A Road Map to RCRA: Small Quantity Generator (SQG) Requirements - Connecticut Department of Environmental Protection
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A Road Map to RCRA: Small Quantity Generator (SQG) Requirements Connecticut Department of Environmental Protection www.ct.gov/dep Amey W. Marrella, Commissioner September 2009
This handbook is intended as an educational tool for Small Quantity Generators. It does not constitute a complete reference to state, federal or local laws. In the event of inconsistency between this document and the regulatory language, the language in the hazardous waste management regulations controls. It is your responsibility to comply with all applicable laws. Relying on the information in this handbook will not protect you legally and may not be relied upon to create a right or benefit substantive or procedural, enforceable at law or in equity by any person. Final determination of the proper handling and disposal of waste is the sole responsibility of the generator. The DEP is an affirmative action/equal opportunity employer. In conformance with the ADA individuals with disabilities who need information in an alternative format, to allow them to benefit and/or participate in the agency’s programs and services, should call (860) 424-3051 or (860) 418-5937 and make their request to the AAO staff person. These requests may be made directly to Marcia Z. Bonitto, ADA Coordinator, via e-mail: Marcia.Bonitto@ct.gov.
Table of Contents DOES YOUR BUSINESS GENERATE HAZARDOUS WASTE?....... iv HOW TO USE THIS GUIDE.............................................................................. v AN INTRODUCTION TO RCRA....................................................................... 1 What is RCRA? .......................................................................................................1 How Does RCRA Affect Connecticut Hazardous Waste Generators? .............................................................................................................1 HAZARDOUS OR NON-HAZARDOUS: THAT IS THE QUESTION! ............................................................................................................... 3 Listed Waste...........................................................................................................3 Characteristic Hazardous Waste..................................................................4 Other Considerations ..........................................................................................6 Are we there yet? (CT Regulated Wastes) ..............................................7 So what do I need to do? ..................................................................................8 Hazardous Waste Determination ..................................................................8 WHAT IS MY STATUS?...................................................................................... 15 Conditionally Exempt Small Quantity Generator (CESQG)...............15 Small Quantity Generator (SQG)..................................................................16 Large Quantity Generator (LQG)..................................................................16 Minimize Your Size!..............................................................................................19 WE HAVE HAZARDOUS WASTE….SO NOW WHAT?........................ 23 Container Specifics ..............................................................................................23 What are the marking and labeling requirements?...............................24 When are my containers “empty”?................................................................24 What additional requirements apply to Hazardous Waste Storage Areas (HWSA)?.......................................................................................................25 What is a Satellite Accumulation Area?....................................................26 Where can I use satellite accumulation?...................................................26 What are the quantity limitations for satellite accumulation?.......26 SQG Guidance Manual i Introduction
TANK TALK................................................................................................................. 29 Tank System Specifics.......................................................................................29 Special Requirements for Ignitable or Reactive Waste ....................30 THE MANIFEST....................................................................................................... 31 How do I complete a manifest?......................................................................31 I found something wrong on the manifest and the waste has already been shipped off-site - what do I do now? .............................32 Recordkeeping and Reporting ..........................................................................33 LAND DISPOSAL RESTRICTION.................................................................. 35 ALWAYS BE PREPARED! ...................................................................................... 37 What is an Emergency Coordinator?............................................................37 How do I prepare for an emergency?..........................................................37 Emergency Response Procedures...................................................................38 LOOKING FOR TROUBLE ................................................................................... 40 What are my Inspection Requirements?....................................................40 How often do I need to inspect?...................................................................40 UNIVERSAL WASTE............................................................................................. 43 How do I store my universal waste? ............................................................43 How do I mark universal containers?...........................................................44 Off-Site Shipments.............................................................................................45 Is Universal Waste training required? .......................................................45 What if there is a spill or release involving universal waste? .........45 USED OIL .................................................................................................................... 47 Used Oil Management .........................................................................................48 How do I ship my used oil? ...............................................................................49 May I burn the used oil on-site? ...................................................................49 GETTING OUT OF THE WASTE GENERATION BUSINESS......... 51 What if I discontinue storing waste? .........................................................51 GO GREEN! .................................................................................................................. 54 Am I required to recycle? ................................................................................54 GLOSSARY OF TERMS......................................................................................... 56 SQG Guidance Manual ii Introduction
Table of Contents (cont'd) APPENDICES A Common F-Listed Wastes B Waste Determination Form Example C Manifest Instructions D Inspection Guidance E Inspection Form Examples SQG Guidance Manual iii Introduction
Preface DOES YOUR BUSINESS GENERATE HAZARDOUS WASTE? Many of us think of individual chemicals when we hear the phrase “hazardous waste.” In reality, this phrase can include many commonly used items such as waste adhesives, unwanted or discarded oil-based paints, and spent solvents. Most businesses generate small quantities of hazardous waste. Businesses that generate between 100 and 1,000 kg (220 and 2,200 pounds or approximately 26 to 260 gallons) of hazardous waste per calendar month are Small Quantity Generators (SQGs). Listed below are examples of businesses that may generate hazardous wastes: • Lawn and Garden Care Centers • Hardware Stores • Laundries and Dry Cleaners • Health Care Providers • Furniture and Wood Refinishers • Metal Working Shops • Chemical Laboratories • Printers • Vehicle Maintenance and Dismantling Shops SQG Guidance Manual iv Introduction
