Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
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Electrical Generation of Spin Currents Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University Funding: Energy Frontiers Research Center Quantum-Materials for Energy Efficient Neuromorphic-Computing SPICE-SPIN+X Seminar: June 16th, 2021 1
Electrical Generation of Spin Currents Chris Safranski, IBM Jonathan Sun, IBM Jun-Wen Xu, NYU Haowen Ren, NYU Laura Rehm, NYU C. Safranski et al., PRL 124, 197204 (2020) L. Rehm et al., APL 115, 182404 (2019) L. Rehm et al., PR Appl. 15, 034088 (2021) SPICE-SPIN+X Seminar: June 16th, 2021 2
Electrical Generation of Spin Currents Outline • Introduction: Spin torques and spin-orbit torques • Charge-to-spin conversion efficiency in switching perpendicular magnetic tunnel junction nanopillars • Planar Hall effect spin torques SPICE-SPIN+X Seminar: June 16th, 2021 3
Electrical Generation of Spin Currents Outline • Introduction: Spin torques and spin-orbit torques • Charge-to-spin conversion efficiency in switching perpendicular magnetic tunnel junction nanopillars • Planar Hall effect spin torques SPICE-SPIN+X Seminar: June 16th, 2021 4
NYU Physics Prize Prediction 2013 Oliver of Spin-Transfer E. Buckley CondensedTorques Matter Physics Priz 2013 Oliver E. Buckley Prize 2013 Oliver E. Buckley Condensed Matter Physics Priz John Slonczewski s Citation: Luc Berger "For predicting spin-transfer torque and opening the field of current- ws Carnegie induced Mellon University Citation: control over magnetic nanostructures." ureships “For predicting Citation: spin-transfer torque and opening the field of current-induced control over magnetic Background: nanostructures.” "For predicting spin-transfer torque and opening the field of current-induced contro ureships John Slonczewski received over magnetic nanostructures." Foundational papers: the Physics BS at Worcester Polytechnic Institute in 1950 J. C. Slonczewski, Phys. and Rev. B.the Physics 39, 6996 (1989) PhD at Rutgers University in 1955. He J. C. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996) pursued Background: L. solid-state Berger, Phys. theory Rev. B 54, 9353 (1996) as Research Staff Member in IBM from 1955 s, until retiring in 2002. He was located at Yorktown Heights, NY USA, hips except Luc Berger for sabbaticals 1933-May-02 in 1965-6, Emeritus 1970-1, andof professor 1987 at Rueschlikon, Physics Carnegie Mellon Universit s, Switzerland. 5000 Forbes Avenue Pittsburgh, PA 15213 B.Sc., Mathematical Sciences, U. of hips His SPICE-SPIN+X Seminar research Lausanne, in 1955. solids Ph.D., included Physics, fundamental U. of theories Lausanne, of 1960. graphite bands, Postdoctoral research 5
NYU Prediction of Spin-Transfer Torques The spin-up electrons are those with spin orientati electrons have anti-parallel alignment with the exte polarizations of the two ferromagnets, P1 and P2: If no voltage is applied to the junction, electrons tunn tunnel preferentially to the positive electrode. With can be described in a two-current model. The total cur another for the spin-down electrons. These vary depen J. C, Applications: SLONCZE~S~ New types of MRAM In magnetic tunnel junctions There are two possibilities to obtain a defined anti-pa 1.2 —ik (by using different materials or different film thickne &p 0.8 antiferromagnet (exchange ~ bias). In this case the mag ~ 0.4 O :// . d a. / /T 0_ a a c Q h N 04 Fg~ ~ - Schelne of ector dy a~&cs due to the trans 1ss j at&v e exchange co oupljng inducced by b an 0.2 0.4 0.6 0.8 . bafgQt I 2/k 2 e&ternal voltagge across the baarriver. FICx.. 7. Dissipativ p 1v h ge coup ling D e (sn In magnetic metallic multilayers (F~g 6) Applications: Magnetic Random g oPt~cal parlance wh p~~fers t mor» Access Memory, STT-MRAM barrier is losing direct~on polarized J. C. Sloncewski, JMMM 159, L1-L7 (1996) electrons and S rift away fr sS shown. er ace greatly in' interface tht o dt'1 t 'ldt n includi at actually th e spin cu«ennt through L. Berger, PRB 54, 9353 (1996) . Nature the junct' n (includin g bothNanotechnology, March longit u d inal and transverse 2015 , sur ace statess a nd the like r Spin-transfer-torque memory SPICE-SPIN+X Seminar erms) is giv 1ven simply Ils(W by = V —VA )(S„+Sa) a)=D( (5.7) The polarizat' za ion coefficien (3.5 ) for the two-ba , ---" hec6 , g
NYU Basic Physics of Spin Transfer Based on conservation of angular momentum ~int ~f S ~i S dS ! ~⌧ θ θ dt ~ S ~int dS ~ = IP sin ✓ € dt 2e 1 dM~ ~int dS + =0 dt dt magnetization itinerant charge ‣Reference layer ‘sets’ spin-polarization of current ‣Enables readout of magnetization state through the tunnel magnetoresistance (TMR), giant magnetoresistance (GMR), or anisotropic magnetoresistance (AMR) effects SPICE-SPIN+X Seminar 7
NYU Charge Current to Spin Current Conversion Ferromagnetic layers to Spin-orbit torques polarize the current Spin-polarization direction set by Spin-polarization direction set by layer geometry reference layer magnetization and current flow direction direction Spin torque foundational theory papers: Heavy metals/Ferromagnet bilayers J. C. Slonczewski, Phys. Rev. B. 39, 6996 (1989) M. Miron et al., Nature Materials 2010 J. C. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996) L. Liu et al., Science 2012 L. Berger, Phys. Rev. B 54, 9353 (1996) Review article: J. Sinova et al., Spin Hall Effects, RMP 87, 1213 (2015) SPICE-SPIN+X Seminar 8
