                            the fact          were
                                                                                                                       that there    analyzed
                                                                                                                                 areisrich   in Cl, K,
                                                                                                                                         a high
Na, andby EDS.
      concentrationResults
            Ca. This,     of   of EDS in
                              oxygen
                           together       analysis
                                            the the
                                         with        of  thethat
                                                 analysis,
                                                      fact     microstructure
                                                              indicates
                                                                    therethat       at the
                                                                             is athese
                                                                                   high      edge are
                                                                                         deposits    (presented
                                                                                           concentration              in  Figureproducts.
                                                                                                           in factofcorrosion
                                                                                                                      oxygen       4)the
                                                                                                                                  in   showed   It
                                                                                                                                            analysis,
       that
      is     surface
         highly         deposits
                   likely   that     are
                                   the     rich in Cl, K, Na,
                                        aforementioned              and Ca.
                                                              elements    come This,
                                                                                   from together
                                                                                          the       with the fact that there is a high
                                                                                                fuel/gas.
indicates that these deposits are in fact corrosion products. It is highly likely that the aforementioned
       concentration of oxygen in the analysis, indicates that these deposits are in fact corrosion products. It
elements come from the fuel/gas.
        is highly likely that the aforementioned elements come from the fuel/gas.

             Figure 3. (a) Stereomicroscope and (b,c) scanning electron microscope (SEM) micrographs of the
             fracture surface of the blade, failed from the root.
       FigureFigure
                3. (a)3.Stereomicroscope
                         (a) Stereomicroscope  andand(b,c)
                                                        (b,c)scanning
                                                              scanning electron
                                                                       electron microscope
                                                                                microscope(SEM) micrographs
                                                                                            (SEM)           of the
                                                                                                  micrographs    of the
              fracture
       fracture        surface
                 surface        of blade,
                           of the  the blade, failed
                                          failed      from
                                                   from     theroot.
                                                          the   root.
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       FigureFigure 4. Energy
               4. Energy      dispersive
                          dispersive     X-ray
                                      X-ray     spectroscopy(EDS)
                                             spectroscopy    (EDS) analysis
                                                                   analysis ofofcorrosion
                                                                                 corrosionproducts at the
                                                                                            products      edgeedge
                                                                                                       at the  of of
             broken4.blade.
            Figure     Energy dispersive X-ray spectroscopy (EDS) analysis of  corrosion  products at the edge of
       broken blade.
              broken blade.
              Results of EDS analysis of the microstructure further away from the edge is presented in Figure
     Results of EDS analysis of the microstructure further away from the edge is presented in Figure 5.
      5. There is hardly
          Results  of EDSany   oxygen,
                            analysis      Na,microstructure
                                      of the  Ca, K, and Cl in the analysis, inferring that  the aforementioned
There is hardly    any    oxygen,   Na,   Ca, K, and Cl infurther   away from
                                                             the analysis,      the edge
                                                                              inferring   is presented
                                                                                         that          in Figure
                                                                                               the aforementioned
      corroded  area  is limited to few   hundred micrometers   from the edge.
     5. There is hardly any oxygen, Na, Ca, K, and Cl in the analysis, inferring that the aforementioned
corroded area is limited to few hundred micrometers from the edge.
       corroded area is limited to few hundred micrometers from the edge.

                   Figure 5. EDS analysis of the area with beach marks in the failed blade, broken from the root.
                Figure
            Figure     5. EDS
                   5. EDS     analysis
                           analysis of of
                                       thethe areawith
                                            area   withbeach
                                                        beach marks
                                                              marks in
                                                                     inthe
                                                                        thefailed
                                                                            failedblade, broken
                                                                                    blade,      from
                                                                                           broken    the root.
                                                                                                   from  the root.
             From the results obtained, it can be concluded that the failure in the blade, broken from the root,
       was From
             controlled     by the    simultaneous         activation of      corrosion      and    fatigue.      Corrosion-fatigue       is a
     From the the        results
                    results        obtained,
                               obtained,     itit can
                                                  can be beconcluded
                                                             concluded    that    the the
                                                                               that   failure   in the
                                                                                            failure      blade,
                                                                                                        in   the broken
                                                                                                                    blade, from
                                                                                                                              brokenthe root,
                                                                                                                                         from the
       common       degradation       mechanism         in  moving      components          exposed
      was controlled by the simultaneous activation of corrosion and fatigue. Corrosion-fatigue is a      to    high-temperature        harsh
root, was    controlled
       working              by [21].
                   conditions     the simultaneous
                                        Corrosion fatigue   activation
                                                                essentially  oftakes
                                                                                  corrosion
                                                                                        place    and fatigue.