Introduction HOW TO USE THIS GUIDE This guide has been developed by the Connecticut Department of Environmental Protection (CTDEP) to assist Small Quantity Generators of hazardous waste navigate the detailed “road” of waste regulations in Connecticut. Throughout this guide you will see “road signs” to help you along your trip. These signs aid in your understanding by focusing on key topics and providing references and sources of further assistance. Here are the road signs that you will see: Additional Clues & Hints Hot Topics STOP! This topic could spell trouble if not understood! Read in-depth and understand thoroughly before reading further! Look to the compass for definitions, acronyms and clarification. Items in the guide that have further clarification available are in italics. You will see throughout this text terms in italics and hyperlinks. Click on these terms for more information when viewing this document electronically. SQG Guidance Manual v Introduction
The road may get bumpy along the way and the CTDEP will always be there to assist you with questions and concerns that you may have. CTDEP encourages generators to contact the Bureau of Materials Management and Compliance Assurance with any questions regarding this manual, small quantity generator requirements, or other regulatory requirements. If you would like a copy of the Hazardous Waste Management Regulations or copies of other publications, please do not hesitate to contact the CTDEP at the telephone numbers provided below or visit the CTDEP’s website at http://www.ct.gov/dep/. Contact Information Emergency Response and Spill Prevention Division Emergency Spill Reporting (860) 424-3338 or (866) 337-7745 Information (860) 424-3377 National Response Center (800) 424-8802 Bureau of Air Management (860) 424-3436 Bureau of Materials Management & Compliance Assurance Hazardous Waste Compliance Assistance (888) 424-4193 Solid Waste and Recycling Program (860) 424-3366/3365 Stormwater and Wastewater Discharge Programs (860) 424-3018 Underground Storage Tank Program (860) 424-3374 Office of Pollution Prevention (860) 424-3297 Bureau of Water Protection and Land Reuse Remediation Division (860) 424-3705 SQG Guidance Manual vi Introduction
Section 1 AN INTRODUCTION TO RCRA What is RCRA? RCRA stands for the federal Resource Conservation and Recovery Act (RCRA). This law addresses the problem of managing and disposing of industrial and municipal solid wastes generated nationwide. RCRA established rules for facilities that generate, ship and dispose of hazardous waste. These regulations require detailed tracking of the waste from its point of generation to its point of final disposal and, thus the term cradle to grave was coined. RCRA also requires facilities to manage their operations to minimize or eliminate potential releases of hazardous waste to the environment. The goals of RCRA are threefold: 1. To protect human health and the environment; 2. To reduce waste and conserve energy and national resources; and 3. To reduce or eliminate the generation of hazardous waste to the maximum extent possible. How Does RCRA Affect Connecticut Hazardous Waste Generators? The CTDEP adopted the federal hazardous waste management regulations by incorporating the federal regulations into the Regulations of Connecticut State Agencies (RCSA) with some changes. These changes made Connecticut’s hazardous waste program broader in scope than the federal program. Since then, the CTDEP has updated these regulations several times. Connecticut’s Hazardous Waste Regulations are codified in sections 22a-449 (c)-100 through 119 and 22a-449(c)-11 of RCSA. RCRA is therefore enforced in Connecticut by the CTDEP. The CTDEP has published many documents that Small Quantity Generators (SQGs) of hazardous waste might find useful in day-to-day operations associated with waste management. For additional guidance, see the clues at the end of this section. SQG Guidance Manual 1 An Introduction to RCRA
Subsequent chapters of this document provide additional details and guidance in complying with Connecticut’s waste laws and regulations. For additional information, visit the CTDEP’s Homepage: www.ct.gov/dep/ and click on Materials & Waste Management The EPA’s Waste Management Homepage: http://www.epa.gov/osw/index.htm Abandoned – A material that is disposed of, burned or incinerated or accumulated, stored or treated (but not recycled before or in lieu of being abandoned by being disposed of, burned or incinerated). Cradle to Grave – A term used to describe RCRA’s goal to manage waste from the point of generation to the point at which it is permanently disposed. Generate – This term refers to the act or process of creating hazardous waste as identified or listed in Title 40 of the Code of Federal Regulations Part 261. If you generate, you are now considered a generator of hazardous waste. Generator – Any person, by site, whose act or process produces hazardous waste. Hazardous waste – A waste may be hazardous either because it is specifically listed in the regulations or because it exhibits characteristics such as ignitability, toxicity, corrosivity and reactivity that would render it subject to RCRA (more information on this later!) RCRA – Resource Conservation and Recovery Act. RCRA waste – A waste that is subject to the RCRA regulations. Solid waste – Any discarded material that is abandoned, recycled, a military munition or inherently waste-like. There are currently only two materials identified as being inherently waste-like, dioxin waste and halogen-containing materials that are burned in halogen-acid furnaces. Only a material that is a solid waste can be classified as a hazardous waste. A solid waste can be solid, liquid, semi-solid or containerized gaseous material. Waste – A material that can no longer be used for its intended purpose. SQG Guidance Manual 2 An Introduction to RCRA
Section 2 HAZARDOUS OR NON-HAZARDOUS: THAT IS THE QUESTION! Before determining whether a waste is hazardous or non-hazardous, the concept of hazardous waste must first be understood. In order to do this, the generator must ask the question: What does it mean to be hazardous? Remember that a waste is a A waste is hazardous if it exhibits a material that can no longer characteristic which would require the generator be used for its intended to assign a RCRA waste code. Waste codes purpose! were developed by EPA as a standard naming convention to allow those working with hazardous wastes to quickly and clearly determine the nature of the material to be handled, shipped or disposed. Some wastes are listed. In other words, that particular waste is specifically referenced by chemical name or constituents in the regulations. Here are the possible listed wastes: The ‘Official’ Definition of Listed Waste Hazardous Waste* These wastes are divided into four specific lists as “A solid waste, or combination of solid described below: waste, which because of its quantity, concentration, or physical, chemical, or • “F” List – Waste from Non-Specific Sources infectious characteristics may (a) Appendix A provides a description of common cause, or significantly contribute to, an increase in mortality or an increase in F Listed waste codes. serious irreversible, or incapacitating • “K” List – Waste from Specific Sources (Not reversible, illness; or (b) pose a Common for SQGs) substantial present or potential hazard to human health or the environment • “U” List – Non-acute Commercial Chemical when improperly treated, stored, Products transported, or disposed of, or otherwise managed.” • “P” List – Acute Commercial Chemical Products *It is important to note that some wastes are specifically excluded from RCRA. Chemicals listed on the “P” List and those on the “U” List noted with hazard code H are regulated as Acute Hazardous Waste. SQGs are only allowed to generate up to 1 kg (2.2 pounds) on site in one calendar month and/or accumulate up to 1 kg on site for up to 180 days. SQG Guidance Manual 3 Hazardous or Non-Hazardous: That is the Question!