NYU Charge Current to Spin Current Conversion Ferromagnetic layers to Spin-orbit torques polarize the current z ℓ y x t FL RL spin-current density charge current Js /Jc ≃ P Js /Jc = θSH density Is /Ic ≃ P Is /Ic ≃ θSH(ℓ/t) spin current is −ℏ ℏJs /(2e) Q ∼ m̂ RL ⊗ z ̂ Q= ξσSHE(z ̂ × E) ⊗ z ̂ 2e Polarization ⊗ Flow direction Polarization ⊗ Flow direction Spin torque foundational theory papers: Heavy metals/Ferromagnet bilayers J. C. Slonczewski, Phys. Rev. B. 39, 6996 (1989) M. Miron et al., Nature Materials 2010 J. C. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996) L. Liu et al., Science 2012 L. Berger, Phys. Rev. B 54, 9353 (1996) Review article: J. Sinova et al., Spin Hall Effects, RMP 87, 1213 (2015) SPICE-SPIN+X Seminar 9
Electrical Generation of Spin Currents Outline • Introduction: Spin torques and spin-orbit torques • Charge-to-spin conversion efficiency in switching perpendicular magnetic tunnel junction nanopillars • Planar Hall effect spin torques SPICE-SPIN+X Seminar 10
NYU memories LETTERS Andrew D. Kent and Daniel C. Worledge Solid-state memory devices with all-electrical read and write operation information storage. PUBLISHED ONLINE: 11 JULY 2010 | DOI: 10.1038/NMAT2804 S pin-transfer-torque magnetic random Spin-transfer torque provides a access memory (STT-MRAM) devices mechanism to write information. On store information in the orientation the other hand, information can be read of the magnetization of nanometre-scale by measuring the device resistance. The A perpendicular-anisotropy CoFeB–MgO Applied Physics Letters ferromagneticARTICLE elements. As such, they are like hard disk drives, which use magnetic states to store information. In contrast to hard disk drives, however, STT-MRAM is scitation.org/journal/apl magnetoresistance refers to the percentage change in resistance between parallel and antiparallel magnetization alignment of the electrodes in a magnetic tunnel junction, magnetic tunnel junction written and read electrically, and does not which is made of a ferromagnetic metal/ have moving parts. This is a key difference insulator/ferromagnetic metal stack5. Until that enables the integration of magnetic 2004, the maximum magnetoresistance devices with semiconductor chips. Such reported6–8 at room temperature was 70%. TABLE I. TMR andmight devices fit parameters fulfil the speed from the pulsed switching requirements measurements Magnetoresistance greater thanfor vari- 100% had, ous temperatures and theworking of a computer’s corresponding memory while optimal write energies. however, been predicted in crystalline S. Ikeda *, K. Miura , H. Yamamoto , K. Mizunuma , H. D. Gan , M. Endo , S. Kanai , 1,2 1,2,3 1,2,3 2 1 2 2 the inherent advantages of using having magnetic states — that no energy is needed Fe/MgO/Fe tunnel junctions9 and was then observed experimentally 10,11. Subsequent LETTERS 3 news & views * J. Hayakawa , F. Matsukura and H. OhnoNATURE MATERIALS 1,2 1,2 DOI: 10.1038/NMAT2804 T TMRadvances V c (mV) to retain information. STT-MRAM is the result of important in physics and materials science s 0 (ns)rapid advances in the growth E (fJ) of thin-film materials have led to junctions with large magnetoresistance of several hundred per (K) (%) made APover !P the pastP! APTheAP 20 years. first!key P P cent, AP AP ! through the use!ofPtransition P ! metalAP finding was the theoretical prediction of electrodes (typically CoFeB). a Magnetic tunnel junctions (MTJs) with ferromagnetic replaced by the demagnetization energy E a a b , resulting in large E, of the interface are needed to correlatedemag spin-transfer torque between conduction V¬ tCoFeB = 2.0 nm Applications: New types of MRAM 4 structure and properties in these materials. 200 399and magnetization: electrons 421 spin-polarized 0.94 1.03 103 286 electrodes possessing a perpendicular magnetic easy axis which is the reason why perpendicular anisotropy is required for the 1 Another question is related to the75 fact 193 electrical393 currents can 416 transfer spin0.94angular 1.05 Bit line 98 283 are of great interest as they have a potential for realizing reduction of switching current. This equation shows that low ↵ is that CoFeB films show low damping. momentum to the magnetic moments of a Cr/Au 150 182 ferromagnet, 381 thus reorienting 403 them0.96 1–3 . In 1.10 94 287 M (T) next-generation high-density non-volatile memory and logic needed for low switching current for a given E. However, commonly m Free layer 0 However, in the devices fabricated a ferromagnet, the majority and minority +m chips with high thermal stability and low critical current for known perpendicular-anisotropy materials and structures use –m by Ohno and colleagues, which have In plane 295 117 electron 225spin states are 305 1.48 shifted in energy. 1.38 51 195 5 nm Ru very thin CoFeB layers, the damping is Thus, if the spin polarization of electrons 1–3 18 current-induced magnetization switching . To attain perpen- noble metals with high spin–orbit interaction , which increases ↵ 5 nm Ta ¬1 stronglyOutenhanced, of plane and the origin of this incident on a ferromagnetic layer is not Word line enhancement is not well understood. In aligned with its magnetization (that is, dicular anisotropy, a number of material systems have been (refs 3,19–21). For example, the typical ↵ is larger than 0.1 for Co/Pt tCoFeB CoFeB acquiring a PMA, the damping apparently The devices the electronare is notfirst characterized in a definite majority by measuring their field and explored as electrodes, which include rare-earth/transition- (ref. 19). In addition, there is no established material system that Al2O3 mp Hard layer ¬0.5 0 0.5 comparable to other becomes 1.0thin-film current pulse or minority spin-state), the electron spin resistance hysteresis loops. Figure 