                                                                                                under                 Corrosion-fatigue      of is a
      common        degradation      mechanism         in moving        components         exposed       tothehigh-temperature
                                                                                                                 synergistic   activation
                                                                                                                                        harsh
common      degradation
       corrosion              mechanism
                    and dynamic                inThis
                                                    moving     components           exposed      toofhigh-temperature            harsh
                                                                                                                                 reasonsworking
      working    conditions     [21].loading.
                                       Corrosion         degradation
                                                      fatigue  essentiallymechanism
                                                                                takes placeis one
                                                                                                under  thethemost    common
                                                                                                                synergistic    activation   for
                                                                                                                                             of
conditions    [21].
       the failureand
      corrosion       Corrosion
                     of turbine      fatigue
                         dynamicblades
                                     loading.   essentially
                                            [22].
                                                ThisCorrosion   takes
                                                                  fatigue
                                                        degradation       place     under
                                                                             is undoubtedly
                                                                         mechanism           the
                                                                                          is one ofsynergistic
                                                                                                   onetheofmost       activation
                                                                                                               the most
                                                                                                                     common complex  of
                                                                                                                                reasons corrosion
                                                                                                                                       failure
                                                                                                                                           for
and dynamic
      the  failureloading.
       mechanisms.      Both This
                     of turbine       degradation
                               mechanical
                                   blades     andCorrosion
                                           [22].          mechanism
                                                     chemical    aspectsis
                                                                 fatigue    ofone
                                                                            is       of the
                                                                                 failure       most
                                                                                          in this
                                                                                undoubtedly            common
                                                                                                    case
                                                                                                  one    ofare
                                                                                                             theequally
                                                                                                                   mostreasons    for failure
                                                                                                                            important.
                                                                                                                           complex     theAnyfailure
       mitigation
of turbine   blades
      mechanisms.    measure
                       [22].     to avoid this
                              Corrosion
                        Both mechanical      and   failure
                                              fatigue     isnecessitates
                                                     chemicalundoubtedly
                                                                aspects of   a multi-disciplinary
                                                                                   one of
                                                                                failure  in the    case approach.
                                                                                             thismost            equallyCorrosion-fatigue
                                                                                                            complex
                                                                                                           are            failure  mechanisms.
                                                                                                                           important.    Any
       failure of the
Both mitigation
      mechanical         bladechemical
                        and
                     measure     root
                                to     in this
                                    avoid       case
                                            aspects
                                           this         has
                                                  failure   possiblyin
                                                         ofnecessitates
                                                            failure      originated
                                                                           this    casefrom      corrosion
                                                                                          are equally
                                                                            a multi-disciplinary                 pits/products
                                                                                                              important.
                                                                                                         approach.             Anydeposited
                                                                                                                                      mitigation
                                                                                                                         Corrosion-fatigue
measureat the
            to root/airfoil
      failure  of
                avoid    thisinterface.
                   the blade               Thecase
                                root in this
                               failure           results
                                          necessitates has showed
                                                            possibly   that   corrosion
                                                                         originated
                                                             a multi-disciplinary       fromproducts/deposits
                                                                                                corrosion pits/products
                                                                                              approach.                 in this case  mostly
                                                                                                                                  deposited
                                                                                                                  Corrosion-fatigue         failure
       contained
      at             CaO, Na
         the root/airfoil      2O, KCl, The
                             interface.   and results
                                                NaCl. The      sensitivity
                                                           showed              of turbineproducts/deposits
                                                                      that corrosion          blades to corrosion-fatigue
                                                                                                                       in this caseinitiation
                                                                                                                                      mostly
of the blade root in this case has possibly originated from corrosion pits/products deposited at the
      contained
root/airfoil     CaO, Na
             interface.  2O, KCl, and NaCl. The sensitivity of turbine blades to corrosion-fatigue initiation
                        The results showed that corrosion products/deposits in this case mostly contained
CaO, Na2 O, KCl, and NaCl. The sensitivity of turbine blades to corrosion-fatigue initiation largely
depends on the integrity of the passive film on the surface [22]. The breakdown of this passive film
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together with the deposition of oxide/corrosion deposits create an ideal condition for corrosion-fatigue
     largely depends
     largely    depends on     on the
                                    the integrity
                                           integrity of   of the
                                                              the passive
                                                                    passive film film onon thethe surface
                                                                                                    surface [22].