Characteristic Hazardous Waste Not all hazardous wastes are listed. A waste is considered hazardous and is regulated under RCRA if it exhibits one or more of the following characteristics: Ignitability, Corrosivity, Reactivity, and Toxicity. To accurately make this determination, a representative sample of the waste should be collected and tested by a state certified laboratory. The regulations assign specific “D” codes to each of these characteristics. Each characteristic is further defined below. Ignitable Hazardous Waste (D001) Ignitable wastes are defined under RCRA as materials which fit into one or more of the following definitions: • A flammable liquid with a flash point less than 60°C (140°F) • A flammable solid – (it is not a liquid and is capable of causing fire through friction, absorption, moisture or spontaneous chemical changes; and, when ignited, burns so vigorously and persistently that it creates a hazard) • An ignitable compressed gas D001 Waste • An oxidizer Note: Aqueous solutions containing less than 24% alcohol by volume are excluded from the characteristic of ignitability. However, if the alcohol has been used for solvent properties, the waste must be evaluated to determine if it should be classified as an F-listed waste. Example: A half empty container of waste alcohol-based hand sanitizer gel that is being disposed of is an example of an Ignitable Waste (D001). In this case, testing a representative sample of the alcohol at a state certified laboratory or a review of the Material Safety Data Sheet (MSDS) may be used to confirm that the alcohol has a flash point of less than 600 C (1400 F). SQG Guidance Manual 4 Hazardous or Non-Hazardous: That is the Question!
D001 Waste Certain waste adhesives can also be considered Ignitable Waste (D001). A common example of an ignitable adhesive is waste rubber cement. Similar to the hand sanitizer, testing a representative sample of the rubber cement at a state certified laboratory or a review of the MSDS may be used to confirm that the rubber cement has a flash point of less than 600 C (1400 F). D002 Waste Corrosive Hazardous Waste (D002) Corrosive hazardous wastes are liquids that have a pH less than or equal to 2 or greater than or equal to 12.5. Waste acids from a laboratory are examples of Corrosive Wastes (D002). Reactive Hazardous Waste (D003) Reactive hazardous wastes are defined under RCRA as: • Chemicals which react with water or air and then ignite and/or explode; • Chemicals which react with water or air and then give off a toxic gas; • Chemicals containing cyanides and/or sulfides; • Chemicals that are stored under pressure and when exposed to heat could explode; and • Some Department of Transportation regulated explosives. A non-empty aerosol can is an example of a Reactive Waste (D003). D003 Waste An aerosol can that is completely empty and contains no propellant must be recycled as scrap metal. SQG Guidance Manual 5 Hazardous or Non-Hazardous: That is the Question!
Toxic Hazardous Waste (D004-D043) Toxic hazardous wastes are materials, which if disposed of on land, may leach constituents into the ground and/or water and are toxic to the environment. See the summary table for examples of toxic characteristic codes. Saturated rollers, brushes, rags and Summary of Common Toxic Characteristic Waste Codes wipes from a painting project using EPA HW Contaminant Regulatory various solvent-based paints, No. Level (mg/L) thinners and lacquers containing Metals Methyl Ethyl Ketone are examples D004 Arsenic 5.0 D005 Barium 100.0 of Toxic Waste (D035). (Note: D006 Cadmium 1.0 this waste may also be considered D007 Chromium 5.0 an F005 waste for spent non- D008 Lead 5.0 halogenated solvents). D009 Mercury 0.2 D010 Selenium 1.0 D011 Silver 5.0 D035 Waste Volatile Organics D018 Benzene 0.5 D019 Carbon tetrachloride 0.5 D021 Chlorobenzene 100.0 D022 Chloroform 6.0 D028 1,2-Dichloroethane 0.5 D029 1,1-Dichloroethylene 0.7 D035 Methyl Ethyl Ketone 200.0 D039 Tetrachloroethylene 0.7 D040 Trichloroethylene 0.5 D043 Vinyl chloride 0.2 Other Considerations Wastes can also become hazardous if the following conditions are met: • It is a mixture of solid waste (i.e., non-hazardous) and one or more listed hazardous waste (this is known as the Mixture Rule). • It is used oil containing more than 1,000 parts per million (ppm) of total halogenated compounds. See Section 11 for more on Used Oil. • It is a waste derived from the treatment of a listed waste (this is known as the Derived from Rule). SQG Guidance Manual 6 Hazardous or Non-Hazardous: That is the Question!