1(b) shows the free precesses rapidly around a momentum- tMgO MgO 4,5 V+ 3,6,7 U µ 0H (T) materials with PMA , which typically metal alloys , L1 -ordered (Co, Fe)–Pt alloys 0 and Co/(Pd, provides high tunnel magnetoresistance (TMR) ratio apart from the 7 layer hysteresis dependentloop (i.e.,field internal a ofhysteresis the ferromagnet. loop in which the applied field is 1,8–10 have large distributions in their magnetic Electron spins dephase because of the Pt) multilayers tCoFeB CoFeB . However, none of them so far satisfy well-known body-centred cubic (bcc) (001) CoFe(B)–MgO system. b properties that may lead to variations always in lessdistribution than theofcoercive field associated electron momenta of the SAF layers) of a 40 nm diame- Figure b 1 | A perpendicularly magnetized magnetic tunnel t junction. =a,1.3 nm Structure of a perpendicular MTJ, high thermal stability at reduced dimension, low-current The crystal structures of perpendicular-anisotropy materials are 5 nm Ta consisting of hard (fixed) and free (switchable) 1 magnetic CoFeB layers separated by a thin MgO tunnel barrier. 1 characteristics. Do such distributions device ter pMTJ device measured with current flow 4. As a in antheapplied perpendicular result, field at 4 K. We Bit-line complement exist in CoFeB–MgO bilayers? To answer component of spin-polarization transverse K. tCoFeB (mJ m–2) current-induced magnetization switching and high tunnel usually different from bcc, and on annealing the initially amorphous Arrows represent the direction of magnetizations of the hard (mp) and free (m) magnetic layers. b, The this question, further studies of filmsobserve and sharp to the switching magnetization from the P to AP state and vice versa with a decays, transferring 10 nm Ru M ( T) PMA of the free layer leads to a large energy barrier (U) to the magnetization switching between up and 0 magnetoresistance ratio all at the same time. Here, we CoFeB tends to crystallize in structures other than the wanted bcc down orientations. 0 field device arrays are necessary. In addition, offset spin angular momentum to the ferromagnet. Figure 1 | STT-MRAM bit cell. A magnetic tunnel of 56 mT, In transition reflecting metal ferromagnets, thethisfringe field from the SAF acting on junction is formed by a fixed reference layer 5 nm Ta the switching speed and energy are critical use interfacial perpendicular anisotropy between the ferro- because they are deposited in direct contact with the perpendicular- metrics for applications. In the perpendicular free layer. 18 This occurs dephasing typically sample at theexhibits interface a (purple), tunnel magnetoresistance a tunnel barrier (grey) and a free-layer ¬1 of the ferromagnet, on a length scale of element (red), with both layers magnetized magnetic electrodes and the tunnel barrier of the MTJ by anisotropy materials . In the following, we show that all three 0 10 junctions, Si/SiO2 sub. magnetization states 40 employing the material combination of CoFeB–MgO, a system conditions at nm Field induced room temperature thin-film elements of less than only 10 nmFIG. 1. in (a) ¬1 of plane. A steady increase in the PMA Schematic of a Current-induced pMTJ device with the pulse and spin-valve readout 1 measurement tCoFeB for high-performance perpendicular MTJs can be met is seen with decreasing CoFeB thickness, switching with (nm) pulses 2 (TMR) magnetization- as short as 0.3 1(c) ratio of ns showsferromagnetic 203% voltage-induced and an layer responds average several atomic layers. However, the entire switching coercive to the torquesof arrows). the same field toofthe283 perpendicular The bit is 40 plane mT. Figure of the junction nmby adiameter selected (black word line and circuit. Nanosecond clearly duration indicatingwrite that pulses PMA is are applied throughhas the beencapacitive port of widely adopted to produce a giant tunnel magnetoresistance free layer with the CoFeB–MgO in diameter. Moreover, these magnetization states are expected to be readily altered a biasusing ¬0.5 effect. tee, while theAnother DC portimportant is used for0 an interface switching result is that device the readout. 0.5 demonstrated, (b)of Resistance 0.1 pJ in thermally with energies standard material system that is widely used 1.0 device stable elements8. vs perpen- in because of the strong exchange coupling of zero field with 100 moments throughout its thickness. ms duration transistor, and operated by applying biases to the voltage bit lines. pulses. We observe a Figure 1 | MTJ structure. a, Schematic of an MTJspin-transfer ratio in MTJs with in-plane anisotropy device for torque TMR 2,3and . free This CIMS , a new mechanism11–13 layerapproach hysteresis loop for of a in-plane-anisotropy µ 0 diameter device at 4MTJs. for anisotropy of the interface is shown toHbe(T) bistable region However, the ultimate switching speed of around zero applied voltage and voltage-induced measurements. b, Top view of an MTJ no requires magnetization pillarmaterial taken by scanning other switching electron than that those dicular field makes ratiopossible used is switching in 203%. sufficient (c) to conventional overcome Voltage-induced the strong switching 40 nm Alltendency withthelongstack CoFeB–MgO duration structures (100 ms) K. The TMR requires in pulses further this of study study and are switching NATURE NANOTECHNOLOGY | VOL 10 | MARCH 2015 | www.nature.com/naturenanotechnology prepared with pulse on ther- amplitudes of 405 mV for AP ! R. P switching Beach et al., IEDM and 2008 spin transfer torque MRAM (STT-MRAM). of CoFeB layers to be magnetized in plane as optimization. Devices