                                                                                                                [22]. The The breakdown
                                                                                                                                  breakdown of         of this
                                                                                                                                                             this
crackpassive
      initiation.film The     film breakdown
                        together      with     the       and deposition
                                                     deposition       of           of corrosion
                                                                          oxide/corrosion               products
                                                                                                   deposits      createcausesan      anodic/cathodic
                                                                                                                                  ideal      condition         for sites,
     passive film together with the deposition of oxide/corrosion deposits create an ideal condition for
leading   to an accelerated
     corrosion-fatigue          crack localized
                                         initiation. Theanodic filmdissolution
                                                        The film       breakdown and     reaction
                                                                                        and              and, hence,
                                                                                                deposition       of corrosion
                                                                                                                     corrosionlocalized products  corrosion
                                                                                                                                                       causes [23].
     corrosion-fatigue         crack    initiation.                   breakdown                 deposition       of                    products        causes
The formation
     anodic/cathodicof  corrosion-induced
                              sites,   leading      to  surface
                                                        an           irregularities
                                                             accelerated        localized creates
                                                                                                anodic
     anodic/cathodic sites, leading to an accelerated localized anodic dissolution reaction and, hence, stress   riser
                                                                                                           dissolution     centers
                                                                                                                               reaction   on    the
                                                                                                                                               and,   surface
                                                                                                                                                        hence, [24].
In case  these    surface
     localized corrosion
     localized                 irregularities
                   corrosion [23].[23]. The
                                          The formationexceed
                                                 formation of      a  critical     size,
                                                                of corrosion-induced      a
                                                                    corrosion-induced surfacefatigue       crack    is
                                                                                                 surface irregularities  likely
                                                                                                            irregularities creates   to   initiate.
                                                                                                                                    creates stressstressTherisercrack
                                                                                                                                                           riser
     centers on
then centers
     propagates on the
                     theunder
                          surface
                          surface     [24]. In
                                   dynamic
                                      [24].    In case
                                                  case
                                                   loadingthesecondition,
                                                         these    surface irregularities
                                                                  surface     irregularities
                                                                                   finally leading exceedthe
                                                                                                  exceed     aa critical
                                                                                                                critical     size,
                                                                                                                  failuresize,  of theaa fatigue
                                                                                                                                         fatigue
                                                                                                                                             turbine  crack
                                                                                                                                                      crackblade.is
                                                                                                                                                                is
     likely to
     Figure
     likely   to6 initiate.
                  initiate.    The crack
                                      crack then
                   shows stereomicroscope/SEM
                               The              then propagates
                                                        propagates        under dynamic
                                                                      micrographs
                                                                          under      dynamicof the loading     condition,
                                                                                                        fracture
                                                                                                   loading                        finally
                                                                                                                      surfacefinally
                                                                                                               condition,                       leading
                                                                                                                                     of theleading sample,    thefailed
                                                                                                                                                              the
     failure
from failure   of the
               of
      the airfoil  the  turbine
                        turbine
                      (see    Figure blade.
                                     blade.
                                          1c,d). SEM micrographs, shown from different areas, indicate that there is
            Figure 66 shows
                         shows stereomicroscope/SEM
                                    stereomicroscope/SEM micrographs    micrographs of the      the fracture
                                                                                                      fracture surface
                                                                                                                  surface of   of the
                                                                                                                                    the sample,
                                                                                                                                           sample, failed
hardly any difference between fracture modes in differentofareas.
           Figure                                                                                       More importantly,                  there is failed
                                                                                                                                                         absolutely
     from the
     from   the airfoil
                  airfoil (see
                            (see Figure
                                   Figure 1c,d).