Are we there yet? (CT Regulated Wastes) Not quite... There are several types of industrial wastes that are not considered to be hazardous waste, but are still regulated by the CTDEP. These are commonly referred to as Connecticut regulated wastes. Connecticut regulated wastes should be evaluated for suspected RCRA hazardous constituents prior to treatment or disposal. A description of the types of waste and waste codes assigned to non-RCRA hazardous waste follows: Code* Description Examples CR01 Waste PCB’s PCB Oils, PCB Ballasts, PCB Transformers CR02 Waste Oil Fuel Oil, Lubricating Oil, Hydraulic Oil CR03 Waste Water Soluble Oil Cutting Oil, Cooling Oil CR04 Waste Chemical Liquids Latex Paint, Sludges, Glycol/Glycol Substitutes CR05 Waste Chemical Solids Grinding Dust, Oily Rags, Corrosive Solids, Contaminated Soil * These are wastes which are neither characteristic nor listed RCRA Hazardous Wastes per 40 CFR 261, but a facility permit is required by Connecticut General Statutes (CGS) Section 22a-454 for a person engaged in the business of storing, treating, disposing or transporting them. However, CGS do not require the transporter to be licensed to transport CR05 (Waste Chemical Solid). Note that the 180-day hazardous waste storage limit does not apply to non- hazardous Connecticut Regulated Waste. Even though these materials are non- RCRA hazardous waste, they are still regulated to ensure proper treatment or disposal. Certain solid waste may be suitable for disposal in a municipal landfill provided it has been approved for land filling in accordance with the CTDEP Special Waste Authorization process. Special wastes may include the following as long as they are not hazardous waste: (1) Water treatment, sewage treatment or industrial sludges, liquid, solids and contained gases; fly-ash and casting sands or slag; and contaminated dredge spoils; (2) scrap tires; (3) bulky waste; (4) asbestos; (5) residue; and (6) biomedical waste. SQG Guidance Manual 7 Hazardous or Non-Hazardous: That is the Question!
So what do I need to do? Now that you know what a hazardous waste is, you need to apply this knowledge to the materials that need to be disposed of by the generator. Prior to disposing of a waste, the generator must determine if the waste should be assigned with one or more of the codes listed in the previous pages. To help make sense of what is, and is not, a hazardous waste (and hence regulated by RCRA), you should be prepared to tell a complete story about the waste that you are preparing for disposal. This story should include information on how the material was used, how it was managed as part of a process and/or how the material was managed after it was used. This story is required to be documented in what is called a waste determination. Hazardous Waste Determination Any person who generates a solid waste must determine if that waste is a hazardous waste. All businesses are required to perform a Hazardous Waste Determination on the waste Your National Trade they generate to identify whether or not that Association or its local waste is hazardous. In Connecticut, hazardous chapter may be able to waste determinations must be reviewed and assist you with Hazardous recertified at least once during each 12-month Waste Determinations. period, or whenever a process generating a waste changes. A hazardous waste determination may be conducted either by having a representative sample of the waste tested by a state certified laboratory, by applying knowledge of the waste and its hazardous characteristics, or by a combination of both methods. Laboratory Testing Laboratory analyses should be conducted for flash point, corrosivity, reactivity, toxicity, volatile organic compounds (VOCs), and semi-volatile organic compounds (semi-VOCs). Some waste streams should also be tested for PCBs and/or specific listed wastes that may have been present in the waste stream. Test for toxicity using the Toxicity Characteristic Leaching Procedure, Test Method 1311 in “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods,” EPA Publication SW-846, as incorporated by reference in 40 CFR 260.11. Such laboratory analyses must be performed by a Connecticut Department of Public Health (DPH) certified laboratory. Laboratories can provide SQG Guidance Manual 8 Hazardous or Non-Hazardous: That is the Question!
guidance regarding correct procedures and equipment for collecting a representative sample. Knowledge of Process A knowledge-based hazardous waste determination involves a well thought out process in which the To assist you in making a materials used, and the waste generating Hazardous Waste processes, are considered. More often than not, it Determination, check the is easier to use knowledge to characterize the Material Safety Data Sheets waste as hazardous, than to characterize it as non- (MSDS) that accompany your hazardous. In a knowledge-based determination, hazardous materials. If an you must be able to document clearly that the MSDS was not made information used is valid, verifiable, and correctly available to you, the web link applied. You may assume a waste is hazardous below may be of assistance. based on its characteristics or on past laboratory http://www.msdssearch.com analysis, provided there is no change in how the waste was generated. Required Recordkeeping As a generator, you must keep records of any SUMMARY test results, waste analysis, or other How do I conduct a hazardous determinations made for at least three (3) waste determination? years from the date that the waste was last A hazardous waste determination sent off-site for treatment, storage, or may be conducted either by having disposal. Re-characterization of the waste the waste tested by a state certified must be done whenever there is a process laboratory or by applying knowledge change. In Connecticut, hazardous waste of the waste and its hazard determinations must be reviewed and characteristics. If applying recertified at least once during each 12-month knowledge, you must be able to period, or whenever a process generating a clearly demonstrate how the waste changes. knowledge was applied in making the determination and maintain The exercise on the next page provides an documentation supporting this determination. You may assume a example of a written waste determination that waste is hazardous based on its can be used to document your hazardous characteristics or on past laboratory waste. By using a quick and easy checklist, analysis provided there is no change you can verify that each of the potential in how the waste was generated. hazards and waste classification/codes are referenced and confirmed. The form can also be helpful to identify additional information on your waste determination such as transportation information, management methods, and disposal methods. A blank waste determination form has been provided in Appendix B. SQG Guidance Manual 9 Hazardous or Non-Hazardous: That is the Question!