with non-collinear © 2015 Macmillan Publishers Limited. All rights reserved microscope. in-plane-anisotropy This MTJs. The perpendicular has led to intense the Figure same worldwide efforts to MTJs 2 | deviceIn-plane at 4 K in consisting a result and zero out-of-plane applied of magnetic shapemally field. magnetization The junction anisotropyoxidized (that curves resistance for for the Si(001) substrate magnetizations data in can switch evenby RF $358 faster 9 , mVsputtering for P !atAProom switching. Table I shows the TMR values realize STT-MRAM show panels with perpendicularly (b) andresults CoFeB/MgO. (c) isa,from measured tCoFeB with = 2.0 magnetic a 30b, nm. dipole mV DC=bias, tCoFeB interactions) a without 1.313nm.bias much Inset: less dependence tCoFeB nanosecond thanincubation the delays 10 of Ta/CoFeB/MgO/CoFeB/Ta a high tunnel magnetore- temperature . The MTJ structures consist extracted of, from from the the pulsed substrate voltage loops from 4 to 295 K. We observe (µ0 : permeability in free space). Theover magnetized saturation layers. The focus magnetization of switching the efforts voltage. for layer thicknesses of about 1 nm seen in collinearly magnetized structures. hasAlso, D.C. Worledge et(~3 atal., sistance ratio, 120%, highmultilayers thermal of the product ofApplied Physics K and tCoFeB , where Letter the intercept the98, to(10)/Ta vertical022501 axis andFe(2011) been on complex of stability dimension monolayers of CoFeB).side, Ta (5)/Ru Nonetheless, (5)/Co there is great20 B20 for (tCoFeB 60almost potential : 1.0–1.3)/MgO a factor of two increase in the TMR at 4 K compared to its value is 1.58 T. The perpendicular-anisotropy as low as 40 nm diameter energy magnetic density and transition lowKswitching aelements at as Co such the slope ofThe current thework of linear 49 extrapolation goes µA. further to(t of the data : 0.85 demonstrate or the correspond 0.9) perpendicularly /Co to Kmagnetized Fe i and B (1.0–1.7)/Ta CoFeB–MgO at room (5)/Ru temperature, (5) (num- which is consistent with earlier studies. 5,19 MgO 20 60 20 5 3 The Perspective: this CoFeB thickness, which determines three andthe conditions magnetic CoA. Ni, orthermal that elements D. and Fe withKent, stability, heavier high-performance like Pt and Pd. Perpendicular non- time These 2 b MS incorporation Kdecreases µ0 . Circles /2 with perpendicular in a device. A all of this and temperature, the interface squares in bers perpendicularly way, anisotropy are obtained contrast are magnetized Nature to nominal devices. macrospin ItMaterials should from magnetization thicknesses increase their model pre- in anisotropy and9, 699 be straightforward nanometres) further to to (2010) permit (Fig. 1a),spin-torque High-speed which areswitching was studied by applying a less is 2.1 ⇥ 10 J m , a value comparable materials to thatareof theto have Co–Pd FMR The dictions. measurements, largest reductionrespectively. inprocessed switching time MTJs need to satisfy impose a stringent known set of perpendicular requirements CoFeB-MTJ on theis shown device to have a largeintooccurscircular stable between devices magnetization room stateswith asmaller in eventhan405 ns or duration 150 nmcurrentdiameter pulse and determining the junction state (P SPICE-SPIN+X Seminar multilayers perpendicular 25 and high enough materials to be used to secure magnetic anisotropy in the MTJ structure.(PMA),goodandtemperature andthe 150thermal are already magnetoresistance First of all, K. Further, (>100%).atWhen by low temperatures, these electron-beam magnetic there is a factor elements, lithography for example, by and Ar-ion oradding AP)milling before and(Fig.after 1b).theForpulse. We start the measurement sequence 11
ectrodes NYU (typically CoFeB). moment of the free layer to be reversed by spin-transfer torque. Magnetic Tunnel Junction Nanopillars FOCUS | COMMENTARY Bit line Device attributes and applications a STT-MRAMs b are potentially suitable for a variety of uses, including as replacement of battery-backed static random access Micromagnetic simulations 1.0 1.0 Resistance (kΩ) Resistance (kΩ) memory (SRAM) and as a fast-write 0.75 0.75 buffer in a hard disk or solid-state drive. Word line 0.5 Table 1 lists0.5the key features of existing and emerging −0.6 memory −0.4 -0.2 technologies. 0 0.2 0.4 0.6 −40 −20 0 20 40 Magnetic field (mT)STT-MRAM is the only Voltagenon-volatile (V) c memory expected 5 to have unlimited +m -m 3 endurance. This is because there is no inherent magnetic wear-out mechanism 1/t (GHz) 2.5 Eb 2 for switching magnetic moments back and forth. No atoms are moved during writing N. Statuto et al., PRB 103, 014409 (2021) I/Ic0 0 P. Bouquin et al., APL 113, 222408 (2018) operations, as is the case in phase change 0 1 2 3 I/I ) & 60 c0 Bit-line Eb /(kTcomplement 1 I. Volvach et al., APL 116, 192408 (2020) memory (PCM) or resistive random access J. B. Mohammadi et al., APL 118, 132407 (2021) memory (RRAM); only the magnetization ℏ ( P bit )cell. 4e 1 + P 2 Eb Vc = α gure 1 | STT-MRAM GP A magnetic−10tunnel−9 is rotated. There is,−5 however, an −3 electrical 0 −8 −7 −6 −4 log t (s) nction J. C.isSlonczewski, formed by PRB a 71, fixed 024411reference (2005) layer wear-out mechanism — the dielectric Figure 2 | STT-MRAM electrical characteristics. a, Resistance versus applied magnetic field, showing bistable resistance states near zero-field associated urple), J. C. a tunnel barrier Slonczewski &with J. Z. (grey) Sun, parallel JMMM and310,a169 (P) and antiparallel free-layer (AP) (2007) breakdown magnetized bits. b, Resistance versus voltage, showingof switching