                                              1c,d). SEM
                                                       SEM micrographs,
                                                               micrographs, shown   shown from from different
                                                                                                       different areas,
                                                                                                                     areas, indicate
                                                                                                                                indicate that  that there
                                                                                                                                                      there is   is
no indication that fatigue has been an active mechanism in this blade, i.e., there is no beach mark                                                               on the
     hardly any
     hardly     any difference
                        difference betweenbetween fracture
                                                        fracture modesmodes in     in different
                                                                                       different areas.areas. More
                                                                                                                 More importantly,
                                                                                                                             importantly, there      there is    is
fracture  surface.noFigure
     absolutely           indication 7 shows        SEM micrographs
                                            that fatigue
                                                   fatigue     has been
                                                                     been an       of
                                                                             an active the mechanism
                                                                                   active   fracture surface        thiswith
                                                                                                               in this      blade, higher         magnification,
                                                                                                                                         i.e., there
                                                                                                                                                 there    is nono
     absolutely      no indication          that               has                          mechanism in                    blade,      i.e.,            is
againbeach
       confirming
     beach mark
              mark on     that
                       on the     there
                             the fracture   is  no
                                   fracture surface. fatigue
                                                surface. Figure  involved
                                                             Figure 77 shows      in
                                                                           shows SEM  this   case.
                                                                                      SEM micrographs   Fracture
                                                                                              micrographs of          in
                                                                                                                  of the    this
                                                                                                                       the fracture sample
                                                                                                                              fracture surface      has with
                                                                                                                                              surface      elements
                                                                                                                                                           with
of ductile
     higherand
     higher         brittle fractures.
               magnification,
               magnification,         again       There arethat
                                      again confirming
                                                confirming        some
                                                                 that       areas
                                                                        there
                                                                        there        nowith
                                                                                 is no
                                                                                 is     fatigue
                                                                                        fatigue colonies
                                                                                                     involved
                                                                                                     involved of dimples
                                                                                                                   in this
                                                                                                                   in  this case.
                                                                                                                               case.and       some in
                                                                                                                                         Fracture
                                                                                                                                         Fracture       areas
                                                                                                                                                        in   this with
                                                                                                                                                            this
cleavage
     sample
     samplefracture.
                has       The fact
                has elements
                      elements       ofthat
                                     of  ductilethere
                                          ductile    and
                                                     and is brittle
                                                            no fatigue
                                                            brittle          in this
                                                                      fractures.
                                                                      fractures.        blade
                                                                                      There
                                                                                     There      areissome
                                                                                               are     indicative
                                                                                                     some     areas with
                                                                                                              areas     that this
                                                                                                                       with      colonies
                                                                                                                                 coloniesblade   ofhas
                                                                                                                                                 of        fractured
                                                                                                                                                     dimples
                                                                                                                                                     dimples
     and
due to
     and   some areas
        a sudden
           some     areas    with cleavage
                       overloading
                             with    cleavage      fracture.
                                              and/or            The fact
                                                          collision.
                                                   fracture.    The    fact
                                                                          Thethat
                                                                            that    there is
                                                                                  logical
                                                                                    there   isfailure
                                                                                                no fatigue
                                                                                                no   fatigue    in this
                                                                                                          scenario
                                                                                                               in   thisisblade
                                                                                                                            blade
                                                                                                                             that is   is indicative
                                                                                                                                       theindicative
                                                                                                                                              blade that    thatfailed
                                                                                                                                                            that
     this
     this  blade
           blade    has
                    has   fractured
                          fractured       due
                                          due    to
                                                 to aa sudden
                                                       sudden      overloading
                                                                   overloading         and/or
                                                                                      and/or      collision.
                                                                                                 collision.
from the root has first undergone a corrosion-fatigue failure. The broken piece has then hit the adjacent       The
                                                                                                                The    logical
                                                                                                                       logical      failure
                                                                                                                                    failure       scenario
                                                                                                                                                  scenario       is
                                                                                                                                                                is
     that
     that
blade,     the
        causing  blade
           the blade       that
                     thethat      failed
                                  failedof
                            fracture         from
                                            from     the
                                               the the
                                                     blade root  has
                                                           rootfrom     first
                                                                 has first     undergone
                                                                               undergone
                                                                         the airfoil.            a
                                                                                           Thea dentcorrosion-fatigue
                                                                                                    corrosion-fatigue
                                                                                                            observed atfailure.  failure.
                                                                                                                                   the edge    The     broken
                                                                                                                                               Theofbroken
                                                                                                                                                         the airfoil
     piece has
     piece   has then
                    then hithit the
                                 the adjacent
                                        adjacent blade,
                                                      blade, causing
                                                                causing the  the fracture of     of the blade
                                                                                                           blade fromfrom the  the airfoil.