EXERCISE 2-1: Business A generates a waste solution from its cleaning of printer rollers using Presswash X. The printer roller uses soy-based ink with non-hazardous constituents. The majority of the waste is Presswash X. To determine if the material used and the process generating the waste solution is hazardous or non-hazardous, Business A is using a knowledge-based determination and relying on process knowledge and information provided in the Material Safety Data Sheets (MSDS). In order to complete the determination, Business A followed the steps below: 1. The generator reviewed the process generating the waste. 2. The generator itemized the raw materials used in the process. 3. The generator obtained the most current Material Safety Data Sheets (MSDS) of raw materials used in the process from the supplier or the manufacturer. 4. The generator used the MSDS to complete the Waste Characterization profile forms. 5. The generator signs and dates the profile and reviews and updates it on an annual basis. The date of review will be placed on the profile or other tracking log. The waste from this process is concluded to be D001 hazardous (i.e., ignitable) because the flashpoint is below 140° F and there were no other constituents of concern that the generator identified in the process and literature review. Reviewed material composition for potential listed compounds { SQG Guidance Manual 10 Hazardous or Non-Hazardous: That is the Question!
EXERCISE 2-1 (CONT): Written Waste Determination Forms SQG Guidance Manual 11 Hazardous or Non-Hazardous: That is the Question!
EXERCISE 2-2: Business B generates a wastewater from the cooling of stainless steel turnings from a machining process. The wastewater contains stainless steel turnings. To determine if this wastewater is hazardous or non-hazardous, Business B is using laboratory results for Toxicity Characteristic Leaching Procedure (TCLP) chromium analysis. In order to complete the determination, Business B followed the steps below: 1. The generator reviewed the process generating the waste. 2. The generator collected a sample of the waste using EPA approved methodology and sampling bottles provided by the laboratory. 3. The generator sent the sample to a state certified laboratory. 4. The generator used the laboratory analytical results to complete the waste characterization profile form. 5. The generator signs and dates the profile and reviews the profile annually. The generator will use the laboratory results and waste characterization profile form as documentation of the review. The generator will update the profile as needed. The waste from this process is concluded to be non-hazardous because no hazardous characteristics applied. The stainless steel turnings are settled out from the wastewater and sent offsite as scrap metal. Only the wastewater is managed as non-hazardous waste. However, the generator still had to identify chromium as a constituent of concern in the process and collect a sample of the waste for analysis. The results demonstrated that the stainless steel turnings wastewater will not leach chromium at a concentration greater than the regulatory limit of 5 mg/L. Written Waste Determination Form Wastewater SQG Guidance Manual 12 Hazardous or Non-Hazardous: That is the Question!
EXERCISE 2-2 (cont): SQG Guidance Manual 13 Hazardous or Non-Hazardous: That is the Question!
Connecticut regulated waste – A waste that is not considered RCRA hazardous but is still regulated as a non-hazardous waste in Connecticut. Halogenated compounds – Volatile compounds containing elements from the halogens family (group 17) on the periodic table of elements. The most common halogens include chlorine and bromine which can be associated with degreasers such as trichloroethylene (TCE) and tetrachloroethylene (PCE or perc). Listed – Term used to describe a particular waste that is specifically referenced by chemical name or genre in the regulations. Remember: Waste codes – The standard naming Waste determinations must convention used by EPA to allow those be reviewed and updated working with hazardous wastes to quickly and annually, if required. This clearly determine the nature of the material to must be a documented be handled, shipped or disposed. review where, if changes to Waste determination – The process used to the determination are made, those changes and categorize a waste as hazardous or non- the reasons for making the hazardous. The term “waste profile” can be changes are provided. used synonymously especially by waste disposal vendors. This analysis can be based on either knowledge or analytical data but must be documented. Each determination must be reviewed and updated (if needed) annually. Visit the CT DEP website (http://www.ct.gov/dep) for more information on making a hazardous waste determination. A list of DPH certified laboratories can be found at the DPH website by searching for “certified laboratories” at www.ct.gov/dph. SQG Guidance Manual 14 Hazardous or Non-Hazardous: That is the Question!
Section 3 WHAT IS MY STATUS? By this point, you have completed your waste determinations and know if you generate hazardous waste. A generator is anyone who generates hazardous waste. Once you have identified your hazardous waste streams, you must now determine your generator classification or status. This classification is based on the amount of hazardous waste generated in a calendar month. In Connecticut, generators fall into one of three classifications. These classifications include large Generator classification is quantity generators (LQGs), small quantity not based on how much generators (SQGs), and conditionally exempt small you ship offsite for disposal quantity generators (CESQGs). per month! Although this is an indication of how To keep it simple, LQGs generate the largest amount of much waste you produce, waste while CESQGs generate the least amount of waste. your classification is based As your generator classifications increases from a CESQG on generation and NOT to SQG to LQG, so do your compliance obligations. disposal volume! Conditionally Exempt Small Quantity Generator (CESQG) You are a CESQG if you generate 220 lbs (100 kg) or less of hazardous waste and less than 2.2 lbs (1 kg) of acute hazardous waste per calendar month (waste codes denoted with the hazard code “H” and all P-listed wastes). CESQGs are exempt from many state requirements if they comply with the following requirements: • You must perform and maintain waste determinations. • You can accumulate less than 2,200 lbs (1,000 kg) of waste, or 220 lbs (100 kg) residue or contaminated soil from cleanup of an acute waste spill on-site at any one time. • You must comply with Department of Transportation (DOT) regulations. • You must either comply with Universal Waste rules or manage the waste as hazardous. • You must comply with Used Oil requirements. CESQGs may either treat or store their waste in an on-site facility, or ensure delivery to an appropriate off-site treatment, storage, or disposal facility. SQG Guidance Manual 15 What is my Status?