the MgO between AP tunnel and P states barrier. Tovice versa (positive bias) and ement (red),A.with both the D. ofKentpulse layers duration and D.magnetized proportional C. to pulse amplitude, characteristic Worledge, “A new avoid of spin this, the ballistic on the switching magnetic limitwrite voltage at shortmemories,” times, must while the dashed-dotted Nature beline kept (negative bias). c, Pulse switching amplitude versus pulse duration, on a logarithmic scale for fixed switching probability. The dashed line shows the inverse of isNanotechnology characteristic 10, 187 (2015) erpendicular to themagnetization plane et al., H. Liuduration ofreversal theΔjunction "Dynamics = U/(kT) (ref. (black of 20); spin torque measurements of sufficiently these switching device characteristics low incan (roughly all-perpendicular thus be used to 400 estimate Δ. mV The spin inset across the long-time behaviour, thermally activated transitions assisted by STT. The slope of the dashed-dotted line is inversely related to the energy barrier to shows valve the nanopillars," inverse pulse JMMM 358, 233 (2014) rows). The bit is selected versusby a amplitude pulse word inline and the short the tunnel barrier) 12 . STT-MRAM can be time limit. The slope of this curve is the STT dynamic parameter A, and the intercept with the x axis occurs at I , the c0 SPICE-SPIN+X Seminar threshold current for STT switching, permitting determination of key device parameters from short-time pulse switching data. 12
NYU High Speed Magnetization Switching 40 nm diameter nanopillar Pulse 1.0 Amplitude (mV) CoFeB/W/CoFeB FL 700 AP→P Bias Tee MgO 600 295 K DC 500 0.8 SAF 400 1 T = 295 K Probability a) 300 AP to P 0.6 P to AP Switching Error Rate 0.1 200 9 9 Resistance (kΩ) Resistance (kΩ) Amplitude (mV) 8 8 800 0.01 P→AP 7 7 700 0.4 6 6 295 K 5 5 0.001 600 4 b) 4 c) 500 0.2 1E-4 3 3 400 -400 -200 0 200 400 -900 -600 -300 0 300 600 900 Field (mT) Voltage (mV) 1E-5 -600 -400 200 400 600 300 Pulse Amplitude (mV) 0.0 Laura Rehm et al., Appl. Phys. Lett. 115, 182404 (2019) Laura Rehm et al., Phys. Rev. Appl. 15, 034088 (2021) ✓ ◆ For pulse duration τ0 the 1 1 I Ic spin-charge conversion Ns (mFL /μB) = = ≃ 0.23 ⌧ ⌧0 Ic efficiency in a macrospin Nc (Icτ0 /e) model: ⌧0 Ic = I⌧ Ic ⌧ Ic ≃ 100 μA critical number Ns = P ≃ 0.11 P = mr /(2 + mr) of transmitted eNc eN dissipation Nc (1 + P 2)ln(4 πΔ) Δ = Eb /(kBT ) charges Nc SPICE-SPIN+X Seminar Write energy: . 250 fJ 13
Electrical Generation of Spin Currents Outline • Introduction: Spin torques and spin-orbit torques • Charge-to-spin conversion efficiency in switching perpendicular magnetic tunnel junction nanopillars • Planar Hall effect spin torques SPICE-SPIN+X Seminar 14
NYU Spin Orbit Torques • Separating read/write paths can • Allow separate optimization of read/write channels • Increase barrier longevity • Eliminate reference layer switching instabilities • Spin Hall and Rashba effects can be used to generate spin current. L. Liu et al., "Spin-Torque Switching with the Giant Spin Hall Effect of Tantalum." Science 336, 6081 (2012) I. M. Miron et al. "Current-driven spin torque induced by the Rashba effect in a ferromagnetic metal layer," Nature Materials 9, 230(2010) SPICE-SPIN+X Seminar 15
PHE M JPHE NYU z z z Q PHE Q PHE +Idc Q PHE Ta/Au/FM/Ta Ta/Pd/FM/Ta Spin Currents Set By Magnetization FM Au FM Au Au Ta/Pt/FM/Ta Ta Ta Ta 0 Symmetry 90 180of antidamping 270 360 spin torques: f ϕ (°) Ta/Au/FM/Ta FM z NM y M Ta/Pd/FM/Ta PHT Blue=antidamping SHT Red=damping +I x dc Ta/Pt/FM/Ta 0 90 180 270 360 θ (°) From C. Safranski, E. A. Montoya & I. N. Krivorotov, Nature Nanotechnology 14, 27 (2019) tryCharge-to-spin and material dependenceconversion of SOTs. a,b, dΔH/dKdc measured at room temperature for different NM1 layers characterizes the ping SHT in the xy plane (a) and that of the antidamping PHT in the xz plane (b). c–e, Schematics of the flow of pure spin current • Spin-orbit NM/FM interface couplingplanar by spin-polarized in non-magnetic Hall current densitymaterials JPHE in the(e.g. by for FM layer Spin-Hall, Rashba Idc!>!0 (c) and and Idc!a!0.charge Error bars show the current standard into a spinerror of least current squares with fit (Methods). a controlled spin polarization that can exert torques on an adjacent magnetic layer and switch perpendicularly magnetized elements tudinal spin current (p̂ ∣∣m̂ ) by the FM can give net angular momentum transfer to the FM and zero PHT, as illus- ng torque. An example SPICE-SPIN+X Seminar of such a mechanism trated in Fig. 3e. In contrast, we found that Au/AlO is a poor spin 16
NYU The spin current flow in the z-direction for the anomalous Hall effect (AHE) mechanism is Planar Hall Driven Spin Current proportional to my , and, again, with a SP direction m̂. So the maximum AHE spin current with a perpendicular spin component is when the magnetization is tilted in the y − z plane; it is zero when m̂ = ẑ because in this case there is no y-component of magnetization. The spin currents and spin torques associated with planar Hall effect (PHE) have a dif- ferent symmetry. For example, they are zero when m̂ = ŷ and can be non-zero when the ℏ magnetization is canted in the x − z plane. These symmetries provide a means to classify Js = η (m̂ ⋅ Jdc) m̂ the response experimentally, as indicated in Fig. 2b. Recently, a torque with a symmetry associated with the planar Hall effect has been identified in single Ni|Co multilayers [95] 2e and a torque consistent with the anomalous Hall effect was observed [96–98]. Spin injec- tion/detection with anomalous Hall effect has also been reported [99]. Recent