                                                                                                                                       airfoil. The The dent
                                                                                                                                                           dent
(highlighted      in Figure       1c,d) has possibly             formed as fracture a result ofthe     a collision       between            the flying          broken
     observed      at  the    edge    of  the   airfoil    (highlighted       in   Figure    1c,d)    has
     observed at the edge of the airfoil (highlighted in Figure 1c,d) has possibly formed as a result of    possibly       formed         as   a  result    of aa
piece and the airfoil.
        collision between
        collision between the
                          the flying
                              flying broken
                                     broken piece
                                            piece and
                                                  and the
                                                      the airfoil.
                                                          airfoil.

                                Figure
                             Figure
                                Figure  6. Images
                                       6.  Images
                                    6. Images     offracture
                                                ofof  fracturesurface
                                                      fracture surface of
                                                               surface of the
                                                                       of the blade,
                                                                           theblade, broken
                                                                               blade,broken
                                                                                      brokenfrom  thethe
                                                                                               from
                                                                                            from  the airfoil.
                                                                                                          airfoil.
                                                                                                      airfoil.

                     Figure
                     Figure
                 Figure     7. (a,b)
                            7. (a,b)
                        7. (a,b)  SEMSEM
                                     SEM micrographsof
                                         micrographs
                                       micrographs   offracture
                                                     of fracture surface
                                                        fracture surface of
                                                                 surfaceof  the
                                                                          ofthe blade,
                                                                             theblade, broken
                                                                                       broken
                                                                                  blade,      from
                                                                                              from
                                                                                         broken    the airfoil.
                                                                                                   the
                                                                                                 from  airfoil.
                                                                                                       the  airfoil.
Materials 2020, 13, 900                                                                                           7 of 8

5. Concluding Remarks
     This paper investigates a failure in gas-turbine blades made of Nimonic-105 nickel-based superalloy.
Two broken blades were investigated, with one having failed from the root and the other from the
airfoil. Blades are from the second row of the gas producer/hot section of a gas turbine with working
temperature being in the range 700–850 ◦ C and rotating speed in the range 15,000–16,000 rpm. The
failure was reported after 20 k hours of service, which is much shorter than the anticipated service life.
The following conclusions can be drawn, based on the data obtained:

−     Nimonic-105 superalloy in this case had a typical dendritic cast structure, with dendrites growing
      from the edges towards the center.
−     There were no surface irregularities, excessive deformation, buckling, or surface cracking observed
      on the surface of the blades, except for a dent on the edge of one of the broken blades.
−     Results showed that corrosion fatigue is the governing failure mechanism in the blade that failed
      from the root. In this case, there are corrosion deposits at the edge of the blade, rich in Cl, Ca, O,
      Na, and K. Fatigue cracks have initiated from corroded spots at the edge of the blade.
−     Fractography of the blade that failed from the airfoil showed that, contrary to the former case,
      there is hardly any fatigue involved in the failure of this blade.
−     It was concluded that the blade that failed from the root first underwent a corrosion-fatigue
      failure, finally ending up in the breakage of the airfoil from the root. The broken piece then hit
      the adjacent blade in its trajectory, causing the fracture of the adjacent blade from the airfoil. The
      dent observed at the edge of the airfoil possibly formed as a result of the collision between the
      flying broken piece and the airfoil.
−     Given that both corrosion and fatigue mechanisms were involved in this failure, it is important to
      minimize mechanical vibrations and to reduce contaminants in the system. The latter necessitates
      further investigation on the origins of the Cl, Na, and Ca-containing residues and how they can
      be controlled/eliminated from the system.

Author Contributions: Conceptualization, M.R. and M.M.; methodology, M.R., S.J.S. and A.B.; formal analysis,
A.B., S.J.S. and M.M.; investigation, M.R. and M.M.; writing—original draft preparation, A.B.; writing—review
and editing, A.B. and P.T.; visualization, A.B.; supervision, A.B., M.M. and P.T.; project administration, P.T. All
authors have read and agreed to the published version of the manuscript.
Funding: This research received no external funding.
Acknowledgments: Authors would like to thank Delft University of Technology for support in publishing
this manuscript.
Conflicts of Interest: The authors declare no conflict of interest.

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