Small Quantity Generator (SQG) You are a SQG if you generate between 220 and 2,200 pounds or approximately 26 to 260 gallons (100 and 1,000 kg) of hazardous waste and less than 2.2 lbs (1 kg) of acute hazardous waste per calendar month. The following list summarizes the specific requirements applicable to SQGs: • You must perform and maintain waste determinations. • You can only store waste on-site for less than 180 days. • You can only accumulate less than 2,200 lbs (1,000) kg of waste on-site at any one time. • Waste can be accumulated in containers or tanks. • You must comply with preparedness and prevention procedures. • Emergency response procedures must be in place. • You must post emergency contact information next to the telephone. • You must develop and maintain a written inspection program. • You must obtain an EPA Identification Number. • You must train your personnel. • You must manifest your waste using the uniform hazardous waste manifest. • You must comply with Department of Transportation rules. • You must “close” your hazardous waste storage area in accordance with the regulations if you discontinue its use. • You must certify on manifests that a good faith effort has been made to minimize hazardous waste generation. • You must either comply with Universal Waste rules or manage the waste as hazardous. • You must comply with Used Oil requirements. Source reduction works! Less waste means fewer regulatory requirements! Large Quantity Generator (LQG) You are a LQG if you generate 2,200 pounds or approximately 260 gallons (1,000 kg) or more of hazardous waste per calendar month, or more than 2.2 lbs (1 kg) of acute hazardous waste. The following list summarizes the specific requirements applicable to LQGs: • You must perform and maintain waste determinations. • You can only store waste on-site for less than 90 days. • There is no quantity limit to on-site accumulation. • Waste can accumulate in containers, tanks, or containment buildings. • You must comply with preparedness and prevention procedures. SQG Guidance Manual 16 What is my Status?
• You must develop and maintain a written contingency plan. • You must develop and maintain a written inspection program. • You must maintain an annual personnel training program and written job descriptions. • You must obtain an EPA Identification Number. • You must manifest your waste using the uniform hazardous waste manifest. • You must comply with Department of Transportation rules. • A biennial report must be completed and submitted to CTDEP. • You must “close” your hazardous waste storage area in accordance with the regulations if you discontinue its use. • You must prepare a written waste minimization program. • You must comply with applicable air emission standards. • You must comply with Universal Waste rules or manage the waste as hazardous. • You must comply with Used Oil requirements. Note: Since this guide is geared towards SQGs, we will not spend more time on this topic. Requirements such as the contingency plan, waste minimization plan and biennial report (at its full extent) are not required for SQGs and therefore will not be covered. See the additional clues and hints at the end of this section if you suspect that you may be an LQG. What do I do if I exceed my allowable generation rates in a calendar month? If this was a unique occurrence due to an unforeseeable/infrequent event, you may be an episodic generator. If this becomes a common occurrence, you may be required to change your generator status. The following table provides additional guidance. Episodic Generator Change Generator Status If Monthly Generation Rate Exceedance If Monthly Generation Rate Exceedance is is an Unforeseeable/Infrequent Event a Common Occurrence 1. Manage generated waste in 1. Notify CTDEP in writing compliance with applicable 2. Complete Form 8700-12 which can generator classification (see above) be found at www.epa.gov and 2. Document monthly generation rates submit to CTDEP. 3. Document accumulation rates 3. Comply with new generator 4. Minimize potential for reoccurrence classification requirements (see of episodic generation above) SQG Guidance Manual 17 What is my Status?
When applying for an EPA Identification Number, a generator should register with CTDEP for their "worst case" generator category. For example, if a generator operates as an SQG during some months and as an LQG during other months, the generator should notify as an LQG and comply with all applicable requirements. If your generator status permanently changes from your original notification, contact CTDEP at 888-424-4193 to obtain the necessary forms to properly change your status. The conversion chart below provides general guidance to help visualize the specific generation quantities for each generator classification. Conversion Chart Kilograms Pounds Gallons* 55 Gal Drums 100 kg 220 lbs 26 gal ½ drum 1,000 kg 2,200 lbs 260 gal 3 to 5 drums *Assumes waste is same approximate density as water. EXERCISE 3-1 Company G generates wastes that have been characterized as hazardous. To determine if the company is a Small Quantity Generator (SQG) or Large Quantity Generator (LQG), the generator performed a review of inventory and shipping documents involving waste generation rate and quantity. 1. The generator reviewed its generation rate inventory for a period of six months. Total Hazardous Waste Generated Quantity Number Month Total (gal) Total (lb/kg)* (gal) of drums January 55 6 330 2,640/1,200 February 0 0 0 0/0 March 55 5 275 2,200/1,000 April 55 3 165 1,320/600 May 55 3 165 1,320/600 June 55 6 330 2,640/1,200 *Assumes a density of 8 pounds per gallon * Approximately 2.2 pounds per kilogram SQG Guidance Manual 18 What is my Status?
EXERCISE 3-1 (cont) 2. The generator reviewed its manifests for a period of six months. Total Hazardous Waste Manifested Number Waste Quantity of Total Total Remaining in Month (gal) drums (gal) (lb/kg)* Storage* (lb/kg) January 55 3 165 1,320/600 1,320/600 February 0 0 0 0/0 1,320/600 March 0 0 0 0/0 3,520/1,600 April 55 5 275 2,200/1,000 2,640/1,200 May 55 2 110 880/400 3,080/1,400 June 55 4 220 1,760/800 3,960/1,800 *Assumes a density of 8 pounds per gallon * Approximately 2.2 pounds per kilogram It has been concluded that the generator is a (LQG) because its total hazardous waste generated is greater than 1,000 kg (2,200 lbs or 260 gal) per calendar month. (It also appears that the generator may be storing waste for more than 180 days.) The generator will need to comply with the regulatory requirements that apply to an (LQG). Minimize Your Size! If you minimize the amount of waste you generate, you will minimize your compliance obligations! Waste minimization may also help by reducing: • The quantity and toxicity of hazardous and solid waste generation • Waste management costs • Raw material and product losses • Raw material purchase costs • Waste management recordkeeping and paperwork burden • Workplace accidents and worker exposure • Compliance violations • Environmental liability SQG Guidance Manual 19 What is my Status?