research from the PIs of this proposal has identified a spin torque from Ni|Co multilayers with symmetry associated with the planar Hall effect acting on a second (CoFeB) detector ferromagnet [34], which we plan to explore further in the proposed project. • Spin current needs to be injected into nearby 3.1.2FM Spin polarization associated with magnetic/nonmagnetic interfaces: It is Non-magnetic now appreciated that the nature of the interfaces can change the layer NM picture significantly. (For an up-to-date review see [100].) Most notably, the spin polarization of interface-generated • Thus only the z component of current is important spin currents is not necessarily in the plane of the interface or bound by crystal symmetry constraints [101]. Amin et al. has shown that at an interface between a ferromagnet and non- magnet in the presence of strong spin-orbit interactions, the resulting spin current entering ℏ ℏ the nonmagnet can have its polarization rotated from the plane of the interface [102–104]. J = η (m̂ ⋅ x)( ̂ m̂ ⋅ z)J ̂ = η cos θ sin θ The spin-current polarization can be written as [102–104]: j = jf ŝ + jp m̂ × ŝ + jm ŝ × (m̂ × ŝ), sz dc where j is the spin polarization direction and ŝ = ẑ × E. At nonmagnetic interfaces, jp and 2e 2e jm vanish, as expected for spin-Hall and Rasha-Edelstein effects (i.e. the spin polarization is in the plane of the interface perpendicular to the electric field). The new theoretical result is that at FM/NM interfaces the net spin current can acquire a polarization at an angle set by ŝ and the magnetization direction m̂. For T. Taniguchi, J. Grollier & M. Stiles, PR Applied 3, 044001 (2015) example, if the magnetization is parallel to x̂ K. D. Belashchenko et al., PR Materials 3, 011401 (2019) & (parallel PRB 101, 020407 to the current(2020) flow direction) the term V. P. Amin, J. Zemen & M. D. Stiles. Interface-generated spin currents. with PRL 121, the prefactor 136805 jp gives (2018) of a component V. P. Amin, P. M. Haney & M. D. Stiles, "Interfacial spin-orbitspin torques," arXiv:2008.01182 polarization in the ẑ direction, perpen- dicular to the interface. In brief, the micro- scopic mechanism is spin precession of spin- SPICE-SPIN+X Seminar polarized electrons in the interface spin-orbit 17
NYU Patterned Samples • CoNi has large AMR and is grown with perpendicular anisotropy • CoFeB has small AMR and is grown to be weakly in-plane • A ~0.1 Tesla field can saturate both layers 1 0.5 M/Ms 0 −0.5 OOP IP −1 • 400 nm x 3 µm bridges −4 −2 0 2 Field (kOe) 4 SiO2/Ta(3)/Pt(3)/[Co(0.65)/Ni(0.98)]x2/Co(0.65)/Au(3)/CoFeB(1.5)/Ta(3) SPICE-SPIN+X Seminar 18
NYU ST-FMR Angular Dependence VIEW LETTERS 124, 197204 (2020) θ • Angular dependence of resonance field with f=14 GHz drive can identify the H in-plane H out-of-plane layer’s modes. 14 GHz (γ) 2 ω 2 2 = μ0 (H − Meff cos 2θ)(H − Meff cos θ) Meff = Ms − Hp • CoNi has out-of-plane anisotropy (Meff < 0): Hres large for H in-plane • CFB has in-plane anisotropy (Meff > 0): Hres large for H out-of-plane SPICE-SPIN+X Seminar 19
NYU ST-FMR Bias Dependence f = 14 GHz, θ = 330 degrees • We work at high enough frequency so that the applied fields saturate both FM’s magnetizations parallel to the applied field. • Application of DC current changes the resonances linewidths ω ℏ η Idc ΔH = ΔH0 + 2α + cos θ sin θ γ e MstFM wttot SPICE-SPIN+X Seminar 20
NYU Linewidth vs Bias f = 14 GHz, θ = 330 degrees • Observe linear modulation of resonance linewidth for both layers. • The slope is proportional to the charge to spin conversion efficiency dΔH ℏ η cos θ sin θ = dIdc e Ms tFM wttot SPICE-SPIN+X Seminar 21
NYU Linewidth vs Bias H PHYSICAL REVIEW LETTERS 124, 197204 (2020) θ = 330 degrees θ = 205 degrees H • Changing the z component of the field changes the sign of the spin-torques -FMR signal at θ ¼ 330 degrees for three different dc bias. Resonance linewidth for each layer as a function of dc bias at grees and (c) θ ¼ 205 degrees. SPICE-SPIN+X Seminar 22
the CFB layer from a spin current produced in the CoNi layer. NYU layer. In Ref. [21], a similar torque was observed in a single sourc Angular Dependence of Spin Torque ferromagnet paired with a spin sink. When comparing the We torque on the CoNi layer in this work to Ref. [21], the θ sign Here is consist with a larger spin current flow from CoNi in the by a direction of the Au layer. While there is a Pt layer on the angle •Slope of linewidth vs bias follows other interface, its resistivity is high due to the thin nature versio expected angular dependence: of the layer [40] and therefore its spin orbit generated spin damp Here, dΔH ℏ η cos θ sin θ the A = conta dIdc e MstFM wttot Assum we w linew •Overall charge to spin conversion Supp efficiency: •CFB η = 0.05 where •CoNi η = 0.09 partic thickn 800 e •Similar conversion efficiency as spin dΔH Hall effect in materials like Pt. efficie FIG. C. Safranski, J. Z. Sun, J-W. Xu and 3. PRL ADK, Angular 124,dependence of dΔH=dI dc for the CFB (top) 197204 (2020) from SPICE-SPIN+X Seminar and CoNi (bottom) layers with a fit to the expected angular the23C
to charge-current flow in the z direction, but the thin-film σ~ E ¼the corrections due to the charge including current itself NYU ∇ðδμ=eÞ ¼ ð∂ z δμ=eÞez . The electric field adjusts itself so σ þ σ AMR m2z geometry that treated no electric here prevents current flows inthat. theExcept for the applied z direction. being zero. The effective conductivities are − ðζσ AH my − ησ AMR mz mx Þ; Spin Currents Set By Magnetization electric potential eE x, only the z components of ∇μ̄ and ð10Þ In a particular ferromagnetic layer, we can solve Eqs. (6) x m z Þðσ AH my − σ AMR mz mx Þ 2 ∇δμ are nonzero, i.e., ∇ð μ̄=eÞ ¼ E e þ ð∂ μ̄=eÞe and ðβσ þ ησ AMR and (7) together with the diffusion equation x x z [63], z σ~ E ¼ and ∇ðδμ=eÞ ¼ ð∂ z δμ=eÞez . The electric field adjusts itself so σ þ σ AMR m2z that no electric current flows in the↑ z direction. ∂ 2 μ − μ ↓ − ðζσ AH my − ησ AMR2mz mx Þ; ð10Þ In a particular ferromagnetic ðμ ↑ − μ ↓ Þ ¼layer, we can ; solve Eqs. (6)ð8Þ σ ~ δμ ¼ σ þ σ AMR z m and (7) together∂zwith the diffusion equation l2sf ! " 2 [63], Spin Hall effect in non-magnetic metals and − ðβσ þ ησ AMR mz Þ 2Spinβσ þHall mz2 ησ AMREffect : ð11Þ (a) σþ σ AMR m2z z∂ ðμ↑ − μ↓ Þ ¼ μ − μ ; 2 ↑ ↓ ∂z2 y l2sf ð8Þ σ~ δμ ¼ σ þ −ℏ σ AMR m2z ! " x − ðβσ Qþ ησ= m Þ ξσ While the effective conductivities βσ þ ησ 2 SHE ( appear z ̂ × AMR : E) ð11Þ ⊗ m complicated, 2 z z ̂ 2emain results of this paper. If dF σ~ simplifies considerably inσ þ certain mlimits and gives AMR z 2 (a) m E σ AMR z z simple illustrations of the x y dN the While anisotropic the effective magnetoresistance conductivities appear ⊗ Polarization can be neglected, complicated, Flow direction F dF → ðβ − ζÞm σ~ Eσ~ Esimplifies considerably y σ AH , i.e.,in certain there limitscurrent is a spin and giveswhenever m simple illustrations Polarization the magnetization ofhas theamaincomponentresultsand of this along flowpaper. the direction If y direction, set by geometry N dN theQ anisotropic magnetoresistance canmagnetization be neglected,out of F Ex iz ∼ m i m y . Thus, by tilting the → ðβ −it ζÞm σ~ Eplane, y σ AH , i.e.,tothere is possible get is ana out-of-plane spin current whenever component of thethe magnetization spins flowing has aintocomponent the other alonglayer, the y something direction, not N Spin Orbit Interaction (b) in magnetic Ex metals Qiz ∼ mi my . Thus, by tiltingAnomalous the magnetization Hallout Effect of achievable with the spin Hall effect in nonmagnetic d1 plane, it is possible to get an out-of-plane component of materials. This feature is illustrated in Fig. 1(b). The factor m the spins flowing into the other layer, something not (b) dN of ðβ − ζÞ arises from two contributions; the term propor- achievable with the spin Hall effect in nonmagnetic d1 tional toThis materials. ζ is directly feature is from theinpolarized illustrated Fig. 1(b). current The accom- factor F1 m d of panying ðβ − ζÞ the anomalous arises from two Hall current. The contributions; the termpropor- term proportional Flow perpendicular to m and E dN 2 to β to tional comes ζ is from directly thefrom polarization the of thecurrent polarized counterflow accom- current N F1 d2 that cancels panying the the anomalous anomalous Hall current.Planar Hall The termHall current. Effect proportional F2N p Whenfrom to β comes the the anomalous polarizationHall of the effect can becurrent counterflow neglected, Ex → ðη −the σ~ Ecancels βÞm m σ σ . This expression is more that anomalous Hall x z AMR σþσ AMR current. m2z F p When the anomalous complicated than that Halltheeffect for anomalouscan beHall neglected, effect above FIG. 1. (a) Schematic geometry forExspin-Hall-effect-induced σ~ → ðη − βÞm m σ 2 σ Ebecause thex anisotropic 2 . This expression is more z AMR σþσ AMR m magnetoresistance affects the spin-transfer torques. In this geometry, the dampinglike torque is complicated than that for the z anomalous conductivity in the z direction, as captured by the last Hall effect Flow above parallel to m with FIG.respect 1. (a)toSchematic the y axis, i.e., mfor geometry × ðspin-Hall-effect-induced ŷ × mÞ (with a smaller because factor in thethisanisotropic expression.magnetoresistance As with the previous affects case,thean out- Figures from spin-transfer fieldlike with T. torques. torque). Taniguchi respect to the y In this geometry, (b) Schematic et al., axis, PR i.e., m the dampinglike geometry Applied × ŷ × mÞ torque is for anomalous-Hall- 3, 044001 (with effect-induced spin-transfer torques. In this case, the dampinglike ð a smaller conductivity (2015) in Polarization the z direction, asand of-plane component of the magnetization gives an out-of-capturedflow by direction the last set by magnetization! fieldlike torque torque). is with (b) Schematic respect geometry to the fixed-layer direction factor for anomalous-Hall- magnetization plane in this expression. component to Asthewithspinthecurrent, previousQcase, an out- iz ∼ mi mx mz . As p,effect-induced i.e., m × ðp × spin-transfer mÞ (with atorques. smallerIn fieldlike this case, torque). the dampinglike of-plane with the component previousofcase, the magnetization the factor of ðη gives − βÞ anappears out-of- from torque is with respect to the fixed-layer magnetization direction plane component to the spin current, Qiz ∼ mi mx mz . As p, i.e., m × ðp × mÞ (with a smaller fieldlike torque). with the previous case, the factor of ðη − βÞ appears from SPICE-SPIN+X Seminar 24