At the same time, waste minimization can improve: • Production efficiency • Profits • Community relations • Employee participation and morale • Product quality • Overall environmental performance Two common approaches are source reduction and recycling. Both of these methods are useful to prevent waste from even being generated and if generated, the waste can be reused and not disposed. The inverted waste pyramid diagram below shows the common approaches to deal with waste. The tip of this inverted pyramid represents the least favorable approach whereas the top of the pyramid is where you would like to take your waste disposal practices. SQG Guidance Manual 20 What is my Status?
Presented below is a summary of requirements for each waste generator classification discussed in this chapter. It is important to determine the type of generator that you are so that you comply with each requirement. Table 3-1 – General Summary Chart CESQGs SQGs LQGs Quantity Limits ≤100 kg/month Between 100 - 1,000 ≥1,000 kg/month ≤1 kg/month of acute kg/month >1 kg/month of acute hazardous waste ≤1 kg/month of acute hazardous waste ≤100 kg/month of hazardous waste >100 kg/month of acute spill residue or ≤100 kg/month of acute spill residue or soil acute spill residue or soil soil EPA ID Number Not required Required Required ≤1,000 kg ≤1,000 kg No limit On-Site ≤1 kg acute ≤1 kg acute Accumulation ≤100 kg of acute spill ≤100 kg of acute spill Quantity residue or soil residue or soil Accumulation Time None ≤180 days ≤90 days Limits Storage None Containment and Full compliance for Requirements management management of tanks, requirements for containers, drip pads, tanks or containers or containment (see text) buildings State approved or RCRA RCRA RCRA permitted/interim permitted/interim Sent To: permitted/interim status facility status facility status facility Manifest Not required Required Required Biennial Report Not required Not required Required Basic training Personnel Training Not required Required required Contingency Plan Not required Basic procedures Full plan required Emergency Not required Required Full plan required Procedures Inspection Not required Required Required Program DOT Transport If required by DOT Yes Yes Requirements SQG Guidance Manual 21 What is my Status?
Episodic Generator – A generator of hazardous waste who infrequently exceeds their allowable generation rate. Generate – This term refers to the act or process of creating hazardous waste as identified or listed in Part 261 of the EPA regulations. If you generate, you are now considered a generator of hazardous waste. Manifest – This term refers to the shipment of hazardous waste from a facility for disposal using the Uniform Hazardous Waste Manifest (more on this later!). Source Reduction – Any action that reduces the amount of waste exiting from a process (waste avoidance). These actions can include: • Process modification • Chemical substitution • Improvements in chemical purity • Improvements in housekeeping • Improvements in management practices • Increase in machine efficiency • Recycling within process • Inventory management Treatment, Storage and Disposal Facility (TSDF) – A facility that has received interim status or a permit for the treatment, storage or disposal of hazardous waste. A CESQG guidance manual is available from CTDEP and is entitled “Conditionally Exempt Small Quantity Generator Handbook – Guidance for Hazardous Waste Handlers”: http://www.ct.gov/dep/lib/dep/waste_management_and_disposal/hazardous _waste/cesqghandbook.pdf LQG guidance and other waste guidance are available from EPA at the following website: http://www.epa.gov/epawaste/hazard/index.htm Guidance and information regarding DOT rules and regulations for the shipment of wastes is available at the following website published by DOT: http://www.phmsa.dot.gov/hazmat/guidance SQG Guidance Manual 22 What is my Status?
Section 4 WE HAVE HAZARDOUS WASTE….SO NOW WHAT? So, now that you have identified that you are a SQG, what do you need to do? You need to manage your waste in compliance with Connecticut hazardous waste regulations. SQGs are allowed to store/accumulate waste in containers in designated Hazardous Waste Storage Areas (HWSA) and satellite accumulation areas. Container Specifics What is a container? A container is a portable In addition to the device in which a material is stored, transported, requirements listed to the left, treated, disposed of, or otherwise handled. use DOT-approved containers to store your waste. If this is The following rules apply to you when waste is stored not done, the waste you in containers: manage on-site will need to be transferred to or over- packed into approved • Containers containers prior to transport. must be free of cracks, rust, holes, and dents. • Containers or container liners must be compatible with the materials being stored. • Containers must be closed unless you are physically adding or removing waste. • Containers must be clearly marked with the words “Hazardous Waste” and other words to describe the waste, such as the chemical name. SQG Guidance Manual 23 We Have Hazardous Waste…So Now What?
What are the marking and labeling requirements? Hazardous waste containers must be marked with the following information when they are offered for transport: • “Hazardous Waste” and other Employees responsible for offering waste words to describe the waste, such for transport (i.e., drumming, labeling, as the chemical name and a signing manifests and loading) must warning statement receive initial DOT training within 90 days • Generator’s name and address of hire. Refresher training is required • Generator’s EPA identification every three years! number • Manifest document number • Accumulation start date • DOT shipping name and ID number In addition, DOT pre-transport requirements do apply before you ship All waste generated by an SQG with listed and/or characteristic hazardous waste. In general, you must waste codes are regulated by the affix applicable DOT primary and DOT when offered for secondary labels to the container when transportation. they are offered for transport and ship wastes in DOT approved containers. Additional labels may be required depending on the specific shipment and/or container. When are my containers “empty”? DOT, OSHA and EPA all have different definitions of “empty”. For the purposes of this guide, only the RCRA requirements will be discussed. The following is a summary of the standards for rendering a container or inner liner RCRA empty. Non-Acutely Hazardous Waste A container or an inner liner from a container holding non-acute hazardous waste (i.e. D, F, K, and U-listed wastes not designated with hazard Code H) is empty when: • Wastes have been removed using practices commonly employed to remove wastes from containers or liners, such as pouring, pumping, aspirating, and draining, and • No more than 2.5 centimeters (1 inch) of material remains in the container or liner, or SQG Guidance Manual 24 We Have Hazardous Waste…So Now What?
• No more than 3 percent by weight of the container remains for containers with a capacity of 110 gallons or less, and no more than 0.3 percent by weight remains for containers with a capacity greater than 110 gallons. Acutely Hazardous Waste A container or inner liner of a container holding acutely hazardous waste (i.e. P-listed wastes and other hazardous wastes with the designated hazard code H) is empty when one of the following conditions is met: • The container has an inner liner that prevents contact with the container and the liner is removed, or • The container has been triple rinsed with the solvent appropriate for removing the acutely hazardous waste, or • When triple rinsing is not appropriate, an equivalent method is used. The rinsate is considered acutely hazardous waste according to the mixture rule; however, the act of triple rinsing is not considered treatment. Gases Containers holding compressed gases that are hazardous wastes are considered empty when the pressure in the container approaches atmospheric pressure. What additional requirements apply to Hazardous Waste Storage Areas (HWSA)? The HWSA, which is also referred to as the less-than-180 day storage area or LT- 180-area, is where the majority of wastes are stored on-site prior to shipment. In addition to the container rules discussed above, the following additional requirements apply to your main accumulation area(s): • Containers must be stored on a sufficiently impervious surface so that if released, waste cannot penetrate into the floor or soils below the floor. For example, spill pallets and/or an epoxy-coated concrete floor may be used to address this requirement. • Container storage areas must have adequate aisle spacing between the drums (CTDEP recommends a minimum of 36 inches for aisle space). • Containers must have secondary containment of either 10% of the total volume of waste in the area or the volume of the largest storage container in the area, whichever value is greater. • Containers of incompatible waste must be segregated in a fashion that would prevent mixing of waste in the event of a container release or spill. • Each container marking should include an accumulation start date. SQG Guidance Manual 25 We Have Hazardous Waste…So Now What?
• The area should be secure from unauthorized entry/access. • Documented weekly inspections must be performed. See Section 9 of this guidance document for additional information regarding inspections. Maintain as few Hazardous Waste Storage Areas as possible! Remember that each HWSA must be closed in accordance with regulation if they are no longer used. (See Section 12 for more details.) This involves wipe sampling and/or soil and concrete sampling that may lead to remediation if a historical release is detected. Additionally, if you maintain fewer Hazardous Waste Storage Areas, fewer inspections are required and fewer opportunities for non-compliance exist. What is a Satellite Accumulation Area? What do the regulations mean when they say “at or near the To provide for the day-to-day management of point of generation”? A hazardous waste, you may manage your waste simple way to understand this containers in a satellite accumulation area, also concept is by asking “is the commonly referred to as a point of generation (POG). container close enough to verify that: Where can I use satellite accumulation? • the appropriate marking is affixed to the container; • Each container must be located in an area at or • the proper wastes are being near the point of generation. added; • the container is sealed and • Each container must be under the control of the leak proof; and operator of the process generating the waste. • a release or spill has not occurred?” What are the quantity limitations for satellite accumulation? • ≤ 55 gallons of non-acute waste per area per waste stream • ≤ 1-quart of acute waste per area per waste stream If different waste streams are generated from a single point of generation, multiple containers can be used to accumulate these waste streams at one satellite accumulation area. For example, you can operate a satellite accumulation area with up to 55 gallons of paint waste and up to 55 gallons of waste acid as long as the area is at or near the point of generation and under the control of the operator generating the waste. Once the quantity limit has been met, you must write the accumulation start date on the container label. Once the container is full and dated, the 180-day SQG Guidance Manual 26 We Have Hazardous Waste…So Now What?
storage time limit begins. You then have three days to move the container to your HWSA. Note: Waste accumulated in satellite accumulation areas must be counted towards your monthly generation rate. EXERCISE 4-1 Company E operates a painting operation. Hazardous wastes are stored in a 55- gallon drum in another section of the factory away from the painting room as a satellite accumulation area with a label that reads “hazardous waste – paint and thinner waste”. An open funnel continuously remains in the bung hole since the operation is performed three times per week. Is this container in compliance with satellite accumulation requirements? This satellite container is not in compliance because the operator is not in control of the container, it is not near the point of generation and the container is not sealed while not in use. EXERCISE 4-2 After realizing their errors, Company E relocates the drum to the painting room and closes the top when the container is not being filled. The drum became full on Monday. Remembering his hazardous waste training, the painter places a start date on the full drum. It is now Friday, and the technician responsible for moving wastes to the hazardous waste storage area has been out sick all week. The painter starts using a new drum and places it with the full drum while he awaits removal. Is this satellite accumulation area in compliance? Unfortunately, this satellite accumulation area is not in compliance since the full drum was not moved to the hazardous waste storage area within three days and there is now greater than 55 gallons of hazardous waste at one accumulation area. The painter would have to move the full drum himself to the hazardous waste storage area or now manage his satellite accumulation area as a main hazardous waste storage area (not a good idea!). SQG Guidance Manual 27 We Have Hazardous Waste…So Now What?
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