dΔH=dI dc angular symmetry of ðm̂ · ŷÞ. This is incon- CFB layer, t NYU sistent with our observation. Spin currents produced by be expected Angular Symmetry AHE have a polarization following m̂ as well, however the flow direction follows m̂ × x̂. When magnetization lies in momentum decreases a the xz plane as studied here, there is no flow of spin current known to h in the ẑ direction towards CFB [17]. higher AM * The angular dependence of the observed torques is consistent with the absorption of angular momentum in Material [29 higher, resu the CFB layer from a spin current produced in the CoNi layer. As su layer. In Ref. [21], a similar torque was observed in a single source of p ferromagnet paired with a spin sink. When comparing the We next torque on the CoNi layer in this work to Ref. [21], the sign Here we aim is consist with a larger spin current flow from CoNi in the by a dimen direction of the Au layer. While there is a Pt layer on the angle. We other interface, its resistivity is high due to the thin nature version effi of the layer [40] and therefore its spin orbit generated spin damping-lik *Symmetry of anti-damping torque under field reversal with fixed current direction Here, interfa the Au laye contained i Assuming a we would e linewidth li Supplement where M s particular l thickness, a 800 emu=cm C. Safranski, J. Z. Sun, J-W Xu and ADK, PRL 124, 197204 (2020) dΔH=dI dc efficiency o SPICE-SPIN+X Seminar 25
NYU Electrical generation of spin currents Summary • Spin torque switching in perpendicular MTJ nanopillars -Charge-to-spin conversion efficiency can be 0.23 for switching! • Spin orbit torques with planar Hall effect symmetry have been observed in CoNi multilayers -Charge-to-spin conversion efficiency (~0.05) is on par with the Spin Hall effect in Pt. -The spin polarization can be partially out-of-plane, making the PHE a candidate for deterministic switching of perpendicularly magnetized MTJs L. Rehm et al., APL 115, 182404 (2019) https://www.spintalks.org/talks/safranski PRL 124, 197204 (2020) L. Rehm et al., PR Appl. 15, 034088 (2021) SPICE-SPIN+X Seminar 26
NYU Kent Group Washington Square Park-June 2010 June 2012 Washington Square Park, February 2013 June 2018 January 2020 http://www.physics.nyu.edu/kentlab/ SPICE-SPIN+X Seminar 27
NYU POSTDOCTORAL POSITION: ANTIFERROMAGNETIC SPINTRONICS @ NYU Description: A postdoctoral position is available in Prof. Andrew Kent’s research group in the Center for Quantum Phenomena of the Department of Physics. The research focus is on antiferromagnetic spintronics, specifically spin-transport phenomena in thin films of antiferromagnetic insulators and at their interfaces with heavy metals, ferrimagnets and ferromagnets. The successful candidate will work within a multi- university and national lab team with expertise in thin film materials, magnetic imaging, measurement, nanofabrication and modeling. Experience with electronic transport and magnetic measurements, magnetic imaging (e.g. x-ray), thin film deposition, nanofabrication and magnetic characterization RES EARCH | R E S E A R C Hmethods ARTICLE is desirable. Good communication, writing and interpersonal skills are essential. → with an effective field H eff comprising the ex- change field (m0HE = 47.05 T), the anisotropy field (m0 HA = 0.82 T), the externally applied field (H), Email: andy.kent@nyu.edu → and the microwave field ½H m ¼ ðHo cosð2pftÞ; Ho sinð2pft þ qÞ; 0Þ&, where the polarization is determined by changing the phase factor q Posted: NYU Physics/Interfolio websites soon from 0 to 2p, and i = 1, 2 labels the two sub- lattices. We used the following parameter values for the calculation: g ¼ ge , saturation magnetization Ms = 47.7 kA/m, and a = 0.001, in agreement with previously reported values (24, 25). The theoretical results are displayed in Fig. 1, together with the measured spectro- scopic antiferromagnetic resonance (AFMR) absorptions; the experimental data are rep- resented by solid symbols corresponding to three different samples studied at four avail- able frequencies (horizontal orange arrows). Figure S1 shows the corresponding spectra. The upper left inset to Fig. 1 shows the electron Downloaded from http://scie paramagnetic resonance (EPR) spectrum ob- tained at frequency f = 395 GHz (red curve) for the magnetic field range corresponding to the HFM resonance (blue triangle at m0 H ¼ 4:70 T). The EPR signal is markedly distorted by saturation of the probe, owing to the large Fig. 1. Antiferromagnetic resonance of MnF2. Positions of the EPR spectroscopy resonances of MnF2. R. Lebrun et al., Nature 561, 222 (2018) thickness of the MnF2 single crystal used in P. Vaidya et al., Science 268, 160 (2020) The solid curves are the computed resonance frequencies associated with the low- and high-frequency AF these experiments, but still allows us to deter- modes (upper right inset), the SF transition (at m0 HSF e9:4 T), and the QFM at high fields. We use the SPICE-SPIN+X Seminar mine the location of the resonances spectro- fitting parameters m0 HA ¼ 0:82 T and m0 HE ¼ 47:05 T in Eq. 1. The different colors correspond to different 28
NYU Acknowledgments NYU Team: Dirk Backes*, Gabriel Chaves*, Eason Chen*, Ege Cogulu, Daniel Gopman*, Christian Hahn*, Jinting Hang*, Yu-Ming Hung*, Marion Lavanant*, Ferran Macia*, Jamileh Beik Mohammadi*, Daniele Pinna*, Laura Rehm, Debangsu Roy*, Sohrab Sani*, Nahuel Statuto, Volker Sluka*, Georg Wolf*, Li Ye* Yassine Quessab, Haowen Ren & Junwen Xu (*=group alumni) Collaborators -NIST: Hans Nembach and Justin Shaw -Advanced Light Source, Berkeley: Rajesh V. Chopdekar & Hendrik Ohldag -IBM T. J. Watson Research Center: Chris Safranski & Jonathan Z. Sun -NYU: Gabriel Chaves and Dan Stein -University of Barcelona and ICMAB-CSIC: Nahuel Statuto & Ferran Macia -Ohio State University: Fengyuan Yang -UVA: Joseph Poon and Avik Ghosh -UC Santa Cruz: David Lederman -University of Central Florida: Enrique del Barco -BBN Raytheon: Tom Ohki, Colm Ryan & Graham Rolands -Spin Memory: Georg Wolf, Bartek Kardasz, Steve Watts & Mustafa Pinarbasi -University of Buffalo: Igor Zutic -Wayne State: Alex Matos Abiague -University of Lorraine: Stephane Mangin -U. Paris Saclay, C2N: Dafine Ravelosona -UCSD: Eric Fullerton SPICE-SPIN+X Seminar 29
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